CN101330899B - Oil-based liquid cleansing composition - Google Patents
Oil-based liquid cleansing composition Download PDFInfo
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- CN101330899B CN101330899B CN2006800475856A CN200680047585A CN101330899B CN 101330899 B CN101330899 B CN 101330899B CN 2006800475856 A CN2006800475856 A CN 2006800475856A CN 200680047585 A CN200680047585 A CN 200680047585A CN 101330899 B CN101330899 B CN 101330899B
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- oil
- fatty acid
- acid
- based liquid
- ester
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
Abstract
The oil-based liquid cleansing composition is characterized by containing a diester of a fatty acid having 6 to 10 carbon atoms and a dihydric alcohol, and a nonionic surfactant.It is intended to provide an oil-based liquid cleansing composition which has a high cleansing ability, an excellent ability to blend with a makeup cosmetic, is easy to be washed out, and has an excellent ability to be used with wet hands.
Description
Technical field
The present invention relates to oil-based liquid cleansing composition.
Background technology
In order to the oil-based liquid cleansing composition of washing dirt on the skin, cosmetic cosmetics off in market sale.Oil-based liquid cleansing composition is compared the cleaning effect excellence with cream shape, emulsion form cleaning composition or the aqueous liquogel shape cleaning composition of oil-in-water type.
Developed the technology (patent documentation 1 TOHKEMY 2003-267835 communique, patent documentation 2 TOHKEMY 2005-2047 communiques) that oil-based liquid cleansing composition viscosity is improved, the solubility of oil-based liquid cleansing composition is improved, the technology (patent documentation 3 TOHKEMY 2005-194249 communiques) that available wet hands uses.The present inventor constantly studies intensively, with above-mentioned art applications patent (patent documentation 4 TOHKEMY 2003-252726 communiques, patent documentation 5 TOHKEMY 2005-162691 communiques).
But, because the cosmetic cosmetics of the excellent durability of resistance to water, oil resistivity etc. in exploitation, are cleaned the excellent more cleaning composition of effect so expectation is developed.
Patent documentation 1 TOHKEMY 2003-267835 communique
Patent documentation 2 TOHKEMY 2005-2047 communiques
Patent documentation 3 TOHKEMY 2005-194249 communiques
Patent documentation 4 TOHKEMY 2003-252726 communiques
Patent documentation 5 TOHKEMY 2005-162691 communiques
Summary of the invention
The invention provides have high clean ability, with cosmetic cosmetics mix excellent performance, the oil-based liquid cleansing composition of the excellent performance that uses of flushing and available wet hands easily.
Of the present invention main composed as follows described:
(1) oil-based liquid cleansing composition is characterized in that, contains carbon number and be diester and nonionic surfactant that 6～10 fatty acid and dihydroxylic alcohols form.
As (1) described oil-based liquid cleansing composition, it is characterized in that (2) fatty acid is a branched chain fatty acid.
(3) as (1) or (2) described oil-based liquid cleansing composition, it is characterized in that, dihydroxylic alcohols be from the group of forming by propylene glycol, 1,3 butylene glycol, dipropylene glycol, select more than a kind or 2 kinds.
(4) as each described oil-based liquid cleansing composition in (1)～(3), it is characterized in that, nonionic surfactant be from the group of forming by polyglyceryl fatty acid ester, polyoxyethylene fatty acid glyceride, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sorbitan fatty acid ester, castor oil hydrogenated polyoxyethylene ether, castor oil polyoxyethylene ether, select more than a kind or 2 kinds.
(5) as each described oil-based liquid cleansing composition in (1)～(4), it is characterized in that, carbon number is that diester that 6～10 fatty acid and dihydroxylic alcohols form is from by two 2 ethyl hexanoic acid propylene glycol esters, two 2 ethyl hexanoic acids 1, select in the group that 3-butanediol ester, two 2 ethyl hexanoic acid dipropylene glycol esters, two different n-nonanoic acid propylene glycol esters, two different n-nonanoic acid 1,3 butylene glycol esters, two different n-nonanoic acid dipropylene glycol esters are formed more than a kind or 2 kinds.
(6) as each described oil-based liquid cleansing composition in (1)～(4), it is characterized in that, carbon number be diester that 6～10 fatty acid and dihydroxylic alcohols form be from the group of forming by two (2 ethyl hexanoic acid/different n-nonanoic acid) propylene glycol ester, two (2 ethyl hexanoic acid/different n-nonanoic acid) 1,3 butylene glycol ester, two (2 ethyl hexanoic acid/different n-nonanoic acid) dipropylene glycol ester, select more than a kind or 2 kinds.
The present invention can provide have high clean ability, with cosmetic cosmetics mix excellent performance, the oil-based liquid cleansing composition of the excellent performance that uses of flushing and available wet hands easily.
