CN101428757A - Water-lysis aluminum hydrogen production formula - Google Patents
Water-lysis aluminum hydrogen production formula Download PDFInfo
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- CN101428757A CN101428757A CNA2008102291735A CN200810229173A CN101428757A CN 101428757 A CN101428757 A CN 101428757A CN A2008102291735 A CNA2008102291735 A CN A2008102291735A CN 200810229173 A CN200810229173 A CN 200810229173A CN 101428757 A CN101428757 A CN 101428757A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The invention relates to a formulation for producing hydrogen through water-aluminum decomposition, and belongs to the technical field of the thermochemical hydrogen production. At present, typical thermochemical cycle hydrogen production processes include a Markl process (Italy), a UT-3 process (Japan), a sulfuration cycle (America), a sulfur-iodine cycle (America), an iodine-lithium cycle (America), a chlorine-ferrum-magnesium cycle (America) and the like. In the processes, pollution exists in part of processes, potential safety hazards exist in part of processes, while equipment in part of processes is cumbersome, so that all the processes are not suitable for vehicles. The invention provides the formulation for producing the hydrogen through water-aluminum decomposition; the formulation mainly comprises AI, AII3, AIBr3, AICI3, water and the like. The invention has the beneficial effects that the hydrogen produced through a self-control pressure-stabilizing device for producing the hydrogen through water-aluminum decomposition can replace a part of gasoline and diesel and be used for a hydrogen and oil mix-combustion internal-combustion engine, so that the oil saving rate is about 30 percent; in addition, the invention can supply the hydrogen to hydrogen fuel cells on the vehicles, and is more suitable for supplying the hydrogen to ships and submarines taking the hydrogen fuel cells as power because half of important hydrogen production materials is the water; and if an electromagnetic propeller made of superconducting coils provides the power for warships and the submarines, the warships and the submarines have no smoke extraction, low noise and high time speed, so that the submarines have higher concealment performance and safety.
Description
Technical field
The present invention relates to a kind of hydrolyzed aluminum hydrogen production formula, belong to the thermochemical cycle for hydrogen production technical field.
Background technology
Many known, typical thermochemical cycle for hydrogen production technology has Markl technology (meaning), UT-3 technology (day), vulcanisation cycle (U.S.), sulphur iodine circulation (U.S.), iodine lithium circulation (U.S.), chlorine iron magnesium circulation (U.S.) etc.Participating in the round-robin metallic element and comprise that Fe, Mg, Cu, Ca, Cd, Li, Cs, Ni etc. are multiple, wherein is (to annotate 1) at most with Fe.In the recent period, domestic have aluminium, water and a mercury chloride hydrogen manufacturing patent disclosure (annotate 2).Aluminium, gallium, the above technological process of water hydrogen manufacturing report (annotating 3) are abroad arranged, and what have has damage ratio as containing mercury etc., and the cost that potential safety hazard is arranged, have that has is height ratio such as gallium etc. too, and the equipment heaviness that has is not suitable for vehicular applications.
Summary of the invention
The invention provides with separating water aluminium and water and auxiliary agent and be combined into a kind of hydrolyzed aluminum hydrogen production formula, comprise in the prescription: separate water aluminium, AII
3, AIBr
3, AICI
36H
2O, KOH, AICI
3, NaOH, by auxiliary agent and the water of separating the preparation of water aluminium and six kinds of chemical materialss, be combined into nine of prescriptions with differential responses speed and character, it is characterized in that: prescription one, separate water aluminium 100g AICI
36H
2O 1～45g water 100～300g; Prescription two is separated water aluminium 100g AICI
31～30g water, 100～300g; Prescription three is separated water aluminium 100g AII
31～20g water, 100～300g; Prescription four is separated water aluminium 100g AIBr
31～25g water, 100～300g; Prescription five is separated water aluminium 100gAII
31～10g AIBr
31～16g water, 100～300g; Prescription six is separated water aluminium 100g AII
31～10g AICI
31～16g water, 100～300g; Prescription seven is separated water aluminium 100g AIBr
31～16g AICI
31～16g water, 100～300g; Prescription eight is separated water aluminium 100g NaOH 50g～180g water 100～300g; Prescription nine is separated water aluminium 100g KOH30g～150g water 100～300g, and more than prescription is selected one as required for use.During use, after selecting for use the prescription material requested to measure respectively by proportioning, be mixed in the plastic tank with weight part, time spent adds water, rise material in the bucket except that separating water aluminium with temperature, and all the other raise with temperature and soluble in water gradually, separate water aluminium and water and react and generate hydrogen and throw out.Temperature of reaction is 1 ℃～100 ℃.
