CN101403674A - Method for fast measurement of methane content in biogas through indirect volume - Google Patents
Method for fast measurement of methane content in biogas through indirect volume Download PDFInfo
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- CN101403674A CN101403674A CNA2008102261706A CN200810226170A CN101403674A CN 101403674 A CN101403674 A CN 101403674A CN A2008102261706 A CNA2008102261706 A CN A2008102261706A CN 200810226170 A CN200810226170 A CN 200810226170A CN 101403674 A CN101403674 A CN 101403674A
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Abstract
The invention discloses a method adopting the indirect volume to quickly measure the methane content in marsh gas. The methane gas in the marsh gas is injected into a methane collecting bottle filled with work liquid; the work liquid of the same volume is discharged into a receiving bottle from the methane collecting bottle; and then the volume of the work liquid in the receiving bottle is measured so as to get the content of the methane in the marsh gas. The invention also discloses a methane quick analyzing instrument formed as follows: an outlet valve of a ZS-2 type marsh-gas content analyzing instrument is connected through a rubber tube with a methane collecting bottle; two apertures are arranged on the bottle cap of the methane collecting bottle for respectively arranging an intake tube and a discharging tube which is connected with a burette through a rubber tube; and the receiving bottle is arranged under the burette. The instrument is provided with a small volume; the measurement speed is high; the analysis cost is low; and the method is suitable for the site analysis.
Description
Technical field
The invention belongs to the analytical chemistry field.Relate in particular to a kind of method by methane content in the indirect volume fast measuring biogas.
Background technology
Biogas is the final product of organic matter biodegradation in the anaerobic environment, and its principal ingredient is methane (CH
4), account for 50%～70% of cumulative volume, secondly be carbon dioxide (CO
2), account for 25%～45%, also contain a spot of nitrogen (N
2), hydrogen (H
2), oxygen (O
2), carbon monoxide (CO) and sulfuretted hydrogen (H
2Gas such as S).What and relative scale of these gas componants can reflect the quality of process, fermentation appearance and the process conditions of biogas fermentation.The methane-generating pit that good zymotechnique and normal operation are arranged, the output of methane and factor of created gase all are high.Therefore, the gas componant of mensuration biogas and content thereof have important directive significance to the operational management of biogas engineering.
The method of measuring biogas composition and content at present mainly contains:
(1) vapor-phase chromatography: gas chromatography can be measured accurately to each component of biogas, but its only suitable laboratory study use is not suitable for the field condition analysis and uses.
(2) infrared method: infrared biogas analytical instrument is a kind of refuse landfill that is widely used in, and is that use in large-sized biogas production places such as sewage treatment plant, be used to detect CH
4, CO
2And O
2The check and analysis instrument, can portable measurement and preserve measurement data in real time by the PDA data acquisition software.Use but be not suitable for field condition equally, and the instrument price is higher.
(3) traditional formula gas analyzer difficult to understand has low price, and is easy to use, but it still needs to analyze in the laboratory, and can only carry out check and analysis one by one to the composition of biogas, and efficient is low.
(4) the portable biogas constituent analysis of ZS-2 type device (Chengdu Marsh Gas Science Inst., Ministry of Agriculture's development) is a kind of CH in the on-site measurement biogas that is suitable for
4, CO
2, H
2S and O
2Hand-held analyzer etc. multiple composition.But owing to adopt the content of soap bubble flowmeter metering methane, in order to improve the precision of measurement, must use elongated glass tube as methane volume detector tube, the volume of whole instrument also reaches 76cm*25cm*10cm, and it is not too convenient to carry still paleosensation; On-the site analysis adopts artificial sample introduction simultaneously, and action need two operating personnel cooperate.Therefore the tacit degree of two people cooperation has determined the success or not of analysis and the accuracy of analysis, in case soap bubble breaks, must test again, and is not only time-consuming, and the consumption of gas detecting tube is higher.
Summary of the invention
The object of the invention provides a kind of method by methane content in the indirect volume fast measuring biogas.This method is simple, detection speed is fast, cost is low.