And said composition is transparent, and is stable in low temperature～pyritous temperature range.
The specific embodiment
It is the diester that 6～10 fatty acid and dihydroxylic alcohols form that the present invention uses carbon number.When use was the diester of the fatty acid formation more than 11 with carbon number, with the intermiscibility variation of cosmetics, and sense of touch was puckery heavy, so the usability variation.As carbon number is 6～10 fatty acid, can be 2 ethyl hexanoic acid, different n-nonanoic acid, caproic acid, sad, capric acid etc.Carbon number is in 6～10 the fatty acid, and the clean ability of branched chain fatty acid is excellent more, and the performance that available wet hands uses is excellent more.Dihydroxylic alcohols can be ethylene glycol, propylene glycol, 1,3 butylene glycol, dipropylene glycol, neopentyl glycol, 1,2-pentanediol etc.In dihydroxylic alcohols, because of propylene glycol, 1,3 butylene glycol, dipropylene glycol can obtain higher clean ability, so preferred.
Carbon number is the diester that 6～10 fatty acid and dihydroxylic alcohols form, be specifically as follows two 2 ethyl hexanoic acid glycol esters, two 2 ethyl hexanoic acid propylene glycol esters, two 2 ethyl hexanoic acids 1, the 3-butanediol ester, two 2 ethyl hexanoic acid dipropylene glycol esters, two 2 ethyl hexanoic acid DOPCP, two 2 ethyl hexanoic acids 1, the 2-pentadiol ester, two different n-nonanoic acid glycol esters, two different n-nonanoic acid propylene glycol esters, two different n-nonanoic acids 1, the 3-butanediol ester, two different n-nonanoic acid dipropylene glycol esters, two different n-nonanoic acid DOPCP, two different n-nonanoic acids 1, the 2-pentadiol ester, two caproic acid glycol esters, two caproic acid propylene glycol esters, two caproic acids 1, the 3-butanediol ester, two caproic acid dipropylene glycol esters, two caproic acid DOPCP, two caproic acids 1, the 2-pentadiol ester, Ethylene glycol dicaprylate, two sad propylene glycol esters, two sad 1, the 3-butanediol ester, two sad dipropylene glycol esters, two sad DOPCP, two sad 1, the 2-pentadiol ester, Ethylene didecanoate, the didecyl acid propylene glycol ester, two capric acid 1, the 3-butanediol ester, two capric acid dipropylene glycol esters, two capric acid DOPCP, two capric acid 1,2-pentadiol ester etc.
In above-mentioned diester, because two 2 ethyl hexanoic acid glycol esters, two 2 ethyl hexanoic acid propylene glycol esters, two 2 ethyl hexanoic acids 1,3-butanediol ester, two 2 ethyl hexanoic acid dipropylene glycol esters, two 2 ethyl hexanoic acid DOPCP, two 2 ethyl hexanoic acids 1,2-pentadiol ester, two different n-nonanoic acid glycol esters, two different n-nonanoic acid propylene glycol esters, two different n-nonanoic acids 1,3-butanediol ester, two different n-nonanoic acid dipropylene glycol esters, two different n-nonanoic acid DOPCP, two different n-nonanoic acids 1, the 2-pentadiol ester can obtain the high ability of cleaning, so preferred.Because of two 2 ethyl hexanoic acid propylene glycol esters, two 2 ethyl hexanoic acids 1,3-butanediol ester, two 2 ethyl hexanoic acid dipropylene glycol esters, two different n-nonanoic acid propylene glycol esters, two different n-nonanoic acids 1,3-butanediol ester, two different n-nonanoic acid dipropylene glycol esters can obtain the performance of excellent clean ability, flushing performance, available wet hands use, so preferred especially.
In addition, can especially preferably use two (2 ethyl hexanoic acid/different n-nonanoic acid) propylene glycol ester, two (2 ethyl hexanoic acid/different n-nonanoic acid) 1,3 butylene glycol ester, two (2 ethyl hexanoic acid/different n-nonanoic acid) dipropylene glycol ester equally as the mixed ester of 2 ethyl hexanoic acid and different n-nonanoic acid.
These carbon numbers are that the diester that 6～10 fatty acid and dihydroxylic alcohols form can be bought the use commercially available product.
Perhaps, can utilize usual way to make carbon number is that 6～10 fatty acid and dihydroxylic alcohols obtain in conjunction with forming ester.
For example, under the condition that catalyst exists, alcohol (1mol) and fatty acid (2.2mol) are heated to 200 ℃, the water of generation is removed in distillation.After sufficient reacting carries out, remove excess fats acid and catalyst, the reactant liquor (about 150～200 ℃, about 0.1Torr) that obtains is made with extra care, can access the target ester by distilling under reduced pressure.Catalyst can use common esterification catalyst (acid catalyst, base catalyst, metallic catalyst etc.).
