CN101468883A - High-temperature calcination technology for 5-10% chromic slag, 10-15% fly ash, 20-30% alkaline residue, and 20-35% limestone cement clinker under 1350 DEG C +/- 100 DEG C in vertical kiln - Google Patents
High-temperature calcination technology for 5-10% chromic slag, 10-15% fly ash, 20-30% alkaline residue, and 20-35% limestone cement clinker under 1350 DEG C +/- 100 DEG C in vertical kiln Download PDFInfo
- Publication number
- CN101468883A CN101468883A CNA2007100606308A CN200710060630A CN101468883A CN 101468883 A CN101468883 A CN 101468883A CN A2007100606308 A CNA2007100606308 A CN A2007100606308A CN 200710060630 A CN200710060630 A CN 200710060630A CN 101468883 A CN101468883 A CN 101468883A
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- CN
- China
- Prior art keywords
- chromium
- chromium slag
- slag
- alkaline residue
- shaft kiln
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/44—Burning; Melting
- C04B7/4476—Selection of the kiln atmosphere
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
- C04B7/26—Cements from oil shales, residues or waste other than slag from raw materials containing flue dust, i.e. fly ash
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/364—Avoiding environmental pollution during cement-manufacturing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Environmental & Geological Engineering (AREA)
- Environmental Sciences (AREA)
- Public Health (AREA)
- Furnace Details (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention belongs to treatment and comprehensive utilization technology of chromium slag, which comprises: mixing 5 to 10 percent of chromium slag, 10 to 15 percent of fly ash, 20 to 30 percent of alkali slag and 20 to 35 percent of limestone with coal and clay; evenly mixing, pulverizing, pelletizing and calcining the mixture; and adopting the high-temperature environment of between 1,250 and 1,450 DEG C and carbonic oxide in a vertical kiln to reduce hexavalent chromium in the chromium slag into trivalent chromium, so as to further achieve the aims of detoxification, usage of firing materials of the fly ash and the alkali slag as cement clinker, no secondary pollution, high treatment speed, low cost and reduction of the construction cost.
Description
Technical field
The invention belongs to hazardous solid waste chromium slag and solid waste flyash, the improvement of building waste and comprehensive utilization technique, be particularly related to and utilize mechanical shaft kiln high-temperature to administer sexavalent chrome and chromium slag and flyash in the chromium slag, alkaline residue, the technology of limestone calcination, with the chromium slag, flyash, alkaline residue, Wingdale and coal, clay all mixes, abrasive dust, balling-up, calcining, utilizing in the shaft kiln 1350 ℃ ± 100 ℃ of high temperature and carbon monoxide environment to make hexavalent chrome reduction is trivalent chromium, but and then reach toxicide and burn till material making cement grog, do not produce secondary pollution, improvement speed is fast, and expense is low, reduces construction costs.
Background technology
Because it is big that a large amount of chromium slags that traditional chromic salts industry discharged lack the improvement amount, expense is low, and the improvement method of non-secondary pollution causes the chromium slag that environment is caused severe contamination, has restricted the development of chromic salts industry to a great extent even is forced to stop production.In addition, coal-fired industry produces a large amount of flyash, and chemical industry produces a large amount of alkaline residue contaminate environment, and loft need are rationally disposed.Dispose chromium slag, flyash, alkaline residue comprehensive utilization technique with shaft kiln, at home and abroad there is no report.The present invention is with 1350 ℃ ± 100 ℃ temperature and the processing condition of shaft kiln calcination cement clinker, utilize 1350 ℃ ± 100 ℃ high temperature, reduzate and acidic conditions are nontoxic trivalent chromium with the hexavalent chrome reduction in the chromium slag, and add flyash, alkaline residue realization resource utilization, through engineering approaches, particularly break through the expense height, improvement speed is slow, realizes social benefit, environmental benefit, economic benefit is obvious, is task of the present invention.
Summary of the invention
The present invention makes in the chromium slag hexavalent chrome reduction for not causing the trivalent chromium of secondary pollution with the reducing atmosphere that 1350 ℃ ± 100 ℃ high temperature of shaft kiln calcination cement clinker and dying fire operation produce.The present invention is a method of utilizing shaft kiln high-temperature calcination chrome slag dry detoxified chromium slag of the high temperature reduction and detoxication method that generally adopts both at home and abroad being improved formation, forms the technology that a kind of chromium slag, flyash, alkaline residue, limestone calcination become cement clinker.
The present invention gives the effect that shaft kiln has 1350 ℃ ± 100 ℃ high temperature, carbon monoxide reduction and detoxication, 5-10% chromium slag 10-15% flyash 20-30% alkaline residue 20-35% Wingdale and coal, clay are all mixed, abrasive dust, balling-up, the chromium slag under shaft kiln dying fire operation through preheating zone, thermal zone, make that hexavalent chrome reduction is a trivalent chromium in the chromium slag, and be fixed in the molten mass, enter cooling zone and put and burn till material exit quick cooling or the high pressure water anti-oxidation of shrend rapidly, principal reaction is as follows: under alkaline condition during greater than 500 ℃: CrO
3+ 3/2O
2=2CrO
3, at 700～800 ℃, shrend produces hydrogen and carbon monoxide: C+H
2O=H
2+ CO stops chromic diffuse pollution in the chromium slag; Utilize shaft kiln high-temperature and carbon monoxide reductive action with 1350 ℃ ± 100 ℃ high temperature in sexavalent chrome and the kiln in the chromium slag and carbon monoxide environment, be reduced to nontoxic trivalent chromium, and generate more stable complex compound, the chromium slag is detoxified.Simultaneously, chromium slag, flyash, alkaline residue, limestone calcination become cement clinker.Present method utilizes shaft kiln high-temperature to administer chromium slag, flyash, alkaline residue in a large number, and the essence of its engineering construction is the technology that forms a detoxifcation simple in structure and resource utilization.Be not afraid of after chromium slag, flyash, the dreg control on the one hand and scatter, run off, the permanent material of infiltration creates conditions again on the other hand and makes full use of the character of the physical mechanics that burns till material, but the making cement grog is realized comprehensive utilization.