The present invention is according to the chemical absorbing principle, adopts the indirect volume method to measure the hand-held analyzer of methane content in the biogas.Gas to be measured enters analyser during mensuration, H in the gas componant to be measured
2S, CO
2And O
2Absorbed by the relevant detection pipe and change color.Methane not with detector tube in chemical substance react, quantitatively by behind each detector tube, enter in the methane collection bottle of filling working fluid, isopyknic working fluid in the methane collection bottle flows in the dry receiving bottle (cup) by balance pipe, after sample introduction finishes, reduce the position of the balance pipe mouth of pipe, make the liquid level of the working fluid in itself and the methane collection bottle contour; With the amount of calibrated pipet metering discharge working fluid, can calculate the volume of methane.
Realize that technical scheme of the present invention is:
The present invention is by the method for methane content in the indirect volume fast measuring biogas, comprise the methane gas in the biogas is fed the methane collection bottle of filling working fluid, the methane collection bottle is discharged isopyknic working fluid in receiving bottle, measure the volume of working fluid in the receiving bottle then, can calculate the content of methane in the biogas.
Working fluid described in the said method is meant little, the not volatile liquid of methane solubleness; As water, saturated salt solution etc. are preferably saturated salt solution; Described saturated salt solution is meant sodium chloride solution or calcium chloride solution etc.
Above-mentioned method by methane content in the indirect volume fast measuring biogas specifically comprises the steps:
(1), fill it up with working fluid in the methane collection bottle with methane analyser, connect draft tube and balance pipe, will with balance pipe that the methane collection bottle is connected in also be full of working fluid;
(2), the thief hatch of methane quick analytic instrument is connected with source of the gas, the swivel tee valve is communicated with injector and source of the gas;
(3), wash injector 2～5 times, constant volume is at 25～50ml then with gas to be measured;
(4), the receiving bottle of drying is placed on the below of the balance pipe mouth of pipe, open outlet valve, then T-valve is rotated to the position that injector communicates with gas detecting tube, in 70～80 seconds, slowly inject gas to be measured;
(5), after sample introduction finishes, the position that reduces the balance pipe mouth of pipe makes the liquid level of the working fluid in itself and the methane collection bottle contour;
(6), with the volume of working fluid in the calibrated pipet metering receiving bottle, can converse the content of methane.
Working fluid described in the said method is little to methane solubleness, not volatile liquid; As water, saturated salt solution etc.; Be preferably saturated salt solution; Described saturated salt solution is sodium chloride solution or calcium chloride solution etc.
Above-mentioned balance pipe is made up of discharging tube, sebific duct and dropper, and discharging tube and dropper link together by sebific duct.
Methane quick analytic instrument of the present invention: be on the basis of ZS-2 type biogas constituent analysis device, finish through improving, specific as follows: the outlet valve place at ZS-2 type biogas constituent analysis device connects a methane collection bottle by sebific duct, the methane collection bottle two holes are arranged beyond the Great Wall, draft tube and discharging tube are housed respectively; Wherein the lower end of the length of draft tube and methane collection bottle cap flushes, and connects a dropper in the upper end of discharging tube by sebific duct, places a receiving bottle below dropper, is methane analyser of the present invention.
The length of the discharging tube described in the above-mentioned methane quick analytic instrument will guarantee that after analyzing end the degree of depth in the end of the pipe immersion working fluid is 1-2cm at least.
Working fluid in the length of the sebific duct described in the above-mentioned methane quick analytic instrument should guarantee to manage when dropper moves freely in the altitude range of methane collection bottle can not be extruded away because of pipe deformation.