In oil-based liquid cleansing composition of the present invention, can also contain above-mentioned carbon number and be the oil preparation beyond the diester that 6～10 fatty acid and dihydroxylic alcohols form, for example hydrocarbon ils, natural oil, ester oil, silicone oil, higher fatty acids, higher alcohol etc.
Hydrocarbon ils can be liquid paraffin, squalane etc., natural oil can be olive oil, Jojoba wet goods, ester oil can be different n-nonanoic acid 2-Octyl Nitrite, isononyl isononanoate, different isodecyl pelargonate, octyl palmitate, 2 ethyl hexanoic acid hexadecyl ester, three (suffering/capric acid) glyceride, three-2 ethyl hexanoic acid glyceride etc., silicone oil can be methyl polysiloxane, methyl phenyl silicone etc., higher fatty acids can be isostearic acid, oleic acid etc., and higher alcohol can be octyldodecanol, oleyl alcohol etc.
The carbon number that the present invention is used is the use level that the diester that forms of 6～10 fatty acid and dihydroxylic alcohols and other oil preparationes add whole oil preparationes together, with respect to whole compositions of oil-based liquid cleansing composition of the present invention, is preferably 40～95 quality %.Be lower than at 40% o'clock, make cosmetics floating effect of coming out in the skin insufficient, not preferred as oil-based liquid cleansing composition.If be more than 95% in addition, be difficult to the water flushing.
The carbon number that the present invention uses is the use level of the diester that forms of 6～10 fatty acid and dihydroxylic alcohols, with respect to whole compositions of oil-based liquid cleansing composition of the present invention, is preferably 5～95 quality %, more preferably 40～95 quality %.Be lower than at 5% o'clock, can not give full play to and the effect that mixes of cosmetics, clean effect.Cooperate by surpassing 40 quality %, with the effect that mixes of cosmetics, clean effect excellence especially.
The surfactant that the present invention uses is a nonionic surfactant.If only use anionic surfactant, cationic surfactant, amphoteric surfactant, poor with the intermiscibility of oil preparation, be not suitable for cleaning composition.In the scope of not destroying effect of the present invention, nonionic surfactant and anionic surfactant, cationic surfactant, amphoteric surfactant can be used in combination.
The nonionic surfactant that the present invention uses can be polyglyceryl fatty acid ester class, polyoxyethylene glycerine fatty acid esters, polyoxyethylene fatty acid ester class, polyoxyethylene sorbitan fatty acid ester class, sorbitan fatty acid ester class, polyoxyethylene alkyl ether class, castor oil hydrogenated polyethenoxy ether class, castor oil polyoxyethylene ether class, polyoxyethylene sorbitol four fatty acid esters, glycerine fatty acid esters, sucrose-fatty esters, alkyl glucose glycoside, alkyl poly glucoside class, fatty acid alkanol amides class etc.The HLB of the nonionic surfactant that uses among the present invention, from the intermiscibility of oil preparation and the dispersibility water, be preferably 5～15, more preferably 6～13.
In nonionic surfactant, particularly can obtain the oil-based liquid cleansing composition of the excellent performance of excellent in stability, easy washability, available wet hands use, so preferred because of polyglyceryl fatty acid ester, polyoxyethylene fatty acid glyceride, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sorbitan fatty acid ester, castor oil hydrogenated polyoxyethylene ether, castor oil polyoxyethylene ether.
As above-mentioned polyglyceryl fatty acid ester, can be ten Risorex PGIS 22s, 20 polyglycereol, six caprylates, polyglyceryl-isostearate, Risorex PGIS 22, polyglycereol three isostearates, the polyglycereol tetraoctyl stearate, the polyglycereol laurate, the polyglycereol dilaurate, the polyglycereol trilaurin, polyglycereol cinnamic acid in April ester, the polyglycereol caprylate, the polyglycereol dicaprylate, polyglycereol three caprylates, polyglycereol four caprylates, POGE-A POGE-B POGE-C Polyglycerin palmitate, the polyglycereol dipalmitate, the polyglycereol tripalmitate, polyglycereol four cetylates etc.
As above-mentioned polyoxyethylene glycerine fatty acid esters, can be polyoxyethylene glycerol three isostearates (20E.O.), polyoxyethylene glycerol list coco-nut oil fatty acid ester (7E.O.), polyoxyethylene glyceryl monostearate (5E.O.), TMGO 5 (15E.O.) etc.
As above-mentioned polyoxyethylene fatty acid ester class, can be polyethyleneglycol isostearate etc.
