CN101423787A - Block-formed material of higher fatty acid zinc and method for producing the same - Google Patents
Block-formed material of higher fatty acid zinc and method for producing the same Download PDFInfo
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- CN101423787A CN101423787A CNA2008101842336A CN200810184233A CN101423787A CN 101423787 A CN101423787 A CN 101423787A CN A2008101842336 A CNA2008101842336 A CN A2008101842336A CN 200810184233 A CN200810184233 A CN 200810184233A CN 101423787 A CN101423787 A CN 101423787A
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Abstract
The present invention provides a higher zinc fatty acid block formed body which is obtained through cooling solidifying the fused mass that comprises the raw materials of higher zinc fatty acid, more than 0 wtand less than 0.12 wt21505067f total amount of I-group alkali metal in periodic table and II-group alkaline earth metal in periodic table. The higher zinc fatty acid block formed body has higher durability and high smoothness comprised with the prior higher zinc fatty acid block formed body. The higher zinc fatty acid block formed body can be used as the lubricant, the grinding agent, the cleaning additive, the developing additive, etc. of office devices of electrostatic printer, etc.
Description
Technical field
The present invention relates to block-formed material of higher fatty acid zinc and the manufacture method thereof in office equipment such as xerographic printer and other precision machinery etc., used as lubricant, abrasive, cleaning additive, video picture auxiliary agent etc.
Background technology
In the past, in office equipment such as xerographic printer, used the higher fatty acid metal-salt as lubricant, abrasive, cleaning additive, video picture auxiliary agent etc.This higher fatty acid metal-salt finally uses with powdery, as supply mode, makes higher fatty acid metal-salt consolidated block in advance, with brush etc. with its scrape get after, the mode of supplying with necessary place is just in practicability.
As the known technology relevant with above-mentioned Application Areas, there is the spy to open " purging method of electrofax duplicating machine " of record in the clear 57-97572 communique (patent documentation 1), as assistant composition, there is the spy to open " the electrofax used in copy machines cleaning additive " of record in the clear 57-73774 communique (patent documentation 2).In addition, as the manufacture method of higher fatty acid salt, " the extrusion molding production line of metal soap blank shaping usefulness and the metal soap blank manufacturing process " put down in writing in the melting and solidification method of record in No. 2796486 communique of special permission (patent documentation 3), " extrusion molding apparatus of metal soap blank shaping usefulness and the metal soap blank manufacturing process " of speciallyying permit record in No. 3192371 communique (patent documentation 4), No. 3192391 communique of special permission (patent documentation 5) arranged.
But, all do not mention about the proterties of the fatty acid metal salt of raw material, in the higher fatty acid metal salt block molding that obtains, see crackle, breach, projection, space etc., can not obtain performance sometimes fully as molding.Particularly, if produce the space, in the scraping in use skewness can take place, problems such as quality instability often take place.Therefore, require exploitation flawless, breach, projection, space etc., the higher fatty acid metal salt block molding of stay in grade.
[patent documentation 1] spy opens clear 57-97572 communique
[patent documentation 2] spy opens clear 57-73774 communique
No. 2796486 communique of [patent documentation 3] special permission
No. 3192371 communique of [patent documentation 4] special permission
No. 3192391 communique of [patent documentation 5] special permission
Summary of the invention
The present invention finishes in view of the above fact, being the block-formed material of higher fatty acid zinc that can use well in the office equipment such as xerographic printer, is to be purpose so that block-formed material of higher fatty acid zinc and manufacture method thereof with high-durability and height smoothness to be provided.
