CN101328295A - Fold-resistant polypropylene sheet production formula and making method thereof - Google Patents
Fold-resistant polypropylene sheet production formula and making method thereof Download PDFInfo
- Publication number
- CN101328295A CN101328295A CNA2008101455263A CN200810145526A CN101328295A CN 101328295 A CN101328295 A CN 101328295A CN A2008101455263 A CNA2008101455263 A CN A2008101455263A CN 200810145526 A CN200810145526 A CN 200810145526A CN 101328295 A CN101328295 A CN 101328295A
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- percent
- fold
- resistant polypropylene
- toner
- sheet material
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- 239000004743 Polypropylene Substances 0.000 title claims abstract description 27
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 27
- -1 polypropylene Polymers 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title abstract description 11
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 33
- 239000003112 inhibitor Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 abstract 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 abstract 1
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- 229920006124 polyolefin elastomer Polymers 0.000 description 6
- 238000009472 formulation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a production formula of a folding resistant polypropylene plate and a manufacturing method thereof. The folding resistant polypropylene plate comprises polypropylene (PP), polyolefine elastomer (POE), ethylenebisstearamide (EBS), antioxidant, ultraviolet absorber, dispersant and toner, etc., the formula comprises the following components in weight percent: 30 to 50 percent of PP-SB9430, 15 to 30 percent of PP-K8303, 5 to 15 percent of PP-AY564, 3 to 12 percent of POE, 1 to 2 percent of EBS, 0.05 to 0.2 percent of antioxidant 1010, 0.05 to 0.2 percent of antioxidant 168, 0.05 to 0.1 percent of UV-327, 0.05 to 0.1 percent of UV-770, 0 to 0.3 percent of toner, 0 to 0.2 percent of turpentine and 0.01 to 0.3 percent of white oil. The product manufactured by the formula has the characteristics of folding resistance, corrosion resistance and aging resistance, and the product can be processed into colorful plates as well as colorless transparent plates, and the plates are widely applied to the production of folding type lifeboats, folding beds and folding chairs, etc.
Description
Affiliated technical field
The present invention relates to a kind of fold-resistant polypropylene sheet production formula and preparation method thereof.
Background technology
At present, the polypropylene board of selling on the market all exists the folded defective of not folding, and fold-resistant polypropylene sheet has special purposes, and for this reason, producing a kind of fold-resistant polypropylene sheet has crucial meaning.
Summary of the invention:
The purpose of this invention is to provide a kind of fold-resistant polypropylene sheet production formula and preparation method thereof.
In order to achieve the above object, a kind of fold-resistant polypropylene sheet production formula of the present invention is mainly by polypropylene (PP), polyolefin elastomer (POE), ethylene bis stearic acid amide (EBS), oxidation inhibitor, UV light absorber and dispersion agent and toner etc. are formed, and its prescription forms and weight percent is: PP-SB9430 30%～50%, PP-K8303 15%～30%, PP-AY564 5%～15%, POE3%～12%, EBS 1%～2%, antioxidant 1010 0.05%～0.2%, oxidation inhibitor 168 0.05%～0.2%, UV-327 0.05%～0.1%, UV-770 0.05%～0.1%, toner 0～0.3%, turps 0～0.2%, white oil 0.01%～0.3%.
The specific embodiment of the present invention is:
1, toner is poured in the little basin of stainless steel, in little basin, add turps then, stir with stainless steel bar, treat to add white oil again in little basin after the toner dissolving, this is toner slurry stand-by (producing the water white transparency fold-resistant polypropylene sheet without toner and turps).
2, the PP-SB9430 in the above-mentioned prescription, PP-K8303, PP-AY564, POE and EBS are added in the high-speed mixer, and then add antioxidant 1010 and oxidation inhibitor 168 and UV-327, UV-770 in high-speed mixer, this is that compound is stand-by.
3, pour in the compound after toner slurry is stirred evenly, open high-speed mixer, high-speed mixing was emitted after 30 minutes, material was sent in the loading hopper of sheet material forcing machine then.
4, material is extruded into certain width and certain thickness sheet material through the sheet material forcing machine, and this sheet material is fold-resistant polypropylene sheet.