As above-mentioned polyoxyethylene sorbitan fatty acid ester class, can be polyoxyethylene sorbitol acid anhydride coco-nut oil fatty acid ester (20E.O.), polyoxyethylene sorbitan monostearate (20E.O.), Tween-81 (20E.O.) etc.
As above-mentioned sorbitan fatty acid ester class, can be sorbitan list isostearate, sorbitan monostearate etc.
As above-mentioned polyoxyethylene alkyl ether class, can be polyoxyethylene laurel ether, polyoxyethylene oleyl ether, polyoxyethylene iso stearyl ether etc.
The use level of the nonionic surfactant that the present invention uses with respect to whole compositions of oil-based liquid cleansing composition of the present invention, is preferably scope 1～40%, is preferably range fit 5～25% especially.Be lower than at 1% o'clock, washing (-)off properties, the washing performance of compositions are insufficient, are higher than at 40% o'clock, consider the probability that has " mobile difference can not keep oil-based liquid ", " producing the problems such as stimulation to skin during use " etc.
Also can hydrous water in the oil-based liquid cleansing composition of the present invention.If but a large amount of hydrous water, water can not wrap in the oil phase fully, can form O/W emulsion composition.Therefore, the use level of preferred water is lower than 50 quality %, especially preferably is lower than 20 quality %.
In oil-based liquid cleansing composition of the present invention, in the scope of not damaging function of the present invention, can cooperate functional components such as polyalcohols, polyalkylene glycols, saccharide, lower alcohols, high score subclass, organic and inorganic powdery type, antiseptic, antioxidant.
Embodiment
Enumerate embodiment below and be elaborated, but the present invention is not limited to these embodiment.
Prepare the oil-based liquid cleansing composition of the composition shown in table 1～4 according to following method for making, according to the transparency of following these oil-based liquid cleansing compositions of sequence evaluating, low-temperature stability, high-temperature stability, cosmetics intermiscibility, the easy performance used of washability, available wet hands.The result is shown in table 1～4.
(method for making)
Mix after oil preparation and surfactant be heated to 80 ℃, be cooled to room temperature.
(transparency)
Observe the outward appearance of oil-based liquid cleansing composition, according to following standard evaluation.
Zero: transparent
△: translucent
*: do not dissolve
(5 ℃ of low-temperature stabilities)
In 5 ℃ temperature chamber, oil-based liquid cleansing composition was preserved 24 hours, according to following standard evaluation.
Zero: transparent
△: translucent
*: muddy or separation
(40 ℃ of high-temperature stabilities)
In 40 ℃ temperature chamber, oil-based liquid cleansing composition was preserved 24 hours, according to following standard evaluation.
Zero: transparent
△: translucent
*: muddy or separation
(cosmetics intermiscibility)
Estimate by the following method with the intermiscibility of cosmetics.Circular artificial skin plate (the white) (eaulax of Co., Ltd. B (Japanese original name: the system PVC ユ of Co., Ltd. one ラ Star Network ス)) go up the liquid foundation of evenly smearing about 0.1g at diameter 5cm with finger tip, use the hair-dryer drying, press medicated napkin with hands, liquid foundation can not rub, even can not adhered to yet when it is taken off.In the flat plate of internal diameter 8.5cm, add the 5g oil-based liquid cleansing composition then, make the liquid foundation spreader portion of artificial skin plate contact and float over liquid level on the oil-based liquid cleansing composition in the flat plate down.Make flat plate up and down, tilt, make buoyant artificial skin plate along pump 2.5 times, about move back and forth 2.5 times, from flat plate, take out then, press medicated napkin with hands, can not rub, it is taken off, this operation is carried out ten times, estimates the situation that liquid foundation drops by color difference measurement again.The beam split variable angle colour difference meter GC5000 type that uses Japanese electric color Industrial Co., Ltd to make, be determined at liquid foundation smear before, smear after, mix with oil-based liquid cleansing composition and pin medicated napkin and remove with hands after the L of artificial skin plate
*a
*b
*Value.
Set the L of the artificial skin plate before liquid foundation is smeared
*a
*b
*Value is L
*(A), a
*(A), b
*The L of the artificial skin plate after (A), liquid foundation is smeared
*a
*b
*Value is L
*(B), a
*(B), b
*(B), mix the L of the artificial skin plate after pinning medicated napkin and removing with oil-based liquid cleansing composition
*a
*b
*Value is L
*(C), a
*(C), b
*(C).
Utilizing formula 1 to obtain liquid foundation smears the back and smears preceding aberration Δ E (0).
Formula 1
ΔE(0)＝[(L
*(B)-L
*(A))
2+(a
*(B)-a
*(A))
2+(b
*(B)-b
*(A))
2]
1/2
Smear liquid foundation, mix with oil-based liquid cleansing composition, the aberration Δ E (1) of artificial skin plate utilized formula 2 to obtain before artificial skin plate after pinning medicated napkin and removing and liquid foundation were smeared.