The inventor thinks, the reason of the problems referred to above takes place in higher fatty acid metal-salt in the past, is not to be conceived to the purity of the higher fatty acid metal-salt of raw material, and that carries out repeatedly in order to achieve the above object deeply and carefully studying found that, as containing
(1) higher fatty acid zinc, perhaps
(2) higher fatty acid zinc: 100 mass parts, and the metal of from periodictable I family's basic metal and periodictable II family alkaline-earth metal, selecting and from lower fatty acid, the metal-salt of the acid of selecting in higher fatty acid and the inorganic carbonate at least a: metal is become surpass 0 mass parts, and the composition of the amount that 0.10 mass parts is following, with in the composition of the higher fatty acid zinc of (1) or (2), by total amount be below the 0.12 quality % concentration (promptly, surpass 0 quality %, and 0.12 quality % is following) contain periodictable I family's basic metal and periodictable II family alkaline-earth metal as raw material, use is with this raw material heating and melting, make the methods such as raw material inflow casting mold of heating and melting that its cooling curing is obtained the block-formed material of higher fatty acid zinc that the such melting and solidification method of molding obtains, have high-durability and height smoothness, successfully solved above-mentioned problem in the past, finished the present invention thereby reach.
Therefore, the invention provides following block-formed material of higher fatty acid zinc and manufacture method thereof.
[1] block-formed material of higher fatty acid zinc, it is characterized in that, obtain for the heating and melting thing cooling curing that surpasses 0 quality % and the higher fatty acid zinc below the 0.12 quality % by the total amount that makes (A) periodictable I family's basic metal and periodictable II family alkaline-earth metal.
[2] block-formed material of higher fatty acid zinc of [1] record is characterized in that the total amount of periodictable I family's basic metal in the above-mentioned higher fatty acid zinc and periodictable II family alkaline-earth metal is more than the 0.0025 quality %.
[3] block-formed material of higher fatty acid zinc is characterized in that, by to containing
(A) total amount of periodictable I family's basic metal and periodictable II family alkaline-earth metal is for surpassing the following higher fatty acid zinc of 0 quality % and 0.12 quality %: 100 mass parts,
(B) metal-salt of metal of selecting from periodictable I family's basic metal and periodictable II family alkaline-earth metal and the acid selected from lower fatty acid, higher fatty acid and inorganic carbonate is at least a: metal is become surpass 0 mass parts and the amount below 0.10 mass parts,
And by make (A) composition and (B) total amount of the periodictable I family's basic metal in the composition and periodictable II family alkaline-earth metal obtain for the heating and melting thing cooling curing that surpasses 0 quality % and the composition below the 0.12 quality %.
[4] block-formed material of higher fatty acid zinc of [3] record is characterized in that the total amount of periodictable I family's basic metal in the above-mentioned composition and periodictable II family alkaline-earth metal is more than the 0.0025 quality %.
[5] block-formed material of higher fatty acid zinc of putting down in writing in each of [1]～[4] is characterized in that, above-mentioned periodictable I family's basic metal and periodictable II family alkaline-earth metal are the metals of selecting from sodium, potassium, magnesium and calcium more than a kind.
[6] manufacture method of block-formed material of higher fatty acid zinc, it is characterized in that, with the total amount of (A) periodictable I family's basic metal and periodictable II family alkaline-earth metal is to surpass 0 quality % and the following higher fatty acid zinc heating and melting of 0.12 quality %, be injected into molten state in the casting mold more than the fusing point that is preheated to higher fatty acid zinc, make its cooling curing.
[7] manufacture method of block-formed material of higher fatty acid zinc is characterized in that, will contain
(A) total amount of periodictable I family's basic metal and periodictable II family alkaline-earth metal is for surpassing the following higher fatty acid zinc of 0 quality % and 0.12 quality %: 100 mass parts,
(B) metal-salt of metal of selecting from periodictable I family's basic metal and periodictable II family alkaline-earth metal and the acid selected from lower fatty acid, higher fatty acid and inorganic carbonate is at least a: metal is become surpass 0 mass parts and the amount below 0.10 mass parts,
And (A) composition and (B) total amount of the periodictable I family's basic metal in the composition and periodictable II family alkaline-earth metal for surpassing the following composition heating and melting of 0 quality % and 0.12 quality %, be injected into molten state in the casting mold more than the fusing point that is preheated to said composition, make its cooling curing.
The invention effect
Block-formed material of higher fatty acid zinc of the present invention is the block-formed material of higher fatty acid zinc that has high-durability and height smoothness than in the past block-formed material of higher fatty acid zinc, can be suitable as the application such as lubricant, shredder, clean-out system, video picture auxiliary agent of office equipment such as xerographic printer.
