CN101422729A - Catalyst for generating reducing water and reducing water generation container - Google Patents
Catalyst for generating reducing water and reducing water generation container Download PDFInfo
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- CN101422729A CN101422729A CNA2007103004381A CN200710300438A CN101422729A CN 101422729 A CN101422729 A CN 101422729A CN A2007103004381 A CNA2007103004381 A CN A2007103004381A CN 200710300438 A CN200710300438 A CN 200710300438A CN 101422729 A CN101422729 A CN 101422729A
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- reducing water
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- generating reducing
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Abstract
The subject of the invention is to provide a composition of catalyst for reduction water generation, wherein the catalyst is an alloy which uses magnesium as a main component and prevents the rapid oxidation of magnesium, and furthermore the catalyst can generate reduction water with a high efficiency. Simultaneously the invention provides a composition of reduction water generation container of catalyst for reduction water generation. For settling the subject of the invention, the basic composition of the invention is as follows: (1) the catalyst for reduction water generation is characterized by forming a plate-shaped or tubular catalyst for reduction water generation with the alloy which uses magnesium (Mg) as a main component and is added with zinc (Zn) and/or manganese (Mn); and (2) the reduction water generation container is characterized in that the base is configured by a catalyst for generating reduction water in (1) and the upside is detachably configured with a lid.
Description
Technical field
The present invention relates to be used to generate the catalyst and the container of reductive water.
Background technology
Usually, as the oxidation-reduction potential of water, for the oxidation-reduction potential value (ORP value) when using silver-silver chloride electrode to measure, the situation of demonstration+200mV is considered to median, and the water that current potential is lower than this median is called as reductive water.
Reductive water because active oxygen is reduced or the like, can be used as healthy beverage water and drinks, but as its generating mode, following mode is widely adopted as the technique known method, that is: configuration anode and negative electrode in container, and the current potential in the container is adjusted to is lower than+mode of the current potential of 200mV.
Such mode has proposed various technique improvements, but must be provided with on this aspect of anode and negative electrode, constitutes complexity, and on this aspect of must switching at ordinary times, uneconomical.
In addition, in the occasion of the many hard water of electrolyte ingredient, the cation of calcium (Ca) etc.s is attached on the negative electrode, and along with the process of service time, becoming can not electrolysis, thereby the miscellaneous property of electrode and the difficulty of maintenance take place to change.
In order to improve such problem, in patent documentation 1, do not need to have proposed the structure of the reductive water generating apparatus of switching on.
Yet, in the mode of patent documentation 1, need anode, negative electrode, and then need ion battery, constituting not variation on complicated this aspect.
Reductive water by disposing catalyst material in water, and produces hydrogen, can realize on principle.
All the time, adopting aluminium or its alloy as catalyst for generating reducing water, but the aluminium ion (Al of stripping in the water
3+) being shot when getting in the human body, can not bring desirable influence, so aluminium or its alloy are inappropriate as catalyst for generating reducing water to human body.
Relative therewith, in the occasion that is magnesium (Mg), because magnesium is mineralogical composition essential in the human body, so its ion (Mg
2+) not only can not bring bad influence when being absorbed in the human body resemble the aluminium ion, can be in gratifying situation on the contrary, so magnesium can be used as the catalyst for generating reducing water use originally.
Yet based on Mg+2H
2O → Mg (OH)
2+ H
2↑ chemical reaction, in water, produce hydrogen, owing to the reduction of this hydrogen generates reductive water, ORP reduces natch.
Yet magnesium forms magnesia (MgO) in water and aerial oxidation rapidly, and when reality was used as catalyst for generating reducing water as described above, for fear of this oxidation, indispensable was the alloy that will form with other metal.
Yet, about as catalyst for generating reducing water, be the alloy of principal component with magnesium, suitable formation also is not provided at present.
The open 2007-075752 communique of [patent documentation 1] Japan Patent.
Summary of the invention
Problem of the present invention is the situation in view of prior art as described above, a kind of formation of catalyst for generating reducing water is provided, it is principal component and the alloy that prevents the magnesium abrupt oxidization with magnesium, and can generate reductive water expeditiously, and can use for a long time and under stable status, the formation based on the reducing water generation container of this catalyst for generating reducing water also is provided simultaneously.
In order to solve above-mentioned problem, basic comprising of the present invention comprises:
(1) a kind of catalyst for generating reducing water is characterized in that, is to be principal component with magnesium (Mg) and to add zinc (Zn) and/or alloy that manganese (Mn) forms forms the catalyst for generating reducing water of tabular or tubulose.
