CN101461365A - Broadspectrum high-efficient polymeric carbamidine disinfecting liquid - Google Patents

Abstract

The invention relates to a broad-spectrum highly active poly-guanidine disinfectant, mainly comprising polyethylene hydroxy guanidine, poly(hexamethylene guanidine) hydrochloride, Is-p double guanidine, bios mixed in proportion into mixture. The broad-spectrum highly active poly-guanidine disinfectant can be used for antibiotic disinfection of all aquiculture industries. Polyethylene hydroxy guanidine, poly(hexamethylene guanidine) hydrochloride, Is-p double guanidine are ramifications of high polymers, as the main antibiotic disinfection components, wherein guanidino in the components has high activity, causing the polymer in electropositivity, adsorbed by all kinds of bacilli and viruses in electronegativity, thereby restraining splitting functions of bacilli and viruses. The film formed by polymer jamps breathing channels of animalcules, chokes to lose life. Under auxiliary effect of bios active materials, through respective activity, entire sterilization effect is completed through synergetic effect. The invention is suitable for antibiotic disinfection of all breeding species in all cultivating fishery, which has the advantages of good effect, toxicological harmless on disinfected human and breeding species, no pollution on water quality and environment; simple operation and using method, and is the antibiotic disinfection product replacing the older products.

Description

Broadspectrum high-efficient polymeric carbamidine disinfecting liquid

Technical field the present invention relates to a kind of Broadspectrum high-efficient polymeric carbamidine disinfecting liquid, its main component be polyethylene hydroxyl guanidine, Polyhaxemethylenguanidine Hydrochloride, just-chlorobenzene biguanides, bios are mixed into mixture in proportion.Broadspectrum high-efficient polymeric carbamidine disinfecting liquid can be used for the antibiotic and sterilizing of various aquaculture industries.Existing professional antibiotic and sterilizing product variety is a lot, common have bleaching powder, bleaching essence, sodium dichloro cyanurate, sym-closene, chlorine dioxide, formalin, potassium permanganate, hydrogen peroxide, Peracetic acid, an acetate etc., the antibiotic and sterilizing performance differs, and the branch of high, medium and low effect is arranged.The content of the valid density of high-effective disinfecting preparation is directly proportional with price often; Influence to water quality is bigger, and disinfectant is heavier to culturing growth effect, and its residual harm is less relatively; Toxic, corrosivity, penetrating odor; Environment there is pollution; To being sterilized article certain shortcomings such as damage are arranged.Therefore, aquaculture industry wishes that a kind of antibiotic and sterilizing efficient height can be arranged always, safety and stability, environmentally safe, the aquaculture antibiotic and sterilizing product of professional biotype that the water quality that is sterilized and article are not had influence.

Background technology the object of the present invention is to provide a kind of antibiotic and sterilizing preparation that can overcome existing aquaculture sterile products deficiency, has antibiotic and sterilizing efficient height, good stability, to human body and the nonhazardous of aquaculture thing, to the aquaculture sterile products of the professional biotype of characteristics such as environment and water nonpollution, security performance height.

Summary of the invention main points of the present invention are to select suitable component, and rationally be mixed, through a series of modern biotechnologies heat, technology such as dissolving, polymerization, cooling, bag quilt forms a kind of aquaculture antibiotic and sterilizing product---Broadspectrum high-efficient polymeric carbamidine disinfecting liquid.

The prescription following (component and percentage by weight % thereof) that the present invention selects: polyethylene hydroxyl guanidine (0.5-0.8); Polyhaxemethylenguanidine Hydrochloride (0.3-0.8); Just-to chlorobenzene biguanides 0.5-0.8); Bios (0.1-3); Purified water adds to 100.Polyethylene hydroxyl guanidine, Polyhaxemethylenguanidine Hydrochloride, just-be the derivative of high molecular polymer to the chlorobenzene biguanides, as the main sterilizing sterile components, guanidine radicals in this component has very high activity in polymerisation, make polymeric derivative be electropositive, so be easy to be usually electronegative each bacterioid, viral adsorbed, thereby the splitting function that has suppressed bacterium, virus, make bacterium, virus lose reproductive function, the film that forms of polymer in addition, stopped up the respiration channel of microorganism, made microorganism suffocate the power of losing one's life and reach sterilization effect.

Bios can be dissolved in acid solution and form the cation group-gucosamine polymer of positively charged, has very high activity, microorganism there is very strong compatibility, so be easy to be usually electronegative each bacterioid, fungi, viral adsorbed, thereby suppressed their schizogamy function; And the film that polymer forms has stopped up the respiration channel of microorganism, makes microorganism death by suffocation and reaches the enhancing sterilization effect.

The preparation method of product of the present invention is:

1), rough bios being carried out 45 ℃ with biotechnology in proportion heats, dissolves, purifies, row absorption bag quilt.

2), with polyethylene hydroxyl guanidine, Polyhaxemethylenguanidine Hydrochloride, just-the chlorobenzene biguanides is dissolved in the rearmounted pure water of organic solvent 54 ℃ of heating in proportion, heat again, polymerisation, cool off in the purified water in proportion again.

3), will wrap and be had active bios and join in the cooled polymerization guanidine solution by proportioning, stir, join in the reactor, mix and carry out emulsion reaction, carry out packing after the cooling.Check, warehousing after passing.

The present invention has the following advantages: 1). be suitable for the antibiotic and sterilizing of each culture fishery industry, various breed species.2). antibiotic and sterilizing is effective, and is harmless to the breed species that are sterilized sterilization.3). eliminated to human body and culture species poisonous, water quality and environment are had harm such as pollution.4). it is easy to manipulate method, and it can be applied widely.5). the Broadspectrum high-efficient polymeric carbamidine disinfecting liquid of special process preparation is the culture fishery updated sterilizing and disinfecting product.

The present invention is described in further detail below in conjunction with embodiment for embodiment:

Be configured according to listed data of following table (percentage by weight %) and described step thereof:

Prescription one:

Polyethylene hydroxyl guanidine 0.5-0.8

Polyhaxemethylenguanidine Hydrochloride 0.3-0.8

Just-to chlorobenzene biguanides 0.5-0.8

Bios 0.1-3.0

Purified water adds to 100

Prescription two:

Polyethylene hydroxyl guanidine 0.5-0.7

Polyhaxemethylenguanidine Hydrochloride 0.3-0.6

Just-to chlorobenzene biguanides 0.5-0.7

Bios 0.1-2.0

Purified water adds to 100

Prescription three:

Polyethylene hydroxyl guanidine 0.6-0.8

Polyhaxemethylenguanidine Hydrochloride 0.5-0.8

Just-to chlorobenzene biguanides 0.6-0.8

Bios 1.0-3.0

Purified water adds to 100

Prescription four:

Polyethylene hydroxyl guanidine 0.5-0.6

Polyhaxemethylenguanidine Hydrochloride 0.3-0.6

Just-to chlorobenzene biguanides 0.5-0.6

Bios 0.1-2.5

Purified water adds to 100.

Claims (2)

1, a kind of Broadspectrum high-efficient polymeric carbamidine disinfecting liquid, its main component be polyethylene hydroxyl guanidine, Polyhaxemethylenguanidine Hydrochloride, just-chlorobenzene biguanides, bios are mixed into mixture in proportion; It is characterized in that having following prescription (component and percentage by weight % thereof): polyethylene hydroxyl guanidine (0.5-0.8); Polyhaxemethylenguanidine Hydrochloride (0.3-0.8); Just-to chlorobenzene biguanides 0.5-0.8); Bios (0.1-3); Purified water adds to 100.

2, the preparation method of the described Broadspectrum high-efficient polymeric carbamidine disinfecting liquid of a kind of claim 1 is characterized in that having following step:

1), rough bios being carried out 45 ℃ with biotechnology in proportion heats, dissolves, purifies, row absorption bag quilt;

2), with polyethylene hydroxyl guanidine, Polyhaxemethylenguanidine Hydrochloride, just-the chlorobenzene biguanides is dissolved in the rearmounted pure water of organic solvent 54 ℃ of heating in proportion, heat again, polymerisation, cool off in the purified water in proportion again;

3), will wrap and be had active bios and join in the cooled polymerization guanidine solution by proportioning, stir, join in the reactor, mix and carry out emulsion reaction, carry out packing after the cooling.Check, warehousing after passing.