Formula 2
ΔE(1)＝[(L
*(C)-L
*(A))
2+(a
*(C)-a
*(A))
2+(b
*(C)-b
*(A))
2]
1/2
Utilize formula 3 to obtain the residual rate of liquid foundation.
Formula 3
Liquid foundation residual rate=Δ E (1)/Δ E (0) * 100
Evaluation criterion is as follows.
Zero: the liquid foundation residual rate is lower than 50%
△: the liquid foundation residual rate is to be lower than 80% more than 50%
*: the liquid foundation residual rate is more than 80%
Or because of oil preparation and immiscible, the inhomogeneous and not measurable situation of surfactant.
(easily washability)
In the beaker of 100ml, add 90g water, add the oil-based liquid cleansing composition of 0.1mL, stir 10 times with scraper plate.Because so the oil-based liquid cleansing composition homodisperse of easy flushing is according to following standard evaluation.
Zero: homodisperse.
△: micro-oil content is floating.
*: there is oil content floating, perhaps has not dispersive floating material in the water.
Or because of oil preparation and immiscible, the inhomogeneous and not measurable situation of surfactant.
(performance that available wet hands uses)
The oil-based liquid cleansing composition that adds 3.5g in vitro adds 0.105g water, the visual assessment transparency.If transparent, water dissolves in oil-based liquid cleansing composition, can bring into play cleaning function.If the muddy degree of trace may be brought into play cleaning action.On the other hand, if the situation of white opacity, water is in undissolvable dispersity in the oil-based liquid cleansing composition, can not bring into play cleaning function.Therefore, according to following standard evaluation.
Zero: transparent
△: muddy a little
*: white opacity
Or because of oil preparation and immiscible, the inhomogeneous and not measurable situation of surfactant.
Table 1
Table 2
Table 3
Table 4
Be combined with carbon number and be two 2 ethyl hexanoic acids 1 of the diester that 6～10 fatty acid and dihydroxylic alcohols form, the oil-based liquid cleansing composition of the embodiment 1～3 of 3-butanediol ester, two different n-nonanoic acid propylene glycol esters and nonionic surfactant, its cosmetics residual rate all is lower than 50%, and the cosmetics intermiscibility is excellent especially.On the other hand, be combined with the oil-based liquid cleansing composition of the comparative example 3～11 of ester oil 2 ethyl hexanoic acid hexadecyl ester, triglycerin ester oil three 2 ethyl hexanoic acid glyceride and nonionic surfactant that hydrocarbon ils liquid paraffin, unary fatty acid and monobasic higher alcohol form, its cosmetics residual rate is more than 50%, or be more than 80%, the cosmetics intermiscibility is poor.In addition, also exist because of oil preparation and the surfactant not measurable situation that can not evenly mix.The performance of the transparency of the oil-based liquid cleansing composition of embodiments of the invention 1,3, low-temperature stability (5 ℃), high-temperature stability (40 ℃), easily washability, available wet hands use is excellence all.Be combined with the embodiment 2 of surfactant polyoxyethylene sorbitan monostearate (20E.O.) and sorbitan list isostearate, the slightly inferior properties that its low-temperature stability (5 ℃), high-temperature stability (40 ℃), easy washability, available wet hands use, but main target detergency of the present invention (cosmetics intermiscibility) excellence.Use surfactant similarly to Example 2, be combined with the comparative example 4,7,10 of liquid paraffin, 2 ethyl hexanoic acid hexadecyl ester, three 2 ethyl hexanoic acid glyceride, its oil preparation and surfactant all can not evenly mix.Therefore, carbon number is that the diester that 6～10 fatty acid and dihydroxylic alcohols form is compared the preparation fitness excellence when making up with nonionic surfactant with other oil preparation.Be combined with the comparative example 3,5 of liquid paraffin, although be combined with nonionic surfactant, oil preparation and surfactant can not evenly mix, and can't measure cleaning function.Be combined with the comparative example 6,8 of 2 ethyl hexanoic acid hexadecyl ester and nonionic surfactant, the performance of its transparency, low-temperature stability (5 ℃), high-temperature stability (40 ℃), easily washability, available wet hands use is excellence all, but it is as mentioned above, poor as the detergency (cosmetics intermiscibility) of main target of the present invention.Be combined with the comparative example 9,11 of three 2 ethyl hexanoic acid glyceride and non-ionic surface active agent, though its transparency, low-temperature stability (5 ℃), high-temperature stability (40 ℃) excellence, but the cosmetics intermiscibility, easily washability is poor, the poor performance that particularly available wet hands uses.In addition, shown in comparative example 1,2, promptly using carbon number is the diester that 6～10 fatty acid and dihydroxylic alcohols form, because of with the immiscible function that can not bring into play cleaning composition of anion surfactant.
