Summary of the invention
In order to solve the difficult problem of sludge treatment, the invention provides a kind of sludge treatment method, this method not only can not cause environmental pollution, and with low cost, can also produce the sludge foaming lightweight concrete that serves many purposes simultaneously.The enforcement of this method not only can solve the sludge treatment problem that sewage treatment industry faces, and can be by the recovery of mud and the light foaming concrete that utilizes production to serve many purposes.
The invention provides a kind of method for sludge treatment, this method for sludge treatment comprises the steps:
(1) in mud, adds unslaked lime, fully stir, thereby make the water generation chemical reaction in unslaked lime and the mud form sludge hydrated lime;
(2) in the sludge hydrated lime that step (1) produces, add cement and water, fully stir, form sludge concrete;
(3) foamed system by foaming machine fully foams whipping agent with mechanical system, and with uniform mixing on the mud coagulation of foam and step (2) generation.
In the method for sludge treatment of the present invention, the mud in the step (1) can be not through the primary sludge of dehydration, drying, concentration, also can be the thickened sludge through preliminary hydro-extraction, drying treatment.In step (1), the main component calcium oxide of unslaked lime and the water generation chemical reaction in the mud generate white lime (main component is a calcium hydroxide), its chemical equation:
CaO+H
2O==Ca(OH)
2
Owing to have only water and unslaked lime in the mud to react, still contain mud in the products therefrom of reaction back, be called sludge hydrated lime so will react the mixture of back formation.
Method for sludge treatment of the present invention, the mud in the step (1) and the part by weight of unslaked lime are 1:1 to 6:1.Unslaked lime in the step (1) preferably uses calcium lime powder.
Method for sludge treatment of the present invention, in step (2), the weight percent of each component is: sludge hydrated lime 30%--60%, cement 15%--40%, water 10%--40%.The preferred weight percent of each component is: sludge hydrated lime 40%--50%, cement 20%--35%, water 20%--30%.The optimum weight per-cent of each component is: sludge hydrated lime 50%, cement 25%, water 25%.
In step (2), can also in sludge hydrated lime, add flyash, described flyash can be the fine coal meeting that forms in the chimney, also can be the cinder that other combustionmaterial burning backs form is pulverized the flyash that the back forms.Under the situation that adds flyash, the weight percent of each component is: sludge hydrated lime 30%--60%, cement 10%--30%, flyash 5%--20%, water 10%--30%.The preferred weight percent of each component is: sludge hydrated lime 40%--50%, cement 15%--25%, flyash 10%--15%, water 15%--25%.The optimum weight per-cent of each component is: sludge hydrated lime 50%, cement 20%, flyash 10%, water 20%.
Whipping agent in the step (3) is to produce the employed whipping agent of common foamed concrete, such as RA rosin acid class whipping agent, metallic aluminium powder whipping agent, vegetable-protein whipping agent, animal protein foaming agent, sodium resinate class whipping agent, hydrolysis blood glue whipping agent, mahogany acid aluminium whipping agent etc., also can be mixtures two or more in them.The weight of used whipping agent is the 1%--10% of the sludge concrete weight of step (2) generation, and preferred 2%--5% is as 3%.
Method for sludge treatment of the present invention, the sludge foaming lightweight concrete that step (3) produces is by the jet orifice ejection of foamed system.
The invention provides on a kind of sludge foaming lightweight coagulation, this sludge foaming lightweight concrete contains dewatered sludge, white lime, cement, water, whipping agent, portion is formed with a large amount of foam holes within it, this sludge foaming lightweight concrete adopts following method to prepare: add unslaked lime in mud, fully stir, make the water generation chemical reaction in unslaked lime and the mud, form sludge hydrated lime; In sludge hydrated lime, add cement and water, and fully stir, form sludge concrete; Foamed system by foaming machine fully foams whipping agent with mechanical system then, and with foam and sludge concrete uniform mixing, promptly obtains sludge foaming lightweight concrete.
Can also contain flyash in the sludge foaming lightweight concrete of the present invention, in its preparation method, in sludge hydrated lime, add in cement and the water, add flyash again, can make in the sludge foaming lightweight concrete of final preparation and contain flyash.