(2) a kind of reducing water generation container is characterized in that, disposes above-mentioned (1) described catalyst for generating reducing water in the bottom, disposes lid freely in the upside loading and unloading.
Description of drawings
Fig. 1 is the skeleton diagram of demonstration based on the basic configuration of the catalyst for generating reducing water of the basic comprising of such scheme (1), (a) shows tabular situation, (b) shows the situation of tubulose.
Fig. 2 shows surfacewise, but is provided with the skeleton diagram of the catalyst for generating reducing water in the slotted hole of permeate water or hole, (a) is presented at the situation that plate-like surface has formed the hole, (b) is presented at the situation that tubular surface has formed slotted hole.
Fig. 3 is the skeleton diagram that shows the example of reducing water generation container.
Symbol description
1 catalyst for generating reducing water
11 slotted holes or hole
2 containers
The platform of 21 support vessels
22 lids
3 annotate comb
The specific embodiment
The catalyst for generating reducing water 1 that relates to the basic comprising of such scheme (1) by adding zinc and/or manganese to the magnesium as principal component, prevents the corrosion that acidifying rapidly causes, and improves ductility and processability simultaneously.
In order to improve such ductility and processability, preferably add zinc and manganese.
On the other hand, in the basic comprising of above-mentioned (1), shown in Fig. 1 (a) and (b), like that, adopted the form of tabular or tubulose.
Adopt the basis of such form to be, compare with for example situation of spherical such three-dimensional shape, above-mentioned tabular and tubulose is under the situation of identical volume, and the surface area that can form is big, so help the degree of generation of the reductive water in the water big.
Especially under the granular situation of the average grain diameter of the thickness same degree when having and form tabular or tubulose, can think and to form bigger surface area, but in so granular occasion, as above-mentioned basic comprising (2), bottom that can not be in container is with steady state configuration, on the other hand, the occasion that contacts with each other in granular unit, the result becomes the state identical with three-dimensional shape, hindered with the surface of water to contact, can not bring into play the high efficiency catalysis that is used to generate reductive water.
Like this, by adopting the form of tabular or tubulose, one brings into play the catalysis of the generation reductive water of extreme efficiency surely.
The 2nd the related example that the present invention asks for protection is characterized in that, the ratio of adding zinc is 1.5～8.5 weight %, and the ratio of adding manganese is 0.5～3.5 weight %.
Addition about zinc, 1.5 the lower limit of weight %, it is the minimum datum quantity that is used to prevent the corrosion that causes by acidifying rapidly, 8.5 the higher limit of weight %, be to come from following consideration: when surpassing this higher limit, be difficult to form the solid solution of magnesium and zinc, and the catalysis of the good generation reductive water of magnesium reduces.
Equally, addition about manganese, 0.5 the lower limit of weight %, it is the minimum datum quantity that is used to prevent the corrosion that causes by acidifying rapidly, 3.5 the higher limit of weight %, be to come from following consideration: when surpassing this higher limit, be difficult to form the solid solution of magnesium and manganese, and the catalysis of the good generation reductive water of magnesium reduces.
In addition, confirmed experimentally: even the occasion that adopts the higher limit of 8.5 weight % and 3.5 weight % to add zinc and manganese respectively also can respectively and form solid solution independently between the magnesium.
By such numerical definiteness, can make to prevent that magnesium from corroding and suitable reduction is set up simultaneously, and then can guarantee good ductility and processability.
The 3rd the example that the present invention asks for protection; such shown in Fig. 2 (a) and (b); it is characterized in that; surface along tabular or tubulose; but be provided with the slotted hole of permeate water or hole 11 (in addition; Fig. 2 (a) shows the situation that hole 11 is set onboard, and Fig. 2 (b) shows the situation that slotted hole 11 is set on pipe.)。
Resembling the occasion that permeable slotted hole of water or hole 11 are set in this wise, the edge in this slotted hole or hole 11 also contacts with water, and near this slotted hole or hole 11 generation sinuous flow or eddy current, thereby the touch opportunity of water and catalyst increases, so can further encourage the catalysis that generates reductive water.
In addition, catalyst for generating reducing water 1 of the present invention, for the purpose of easy to operate, sometimes with plastic wire parcel, but in this occasion, water from slotted hole or hole 11 by the time, can pass through this net.
The 4th the example that the present invention asks for protection is characterized in that, to surface impregnation at least one side of citric acid or acetate.
