CN101326919A

CN101326919A - Novel surfactants and preparation

Info

Publication number: CN101326919A
Application number: CNA2008101361232A
Authority: CN
Inventors: P·J·勒奴恩; X·陈; G·B·阿翰赛特; J·L·格兰泽尔; J·L·吉列司派; J·A·格拉哈姆; D·Z·拜施尔; D·L·沃利特; H·E·阿格巴耶; X·C·徐; W·阿布拉汉姆; R·J·布林克尔; N·R·帕拉斯; A·S·维德曼; M·D·玛哈尼; S·L·翰克
Original assignee: Monsanto Technology LLC
Current assignee: Monsanto Technology LLC
Priority date: 2000-05-19
Filing date: 2001-05-21
Publication date: 2008-12-24
Also published as: GT200100090A; RU2335899C2

Abstract

A herbicidal composition is provided comprising an aqueous solution of N-phosphonomethylglycine, predominantly in the form of the potassium salt thereof, at a concentration of at least 300 g a.e./l of the composition; and a surfactant component in solution or stable suspension, emulsion, or dispersion in the water, comprising one or more surfactants in a total amount of about 20 to about 300 g/l of the composition, wherein the composition has a viscosity of less than about 250 centipoise at 0 DEG C or a Gardner color value less than 10.

Description

Novel surfactant and preparation

The application is dividing an application of Chinese invention patent application No.01812059.8, and its applying date is May 21 calendar year 2001, and priority date is on May 19th, 2000.

Invention field

The present invention relates to contain the aqueous agricultural-chemical preparation of high concentration herbicide, for example glyphosate potassium and surfactant or other auxiliary agents, be included in above the plant leaf blade or the inner preparation that forms anisotropy aggregation (AA) or liquid crystal (LC).More specifically, the present invention relates to contain the weed killer herbicide of glyphosate, wherein contain the surfactant that one or more form anisotropy aggregation and/or liquid crystal, to promote introducing, absorption and the transposition (translocation) of glyphosate to plant.The method of using this class preparation to kill or control unwanted plant has also been described.The invention still further relates to novel surfactant and the composition pesticide that contains this class surfactant.

Background of invention

Glyphosate is a foliage applying weed killer herbicide behind effective seedling well known in the art.The glyphosate of acid form has the structure by formula (1) representative:

In water insoluble relatively (1.16 weight % under 25 ℃).For this reason, usually it is mixed with water soluble salt.

Monobasic, binary and the ternary salt that can prepare glyphosate.But, generally preferably prepare glyphosate and be applied to plant with the form of monobasic salt.The salt of widely used glyphosate is one (different third ammonium) salt, often is abbreviated as IPA salt.IPA salt with glyphosate comprises as the commodity weed killer herbicide of the Monsanto Corporation of active component

Ultra, Xtra and

Weed killer herbicide.All these is that the aqueous solution concentrates (SL) preparation, generally is diluted in the water by the user before being applied to plant leaf blade.Another kind comprises the trimethyl sulfonium salt at the glyphosate salt of the commercial SL of being mixed with preparation, often is abbreviated as TMS salt, for example is used in Zeneca's (Syngenta)

In the weed killer herbicide.

The various salt of glyphosate, be used to prepare the method for glyphosate salt, the method that the preparation of glyphosate or its salt and glyphosate or its salt are used to kill and control weeds and other plant is disclosed in the U.S. Patent No. 4 of Bakel, 507,250, the U.S. Patent No. 4 of Prisbylla, 481,026, the U.S. Patent No. 4,405,531 of Franz, the U.S. Patent No. 4 of Large, 315,765, the U.S. Patent No. 4,140,513 of Prill, the U.S. Patent No. 3 of Franz, 977,860, the U.S. Patent No. 3,853,530 of Franz and the U.S. Patent No. 3 of Franz, in 799,758.Above-mentioned patent is incorporated herein by reference in full at this.

But document known before the application's priority date never the water soluble salt at the glyphosate of commercial use be sylvite, have structure by formula (2) representative:

Mainly be present in the aqueous solution with ionic species, pH about 4.The molecular weight of glyphosate potassium is 207.In the U.S. Patent No. 4,405,531 of the Franz that this salt was quoted above for example being disclosed in, be one of " alkali metal " salt of the glyphosate of useful as herbicides, potassium is one of concrete disclosed alkali metal, and other also have lithium, sodium, caesium and rubidium.Embodiment C discloses the preparation of a sylvite, and the glyphosate of specified amount and potash are reacted in aqueous medium.

Weed killer herbicide is seldom with the potassium salt form commercialization.Pesticide Manual (agricultural chemicals handbook) the 11st edition 1997 enumerates the auxin type weed killer herbicide 2 of potassium salt form, 4-DB ((2, the 4-dichlorophenoxy) dicamba (3 butyric acid),, 6-two chloro-O-Anisic Acids), 2,4-drips propionic acid, and (2-(2, the 4-dichlorophenoxy) propionic acid), MCPA ((4-chloro-2-methylphenoxy) acetate) and picloram (4-amino-3,5,6-three chloro-2-Pyridinecarboxylic Acids), some weed killer herbicide product activity composition is sold by Dow Agrosciences, and trade mark is Tordon.

The solvability of glyphosate potassium in water is recorded in the pending application Serial No.09/444 that submitted on November 22nd, 1999, in 766, its in full content be incorporated herein by reference.As wherein disclosed, at the about 54 weight % of the solvability of 20 ℃ of following glyphosate potassiums in pure water, just about 44 weight % glyphosate equivalents (a.e.).This is very similar to the solvability of IPA salt.This paper concentration as expressed in weight percent relates to the salt in per 100 parts by weight solution or the parts by weight of acid equivalent.Therefore, compare, for example can obtain from Monsanto Corporation with commercial available glyphosate IPA salt D-Pak ^TMAqueous solution concentrate, the concentration of the simple aqueous concentrate of glyphosate potassium reach for example 44 weight %a.e. easily.Slightly excessively neutralizing with potassium hydroxide,---for example 5 to 10%---aqueous solution of glyphosate potassium can obtain higher concentration.

The major advantage that the IPA salt of glyphosate is better than a lot of other salt be in the aqueous solution concentrate formulation of this salt with the excellent compatibility of wide surface activating agent.Term used herein " surfactant " plan comprises auxiliary agent widely, they can join in the weeding glyphosate composition, with do not have this analog assistant in the presence of the activity of glyphosate salt compare, strengthen its weeding effect, with stability, the property prepared or other useful dissolution properties, the traditional definition that whether satisfies " surfactant " with this analog assistant is irrelevant.

Glyphosate salt generally needs the existence of suitable surfactant, to reach best herbicidal performance.Surfactant can be provided in concentrate formulation, perhaps can join in the spray composite of dilution by the terminal use.The selection of surfactant has material impact to herbicidal performance.For example, at " weeds science " (Weed Science), in the broad research of reporting in 1977, the 25 volume 275-287 pages or leaves, there are extensive difference in Wyrill and Burnside table of discovery surface-active agent on the ability of the weeding effect that strengthens the glyphosate of using with the IPA salt form.

Except general general character, the relative ability that the different surfaces activating agent strengthens the Gyphosate herbicice effect is very unpredictable.

The surfactant that is tending towards strengthening the Gyphosate herbicice effect generally is but is not only cationic surfactant, be included in the aqueous solution or the disperse system and generate cationic surfactant, the pH level about 4-5 is that the SL preparation of monobasic salt of glyphosate is peculiar.Example is long-chain (common C ₁₂To C ₁₈) the alkyl amine surfactant and season the alkylammonium surfactant.Especially generally the alkyl amine surfactant that is used in the aqueous solution concentrate formulation of glyphosate IPA salt is very hydrophilic surfactant polyoxyethylene (a 15) beef tallow amine, just in the oxygen ethylene chain of two polymerizations that are connected with amido, have the beef tallow amine that amounts to about 15 mole oxygen alkylidenes, as the formula (3):

Wherein R is mainly C from what butter were derived ₁₆With C ₁₈The mixture of alkyl and alkenylene chain, m+n sum are about 15 mean.

Use about some, have been found that and need use the alkylamine surfactant of slightly water-wet slightly, for example have and be less than about 10 moles of ethylene oxide persons, in U.S. Patent No. 5,668,085 is proposed, for example polyoxyethylene (2) coco amine as Forbes etc.This patent disclosure illustrative waterborne compositions, comprise IPA, ammonium or the sylvite of a kind of like this surfactant and glyphosate.Shown in the patent table 3 of ' 085 in the sylvite preparation maximum concentration of glyphosate be 300g glyphosate a.e./l, the weight ratio of glyphosate a.e. and surfactant is 2: 1.

WO 00/59302 discloses the alkoxylated alkylamines that a class is used for the weeding spray composite.Wherein describe glyphosate potassium solution, comprised various Jeffamine ^TMEO/PO propylamine or propane diamine.

Disclosing widely, quaternary surfactant is the component of the aqueous solution concentrate formulation of glyphosate IPA salt.Illustrative example is to be disclosed in chlorination N-methyl polyoxyethylene (2) cocounut oil ammonium among the European patent No.0274369, to be disclosed in U.S. Patent No. 5,317, chlorination N-methyl in 003 gathers oxireme (15) cocounut oil ammonium and is disclosed in U.S. Patent No. 5,464, various quaternary ammonium compounds in 807 have formula (4):

(R ¹)(R ²)(R ³)N ⁺-CH ₂CH ₂O-(CH ₂CH(CH ₃)O) _nHCl ^- (4)

R wherein ¹, R ²And R ³Each is C naturally _1-3Alkyl, n are from 2 to 20 mean.

PCT communique No.WO 97/16969 discloses the aqueous solution concentrate composition of the glyphosate of IPA, first ammonium and di-ammonium salts form, comprises the hydrochlorate of quaternary surfactant and primary, the second month in a season or alkyl amine compound.

Other cationic surfactants that can be used for the aqueous solution concentrate composition of glyphosate salt by discriminating comprise and are disclosed among the PCT communique No.WO 95/33379 those.In PCT communique No.WO/97/32476, further disclose the highly enriched waterborne compositions that utilizes these identical cationic surfactants can prepare glyphosate salt, further added defined component, the stability of enhancing composition.The glyphosate salt that wherein exemplifies is IPA salt and one and di-ammonium salts.

It is reported it is that the both sexes or the zwitterionic surfactant of useful constituent of aqueous solution concentrate formulation of glyphosate IPA salt is to be disclosed in U.S. Patent No. 5,118, the alkyl amine oxide in 444, for example polyoxyethylene (10-20) beef tallow amine oxide

When as the single surface active agent composition of glyphosate IPA salt SL preparation, non-ionic surface active agent it is reported strengthen on the activity of weeding general not as cation or amphoteric surfactant effective; As if exception comprise some alkyl polyglycoside that for example is disclosed among the Australian Patent No.627503 and polyoxyethylene (10-100) C that is disclosed among the PCT communique No.WO 98/17109 _16-22Alkyl ether.Anion surfactant is except as U.S. Patent No. 5,389,598 and U.S. Patent No. 5,703,015 disclosed with the cationic surfactant associating beyond, generally be unprofitable to glyphosate IPA salt SL preparation.' 015 patent disclosure dialkoxy alkylamine and anion eye stimulate the surfactant mixture that reduces the property compound.This surfactant mixture is suitable for preparing the aqueous solution concentrate formulation of various glyphosate salts, comprises sylvite in the salt of being mentioned.The concentrate of ' 015 patent contains has an appointment 5 to about 50%, preferred about 35 to about 45% glyphosate a.i. and about 5 to about 25% surfactant.And then PCT communique No.WO00/08927 discloses to unite in containing the preparation of glyphosate and has used some polyalkoxylated phosphate and some polyalkoxylated amidoamines.Potassium is one of some glyphosate salts of " being fit to ".

Recently, U.S. Patent No. 5,750,468 disclose the aqueous solution concentrate formulation that a class alkyl ether amine, alkyl ether ammonium salt and alkyl ether amine oxide surface activating agent are suitable for preparing various glyphosate salts, comprise sylvite in the salt of being mentioned.Wherein disclosing the advantage of this surfactant when being used in the waterborne compositions with glyphosate salt is that these surfactants allow the glyphosate concentration of composition to be increased to very high level.

Relative difficulty when glyphosate potassium is mixed with highly enriched SL product with the surfactant of preferred type may suppress this salt thinking better of as herbicidal active component.For example, in glyphosate IPA salt composite widely used surfactant, just polyoxyethylene (15) beef tallow amine of following formula (3) is very inconsistent with glyphosate potassium in the aqueous solution.And then PCT communique No.WO 00/15037 mentions the low compatibility of the general and high concentration glyphosate concentrate of alkoxylated alkylamines surfactant.As wherein disclosed,, need the associating of alkyl polyglycoside surfactant and alkoxylated alkylamines surfactant, to obtain containing the high concentration concentrate of glyphosate potassium for the level of significance of " foundation " surfactant.

The adding of this class alkyl polyglycoside causes the viscosity of preparation higher (comparing with the preparation that does not have alkyl polyglycoside).The viscosity increase of these high concentrate formulations is undesirable for various reasons.Except being difficult to easily in container, to pour out or therefrom to wash out residue more, about pumping the richer illeffects that causes by high viscosity formulation of observing dramatically of requirement.The volume of the liquid waterborne glyphosate products of being bought by the terminal use increases, and is contained in the large-scale refillable container, is known as shuttle (shuttle) sometimes, has intrinsic pump or outer pump communicating pipe usually, so that transfer liquid.The liquid waterborne glyphosate products also is transportation in enormous quantities, and the volume of large tank can reach about 100,000 liters.Liquid generally shifts being pumped in the hold-up tank by whole seller, retailer or partner's apparatus operating, therefrom can further be transferred to shuttle or littler container, is used for distributing forward.Because a large amount of glyphosate formulations were bought and transportation in early spring, the temperature pumping feature of this class preparation is very important.

When add this class alkyl polyglycoside (Agrimul for example to the glyphosate concentrate ^TMAPG-2067 and 2-ethylhexyl glucosides) time, the product of being prepared is dark brown.The glyphosate products of being prepared is need be on color more shallow than the disclosed product that contains alkyl polyglycoside of WO 00/15037, and it is 14 to 18 that the latter measures colour with the Gardner colorimeter.When prepared when the Gardner colour adds dyestuff greater than about 10 glyphosate products, concentrate still is dark brown.The Gardner colour is that 10 concentrate is difficult to dye blueness or green, this be because often need to distinguish glyphosate products with other except that grass product.

The water-based concentrate composition (being preparation) of the stable storage of glyphosate potassium or other glyphosate salts except that glyphosate IPA need be provided, have the surfactant component of agriculturally useful, perhaps it " fully loads " surfactant.These preparations show viscosity and reduce, and pump so that they can be under 0 ℃ pump the equipment from standard, and speed is at least 7.5 gallons of per minutes, and per minute surpasses 10 gallons usually, and preferred per minute is greater than 12.5 gallons." surfactant component of agriculturally useful " expression contains like this one or more surfactants of one or more types, content make the user recognize said composition with herbicidal effect that the analogous composition that does not contain surfactant is compared on have usefulness.The suitable surfactant concentrations of " fully loading " expression is enough to provide at the dilute with water of routine and after being applied to blade the herbicidal effect to one or more important weeds, and the composition that need not after dilution adds other surfactants.

" stable storage " is illustrated on the water-based concentrate composition meaning of the glyphosate salt that further contains surfactant that not showing under about at the most 50 ℃ temperature is separated reaches 14-28 days, the crystal that does not preferably generate glyphosate or its salt under about 0 ℃ temperature was up to about 7 days (that is to say that the crystalline temperature of composition must be 0 ℃ or lower).About aqueous solution concentrate, high-temperature storage stability through be often expressed as cloud point about 50 ℃ or more than.The cloud point of composition is normally measured like this, and heating combination until the solution becomes muddiness, under agitation makes the mixture cooling, its temperature of continuous monitoring simultaneously then.The temperature that is read when solution is clarified is measuring of cloud point.For most of commercial objects of glyphosate SL preparation, 50 ℃ or above cloud point are regarded as acceptable usually.Ideally, cloud point should be 60 ℃ or more than, even in the presence of the glyphosate salt crystal seed, composition also should stand be low to moderate approximately-10 ℃ temperature up to about 7 days, and do not have crystal to separate out.

This paper is described as can providing with the surfactant of glyphosate salt " compatible " under the surfactant of appointment and glyphosate a.e. concentration as defined bin stability water-based concentrate person just now, wherein contains this surfactant and the salt of prescribed concentration.

The user of liquid herbicidal product is usually by volume but not weight is come dosing, such product indicates the guidance about the usage ratio that is fit to usually, volume with per unit area is represented, for example rises every acre of per hectare (l/ha) or fluid ounce (oz/acre).Therefore, with the concentration of subscriber-related herbicidal active component be not percentage by weight, but the weight of per unit volume for example restrains every liter (g/l) or pound per gallon (lb/gal).Under the situation of glyphosate salt, concentration is often with every liter of (g a.e./l) expression of acid equivalent gram number.

In history, the most general glyphosate IPA product salt that contains surfactant of preparation Monsanto Corporation for example

With

The Ultra weed killer herbicide, the about 360g a.e./l of the concentration of glyphosate.Contain the glyphosate TMS product salt Zeneca's of surfactant

The about 330g a.e./l of glyphosate concentration.A.e. lower, the just rarer product of concentration also has sale, but their glyphosates of being contained of per unit spend more cost, mainly are reflected as packing, transportation and inventory cost.

It is possible saving cost and user friendly further benefit, if the water-based concentrate composition of " fully load " can be provided or have the surface-active contents person of agriculturally useful at least, the concentration of glyphosate is at least about 320g a.e./l, 340g a.e./l, or significantly above 360g a.e./l, for example at least about 420g a.e./l or more than, at least 440,450,460,470,480,490,500,510,520,530,540,550 or 600g a.e./l or more than.

Under very high glyphosate a.e. concentration, for example above-mentioned, significant problem takes place usually.Here it is by the high viscosity of concentrate cause in the difficulty of pouring out and/or pumping on the water-based concentrate, performance is especially obvious at low temperatures.Therefore will be starved of the highly enriched aqueous solution with glyphosate potassium, fully be loaded with the surfactant of agriculturally useful, the viscosity of this class preparation is preferably less than the glyphosate potassium salt pref that contains the alkyl polyglycoside surfactant, for example is disclosed among the PCT communique No.WO 00/15037 those.

Still need can with pesticidal preparations, the compatible surfactant of for example water-based Gyphosate herbicice concentrate.Surfactant of the present invention comprises novel surfactant and former known surface activating agent in pesticidal preparations of no use.The surfactant compatible especially with glyphosate potassium or other glyphosate salts except that glyphosate IPA has been determined and can be used for preparing concentrate, compares with known glyphosate concentrate and improved viscosity, bin stability and load.

See from hereinafter openly knowing, the invention provides these and other benefits.

Summary of the invention

The invention provides novel surfactant, be used to prepare composition pesticide, for example contain the aqueous herbicidal concentrate of glyphosate or its salt or ester.The surfactant that also has been found that some agricultural use the unknown in the past strengthens the weeding effect, and is simultaneously still compatible with glyphosate after long term storage.

One embodiment of the present invention relate to the aqueous herbicidal concentrate composition, wherein comprise glyphosate, mainly be the solution of its sylvite, content surpasses every liter of composition of 300 gram acid equivalents, solution or stable suspension, emulsion or dispersion with surface active agent composition, comprise one or more surfactants, total amount about 20 is to every liter of composition of about 300 grams.Said composition (a) is under 0 ℃ and 45/s shearing rate, viscosity is less than about 250 centipoises, (b) when not containing dyestuff or colouring agent, the Gardner colour is not more than 14, (c) viscosity is less than the glyphosate potassium salt composite of similar loading, wherein comprise the combination of alkyl polyglycoside surfactant and alkoxylated alkylamines surfactant, the weight ratio of described alkyl polyglycoside and alkylamine surfactant is between about 5: 1 and 1: 1, (d) compare with a kind of like this glyphosate potassium salt composite of similar loading, the growth of control piemarker, (e) contain a kind of like this surface active agent composition, it does not comprise the alkyl polyglycoside of effective dose, and be to select like this, when when storing 14 to 28 days down for 50 ℃, make composition keep even basically, perhaps (f) comprises a kind of like this surface active agent composition, it contains effective dose alkyl polyglycoside and the combination of another surfactant at least, does not contain the alkoxylated alkylamines of effective dose.

Another embodiment of the invention relates to a kind of like this glyphosate concentrate, and the viscosity under 0 ℃ and 45/s shearing rate is less than about 250 centipoises, and wherein this surface active agent composition comprises one or more amine or quarternary ammonium salt compound.Every kind of compound in compound, comprise have about 4 to the alkyl or aryl substituting group of about 16 carbon atoms be no more than 10 oxygen ethene and be connected base.The content of compound is enough to strengthen the compatibility of surfactant and glyphosate salt.

The invention still further relates to such preparation, after using said preparation, it forms the anisotropy aggregation of being made up of surfactant outside plant leaf blade wax shape cuticula.Other herbicidal formulations of the present invention are being used the back liquid crystal that formation is made up of surfactant outside plant leaf blade wax shape cuticula.Other herbicidal formulations of the present invention are being used the back liquid crystal that formation is made up of surfactant outside inside plants and blade wax shape cuticula.Whether have been found that existence that the outer formation with the interior liquid crystal of cuticula of anisotropy aggregation and cuticula do not rely on the second surface activating agent, and significantly strengthen the performance of herbicidal formulations of the present invention.

Brief description of drawings

Figure A1 and A2 show that (A1 is the polarised light of 100x magnifying power for the birefringence pattern of negative sector element; A2 is the polarised light of 200x magnifying power), they are that hexagonal phase liquid crystal is peculiar.The preparation that produces the outer liquid crystal of these cuticula is made up of glyphosate potassium and surfactant mixture.Particularly, preparation is that 3: 1 glyphosate and surfactant formed by weight ratio, and the former is a glyphosate potassium, and the latter is Tomah 1816 E20PA and Witcamine 405 surfactant mixtures.