Adopt method for sludge treatment of the present invention to handle mud and directly obtain sludge foaming lightweight concrete of the present invention.
Because in step (1), water section in the mud or all with unslaked lime in calcium oxide generation chemical reaction generate white lime, be that unslaked lime plays the effect of dehydration to mud, so contain dewatered sludge and white lime in the final sludge foaming lightweight concrete that forms of method for sludge treatment of the present invention.
Sludge foaming lightweight concrete of the present invention has following performance: 1. light weight, and volume density is 300-1500kg/m3, is equivalent to about 1/5~1/10 of normal concrete; 2. crushing resistance, ultimate compression strength and have good lateral pressure resistant performance more than 1.2Mpa, can produce the sludge foaming lightweight concrete of varying strength as required; 3. heat retaining property, extremely low thermal conductivity, thermal conductivity is lower than 0.2W/ (mk); 4. sound insulation contains a large amount of separated foams, and is evenly distributed in the sludge foaming lightweight concrete, sound absorbing power is 0.09-0.19%, is 5 times of normal concrete, possesses unique sound insulation function; 5. have good thermal insulation, thermal resistance is about 20-30 times of normal concrete, can play good effect of heat insulation; 6. the low shock resistance that plays, the porousness of sludge foaming lightweight concrete makes it have lower Young's modulus, thereby makes its impact load have good absorption and dispersion, and externally the power effect shows cushion, has improved shock resistance; 7. low absorptivity, sludge foaming lightweight concrete have tough and independently foaming connect, specific absorption makes it have certain protection against the tide, anti-permeability performance in 25%; 8. good integrity, but the cast-in-site construction combine closely with main construction, need not stay boundary's space and permeability cell; 9. from filling and self compacting ability, adopt this sludge foaming lightweight concrete operation, need not the machinery compacting, can fill voluntarily with closely knit; 10. pumpability is good, and mud foamed concrete has unique liquid and tough foaming, adds mobile strong, can carry out long distance pumping, and the operation injectability is strong, the mechanization degree height, but large-area construction is used to fill the tunnel and as the bed course of various interior of buildings.
The invention provides of the application of a kind of sludge foaming lightweight concrete, especially as the application of narrow slit, narrow groove packing material in roadbed, abutment packing material and the buildings as the building packing material.Owing to have good self-compacting from filling properties and lateral pressure resistant performance after sludge foaming lightweight concrete of the present invention solidifies, when being used as the building packing material, need not the machinery compacting, can form stable, firm obturator.If be used for roadbed, abutment packing material, can avoid roadbed, settlement; To carrying out narrow slit, the narrow groove of machinery compacting, sludge foaming lightweight concrete of the present invention can form the obturator with certain intensity in narrow slit, narrow groove.
The invention provides of the application of a kind of sludge foaming lightweight concrete as building thermal insulation material.Because sludge foaming lightweight concrete of the present invention has extremely low thermal conductivity, thermal conductivity is lower than 0.2W/ (mk), is used as lagging material, has good heat insulation effect.
The invention provides of the application of a kind of sludge foaming lightweight concrete as the body of wall construction material.Sludge foaming lightweight concrete of the present invention has certain compressive property, and ultimate compression strength and has good lateral pressure resistant performance more than 1.2Mpa, can be used for wall constructed; In addition, because it has in light weight, low density performance, with its wall constructed weight that can reduce body of wall itself.When especially adopting sludge foaming lightweight concrete of the present invention to construct non-bearing wall body, have certain intensity, reduce pressure, and have good sound insulation and heat insulation effect other structures in the buildings.
The invention provides of the application of a kind of sludge foaming lightweight concrete as sound-proof material.Such as, be used for making insulating board.Owing to contain a large amount of separated foams in the sludge foaming lightweight concrete of the present invention, and be evenly distributed, sound absorbing power is 0.09-0.19%, be 5 times of normal concrete, possesses unique sound insulation function, so can be used as sound-proof material, be used for making insulating board, for example the insulating board between urban road and the residential quarter.
The invention provides of the application of a kind of sludge foaming lightweight concrete as tunnel, mine packing material.After the mining of zone, mine, coal mining, quarrying, can form various tunnels, because sludge foaming lightweight concrete of the present invention has good self-compacting ability of filling certainly and lateral pressure resistant performance, after utilizing the anti-road of sludge foaming lightweight concrete backfill of the present invention, sedimentation can not take place in the mining area, mining area safety be can improve, the redevelopment in mining area and utilization again helped.