The invention has the beneficial effects as follows that this sheet material has folded, corrosion-resistant, the ageing-resistant characteristics of folding, sheet material can folding be folded more than 200 times.This fold-resistant polypropylene sheet is applicable to fields (as being used to produce collapsible life boat, folding bed, folding seat or the like) such as military affairs, rescue.
Embodiment 1, (production of blue fold-resistant polypropylene sheet)
(1), blue powder 0.1% (weight percent, below identical) is poured in the little basin of stainless steel, add turps 0.1% then in little basin, stir with stainless steel bar, treat to add white oil 0.1% again after the toner dissolving in little basin, this starches stand-by for toner.
(2), PP-SB9430 50%, PP-K8303 30%, PP-AY564 7.3%, POE 10% and EBS 2% are added in the high-speed mixer, and then in high speed machine, add antioxidant 1010 0.1%, oxidation inhibitor 168 0.1%, and UV-327 0.1%, UV-770 0.1%, this is that compound is stand-by.
(3), pour in the compound after toner slurry stirred evenly, open high-speed mixer, high-speed mixing was emitted after 30 minutes, material was sent in the loading hopper of sheet material forcing machine then.
(4), material is extruded into certain width and certain thickness sheet material through the sheet material forcing machine, this sheet material is blue fold-resistant polypropylene sheet.
Embodiment 2, (production of water white transparency fold-resistant polypropylene sheet)
(1), add in the little basin of stainless steel white oil 0.1% stand-by.
(2), PP-SB9430 46%, PP-K8303 25%, PP-AY564 15%, POE 12% and EBS 1.5% are added in the high-speed mixer, and then in high speed machine, add antioxidant 1010 0.1%, oxidation inhibitor 168 0.1%, and UV-327 0.1%, UV-770 0.1%, this is that compound is stand-by.
(3), white oil is poured in the compound, open high-speed mixer, high-speed mixing was emitted after 30 minutes, material was sent in the loading hopper of sheet material forcing machine then.
(4), material is extruded into certain width and certain thickness sheet material through the sheet material forcing machine, this sheet material is the water white transparency fold-resistant polypropylene sheet.
Embodiment 3, (production of yellow fold-resistant polypropylene sheet)
(1), chrome yellow 0.1%, turps 0.1% added in the little basin of stainless steel, stir with stainless steel bar, treat to add white oil 0.1% again after the toner dissolving in little basin, this starches stand-by for toner.
(2), PP-SB9430 48%, PP-K8303 30%, PP-AY564 10%, POE 10% and EBS 1.3% are added in the high-speed mixer, and then in high speed machine, add antioxidant 1010 0.1%, oxidation inhibitor 168 0.1%, and UV-327 0.1%, UV-770 0.1%, this is that compound is stand-by.
(3), pour in the compound after toner slurry stirred evenly, open high-speed mixer, high-speed mixing was emitted after 30 minutes, material was sent in the loading hopper of sheet material forcing machine then.
(4), material is extruded into certain width and certain thickness sheet material through the sheet material forcing machine, this sheet material is yellow fold-resistant polypropylene sheet.
Claims (3)
1, a kind of fold-resistant polypropylene sheet is characterized in that the prescription composition and the weight percent of this sheet material is: PP-SB9430 30%～50%, PP-K8303 15%～30%, PP-AY564 5%～15%, POE 3%～12%, EBS 1%～2%, antioxidant 1010 0.05%～0.2%, oxidation inhibitor 168 0.05%～0.2%, UV-327 0.05%～0.1%, UV-770 0.05%～0.1%, toner 0～0.3%, turps 0～0.2%, white oil 0.01%～0.3%.
2, the making method of the described a kind of fold-resistant polypropylene sheet of claim 1, earlier PP-SB9430, PP-K8303, PP-AY564, POE, EBS are added in the high-speed mixer when it is characterized in that making, adding toner slurry or white oil then in high-speed mixer (starches without toner when processing water white transparency fold-resistant polypropylene sheet, only use white oil), cover tight high-speed mixer, the material high-speed mixing is emitted and sent into after 30 minutes in the loading hopper of sheet material forcing machine, and material is extruded into certain width and certain thickness sheet material through the sheet material forcing machine.
