A kind of polyacrylic polymer and preparation method thereof
Technical field
The present invention relates to the chemical composition technical field, relate in particular to scratch resistance wound, high gloss, flame-proof polypropelene composition and preparation method thereof.
Background technology
Advantages such as polypropylene has light weight, is easy to machine-shaping as a kind of general-purpose plastics, and thermotolerance and chemical resistance are good, mechanical mechanics property is good, thereby be widely used in industries such as automobile, building, electronic apparatus.And partially modified polypropylene product replaces the higher engineering plastics of price gradually.But because polyacrylic oxygen index only has about 17.4, meet that fire is inflammable, thermal value is high, combustionvelocity is fast and be fuming, drip phenomenon, thereby its Application Areas is restricted.
In electronic enterprises, for switch on wall, power connector, socket etc., because of its directly with electrically contact, so the flame retardant resistance of material is required very high, so the used acrylic plastering of electronic apparatus is carried out flame-retardant modified being very important.
Wherein, very high for the surface requirements of electrician's panel material, wish that the surface not only has high gloss but also have the scoring resistance energy.General polypropylene glossiness is not enough, can by with nucleator or adopt consistency preferably fire retardant etc. improve glossiness, but its scoring resistance can descend after improving glossiness.Equally, general polypropylene scoring resistance is bad, can add the alloy type scratch resistance and hinder agent or filler etc. and improve its scoring resistance energy, but glossiness descends after adding filler.General method is difficult to make glossiness and scoring resistance to improve simultaneously.
Summary of the invention
Purpose of the present invention is exactly that a kind of scratch resistance wound, high gloss, fire-retardant polyacrylic polymer and preparation method thereof are provided in order to overcome the defective that above-mentioned prior art exists.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of polyacrylic polymer is characterized in that, said composition comprises following composition and content (weight part):
Polypropylene 500~800;
Nano filling 100~300;
Fire retardant 50~200;
Oxidation inhibitor 1~10;
Nucleator 1~5;
Dispersion agent 1~5;
Other auxiliary agent 0~10.
Described polypropylene comprises homo-polypropylene or Co-polypropylene, and melting index is 3~60g/10min.
Described Nano filling is made up of one or more compositions in nano-calcium carbonate, nano imvite, nano-sized magnesium hydroxide, mica powder, barium sulfate, the wollastonite.
Described fire retardant comprises brominated epoxy resin, brominated flame retardant and antimonous oxide; Described oxidation inhibitor comprises primary antioxidant and auxiliary anti-oxidant; Described nucleator comprises two benzal Sorbic Acids and derivative thereof, organophosphate compounds, aromatic series metallic soap.
Described fire retardant comprises TDE, eight bromo ether, decabromodiphenyl oxide; Described primary antioxidant comprises hindered phenol and thioesters class; Described auxiliary anti-oxidant comprises the phosphorite class; Described nucleator comprises nucleator 3905, nucleator 3940, nucleator NC-4, nucleator NA-10, nucleator NA-11 and nucleator AL-PTBBA.
Described primary antioxidant comprises antioxidant 1010, oxidation inhibitor DSTDP; Described auxiliary anti-oxidant comprises oxidation inhibitor 168.
Described dispersion agent comprises EBS, calcium stearate.
Described other auxiliary agent comprises tetrafluoroethylene.
A kind of preparation method of polyacrylic polymer, it is characterized in that, polypropylene 500~800 weight parts, Nano filling 100~300 weight parts, fire retardant 50~200 weight parts, oxidation inhibitor 1~10 weight part, nucleator 1~5 weight part, dispersion agent 1~5 weight part and other auxiliary agent 0~10 weight part are put into high-speed mixer and mixing 2~5 minutes, make pre-composition; Again pre-composition is melt extruded granulation in twin screw extruder, add and to add usual auxiliaries as required man-hour.