Embodiment
Then exemplify embodiment and be elaborated, but the present invention is not limited to these embodiment.
The same method for making of the oil-based liquid cleansing composition of utilization and above-mentioned table 1～table 4 prepares the oil-based liquid cleansing composition of the composition shown in the table 5, and the same quadrat method of the performance utilization of its transparency, low-temperature stability, high-temperature stability, cosmetics intermiscibility, easily washability, available wet hands use and the oil-based liquid cleansing composition of above-mentioned table 1～table 4 is estimated.The result is as shown in table 5.
Table 5
Be combined with carbon number and be two different n-nonanoic acids 1 of the diester that 6～10 fatty acid and dihydroxylic alcohols form, the oil-based liquid cleansing composition of the embodiment 4～6 of 3-fourth diester and nonionic surfactant, its cosmetics residual rate all is lower than 50%, and the cosmetics intermiscibility is excellent especially.The performance of the transparency of the oil-based liquid cleansing composition of embodiments of the invention 4～6, low-temperature stability (5 ℃), high-temperature stability (40 ℃), easily washability, available wet hands use is excellence all.
Prescription example 1
Composition name use level (quality %)
1 two 2 ethyl hexanoic acid 1,3 butylene glycol esters 60
2 octyl palmitates 20
30 Risorex PGIS 22s 10
4 two ten polyglycereol, six caprylates 9.9
5 dextrin cetylates 0.1
Prescription example 2
Composition name use level (quality %)
1 two different n-nonanoic acid propylene glycol esters 70
2 three 2 ethyl hexanoic acid glyceride 10
3 polyoxyethylene glycerol, three isostearates 18
4 (mountain Yu acid/eicosane diacid) glyceride 2
Prescription example 3
Composition name use level (quality %)
1 two different n-nonanoic acid 1,3 butylene glycol esters 70
2 octyldodecanols 10
30 Risorex PGIS 22s 15
4 two ten polyglycereol, six caprylates 4.5
5 (mountain Yu acid/eicosane diacid) glyceride 0.5
Prescription example 4
Composition name use level (quality %)
1 two 2 ethyl hexanoic acid propylene glycol esters 70
2 spiraea oils 10
30 Risorex PGIS 22s 10
4 two ten polyglycereol, six caprylates 9.9
5 dextrin cetylates 0.1
Prescription example 5
Composition name use level (quality %)
1 two 2 ethyl hexanoic acid propylene glycol esters 50
2 two different n-nonanoic acid 1,3 butylene glycol esters 30
30 Risorex PGIS 22s 10
4 two ten polyglycereol, six caprylates 8.5
5 (mountain Yu acid/eicosane diacid) glyceride 1.5
Prescription example 6
Composition name use level (quality %)
1 two 2 ethyl hexanoic acid 1,3 butylene glycol esters 40
22 ethyl hexanoic acid hexadecyl esters 40
3 polyoxyethylene glycerol, three isostearates 15
4 castor oil hydrogenated polyoxyethylene ether 4.5
5 dextrin cetylates 0.5
Prescription example 7
Composition name use level (quality %)
1 two different n-nonanoic acid 1,3 butylene glycol esters 44
2 three (the hot last of the ten Heavenly stems) acid glyceride 40
30 Risorex PGIS 22s 10
4 two ten polyglycereol, six caprylates 5
5 (mountain Yu acid/eicosane diacid) glyceride 1
Prescription example 8
Composition name use level (quality %)
1 two 2 ethyl hexanoic acid 1,3 butylene glycol esters 70
2 squalanes 10
3 polyoxyethylene glycerol, three isostearates 15
4 castor oil hydrogenated polyoxyethylene ether 5
Prescription example 9
Composition name use level (quality %)
1 two different n-nonanoic acid propylene glycol esters 70
2 olive oil 10
30 Risorex PGIS 22s 10
4 two ten polyglycereol, six caprylates 9.5
5 dextrin cetylates 0.5
Prescription example 10
Composition name use level (quality %)
1 two 2 ethyl hexanoic acid propylene glycol esters 70
2 Jojoba oils 10
3 polyoxyethylene glycerol, three isostearates 15
4 castor oil hydrogenated polyoxyethylene ether 4
5 (mountain Yu acid/eicosane diacid) glyceride 1
Prescription example 11
Composition name use level (quality %)
1 two sad propylene glycol esters 40
22 ethyl hexanoic acid hexadecyl esters 40
30 Risorex PGIS 22s 10
4 two ten polyglycereol, six caprylates 9
5 (mountain Yu acid/eicosane diacid) glyceride 1
Claims (6)
1. oil-based liquid cleansing composition, it is characterized in that, contain carbon number and be diester that 6～10 fatty acid and dihydroxylic alcohols form and HLB value and be 5～15 nonionic surfactant, wherein, carbon number is that diester that 6～10 fatty acid and dihydroxylic alcohols form is from by two 2 ethyl hexanoic acid propylene glycol esters, two 2 ethyl hexanoic acids 1, the 3-butanediol ester, two 2 ethyl hexanoic acid dipropylene glycol esters, two different n-nonanoic acid propylene glycol esters, two different n-nonanoic acids 1, the 3-butanediol ester, select in the group that two different n-nonanoic acid dipropylene glycol esters are formed more than a kind or 2 kinds, wherein, carbon number is that the use level of the diester that forms of 6～10 fatty acid and dihydroxylic alcohols is 5～95 quality %, and the use level of nonionic surfactant is 1～40%.