3, the described a kind of fold-resistant polypropylene sheet of claim 1 can be processed into various color plates, also can be processed into water white transparency sheet material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101455263A CN101328295B (en) | 2008-07-28 | 2008-07-28 | Fold-resistant polypropylene sheet production formula and making method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101455263A CN101328295B (en) | 2008-07-28 | 2008-07-28 | Fold-resistant polypropylene sheet production formula and making method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101328295A true CN101328295A (en) | 2008-12-24 |
| CN101328295B CN101328295B (en) | 2011-04-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101455263A Active CN101328295B (en) | 2008-07-28 | 2008-07-28 | Fold-resistant polypropylene sheet production formula and making method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101328295B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701095B (en) * | 2009-11-24 | 2011-06-15 | 王崇高 | Folding-resisting antibacterial resin |
| CN101767630B (en) * | 2010-01-30 | 2012-07-25 | 王崇高 | Foldable type yacht |
| CN103010400A (en) * | 2013-01-01 | 2013-04-03 | 王崇高 | Portable combined-type yacht |
| CN103819812A (en) * | 2012-11-16 | 2014-05-28 | 江苏金发科技新材料有限公司 | Folding-resistant polypropylene composite material and preparation method for same |
| CN105346671A (en) * | 2015-12-01 | 2016-02-24 | 王崇高 | Folding and rolling type canoeing |
| CN105725561A (en) * | 2016-01-27 | 2016-07-06 | 河南工程学院 | Multifunctional folding chair |
-
2008
- 2008-07-28 CN CN2008101455263A patent/CN101328295B/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701095B (en) * | 2009-11-24 | 2011-06-15 | 王崇高 | Folding-resisting antibacterial resin |
| CN101767630B (en) * | 2010-01-30 | 2012-07-25 | 王崇高 | Foldable type yacht |
| CN103819812A (en) * | 2012-11-16 | 2014-05-28 | 江苏金发科技新材料有限公司 | Folding-resistant polypropylene composite material and preparation method for same |
| CN103010400A (en) * | 2013-01-01 | 2013-04-03 | 王崇高 | Portable combined-type yacht |
| CN105346671A (en) * | 2015-12-01 | 2016-02-24 | 王崇高 | Folding and rolling type canoeing |
| CN105725561A (en) * | 2016-01-27 | 2016-07-06 | 河南工程学院 | Multifunctional folding chair |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101328295B (en) | 2011-04-13 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhou Debiao Inventor before: Wang Chonggao |
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| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161010 Address after: 515100, Guangdong, Shantou province Chaonan Si Si Gang Industrial Zone Patentee after: Shantou Kang Kang Industrial Co.,Ltd. Address before: 200000 room Changning District, Zhongshan West Road, No. 610, room 999, Shanghai Patentee before: Shanghai Airlines Intellectual Property Services Ltd. Effective date of registration: 20161010 Address after: 200000 room Changning District, Zhongshan West Road, No. 610, room 999, Shanghai Patentee after: Shanghai Airlines Intellectual Property Services Ltd. Address before: 225300 Jiangsu Province, Taizhou City Hailing District eight Bridge Street 3 building 503 room Patentee before: Wang Chonggao |
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| CP03 | Change of name, title or address |
Address after: 515000 Xiashan Silian Industrial Zone, Chaonan District, Shantou City, Guangdong Province Patentee after: GUANGDONG KANGBAI WENCHUANG TECHNOLOGY Co.,Ltd. Address before: 515100 Xiashan Silian Industrial Zone, Chaonan District, Shantou City, Guangdong Province Patentee before: Shantou Kang Kang Industrial Co.,Ltd. |
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| CP03 | Change of name, title or address | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a production formula of folding resistant polypropylene plate and a manufacturing method thereof Effective date of registration: 20211215 Granted publication date: 20110413 Pledgee: Shantou SME financing Company limited by guarantee Pledgor: GUANGDONG KANGBAI WENCHUANG TECHNOLOGY Co.,Ltd. Registration number: Y2021980015206 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |