CN101457282A - Processing method of marine vehicle diesel cylinder sleeve erosion resistance - Google Patents

Processing method of marine vehicle diesel cylinder sleeve erosion resistance Download PDF

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Publication number
CN101457282A
CN101457282A CNA2008102496491A CN200810249649A CN101457282A CN 101457282 A CN101457282 A CN 101457282A CN A2008102496491 A CNA2008102496491 A CN A2008102496491A CN 200810249649 A CN200810249649 A CN 200810249649A CN 101457282 A CN101457282 A CN 101457282A
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China
Prior art keywords
cylinder sleeve
high energy
energy beam
cast iron
cylinder liner
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CNA2008102496491A
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Chinese (zh)
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李惠琪
李敏
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Shandong University of Science and Technology
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Shandong University of Science and Technology
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Priority to CNA2008102496491A priority Critical patent/CN101457282A/en
Publication of CN101457282A publication Critical patent/CN101457282A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an anti-cavitation treatment method of a cylinder liner of a marine diesel engine. The implementation steps are as follows: a machined cast iron cylinder liner is positioned on a rotary device, and one side of the cylinder liner is provided with a high energy beam generation device which is capable of being in relative motion with the cylinder liner along the axial direction of the cylinder liner at uniform velocity. The high energy beams irradiates the surface of a water-cooling part of an external wall of the cylinder liner to be sequentially melted and rapidly frozen to form a chill. The anti-cavitation service life of the chill is longer than that of a nitrided layer. In the method, the anti-cavitation capacity of a white cast iron layer produced on the surface of a grey cast iron cylinder liner is far higher than that of the grey cast iron, the method does not has the problem of easy exfoliation due to poor binding force, and the whole production course does not produce environmental pollution.