Figure B1 and B2 show that (B1 is the polarised light of 100x magnifying power for the birefringence pattern of fine fluid mosaic model; B2 is the polarised light of 200x magnifying power), they are that sheet phase liquid crystal is peculiar.The preparation that produces the outer liquid crystal of these cuticula is made up of isopropylamine glyphosate and surfactant.Particularly, preparation is that 3: 1 glyphosate and surfactant formed by weight ratio, and the former is the isopropylamine glyphosate, and the latter is a Plurafac A38 surfactant.

Detailed description of the invention

Composition pesticide of the present invention comprises the aqueous herbicidal composition of one or more surfactants of the sylvite of glyphosate or another kind glyphosate salt except glyphosate IPA and weeding effect enhancing amount. Composition of the present invention is stable storage under temperature widely. Composition of the present invention is compared with the glyphosate potassium salt composite of the combination of alkoxylated alkylamines surfactant with containing many glycosides of alkyl surfactant, the also viscosity characteristics of performance improvement and significantly more shallow color. By selecting a kind of like this surfactant system to make the preparation of this class " viscosity of improvement " and " color of improvement " become possibility, this system does not comprise many glycosides of alkyl surfactant, still making this class preparation is fully to load, after the water dilution, before using, do not need other surfactant for reaching the business level performance. Also have been found that, the combination of many glycosides of alkyl surfactant and the surfactant except alkoxyalkyl amine surfactant can be used in and provides the glyphosate potassium of usefulness salt composite, although lose the viscosity characteristics of the improvement of some preferred compositions of the present invention that do not contain many glycosides of alkyl surfactant. And then by the content of the control many glycosides of alkyl in the glyphosate potassium salt composite, the alkoxylated alkylamines of capacity or other surfactants described herein can be used in the preparation that preparation is fit to. Generally speaking, the ratio of the many glycosides of alkyl and other surfactants should be between about 1: 5 and 5: 1, preferably between about 1: 5 and 1: 1.1, more preferably between about 1: 5 and 1: 1.2, most preferably between about 1: 5 and 1: 1.5. The color of this class concentrate is quite shallow compared with the concentrate that contains the many glycosides of greater amount alkyl, and colour is less than 14, preferably less than about 13,12,11,10,9,8,7,6 or 5.

But herbicidal formulations of the present invention can selection of land contain one or more other surfactants, one or more other herbicides and/or other auxiliary agents or composition, for example dicarboxylic acids, for example oxalic acid or its salt or ester. Preparation of the present invention can not long ago be prepared by the end user on the spot being applied to the plant that will eliminate or the blade of weeds, and dilution water-based concentrate herbicidal formulations or dissolving or dispersion contain the solid particle of glyphosate. Select as an alternative, herbicidal formulations of the present invention can offer on the basis of " namely using " final consumer.

The present invention adopts the concentrated aqueous solution of hyperbaric glyphosate potassium. Therefore, under given weight percent concentration, the water-based concentrate composition of glyphosate potassium comes to provide the significantly active component of higher weight of per unit volume composition for the user compared with corresponding glyphosate IPA salt composite.

In one embodiment of the invention, have been found that in the water-based concentrate formulation, in the presence of the surfactant component of agriculturally useful, can obtain the glyphosate potassium of unexpected high concentration, resulting composition performance viscosity and stable storage feature acceptable or that performance improves in some situation. The selection of surfactant has been found that realizing that these results are very important.

Therefore in such embodiment, the invention provides the aqueous herbicidal composition, comprise:

(1) the N-phosphonomethylglycine, be mainly the solution of form in water of its sylvite, content surpasses every liter of composition of 360 gram N-phosphonomethylglycine equivalents; With

(2) solution or the stabilising dispersions of surface active agent composition in water comprises one or more surfactants of agriculturally useful amount.Preferably this surface active agent composition is chosen such that and makes the viscosity of composition under 10 ℃ be not more than about 1000 centipoises, and cloud point is not less than about 50 ℃, when performance when storing up to about 7 days under about 0 ℃ temperature does not have the crystallization of glyphosate or its salt basically.More preferably, composition was at 45 seconds ^-1Be not more than about 500 centipoises with the viscosity under 10 ℃, it is most preferred being not more than 250,225,200,175,150,125 or 100 centipoises.But, higher viscosity also is acceptable in some cases, and for example the consideration about temperature pumping is not important.The surface active agent composition that hydrotropism's weeding concentrate composition adds is solution or stable suspension, emulsion or dispersion.

Word above " mainly " means at least about 50%, preferably at least about 75%, more preferably at least about the glyphosate of 90% weight, represent to exist with potassium salt form with a.e..Surplus can be other salt and/or glyphosate, but preferably viscosity, cloud point and the noncrystalline character of composition still shown in the limit.

As further aspect of the present invention, determined the specific surfactant of a class, wherein with greater than 300g a.e./l to the tolerability of the glyphosate potassium salinity of about 600g a.e./l be that accident is high.Therefore, embodiments of the present invention are aforesaid Herbicidal combinations that contain surfactant, and wherein this surface active agent composition mainly comprises one or more surfactants, have a kind of like this molecular structure separately, comprise:

(1) hydrophobic parts comprises the alkyl of at least one alkyl or replacement; With

(2) hydrophilic parts comprises (i) amino, ammonium or amine oxide group, comprises the hydrocarbyl substituent of alkyl or replacement; And/or (ii) carbohydrate group.

The carbohydrate of hydrophilic parts is preferably sugar, for example monose, disaccharides or polysaccharide.Preferred steamed bun stuffed with sugar is drawn together glycosides, for example alkylglycoside, alkyl polyglycoside and aminoglycoside.It is preferred containing the surfactant that average each surfactant molecule is no more than about two carbohydrate group.

In such surfactant, hydrophobic parts is connected with hydrophilic parts one of in the following manner.The terminal atom of hydrophobic parts is to connect like this, (a) is directly connected in the nitrogen in amino, ammonium or the amine oxide group, and if any, perhaps (b) is directly connected in carbohydrate group, if any.

In preferred embodiment, the hydrophobic parts of surfactant is the alkyl that comprises the replacement of at least one oxyalkylene in main chain.The alkyl that this class replaces for example comprises alkyl oxyalkylene and thiazolinyl oxyalkylene, contains one to 30 oxyalkylene RO, and wherein R is C in each RO group independently ₂-C ₄Alkylidene.

In one embodiment of the invention, surface active agent composition mainly comprises one or more surfactants that has certain molecular structure separately, and this molecular structure comprises:

(1) hydrophobic parts has that one or more independences are saturated or undersaturated, branch or unbranched, aliphatic, an alicyclic or aromatics C _3-18Alkyl or alkylene link together to about 7 keys by 0, and these keys are independently selected from ether, thioether, sulfoxide, ester, thioester and amido link, and this hydrophobic parts has the carbon atom that adds up to J, and wherein J is about 8 to about 30; With

(2) hydrophilic parts comprises:

(i) amino, it is cationic or can be by protonated and become cationic, have direct-connected with it 0 to 3 oxyethylene group or polyoxyethylene chain, these oxyethylene groups and polyoxyethylene chain comprise average each surfactant molecule and are no more than the oxygen ethylene unit that quantity is E, make E+J≤50; And/or

(ii) alkyl sugar derivatives unit, for example glycosides, many glycosides or aminoglycoside group comprise average each surfactant molecule and are no more than 2 alkyl sugar derivatives unit.

In such surfactant, hydrophobic parts is connected with hydrophilic parts one of in the following manner: (a) be directly connected in amino, if any, (b) ehter bond of the oxygen atom of the terminal oxygen ethylene unit of one of the oxygen atom by being combined with one of oxyethylene group or polyoxyethylene chain, if any, or (c) be connected in one of alkyl sugar derivatives unit by ehter bond, if any.

In preferred embodiment, J is about 8 to about 25, and E+J is no more than 45, preferably is no more than 40, more preferably no more than 28.For example, the compound JJJ in the table 4 comprises having the hydrophobic parts that adds up to 24 carbon and comprise the hydrophilic parts of 9 oxygen ethylene unit altogether, makes E+J=33.Compound C comprises 18 carbon atoms (J) and 7 oxygen ethylene unit (E) altogether in its hydrophobic parts, makes E+J=25.

In one embodiment of the invention, surface active agent composition mainly comprises one or more surfactants, has a kind of like this molecular structure separately, comprises:

(1) hydrophobic parts has that one or more independences are saturated or undersaturated, branch or unbranched, aliphatic, an alicyclic or aromatics C _3-18Alkyl or alkylene link together to about 7 keys by 0, and these keys are independently selected from ether, thioether, sulfoxide, ester, thioester and amido link, and this hydrophobic parts has the carbon atom that adds up to J, and wherein J is about 8 to about 18; With

(2) hydrophilic parts comprises:

(i) amino, it is cationic or can be by protonated and become cationic, have direct-connected with it 0 to 3 oxyethylene group group or polyoxyethylene chain, these oxyethylene group groups and polyoxyethylene chain comprise average each surfactant molecule and are no more than the oxygen ethylene unit that quantity is E, make E+J≤22; And/or

(ii) alkyl sugar derivatives unit, for example glycosides, many glycosides or aminoglycoside group comprise average each surfactant molecule and are no more than about 2 alkyl sugar derivatives unit.

In such surfactant, hydrophobic parts is connected with hydrophilic parts one of in the following manner: (a) be directly connected in amino, if any, (b) by ehter bond in conjunction with the oxygen atom of the terminal oxygen ethylene unit of one of one of oxyethylene group group or polyoxyethylene chain, if any, or (c) be connected in one of alkyl sugar derivatives unit by ehter bond, if any.

On the meaning of surfactant component, expression way " mainly comprise " mean at least about 50%, preferably at least about 75%, more preferably specify the surfactant of molecular characterization to form by having at least about the surface active agent composition of 90% weight.For this reason, the weight of surface active agent composition defined herein or concentration do not comprise the compound that is essentially non-surface-active agent, they are introduced with surface active agent composition sometimes, for example water, isopropyl alcohol or other solvents, or glycol (for example ethylene glycol, propane diols, polyethylene glycol etc.).

Under the prerequisite that never limits the scope of the invention, be particularly useful for composition of the present invention as shown in the formula (5) and (6) defined various surfactant groups.

One embodiment of the present invention are aforesaid weeding concentrate compositions, and wherein this surface active agent composition mainly comprises one or more chemically stabilized surfactant, have formula (5):

[R ¹-(XR ²) _m-(NR ³) _n-(R ⁸O) _p-(R ⁴) _q-(NR ⁵R ⁶-(CH ₂) _r) _s-(NR ⁷) _t(sug) _uOH] _v[A] _w (5)

R wherein ¹Be hydrogen or C _1-18Alkyl, each X are ether, thioether, sulfoxide, ester, thioester or amido link independently, each R ²Be C independently _2-6Alkylene, m are 0 to about 8 mean, R ¹-(XR ²) _mIn the sum of carbon atom be about 8 to about 24, n is 0 or 1, p is 0 to about 5 mean, R ³, R ⁴, R ⁵, R ⁶And R ⁷Be hydrogen or C independently _1-4Alkyl, R ⁸Be C independently ₂-C ₄Alkylidene, q are 0 or 1, and r is 0 to 4, s is 0 or 1, t is 0 or 1, and sug is open chain or the circulus that (i) derives from sugar, for example glucose or sucrose (this paper is referred to as sugar unit), or (ii) hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl, u is from 1 to about 2 mean, and A is the anion entity, and v is from 1 to 3 integer, w is 0 or 1, so that keep electroneutral.Preferred formula 5 type compound examples are aminoglucoses, wherein R ¹Be C ₈H ₁₇Alkyl, m, p, q, s, t and w are 0, n, u and v are 1, R ³Be hydrogen, sug is the open chain glucosan derivative, has structure C H (OH) CH (OH) CH (OH) CH (OH) CH ₂

Another embodiment of the invention is aforesaid weeding concentrate composition, and wherein this surface active agent composition mainly comprises one or more surfactants with formula (6):

R wherein ¹Be hydrogen or C _1-18Alkyl, each X are ether, thioether, sulfoxide, ester, thioester or amido link independently, each R ²Be C independently _2-6Alkylene, each R ⁸Be C independently ₂-C ₄Alkylidene, m are 0 to about 9 mean, R ¹-(XR ²) _mIn the total J of carbon atom be about 8 to about 18, n is 0 to about 5 mean, R ⁵Be hydrogen, C _1-4Alkyl, benzyl, anion oxidation thing group or anionic group-(CH ₂) _uC (O) O, wherein u is 1 to 3, R ⁶And R ⁷Be hydrogen, C independently _1-4Alkyl or C _2-4Acyl group, x and y are such mean, make x+y+n be not more than E number as defined above, and A is an anionicsite, and s is from 1 to 3 integer, and t is 0 or 1, so that keep electroneutral.

With what figure out is that the surfactant that meets following formula (5) or (6) comprises without limitation and can be described to following those: alkyl polyglycoside, the alkyl amino glycosides, the polyoxyalkylene alkylamine, polyoxyalkylene alkyl amine, alkyltrimethylammonium salt, alkyl dimethyl benzyl ammonium salt, polyoxyalkylene N-methyl alkyl ammonium salt, polyoxyalkylene N-methyl alkyl ether ammonium salt, the alkyl-dimethyl amine oxide, the polyoxyalkylene alkyl amine oxide, the polyoxyalkylene alkyl amine oxide, the alkyl betaine, alkyl amido propylamine etc.In one embodiment of the invention,---mean if any---is not more than 22-J for the alkylidene oxide unit of each surfactant molecule, for example ethylene oxide unit, wherein J is as defined above, and---mean if any---is not more than about 2 to the glucose unit of each surfactant molecule.In another embodiment of the invention,---mean if any---is not more than 50-J for the alkylidene oxide unit of each surfactant molecule, for example ethylene oxide unit, wherein J is as defined above, and---mean if any---is not more than about 42 to the glucose unit of each surfactant molecule.

Have been found that the illustrative surfactant types that can be used for the present composition comprises as follows:

(A) be equivalent to the surfactant of formula (5), wherein R ¹Be C _8-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, m, n, p, s, t and w are 0, v is 1.This group comprises some commodity list surface-active agents well known in the art or is referred to herein as " APG " or " APG ".The example that is fit to is the Agrimul that is sold by Henkel ^TMPG-2069 and Agrimul ^TMPG-2076.

(B) be equivalent to the surfactant of formula (6), wherein R ¹Be C _8-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, m is 0.In this group, R ¹Constitute separately the hydrophobic parts of surfactant, directly be connected with amino-functional, alkylamine for example perhaps passes through the ehter bond connection that the terminal oxygen atom by the oxygen atom of alkylidene oxide or polyoxyalkylene chain forms, for example some alkyl ether amine.Having the different hydrophilic group comprises:

(1) such surfactant, wherein x and y are 0, R ⁵And R ⁶Be C independently _1-4Alkyl, R ⁷Be hydrogen, t is 1.This group comprises (R wherein ⁵And R ⁶Each methyl naturally) some commodity list surface-active agents known in the art or be referred to herein as " alkyl dimethylamine ".The example that is fit to is a domiphen, for example the Armeen that can obtain from Akzo ^TMDM12D, cocounut oil dimethylamine and butter dimethylamine, the Noram that for example can obtain from Ceca respectively ^TMDMC D and Noram ^TMDMS D.This class surfactant generally provides with non-protonization form, and anion A does not supply with surfactant.But, in the glyphosate potassium salt pref of the about 4-5 of pH, surfactant will be by protonated, and anion A can be a glyphosate, and it can generate binary salt.

(2) such surfactant, wherein x and y are 0, R ⁵, R ⁶And R ⁷Be C independently _1-4Alkyl, t are 1.This group comprises (R wherein ⁵, R ⁶And R ⁷Each methyl naturally, A is a chlorion) some commodity list surface-active agents known in the art or be referred to herein as " alkyl chlorination trimethylammonium ".The example that is fit to is a cocounut oil alkyl chlorination trimethylammonium, for example the Arquad that can obtain from Akzo ^TMC.

(3) such surfactant, wherein x+y is 2 or bigger, R ⁶And R ⁷Be hydrogen, t is 1.This group comprises some commodity list surface-active agents known in the art or is referred to herein as " polyoxyalkylene alkylamine " that (wherein n is 0, R ⁵Be hydrogen), some " polyoxyalkylene alkyl amine " (wherein n is 1-5, R ⁵Be hydrogen), " polyoxyalkylene methyl alkyl ammonium chloride " (wherein n is 0, R ⁵Be methyl) and some " polyoxyalkylene methyl alkyl ether ammonium chloride " (wherein n is 1-5, R ⁵Be methyl).The example that is fit to is polyoxyethylene (2) coco amine, polyoxyethylene (5) beef tallow amine and polyoxyethylene (10) coco amine, respectively the Ethomeen that for example can obtain from Akzo ^TMC/12, Ethomeen ^TMT/15 and Ethomeen ^TMC/20; The surfactant of constitutional formula (7), this moment, its amido right and wrong were protonated:

R wherein ¹Be C _12-15Alkyl, X are ethyl, propyl group or first and second bases, and x+y is 5, for example are disclosed in U.S. Patent No. 5,750, in 468; The stearic ammonium of polyoxyethylene (2) N-methyl chlorination cocounut oil ammonium and the chlorination of polyoxyethylene (2) N-methyl, the Ethoquad that for example can obtain from Akzo respectively ^TMC/12 and Ethoquad ^TM18/12.R therein ⁵Be under the situation of hydrogen, just with the diametrically opposite tertiary amine surfactant of quaternary ammonium, anion A does not supply with surfactant usually.But, in the glyphosate potassium salt pref of the about 4-5 of pH, surfactant will be by protonated, and anion A can be a glyphosate, and it can generate binary salt.

(4) such surfactant, wherein R ⁵Be anion oxidation thing group, t is 0.This group comprises commodity list surface-active agent known in the art or is referred to herein as " alkyl-dimethyl amine oxide " that (wherein n, x and y are 0, R ⁶And R ⁷Be methyl), some " alkyl ether dimethylamine oxide " (wherein n is 1-5, and x and y are 0, R ⁶And R ⁷Be methyl), " polyoxyalkylene alkyl amine oxide " (wherein n is 0, and x+y is 2 or bigger, R ⁶And R ⁷Be hydrogen) and some " polyoxyalkylene alkyl amine oxide " (wherein n is 1-5, and x+y is 2 or bigger, R ⁶And R ⁷Be hydrogen).The example that is fit to is a cocounut oil dimethylamine oxide, by the Aromox of Akzo sale ^TMDMC, and polyoxyethylene (2) coco amine oxide are by the Aromox of Akzo sale ^TMC/12.

(5) such surfactant, wherein R ⁵Be anionic group-CH ₂C (O) O (acetate), x and y are 0, t is 0.This group comprises commodity list surface-active agent known in the art or is referred to herein as " alkyl betaine " that (wherein n is 0, R ⁵Be acetate, R ⁶And R ⁷Be methyl) and some " alkyl ether betaine " (wherein n is 1-5, R ⁵Be acetate, R ⁶And R ⁷Be methyl).The example that is fit to is the cocounut oil betaine, for example the Velvetex that is sold by Henkel ^TMAB-45.

(C) be equivalent to the surfactant of formula (6), wherein R ¹Be C _8-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, m is 1, X is an ehter bond, R ²Be inferior n-pro-pyl, n is 0.In this group, R ¹With OR ²Constitute the hydrophobic parts of surfactant together, it directly passes through R ²Key is connected with amino-functional.These surfactants are to be disclosed in U.S. Patent No. 5,750, the group alkyl ether amine in 468.Illustrative group has different hydrophilic parts, and for example above-mentioned (B-1) is to (B-5).The example that is fit to is the surfactant of constitutional formula (8), and this moment, its amido right and wrong were protonated:

The surfactant of constitutional formula (9):

And the surfactant of constitutional formula (10):

Wherein in each formula (8), (9) and (10), R ¹Be C _12-15Alkyl, x+y are 5, for example are disclosed in U.S. Patent No. 5,750, in 468.

(D) be equivalent to the surfactant of formula (6), wherein R ¹Be C _8-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, m is 1-5, each XR ²Be group-OCH (CH ₃) CH ₂-, n is 0.In this group, R ¹With group-OCH (CH ₃) CH ₂-constituting the hydrophobic parts of surfactant together, it directly is connected with amino-functional.

These surfactants are to be disclosed in U.S. Patent No. 5,750, another group alkyl ether amine in 468.Illustrative group has different hydrophilic parts, and for example above-mentioned (B-1) is to (B-5).

(E) be equivalent to the surfactant of formula (6), wherein R ¹Be C _8-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, m is 1, X is an amido link, R ²Be inferior n-pro-pyl, n is 0.In this group, R ¹With XR ²Constitute the hydrophobic parts of surfactant together, it directly passes through R ²Key is connected with amino-functional.In preferred this group surfactant, x and y are 0, R ⁵Be hydrogen or C _1-4Alkyl, R ⁶And R ⁷Be C independently _1-4Alkyl, t are 1.The example that is fit to is a coconut palm Tegamine O 13 propionate, for example the Mackalene that is sold by Mclntyre ^TM117.

(F) be equivalent to the surfactant of formula (6), wherein R ¹Be hydrogen, m is 3-8, each XR ²Be group-OCH (CH ₃) CH ₂-.In this group ,-OCH (CH ₃) CH ₂The polyether chain of-group (poly(propylene oxide) chain) constitutes the hydrophobic parts of surfactant, and it directly or via one or more oxygen ethylene unit is connected with amino-functional.In preferred this group surfactant, x and y are 0, R ⁵, R ⁶And R ⁷Be C independently _1-4Alkyl, t are 1.These surfactants are to be disclosed in U.S. Patent No. 5,652, the group polyoxypropylene quaternary surfactant in 197.In the example that is fit to, m is 7, and n is 1, R ⁵, R ⁶And R ⁷Each is methyl naturally, and A is a chlorine.

T is in 1 the surfactant therein, A can be that arbitrarily agricultural goes up acceptable anion, but is preferably chloride, bromide, iodide, sulphate, ethylsulfate, phosphate, acetate, propionate, succinate, lactate, citrate or tartrate or is the anion of glyphosate as mentioned above.

In one embodiment of the invention, composition contains and is disclosed in U.S. Patent No. 5,750, the class alkyl ether amine surfactant in 468, and its disclosure is incorporated herein by reference.In further embodiment, surfactant is not to be disclosed in U.S. Patent No. 5,750, the alkyl ether amine in 468, and its disclosure is incorporated herein by reference.