Like this, occasion at made surface impregnation citric acid or acetate, can will dissolve at the magnesia film (epithelium :) that alloy surface forms rapidly, and can help to bring into play the catalysis that is used for generating rapidly reductive water owing to being alloy, so the state of oxidation is not penetrated into inside.
In addition, sulfuric acid or hydrochloric acid also can be brought into play dissolution as described above, but with water is fastened as the pass of drinking, can not adopt these acid, can select citric acid or acetate very suitably.
The grown form of above-mentioned (2), be by will be, and then will be configured in the bottom of container based on the catalyst for generating reducing water of above-mentioned each example based on the catalyst for generating reducing water of the grown form of above-mentioned (1), dispose lid freely in upside loading and unloading, generate reductive water.
Can generate the degree of reductive water and generation, about waiting by the area of the water yield in the container, water quality and catalyst for generating reducing water,, require to accumulate resulting empirical rule and set particularly according to Individual testwas for this point.
The 6th the example that the present invention asks for protection; as shown in Figure 3; it is characterized in that; by engaging the 3rd the described tabular catalyst for generating reducing water 1 that the present invention asks for protection in turn; it is polygon-shaped forming the cross section, and forms and be provided for to make the screw rod that has CD-ROM drive motor that water passes through from slotted hole or hole 11 or circulating pump (not shown go out).
Like this, utilize screw rod or circulating pump with the rotary driving source interlock, water circulate container 2 in, and the occasion passed through from slotted hole or hole 11 of the water that is circulating, but extreme efficiency the generation reductive water.
Explanation is in passing, in the container that can hold 3.6L water, uses 6 plates, and described plate is high 35mm * wide 25mm, thick is 3mm, and magnesium is 95 weight %, and zinc is 4 weight %, manganese is 1 weight %, is roughly orthohexagonal occasion forming the cross section, and the area at the surface and the back side is 10500mm
2, but in the container of 3.6L, be roughly orthohexagonal catalyst for generating reducing water in its above-mentioned cross section of configuration, bottom, and make under the situation of water circulation, having confirmed can be by the water of the ORP value of 500mV, promptly generation-250mV～-reductive water of 300mV.
Below, describe according to embodiment based on concrete experiment.
Embodiment
In the adding proportion that forms magnesium is that the adding proportion of about 95 weight %, zinc is that the adding proportion of about 4.0 weight %, manganese is on the rectangular-shaped basis of about 1.0 weight %, also make its surface impregnation citric acid, under holding the situation of ORP value for the water before the reduction of 500mV, after 3 hours the ORP value become-area of the such catalyst for generating reducing water of 250mV (wherein, comprise the surface and the back side the two) relation of the interior water yield with being contained in container, be shown in the following table 1.
Table 1
| Area (cm 2) | 20 | 40 | 60 | 80 | 100 | 120 |
| The water yield (L) | 0.6 | 1.2 | 1.8 | 2.4 | 3.0 | 3.6 |
Distinguish clearly that from top table 1 area of the catalyst for generating reducing water that is adopted (comprising the surface and the back side) is with the proportional substantially relation of the water yield of the ORP value that can reach defined.
Such situation has proved objectively: as the present invention, by making tabular the shape of catalyst for generating reducing water or tubulose, even in the occasion of container capacious, also can realize the generation of high efficiency reductive water by increasing the surface area of catalyst for generating reducing water.
The invention effect
In the reducing water generation container of above-mentioned (2) of the catalyst for generating reducing water that has adopted above-mentioned (1), can in container, generate rapidly reductive water, and can prevent the rapidly oxidation of magnesium, so can use constantly for a long time.
Industrial applicibility
The present invention can be applied to the generation of the reductive water drunk in eating and drinking establishment, office, the family etc.
Claims (6)
1. a catalyst for generating reducing water is characterized in that, is to be principal component with magnesium (Mg) and to add zinc (Zn) and/or alloy that manganese (Mn) forms forms the catalyst for generating reducing water of tabular or tubulose.
2. catalyst for generating reducing water as claimed in claim 1 is characterized in that, the ratio of adding zinc is 1.5～8.5 weight %, and the ratio of adding manganese is 0.5～3.5 weight %.
3. catalyst for generating reducing water as claimed in claim 1 or 2 is characterized in that, is provided with permeable slotted hole of water or hole along the surface of tabular or tubulose.
4. as each described catalyst for generating reducing water of claim 1～3, it is characterized in that, to surface impregnation at least one side of citric acid or acetate.