Description

A kind of treatment process of marine vehicle diesel cylinder sleeve erosion resistance
Technical field
The invention belongs to material corrosion and guard technology field, relate in particular to the treatment process of boat diesel engine cylinder sleeve.
Background technology
At present, the boats and ships more than 90% all use the water-cooled diesel engine as advancing and generation driving force, and the cylinder sleeve of diesel engine cylinder iron casting processing forms.When boat diesel engine is worked for a long time, can produce the fixed vibrational frequency under low rotation speed large torque.When amplitude is in negative pressure, outer wall of cylinder jachet water-cooled position is dissolved in that gas in the cooling fluid comes out with the isolated in form of bubble and attached on the casing wall, these bubbles are crumbled and fall rapidly when vibration amplitude is in malleation, gas dissolves in again volume and local pressure is reduced suddenly, cooling fluid is to the low pressure area high-speed motion, thereby the bubble position of crumbling and fall is produced great surging force and high temperature.Because Cast iron liner is free machining grey cast iron, its interior tissue is the mixed structure of ferrite, perlite and graphite, and wherein ferrite hardness is low, easily viscous deformation, and graphite does not have any intensity, very easily peels off under external force.Above-mentioned in addition mixed structure has constituted a large amount of microcorrosion batteries, makes the collaborative generation of galvanic corrosion and cavitation pitting to have aggravated cavitation pitting destruction.Go round and begin again thus, the top layer of casing wall part surface produces tired and comes off gradually, a large amount of needle-like apertures occurs, is called " cavitation pitting ", and these apertures are expanded gradually, form deep hole or crackle at last.
Existing anti-cavitation pitting surface treatment method has following three kinds:
(1), applies organic composite coating.Its weak point is the heat radiation that influences cylinder sleeve, and shock resistance descends significantly and causes coating shedding under the high temperature.
(2), thermospray zinc-aluminium corrosion protection coating.Its weak point is that zinc-aluminium layer hardness is low, and shock resistance and anti-fatigue performance are poor, and is poor with the bonding force of cast iron, comes off in the form of sheets easily.
(3), nitrogenize.There is not the bonding force problem in this method, and the hardness height, and shock resistance and anti-fatigue performance are good, thereby uses at most at present.But weak point is arranged also, the one: because nitride layer is thinner, nitrogenize can only be last procedure of cylinder sleeve processing, do not allow precision work again after the nitrogenize, but nitridation process needs keeping tens of hours more than 500 ℃, very serious as the cylinder-liner distortion problem of thin wall cylinder precision part, distortion in a single day in these tens of hours, the lighter has destroyed cylinder sleeve piston tolerance clearance aggravation wearing and tearing and vibration, and weight person scraps, and causes production cost sharply to increase; The 2nd, nitrogenize is only carried out on the ferrite surface, and any variation can not take place graphite, and cylinder sleeve in use graphite takes the lead in coming off, and exposes the not ferrite of nitrogenize of bottom, forms a large amount of corrosion microbatterys, has aggravated cavitation pitting speed and has developed into the ulcer corrosion; The 3rd: consume energy big efficient of nitrogenize is low-cost high.
Therefore, the method that does not have a kind of anti-cavitation pitting of feeling quite pleased to handle at present as yet.
Summary of the invention
The objective of the invention is to overcome the deficiency of present three kinds of anti-cavitation pitting surface treatment methods, propose a kind of treatment process of new marine vehicle diesel cylinder sleeve erosion resistance, this method is actual to be to make the Cast iron liner outer wall produce the treatment process that the phase transformation rapidly solidification becomes white cast iron.
For achieving the above object, step of the present invention is as follows:
1, manufactured Cast iron liner is positioned on the swivel arrangement, Cast iron liner one side install one can with cylinder sleeve along the cylinder sleeve axis direction high energy beam current generating unit of relative movement at the uniform velocity.
2, start swivel arrangement cylinder sleeve is rotated around axis, start the high energy beam generating unit, produce high energy beam.
3, high energy beam shines on the surface, outer wall of cylinder jachet water-cooled position and makes it to produce partial instant melting, along with the cylinder sleeve rotation reaches and the at the uniform velocity relative movement of high energy beam along axis direction, surface, outer wall of cylinder jachet water-cooled position finally forms the hard uniform chill of one deck according to helical trajectory fusing and rapid solidification.
The temperature of above-mentioned high energy beam current is not less than 5000 ℃, and beam diameter is not less than 3mm.
Above-mentioned high energy beam can be laser beam, beam-plasma or other gathering high-energy beam.
In order to eliminate the internal stress that rapidly solidification process and casting are before this produced with roughing, the present invention can be according to following operation production:
Cylinder sleeve casting → roughing → high energy beam rapidly solidification → stress relieving → precision work.Be specially;
1, the cylinder sleeve casting first roughing in back is worked into the finished figure paper size with outer wall of cylinder jachet water-cooled position, and other precision-fit faces leave certain allowance for finish;
2, undertaken by aforesaid the 1st, 2,3 steps;
3, with cylinder sleeve annealing, eliminate all internal stresss that produce before this;
4, press drawing precision work, eliminate all distortion that produce before this.
The Cast iron liner of handling through aforesaid method can anti-cavitation pitting principle be:
Because cavitation pitting be when cavity is crumbled and fall, produce the violent viscous deformation in high-speed micro-jet atarting material surface and the material surface crack initiation that causes, expansion, local fracture so that peel off, so the hardness of material surface is high more, viscous deformation is difficult more, just difficult more generation of cavitation pitting.After grey cast iron refuse and quick cooled and solidified, graphite can all be dissolved in the iron, forms and the diverse white cast iron of grey cast iron interior tissue.The interior tissue of white cast iron is single cementite.Cementite is a kind of very hard iron-carbon compound, can produce viscous deformation hardly, and cementite has higher thermal conductivity and erosion resistance, and single organizing yet can not form corrosion cell, and therefore anti-cavitation pitting ability is higher than grey cast iron far away.
The high energy beam rapidly solidification is only handled outer wall of cylinder jachet water-cooled position, does not relate to other precision-fit faces.
Positively effect of the present invention is: 1, the white cast iron layer that generates on grey cast iron cylinder sleeve surface is made up of single cementite, the hardness height, and thermal conductivity is good, and anti-cavitation pitting ability is higher than grey cast iron far away.Chill is to generate on the basis of cylinder sleeve self fusing, does not therefore have the flaky problem of bonding force difference; 2, chill thickness is controlled easily, and thickness is much larger than nitride layer thickness, and does not have graphite and be mingled with, and the whole anti-cavitation pitting life-span is higher than nitride layer; 3, consolidation whitening operation can be carried out before stress relieving and precision work, had eliminated all internal stresss and distortion that cylinder sleeve produces before this; 4, production technique is simple, the efficient height, and less energy consumption, no waste product, production process does not produce environmental pollution.
Description of drawings
Fig. 1 is the relative cavitation pitting performance comparison diagram behind 12 hours cavitation pittings, and curve is the outer wall of cylinder jachet sample cavitation pitting weight-loss curve of three kinds of situations among the figure, and ordinate represents that accumulative total is weightless, and unit is a milligram, and abscissa is the cavitation pitting time, and unit is hour.
Fig. 2 is the surface topography contrast photo of Cast iron liner after 8 hours ultrasonic wave are quickened the cavitation pitting processing, wherein figure (a) is the erosion profile without any processing cylinder sleeve sample, figure (b) is the erosion profile of cylinder sleeve sample after nitriding is handled, the erosion profile of figure (c) cylinder sleeve sample after rapidly solidification is handled.
Embodiment
Enforcement of the present invention no longer repeats at this as described in the summary of the invention.
The front further specifies effect of the present invention in conjunction with Fig. 1 Fig. 2 again.
Find out that by Fig. 1 the trust of anti-cave performance that the anti-relatively cavitation pitting performance comparison diagram behind 12 hours cavitation pittings, rapidly solidification are handled cylinder sleeve is 1.36 times that nitriding is handled, and is 4.48 times without any processing.From the development trend of weight-loss curve, along with the prolongation of time, above-mentioned gap also can continue to enlarge.
As seen from Figure 2, (Fig. 2 a) cavitation pitting and galvanic corrosion is very serious, and the top layer part comes off fully, and the bottom still has a large amount of darker cavitation pittings hole, is cellular distribution on unprocessed surface.Nitriding treat surface (Fig. 2 b) cavitation pitting is cheated network-like distribution, and the cavitation pitting hole is darker, has produced serious ulcer corrosion, and textura epidermoidea partly comes off.Surface melting treat surface (Fig. 2 c) has only the subregion more shallow cavitation pitting hole to occur, is interrupted spot distribution.