In another embodiment of the invention, composition contains the have general formula surfactant of (11):

R ¹R ²N(CH ₂) _nNR ³R ⁴ (11)

R wherein ¹And R ²Be C independently _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ³And R ⁴Be C independently _1-4Alkyl or hydrogen, n is greater than 2.The particularly preferred compound of this specification is R wherein ¹And R ²Be C ₈H ₁₇, n is 3, R ³And R ⁴Be hydrogen.

In another embodiment of the invention, composition contains the have general formula surfactant of (12):

R ¹R ²N(CH ₂CH ₂O) _nR ³ (12)

R wherein ¹Be C _8-18Aliphatic, saturated or undersaturated, straight or branched alkyl, R ²And R ³Be C independently _1-10, preferred C _1-4Alkyl or hydrogen, n are 1 or bigger, preferred 2 to 15.At least a compound that it is believed that Ben Shinei was not reported so far as yet in the prior art, therefore was novel compound.The structure of this compound is

CH ₃(CH ₂) ₁₇N(CH ₃)(CH ₂CH ₂O) ₇CH ₃

The compound of this novelty and it are as the purposes of insecticides adjuvant, especially with glyphosate and then more particularly all belong to scope of the present invention with the glyphosate potassium combination.In addition, the hydroxy analogs of above-claimed cpd shows good especially and the compatibility glyphosate potassium salt pref.

In other embodiments of the present invention, composition contains the surfactant with one or more following formulas:

R ¹R ²R ³N ⁺(CH ₂) _nNR ⁴R ⁵ (13)

R wherein ¹Be C _8-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ², R ³, R ⁴And R ⁵Be C independently _1-4Alkyl or hydrogen, X are anionicsites, and n is 2 or bigger;

R ¹O(CH ₂) _nNR ²R ³ (14)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ²And R ³Be C independently _1-4Alkyl or hydrogen, n equal 2 or bigger;

R ¹O(CH ₂) _mNR ²(CH ₂) _nNR ³R ⁴ (15)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ², R ³And R ⁴Be C independently _1-4Alkyl or hydrogen, m and n equal 2 or bigger independently;

R ¹O(CH ₂) _mNR ²(CH ₂) _nNR ³R ⁴ (16)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ², R ³And R ⁴Be poly-(oxygen ethene) chain independently, the total amount of oxygen ethene is equal to or greater than 3 moles, and m and n equal 2 or bigger independently;

R ¹O(CH ₂) _mN[(CH ₂CH ₂O) _nR ²](CH ₂) _p[(CH ₂CH ₂O) _qR ³] ₂ (17)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ²And R ³Be methyl or hydrogen independently, m and p are equal to or greater than about 2 and be equal to or less than approximately 6 independently, and n and q equal about 1-10 independently;

R ¹-X-(CH ₂) _n-NR ²R ³ (18)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ²And R ³Be C independently _1-4Alkyl or hydrogen, X are amido links, and n equals 2 or bigger;

R ¹R ²R ³(N ⁺O ^-) (19)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ²And R ³Be C independently _1-4Alkyl;

R ¹-NR ²-carbohydrate (20)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ²Be C _1-4Alkyl or hydrogen, " carbohydrate " is carbohydrate, for example-CH ₂CH (OH) CH (OH) CH (OH) CH (OH) CH ₂OH.And then other derivatives, for example ethoxylation or non-ethoxylated alkyl or the amide derivatives of aminosugar (particularly 2-Glucosamine) are to make us interested especially in glyphosate or other weed killer herbicide/pesticidal preparations.Two osamines also are to make us interested especially in this.

R ¹-N-[(CH ₂) _nNR ²R ³] ₂ (21)

R wherein ¹Be C _4-18Aliphatic, saturated or undersaturated, straight or branched hydrocarbyl chain, R ²And R ³Be C independently _1-4Alkyl or hydrogen, n are 2 or bigger, and preferably n is 2 or 3;

R ¹R ²N(CH ₂) _m-O-(CH ₂CH ₂O) _n-(CH ₂) _p-NR ³R ⁴ (22)

R wherein ¹, R ², R ³And R ⁴Be C independently _1-4Alkyl, polyoxyethylene or hydrogen, m and p are 2 or bigger independently, preferred 2 or 3, and n is 1 or bigger, preferred 1.

Have been found that novel surfactant is particularly suitable for preparing composition pesticide, for example weed killer herbicide.The various water soluble salts that have been found that surfactant and glyphosate are very compatible, especially the potassium of glyphosate, ammonium and di-ammonium salts.The cationic surfactant that is suitable for preparing pesticidal preparations comprises:

(a) have the monoalkoxy amine of following formula:

R wherein ¹Be hydrogen or have the alkyl of at least 7 carbon atoms (preferably containing 8) or the alkyl of replacement to about 30 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be to have 2 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁴And R ⁵Be hydrogen independently of one another, have 1 alkyl to the alkyl of about 30 carbon atoms or replacement ,-(R ⁶) _n-(R ²O) _yR ⁷, perhaps R ⁴And R ⁵Constitute the ring of ring-type or heterocycle with the nitrogen-atoms that they connected; R ⁶Be to contain 1 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; N is 0 or 1; X and y are 1 to about 60 mean independently; But if its condition is R ²And R ³At each x (R ²O) in the group be ethylidene, then R ¹Not unsubstituted alkyl, perhaps if R ⁵Be hydrogen or unsubstituted alkyl, then R ⁴Not hydrogen or unsubstituted alkyl, if R ²And R ³Be isopropylidene, x is 1, then R ¹Not unsubstituted alkyl or R ⁴Be not-(R ²O) _yR ⁷On this meaning, preferred R ¹, R ⁴, R ⁵And R ⁶Alkyl (alkylene) comprises straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 25 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be ethylidene or 2-hydroxy propylidene; R ⁴And R ⁵Be hydrogen independently of one another or have 1 straight or branched alkyl to about 6 carbon atoms; X is from 1 to about 30 mean.More preferably, R ¹Be to have about 12 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be ethylidene or 2-hydroxy propylidene; R ⁴And R ⁵Be hydrogen, methyl or three (methylol) methyl independently of one another; X is from about 2 to about 30 mean.And then more preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be ethylidene or 2-hydroxy propylidene; R ⁴And R ⁵Be hydrogen or methyl independently of one another; X is from about 4 to about 20 mean.Most preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be ethylidene or 2-hydroxy propylidene; R ⁴And R ⁵It is methyl; X is from about 4 to about 20 mean.

(b) have alkoxylate many (hydroxy alkyl) amine of following formula:

R wherein ¹And R ³Be hydrogen independently, have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ⁴Be to have 1 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ⁵Be hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl; X is from 0 to about 30 mean; Y is 0 or 1.On this meaning, preferred R ¹, R ³And R ⁴Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferred alkoxylated many (hydroxy alkyl) amine has following formula:

R wherein ¹And R ³Be hydrogen independently, have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ⁴Be to have 1 to the alkylene of about 30 carbon atoms or the alkylene of replacement; M and n are from 0 to about 7 integer independently, and m and n sum are not more than about 7; P is from 1 to about 8 integer; X is from 0 to about 30 mean; Y is 0 or 1.On this meaning, preferred R ¹, R ³And R ⁴Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, have 1 straight or branched alkyl or a straight or branched thiazolinyl to about 30 carbon atoms; R ⁴Be to have 1 straight or branched alkylidene to about 30 carbon atoms; M and n are from 0 to about 7 integer independently, and m and n sum are about 3 to 7; P is from 1 to about 8 integer; X is from 0 to about 30 mean; Y is 0 or 1.More preferably, R ¹Be to have about 8 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or have 1 straight or branched alkyl to about 6 carbon atoms; R ⁴Be to have 1 straight or branched alkylidene to about 6 carbon atoms; M and n are from 0 to about 7 integer independently, and m and n sum are about 3 to 7; P is from 1 to about 8 integer; X is from 0 to about 30 mean; Y is 0 or 1.Most preferably, R ¹Be to have about 8 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; M and n are from 0 to about 7 integer independently, and m and n sum are about 3 to 7; P is from 1 to about 8 integer; X is from 0 to about 30 mean; Y is 0.

(c) have two of following formula-many (hydroxy alkyl) amine:

R wherein ¹And R ³Be hydrogen independently or have 1 to the alkyl of about 22 carbon atoms or the alkyl of replacement; R ²Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; R ⁴And R ⁵Be hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl independently; But if its condition is R ¹And R ³Be methyl, R then ²Not Ya Xinji.On this meaning, preferred R ¹, R ²And R ³Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferred two-many (hydroxy alkyl) amine have following formula:

R wherein ¹And R ³Be hydrogen independently or have 1 to the alkyl of about 22 carbon atoms or the alkyl of replacement; R ²Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; M and n are from 1 to about 8 integer independently; But if its condition is R ¹And R ³Be methyl, R then ²Not Ya Xinji.On this meaning, preferred R ¹, R ²And R ³Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).In one embodiment, R ¹And R ³Be hydrogen independently or have 1 straight or branched alkyl to about 6 carbon atoms; R ²Be to have 9 straight or branched alkylidenes, straight or branched alkenylene, straight or branched alkynylene, arlydene and alkyl arylene to about 18 carbon atoms; M and n are as defined above.In another embodiment, R ¹And R ³Be hydrogen independently or have 2 straight or branched alkyl to about 22 carbon atoms; R ²Be to have the 2 straight or branched alkylidenes to about 7 carbon atoms, straight or branched alkenylene, straight or branched alkynylene, arlydene and alkyl arylene, m and n are as defined above.Preferably, R ¹And R ³Be hydrogen independently or have 1 straight or branched alkyl to about 18 carbon atoms; R ²Be to have 2 straight or branched alkylidene or straight or branched alkenylenes to about 18 carbon atoms; M and n are from 1 to about 8 integer independently.More preferably, R ¹And R ³Be hydrogen independently or have 6 straight or branched alkyl, R to about 12 carbon atoms ²Be to have the 2 straight or branched alkylidenes to about 6 carbon atoms, m and n are from about 4 to about 8 integer independently; Perhaps R ¹And R ³Be hydrogen independently or have 1 straight or branched alkyl, R to about 4 carbon atoms ²Be to have the 2 straight or branched alkylidenes to about 16 carbon atoms, m and n are from about 4 to about 8 integer independently.Most preferably, R ¹And R ³Be hydrogen independently or have 6 straight or branched alkyl, R to about 12 carbon atoms ²Be ethylidene or propylidene, m and n are from about 4 to about 8 integer independently; Perhaps R ¹And R ³Be hydrogen independently or have 1 straight or branched alkyl, R to about 4 carbon atoms ²Be to have the 2 straight or branched alkylidenes to about 12 carbon atoms, m and n are from about 4 to about 8 integer independently.

(d) have the alkoxylate triamine of following formula:

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ², R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ⁸) _s(R ⁷-O) _nR ⁶R ⁶Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁷At each n (R ⁷O) in the group be C independently ₂-C ₄Alkylidene; R ⁸Be to have 1 to the alkylene of about 6 carbon atoms or the alkylene of replacement; N is from 1 to about 10 mean, and s is 0 or 1; X and y are 1 to about 4 integer independently; But if its condition is R ¹Be alkyl, R ²Be not hydrogen, x is 3 or 4, perhaps R ⁴Be not-(R ⁷-O) _nR ⁶On this meaning, preferred R ¹, R ², R ³, R ⁴, R ⁵And R ⁸Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).In one embodiment, R ²Be have 1 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl to about 30 carbon atoms or-(R ⁸) _s(R ⁷-O) _nR ⁶All the other groups as mentioned above.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms; R ², R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the straight or branched alkyl of about 30 carbon atoms or straight or branched thiazolinyl or-(R ⁷-O) _nR ⁶R ⁶Be hydrogen, methyl or ethyl; R ⁷At each n (R ⁷O) in the group be C independently ₂-C ₄Alkylidene; N is from 1 to about 10 mean; X and y are 1 to about 4 integer independently.More preferably, R ¹Be to have about 8 straight or branched alkyl to about 18 carbon atoms; R ², R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the straight or branched alkyl of about 6 carbon atoms or-(R ⁷-O) _nR ⁶R ⁶Be hydrogen or methyl; R ⁷At each n (R ⁷O) in the group be ethylidene or propylidene independently; N is from 1 to about 5 mean; X and y are 1 to about 4 integer independently.Most preferably, R ¹Be to have about 8 straight or branched alkyl to about 18 carbon atoms; R ², R ³, R ⁴And R ⁵Be independently hydrogen or-(R ⁷-O) _nR ⁶R ⁶Be hydrogen; R ⁷At each n (R ⁷O) in the group be ethylidene or propylidene independently; N is from 1 to about 5 mean; X and y are 1 to about 4 integer independently.

(e) have the monoalkoxy amine of following formula:

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²Be C ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁴Be to have 1 straight or branched alkynyl, aryl or aralkyl to about 30 carbon atoms; X is from 1 to about 60 mean.On this meaning, preferred R ¹The alkyl of alkyl or replacement is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have 1 straight or branched alkyl or straight or branched thiazolinyl to about 25 carbon atoms; R ²Be C ₂-C ₄Alkylidene, R ³Be hydrogen, methyl or ethyl; R ⁴Be to have 1 straight or branched alkynyl, aryl or aralkyl to about 25 carbon atoms; X is from 1 to about 40 mean.More preferably, R ¹Be to have 8 straight or branched alkyl to about 22 carbon atoms; R ²Be ethylidene or propylidene; R ³Be hydrogen or methyl; R ⁴Be to have 1 straight or branched alkynyl, aryl or aralkyl to about 6 carbon atoms; X is from 1 to about 20 mean.In one embodiment, compound has structural formula shown in the table 4C.

(f) have the amine oxide of following formula:

R wherein ¹Be to have about 8 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²And R ³Be independently-(R ⁴O) _xR ⁵R ⁴At each x (R ⁴O) in the group be C independently ₂-C ₄Alkylidene; R ⁵Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; X is from 1 to about 50 mean.On this meaning, preferred R ¹And R ⁵Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 22 carbon atoms; R ²And R ³Be independently-(R ⁴O) _xR ⁵R ⁴At each x (R ⁴O) in the group be C independently ₂-C ₄Alkylidene; R ⁵Be hydrogen or have 1 straight or branched alkyl or straight or branched thiazolinyl to about 30 carbon atoms; X is from 1 to about 20 mean.More preferably, R ¹Be to have about 8 straight or branched alkyl to about 22 carbon atoms; R ²And R ³Be independently-(R ⁴O) _xR ⁵R ⁴At each x (R ⁴O) in the group be ethylidene or propylidene independently; R ⁵Be hydrogen or have 1 straight or branched alkyl or straight or branched thiazolinyl to about 30 carbon atoms; X is from 1 to about 10 mean.Most preferably, R ¹Be to have about 8 straight or branched alkyl to about 18 carbon atoms; R ²And R ³Be independently-(R ⁴O) _xR ⁵R ⁴At each x (R ⁴O) in the group be ethylidene or propylidene independently; R ⁵Be hydrogen or have 8 alkyl to about 18 carbon atoms; X is from 1 to about 5 mean.

(g) have the alkoxylate amine oxide of following formula:

R wherein ¹Be hydrogen or have about 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be to have 2 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁴And R ⁵Be hydrogen independently of one another, have 1 alkyl to the alkyl of about 30 carbon atoms or replacement ,-(R ⁶) _n-(R ²O) _yR ⁷R ⁶Be to contain 1 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; N is 0 or 1; X and y are from 1 to about 60 mean independently.On this meaning, preferred R ¹, R ⁴, R ⁵And R ⁶Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 25 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be to have 2 straight or branched alkylidene or alkenylenes to about 6 carbon atoms; R ⁴And R ⁵Be hydrogen independently of one another or have 1 straight or branched alkyl to about 6 carbon atoms; X is from 1 to about 30 mean.More preferably, R ¹Be to have about 12 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be to have 2 straight or branched alkylidene or alkenylenes to about 6 carbon atoms; R ⁴And R ⁵Be hydrogen, methyl or three (methylol) methyl independently of one another; X is from about 2 to about 30 mean.And then more preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be ethylidene, propylidene or 2-hydroxy propylidene; R ⁴And R ⁵Be hydrogen or methyl independently of one another; X is from about 4 to about 20 mean.Most preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be ethylidene, propylidene or 2-hydroxy propylidene; R ⁴And R ⁵It is methyl; X is from about 4 to about 20 mean.

(h) have the alkoxylated diamine of following formula:

R wherein ¹Be to have about 8 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³, R ⁵And R ⁶Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ²O) _yR ⁷R ⁴Be have 2 alkylene to the alkylene of about 6 carbon atoms or replacement ,-C (=NR ¹¹) NR ¹²R ¹³-,-C (=O) NR ¹²R ¹³-,-C (=S) NR ¹²R ¹³-,-C (=NR ¹²)-,-C (S)-or-C (O)-; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ¹¹, R ¹²And R ¹³Be hydrogen, have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; X is from 1 to about 30 mean; Y is from 1 to about 50 mean; But its condition is R ³, R ⁵And R ⁶Have at least one to be-(R ²O) _yR ⁷, at least one R ²Not ethylidene, R ⁴Not unsubstituted propylidene, R ¹Be not unsubstituted alkyl, perhaps x is 2 to about 30.On this meaning, preferred R ¹, R ³, R ⁴, R ⁵And R ⁶Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 22 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³, R ⁵And R ⁶Be hydrogen independently, have 1 to the straight or branched alkyl of about 22 carbon atoms or straight or branched thiazolinyl or-(R ²O) _yR ⁷R ⁴Be to have 2 straight or branched alkylidene or straight or branched alkenylenes to about 6 carbon atoms; R ⁷Be hydrogen, methyl or ethyl; X is from 1 to about 20 mean; Y is from 1 to about 20 mean.More preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 18 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³, R ⁵And R ⁶Be hydrogen independently, have 1 to the straight or branched alkyl of about 6 carbon atoms or-(R ²O) _yR ⁷R ⁴Be ethylidene, propylidene or 2-hydroxy propylidene; R ⁷Be hydrogen or methyl; X is from 1 to about 15 mean; Y is from 1 to about 10 mean.Most preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 18 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³, R ⁵And R ⁶Be independently hydrogen, methyl or-(R ²O) _yR ⁷R ⁴Be ethylidene, propylidene or 2-hydroxy propylidene; R ⁷Be hydrogen; X is from 1 to about 10 mean; Y is from 1 to about 5 mean.

(i) have the dialkoxy amine of following formula:

R wherein ¹Be have about 6 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-R ⁴SR ⁵R ⁴And R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁵Be to have about 4 straight or branched alkyl to about 15 carbon atoms; X and y are from 1 to about 40 mean independently.On this meaning, preferred R ¹Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have about 8 straight or branched alkynyl, aryl or aralkyls to about 30 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, methyl or ethyl; X and y are from 1 to about 20 mean independently.More preferably, R ¹Be to have about 8 straight or branched alkynyl, aryl or aralkyls to about 25 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X and y are from 1 to about 30 mean independently.And then more preferably, R ¹Be to have about 8 straight or branched alkynyl, aryl or aralkyls to about 22 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X and y are from 1 to about 5 mean independently.

The ionic surfactant pack that is used in the pesticidal preparations is drawn together the dialkoxy alcohol with following formula:

R ¹(OR ²) _xO-R ³-O-(R ²O) _yR ¹

(35)

R wherein ¹Be hydrogen independently or have 1 straight or branched alkyl to about 4 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; X and y are from 1 to about 60 mean independently.On this meaning, preferred R ³Alkylene is straight or branched alkylidene, straight or branched alkenylene, straight or branched alkynylene, arlydene or inferior aralkyl.Preferably, R ¹Be hydrogen, methyl or ethyl; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be to have about 8 straight or branched alkylidene or straight or branched alkenylenes to about 25 carbon atoms; X and y are from about 1 to about 20 mean independently.More preferably, R ¹Be hydrogen or methyl; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be to have about 8 straight or branched alkylidene or straight or branched alkenylenes to about 18 carbon atoms; X and y are from 1 to about 10 mean independently.And then more preferably, R ¹Be hydrogen; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be to have about 8 straight or branched alkylidenes to about 18 carbon atoms; X and y are from 1 to about 5 mean independently.