Embodiment
The block-formed material of higher fatty acid zinc of the 1st mode of the present invention is the block-formed material of higher fatty acid zinc that obtains for the heating and melting thing cooling curing that surpasses 0 quality % and the higher fatty acid zinc below the 0.12 quality % by the total amount that makes (A) periodictable I family's basic metal and periodictable II family alkaline-earth metal.In addition, the block-formed material of higher fatty acid zinc of the 2nd mode of the present invention, be by to the total amount that contains (A) periodictable I family's basic metal and periodictable II family alkaline-earth metal for surpassing 0 quality %, and the higher fatty acid zinc that 0.12 quality % is following: 100 mass parts, (B) metal of from periodictable I family's basic metal and periodictable II family alkaline-earth metal, selecting and from lower fatty acid, the metal-salt of the acid of selecting in higher fatty acid and the inorganic carbonate at least a: metal is become surpass 0 mass parts, and the amount that 0.10 mass parts is following and forming, and (A) composition and (B) total amount of the periodictable I family's basic metal in the composition and periodictable II family alkaline-earth metal for surpassing 0 quality %, and the heating and melting thing cooling curing of the composition that 0.12 quality % is following and the block-formed material of higher fatty acid zinc that obtains.Under the situation of arbitrary block-formed material of higher fatty acid zinc, be that concentration (that is, surpass 0 quality % and 0.12 quality % following) below the 0.12 quality % contains periodictable I family's basic metal and periodictable II family alkaline-earth metal all by total amount.The Bulk Specific Gravity of block-formed material of higher fatty acid zinc of the present invention normally 1.090～1.110 is arranged again.
In the present invention, block-formed material of higher fatty acid zinc, with from periodictable I family's basic metal and periodictable II family alkaline-earth metal, select more than a kind, preferably the total amount of the metal of selecting from sodium, potassium, magnesium, calcium more than a kind be below the 0.12 quality %, particularly below the 0.10 quality %, more than the preferred 0.0025 quality %, more preferably the higher fatty acid zinc more than the 0.005 quality %, more than the preferred especially 0.01 quality % uses as raw material.When the 1st mode, the total amount of life cycle table the I family's basic metal and periodictable II family alkaline-earth metal surpasses the raw material of 0 quality %.On the other hand, when the 2nd mode, also can be not contain periodictable I family's basic metal and periodictable II family alkaline-earth metal (that is 0 quality %).
And, use will be measured the higher fatty acid zinc that contains (A) composition respectively in accordance with regulations, perhaps the higher fatty acid zinc of (A) composition and (B) metal of from periodictable I family's basic metal and periodictable II family alkaline-earth metal, selecting of composition, preferably from sodium, potassium, the metal more than a kind that magnesium and calcium are selected and from lower fatty acid, at least a composition heating and melting of the metal-salt of the acid of selecting in higher fatty acid and the inorganic carbonate, make the raw material of heating and melting flow into the medium method of casting mold, for example cool off to the other end, carry out the melting and solidification method that cooling curing obtains molding and just can access by the end from casting mold successively.
The reason that the content of periodictable I family's (1A family) basic metal in the raw material and periodictable II family (2A family) alkaline-earth metal is decided to be specified amount is, because in raw material, contain basic metal and alkaline-earth metal if surpass specified quantitative ground, not only the wear resistant of resulting block-formed material of higher fatty acid zinc reduces, and is easy to generate crackle, cracking, projection etc.That is, basic metal in the raw material and alkaline-earth metal are if surpassing specified quantitative ground contains, and the stabilization during goods use just becomes problem, therefore the content of basic metal and alkaline-earth metal need be defined as below the 0.12 quality % by its total amount, preferably below the 0.10 quality %.