2. oil-based liquid cleansing composition, it is characterized in that, contain carbon number and be diester that 6～10 fatty acid and dihydroxylic alcohols form and HLB value and be 5～15 nonionic surfactant, wherein, carbon number is that diester that 6～10 fatty acid and dihydroxylic alcohols form is from by two (2 ethyl hexanoic acid/different n-nonanoic acid) propylene glycol ester, two (2 ethyl hexanoic acids/different n-nonanoic acid) 1, the 3-butanediol ester, select in the group that two (2 ethyl hexanoic acid/different n-nonanoic acid) dipropylene glycol ester is formed more than a kind or 2 kinds, wherein, carbon number is that the use level of the diester that forms of 6～10 fatty acid and dihydroxylic alcohols is 5～95 quality %, and the use level of nonionic surfactant is 1～40%.
3. oil-based liquid cleansing composition as claimed in claim 1 or 2 is characterized in that, carbon number is that the use level of the diester that forms of 6～10 fatty acid and dihydroxylic alcohols is 40～95 quality %.
4. oil-based liquid cleansing composition as claimed in claim 1 or 2 is characterized in that, the HLB value of nonionic surfactant is 6～13.
5. oil-based liquid cleansing composition as claimed in claim 1 or 2 is characterized in that, the use level of nonionic surfactant is 5～25%.
6. oil-based liquid cleansing composition as claimed in claim 1 or 2, it is characterized in that, nonionic surfactant be from the group of forming by polyglyceryl fatty acid ester, polyoxyethylene fatty acid glyceride, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sorbitan fatty acid ester, castor oil hydrogenated polyoxyethylene ether, castor oil polyoxyethylene ether, select more than a kind or 2 kinds.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP375490/2005 | 2005-12-27 | ||
| JP2005375490 | 2005-12-27 | ||
| PCT/JP2006/325251 WO2007074675A1 (en) | 2005-12-27 | 2006-12-19 | Oil-based liquid cleansing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101330899A CN101330899A (en) | 2008-12-24 |
| CN101330899B true CN101330899B (en) | 2011-04-20 |
Family
ID=38217894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800475856A Expired - Fee Related CN101330899B (en) | 2005-12-27 | 2006-12-19 | Oil-based liquid cleansing composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5248863B2 (en) |
| CN (1) | CN101330899B (en) |
| HK (1) | HK1119973A1 (en) |
| TW (1) | TWI423824B (en) |
| WO (1) | WO2007074675A1 (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4901464B2 (en) * | 2006-12-28 | 2012-03-21 | 高級アルコール工業株式会社 | Diester and cleansing cosmetic containing the same |
| JP5054418B2 (en) * | 2007-04-23 | 2012-10-24 | ポーラ化成工業株式会社 | Skin external preparation suitable for cosmetics for cleansing |
| JP2008266227A (en) * | 2007-04-23 | 2008-11-06 | Pola Chem Ind Inc | Branched fatty acid ester of polyhydric alcohol |
| JP5550873B2 (en) * | 2008-11-27 | 2014-07-16 | 株式会社ファンケル | Oily liquid cleansing composition. |
| CN101744745B (en) * | 2008-11-27 | 2013-07-17 | 株式会社芳珂 | Composition for oil-based liquid cleansing |
| JP5539657B2 (en) * | 2009-02-24 | 2014-07-02 | 株式会社ダスキン | Transparent detergent for food dishes |
| WO2011052674A1 (en) * | 2009-10-30 | 2011-05-05 | 日清オイリオグループ株式会社 | Composition for cosmetics, cosmetic, method for producing oil-in-water emulsion cosmetic, and two separate layer-type cosmetic |
| CN103694773A (en) * | 2013-12-26 | 2014-04-02 | 青岛中科菲力工程技术研发有限公司 | Cleaning agent for printing damping roller |