Other surfactants that are used in the composition pesticide comprise following formula: compound:

Or

Or

Or

Or

Or

Or

R wherein ¹, R ⁹And R ¹²Be independently have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ²O) _pR ¹³R ²At each m (R ²O), n (R ²O), p (R ²O) and q (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³, R ⁸, R ¹¹, R ¹³And R ¹⁵Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁵, R ⁶And R ⁷Be hydrogen independently, have 1 to the alkyl of about 30 carbon atoms or the alkyl or the R of replacement ⁴R ¹⁰Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ¹⁴Be have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(CH ₂) _zO (R ²O) _pR ³M, n, p and q are from 1 to about 50 mean independently; X is-O-,-N (R ¹⁴)-,-C (O)-,-C (O) O-,-OC (O)-,-N (R ¹⁵) C (O)-,-C (O) N (R ¹⁵)-,-S-,-SO-or-SO ₂-; T is 0 or 1; A-is that agricultural goes up acceptable anion; Y and z are from 0 to about 30 integer independently.On this meaning, preferred R ¹, R ³And R ⁵-R ¹⁵Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹, R ⁹And R ¹²Be independently have 1 to the straight or branched alkyl or alkenyl of about 22 carbon atoms or-(R ²O) _pR ¹³R ²At each m (R ²O), n (R ²O), p (R ²O) and q (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, methyl or ethyl; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁸, R ¹¹, R ¹³And R ¹⁵Be hydrogen independently or have 1 straight or branched alkyl or alkenyl to about 22 carbon atoms; R ⁵, R ⁶And R ⁷Be hydrogen independently, have 1 straight or branched alkyl or alkenyl or a R to about 22 carbon atoms ⁴R ¹⁰Be to have 2 straight or branched alkylidene or alkenylenes to about 18 carbon atoms; R ¹⁴Be have 1 to the straight or branched alkyl or alkenyl of about 22 carbon atoms or-(CH ₂) _zO (R ²O) _pR ³M, n, p and q are from 1 to about 30 mean independently; X is-O-,-N (R ¹⁴)-,-C (O)-,-C (O) O-,-OC (O)-,-N (R ¹⁵) C (O)-,-C (O) N (R ¹⁵)-,-S-,-SO-or-SO ₂-; T is 0 or 1; A-is that agricultural goes up acceptable anion; Y and z are from 0 to about 30 integer independently.More preferably, R ¹Be have about 8 to the straight or branched alkyl or alkenyl of about 18 carbon atoms or-(R ²O) _pR ¹³R ⁹And R ¹²Be independently have 1 to the straight or branched alkyl or alkenyl of about 22 carbon atoms or-(R ²O) _pR ¹³R ²At each m (R ²O), n (R ²O), p (R ²O) and q (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁸, R ¹¹And R ¹⁵Be hydrogen independently or have 1 straight or branched alkyl or alkenyl to about 22 carbon atoms; R ⁵, R ⁶And R ⁷Be hydrogen independently, have 1 straight or branched alkyl or alkenyl or a R to about 22 carbon atoms ⁴R ¹⁰Be to have 2 straight or branched alkylidene or alkenylenes to about 6 carbon atoms; R ¹³Be hydrogen or have about 6 straight or branched alkyl or alkenyls to about 22 carbon atoms; R ¹⁴Be have 1 to the straight or branched alkyl or alkenyl of about 22 carbon atoms or-(CH ₂) _zO (R ²O) _pR ³M, n, p and q are from 1 to about 20 mean independently; X is-O-,-N (R ¹⁴)-,-C (O)-,-C (O) O-,-OC (O)-,-N (R ¹⁵) C (O)-,-C (O) N (R ¹⁵)-,-S-,-SO-or-SO ₂-; T is 0 or 1; A-is that agricultural goes up acceptable anion; Y and z are from 0 to about 10 integer independently.Most preferably, R ¹Be have about 12 to the straight or branched alkyl or alkenyl of about 18 carbon atoms or-(R ²O) _pR ¹³R ⁹And R ¹²Be independently have 1 to the straight or branched alkyl or alkenyl of about 6 carbon atoms or-(R ²O) _pR ¹³R ²At each m (R ²O), n (R ²O), p (R ²O) and q (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁸, R ¹¹And R ¹⁵Be hydrogen independently or have 1 straight or branched alkyl or alkenyl to about 6 carbon atoms; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁵, R ⁶And R ⁷Be hydrogen independently, have 1 straight or branched alkyl or alkenyl or a R to about 22 carbon atoms ⁴R ¹⁰Be to have 2 straight or branched alkylidene or alkenylenes to about 6 carbon atoms; R ¹³Be hydrogen or have about 6 straight or branched alkyl or alkenyls to about 22 carbon atoms; R ¹⁴Be have 1 to the straight or branched alkyl or alkenyl of about 22 carbon atoms or-(CH ₂) _zO (R ²O) _pR ³M, n, p and q are from 1 to about 5 mean independently; X is-O-or-N (R ¹⁴)-; T is 0 or 1; A-is that agricultural goes up acceptable anion; Y and z are from 1 to about 3 integer independently.

Surface activator composition of the present invention comprises any combination of above-mentioned novel surfactant.Surface activator composition is particularly preferred for preparing potassium, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, dimethylamine and/or the trimethylsulfonium salt pref of glyphosate, for example water-based concentrate.Can in the preparation of any combination that comprises these glyphosate salts, mix surface activator composition.

The various surfactants that were not used in the preparation composition pesticide in the past have been found that it is effectively, particularly contain in the aqueous herbicidal concentrate of glyphosate potassium or ammonium in preparation.The cationic surfactant that effectively forms pesticidal preparations comprises:

(a) have the amination alcohol alcoxylates of following formula:

Or

R wherein ¹Be to contain the alkyl of at least 7 carbon atoms (preferably containing 8) or the alkyl of replacement to about 30 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³And R ⁶Be to have 1 independently of one another to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁴Be hydrogen, have alkyl that 1 alkyl to the alkyl of about 30 carbon atoms or replacement, hydroxyl replace ,-(R ⁶) _n-(R ²O) _yR ⁷,-C (=NR ¹¹) NR ¹²R ¹³,-C (=O) NR ¹²R ¹³,-C (=S) NR ¹²R ¹³, perhaps with R ⁵The nitrogen-atoms that is connected with them constitutes the ring of ring-type or heterocycle together; R ⁵Be hydrogen, have alkyl that 1 alkyl to the alkyl of about 30 carbon atoms or replacement, hydroxyl replace ,-(R ⁶) _n-(R ²O) _yR ⁷,-C (=NR ¹¹) NR ¹²R ¹³,-C (=O) NR ¹²R ¹³,-C (=S) NR ¹²R ¹³, perhaps with R ⁴The nitrogen-atoms that is connected with them constitutes the ring of ring-type or heterocycle together; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ¹¹, R ¹²And R ¹³It is the alkyl of hydrogen, alkyl or replacement; R ¹⁴Be hydrogen, have alkyl that 1 alkyl to the alkyl of about 30 carbon atoms or replacement, hydroxyl replace ,-(R ⁶) _n-(R ²O) _yR ⁷,-C (=NR ¹¹) NR ¹²R ¹³,-C (=O) NR ¹²R ¹³Or-C (=S) NR ¹²R ¹³N is 0 or 1; X and y are from 1 to about 60 mean independently; A-is that agricultural goes up acceptable anion; But if its condition is R ²And R ³Be isopropylidene, x is 1, then R ¹Not alkyl or R ⁴Be not-(R ²O) _yR ⁷On this meaning, preferred R ¹, R ³, R ⁴, R ⁵, R ⁶, R ¹¹, R ¹²And R ¹³Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).In one embodiment, R ³Be straight-chain alkyl-sub-, preferred ethylidene, R ¹, R ², R ⁴And R ⁵Define the same.In another embodiment, R ⁴Be H, alkyl or-R ²OR ⁷, R ¹, R ², R ³, R ⁵And R ⁷Define the same.In another embodiment, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 25 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be to have 1 straight or branched alkylidene to about 6 carbon atoms; R ⁴And R ⁵Be hydrogen independently of one another or have 1 straight or branched alkyl to about 6 carbon atoms; X is from about 2 to about 30 mean.More preferably, R ¹Be to have about 12 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be to have 1 straight or branched alkylidene to about 4 carbon atoms; R ⁴And R ⁵Be hydrogen, methyl or three (methylol) methyl independently of one another; X is from about 2 to about 30 mean.And then more preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³It is ethylidene; R ⁴And R ⁵Be hydrogen or methyl independently of one another; X is from about 4 to about 20 mean.Most preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³It is ethylidene; R ⁴And R ⁵It is methyl; X is from about 4 to about 20 mean.Formula (45) compound has above-mentioned preferred group, R ¹⁴Be preferably hydrogen or straight or branched alkyl or alkenyl, more preferably alkyl most preferably is methyl.Preferred monoalkoxy amine comprises PEG 13 or 18C _14-15Ether propylamine and PEG 7,10,15 or 20C _16-18Ether propylamine (from Tomah) and PEG 13 or 18C _14-15Ether dimethyl propylamine and PEG 10,15,20 or 25C _16-18Ether dimethyl propylamine (from Tomah).

(b) have the hydroxylated amine of following formula:

R wherein ¹Be to have about 4 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ³Be hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl.On this meaning, preferred R ¹And R ²Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, hydroxylated amine has following formula:

R wherein ¹Be to have about 4 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; N is 1 to about 8.On this meaning, preferred R ¹And R ²Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R to about 30 carbon atoms ²Be hydrogen or have 1 straight or branched alkyl or straight or branched thiazolinyl that n is about 4 to about 8 to about 30 carbon atoms; Perhaps R ¹And R ²Be to have about 4 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms independently, n is about 4 to about 8.More preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R to about 22 carbon atoms ²Be hydrogen or have 1 straight or branched alkyl or straight or branched thiazolinyl that n is about 4 to about 8 to about 6 carbon atoms; Perhaps R ¹And R ²Be to have about 4 straight or branched alkyl or straight or branched thiazolinyls to about 8 carbon atoms independently, n is about 4 to about 8.

(c) have the diamines of following formula:

R wherein ¹, R ²And R ⁵Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-R ⁸(OR ⁹) _nOR ¹⁰R ³Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; R ⁸And R ⁹Be to have 2 independently to the alkylene of about 4 carbon atoms or the alkylene of replacement; R ⁴And R ¹⁰Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; M is 0 or 1; N is from 0 to about 40 mean; X is-C (O)-or-SO ₂-; A-is that agricultural goes up acceptable anion.On this meaning, preferred R ¹, R ³, R ⁴And R ⁵Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹, R ², R ⁴And R ⁵Be hydrogen independently, have 1 a straight or branched alkyl or alkenyl to about 6 carbon atoms; R ³Be to have 2 straight or branched alkylidenes to about 6 carbon atoms.More preferably, R ¹, R ², R ⁴And R ⁵Be hydrogen independently, have 1 a straight or branched alkyl to about 6 carbon atoms; R ³Be to have 2 straight or branched alkylidenes to about 6 carbon atoms.Most preferably, R ¹, R ², R ⁴And R ⁵Be hydrogen or methyl independently, R ³Be ethylidene or propylidene.

(d) have the list of following formula-or two-ammonium salt:

Or

R wherein ¹, R ², R ⁴, R ⁵And R ⁷Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-R ⁸(OR ⁹) _nOR ¹⁰R ⁶Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ³Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; R ⁸, R ⁹And R ¹¹Be to have 2 independently to the alkylene of about 4 carbon atoms or the alkylene of replacement; R ¹⁰Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; M is 0 or 1; N is from 0 to about 40 mean; X is-C (O)-or-SO ₂-; Z is-C (O)-; A-is that agricultural goes up acceptable anion.On this meaning, preferred R ¹, R ³, R ⁴, R ⁵And R ⁷Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹, R ², R ⁴, R ⁵And R ⁷Be hydrogen independently, have 1 a straight or branched alkyl or alkenyl to about 6 carbon atoms; R ⁶Be to have about 8 straight or branched alkyl or alkenyls to about 30 carbon atoms; M is 0 or 1; R ³Be to have 2 straight or branched alkylidenes to about 6 carbon atoms.More preferably, R ¹, R ², R ⁴, R ⁵And R ⁷Be hydrogen independently, have 1 a straight or branched alkyl to about 6 carbon atoms; R ⁶Be to have about 8 straight or branched alkyl to about 22 carbon atoms; M is 0 or 1; R ³Be to have 1 straight or branched alkylidene to about 6 carbon atoms.Most preferably, R ¹, R ², R ⁴, R ⁵And R ⁷Be hydrogen or methyl independently; R ⁶Be to have about 8 straight or branched alkyl to about 18 carbon atoms; M is 0 or 1; R ³Be ethylidene or propylidene.

(e) have many (hydroxy alkyl) amine of following formula:

R wherein ¹Be have about 4 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-R ⁴OR ⁵R ²Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ³Be hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl; R ⁴Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; R ⁵Be hydrogen or have about 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement.Preferably, many (hydroxy alkyl) amine has following formula:

Or

R wherein ¹Be have about 4 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-R ³OR ⁴R ²Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ³Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; R ⁴Be hydrogen or have about 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; M and n are from 0 to about 7 integer independently, and m and n sum are not more than about 7; P is from 1 to about 8 integer.On this meaning, preferred R ¹, R ², R ³And R ⁴Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be have about 8 to the straight or branched alkyl of about 30 carbon atoms or straight or branched thiazolinyl or-R ³OR ⁴, R ²Be hydrogen or have 1 straight or branched alkyl or straight or branched thiazolinyl, R to about 30 carbon atoms ³Be to have 2 straight or branched alkylidene or alkenylenes, R to about 6 carbon atoms ⁴Be to have the about 8 straight or branched alkyl or alkenyls to about 22 carbon atoms, m and n are from 0 to about 7 integer independently, and m and n sum are from about 3 to 7, and p is from about 4 to about 8 integer; Perhaps R ¹And R ²Be to have about 4 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms independently, m and n are from 0 to about 7 integer independently, and m and n sum are from about 3 to 7, and p is from about 4 to about 8 integer.More preferably, R ¹Be have about 8 to the straight or branched alkyl of about 22 carbon atoms or straight or branched thiazolinyl or-R ³OR ⁴, R ²Be hydrogen or have 1 straight or branched alkyl or straight or branched thiazolinyl, R to about 6 carbon atoms ³Be to have 2 straight or branched alkylidene or alkenylenes, R to about 6 carbon atoms ⁴Be to have the about 8 straight or branched alkyl or alkenyls to about 18 carbon atoms, m and n are from 0 to about 7 integer independently, and m and n sum are from about 3 to 7, and p is from about 4 to about 8 integer; Perhaps R ¹And R ²Be to have about 4 straight or branched alkyl or straight or branched thiazolinyls to about 8 carbon atoms independently, m and n are from 0 to about 7 integer independently, and m and n sum are from about 3 to 7, and p is from about 4 to about 8 integer.And then more preferably, R ¹Be have about 8 to the straight or branched alkyl of about 18 carbon atoms or-R ³OR ⁴, R ²Be hydrogen or methyl, m and n are from 0 to about 4 integer independently, R ³Be to have 2 straight or branched alkylidenes, R to about 6 carbon atoms ⁴Be to have the about 8 straight or branched alkyl to about 18 carbon atoms, m and n sum are about 4, and p is about 4 integer.Most preferably, R ¹Be have about 8 to the straight or branched alkyl of about 18 carbon atoms or-R ³OR ⁴, R ²Be methyl, R ³Be ethylidene, propylidene, hydroxy ethylene or 2-hydroxy propylidene, R ⁴Be to have the about 8 straight or branched alkyl to about 18 carbon atoms, m and n are from 0 to about 4 integer independently, and m and n sum are about 4, and p is about 4 integer.Such compound can obtain from Aldrich and Clariant commercial.

(f) have two of following formula-many (hydroxy alkyl) amine:

R wherein ¹And R ³Be hydrogen independently or have 1 to the alkyl of about 22 carbon atoms or the alkyl of replacement; R ²Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; R ⁴And R ⁵Be hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl independently.On this meaning, preferred R ¹, R ²And R ³Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, two-many (hydroxy alkyl) amine have following formula:

R wherein ¹And R ³Be hydrogen independently or have 1 to the alkyl of about 22 carbon atoms or the alkyl of replacement; R ²Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; M and n are from 1 to about 8 integer independently.On this meaning, preferred R ¹, R ²And R ³Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹And R ³Be hydrogen independently or have 1 straight or branched alkyl to about 18 carbon atoms; R ²Be to have 2 straight or branched alkylidene or straight or branched alkenylenes to about 18 carbon atoms; M and n are from 1 to about 8 integer independently.More preferably, R ¹And R ³Be hydrogen independently or have 6 straight or branched alkyl, R to about 12 carbon atoms ²Be to have the 2 straight or branched alkylidenes to about 6 carbon atoms, m and n are from about 4 to about 8 integer independently; Perhaps R ¹And R ³Be hydrogen independently or have 1 straight or branched alkyl, R to about 4 carbon atoms ²Be to have the 2 straight or branched alkylidenes to about 16 carbon atoms, m and n are from about 4 to about 8 integer independently.Most preferably, R ¹And R ³Be hydrogen independently or have 6 straight or branched alkyl, R to about 12 carbon atoms ²Be ethylidene or propylidene, m and n are from about 4 to about 8 integer independently; Perhaps R ¹And R ³Be hydrogen independently or have 1 straight or branched alkyl, R to about 4 carbon atoms ²Be to have the 2 straight or branched alkylidenes to about 12 carbon atoms, m and n are from about 4 to about 8 integer independently.

(g) have season many (hydroxy alkyl) amine salt of following formula:

R wherein ¹Be to have about 4 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²And R ³Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ⁴Be hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl.On this meaning, preferred R ¹, R ²And R ³Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, many (hydroxy alkyl) amine salt has following formula season:

Or

R wherein ¹Be to have about 4 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²And R ³Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; M and n are from 0 to about 7 integer independently, and m and n sum are not more than about 7; P is from 1 to about 8 integer.On this meaning, preferred R ¹, R ²And R ³Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R to about 30 carbon atoms ²And R ³Be hydrogen independently or have 1 straight or branched alkyl or straight or branched thiazolinyl to about 30 carbon atoms, m and n are from 0 to about 7 integer independently, and m and n sum are from about 3 to 7, and p is from about 4 to about 8 integer; Perhaps R ¹, R ²And R ³Be to have about 4 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms independently, m and n are from 0 to about 7 integer independently, and it is about 7 that m and n sum are not more than, and p is from about 4 to about 8 integer.More preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R to about 22 carbon atoms ²And R ³Be hydrogen independently or have 1 straight or branched alkyl or straight or branched thiazolinyl to about 6 carbon atoms, m and n are from 0 to about 7 integer independently, and m and n sum are from about 3 to 7, and p is from about 4 to about 8 integer; Perhaps R ¹, R ²And R ³Be to have about 4 straight or branched alkyl or straight or branched thiazolinyls to about 8 carbon atoms independently, m and n are from 0 to about 7 integer independently, and m and n sum are from about 3 to 7, and p is from about 4 to about 8 integer.And then more preferably, R ¹Be to have about 8 straight or branched alkyl, R to about 18 carbon atoms ²And R ³Be hydrogen or methyl independently, m and n are from 0 to about 4 integer independently, and m and n sum are about 4, and p is about 4 integer.Most preferably, R ¹Be to have about 8 straight or branched alkyl, R to about 18 carbon atoms ²And R ³Be methyl, m and n are from 0 to about 4 integer independently, and m and n sum are about 4, and p is about 4 integer.

(h) have the triamine of following formula:

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ², R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ⁸) _s(R ⁷O) _nR ⁶R ⁶Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁷At each n (R ⁷O) in the group be C independently ₂-C ₄Alkylidene; R ⁸Be to have 1 to the alkylene of about 6 carbon atoms or the alkylene of replacement; N is from 1 to about 10 mean; S is 0 or 1; X and y are from 1 to about 4 integer independently.On this meaning, preferred R ¹, R ², R ³, R ⁴, R ⁵And R ⁸Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms; R ², R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the straight or branched alkyl of about 30 carbon atoms or straight or branched thiazolinyl or-(R ⁷-O) _nR ⁶R ⁶Be hydrogen, methyl or ethyl; R ⁷At each n (R ⁷O) in the group be C independently ₂-C ₄Alkylidene; N is from 1 to about 10 mean; X and y are from 1 to about 4 integer independently.More preferably, R ¹Be to have about 8 straight or branched alkyl to about 18 carbon atoms; R ², R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the straight or branched alkyl of about 6 carbon atoms or-(R ⁷-O) _nR ⁶R ⁶Be hydrogen or methyl; R ⁷At each n (R ⁷O) in the group be ethylidene or propylidene independently; N is from 1 to about 5 mean; X and y are from 1 to about 4 integer independently.Most preferably, R ¹Be to have about 8 straight or branched alkyl to about 18 carbon atoms; R ², R ³, R ⁴And R ⁵Be independently hydrogen or-(R ⁷-O) _nR ⁶R ⁶Be hydrogen; R ⁷At each n (R ⁷O) in the group be ethylidene or propylidene independently; N is from 1 to about 5 mean; X and y are from 1 to about 4 integer independently.Commercial available triamine comprises Acros and ClariantGenamin 3119.

Another kind effective cationic surfactant in any glyphosate formulation is:

(i) have the diamines of following formula:

R wherein ¹, R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ⁶O) _xR ⁷R ²Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be C independently ₂-C ₄Alkylidene; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 30 carbon atoms; X is from 1 to about 30 mean; Y is from about 3 to about 60 mean; But if its condition is R ²Be ethylidene, then y is greater than 4, R ³, R ⁴And R ⁵Be hydrogen independently, have 1 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl to about 30 carbon atoms or-(R ⁶O) _xR ⁷, R ⁶Not ethylidene, perhaps R ¹, R ³, R ⁴And R ⁵In be no more than one be alkyl or-(R ⁶O) _xR ⁷On this meaning, preferred R ¹, R ², R ³, R ⁴And R ⁵Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹, R ³, R ⁴And R ⁵Be hydrogen independently, have about 1 to the straight or branched alkyl or alkenyl of about 22 carbon atoms or-(R ⁶O) _xR ⁷R ²Be to have about 1 straight or branched alkylidene or alkenylene to about 6 carbon atoms; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be C independently ₂-C ₄Alkylidene; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 30 mean; Y is from about 1 to about 60 mean.More preferably, R ¹, R ³, R ⁴And R ⁵Be hydrogen independently, have about 1 to the straight or branched alkyl of about 18 carbon atoms or-(R ⁶O) _xR ⁷R ²Be to have about 1 straight or branched alkylidene to about 6 carbon atoms; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be ethylidene or propylidene independently; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 10 mean; Y is from about 1 to about 60 mean.Most preferably, R ¹And R ³Be to have about 8 straight or branched alkyl independently to about 18 carbon atoms; R ⁴And R ⁵Be hydrogen independently; R ²Be to have about 1 straight or branched alkylidene to about 6 carbon atoms; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be ethylidene or propylidene independently; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 10 mean; Y is from about 10 to about 50 mean.

(j) have the list of following formula-or two-quaternary ammonium salt:

Or

R wherein ¹, R ³, R ⁴, R ⁵, R ⁸And R ⁹Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ⁶O) _xR ⁷R ²Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be C independently ₂-C ₄Alkylidene; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 30 mean; Y is from about 3 to about 60 mean; X ^-Be that agricultural goes up acceptable anion.On this meaning, preferred R ¹, R ², R ³, R ⁴, R ⁵, R ⁸And R ⁹Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹, R ³, R ⁴, R ⁵, R ⁸And R ⁹Be hydrogen independently, have 1 to the straight or branched alkyl or alkenyl of about 22 carbon atoms or-(R ⁶O) _xR ⁷R ²Be to have about 1 straight or branched alkylidene or alkenylene to about 6 carbon atoms; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be C independently ₂-C ₄Alkylidene; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 30 mean; Y is from about 1 to about 60 mean.More preferably, R ¹, R ³, R ⁴, R ⁵, R ⁸And R ⁹Be hydrogen independently, have about 1 to the straight or branched alkyl or alkenyl of about 18 carbon atoms or-(R ⁶O) _xR ⁷R ²Be to have about 1 straight or branched alkylidene to about 6 carbon atoms; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be ethylidene or propylidene independently; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 10 mean; Y is from about 1 to about 60 mean.Most preferably, R ¹And R ³Be to have about 8 straight or branched alkyl independently to about 18 carbon atoms; R ⁴, R ⁵, R ⁸And R ⁹Be hydrogen or methyl independently; R ²Be to have about 1 straight or branched alkylidene to about 6 carbon atoms; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be ethylidene or propylidene independently; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 10 mean; Y is from about 10 to about 50 mean.