Methane quick analytic instrument (see figure 1) described in the said method: comprise injector 1, thief hatch 2, injector 1 flexibly connects with an end of T-valve 3, the other end of thief hatch 2 and T-valve 3 flexibly connects, and the 3rd end of T-valve 3 and fixation kit 4 flexibly connect; The two ends of sulfuretted hydrogen detector tube 6 are equipped with fixation kit 4 and fixation kit 5 movably respectively, the two ends of carbon dioxide detector tube 7 are equipped with fixation kit 13 and fixation kit 23 movably respectively, fixation kit 5 is connected with fixation kit 23 by pipeline 9, and sulfuretted hydrogen detector tube 6 and carbon dioxide detector tube 7 are communicated; The two ends of Oxygen-detecting tube 8 are equipped with fixation kit 21 and fixation kit 22 movably respectively, and fixation kit 22 links together by pipeline 24 and fixation kit 13, and carbon dioxide detector tube 7 and Oxygen-detecting tube 8 are communicated; Fixation kit 21 flexibly connects by screw thread and outlet valve 18, outlet valve 18 is connected with draft tube 11 by sebific duct 10, the hole that draft tube 11 is passed methane collection bottle bottle stopper 12 is inserted in the methane collection bottle 14, and the diameter in the hole of the diameter of draft tube 11 and methane collection bottle bottle stopper 12 is corresponding; Another hole of methane collection bottle bottle stopper 12 is inserted with discharging tube 15, and the diameter in the hole of the diameter of discharging tube 15 and receiving flask bottle stopper 12 is corresponding, and discharging tube 15 links to each other with dropper 16 by sebific duct 20, and dropper is placed receiving bottle 17 16 times; Sulfuretted hydrogen detector tube 6, carbon dioxide detector tube 7 and Oxygen-detecting tube 8 fixing can being fixed on the work in combination platform 19.
Above-mentioned methane quick analytic instrument will be with the sulfuretted hydrogen detector tube with adsorbing a certain amount of Pb (Ac) before assembling
2The silica gel of reagent is filled; Use the silica gel of handling through the thymolphthalein dilute alkaline soln to fill the carbon dioxide detector tube; The silica gel that the effective pyrogallic acid of oxygen detection was handled is filled.
By using calibrated pipet to measure the volume of methane, make the volume of methane quick analytic instrument of the present invention have only 1/3rd of ZS-2 type biogas constituent analysis device.For the precision that guarantees to analyze, the lid of methane collection bottle with and peripheral connecting line good air-tightness will be arranged.
The workflow of methane quick analytic instrument of the present invention: biogas enters by injector in the H2S detector tube of being filled by the silica gel of absorption a certain amount of Pb (Ac) 2 reagent, the H in the biogas
2S and Pb (Ac) 2 reacts, and generates vulcanized lead and becomes pitchy; The biogas that removes sulfuretted hydrogen continues to enter the CO that has filled the silica gel of handling through the thymolphthalein dilute alkaline soln along pipeline
2Detector tube, carbon dioxide and alkali react generation carbonate and remove from combination gas; Remaining gas enters O along pipeline
2Detector tube, oxygen that may exist in the mixed gas and O
2Pyrogallic acid in the detector tube reacts and is absorbed; Remaining gas enters the methane collection bottle of filling working fluid, and isopyknic working fluid is discharged in the receiving bottle, measures the volume of working fluid in the receiving bottle, can calculate the content of methane.According to the content of oxygen, calculate the content of nitrogen.Can proofread and correct the data of analyzing.
The advantage that the present invention has: utilize that instrument volume of the present invention is little, simple to operate, finding speed is fast, analysis cost is low, be particularly suitable for on-the site analysis.
Description of drawings
Fig. 1 is a methane quick analytic instrument cut-open view of the present invention.
1 injector wherein, 2 thief hatchs, 3 T-valve, 4 fixation kits, 5 fixation kits movably, 6 sulfuretted hydrogen detector tubes, 7 carbon dioxide detector tubes, 8 Oxygen-detecting tubes, 9 pipelines, 10 sebific ducts, 11 draft tube, 12 receiving flask bottle stoppers, 13 fixation kits, 14 methane collection bottles, 15 discharging tubes, 16 droppers, 17 receiving bottles, 18 outlet valves, 19 work in combination platforms, 20 sebific ducts, 21 fixation kits, 21 fixation kits, 22 fixation kits movably, 23 fixation kits movably, 24 pipelines.
Fig. 2 is a methane quick analytic instrument workflow synoptic diagram of the present invention.