Positively effect of the present invention is: by automatic control voltage regulation type water-lysis aluminum hydrogen production pot, can be mixed fuel of petrol and hydrogen oil engine hydrogen supply, rate of economizing gasoline about 30%; Can be the hydrogen fuel cell hydrogen supply on the vehicles; Being more suitable for the hydrogen fuel cell is boats and ships, the submarine hydrogen supply of power, because half of fuel from water, is warship if make electromagnetic propeller with superconducting coil, submarine provides power, does not then discharge fume friction, low-noise, high speed per hour, submarine has better disguise and security.Also can be hydrogen burner hydrogen supply and be used for life and production.
Description of drawings
Accompanying drawing is that a kind of hydrolyzed aluminum hydrogen production formula is used synoptic diagram.
Among the figure, 1 offlet, 2 bungs, 3 plastic tanks, 4 electric heaters, 5 water, 6 water-soluble auxiliary agent, 7 aluminium, 8 heat exchange water.
Embodiment
A kind of hydrolyzed aluminum hydrogen production formula using method of the present invention:
Select what a prescription earlier, after measuring respectively by the prescription material requested, be mixed in the plastic tank 3, build bung 2 and put in the heat exchange water 8 of electric heater 4.Connect power supply, heat exchange water 8 temperature rise, and the reaction material in the plastic tank 3 is separated water aluminium 7 and water 5 and water-soluble auxiliary agent 6 and is heated simultaneously, along with temperature rising speed of response is accelerated, at this moment, there is the mixed gas of water vapour and hydrogen to discharge, collects the filtrate steam and utilize hydrogen from eduction pipe 1; After the reaction knot speed, the throw out of generation can get Chemicals after treatment, contains the filtrate of auxiliary agent, through clarification purification usefulness capable of circulation.
Annotate 1 " hydrogen storage material " author: the beard dragon is write Chemical Industry Press and publishes P18 in August, 2002.
Annotate 2: patent of invention publication number CN1836773A.
Annotate 3: U.S.'s " science every day " website report on May 18th, 2007.
Claims (2)
1, a kind of hydrolyzed aluminum hydrogen production formula comprises in the prescription: separate water aluminium, AII
3, AIBr
3, AICI
3.6H
2O, KOH, AICI
3, NaOH, by auxiliary agent and the water of separating the preparation of water aluminium and six kinds of chemical materialss, be combined into nine of prescriptions with differential responses speed and character, it is characterized in that: prescription one, separate water aluminium 100g AICI
36H
2O1～45g water 100～300g; Prescription two is separated water aluminium 100g AICI
31～30g water, 100～300g; Prescription three is separated water aluminium 100g AII
31～20g water, 100～300g; Prescription four is separated water aluminium 100g AIBr
31～25g water, 100～300g; Prescription five is separated water aluminium 100g AII
31～10g AIBr
31～16g water, 100～300g; Prescription six is separated water aluminium 100g AII
31～10g AICI
31～16g water, 100～300g; Prescription seven is separated water aluminium 100g AIBr
31～16g AICI
31～16g water, 100～300g; Prescription eight is separated water aluminium 100g NaOH50g～200g water 100～300g; Prescription nine is separated water aluminium 100g KOH30g～150g water 100～300g.
2, a kind of hydrolyzed aluminum hydrogen production formula according to claim 1, it is characterized in that: the temperature of reaction of these nine prescriptions is all 1
0C～100
0Between the C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102291735A CN101428757A (en) | 2008-12-01 | 2008-12-01 | Water-lysis aluminum hydrogen production formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102291735A CN101428757A (en) | 2008-12-01 | 2008-12-01 | Water-lysis aluminum hydrogen production formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101428757A true CN101428757A (en) | 2009-05-13 |
Family
ID=40644440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008102291735A Pending CN101428757A (en) | 2008-12-01 | 2008-12-01 | Water-lysis aluminum hydrogen production formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101428757A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2544652C2 (en) * | 2013-07-30 | 2015-03-20 | Степан Георгиевич Тигунцев | Hydrogen generation method |
| WO2021139688A1 (en) * | 2020-01-06 | 2021-07-15 | 王彩云 | Energy saving system, method, and apparatus of internal combustion engine, and storage medium |
-
2008
- 2008-12-01 CN CNA2008102291735A patent/CN101428757A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2544652C2 (en) * | 2013-07-30 | 2015-03-20 | Степан Георгиевич Тигунцев | Hydrogen generation method |
| WO2021139688A1 (en) * | 2020-01-06 | 2021-07-15 | 王彩云 | Energy saving system, method, and apparatus of internal combustion engine, and storage medium |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090513 |