Effectively surfactant comprises nonionic as described below, cation, anion and amphoteric surfactant and composition thereof in potassium, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, dimethylamine and/or the trimethylsulfonium salt pref of preparation glyphosate.

Effectively cationic surfactant comprises in this class glyphosate formulation:

(a) have the second month in a season or the tertiary amine of following formula:

R wherein ¹And R ²Be alkyl with 1 to 30 carbon atom, R ³Be hydrogen or have 1 alkyl to about 30 carbon atoms.On this meaning, preferred R ¹, R ²And R ³Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R to about 30 carbon atoms ²And R ³Be hydrogen independently or have 1 straight or branched alkyl or straight or branched thiazolinyl to about 6 carbon atoms.More preferably, R ¹Be to have about 12 straight or branched alkyl, R to about 22 carbon atoms ²And R ³Be hydrogen, methyl or ethyl independently.In a kind of embodiment of formula (CC) amine, R ¹Be to have about 12 straight or branched alkyl, R to about 22 carbon atoms ²And R ³Be to have 1 straight or branched hydroxy alkyl independently to about 6 carbon atoms.

In a kind of by way of example, surfactant has formula (48), wherein R ¹Be to have about 8 to the alkyl of about 30 carbon atoms or the alkyl of replacement, R ²Be hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl, R ³Be hydrogen, hydroxy alkyl, polyhydroxy alkyl or many (hydroxy alkyl) alkyl.On this meaning, preferred R ¹Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.In one embodiment, R ¹Be to have about 8 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl, R to about 30 carbon atoms ²Be to have 1 straight or branched hydroxy alkyl, R to about 6 carbon atoms ³Be hydrogen or have 1 straight or branched hydroxy alkyl to about 6 carbon atoms.Preferably, R ¹Be to have about 8 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl, R to about 22 carbon atoms ²Be to have 1 straight or branched hydroxy alkyl, R to about 4 carbon atoms ³Be hydrogen or have 1 straight or branched hydroxy alkyl to about 4 carbon atoms.More preferably, R ¹Be to have about 8 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl, R to about 18 carbon atoms ²Be methylol or ethoxy, R ³Be hydrogen, methylol or ethoxy.

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise the second month in a season or tertiary amine, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

(b) have the monoalkoxy amine of following formula:

R wherein ¹And R ⁴Be independently have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-R ⁵SR ⁶R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁵Be to have about 6 straight or branched alkyl to about 30 carbon atoms; R ⁶Be to have 4 to the alkyl of about 15 carbon atoms or the alkyl of replacement; X is from 1 to about 60 mean.On this meaning, preferred R ¹, R ⁴And R ⁶Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.In one embodiment, R ¹Comprise about 7 to about 30 carbon atoms, preferred about 8 to about 22 carbon atoms, and all the other groups as mentioned above.Preferably, R ¹And R ⁴Be to have 1 straight or branched alkyl or straight or branched thiazolinyl independently to about 25 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or methyl; X is from 1 to about 30 mean.More preferably, R ¹And R ⁴Be to have 1 straight or branched alkyl independently to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X is from 1 to about 30 mean.And then more preferably, R ¹Be to have about 8 straight or branched alkyl, R to about 22 carbon atoms ⁴Be to have 1 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X is from 1 to about 10 mean.Most preferably, R ¹Be to have about 16 straight or branched alkyl, R to about 22 carbon atoms ⁴Be methyl, R ²At each x (R ²O) in the group be ethylidene, R ³Be hydrogen, x is from 1 to about 5 mean; Perhaps R ¹Be straight or branched alkyl with about 15 carbon atoms, R ⁴Be methyl, R ²At each x (R ²O) in the group be ethylidene, R ³Be hydrogen, x is from about 5 to about 10 mean.

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise monoalkoxy amine, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

(c) have the dialkoxy quaternary ammonium salt of following formula:

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁴Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; X and y are from 1 to about 40 mean independently; X-is that agricultural goes up acceptable anion.On this meaning, preferred R ¹And R ⁴Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹And R ⁴Be to have 1 straight or branched alkyl or straight or branched thiazolinyl independently to about 25 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, methyl or ethyl; X and y sum are from about 2 to about 30 mean.More preferably, R ¹And R ⁴Be to have 1 straight or branched alkyl independently to about 22 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X and y sum are from about 2 to about 20 mean.And then more preferably, R ¹Be to have about 8 straight or branched alkyl, R to about 22 carbon atoms ⁴Be to have 1 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X and y sum are from about 2 to about 20 mean.Most preferably, R ¹Be to have about 8 straight or branched alkyl, R to about 22 carbon atoms ⁴Be to have 1 straight or branched alkyl, R to about 6 carbon atoms ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently, R ³Be hydrogen or methyl, x is from about 2 to about 15 mean; Perhaps R ¹And R ⁴Be to have about 8 straight or branched alkyl, R independently to about 22 carbon atoms ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently, R ³Be hydrogen or methyl, x is from about 5 to about 15 mean.Preferred dialkoxy quaternary surfactant comprises Ethoquad ^TMC12 (from the PEG 2 cocounut oil ammonio methacrylates of Akzo Nobel), PEG 5 cocounut oil ammonio methacrylates, PEG 5 butter ammonio methacrylates, PEG 5 two butter ammonium bromides and PEG 10 2 butter ammonium bromides.

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise the dialkoxy quaternary ammonium salt, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

(d) have the monoalkoxy quaternary ammonium salt of following formula:

R wherein ¹And R ⁵Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ⁴Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; X is from 1 to about 60 mean; X-is that agricultural goes up acceptable anion.On this meaning, preferred R ¹, R ⁴And R ⁵Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹, R ⁴And R ⁵Be to have 1 straight or branched alkyl or straight or branched thiazolinyl independently to about 25 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, methyl or ethyl; X is from 1 to about 40 mean.More preferably, R ¹, R ⁴And R ⁵Be to have 1 straight or branched alkyl independently to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X is from 1 to about 30 mean.And then more preferably, R ¹Be to have about 8 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; R ⁴And R ⁵Be from 1 straight or branched alkyl independently to about 22 carbon atoms; X is from 1 to about 30 mean.And then more preferably, R ¹Be to have about 8 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; R ⁴And R ⁵Be from 1 straight or branched alkyl independently to about 6 carbon atoms; X is from about 5 to about 25 mean.Most preferably, R ¹Be to have about 16 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; R ⁴And R ⁵Be from 1 straight or branched alkyl independently to about 3 carbon atoms; X is from about 5 to about 25 mean.Preferred monoalkoxy quaternary surfactant comprises PEG 7 C ₁₈Alkyl dimethyl ammonium chloride and PEG 22 C ₁₈Alkyl dimethyl ammonium chloride.

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise the monoalkoxy quaternary ammonium salt, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

(e) have the quaternary ammonium salt of following formula:

R wherein ¹, R ³And R ⁴Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; X-is that agricultural goes up acceptable anion.On this meaning, preferred R ¹, R ², R ³And R ⁴Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R to about 30 carbon atoms ², R ³And R ⁴Be to have 1 straight or branched alkyl or straight or branched thiazolinyl independently to about 30 carbon atoms.More preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R to about 22 carbon atoms ², R ³And R ⁴Be to have 1 straight or branched alkyl or straight or branched thiazolinyl independently to about 6 carbon atoms.And then more preferably, R ¹Be to have about 8 straight or branched alkyl, R to about 16 carbon atoms ², R ³And R ⁴Be to have 1 straight or branched alkyl independently to about 6 carbon atoms.Most preferably, R ¹Be to have about 8 straight or branched alkyl, R to about 14 carbon atoms ², R ³And R ⁴It is methyl.Preferred commercial available quaternary surfactant comprises Arquad ^TMC-50 (from the Dodecyl trimethyl ammonium chloride of Akzo Nobel) and Arquad ^TMT-50 (from the butter trimethyl ammonium chloride of Akzo Nobel).

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise quaternary ammonium salt, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

(f) have the ether amine of following formula:

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ³And R ⁴Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ⁵O) _xR ⁶R ⁵At each x (R ⁵-O) be C independently in the group ₂-C ₄Alkylidene; R ⁶Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 50 mean.On this meaning, preferred R ¹, R ², R ³And R ⁴Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be to have 8 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl to about 25 carbon atoms; R ²Be to have 2 straight or branched alkylidene or alkenylenes to about 30 carbon atoms; R ³And R ⁴Be hydrogen independently, have 1 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl to about 30 carbon atoms or-(R ⁵O) _xR ⁶R ⁵At each x (R ⁵-O) be C independently in the group ₂-C ₄Alkylidene; R ⁶Be hydrogen, methyl or ethyl; X is from 1 to about 30 mean.More preferably, R ¹Be to have 8 straight or branched alkyl or alkenyls to about 22 carbon atoms; R ²Be to have 2 straight or branched alkylidene or alkenylenes to about 6 carbon atoms; R ³And R ⁴Be hydrogen independently, have 1 to the straight or branched alkyl or alkenyl of about 6 carbon atoms or-(R ⁵O) _xR ⁶R ⁵At each x (R ⁵-O) be ethylidene or propylidene independently in the group; R ⁶Be hydrogen or methyl; X is from 1 to about 15 mean.Most preferably, R ¹Be to have 8 straight or branched alkyl or alkenyls to about 18 carbon atoms; R ²Be ethylidene or propylidene; R ³And R ⁴Be independently hydrogen, methyl or-(R ⁵O) _xR ⁶R ⁵At each x (R ⁵-O) be ethylidene or propylidene independently in the group; R ⁶Be hydrogen; X is from 1 to about 5 mean.

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise ether amine, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540ga.e./l.

(g) have the diamines of following formula:

R wherein ¹, R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ⁶O) _xR ⁷R ²And R ⁸Be to have 2 independently to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ⁶At each x (R ⁶O) and y (R ⁶O) in the group be C independently ₂-C ₄Alkylidene; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 30 carbon atoms; X is from 1 to about 30 mean; X is-O-,-N (R ⁶)-,-C (O)-,-C (O) O-,-OC (O)-,-N (R ⁹) C (O)-,-C (O) N (R ⁹)-,-S-,-SO-or-SO ₂-; Y is 0 or from 1 to about 30 mean; N and z are 0 or 1 independently; R ⁹It is the alkyl of hydrogen or alkyl or replacement.On this meaning, preferred R ¹, R ², R ³, R ⁴, R ⁵And R ⁹Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹And R ⁴Be to have about 1 straight or branched alkyl or straight or branched thiazolinyl, R independently to about 22 carbon atoms ²And R ⁸Be to have 2 straight or branched alkylidenes, R independently of one another to about 25 carbon atoms ³And R ⁵Be hydrogen independently of one another or have 1 straight or branched alkyl that n, y and z are 0 to about 6 carbon atoms; Perhaps R ¹, R ², R ³And R ⁴Be hydrogen independently or have about 1 straight or branched alkyl or alkenyl, R to about 6 carbon atoms ²Be to have about 8 straight or branched alkylidene or alkenylenes to about 25 carbon atoms, n, y and z are 0; Perhaps R ¹, R ², R ³And R ⁴Be hydrogen independently or have about 1 straight or branched alkyl or alkenyl, R to about 6 carbon atoms ²Be to have about 1 straight or branched alkylidene or alkenylene, R to about 6 carbon atoms ⁶At each y (R ⁶O) in the group be C independently ₂-C ₄Alkylidene, y are from 1 to about 20 mean, and n and z are 0; Perhaps R ¹And R ³Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls, R independently to about 22 carbon atoms ²Be to have 2 straight or branched alkylidenes, R to about 25 carbon atoms ⁴And R ⁵Be hydrogen independently of one another, have 1 to the straight or branched alkyl or alkenyl of about 6 carbon atoms or-(R ⁶O) _xR ⁷, R ⁶At each x (R ⁶O) in the group be C independently ₂-C ₄Alkylidene, R ⁷Be hydrogen or have the 1 straight or branched alkyl to about 4 carbon atoms, x is from 1 to about 30 mean, and n, y and z are 0; Perhaps R ¹Be to have about 1 straight or branched alkyl or straight or branched thiazolinyl, R to about 22 carbon atoms ²Be to have about 2 straight or branched alkylidenes, R to about 25 carbon atoms ³, R ⁴And R ⁵Being hydrogen independently of one another or having 1 straight or branched alkyl to about 6 carbon atoms, X is-C (O)-or-SO ₂-, n and y are 0, z is 1.More preferably, R ¹And R ⁴Be to have about 4 straight or branched alkyl or straight or branched thiazolinyls, R independently to about 18 carbon atoms ²Be to have about 2 straight or branched alkylidenes, R to about 6 carbon atoms ³And R ⁵Be hydrogen independently of one another or have 1 straight or branched alkyl that n, y and z are 0 to about 6 carbon atoms; Perhaps R ¹, R ², R ³And R ⁴Be hydrogen independently or have about 1 straight or branched alkyl, R to about 6 carbon atoms ²Be to have the about 8 straight or branched alkylidenes to about 25 carbon atoms, y is 0; Perhaps R ¹, R ², R ³And R ⁴Be hydrogen independently or have about 1 straight or branched alkyl, R to about 6 carbon atoms ²Be to have about 1 straight or branched alkylidene, R to about 6 carbon atoms ⁶At each y (R ⁶O) in the group be ethylidene or propylidene independently, y is from 1 to about 10 mean, and n and z are 0; Perhaps R ¹And R ³Be to have about 8 straight or branched alkyl, R independently to about 22 carbon atoms ²Be to have about 2 straight or branched alkylidenes, R to about 6 carbon atoms ⁴And R ⁵Be hydrogen independently of one another, have 1 to the straight or branched alkyl of about 6 carbon atoms or-(R ⁶O) _xR ⁷, R ⁶At each x (R ⁶O) in the group be ethylidene or propylidene independently, R ⁷Be hydrogen or methyl, x is from 1 to about 15 mean, and n, y and z are 0; Perhaps R ¹Be to have about 1 straight or branched alkyl, R to about 22 carbon atoms ²Be to have about 2 straight or branched alkylidenes, R to about 6 carbon atoms ³, R ⁴And R ⁵Be hydrogen independently of one another, X is-C (O)-or-SO ₂-, n and y are 0, z is 1.Preferred diamines comprises that Gemini14-2-14, Gemini 14-3-14, Gemini 10-2-10, Gemini 10-3-10, Gemini10-4-10 and Gemini 16-2-16 are (from the C of Monsanto ₁₀, C ₁₄Or C ₁₆Ethylidene, propylidene or butylidene N-methanediamine), Ethoduomeens ^TMAnd Jeffamine ^TMEDR-148.

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise diamines, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540ga.e./l.

(h) have the amine oxide of following formula:

R wherein ¹, R ²And R ³Be independently hydrogen, alkyl or replacement alkyl ,-(R ⁴O) _xR ⁵Or-R ⁶(OR ⁴) _xOR ⁵R ⁴At each x (R ⁴O) in the group be C independently ₂-C ₄Alkylidene; R ⁵Be hydrogen or have 1 straight or branched alkyl to about 30 carbon atoms; R ⁶Be to have 2 to the alkylene of about 6 carbon atoms or the alkylene of replacement; X is from 1 to about 50 mean; R ¹, R ²And R ³The sum of middle carbon atom is 8 at least.On this meaning, preferred R ¹, R ², R ³And R ⁶Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹And R ²Be hydrogen independently, have 1 to the straight or branched alkyl of about 30 carbon atoms or straight or branched thiazolinyl or-(R ⁴O) _xR ⁵R ³Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms; R ⁴At each x (R ⁴O) in the group be C independently ₂-C ₄Alkylidene; R ⁵Be hydrogen, methyl or ethyl; X is from 1 to about 30 mean.More preferably, R ¹And R ²Be hydrogen independently or have 1 straight or branched alkyl, R to about 6 carbon atoms ³Be to have about 8 straight or branched alkyl to about 22 carbon atoms; Perhaps R ¹And R ²Be independently-(R ⁴O) _xR ⁵, R ³Be to have about 8 straight or branched alkyl, R to about 22 carbon atoms ⁴At each x (R ⁴O) in the group be ethylidene or propylidene independently, R ⁵Be hydrogen or methyl, x is from 1 to about 10 mean.Most preferably, R ¹And R ²Be methyl independently, R ³Be to have about 8 straight or branched alkyl to about 18 carbon atoms; Perhaps R ¹And R ²Be independently-(R ⁴O) _xR ⁵, R ³Be to have about 8 straight or branched alkyl, R to about 18 carbon atoms ⁴At each x (R ⁴O) in the group be ethylidene or propylidene independently, R ⁵Be hydrogen, x is from 1 to about 5 mean.Commercial available amine oxide surfactant comprises Chemoxide L70.

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise amine oxide, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

(i) have the dialkoxy amine of following formula:

R wherein ¹Be have about 6 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl to about 30 carbon atoms or-R ⁴SH; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁴Be to have about 6 straight or branched alkyl to about 30 carbon atoms; X and y are from 1 to about 40 mean independently.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, methyl or ethyl; X and y are from 1 to about 20 mean independently.More preferably, R ¹Be to have about 8 straight or branched alkyl to about 25 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X and y are from 1 to about 10 mean independently.And then more preferably, R ¹Be to have about 8 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) and y (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X and y are from 1 to about 5 mean independently.Preferred commercial available dialkoxy amine comprises TrymeenTM 6617 (Cognis) and EthomeenTMC/12, C/15, C/20, C/25, T/12, T/15, T/20 and T/25 (Akzo Nobel).

Preferably this class dialkoxy amine is used in such glyphosate potassium concentrate, wherein contains every liter of glyphosate potassium of at least 550 gram a.e., more preferably every liter of glyphosate potassium of at least 560,570 or 580 gram a.e..Preferably this class glyphosate potassium concentrate contains 550 to the about 600 gram a.e. every liter of glyphosate potassiums of having an appointment.

Select as an alternative, preferably dialkoxy amine is formulated in such glyphosate potassium concentrate, wherein contain every liter of glyphosate potassium of at least 320 gram a.e., it is not contain alkyl polyglycoside, perhaps only contain colour less than 10 alkyl polyglycoside, preferably, measure with the Gardner colorimeter less than 9,8,7,6 or 5.In one embodiment, this class concentrate comprises every liter of glyphosate potassium of at least 330,340,350,360,370,380,390,400,410,420,430,440,450,460,470,480,490,500,510,520,530,540,550,560,570 or 580 gram a.e..Preferably this class glyphosate potassium concentrate contains 400 to the about 600 gram a.e. every liter of glyphosate potassiums of having an appointment, more preferably from about 450 to about 600, about 500 to about 600, about 540 to about 600 or about 550 to about 600 gram a.e. every liter of glyphosate potassiums.

Select as an alternative, preferably dialkoxy amine is incorporated in such glyphosate potassium concentrate, wherein contain 20 to about 150 total surfactants that restrain in every liter of preparation of having an appointment, more preferably from about 20 to every liter of about 130 gram.In another embodiment, dialkoxy amine is incorporated in such glyphosate potassium concentrate, wherein contain 20 to about 150 total surfactants that restrain in every liter of preparation of having an appointment, every liter of glyphosate potassium of at least 320 gram a.e., more preferably every liter of glyphosate potassium of at least 330,340,350,360,370,380,390,400,410,420,430,440,450,460,470,480,490,500,510,520,530,540,550,560,570 or 580 gram a.e..Preferably this class glyphosate potassium concentrate contains 400 to the about 600 gram a.e. every liter of glyphosate potassiums of having an appointment, more preferably from about 450 to about 600, about 500 to about 600, about 540 to about 600 or about 550 to about 600 gram a.e. every liter of glyphosate potassiums.

(j) have the amination alcohol alcoxylates of the following chemical structure:

R wherein ¹, R ⁷, R ⁸And R ⁹Be hydrogen independently of one another, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ¹¹) _s(R ³O) _vR ¹⁰X is-O-,-OC (O)-,-C (O) O-,-N (R ¹²) C (O)-,-C (O) N (R ¹²)-,-S-,-SO-,-SO ₂-or-N (R ⁹)-; R ³At each n (R ³O) and v (R ³O) in the group be C independently ₂-C ₄Alkylidene; R ¹⁰Be hydrogen or have 1 straight or branched alkyl to about 30 carbon atoms; N is from 1 to about 60 mean; V is from 1 to about 50 mean; R ²And R ¹¹Be to have 1 independently of one another to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁴Be to have 2 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ¹²Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; M and s are 0 or 1 independently of one another; R ⁶Be have 2 alkylene to the alkylene of about 30 carbon atoms or replacement ,-C (=NR ¹²)-,-C (S)-or-C (O)-; Q is from 0 to 5 integer; R ⁵Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement.On this meaning, preferred R ¹, R ², R ⁴, R ⁵, R ⁶, R ⁷, R ⁸, R ⁹, R ¹¹And R ¹²Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise the amination alcohol alcoxylates, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

This cationoid surfactant of one group comprises the monoalkoxy amine with following formula:

R wherein ¹Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) and y (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ⁴And R ⁵Be hydrogen independently of one another, have 1 alkyl to the alkyl of about 30 carbon atoms or replacement ,-(R ⁶) _n(R ²O) _yR ⁷, perhaps R ⁴And R ⁵Constitute the ring of ring-type or heterocycle with the nitrogen-atoms that they connected; R ⁶Be to have 1 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; N is 0 or 1; X and y are from 1 to about 60 mean independently.On this meaning, preferred R ¹, R ³, R ⁴, R ⁵And R ⁶Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).Preferably, R ¹Be hydrogen or have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 25 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be to have 2 straight or branched alkylidenes to about 20 carbon atoms; R ⁴And R ⁵Be hydrogen independently of one another or have 1 straight or branched alkyl to about 6 carbon atoms; X is from 1 to about 30 mean.More preferably, R ¹Be hydrogen or have about 12 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be to have 2 straight or branched alkylidenes to about 6 carbon atoms; R ⁴And R ⁵Be hydrogen, methyl or three (methylol) methyl independently of one another; X is from about 2 to about 30 mean.And then more preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be ethylidene or propylidene; R ⁴And R ⁵Be hydrogen, methyl or three (methylol) methyl independently of one another; X is from about 4 to about 20 mean.Most preferably, R ¹Be to have about 12 straight or branched alkyl to about 18 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³It is ethylidene; R ⁴And R ⁵It is methyl; X is from about 4 to about 20 mean.Preferred monoalkoxy amine comprises PEG 13 or 18C _14-15Ether propylamine and PEG 7,10,15 or 20C _16-18Ether propylamine (Tomah) and PEG 13 or 18C _14-15Ether dimethyl propylamine and PEG 10,15,20 or 25C _16-18Ether dimethyl propylamine (Tomah) and Surfonic ^TMAGM-550 (Huntsman).