Dry detoxified being meant of 1350 ℃ ± 100 ℃ high temperature reductions of indication of the present invention contains 1350 ℃ ± 100 ℃ of shaft kiln high-temperatures, carbon monoxide reduction mechanism, the incinerating sintered material is arranged in the reducing substances environment when 500 ℃ of dischargings through calcining in about seven hours, quick cooling (shrend is better) prevents oxygenizement to the trivalent chromium that has been reduced in the chromium slag.
It is a kind of 1350 ℃ ± 100 ℃ high temperature, carbon monoxide condition utilized that the present invention utilizes the idle dry detoxified method of machine vertical kiln special calcination chrome slag in cement mill; Being to adopt to administer the comprehensive utilization technique of the sophisticated high-temperature detoxification technology of chromium slag after improving both at home and abroad, is a safe non-secondary pollution, economic benefit, and social benefit, environmental benefit significantly fully utilize the technology of chromium slag, flyash, alkaline residue.
Description of drawings
Accompanying drawing is the structural representation of present method
Embodiment
Below in conjunction with accompanying drawing present method is further described
Embodiment 1
Press the engineering synoptic diagram of Fig. 1, chromium slag, flyash, alkaline residue, Wingdale pulverizing are placed in the dryer and dry, enter raw grinding respectively through batching scale and coal, clay, alkaline residue then, enter the homogenizing storehouse, again through lift, add water, balling-up in advance, going into shaft kiln high-temperature burns till, at shaft kiln through preheating zone, thermal zone, cooling zone, the time (see figure 2) is 1350 ℃ ± 100 ℃ of high temperature about seven hours, burn till material in the carbon monoxide environment, relevant chromic regulation Zhi Shuo ≦ 1.5mg/L becomes cement clinker in the judging standard.
Claims (4)
1, a kind of the chromium slag is used for the high temperature of machine shaft kiln 1350 DEG C ± 100 ℃, carbon monoxide forms chromium residue detoxifying and flyash, alkaline residue resource technology to hexavalent chrome reduction mechanism in the chromium slag; Burning till material after the detoxifcation is: utilize machine shaft kiln 1350 DEG C ± 100 ℃ high temperature, 5-10% chromium slag 10-15% flyash 20-30% alkaline residue 20-35% Wingdale enters thermal zone 1350 ℃ ± 100 ℃ through the preheating zone under the carbon monoxide reductive condition under the operation of machine shaft kiln dying fire, make that hexavalent chrome reduction is a trivalent chromium in the chromium slag, after entering cooling zone, put and burn till the material exit in 500 ℃ ± 50 ℃ quick cooling or the high pressure water anti-oxidation of shrend rapidly, and then generate stable chromium slag and burn till material, form a safe non-secondary pollution economy, society, the tangible cement clinker technology of environmental benefit.
2, under 1350 ℃ ± 100 ℃ of claim " 1 " high temperature zone temperatures, high-temperature calcination makes hexavalent chrome reduction under reducing atmosphere be trivalent chromium.
3, the preheating zone in claim " 1 " and " 2 " machine shaft kiln is 1350 ℃ ± 100 ℃, and thermal zone 900 ℃, 500 ℃ ± 50 ℃ of cooling zones; Sexavalent chrome in the chromium slag there is the intensive reduction, detoxifies and prevents oxygenizement.
4, the ratio of chromium slag, flyash, alkaline residue, Wingdale and coal, clay in the claim " 1-3 " should be controlled the chromium slag and be advisable at 5-10:10-15:20-30:20-35:15:10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100606308A CN101468883A (en) | 2007-12-28 | 2007-12-28 | High-temperature calcination technology for 5-10% chromic slag, 10-15% fly ash, 20-30% alkaline residue, and 20-35% limestone cement clinker under 1350 DEG C +/- 100 DEG C in vertical kiln |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100606308A CN101468883A (en) | 2007-12-28 | 2007-12-28 | High-temperature calcination technology for 5-10% chromic slag, 10-15% fly ash, 20-30% alkaline residue, and 20-35% limestone cement clinker under 1350 DEG C +/- 100 DEG C in vertical kiln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101468883A true CN101468883A (en) | 2009-07-01 |
Family
ID=40826727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007100606308A Pending CN101468883A (en) | 2007-12-28 | 2007-12-28 | High-temperature calcination technology for 5-10% chromic slag, 10-15% fly ash, 20-30% alkaline residue, and 20-35% limestone cement clinker under 1350 DEG C +/- 100 DEG C in vertical kiln |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101468883A (en) |
-
2007
- 2007-12-28 CN CNA2007100606308A patent/CN101468883A/en active Pending
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Open date: 20090701 |