| CN104513701A (en) * | 2014-12-09 | 2015-04-15 | 安徽荣达阀门有限公司 | Extreme pressure antiwear and antirust oil |
| JP6684648B2 (en) * | 2016-05-17 | 2020-04-22 | 株式会社ファンケル | Oily cleansing cosmetics |
| JP6234533B1 (en) * | 2016-10-27 | 2017-11-22 | 株式会社ファンケル | Cleansing oil |
| CN111286411B (en) * | 2018-12-10 | 2022-08-26 | 上海家化联合股份有限公司 | Cleaning composition for hard surface cleaning |
| JP6726344B1 (en) * | 2019-08-19 | 2020-07-22 | 株式会社ファンケル | Cleansing fee |
| JP7117719B1 (en) * | 2021-01-29 | 2022-08-15 | 中井紙器工業株式会社 | Non-wiping cleansing sheet, cleansing method, and kit for preparing non-wiping cleansing sheet |
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|---|---|---|---|---|
| US5474776A (en) * | 1992-07-03 | 1995-12-12 | Kao Corporation | Cosmetic composition |
| JP3002793B2 (en) * | 1991-04-04 | 2000-01-24 | 株式会社コーセー | Oil-based cleansing fee |
| JP2001302451A (en) * | 2000-04-24 | 2001-10-31 | Nikko Seiyaku Kk | Low-irritating cleansing cosmetics |
| WO2003026698A1 (en) * | 2001-09-26 | 2003-04-03 | Shiseido Company, Ltd. | External preparation for the skin |
| JP2004256514A (en) * | 2003-02-06 | 2004-09-16 | Nisshin Oillio Ltd | Self-emulsifying type oily liquid cosmetic |
| WO2006003491A1 (en) * | 2004-06-30 | 2006-01-12 | Nokia Corporation | Charging in a communication system |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60115509A (en) * | 1983-11-28 | 1985-06-22 | Sunstar Inc | Transparent gel composition for cleansing skin |
| JP2527970B2 (en) * | 1987-07-13 | 1996-08-28 | 株式会社資生堂 | Liquid cleaning charge |
| GB8928903D0 (en) * | 1989-12-21 | 1990-02-28 | Unilever Plc | Cosmetic composition |
| JPH0616523A (en) * | 1992-07-03 | 1994-01-25 | Kao Corp | Composition for cleansing |
| JPH09175935A (en) * | 1995-12-27 | 1997-07-08 | Kao Corp | Cleansing composition |
| JP2003267836A (en) * | 2002-03-18 | 2003-09-25 | Rohto Pharmaceut Co Ltd | Gel-like cleansing cosmetic |
| JP4824301B2 (en) * | 2004-12-16 | 2011-11-30 | 株式会社コーセー | Liquid oily cosmetics |
| JP4573690B2 (en) * | 2005-04-11 | 2010-11-04 | 日本精化株式会社 | Cosmetic oil or skin external preparation oil, and cosmetic or skin external preparation |
-
2006
- 2006-12-19 CN CN2006800475856A patent/CN101330899B/en not_active Expired - Fee Related
- 2006-12-19 JP JP2007551907A patent/JP5248863B2/en active Active
- 2006-12-19 WO PCT/JP2006/325251 patent/WO2007074675A1/en active Application Filing
- 2006-12-20 TW TW95147955A patent/TWI423824B/en active
-
2009
- 2009-01-14 HK HK09100381.8A patent/HK1119973A1/en unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3002793B2 (en) * | 1991-04-04 | 2000-01-24 | 株式会社コーセー | Oil-based cleansing fee |
| US5474776A (en) * | 1992-07-03 | 1995-12-12 | Kao Corporation | Cosmetic composition |
| JP2001302451A (en) * | 2000-04-24 | 2001-10-31 | Nikko Seiyaku Kk | Low-irritating cleansing cosmetics |
| WO2003026698A1 (en) * | 2001-09-26 | 2003-04-03 | Shiseido Company, Ltd. | External preparation for the skin |
| JP2004256514A (en) * | 2003-02-06 | 2004-09-16 | Nisshin Oillio Ltd | Self-emulsifying type oily liquid cosmetic |
| WO2006003491A1 (en) * | 2004-06-30 | 2006-01-12 | Nokia Corporation | Charging in a communication system |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5248863B2 (en) | 2013-07-31 |
| TWI423824B (en) | 2014-01-21 |
| HK1119973A1 (en) | 2009-03-20 |
| JPWO2007074675A1 (en) | 2009-06-04 |
| WO2007074675A1 (en) | 2007-07-05 |
| CN101330899A (en) | 2008-12-24 |
| TW200803909A (en) | 2008-01-16 |
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