Quaternary ammonium, sulfonium and oxidation sulfonium salt also are effective cationic surfactants in forming the glyphosate potassium concentrate, have the following chemical structure:

Or

R wherein ¹, R ⁷, R ⁸, R ⁹, R ¹⁰And R ¹¹Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ¹³) _s(R ³O) _vR ¹²X is-O-,-OC (O)-,-N (R ¹⁴) C (O)-,-C (O) N (R ¹⁴)-,-C (O) O-or-S-; R ³At each n (R ³O) and v (R ³O) in the group be C independently ₂-C ₄Alkylidene; R ¹²Be hydrogen or have 1 straight or branched alkyl to about 30 carbon atoms; N is from 1 to about 60 mean; V is from 1 to about 50 mean; R ²And R ¹³Be to have 1 independently of one another to the alkylene of about 6 carbon atoms or the alkylene of replacement; M and s are 0 or 1 independently of one another; R ⁴Be to have 2 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁶Be have 2 alkylene to the alkylene of about 30 carbon atoms or replacement ,-C (=NR ¹²)-,-C (S)-or-C (O)-; R ¹⁴Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; Q is from 0 to 5 integer; R ⁵Be hydrogen or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; Each A-is that agricultural goes up acceptable anion.On this meaning, preferred R ¹, R ², R ⁴, R ⁵, R ⁶, R ⁷, R ⁸, R ⁹, R ¹⁰, R ¹¹, R ¹³And R ¹⁴Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).

Another kind effective cationic surfactant in any glyphosate formulation is diamines or the di-ammonium salts with following formula:

R wherein ¹, R ⁴, R ⁵, R ⁶, R ⁷And R ⁸Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each m (R ²O) and n (R ²O) in the group and R ⁹Be C independently ₂-C ₄Alkylidene; R ³Be have about 2 to the alkylene of the alkylene of about 6 carbon atoms or replacement or-(R ²O) _pR ⁹-; M and n are from 0 to about 50 mean independently; P is from 0 to about 60 mean.On this meaning, preferred R ¹, R ³, R ⁴, R ⁵, R ⁶, R ⁷And R ⁸Alkyl (alkylene) is straight or branched alkyl (alkylidene), straight or branched thiazolinyl (alkenylene), straight or branched alkynyl (alkynylene), aryl (arlydene) or aralkyl (inferior aralkyl).In a kind of embodiment of formula (DA), R ³Be to have about 2 alkylene to about 6 carbon atoms, all the other group definition are the same.

The ionic surfactant pack that is preferred for this class glyphosate concentrate is drawn together the alcohol alcoxylates with following formula:

R ¹O-(R ²O) _xR ³

(80)

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 60 mean.On this meaning, preferred R ¹Alkyl is straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl.Preferably, R ¹Be to have about 8 straight or branched alkyl or straight or branched thiazolinyls to about 30 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, methyl or ethyl; X is from about 5 to about 50 mean.More preferably, R ¹Be to have about 8 straight or branched alkyl to about 25 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X is from about 8 to about 40 mean.And then more preferably, R ¹Be to have about 12 straight or branched alkyl to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X is from about 8 to about 30 mean.Preferred commercial available alcohol alcoxylates comprises Procol ^TMLA-15 (Protameen), Brij ^TM35, Brij ^TM76, Brij ^TM78, Brij ^TM97 and Brij ^TM98 (Sigma Chemical Co.), Neodol ^TM25-12 (Shell), Hexotol ^TMCA-10, Hexotol ^TMCA-20, Hexotol ^TMCS-9, Hexotol ^TMCS-15, Hexotol ^TMCS-20, Hexotol ^TMCS-25, Hexotol ^TMCS-30 and Plurafac ^TMA38 (BASF), ST-8303 (Cognis) and Arosurf ^TM66 E20 (Witco/Crompton).

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise alcohol alcoxylates, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

Other ionic surfactant pack that are used in this class glyphosate formulation are drawn together the alkoxylate dialkyl group phenol with following formula:

R wherein ¹And R ⁴Be hydrogen independently or have 1 straight or branched alkyl, R to about 30 carbon atoms ¹And R ⁴Have at least one to be alkyl; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; X is from 1 to about 60 mean.Preferably, R ¹And R ⁴Be to have 8 straight or branched alkyl independently to about 30 carbon atoms; R ²At each x (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³Be hydrogen, methyl or ethyl; X is from about 5 to about 50 mean.More preferably, R ¹And R ⁴Be to have about 8 straight or branched alkyl independently to about 22 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X is from about 8 to about 40 mean.And then more preferably, R ¹And R ⁴Be to have about 8 straight or branched alkyl independently to about 16 carbon atoms; R ²At each x (R ²O) in the group be ethylidene or propylidene independently; R ³Be hydrogen or methyl; X is from about 10 to about 30 mean.Preferred commercial available alkoxylate dialkyl group phenol comprises ethoxylation dinonyl phenol, for example Surfonic ^TMDNP 100, Surfonic ^TMDNP 140 and Surfonic ^TMDNP 240 (Huntsman).

In one embodiment, in the glyphosate concentrate that is not glyphosate IPA, comprise described phenol, the potassium that for example contains glyphosate, two ammoniums, ammonium, sodium, MEA, n-propylamine, methylamine, ethamine, hexamethylene diamine, the glyphosate concentrate of dimethylamine or trimethyl sulfonium salt and composition thereof, they contain at least about 20wt% glyphosate a.e., more preferably at least about 25%, 30%, 35%, 40%, 45%, 50% or 55wt%a.e., perhaps at least about every liter of 270g a.e. glyphosate, more preferably at least 300,360,400,420,440,460,480,500,520 or 540g a.e./l.

Effectively the preferred anionic surfactants surfactant comprises saturated carboxylic acid in forming the glyphosate potassium preparation, for example butyric acid, caproic acid, sad, capric acid, lauric acid, palmitic acid, myristic acid or stearic acid, with undersaturated carboxylic acid, for example palmitoleic acid, oleic acid, linoleic acid or linolenic acid.Preferred carboxylic acid comprises palmitic acid, oleic acid or stearic acid.Other preferred anionic surfactants surfactants comprise alkyl sulfate, and for example NaLS and alkyl alkoxylated phosphate have following formula:

R wherein ¹And R ³Be to have about 4 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl independently to about 30 carbon atoms; R ²At each m (R ²O) and n (R ²O) in the group be C independently ₂-C ₄Alkylidene; M and n are 1 to about 30 independently;

Or

R wherein ¹Be to have about 8 straight or branched alkyl, straight or branched thiazolinyl, straight or branched alkynyl, aryl or aralkyl to about 30 carbon atoms; R ²At each m (R ²O) in the group be C independently ₂-C ₄Alkylidene; M is 1 to about 30.Representative alkyl alkoxylated phosphate comprises oleth-10 phosphate, oleth-20 phosphate and oleth-25 phosphate.

Comprise following material according to the operable exemplary table surface-active agent of the present invention:

With

In water-based concentrate formulation of the present invention or dry preparation, the ratio of glyphosate a.e. and surfactant (weight) usually at about 1: 1 to about 20: 1 scope, preferably from about 2: 1 to about 10: 1, more preferably from about 2: 1 to about 8: 1, and then more preferably from about 2: 1 to about 6: 1, and then more preferably from about 3: 1 to about 6: 1.

The density that contains the preparation of glyphosate arbitrarily of the present invention is preferably at least 1.210 grams per liters, more preferably at least about 1.215,1.220,1.225,1.230,1.235,1.240,1.245,1.250,1.255,1.260,1.265,1.270,1.275,1.280,1.285,1.290,1.295,1.300,1.305,1.310,1.315,1.320,1.325,1.330,1.335,1.340,1.345,1.350,1.355,1.360,1.365,1.370,1.375,1.380,1.385,1.390,1.395,1.400,1.405,1.410,1.415,1.420,1.425,1.430,1.435,1.440,1.445 or 1.450 grams per liters.

As this paper further discuss, can in preparation of the present invention, introduce other additives, auxiliary agent or composition, to improve some character of gained preparation.Even preparation of the present invention does not add any other additive and shows good general stability and viscometric properties yet, but add the character that solubilizer (also generally being called cloud point improving agent or stabilizing agent) can significantly improve preparation of the present invention.The solubilizer that is applicable to novel formulation of the present invention for example comprises coco amine (Armeen C), dimethyl coco amine (Arquad DMCD), chlorination cocounut oil ammonium (Arquad C), PEG 2 coco amine (Ethomeen C12), PEG 5 beef tallow amines (Ethomeen T15) and PEG 5 coco amine (Ethomeen C15), and all these are made by Akzo Nobel (California).

In addition, have been found that adding C ₄To C ₁₆Alkyl or aryl amines or corresponding quaternary ammonium compound strengthen some glyphosate salt (for example potassium or isopropylamine) and the compatibility that shows the surfactant of low or edge compatibility under given glyphosate LOADING RATES greatly.The alkyl or aryl amines that is fit to can also contain 0 to about 5 EO groups.Preferred alkyl ammonium compounds comprises the C with 0 to 2 EO group ₆To C ₁₂Alkylamine.Similarly, have 4 to 12 carbon and 0 and also strengthen the compatibility of this class preparation to the ether amines of about 5 EO groups and corresponding quaternary ammonium compound.In one embodiment, the compound that strengthens the compatibility of this class surfactant comprises amine or the quaternary ammonium salt with following formula:

Or

Or

Or

R wherein ¹Be to have about 4 straight or branched alkyl or aryls to about 16 carbon atoms; R ²Be hydrogen, methyl, ethyl or-(CH ₂CH ₂O) _xH, R ³Be hydrogen, methyl, ethyl or-(CH ₂CH ₂O) _yH, wherein x and y sum are no more than about 5; R ⁴Be hydrogen or methyl; R ⁶At each n (R ⁶O) in the group be C independently ₂-C ₄Alkylidene; R ⁵Be to have 2 to the alkylene of about 6 carbon atoms or the alkylene of replacement; A-is that agricultural goes up acceptable anion.

The present invention also provides herbicidal methods, comprises the composition that this paper provided with the water dilution weeding effective volume of proper volume, forms and uses composition, again this is used composition and is applied to plant leaf blade.

Definition

Term used herein " hydrocarbon " and " alkyl " are described organic compound or the group of only being made up of elemental carbon and hydrogen.These parts comprise alkyl, thiazolinyl, alkynyl and aryl moiety.These parts also comprise by alkyl, thiazolinyl, alkynyl and the aryl moiety of other aliphatic series or the replacement of cyclic hydrocarbon group, for example alkylaryl, alkenyl aryl and alkynyl aryl.Unless otherwise specified, these parts preferably comprise 1 to 30 carbon atom.

The group that is connected with other atomic groups at two end in the organic compound described in term used herein " alkylene ", only is made up of elemental carbon and hydrogen.These parts comprise alkylidene, alkenylene, alkynylene and arlydene part.These parts also comprise by alkyl, thiazolinyl, alkynyl and the aryl moiety of other aliphatic series or the replacement of cyclic hydrocarbon group, for example alkylaryl, alkenyl aryl and alkynyl aryl.Unless otherwise specified, these parts preferably comprise 1 to 30 carbon atom.

" alkyl of replacement " described herein part is by the hydrocarbyl portion that the atom beyond at least one de-carbon replaces, and comprises the part that carbochain atom is wherein replaced by hetero atom, and hetero atom is nitrogen, oxygen, silicon, phosphorus, boron, sulphur and halogen atom for example.These substituting groups comprise hydroxyl, ketal, acyl group, acyloxy, nitro, amino, acylamino-, cyano group, mercaptan, acetal, sulfoxide, ester, thioester, ether, thioether, hydroxy alkyl, urea, guanidine, amidine, phosphate, amine oxide and the quaternary ammonium salt of halogen, heterocycle, alkoxyl, alkene oxygen base, alkynyloxy group, aryloxy group, hydroxyl, protection.

" alkylene of replacement " described herein part is by the alkylene part that the atom beyond at least one de-carbon replaces, and comprises the part that carbochain atom is wherein replaced by hetero atom, and hetero atom is nitrogen, oxygen, silicon, phosphorus, boron, sulphur and halogen atom for example.These substituting groups comprise hydroxyl, ketal, acyl group, acyloxy, nitro, amino, acylamino-, cyano group, mercaptan, acetal, sulfoxide, ester, thioester, ether, thioether, hydroxy alkyl, urea, guanidine, amidine, phosphate, amine oxide and the quaternary ammonium salt of halogen, heterocycle, alkoxyl, alkene oxygen base, alkynyloxy group, aryloxy group, hydroxyl, protection.

Unless otherwise specified, alkyl described herein is preferably and contains 1 to 18 carbon atom and the low alkyl group of 30 carbon atoms at the most in main chain.They can be straight or branched or ring-type, comprise methyl, ethyl, propyl group, isopropyl, normal-butyl, isobutyl group, hexyl, 2-ethylhexyl etc.

Unless otherwise specified, thiazolinyl described herein is preferably and contains 2 to 18 carbon atoms and the low-grade alkenyl of 30 carbon atoms at the most in main chain.They can be straight or branched or ring-type, comprise vinyl, acrylic, isopropenyl, cyclobutenyl, isobutenyl, hexenyl etc.

Unless otherwise specified, alkynyl described herein is preferably and contains 2 to 18 carbon atoms and the low-grade alkynyl of 30 carbon atoms at the most in main chain.They can be straight or brancheds, comprise acetenyl, propinyl, butynyl, isobutyl alkynyl, hexin base etc.

This paper represents optional substituted carbocyclic aromatic group separately or as the used term " aryl " of another group part, preferred monocycle or bicyclic groups, in loop section, contain 6 to 12 carbon, for example naphthyls of the xenyl of the phenyl of phenyl, xenyl, naphthyl, replacement, replacement or replacement.The phenyl of phenyl and replacement is preferred aryl.

Term used herein " aralkyl " expression contains the group of alkyl and aryl structure, for example benzyl.

Alkyl used herein, thiazolinyl, alkynyl, aryl and aralkyl can be replaced by the atom beyond at least one de-carbon, comprise the part that carbochain atom is wherein replaced by hetero atom, and hetero atom is nitrogen, oxygen, silicon, phosphorus, boron, sulphur or halogen atom for example.These substituting groups comprise hydroxyl, nitro, amino, acylamino-, cyano group, sulfoxide, mercaptan, thioester, thioether, ester and ether, or any other can increase surfactant compatibility and/or its effect and does not influence the substituting group of preparation stored stability in the glyphosate potassium preparation.

This paper represents chlorine, bromine, fluorine and iodine separately or as another group part used term " halogen " or " halo ".Fluoro substituents often is preferred in surfactant compounds.

Unless otherwise specified, term " hydroxy alkyl " comprises the alkyl that is replaced by at least one hydroxyl, comprises two (hydroxy alkyl) alkyl, three (hydroxy alkyl) alkyl and many (hydroxy alkyl) alkyl.Preferred hydroxy alkyl comprises methylol (CH ₂OH), ethoxy (C ₂H ₄OH), two (methylol) methyl (CH (CH ₂OH) ₂) and three (methylol) methyl (C (CH ₂OH) ₃).

Used term " ring-type " expression has the group of at least one closed hoop to this paper separately or as another group part, comprises alicyclic, aromatics (aromatic hydrocarbons) and heterocyclic group.

This paper separately or as optional substituted, fully saturated or undersaturated, monocycle of the used term " heterocycle " of another group part or " heterocycle " expression or two rings, aromatics or non-aromatic group, in at least one ring, has at least one hetero atom, preferred 5 or 6 atoms of every ring.Heterocyclic group preferably has 1 or 2 oxygen atom, 1 or 2 sulphur atom and/or 1 to 4 nitrogen-atoms in ring, and can pass through carbon or hetero atom and molecule remainder bonding.Exemplary heterocycle comprises heteroaryl, for example furyl, thienyl, pyridine radicals, oxazolyl, pyrrole radicals, indyl, quinolyl or isoquinolyl etc., and non-aromatic heterocycle, for example tetrahydrofuran base, tetrahydro-thienyl, piperidyl, pyrrolidinyl etc.Exemplary substituting group comprises one or more following groups: the hydroxyl of the alkyl of alkyl, replacement, ketone group, hydroxyl, protection, acyl group, acyloxy, alkoxyl, alkene oxygen base, alkynyloxy group, aryloxy group, halogen, acylamino-, amino, nitro, cyano group, mercaptan, thioester, thioether, ketal, acetal, ester and ether.

This paper represents optional substituted aromatic group separately or as the used term " heteroaryl " of another group part, has at least one hetero atom, preferred 5 or 6 atoms of every ring at least one ring.Heteroaromatic group preferably has 1 or 2 oxygen atom, 1 or 2 sulphur atom and/or 1 to 4 nitrogen-atoms in ring, and can pass through carbon or hetero atom and molecule remainder bonding.Exemplary heteroaryl comprises furyl, thienyl, pyridine radicals, oxazolyl, pyrrole radicals, indyl, quinolyl or isoquinolyl etc.Exemplary substituting group comprises one or more following groups: the hydroxyl of the alkyl of alkyl, replacement, ketone group, hydroxyl, protection, acyl group, acyloxy, alkoxyl, alkene oxygen base, alkynyloxy group, aryloxy group, halogen, acylamino-, amino, nitro, cyano group, mercaptan, thioester, thioether, ketal, acetal, ester and ether.

This paper separately or as another group part used term " acyl group " expression from the group-COOH of organic carboxyl acid, remove the formed part of hydroxyl, for example RC (O)-, wherein R is R ¹, R ¹O-, R ¹R ²N-or R ¹S-, R ¹Be the alkyl or the heterocycle of alkyl, replacement, R ²It is the alkyl of hydrogen, alkyl or replacement.

(wherein R is defined as term " acyl group " to this paper for O-) the above-mentioned acyl group of bonding, RC (O) O-for example separately or as the used logical peroxide bridge of term " acyloxy " expression of another group part.

Term " agricultural chemicals " comprises chemicals and the microorganism reagent as product active ingredient, and this product is used for controlling the insect of crops and meadow insect and disease, animal ectoparasite and other public health.This term also comprises plant growth regulator, exterminator, synergist, herbicide-safener (reducing the phytotoxicity of weed killer herbicide to crop plants) and preservative, they to the release of target can expose skin, especially part tissue of eye is in agricultural chemicals.This exposure can be by agricultural chemicals from releasing device to carrying out the applications of pesticide or being positioned at the drift of the personnel using near and causing.

When this paper quotes maximum or minimum " mean " about architectural feature, for example oxygen alkylidene unit or glycoside units, it will be changed usually within the specific limits by the integer that those skilled in the art be interpreted as this class unit in the surfactant formulations individual molecule, and it can comprise greater than maximum or less than the integer of minimum " mean ".Single surfactant molecule the existence in composition of this class unit integer beyond described " mean " scope do not got rid of composition outside scope of the present invention, as long as " mean " in described scope, and satisfies other requirements and gets final product.

As mentioned above, the concentrated aqueous solution of glyphosate potassium has been found that and has especially high proportion.For example, table 1 is relatively about glyphosate potassium and the organic ammonium present or listing in the past and the measured proportion of 30 weight % glyphosate a.e. solution of other salt.Proportion utilizes MettlerDA-300 density/specific gravity instrumentation amount.

The proportion (20/15.6 ℃) of table 1:30 weight %a.e. glyphosate monobasic salting liquid

Salt	Proportion
Salt	Proportion	Potassium	1.2539
Monoethanol ammonium (MEA)	1.2357	Potassium	1.2539
Monoethanol ammonium (MEA)	1.2357	Different third ammonium (IPA)	1.1554
Positive third ammonium	1.1429	Different third ammonium (IPA)	1.1554
Positive third ammonium	1.1429	The first ammonium	1.1667
The second ammonium	1.1599	The first ammonium	1.1667
The second ammonium	1.1599	Ammonium	1.1814
Trimethylsulfonium (TMS)	1.1904	Ammonium	1.1814

Therefore, 1 liter of 30 weight %a.e. glyphosate potassium salting liquid contains about 376g glyphosate a.e./l under 20 ℃, and 1 liter of 30 weight %a.e. glyphosate IPA salting liquid contains about 347g glyphosate a.e./l under 20 ℃.In other words, under the a.e. weight concentration that equates, every liter of about 8% glyphosate a.e. of the many releases of potassium salt soln.

The high specific gravity of potassium salt soln is a particular importance in containing the solution of surfactant, and wherein maximum glyphosate concentration not only is confined to the limit of the solvability of sylvite in water, and is confined to the limit of surfactant compatibility.In this class solution, the advantage of sylvite can mean that (a) is in the presence of identical compatible surfactants, under similar face activating agent percent concentration, reach the maximum glyphosate a.e. concentration higher than IPA salt, (b) under the given concentration of glyphosate a.e. and surfactant, reach than the better bin stability of corresponding composition with the preparation of IPA salt, and/or (c) under the given concentration of glyphosate a.e. and surfactant, reach than better the toppling over and pumping character of corresponding composition with the preparation of IPA salt.

The advantage of the present composition reduces and reduces along with glyphosate concentration, and being lower than in glyphosate concentration only has bottom line under about 360g a.e./l, just be lower than the concentration of being found in this class commodity glyphosate IPA product salt, for example

Weed killer herbicide.In the preferred present composition, glyphosate concentration is not less than 400g a.e./l or about 420g a.e./l, is not less than about 440,460 or 480g a.e./l in particularly preferred composition, and for example about 480 to about 540g a.e./l.The upper limit that it is believed that glyphosate concentration in the composition that contains surfactant of stable storage of the present invention surpasses about 650g a.e./l, and this limit is the result of the solubility limit of glyphosate potassium in water, further is subjected to the restriction of the existence of surfactant.