Compared with prior art, polypropylene flame redardant of the present invention had both had high glossiness, had improved its scoring resistance energy again, thereby more was applicable to the electronic apparatus goods.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
The base mateiral polypropylene is the PPK7726 of Yanshan Petrochemical, TDE and antimonous oxide are fire retardant, nano-calcium carbonate, nano imvite, nano-sized magnesium hydroxide composition are Nano filling, primary antioxidant 1010 and auxiliary anti-oxidant 168 are composite to be oxidation inhibitor, and two (4-tert-butyl-phenyl) phosphoric acid ester sodiums (NA-10) are nucleator.The content of other blend components (weight part) is as follows:
Component (weight part) |
Embodiment 1 |
Polypropylene |
740 |
Nano filling |
200 |
Fire retardant |
60 |
Oxidation inhibitor |
5 |
Nucleator |
3 |
Dispersion agent |
1 |
Said components was placed high-speed mixer and mixing 2~5 minutes, material is placed melt pelletization on the twin screw extruder.Five interval temperature of forcing machine are respectively: 180 ℃ in an interval, 190 ℃ in two intervals, 195 ℃ in 345 intervals.Screw speed is 240rpm.Material is injection molded into the standard batten after water-cooled, pelletizing, drying, for performance test.Wherein, the scoring resistance testing method adopt to be intersected cut spalling test machine (grid trier), and the scratch pin marks 11 * 11 grids that are spaced apart 1mm, 3 times repeatedly under 300g load.Be divided into 5 grades according to visual observation: 5 grades are no marking; 4 grades for there being shadow scratch; 3 grades for there being obvious cut; 2 grades for there being more significant cut; 1 grade for there being very serious scuffing.
Comparative example 1
Adopt the preparation method identical with embodiment 1, preparation one-component polypropylene (PPK7726), and adopt its physicals of mensuration that uses the same method.The result is as follows:
Test event |
Embodiment 1 |
Comparative example 1 (pure PPK7726) |
Melting index (230 ℃, 2.16kg) g/10min |
16 |
26 |
The scratch grade |
5 grades |
1 grade |
Fire-retardant rank (UL94 vertical combustion method) |
The V2 level |
HB |
Tensile strength MP |
23 |
26.1 |
Modulus in flexure MP |
2100 |
1150 |
Embodiment 2~3
Adopt the method identical with embodiment 1 to prepare and be used to test the sample of physicals, difference is polypropylene, Nano filling content difference.Specific as follows:
Component (weight part) |
Embodiment 2 |
Embodiment 3 |
Polypropylene |
790 |
840 |
Nano filling |
150 |
100 |
Fire retardant |
60 |
60 |
Oxidation inhibitor |
5 |
5 |
Nucleator |
3 |
3 |
Dispersion agent |
1 |
1 |
The test result of embodiment 2~3 is as follows:
Test event |
Embodiment 2 |
Embodiment 3 |
Melting index (230 ℃, 2.16kg) g/10min |
18 |
20 |
The scratch grade |
4 grades |
4 grades |
Fire-retardant rank |
The V2 level |
The V2 level |
Tensile strength MP |
23.7 |
25.1 |
Modulus in flexure MP |
1850 |
1700 |
The present invention has improved the scoring resistance energy by adding nano-filler modified polypropylene when improving its glossiness.This scratch resistance wound, high gloss, polypropylene flame redardant have the performance of every excellence, are applicable to the requirement of hyundai electronics electrician trade especially.
Embodiment 4
A kind of polyacrylic polymer comprises that melting index is homo-polypropylene 500 weight parts, nano-calcium carbonate 100 weight parts, eight bromo ether 50 weight parts, oxidation inhibitor DSTDP 1 weight part of 3g/10min, nucleator 3940, the dispersion agent EBS1 weight part of 1 amount part Millken, above-mentioned raw materials is put into high-speed mixer and mixing 2 minutes, make pre-composition; Again pre-composition is melt extruded granulation in twin screw extruder, add and to add usual auxiliaries as required man-hour.
Embodiment 5
A kind of polyacrylic polymer comprises that melting index is homo-polypropylene 800 weight parts, nano imvite 300 weight parts, antimonous oxide 200 weight parts, 8 weight part antioxidant 1010s of 60g/10min, nucleator AL-PTBBA, dispersion agent calcium stearate 5 weight parts and tetrafluoroethylene 10 weight parts of 2 weight part oxidation inhibitor, 168,5 amounts part Mitsui East Asia chemistry, above-mentioned raw materials is put into high-speed mixer and mixing 5 minutes, make pre-composition; Again pre-composition is melt extruded granulation in twin screw extruder, add and to add usual auxiliaries as required man-hour.