In addition, in order not form the skewness of the scraping in the use, obtain the block-formed material of higher fatty acid zinc of stabilizing quality, it is necessary containing basic metal or alkaline-earth metal in raw material, but more than the preferred 0.0025 quality % of the content of basic metal in the raw material and alkaline-earth metal, more than the preferred especially 0.005 quality %, more than the especially preferred 0.01 quality %.If very few, crackle, breach, projection etc. take place in molding sometimes.
Have, as the higher fatty acid zinc in the raw material, though not restriction especially, the carbonatoms that constitutes the higher fatty acid of higher fatty acid zinc is 8～20, most preferably 12～18, suitable uses such as Zinc tetradecanoate, Zinic stearas, zinc palmitate again.In addition, as higher fatty acid zinc, can use and make granular or granular higher fatty acid zinc.
In addition, in the 2nd mode, the higher fatty acid zinc that contains (A) composition, (B) metal of from periodictable I family's (1A family) basic metal and periodictable II family (2A family) alkaline-earth metal, selecting and from lower fatty acid, the metal-salt of the acid of selecting in higher fatty acid and the inorganic carbonate at least a, use (A) composition 100 mass parts relatively, surpass 0 mass parts with metal, more than preferred 0.001 mass parts, become the composition that the following amount of 0.10 mass parts cooperates (B) composition, in the case, in composition in its entirety, the concentration of periodictable I family's basic metal and periodictable II family alkaline-earth metal, total amount by these metals is below the 0.12 quality %, be preferably especially below the 0.10 quality %, and more than the preferred 0.0025 quality %, more than the preferred especially 0.005 quality %, more than the especially preferred 0.01 quality %.
(B) metal-salt of composition, it constitutes metal is basic metal or alkaline-earth metal, but (A) basic metal that contains in the higher fatty acid zinc of composition or the effect of alkaline-earth metal are different, with the metal-salt of (B) composition, can make the impact of the block-formed material of higher fatty acid zinc that obtains better by also.As this metal, for example can enumerate an alkali metal salts such as lithium, sodium, potassium, alkaline earth salts such as calcium, barium.
As the metal-salt of lower fatty acid, restriction especially, but the metal-salt of preferred carbonatoms below 7, particularly 1～3 lipid acid can be fit to use sodium acetate, Sodium Propionate.In addition, as the metal-salt of higher fatty acid, restriction especially, but the metal-salt of preferred carbonatoms 8～30, particularly 10～20, especially 12～18 higher fatty acid is fit to use sodium stearate.Have again, as inorganic carbonate, not restriction especially, but be fit to use yellow soda ash, sodium bicarbonate.
Preparation method as being the higher fatty acid zinc of raw material for example can enumerate method shown below.Have again, as an example Zinic stearas is narrated, but be not limited thereto at this.At first, in a large amount of water stir stearic acid (higher fatty acid) on one side, add 1～2 Equivalent Hydrogen sodium oxide (oxyhydroxide) on one side and form sodium stearate.After this, add total 1.5～3 normal zinc chloride (muriate) more bit by bit, make the sodium of sodium stearate be replaced as zinc, generate the Zinic stearas precipitation.After this, implement washing.Washing is the temperature about 10～30 ℃ preferably, with the ratio of feedstock/water=1/5～1/20, carries out cleaning in 10～60 minutes.When using other higher fatty acid, too, can change the kind of higher fatty acid and make aptly.
The manufacture method of block-formed material of higher fatty acid zinc then, is described.The casting mold that uses among the present invention from becoming high temperature in use, requiring considerations such as heat conductivity or intensity, can use metal casting mold (after, simply be designated as metallic mould).The material of metallic mould, preferred processibility and heat conductivity are good, processing ease, be the few material of inertia, surface attachment to higher fatty acid zinc, preferably use materials such as A1 system.
The shape of block-formed material of higher fatty acid zinc has different shape, uses to possess to be fit to the metallic mould of the cavity of shape separately.For example in the manufacturing of the piece molding of rectangular parallelepiped, use the occasion of metallic mould, in metallic mould, be provided with in the cavity corresponding to the rectangular parallelepiped of product size of the number that requires, in order to form as required on metallic mould the additional temp gradient, go up heating arrangements such as well heater can be set and/or cooling body (preferably water-cooled mechanism) at the platform of metallic mould and/or mounting metallic mould (metal that preferred heat conductivity is good).The metallic mould preferable separation becomes the divided casting mold more than 2.