Expection is more near this glyphosate upper limit of concentration, the amount of the surfactant that can hold few more.In some cases, low quantity of surfactant may be not suitable for strengthening reliably the weeding effect of glyphosate to acceptable degree.But, in the using of some specific purposes, composition be will be with relatively small amount water-reducible, the volume for example about 10 that is used for plant treatment is to about 50l/ha, the surfactant concentration in the concentrate composition of the present invention can hang down and reach about 20g/l at this moment.These class specific purposes are used and are comprised that (rope-wick) used in wicking, the control drop is used and ultralow volume aerial spraying.Use about general objects, spraying to about 400l/ha water dilution back with about 50 to about 1000l/ha, the most about 100 usually, the surfactant concentration in the concentrate composition of the present invention preferably about 60 is to about 300g/l, and more preferably from about 60 to 200g/l/

Herbicidal formulations of the present invention comprises the combination of at least a surfactant and glyphosate or its salt or ester, in prepared the using of preparation or dilute with water preparation after mixture is applied to plant, go up at plant leaf blade (wax outside the cuticula) and to form the anisotropy aggregation that comprises surfactant.In some preparation of the present invention, surfactant and glyphosate or its salt or ester be combined in preparation or the prepared mixture of using of dilute with water preparation is applied to after the plant, go up to form the liquid crystal that comprises surfactant at plant leaf blade (wax outside the cuticula).In other preparations of the present invention, surfactant and glyphosate or its salt or ester be combined in preparation or the prepared mixture of using of dilute with water preparation is applied to after the plant, formation comprises the liquid crystal (outside the cuticula in wax and the cuticula liquid crystal) of surfactant on plant leaf blade and in the plant itself.In other preparations of the present invention, the herbicidal formulations that comprises the aqueous mixture that contains glyphosate or its salt or ester and surfactant contains the liquid crystal that comprises surfactant.

The salt form that is fit to according to the operable glyphosate of preparation of the present invention for example comprises alkali metal salt, for example sodium and sylvite, ammonium salt, di-ammonium salts, for example dimethylammonium, alkylamine salt, for example dimethylamine and isopropyl amine salt, alkanol amine salt, for example ethanolamine salt, alkyl sulfonium salt, for example trimethyl sulfonium salt, oxidation sulfonium salt and their mixture or combination.The extensive stock glyphosate formulation of being sold by MonsantoCorporation comprises ammonium salt, sodium salt and isopropyl amine salt so far.The glyphosate formulation of being sold by Zeneca has comprised the trimethyl sulfonium salt so far.Especially the glyphosate salt that is preferred for novel formulation of the present invention comprises sylvite, isopropyl amine salt, ammonium salt, di-ammonium salts, sodium salt, monoethanolamine salt and trimethyl sulfonium salt.Sylvite, sodium salt, ammonium salt and di-ammonium salts are preferred, because the preparation of these glyphosate salts most possibly forms liquid crystal.

Except glyphosate or its salt or ester, herbicidal formulations of the present invention also comprises at least a surfactant.In one embodiment of the invention, the character of surfactant and the composition of herbicidal formulations are such, after mixture was applied to plant, (outside the cuticula) formed the anisotropy aggregation that comprises surfactant on vegetable wax shape cuticula in prepared the using of preparation or dilute with water preparation.These anisotropy aggregations form on plant leaf blade, with whether there being the second surface activating agent in the preparation have nothing to do.The anisotropy aggregation can be formed at immediately and be applied to after the plant leaf blade, perhaps can use the back along with the preparation of moisture from blade the evaporation and form.And then the anisotropy aggregation can also be formed in the concentrated herbicidal preparation.

In order to determine that whether the herbicidal formulations that comprises glyphosate or its salt or ester and surfactant forms the anisotropy aggregation that comprises surfactant on plant leaf blade, can adopt following birefringence test method.

At first, preparation wax is coated with slide.The wax that is preferred for preparing slide is the mixture of Brazil wax and beeswax, and w/w was than about 10: 1.The wax mixture of preparation clarification is made up of about 5% Brazil wax and about 0.5% beeswax in isopropyl alcohol, remains under about 82 ℃ temperature.With terminal vertical the immersion in the wax mixture of glass 2.4cmx7.2cm microslide, the degree of depth is approximately 1/3rd of slide length.After about 10 to 15 seconds, from wax mixture, slowly and stably extract slide out, cooling, deposition one deck wax on the two sides of slide.

The visual inspection slide obtains thickness and inhomogeneity Preliminary study to the wax clothing.If flaw is obvious, repel such slide so.Do not have tangible flaw if slide shows,, remove the dewax clothing carefully with the one side of acetone wiping slide.At the test under microscope slide, further checkout facility is coated with the acceptability of slide with wax.If utilize the 4.9x object lens to carry out microexamination, wax clothing thickness is even, and the slide grain density of waxing is even, selects such slide to be used for test so.Preferred such wax clothing does not almost have observable Wax particles, and the very dark visual field of performance when checking under polarised light.

The next stage of method is to test.For this reason, if necessary, the Gyphosate herbicice preparation sample that will contain one or more surfactants is diluted to the glyphosate equivalent of 15% to 20% weight.The preparation sample for reference is made up of the aqueous solution of 41 weight % glyphosate IPA salt.

Test method needs or can adopt following instrumentation or project of equal value:

Nikon SMZ-10A stereoscope is used for polarised light observation, microphotograph and video and observes and record.

3CCD MTI camera.

Diagnostic Instruments 150 IL-PS power supplys.

Sony Trinitron color video monitor, the PVM-1353MD type.

The long-time video boxlike of Mitsubishi video camera, the HS-S5600 type.

Hewlett Packard Pavillion 7270 calculators are equipped with 2.0 editions electronic imaging programs of Windows 95 and Image-Pro Plus.

Hewlett Packard Deskjet 870Cse printer.

About test, the wax for preparing as mentioned above and select is coated with slide is positioned on the microscope stage, system is set, so that the transmitted light of straight line and polarization to be provided.Utilizing fully, 1 microlitre Hamilton syringe of cleaning originally is applied to the wax surface with 1 microlitre for sample.This step operation and operation subsequently all utilize microscope to carry out under the 4.9x object lens.Every kind of composition all carries out duplicate or in triplicate test.On single slide, can test in a large number simultaneously.Utilize the progress of microscopic examination sample microscope appearance change, by fixed time interval record.Useful is at interval had been applied to the wax surface back 1 minute, 10 minutes, 2 hours and greater than 24 hours.Also observe at interlude, to catch the remarkable transformation that may in these times, take place.

Along with the time lengthening that is exposed to microscope light, the temperature of wax layer is tending towards increasing.Under many circumstances, determined that this can significantly not disturb the gained result.But in some cases, temperature does not influence the result of test, under these circumstances, preferably only observes and necessaryly illuminates in short-term, so that the temperature of wax layer still approaches environmental temperature.

In each time interval, (polarised light) observes the birefringence of wax layer under the dark visual field, the feature of observing the point sample surface under the bright visual field.Preferably carry out following record:

Birefringence (y/n);

The time of initial birefringence outward appearance;

Birefringent feature;

" do " outward appearance on composition point sample surface;

The degree of drop diffusion;

Temperature Influence (slide intensification), if any;

Other noticeable variations.

Alternatively, utilize 3CCD MTI camera and Image-Pro Plus program at significant time card record image, as the document of viewed variation.If necessary, can also on video, write down test, especially in preceding 15 minutes.Except utilizing the image that the 4.9x object lens are caught, can also utilize 0.75 object lens to write down full cyclogram, clearly to contrast the different samples of on same slide, testing.The parameter that is particularly useful for observing the anisotropy aggregation is that experimental liquid drops in wax and is coated with the birefringence (y/n) of deposition back in the time of 5-20 minute on the slide.

The herbicidal formulations of the present invention that forms the outer anisotropy aggregation of cuticula has the performance that is better than present available herbicidal formulations basically.What be not subjected to particular theory restriction is, it is believed that the outer anisotropy aggregation of cuticula can produce or enlarges the hydrophilic channel that passes the outer wax shape surface of the cuticular cuticula of plant.The mass transfer that the cuticula passage can promote glyphosate of striding of passing wax shape surface that these produced or enlarged is more promptly passed the outer wax of the cuticular cuticula of plant and is entered plant than the system that does not have the anisotropy aggregation.Believe that further most of anisotropy aggregations of being present on the cuticula outer surface exist with the form of non-simple micella, for example bilayer or sandwich construction, because they are tending towards forming labyrinth, for example cylinder, discotic or banded structure." great majority " mean that the surfactant that surpasses 50 weight % exists with the complicated aggregate form of non-simple micella.Preferably, the surfactant that surpasses 75 weight % exists with the complicated aggregate form of non-simple micella.The diameter of anisotropy aggregation of the present invention is usually at least about 20 nanometers, preferably at least about 30 nanometers.

Formation about the anisotropy aggregation that in the presence of glyphosate, comprises surfactant, critical packing parameter (P) may be important aspect, it is defined as P=V/IA, wherein V is the volume of molecule hydrophobicity afterbody, I is the effective length of hydrophobicity afterbody, and A is by the occupied area of hydrophilic head base.The critical packing parameter that it is believed that the amphiphilic species that can be used for forming the anisotropy aggregation approximately about 1/3.

In preferred embodiment, the anisotropy aggregation forms on the wax outside the cuticular cuticula of plant, and the surfactant that comprises the anisotropy aggregation is the amphiphilic species that comprises the compound with cationic head base and hydrophobicity afterbody.What be not subjected to the particular theory restriction is to it is believed that cation group strengthens the adhesion of initial and leaf surface, because negative electrical charge is carried on this class surface of great majority in general.And then, it is believed that cation group helps in the outer wax of cuticula the hydrophily of striding the cuticula passage by surfactant of the present invention formed or enlarged.Cation group attracts hydrone, and the latter further enlarges hydrophilic pathway, thereby improves the path that glyphosate enters, because glyphosate is a polarity.

The surfactant that effectively forms the anisotropy aggregation in the presence of glyphosate comprises nonionic, cation, anion and amphoteric surfactant and composition thereof.

Above-mentioned surfactant mixtures also effectively forms the anisotropy aggregation.Preferred mixture comprises alcohol alcoxylates non-ionic surface active agent and dialkoxy quaternary ammonium, monoalkoxy quaternary ammonium, quaternary ammonium, dialkoxy amine, diamines or alkyl choline halide (for example lauryl chlorination choline) cationic surfactant.Other preferred mixtures contain: phosphatide amphoteric surfactant and dialkoxy amine or dialkoxy quaternary ammonium cation surfactant, fluoridize quaternary surfactant, for example Fluorad ^TM754, or the alcohol alcoxylates non-ionic surface active agent; Or carboxylic anionic surfactant and dialkoxy amine cationic surfactant.The preferred mixture examples of this class comprises Hetoxol ^TMCS-20 is (from the PEG 20C of Heterene ₁₆-C ₁₈Pure) and Ethomeen ^TMT/20 (from the 10EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/25 (from the 15EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-25 is (from PEG 25 C of Heterene ₁₆-C ₁₈Pure) and Ethomeen ^TMT/20, Hetoxol ^TMCS-25 and Ethomeen ^TMT/25, Brij ^TM78 (from PEG 20 C of SigmaChemical Company ₁₈Pure) and Ethomeen ^TMT/20, Brij ^TM78 and Ethomeen ^TMT/25, Brij ^TM78 and Ethoquad ^TMT/20 (from the PEG 10 butter ammonio methacrylates of Akzo Nobel), Brij ^TM78 and Ethoqua ^TMT/25 (from the PEG 15 butter ammonio methacrylates of AkzoNobel), Plurafac ^TMA38 is (from the PEG27 C of Basf ₁₆-C ₁₈Pure) and Ethomeen ^TMT/20, Plurafac ^TMA38 and Ethomeen ^TMT/25, Plurafac ^TMA38 and Ethoquad ^TMT/20, Plurafac ^TMA38 and Ethoquad ^TMT/25, ST 8303 are (from PEG 14 C of Cognis ₁₆Pure) and Ethoquad ^TMT/25, Arosurf ^TM66 E10 are (from the PEG 10 different C of Witco/Crompton ₁₈Pure) and Ethoquad ^TMT/25, Arosurf ^TM66 E20 are (from the PEG 20 different C of Witco/Crompton ₁₈Pure) and Ethoquad ^TMT/25, Arosurf ^TM66 E20 and Ethomeen ^TMT/25, Hetoxol ^TMCS-20 and Ethomeen ^TMT/15 (from the 5EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/30 (from the 20EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/35 (from the 25EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/40 (from the 30EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Trymeen ^TM6617 (from PEG 50 stearylamines of Cognis), Hetoxol ^TMCS-15 is (from PEG 15 C of Heterene ₁₆-C ₁₈Pure) and Ethomeen ^TMT/25, Hetoxol ^TMCS-20 and PEG 22 dimethyl chlorination quaternary ammoniums, Hetoxol ^TMCS-20 and lecithin, Hetoxo ^TMCS-25 and lecithin, Hetoxol ^TMCS-20 and Arquad ^TMC-50 (from the Dodecyl trimethyl ammonium chloride of Akzo Nobel), Hetoxol ^TMCS-20 and lauryl chlorination choline, Hetoxol ^TMCS-15 and lauryl chlorination choline, Procol ^TMLA 15 is (from PEG 15 C of Protameen ₁₂Pure) and Ethoqua ^TMT/25, Hetoxol ^TMCS-20 and PEG 7 dimethyl chlorination quaternary ammoniums, Hetoxol ^TMCS-20 and Gemini ^TM10-2-10 is (from the C of Monsanto ₁₀Ethylidene N-methanediamine), Hetoxol ^TMCS-20 and Gemini ^TM10-3-10 is (from the C of Monsanto ₁₀Propylidene N-methanediamine), Hetoxol ^TMCS-20 and Gemini ^TM10-4-10 is (from the C of Monsanto ₁₀Butylidene N-methanediamine), Hetoxol ^TMCS-20 and Gemin ^TM14-2-14 is (from the C of Monsanto ₁₄Ethylidene N-methanediamine), Hetoxol ^TMCS-20 and Gemini ^TM14-3-14 is (from the C of Monsanto ₁₄Propylidene N-methanediamine), palmitic acid and Ethomeen ^TMT/25, lecithin and Ethomeen ^TMT/25, lecithin and Ethoqua ^TMT/25, lecithin and Ethomeen ^TMT/20, lecithin and Ethoqua ^TMT/20 and lecithin and Fluorad ^TMFC 754 (from the fluorinated alkyl chlorination quaternary ammonium of 3M).Said mixture is synergitic a bit, that is to say that they are surfactant mixtures, when routine tests, does not form the anisotropy aggregation.

The herbicidal formulations of the present invention that comprises glyphosate and form the surfactant of anisotropy aggregation on wax shape plant surface can be made into the water-based concentrate formulation, comprise at least about 50g glyphosate a.e./L, more preferably at least about 250g glyphosate a.e./L, and then more preferably at least about 300,360,380,400,440,480,500,540 or 600g glyphosate a.e./L.A kind of example that preferred water-based concentrates glyphosate formulation contains glyphosate isopropyl amine or the sylvite of the 360g glyphosate a.e./L that has an appointment, perhaps approximates greatly at present by Monsanto Corporation at its commodity Used level in the herbicide formulations.Another kind of preferred water-based concentrates glyphosate formulation and contains have an appointment 300 to about 600 glyphosate a.e./L glyphosate isopropyl amine or sylvite, and preferred about 400 to about 600, about 440 to about 600, about 440 to about 480, about 480 to about 600 or about 480 to about 540g glyphosate a.e./L.

On weight basis, the glyphosate concentration that is included on the cuticula surface the stable water-based concentrate composition of the present invention of the surfactant that forms the anisotropy aggregation can be at least about 35,40,41,42,43,44,45,46,47,48,49 or 50%a.i..Especially for glyphosate potassium, preferred concentration be about 35 to about 50%a.e., about 40 to about 50%a.i., about 45 to about 50%a.i. or more than.

In another embodiment, the concentrate formulation that forms the anisotropy aggregation on vegetable wax shape surface can be dry preparation, and it can be the form of pulvis, pilule, tablet or granule.Usually before use these drying agents are dispersed or dissolved in the water.Preferably, do not have basically that water insoluble active ingredient is present in this class preparation with suitable level, so that preparation is water miscible basically.Water-soluble or the water-dispersible preparation of drying of the present invention comprises about 20% usually to about 80% (weight) glyphosate a.e., and preferred about 50% to about 80% (weight) glyphosate a.e., and most preferably from about 60% to about 75% (weight) glyphosate a.e..

In drying agent of the present invention, glyphosate itself can provide carrier for other preparation compositions, and the other inert fraction that this class carrier is provided perhaps can be arranged.A kind of example according to the operable inert carrier composition of the present invention is an ammonium sulfate.Those skilled in the art will recognize that term used herein " drying " does not hint that drying agent of the present invention is 100% water-free.Usually, drying agent of the present invention comprises about 0.5% water to about 5% (weight).Drying agent preferably of the present invention contains the water less than about 1% (weight).

Can be prepared by any method known in the art according to the water-soluble of drying of the present invention or water-dispersible preparation, comprise atomized drying, fluidized bed agglomeration, disk granulation or extrude.In drying agent, glyphosate can be the form of salt or acid.The preparation that contains glyphosate can contain acid acceptor alternatively, and for example ammonium or alkali-metal carbonate or bicarbonate, ammonium dihydrogen phosphate (ADP) etc. are so that by after user's dissolving or being dispersed in the water, generate the water soluble salt of glyphosate.

Usually, the glyphosate concentration that directly is applied to easily the Herbicidal combinations of the present invention of blade can be from about 1 to every liter of about 40 gram acid equivalent, preferably from about 2 to every liter of about 18 gram acid equivalent, more preferably from about 4 to every liter of about 11 gram acid equivalent.Those skilled in the art will recognize that various factors can influence for reaching the ratio of using of the required glyphosate of required result.

In glyphosate formulation of the present invention, can use any suitable, activity of weeding enhancing amount, surfactant of on vegetable wax shape surface, comprising the anisotropy aggregation.Preferably, surfactant concentrates concentration in the glyphosate formulation from about 25 to about 250g/L in the present invention, more preferably from about 50 to about 200g/L.Although can mix the surfactant of higher concentration, but, generally be more suitable for using above-mentioned concentration range for economic reasons to glyphosate formulation of the present invention.The surfactant concentration that directly is applied to the herbicidal formulations of the present invention of blade easily can be from about 0.1g/L to about 10g/L, preferably from about 1g/L to about 5g/L.

In some herbicidal formulations of the present invention, the character of surfactant and the composition of herbicidal formulations are such, after mixture is applied to plant, on plant leaf blade, form the liquid crystal (liquid crystal outside the cuticula) that comprises surfactant in prepared the using of preparation or dilute with water preparation.In other words, the hydrophilic pathway of the outer wax of the cuticular cuticula of plant is passed in liquid crystal generation or the expansion that comprises surfactant.The key character of herbicidal formulations of the present invention is in the presence of glyphosate, and surfactant can form liquid crystal on the substrate of wax shape porous, for example leaf cuticle, pass the cuticular cuticula hydrophilic pathway of striding of wax shape outward to be created in cuticula.The prominent features that comprises the surfactant of liquid crystal in the presence of glyphosate is the trend that surfactant molecule is arranged along common axis with orderly fashion.Usually, the order degree of liquid crystal is higher than isotropic aqueous solution, flows than solid crystal is easier.Flow of liquid crystal may be important factor in the transposition in plant improving glyphosate.

Discussed in this articlely in the presence of glyphosate, in concentrated glyphosate solution, do not forming liquid crystal under the commercial concentration usually with a lot of surfactants that promote glyphosate transposition in plant foundation structure forming liquid crystal on the cuticula surface.Usually, these surfactants form liquid crystal in glyphosate/surfactant sediments that drying is sunk, and sediments is the dilution preparation is dripped or to be sprayed on the plant cuticula surface formed.As if what generally and not be subjected to particular theory restriction is, liquid crystal be there is no need with interior formation on plant surface is important or relevant (although may be helpful in some cases) in the formation of liquid crystal in concentrating glyphosate solution itself.Usually, the more important thing is that the liquid crystal of being made up of surfactant forms the sediments of dry sinking on leaf surface.But in some preparation, may not form liquid crystal in concentrated glyphosate/surfactant solution and on the leaf with in the spraying mixture interior but that do not diluting.

As noted earlier, the formation of liquid crystal outside cuticula may be applied to due to drying behind the plant sinks by the drop that contains glyphosate and surfactant.Some environmental factors, comprise temperature, humidity and wind speed can influence in plant with on how to form liquid crystal fast.In some cases, in fact liquid crystal may form because of main being separated of drop on the blade.Although surfactant cited herein forms liquid crystal in the presence of glyphosate, but it is believed that concerning surfactant molecule preferably molecular weight is less than about 2500.When the molecular weight of surfactant surpasses 2500, may still form liquid crystal, but not resemble the little molecular surface active agent in the transposition of glyphosate quite effectively and efficient.

The liquid crystal that comprises surfactant in the presence of the external glyphosate of cuticula is lyotropic liquid crystal (lyotropic liquid crystal) normally; The formation that is to say liquid crystal is subjected to inducing of solvent usually, is water in this case.Not only depend on solvent mutually in the middle of the liquid crystal, and depend on temperature.During formation strode that the lyotropic liquid crystal cuticula hydrophilic pathway, comprise surfactant in the presence of glyphosate has seen that hexagon forms, anti-hexagon formation and stratiform form with multilayer, the latter had at least about 20 to about 30 or above independently different layers.Lyotropic liquid crystal also might be a cube.And, observed the smectic of the liquid crystal of in the presence of glyphosate, forming and to the row form by surfactant.In herbicidal formulations of the present invention, whether irrelevant the existence of the formation of liquid crystal and second surface activating agent is.

And then some surfactant can form worm sample micella in the presence of glyphosate, and this is the systematism structure of another kind of liquid form, and it can promote the transposition of glyphosate, passes wax shape cuticula, enters plant.Worm sample micella still still has sufficient tissue usually not as the liquid crystal systematism, with interior formation hydrophilic pathway, promotes glyphosate in endophytic transposition on plant.Usually, the surfactant of enough " pliability " will form the worm sample micella of these types.

Is initial concentration in the drying sinking sediments of liquid crystal in order to measure glyphosate and surfactant in person's character, can utilize following test method.Experiment is carried out under 50% relative moisture and 24 ℃.According to the stripped cuticula of scheme preparation described herein.To contain a certain amount of glyphosate salt (for example potassium) and liquid crystal and form surfacant (C for example _16-181 microlitre drop of formation property of liquid crystal ether EO 15 dimethyl propylamines) glyphosate formulation places on the previously prepared stripped leaf cuticle, observes birefringent beginning under polarizing microscope.In independent experiment, check to show birefringent drop, confirm indicating characteristic liquid crystal pattern.