Embodiment
Embodiment 1 methane quick analytic instrument of the present invention
(1) in conjunction with the accompanying drawings methane quick analytic instrument of the present invention is further described
Methane quick analytic instrument (see figure 1) of the present invention comprises injector 1, thief hatch 2, injector 1 flexibly connects with an end of T-valve 3, the other end flexible connection of thief hatch 2 and T-valve 3, the 3rd end of T-valve 3 and fixation kit 4 flexibly connect, the two ends of sulfuretted hydrogen detector tube 6 are equipped with fixation kit 4 and fixation kit 5 movably respectively, the two ends of carbon dioxide detector tube 7 are equipped with fixation kit 13 and fixation kit 23 movably respectively, fixation kit 5 is connected with fixation kit 23 by pipeline 9, and sulfuretted hydrogen detector tube 6 and carbon dioxide detector tube 7 are communicated; The two ends of Oxygen-detecting tube 8 are equipped with fixation kit 21 and fixation kit 22 movably respectively, and fixation kit 22 links together by pipeline 24 and fixation kit 13, and carbon dioxide detector tube 7 and Oxygen-detecting tube 8 are communicated; Fixation kit 21 flexibly connects by screw thread and outlet valve 18, outlet valve 18 is connected with draft tube 11 by sebific duct 10, the hole that draft tube 11 is passed methane collection bottle bottle stopper 12 is inserted in the methane collection bottle 14, and the diameter in the hole of the diameter of draft tube 11 and receiving flask bottle cap 12 is corresponding; Another hole of methane collection bottle bottle stopper 12 is inserted with discharging tube 15, and the diameter in another hole of the diameter of discharging tube 15 and receiving flask bottle stopper 12 is corresponding, and discharging tube 15 links to each other with dropper 16 by sebific duct 20, and dropper is placed receiving bottle 17 16 times; Sulfuretted hydrogen detector tube 6, carbon dioxide detector tube 7 and Oxygen-detecting tube 8 fixing can being fixed on the work in combination platform 19; Will be before assembling with the sulfuretted hydrogen detector tube with adsorbing a certain amount of Pb (Ac)
2The silica gel of reagent is filled; Use the silica gel of handling through the thymolphthalein dilute alkaline soln to fill the carbon dioxide detector tube; The silica gel that the effective pyrogallic acid of oxygen detection was handled is filled.
(2) workflow of methane quick analytic instrument (seeing Fig. 1 and Fig. 2):
A, outlet valve 18 cuts out, open receiving flask bottle stopper 12 then, in methane collection bottle 14, fill it up with working fluid; Cover again and collect bottle stopper 12, will guarantee when covering to be full of working fluid in discharging tube 15, sebific duct 20, the dropper 16;
B, swivel tee valve 3 make conducting between injector 1 and the thief hatch 2, and sample to be measured is sucked in the injector 1; Open outlet valve 18, swivel tee valve 3 makes conducting between injector 1 and the detector tube fixation kit 4, slowly biogas is injected;
C, biogas at first enter by absorption a certain amount of Pb (Ac)
2The H that the silica gel of reagent is filled
2In the S detector tube 6, at this H
2S and Pb (Ac)
2React, generate vulcanized lead and become pitchy; The biogas that removes sulfuretted hydrogen continues to enter the CO that has filled the silica gel of handling through the thymolphthalein dilute alkaline soln along pipeline 9
2Detector tube 7 is at CO
2In the detector tube 7, carbon dioxide and alkali react and generate carbonate and remove from combination gas; Remaining gas enters O along pipeline 24
2Detector tube 8, oxygen that may exist in the mixed gas and O
2Pyrogallic acid in the detector tube 8 reacts and is absorbed;
D, remaining gas enter methane collection bottle 14 by draft tube 10, draft tube 11, and the working fluid of methane collection bottle 14 medium volumes is discharged in the receiving bottle 17 through discharging tube 15, sebific duct 20, dropper 16; With the volume of working fluid in the calibrated pipet metering receiving bottle, can calculate the content of methane again.