Manufacturing sequence for example can be stipulated as following.At first, metallic mould integral body is heated in advance more than the melt temperature of higher fatty acid zinc or composition, chamber at 120～200 ℃ of generals fused higher fatty acid zinc or composition injection metallic mould, proceed 30 minutes～heating (120～200 ℃) about 5 hours after, the cooling body (water-cooled etc.) that utilization is arranged on the platform of metallic mould body bottom or mounting metallic mould cools off, meanwhile the downside from metallic mould sequentially stops heating, Yi Bian Yi Bian make the cured article of higher fatty acid zinc begin from the bottom little by little to pile up to form.The voltage that for example at first can use the well heater that makes the bottom little by little descends, temperature is reduced at leisure, reduce from the temperature of the whole bottom of metallic mould, behind certain hour, the method that the heating that make the heating that produced by the well heater of central part, after this well heater by top is produced stops successively.In this occasion, after the temperature of metallic mould integral body becomes below 40 ℃, can open metallic mould, take out molding.
Below, embodiment and Comparative Examples are shown, specifically describe the present invention, but the present invention is not subjected to the restriction of following embodiment.
Embodiment 1
In the water of 30L, stir the 4.5g stearic acid on one side,, form sodium stearate, after this, add total 1.5 normal zinc chloride more bit by bit, obtain Zinic stearas Yi Bian add 1.2 Equivalent Hydrogen sodium oxides.After this, 20 ℃ of water temperatures, with the ratio of Zinic stearas/water=1/10 carry out 30 minutes the washing.When the basic metal of the Zinic stearas that mensuration obtains (as Zinic stearas A) and the concentration of alkaline-earth metal, sodium is 0.05 quality %.
The basic metal in the higher fatty acid zinc and the concentration of alkaline-earth metal, as test portion, add 10ml distilled water and 3ml concentrated hydrochloric acid, at 70～80 ℃ with 1g higher fatty acid zinc heating for dissolving, after this, put cold, filtration, by basic metal in the filtrate and alkaline-earth metal quantitatively being measured with ICP luminescence spectrophotometer (IRIS Intrepid II XSP).
Then, on the one side of thick aluminium sheet, make the metallic mould of 10 ditches that are provided with 10 wide 8mm, dark 8mm, long 400mm and the dull and stereotyped two ends of aluminum of 11 installation well heaters become superimposed mutually dull and stereotypedly, tighten it integrated and fixing with bolt, such according to the length direction or the above-below direction that form above-mentioned ditch, be positioned on the mounting table of the metallic mould that possesses water-cooled mechanism.
In advance this metallic mould is preheated to 160～200 ℃, Zinic stearas A through 180 ℃, 3 hours heating and meltings is flowed into, 180 ℃ keep 30 minutes after, begin cold water to be circulated in the water-cooled mechanism of metallic mould mounting table from the bottom to the energising of order cut-out in top to well heater.Carry out being cooled in 4 hours after whole metallic mould temperature becomes below 40 ℃, open metallic mould, obtain the piece molding of Zinic stearas.
When 100 stearic acid spelter moldinies that obtain were confirmed, crackle took place 1%, and breach takes place 1%, but projection did not take place.In addition, estimate wear resistant with following method, wear resistant is also good, can be fully durable.The results are shown in the table 1.
＜wearability 〉
Use new eastern scientific company system ヘ イ De Application 14DR to measure.Cut out the piece of high 8mm, wide 8mm, long 10mm from molding, use the file (3M corporate system, piece number AL202 (50 μ m)) of oxidation aluminum, 8mm * 8mm section rubs with 100mN load (carrying out 5 times between 100mm back and forth, speed 17mm/s).The wearing and tearing decrement of representing this moment with percentage.As this stearic acid spelter molding, 0.1～0.3%, optimum scope.