The invention provides the application of a kind of sludge foaming lightweight concrete in making man-made tourist site.Sludge foaming lightweight concrete of the present invention has pumpability, and is mobile strong, can carry out long distance pumping, and have certain intensity after solidifying, and can be used for making man-made tourist site, as artificial hillock.
The invention provides a kind of sludge foaming lightweight concrete as the speedily carry out rescue work application of material of road.Road subsides or damaged situation happens occasionally, and in order to guarantee The coast is clear, often needs to carry out road emergency and speedily carries out rescue work.Because sludge foaming lightweight concrete of the present invention has moderate ultimate compression strength, subside or breakage is filled sludge foaming lightweight concrete of the present invention at road, as the road emergency material of speedily carrying out rescue work, can ensure The coast is clear, root out when also being convenient to road rehabilitation and excavate.
The invention provides of the application of a kind of sludge foaming lightweight concrete as the basic packing material of pipe.When laying various pipeline, pipeline is transferred and will be laid packing material, lay soil or sand during traditional constructional method as packing material, because of the existence of pipeline is difficult to carry out the machinery compacting, especially the laying of alleyway pipeline, owing to be subjected to the restriction of surrounding environment, be difficult to carry out the machinery compacting more, because of soil and sand softer, sedimentation in various degree can take place, especially sand can run off with rainwater, sedimentation phenomenon is more serious, can cause pipe base the cavity to occur like this, cause piping displacement, even cause pipeline break because of unbalance stress.Because sludge foaming lightweight concrete of the present invention has from filling the self-compacting function, adopts sludge foaming lightweight concrete of the present invention as the pipeline packing material, need not mechanical compacting and can reach closely knit effect, effectively avoids the generation of sedimentation phenomenon; In addition, after sludge foaming lightweight concrete of the present invention solidifies, can form and the corresponding Guan Ji of the shape of pipeline, can make pipeline keep stable.
Method for sludge treatment of the present invention is not only with low cost, the protection environment; and can reach the effect of mud recycle; can produce the sludge foaming lightweight concrete that serves many purposes; also can be that the flyash that pile up like a mountain obtains recycle simultaneously, meet resource utilization, minimizing, the harmless treatment requirement of solid waste.
Embodiment
At first, in mixing system 1, add mud and unslaked lime, under the stirring of stirring system 2, make the water reaction in unslaked lime and the mud, generate sludge hydrated lime; Then, cement and water are added in the mixing system 1, under the stirring of stirring system 2, make their thorough mixing, form sludge concrete.Inhale at pump under the effect of foamed system 4, make in sludge concrete in the mixing system 1 and the whipping agent bucket 3 whipping agent enter pump and inhale foamed system 4, inhale in the foamed system 4 at pump, foam that whipping agent produces and sludge concrete mix, and promptly produce sludge foaming lightweight concrete.
Can also add flyash when in mixing system 1, adding cement and water.Pump is inhaled jet orifice 5 ejections of the sludge foaming lightweight concrete of formation in the foamed system 4 by pump suction foamed system 4.
Below by embodiment, sludge foaming lightweight concrete that method for sludge treatment of the present invention and this method are formed and uses thereof is further described.Embodiment and the following examples only are for technical scheme of the present invention is described, are not limitation of the present invention.
Embodiment 1
In 1000 gram mud, add 1000 gram unslaked limes, fully stir, make the water generation chemical reaction in unslaked lime and the mud form sludge hydrated lime; In sludge hydrated lime, add cement 800 grams, flyash 400 grams, water 800 grams then, fully stir, form sludge concrete; Foamed system by foaming machine fully foams 120 gram whipping agents with mechanical system, with foam and sludge concrete uniform mixing, can obtain sludge foaming lightweight concrete.
Embodiment 2
In 1000 gram mud, add 750 gram unslaked limes, fully stir, make the water generation chemical reaction in unslaked lime and the mud form sludge hydrated lime; In sludge hydrated lime, add cement 875 grams, flyash 650 grams, water 1100 grams then, fully stir, form sludge concrete; Foamed system by foaming machine fully foams 87.5 gram whipping agents with mechanical system, with foam and sludge concrete uniform mixing, can obtain sludge foaming lightweight concrete.