The determination test of methane content in embodiment 2 biogas
One, this is tested on July 30th, 2007 and carries out at stalk fermentation biogas engineering scene, Qing Country, Hebei Province.Method is as follows:
(1) fills it up with saturated calcium chloride solution in the methane collection bottle 14 with the methane quick analytic instrument, connect draft tube 10,11 and discharging tube 15, sebific duct 20, dropper 16, and make in discharging tube 15, sebific duct 20 and the dropper 16 of methane collection bottle and be full of saturated calcium chloride solution;
(2), thief hatch 2 is connected with source of the gas, swivel tee valve 3 is communicated with injector 1 and source of the gas;
(3), injector 1 is washed 3 times, constant volume is at 50ml then with biogas to be measured;
(4), the receiving bottle 17 of drying is placed on the below of dropper 16, open outlet valve 18, then T-valve 3 is rotated to the position that injector 1 communicates with sulfuretted hydrogen detector tube 6, slowly inject the gas sample, sample injection time is 70～80 seconds;
(5), advanced sample after, with the lower end mouth of pipe of dropper 16 to move down into methane collection bottle 14 in the contour position of liquid level;
(6), with the volume of working fluid in the calibrated pipet metering receiving bottle, the result be 25.1ml, the content that passes through methane in the conversion biogas is 50.2%.
Two, gas chromatography check analysis test:
On July 30th, 2007 is at Qing Country, Hebei Province stalk fermentation biogas engineering on-site sampling, on July 31st, 2007 was carried out gas chromatographic analysis to the biogas sample of being got with Agilent 1490 gas chromatographies in China Agricultural University gas analysis laboratory, its measured methane content 51% of result's (seeing Table 1) is basic identical with the methane content 50.2% that utilizes methane quick analytic instrument of the present invention scene to record, and illustrates that the inventive method accurately, reliably, fast.
Table 1 biogas gas chromatographic analysis result
| Sequence number | Retention time | Title | Concentration | Peak area |
| 1 | 1.543 | CO | 0.08777％ | 1431 |
| 2 | 1.880 | CH 4 | 51％ | 588581 |
| 3 | 2.662 | CO 2 | 48.09％ | 725826 |
| 4 | 7.628 | H 2S | 0.02974％ | 17391 |
Claims (10)
1, passes through the method for methane content in the indirect volume fast measuring biogas, it is characterized in that the methane gas in the biogas is fed the methane collection bottle of filling working fluid, the methane collection bottle is discharged isopyknic working fluid in receiving bottle, measure the volume of working fluid in the receiving bottle then, can calculate the content of methane in the biogas.
2, in accordance with the method for claim 1, it is characterized in that described working fluid is meant little, the not volatile liquid of methane solubleness.
3,, it is characterized in that described working fluid is water or saturated salt solution according to claim 1 or 2 described methods.
4, in accordance with the method for claim 3, it is characterized in that described saturated salt solution is sodium chloride solution or calcium chloride solution.
5, the described method by methane content in the indirect volume fast measuring biogas of claim 1 specifically comprises the steps:
(1), fill it up with working fluid in the methane collection bottle with methane analyser, connect draft tube and balance pipe, will with balance pipe that the methane collection bottle is connected in also be full of working fluid; Described balance pipe is made up of discharging tube, sebific duct and dropper, and discharging tube and dropper link together by sebific duct;
(2), the thief hatch of methane quick analytic instrument is connected with source of the gas, the swivel tee valve is communicated with injector and source of the gas;
(3), wash injector 2～5 times, constant volume is at 25～50ml then with gas to be measured;
(4), the receiving bottle of drying is placed on the below of the balance pipe mouth of pipe, open outlet valve, then T-valve is rotated to the position that injector communicates with gas detecting tube, in 70～80 seconds, slowly inject gas to be measured;
(5), after sample introduction finishes, the position that reduces the balance pipe mouth of pipe makes the liquid level of the working fluid in itself and the methane collection bottle contour;
(6), with the volume of working fluid in the calibrated pipet metering receiving bottle, can converse the content of methane.
6, in accordance with the method for claim 5, it is characterized in that described working fluid is little to methane solubleness, not volatile liquid.
7,, it is characterized in that described working fluid is water or saturated salt solution according to claim 5 or 6 described methods.
8, in accordance with the method for claim 7, it is characterized in that described saturated salt solution is sodium chloride solution or calcium chloride solution.