Embodiment 2
Except carry out washing in 30 minutes with the ratio of 20 ℃ of water temperatures, Zinic stearas/water=1/15, use and obtain Zinic stearas with embodiment 1 identical method.When the basic metal of the Zinic stearas that mensuration obtains (as Zinic stearas B) and the concentration of alkaline-earth metal, sodium is 0.01 quality %.In addition, use Zinic stearas B,, it is estimated with obtaining stearic acid spelter molding with embodiment 1 identical method.The results are shown in the table 1.
Embodiment 3
Except carry out washing in 15 minutes with the ratio of 20 ℃ of water temperatures, Zinic stearas/water=1/10, use and obtain Zinic stearas with embodiment 1 identical method.When the basic metal of the Zinic stearas that mensuration obtains (as Zinic stearas C) and the concentration of alkaline-earth metal, sodium is 0.10 quality %, and magnesium is 0.02 quality %.In addition, use Zinic stearas B,, it is estimated with obtaining stearic acid spelter molding with embodiment 1 identical method.The results are shown in the table 1.
Embodiment 4
In the Zinic stearas B of 100 mass parts embodiment 2, mix 0.06 mass parts Sodium Propionate (is 0.014 mass parts as sodium), form composition (Na adds up to 0.024 quality %).Use said composition,, it is estimated with obtaining stearic acid spelter molding with embodiment 1 identical method.The results are shown in the table 1.
Embodiment 5
In the Zinic stearas B of 100 mass parts embodiment 2, mix 0.02 mass parts sodium stearate (is 0.002 mass parts as sodium), form composition (Na adds up to 0.012 quality %).Use said composition,, it is estimated with obtaining stearic acid spelter molding with embodiment 1 identical method.The results are shown in the table 1.
Embodiment 6
In the Zinic stearas B of 100 mass parts embodiment 2, mix 0.06 mass parts sodium bicarbonate (is 0.016 mass parts as sodium), form composition (Na adds up to 0.026 quality %).Use said composition,, it is estimated with obtaining stearic acid spelter molding with embodiment 1 identical method.The results are shown in the table 1.
Embodiment 7
Except stearic acid being altered to palmitinic acid, using and obtain zinc palmitate with embodiment 1 identical method.After this, to implement washing with embodiment 1 identical condition.When the basic metal of the zinc palmitate that mensuration obtains and the concentration of alkaline-earth metal, sodium is 0.07 quality %.In addition, use zinc palmitate,, it is estimated with obtaining palmitinic acid spelter molding with embodiment 1 identical method.The results are shown in the table 1.
Comparative Examples 1
Except carry out washing in 10 minutes with the ratio of 20 ℃ of water temperatures, Zinic stearas/water=1/4, use and obtain Zinic stearas with embodiment 1 identical method.When the basic metal of the Zinic stearas that mensuration obtains (as Zinic stearas D) and the concentration of alkaline-earth metal, sodium is 0.13 quality %.In addition, use Zinic stearas D,, it is estimated with obtaining stearic acid spelter molding with embodiment 1 identical method.The results are shown in the table 1.
Table 1
＜crackle, breach, protruding criterion of acceptability 〉
Crackle, projection: do not take place
Breach:, be that length is less than 5mm, highly less than 2mm to the goods of long 400mm
＜yield 〉
Represent to remove crackle, breach, the protruding ratio that the molding of product takes place with percentage.
Claims (7)
1. block-formed material of higher fatty acid zinc, it is characterized in that, obtain for the heating and melting thing cooling curing that surpasses 0 quality % and the higher fatty acid zinc below the 0.12 quality % by the total amount that makes (A) periodictable I family's basic metal and periodictable II family alkaline-earth metal.
2. block-formed material of higher fatty acid zinc according to claim 1 is characterized in that, the total amount of periodictable I family's basic metal in the above-mentioned higher fatty acid zinc and periodictable II family alkaline-earth metal is more than the 0.0025 quality %.