Claims (4)

1. the treatment process of a marine vehicle diesel cylinder sleeve erosion resistance is characterized in that, step is as follows:
The first step: manufactured Cast iron liner is positioned on the swivel arrangement, Cast iron liner one side install one can with cylinder sleeve along the cylinder sleeve axis direction high energy beam current generating unit of relative movement at the uniform velocity;
Second step: start swivel arrangement cylinder sleeve is rotated around axis, start the high energy beam generating unit, produce high energy beam;
The 3rd step: high energy beam shines on the surface, outer wall of cylinder jachet water-cooled position and makes it to produce partial instant melting, along with the cylinder sleeve rotation reaches and the at the uniform velocity relative movement of high energy beam along axis direction, surface, outer wall of cylinder jachet water-cooled position finally forms the hard uniform chill of one deck according to helical trajectory fusing and rapid solidification.
2, the treatment process of marine vehicle diesel cylinder sleeve erosion resistance as claimed in claim 1 is characterized in that, step is as follows:
The first step: the cylinder sleeve casting first roughing in back, outer wall of cylinder jachet water-cooled position is worked into the finished figure paper size, other precision-fit faces leave certain allowance for finish;
Second step: carry out according to the described steps in sequence of claim 1;
The 3rd step:, eliminate all internal stresss that produce before this with cylinder sleeve annealing;
The 4th step: press drawing precision work, eliminate all distortion that produce before this.
3, the treatment process of marine vehicle diesel cylinder sleeve erosion resistance as claimed in claim 1 or 2 is characterized in that, the temperature of described high energy beam current is not less than 5000 ℃, and beam diameter is not less than 3mm.
4, the treatment process of marine vehicle diesel cylinder sleeve erosion resistance as claimed in claim 1 or 2 is characterized in that, described high energy beam is laser beam, beam-plasma or assembles high-energy beam.
CNA2008102496491A 2008-12-25 2008-12-25 Processing method of marine vehicle diesel cylinder sleeve erosion resistance Pending CN101457282A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2008102496491A CN101457282A (en) 2008-12-25 2008-12-25 Processing method of marine vehicle diesel cylinder sleeve erosion resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2008102496491A CN101457282A (en) 2008-12-25 2008-12-25 Processing method of marine vehicle diesel cylinder sleeve erosion resistance

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CN101457282A true CN101457282A (en) 2009-06-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104911303A (en) * 2015-07-07 2015-09-16 中原内配集团股份有限公司 Surface micro-melting treated cylinder jacket and preparation method thereof
CN108611484A (en) * 2018-08-08 2018-10-02 广东工业大学 A kind of metal blade laser shock peening method free of surface defects without deformation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104911303A (en) * 2015-07-07 2015-09-16 中原内配集团股份有限公司 Surface micro-melting treated cylinder jacket and preparation method thereof
CN108611484A (en) * 2018-08-08 2018-10-02 广东工业大学 A kind of metal blade laser shock peening method free of surface defects without deformation

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Open date: 20090617