9, the methane quick analytic instrument described in the claim 5 is characterized in that it being to connect a methane collection bottle at the outlet valve place of ZS-2 type biogas constituent analysis device by sebific duct, the methane collection bottle two holes are arranged beyond the Great Wall, draft tube and discharging tube are housed respectively; Wherein the lower end of the length of draft tube and methane collection bottle cap flushes, and connects a dropper in the upper end of discharging tube by sebific duct, places a receiving bottle below dropper, is methane analyser of the present invention.
10, according to the described methane analyser of claim 9, comprise injector (1), thief hatch (2), injector (1) flexibly connects with an end of T-valve (3), and the other end of thief hatch (2) and T-valve (3) flexibly connects, and the 3rd end of T-valve (3) and fixation kit (4) flexibly connect; The two ends of sulfuretted hydrogen detector tube (6) are equipped with fixation kit (4) and fixation kit (5) movably respectively, the two ends of carbon dioxide detector tube (7) are equipped with fixation kit (13) and fixation kit (23) movably respectively, fixation kit (5) is connected with fixation kit (23) by pipeline (9), and sulfuretted hydrogen detector tube (6) and carbon dioxide detector tube (7) are communicated; The two ends of Oxygen-detecting tube (8) are equipped with fixation kit (21) and fixation kit (22) movably respectively, and fixation kit (22) links together by pipeline (24) and fixation kit (13), and carbon dioxide detector tube (7) and Oxygen-detecting tube (8) are communicated; Fixation kit (21) flexibly connects by screw thread and outlet valve (18); It is characterized in that outlet valve (18) is connected with draft tube (11) by sebific duct (10), the hole that draft tube (11) is passed methane collection bottle bottle stopper (12) is inserted in the methane collection bottle (14), and the diameter in the hole of the diameter of draft tube (11) and methane collection bottle bottle stopper (12) is corresponding; Another hole of methane collection bottle bottle stopper (12) is inserted with discharging tube (15), the diameter in the hole of the diameter of discharging tube (15) and receiving flask bottle stopper (12) is corresponding, discharging tube (15) links to each other with dropper (16) by sebific duct (20), and dropper (16) is placed receiving bottle (17) down; Sulfuretted hydrogen detector tube (6), carbon dioxide detector tube (7) and Oxygen-detecting tube (8) are fixing can be fixed on the work in combination platform (19).
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102261706A CN101403674B (en) | 2008-11-14 | 2008-11-14 | Method for fast measurement of methane content in biogas through indirect volume |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102261706A CN101403674B (en) | 2008-11-14 | 2008-11-14 | Method for fast measurement of methane content in biogas through indirect volume |
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| CN101403674B CN101403674B (en) | 2011-05-04 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102621032A (en) * | 2012-03-19 | 2012-08-01 | 扬州大学 | Automatic tester for gas content in coal gas |
| WO2015103758A1 (en) * | 2014-01-09 | 2015-07-16 | 中国石油天然气股份有限公司 | Apparatus for testing dense rock gas desorption rate |
| CN105699603A (en) * | 2016-03-24 | 2016-06-22 | 山西启光万嘉电子科技有限公司 | Gas purity converting instrument and methane gas converting method |
| CN112525766A (en) * | 2020-11-20 | 2021-03-19 | 张俊霞 | Device and method for measuring content of biological hydrogen alkane |
-
2008
- 2008-11-14 CN CN2008102261706A patent/CN101403674B/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102621032A (en) * | 2012-03-19 | 2012-08-01 | 扬州大学 | Automatic tester for gas content in coal gas |
| WO2015103758A1 (en) * | 2014-01-09 | 2015-07-16 | 中国石油天然气股份有限公司 | Apparatus for testing dense rock gas desorption rate |
| CN105699603A (en) * | 2016-03-24 | 2016-06-22 | 山西启光万嘉电子科技有限公司 | Gas purity converting instrument and methane gas converting method |
| CN112525766A (en) * | 2020-11-20 | 2021-03-19 | 张俊霞 | Device and method for measuring content of biological hydrogen alkane |
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| Publication number | Publication date |
|---|---|
| CN101403674B (en) | 2011-05-04 |
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