5. a reducing water generation container is characterized in that, disposes each described catalyst for generating reducing water of claim 1～4 in the bottom, disposes lid freely in the upside loading and unloading.
6. reducing water generation container as claimed in claim 5, it is characterized in that, by engaging the described tabular catalyst for generating reducing water of claim 3 in turn, it is polygon-shaped forming the cross section, and the screw rod that has CD-ROM drive motor or the circulating pump that form and be provided for to make water to pass through from slotted hole or hole.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP284673/2007 | 2007-11-01 | ||
| JP2007284673 | 2007-11-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101422729A true CN101422729A (en) | 2009-05-06 |
Family
ID=40613746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007103004381A Pending CN101422729A (en) | 2007-11-01 | 2007-12-27 | Catalyst for generating reducing water and reducing water generation container |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4326577B2 (en) |
| CN (1) | CN101422729A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10639249B2 (en) | 2014-09-25 | 2020-05-05 | Eiko Kinoshita | Reduction treatment agent, reduction cosmetic, reduction food and method for producing reduction treatment agent |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5358030B2 (en) * | 2012-03-07 | 2013-12-04 | 立比古 小川 | Reduced powder and method for producing the same |
| JP6414758B2 (en) * | 2016-08-23 | 2018-10-31 | 株式会社アンノオフィス | Hydrogen generator reaction vessel |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005111037A (en) * | 2003-10-09 | 2005-04-28 | Matsushita Electric Ind Co Ltd | Rice cooker |
| CN1989067A (en) * | 2005-01-07 | 2007-06-27 | 日立麦克赛尔株式会社 | Hydrogen generating material, hydrogen generator and fuel cell |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61234988A (en) * | 1985-04-11 | 1986-10-20 | Mitsumine Matsumoto | Water treating and activating device |
| JPS6230598A (en) * | 1985-08-01 | 1987-02-09 | Matsushita Electric Ind Co Ltd | Neutralization apparatus for supplying water and hot water |
| JP2784651B2 (en) * | 1988-07-27 | 1998-08-06 | 太陽 天門 | Mineral water production method |
| JPH1085766A (en) * | 1996-09-16 | 1998-04-07 | Mitsuo Wada | Water quality improving material and method for improving water quality |
| JP3048651U (en) * | 1997-11-06 | 1998-05-22 | バイタル・ジャパン株式会社 | Ceramics for water quality modification |
| JP2000308884A (en) * | 1999-04-26 | 2000-11-07 | Asahitekku Corporation:Kk | Water purification accelerating method and water purifying device |
| JP2001029958A (en) * | 1999-07-20 | 2001-02-06 | Otsuka Kazuo | Method for improving quality of water |
| JP2003010865A (en) * | 2001-07-02 | 2003-01-14 | Hikari Berukomu:Kk | Apparatus for producing acidic and reduced water |
| JPWO2003064332A1 (en) * | 2002-01-29 | 2005-05-26 | 本田技研工業株式会社 | Water activation device and activation method |
| JP3973152B2 (en) * | 2002-11-25 | 2007-09-12 | 有限会社善玉倶楽部 | Structure for producing high hydrogen concentration water |
| JP2004243151A (en) * | 2003-02-10 | 2004-09-02 | Yoshiro Tanaka | Hydrogen-dissolved water making appliance |
| JP2006044998A (en) * | 2004-08-05 | 2006-02-16 | Toshihiro Kido | Hydrogen generating method and hydrogen generating device |
| JP4104016B2 (en) * | 2005-01-07 | 2008-06-18 | 日立マクセル株式会社 | Hydrogen generating material, hydrogen production cartridge, hydrogen production apparatus, hydrogen production method and fuel cell system |
-
2007
- 2007-12-27 CN CNA2007103004381A patent/CN101422729A/en active Pending
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- 2008-02-04 JP JP2008023464A patent/JP4326577B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005111037A (en) * | 2003-10-09 | 2005-04-28 | Matsushita Electric Ind Co Ltd | Rice cooker |
| CN1989067A (en) * | 2005-01-07 | 2007-06-27 | 日立麦克赛尔株式会社 | Hydrogen generating material, hydrogen generator and fuel cell |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10639249B2 (en) | 2014-09-25 | 2020-05-05 | Eiko Kinoshita | Reduction treatment agent, reduction cosmetic, reduction food and method for producing reduction treatment agent |
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| Publication number | Publication date |
|---|---|
| JP4326577B2 (en) | 2009-09-09 |
| JP2009131825A (en) | 2009-06-18 |
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