3. block-formed material of higher fatty acid zinc is characterized in that, by to containing
(A) total amount of periodictable I family's basic metal and periodictable II family alkaline-earth metal is for surpassing the following higher fatty acid zinc of 0 quality % and 0.12 quality %: 100 mass parts,
(B) metal-salt of metal of selecting from periodictable I family's basic metal and periodictable II family alkaline-earth metal and the acid selected from lower fatty acid, higher fatty acid and inorganic carbonate is at least a: metal is become surpass 0 mass parts and the amount below 0.10 mass parts,
And (A) composition and (B) total amount of the periodictable I family's basic metal in the composition and periodictable II family alkaline-earth metal obtain for the heating and melting thing that surpasses 0 quality % and the composition below the 0.12 quality % carries out cooling curing.
4. block-formed material of higher fatty acid zinc according to claim 3 is characterized in that, the total amount of periodictable I family's basic metal in the above-mentioned composition and periodictable II family alkaline-earth metal is more than the 0.0025 quality %.
5. according to each the described block-formed material of higher fatty acid zinc in the claim 1～4, it is characterized in that above-mentioned periodictable I family's basic metal and periodictable II family alkaline-earth metal are the metals of selecting more than a kind from sodium, potassium, magnesium and calcium.
6. the manufacture method of block-formed material of higher fatty acid zinc, it is characterized in that, with the total amount of (A) periodictable I family's basic metal and periodictable II family alkaline-earth metal is to surpass 0 quality % and the following higher fatty acid zinc heating and melting of 0.12 quality %, be injected into molten state in the casting mold more than the fusing point that is preheated to higher fatty acid zinc, make its cooling curing.
7. the manufacture method of block-formed material of higher fatty acid zinc is characterized in that, will contain
(A) total amount of periodictable I family's basic metal and periodictable II family alkaline-earth metal is for surpassing the following higher fatty acid zinc of 0 quality % and 0.12 quality %: 100 mass parts,
(B) metal-salt of metal of selecting from periodictable I family's basic metal and periodictable II family alkaline-earth metal and the acid selected from lower fatty acid, higher fatty acid and inorganic carbonate is at least a: metal is become surpass 0 mass parts and the amount below 0.10 mass parts,
And (A) composition and (B) total amount of the periodictable I family's basic metal in the composition and periodictable II family alkaline-earth metal for surpassing the following composition heating and melting of 0 quality % and 0.12 quality %, be injected into molten state in the casting mold more than the fusing point that is preheated to said composition, make its cooling curing.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007022632 | 2007-02-01 | ||
| JP2007-022632 | 2007-02-01 | ||
| JP2007022632A JP5037154B2 (en) | 2007-02-01 | 2007-02-01 | Higher fatty acid zinc block moldings |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101423787A true CN101423787A (en) | 2009-05-06 |
| CN101423787B CN101423787B (en) | 2011-07-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101842336A Expired - Fee Related CN101423787B (en) | 2007-02-01 | 2008-02-01 | Block-formed material of higher fatty acid zinc and method for producing the same |
Country Status (2)
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| JP (1) | JP5037154B2 (en) |
| CN (1) | CN101423787B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104402700A (en) * | 2014-12-11 | 2015-03-11 | 东莞市汉维新材料科技有限公司 | Preparation method of bulk zinc stearate |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003195684A (en) * | 2001-12-26 | 2003-07-09 | Canon Inc | Image forming device |
| JP2005091979A (en) * | 2003-09-19 | 2005-04-07 | Konica Minolta Business Technologies Inc | Image forming apparatus |
-
2007
- 2007-02-01 JP JP2007022632A patent/JP5037154B2/en not_active Expired - Fee Related
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104402700A (en) * | 2014-12-11 | 2015-03-11 | 东莞市汉维新材料科技有限公司 | Preparation method of bulk zinc stearate |
| CN104402700B (en) * | 2014-12-11 | 2016-07-27 | 东莞市汉维新材料科技有限公司 | A kind of preparation method of block zinc stearate |
Also Published As
| Publication number | Publication date |
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| JP2008189557A (en) | 2008-08-21 |
| CN101423787B (en) | 2011-07-27 |
| JP5037154B2 (en) | 2012-09-26 |
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