Embodiment 3
In 1000 gram mud, add 500 gram unslaked limes, fully stir, make the water generation chemical reaction in unslaked lime and the mud form sludge hydrated lime; In sludge hydrated lime, add cement 1070 grams, flyash 645 grams, water 1070 grams then, fully stir, form sludge concrete; Foamed system by foaming machine fully foams 215 gram whipping agents with mechanical system, with foam and sludge concrete uniform mixing, can obtain sludge foaming lightweight concrete.
Embodiment 4
In 1000 gram mud, add 250 gram unslaked limes, fully stir, make the water generation chemical reaction in unslaked lime and the mud form sludge hydrated lime; In sludge hydrated lime, add cement 625 grams, flyash 470 grams, water 780 grams then, fully stir, form sludge concrete; Foamed system by foaming machine fully foams 62.5 whipping agents with mechanical system, with foam and aforementioned mixture uniform mixing, can obtain sludge foaming lightweight concrete.
Embodiment 5
The sludge foaming lightweight concretes that embodiment 1,2,3 or 4 is produced are by cast-in-site, as roadbed, abutment packing material, fill closely knitly after sludge foaming lightweight concrete solidifies voluntarily, can avoid road surface, bridge floor sedimentation.
Embodiment 6
The sludge foaming lightweight concretes that embodiment 1,2,3 or 4 is produced are by cast-in-site, as narrow slit, narrow groove packing material in the building structure, fill closely knitly after sludge foaming lightweight concrete solidifies voluntarily, need not to carry out machinery and tamp.
Embodiment 7
The sludge foaming lightweight concretes that embodiment 1,2,3 or 4 is produced spread upon the outside surface of buildings, as lagging material, can avoid winter indoor heat to scatter and disappear, and can avoid summer in the outdoor heat inlet chamber.
Embodiment 8
Adopt non-bearing wall body in embodiment 1,2,3 or the 4 sludge foaming lightweight concrete building constructions that produce, the wall weight of constructing is light, not only can alleviate the pressure of body of wall to other structures of buildings, and has good soundproof effect.
Embodiment 9
Embodiment 1,2,3 or 4 sludge foaming lightweight concretes that produce are made into platy structure, can be used as insulating board, can also in insulating board, build as required, this insulating board is installed between road and the residential quarter, can obtain good soundproof effect into stiffeners such as reinforcing bars.
Embodiment 10
Adopt embodiment 1,2,3 or 4 sludge foaming lightweight concretes that produce to fill tunnel, waste and old colliery, sludge foaming lightweight concrete solidifies the back fills closely knitly, and can form firm obturator, can sedimentation, improve security.
Embodiment 11
Embodiment 1,2,3 or 4 sludge foaming lightweight concretes that produce are sprayed, and adopt mechanical means to make it form predetermined shape, can form artificial hillock after solidifying.
Embodiment 12
The sludge foaming lightweight concretes that embodiment 1,2,3 or 4 is produced lay or are filled in that road subsides or breakage, and make the sludge foaming lightweight concrete of laying or filling concordant with the intact part of road, make the road maintenance unimpeded.When road rehabilitation, the sludge foaming lightweight concrete that will solidify is rooted out with comparalive ease.
Embodiment 13
When the pipe laying of alleyway, the sludge foaming lightweight concretes that embodiment 1,2,3 or 4 is produced are laid on pipeline and transfer, as the pipe sill, then circular pipe is laid on the sludge foaming lightweight concrete, need not to carry out the machinery compacting, can fill closely knitly, after sludge foaming lightweight concrete solidifies, can below pipeline, form firm Guan Ji.
The present invention can also summarize with other specific forms without prejudice to spirit of the present invention or principal character.Therefore; no matter from which point; above-mentioned embodiment of the present invention can only be thought can not limit the present invention to explanation of the present invention; claim has been pointed out technical scheme of the present invention and scope; therefore; in implication suitable and any modification in the scope, all will be understood that in the protection domain that is included in claim with the present invention.