In case observe birefringent beginning, scrape off drop from cuticula as far as possible apace, be dissolved in 1ml 99.9% (nominal) D ₂O is transferred to 5mm NMR in vitro.The Varian Unity Inova 400MHz spectrometer that 5mmNalorac pulse sound probe is equipped with in utilization can obtain spectrum.For example, 30 degree pulses can be used to obtain to have the scintigram of suitable circulation timei.Can measure by integrating bimodal signal of glyphosate and water signal.

According to the method, having measured the concentration of glyphosate in these drops is 37% (+/-6%).But, it should be noted that the evaporation of water from drying sinking drop is quickish (in minute).Therefore, the possibility of result does not wait from 37% to 50%w/wt, depends on personnel's the technical ability of carrying out being transferred to from cuticula the task of NMR test tube.

Whether on plant leaf blade, form the liquid crystal that comprises surfactant in order to measure the herbicidal formulations that comprises glyphosate or its salt or ester and surfactant, can utilize following high-resolution polarizing microscope birefringence test method.This high-resolution birefringence test can be distinguished formation and the characteristic micro-texture and the other types anisotropy aggregation or the solid crystal that are precipitated out owing to water evaporates of liquid crystalline phase from solution.Test method is as follows.

Before the birefringence test, the piemarker from be grown in the greenhouse (Abutilontheophrasti) SCD is used for test.Can be used in the cuticular other plant of supply test and comprise thorn bur, three leaf artemisiifolia and morning glories.For SCD, the stock solution of preparation glacial acetic acid and sodium acetate.The concentration of glacial acetic acid stock solution is about 1 between about 5% (w/w), the concentration of sodium acetate stock solution about 1 between about 5% (w/w).Stock solution is mixed, form buffer solution, pH from about 4.2 to about 4.6.

Behind the preparation buffer solution, the preparation enzyme solutions.Usually, enzyme solutions is to prepare in cuticula separates or in very approaching, to reach maximum validity.Enzyme solutions is like this preparation, in water, add about 1 to about 5% (w/w) pectase and about 0.1 to about 0.5% (w/w) cellulase.Usually, pectase has the activity of 3600 units/gram, and cellulase has the activity of about 10,600 units/gram.Standby or the storage with the aseptic diafiltration of enzyme solutions then.

Get the healthy leaf of source plant, with fine extra large sand milling rubdown face.Then leaf is used the as above buffer solution cleaning down of preparation, the healthy part of excision leaf is used for cuticula and separates.Use the enzyme solutions of prepared fresh to soak into the cut-out of leaf, to about 35 ℃ temperature, kept about 1 hour, perhaps break away from from leaf texture's substrate until leaf cuticle at about 30 ℃.After the disengaging, take out cuticula carefully the solution, use the deionized water cleaning down, be stored in about 4 to 6 the buffer solution of pH from buffering, place humidity about 30% to about 75%, temperature about 20 is standby to about 30 ℃ environment.Usually, cuticula is stored in the environment of controlled condition at least about 24 hours, so that reach balance with its environment.

Behind the SCD, be used for test, whether the specific herbicidal formulations that contains glyphosate and surfactant with mensuration forms the liquid crystal that comprises surfactant on wax shape cuticula.Cuticula is transferred to slide, in test under microscope (not having any polarised light) crack and other damages.If on the cuticula surface, identify crack or other damages, give it up so.In case observe suitable cuticula, further having inspection under the microscope of polarised light (7.5x magnifying power), to confirm to observe the dark visual field.If on the cuticula surface, record small size crystallinity wax, cautiously abstain these zones at duration of test so.

After observing cuticular defective, slide is connected with heating/cooling circuit, the latter can regulate the temperature of glass plate at duration of test.To glass plate heating, make 15 ℃ of cuticula and glass plates extremely about 35 ℃ temperature reach balance.After reaching balance, the sample of preparation test solution.Sample can be dilution or concentrated form, but preferably sample is the form of dilution, so that for the glyphosate concentration (a.e.) of sample in this about 1% to the scope of about 10% (w/w), the ratio of glyphosate and surfactant about 1: 1 to the scope of about 10: 1 (w/w), preferred about 3: 1 (w/w).A water is originally placed on the cuticula for sample, pass under the cuticular polarised light (7.5x magnifying power) in emission and observe.Utilize the image of Flash Point 128 software records sample droplets on cuticula by the listed time interval, be stored in calculator that video-frequency monitor is connected in.Utilize the Image Pro of Media Cybernetics to make image digitazation then.

In each test, sample droplets is placed on two cuticula much at one in duplicate.If observe birefringence under the polarizing microscope of 7.5x magnifying power, so sample being transferred to immediately amplifying power is the polarizing microscope of 100x magnifying power to the 400x magnifying power.Utilize this microscope, under the 200x magnifying power, can see characteristic liquid crystal pattern, and distinguish over solid crystal or other birefringent materials.If observe liquid crystal under high x magnification, the sample preparation forms liquid crystal outside the cuticula on plant leaf blade so.

Form the outer herbicidal formulations of the present invention liquid crystal, that contain glyphosate or its salt or ester of cuticula and have the performance that is better than present available herbicidal formulations basically, also may be better than the simple herbicidal formulations that forms the anisotropy aggregation outside cuticula.As if what be not subjected to particular theory restriction is, the tectal hydrophilic pathway of blade wax shape is passed in the liquid crystal formation on partly and then formation or expansion the plant cuticula outside.The hydrophilic pathway that these produced or enlarged can pass wax shape cuticula from increasing the mass transfer of glyphosate basically, enters plant.

The surfactant that effectively forms liquid crystal outside the cuticula in the presence of glyphosate comprises nonionic, cation, anion and amphoteric surfactant and composition thereof.

Above-mentioned surfactant mixtures also effectively forms the outer liquid crystal of cuticula.Preferred mixture comprises alcohol alcoxylates non-ionic surface active agent and dialkoxy quaternary ammonium, monoalkoxy quaternary ammonium or dialkoxy amine cationic surfactant.Other preferred mixtures contain: phosphatide amphoteric surfactant and alcohol alcoxylates non-ionic surface active agent.The preferred mixture examples of this class comprises Hetoxol ^TMCS-20 is (from PEG 20 C of Heterene ₁₆-C ₁₈Pure) and Ethomeen ^TMT/20 (from the 10EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/25 (from the 15EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-25 is (from PEG 25 C of Heterene ₁₆-C ₁₈Pure) and Ethomeen ^TMT/20, Hetoxol ^TMCS-25 and Ethomeen ^TMT/25, Brij ^TM78 (from PEG 20 C of Sigma Chemical Company ₁₈Pure) and Ethomeen ^TMT/20, Brij ^TM78 and Ethomeen ^TMT/25, Bri ^TM78 and Ethoquad ^TMT/20 (from the PEG 10 butter ammonio methacrylates of Akzo Nobel), Brij ^TM78 and Ethoquad ^TMT/25 (from the PEG 15 butter ammonio methacrylates of Akzo Nobel), Plurafac ^TMA38 is (from PEG 27 C of Basf ₁₆-C ₁₈Pure) and Ethomeen ^TMT/20, Plurafac ^TMA38 and Ethomeen ^TMT/25, Plurafac ^TMA38 and Ethoquad ^TMT/20, Plurafac ^TMA38 and Ethoquad ^TMT/25, ST 8303 are (from PEG 14 C of Cognis ₁₆Pure) and Ethoquad ^TMT/25, Arosurf ^TM66 E10 are (from the PEG 10 different C of Witco/Crompton ₁₈Pure) and Ethoquad ^TMT/25, Arosurf ^TM66 E20 are (from the PEG 20 different C of Witco/Crompton ₁₈Pure) and Ethoquad ^TMT/25, Arosurf ^TM66 E20 and Ethomeen ^TMT/25, Hetoxol ^TMCS-20 and Ethomeen ^TMT/15 (from the 5EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/30 (from the 20EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/35 (from the 25EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Ethomeen ^TMT/40 (from the 30EO beef tallow amine of Akzo Nobel), Hetoxol ^TMCS-20 and Trymeen ^TM6617 (from PEG 50 stearylamines of Cognis), Hetoxol ^TMCS-15 is (from PEG 15 C of Heterene ₁₆-C ₁₈Pure) and Ethomeen ^TMT/25, Hetoxol ^TMCS-20 and PEG 22 dimethyl chlorination quaternary ammoniums, Hetoxol ^TMCS-20 and lecithin, Hetoxol ^TMCS-25 and lecithin.Said mixture is synergitic a bit, that is to say that they are surfactant mixtures, when routine tests, does not form the outer liquid crystal of anisotropy aggregation and/or cuticula.

In some herbicidal formulations of the present invention, the character of surfactant and the composition of herbicidal formulations are such, in prepared the using of preparation or dilute with water preparation after mixture is applied to plant, form the liquid crystal that comprises surfactant (outside the cuticula in liquid crystal and the cuticula liquid crystal) on plant leaf blade and in the plant leaf blade.In other words, comprise the liquid crystal generation of surfactant or enlarge the hydrophilic pathway that passes the outer wax of the cuticular cuticula of plant, also form the path of going deep into inside plants at inside plants (in the cuticula), it can significantly strengthen the transposition of glyphosate by the plant path.These stride the cuticula path can be responsible for increasing the effect that is provided by this class preparation.The key character that forms the outer herbicidal formulations of the present invention with the interior liquid crystal of cuticula of cuticula is that surfactant can be on plant and interior formation liquid crystal.

Discussed in this articlely in the presence of glyphosate, in concentrated glyphosate solution, do not forming liquid crystal under the commercial concentration usually with a lot of surfactants that promote glyphosate transposition in plant foundation structure forming liquid crystal with inside plants on the cuticula surface.Usually, these surfactants form liquid crystal in glyphosate/surfactant sediments that drying is sunk, and sediments is the dilution preparation is dripped or to be sprayed on the plant cuticula surface formed.As if what generally and not be subjected to particular theory restriction is, liquid crystal be there is no need with interior formation on plant surface is important or relevant (although may be helpful in some cases) in the formation of liquid crystal in concentrating glyphosate solution itself.Usually, the more important thing is that the liquid crystal of being made up of surfactant forms the sediments of dry sinking on leaf surface.But in some preparation, may not form liquid crystal in concentrated glyphosate/surfactant solution and on the leaf with in the spraying mixture interior but that do not diluting.

As noted earlier, liquid crystal outside cuticula with cuticula in formation may be applied to due to the drying sinking behind the plant by the drop that contains glyphosate and surfactant.Some environmental factors, comprise temperature, humidity and wind speed can influence in plant with on how to form liquid crystal fast.In some cases, in fact liquid crystal may form because of main being separated of drop on the blade.Although surfactant cited herein forms liquid crystal in the presence of glyphosate, but it is believed that concerning surfactant molecule preferably molecular weight is less than about 2500.When the molecular weight of surfactant surpasses 2500, may be still in plant with on form liquid crystal, but do not resemble the little molecular surface active agent in the transposition of glyphosate quite effectively and efficient.

Outside cuticula with cuticula in the presence of glyphosate, comprise surfactant liquid crystal lyotropic liquid crystal normally; The formation that is to say liquid crystal is subjected to inducing of solvent, for example water usually.Not only depend on solvent mutually in the middle of the liquid crystal, and depend on temperature.Outside cuticula with cuticula in the presence of glyphosate, comprise surfactant lyotropic liquid crystal seen that cube forms, hexagon forms, during anti-hexagon formation and stratiform form with multilayer, the latter have at least about 20 to about 30 or above independently layer.And, outside cuticula and in the cuticula, observed the smectic of the liquid crystal of in the presence of glyphosate, forming and to the row form by surfactant.In herbicidal formulations of the present invention, form in the presence of glyphosate whether the existence of liquid crystal and second surface activating agent has nothing to do in the cuticula comprise surfactant and the cuticula.

Comprising glyphosate and forming in some preparation of the present invention of the surfactant of liquid crystal in the outer and cuticula of cuticula, liquid crystal comprises the tier array of surfactant molecule, so that the surfactant molecule hydrophilic parts in one deck tier array is oriented to the surfactant molecule hydrophilic parts in second layer tier array.Cuticula of the present invention outer with cuticula in liquid crystal can form such tier array, can have in a large number as discussed above layer.

Comprising glyphosate and forming in some preparation of the present invention of the surfactant of liquid crystal in the outer and cuticula of cuticula, liquid crystal can be in tier array self orientation so that the hydrophobic surface on the plant leaf blade of the surfactant molecule hydrophilic parts in one deck tier array and administered formulation contacts.And then the surfactant molecule of one deck tier array can contact with the hydrophobic surface of the plant cuticula that is positioned at administered formulation.

And then some surfactant can form worm sample micella in the presence of glyphosate, and this is the systematism structure of another kind of liquid form, it can be outside cuticula and cuticula in promote the transposition of glyphosate, pass wax shape cuticula, enter and spread all over plant.Worm sample micella is usually not as the liquid crystal systematism, but still has sufficient tissue, on plant with interior formation hydrophilic pathway, promote glyphosate in plant with the introducing and the transposition that spread all over plant.Usually, the surfactant of enough " pliability " will form the worm sample micella of these types.

Although the present invention relates generally to the water-based concentrate formulation of glyphosate potassium, but this class water-based concentrate formulation can further comprise another or Multiple Pesticides alternatively, water-soluble herbicidal active component for example, the non-limiting acifluorfen that comprises water-soluble form, the spirit of sulphur grass, benazolin, bentazone, bilanafos, two careless ethers, bromacil, Brominal, carfentrazoneethyl, weed eradication is flat, clopyralid, 2,4-drips, 2, the 4-Embutox, dalapon, dicamba, 2,4-drips propionic acid, diclofop-methyl, two benzene azoles are fast, diquat, endothal, Fenac oxazole diclofop-methyl, the wheat straw volt, fluazifop, fluoroglycofen-ethyl, fluroxypyr, Fomesafen, creeping weed phosphorus, grass ammonium phosphine, the spirit of pyrrole fluorine chlorine standing grain, imazameth, miaow grass ester, imazamox, imazapic, the weed eradication cigarette, the weed eradication quinoline, Imazethapyr, ioxynil, 2 first, 4 chlorine, Thistrol, Vi par, methanearsonic acid, quinclorac, n-nonanoic acid, paraquat, picloram, sulfamic acid, trysben, trichloroacetic acid and Triclopyr.

Therefore embodiments of the present invention are the water-based concentrate compositions of weeding, comprise the glyphosate that is mainly its potassium salt form and be mainly its sylvite or other agriculture second kind of anion weed killer herbicides acceptable salt form, the total concentration of glyphosate and second kind of anion weed killer herbicide is about 360 to about 570g a.e./l, said composition further comprises the surface active agent composition of selecting according to the present invention, and concentration is about 20 to about 300g/l.

In this embodiment, preferably glyphosate a.e. is not less than about 1: 1 with the w/w ratio of second kind of anion weed killer herbicide, for example from about 1: 1 to about 200: 1, preferably between 1: 1 to about 30: 1.Second kind of anion weed killer herbicide preferably is selected from acifluorfen, bilanafos, carfentrazoneethyl, clopyralid, 2,4-drips, 2,4-Embutox, dicamba, 2,4-drips propionic acid, careless ammonium phosphine, 2 first, 4 chlorine, Thistrol, Vi par, methanearsonic acid, n-nonanoic acid, picloram, Triclopyr and imidazolinone herbicide, comprises imazameth, miaow grass ester, imazamox, imazapic, weed eradication cigarette, weed eradication quinoline and Imazethapyr.

The liquid concentrated formula with water and nonaqueous phase is also contained in the present invention, and the aqueous phase glyphosate mainly exists with its potassium salt form, and nonaqueous phase contains second kind of herbicidal active component of relative water-insoluble alternatively.This class formulation example is as comprising emulsion (comprising thick emulsion and microemulsion, water-in-oil type, oil-in-water type and W/O/W type), suspension and suspended emulsion.Nonaqueous phase can comprise the component of microencapsulation, for example weed killer herbicide of microencapsulation alternatively.In having the preparation of the present invention of nonaqueous phase, the concentration of glyphosate a.e. is generally still in the scope that this paper is quoted about the water-based concentrate formulation in the composition.

The insoluble herbicide of illustrative water that can be used in this class preparation comprises second grass amine; Aclonifen; Alachlor; Ametryn; Amidosulfuron; Anilofos; Atrazine; Azafenidin; Azimsulfuron; Benfluralin; Benfuresate; The benzyl Sulfometuron Methyl; Bensulide; Benzofenap; Bifenox; Bromobutide; Bromofenoxim; Butachlor; Butamifos; Butralin; Butroxydim; The fourth grass is special; Amine grass azoles; Block careless amine; Carfentrazoneethyl; Chlomethoxyfen; Green bromine is grand; Pyrazon; Chlorimuron; Mo 9 granular; Chlortoluron; The chlorine Chem hoe; Greenish-yellow grand; The chlorine phthalandione; Chlorothiamid; Cinmethylin; Ether is yellow grand; Clethodim; Clodinafop-propargyl; Clomazone; Clomeprop; Cloransulammethyl; Cyanazine; The grass that goes out is special; AC322140; Cycloxydim; Cyhalofop-butyl; Daimuron; Desmedipham; Desmetryn; Dichlobenil; Diclofop-methyl; Diflufenican; Ding Evil is grand; Dimepiperate; Dimethachlor; Diformazan the third second is clean; Dimethenamid; Amino second fluorine spirit; Dinoterb; Diphenamide; Dithiopyr; Diuron; EPTC; Esprocarb; Ethalfluralin; Ethametsulfuron-methyl; Ethofumesate; Ethoxysulfuron; Etobenzanid; The oxazole diclofop-methyl; Fenuron; Wheat straw volt M; The pyridine ethyl methyl; Fluazifop; Fluchloraline; Flumetsulam amine; Flumicloracpentryl; Flumioxazin; Fluometuron; Fluorochloridone; Fluoroglycofen-ethyl; Amine grass azoles; The fluorenes butyric acid; Fluorine is decided ketone; Fluroxypyr; Flurtamone; Fluthiacetmethyl; Fomesafen; Halosulfuronmethyl; Haloxyfop; Hexazinone; Imazosulfuron; Indanofan; Isopropyl is grand; Yi Evil is grand; Isoxaben; Isoxaflutole; The Evil humulone; Lactofen; Lenacil; Linuron; Mefenacet; Metamitron; Metazachlor; Methabenzthiazuron; Methyldymron; Metobenzuron; Metobromuron; Isopropyl methoxalamine; Metosulam; Metoxuron; The piperazine humulone; Metsulfuron-methyl; Hydram; Afesin; Naproanilide; Napropamide; Quinclorac; Neburea; Nicosulfuron; Norflurazon; Orbencarb; Oryzalin; Oxadiargyl; The Evil humulone; Oxasulfuron; Second oxygen AKH7088; The gram grass is violent; Pendimethalin; Valeryl benzene grass amine; Pentoxazone; Beet is peaceful; Piperazine grass phosphorus; The third careless amine; Fluoropyrimidinesulfuron; Prodiamine; Prometon; Prometryn; Propachlor; Stam F-34; Propaquizafop; Put out Tianjin; Chem hoe; Propisochlor; Pentyne grass amine; Prosulfocarb; Prosulfuron; Pyrrole grass ether; Pyrazolate; Pyrazosulfuron; Pyrazoxyfen; Pyributicarb; Pyridate; KIH 6127; Dichloro quinolinic acid; Quinmerac; Quizalofop-ethyl; Rimsulfuron 25; Rare standing grain is fixed; Tupersan; Simanex; Symetryne; Sulcotrione; Sulphonyl azoles humulone; Ethyl methyl; Sulfosulfuron; Tebutam; Terbufos benzthiazuron; Terbacil; Te Dingtong; Garagard; Terbutryn; P DimethenamidP; Thiazopyr; Thiophene methyl; Benthiocarb; Tiocarbazil; Tralkoxydim; Triallate; Triasulfuron; Tribenuron-methyl; Trietazine; Trefanocide; Triflusulfuron and vernolate. Preferably glyphosate a.e. is not less than 1:1 with the w/w ratio of this class water-insoluble weed killer herbicide, for example from about 1:1 to about 200:1, preferably between 1:1 to about 30:1.

In the present composition, can contain the excipient composition except that surface active agent composition as defined above alternatively, as long as keep the cloud point and the noncrystalline character of composition according to the present invention.The other excipient composition of this class comprises conventional formulation additives, for example stain, thickener, crystallization inhibitor, antifreezing agent (comprising glycols), defoamer, anti-drift agent, compatibilizing agent etc.

Class excipient composition in being commonly used in glyphosate formulation is mineral salt, and ammonium sulfate for example is with the activity of weeding that strengthens glyphosate or the uniformity of activity of weeding.Owing to need in the preparation to provide the content of mineral salt of this class humidification normally high relatively, often, therefore seldom in the present composition, add this class salt greater than the content of glyphosate.For example, contain concentration at least the glyphosate potassium of 360g a.e./l the bin stability waterborne compositions the amount of the ammonium sulfate that can hold will be so little, do not bring substantive beneficial effect.Therefore, alternative is to comprise a small amount of synergist, and for example the olefin(e) compound of anthraquinone compounds or phenyl replacement is disclosed in respectively among international publication No.WO 98/33384 and the WO 98/33385.

Whether the herbicidal formulations that utilizes following method mensuration to comprise glyphosate or its salt or ester and surfactant forms the liquid crystal that comprises surfactant on plant leaf blade and in the plant leaf blade.At first, whether testing surface activating agent/glyphosate formulation forms liquid crystal outside the cuticula to measure on plant leaf blade as mentioned above.Really form the outer liquid crystal of cuticula on the plant leaf blade if be determined at, utilize following high-resolution polarizing microscope determination of test method whether also in cuticula, to form liquid crystal so.

Measuring when whether forming in the cuticula liquid crystal, use the fruit cuticula usually, for example pears cuticula or tomato cuticula are because they are very healthy and strong.Fruit is cuticular separating analogously to carry out in above-mentioned broad-leaved cuticula, and does some change.Usually, being used to remove the cuticular enzyme of fruit is pectase (the every 100ml of 10,000 active units).The concentration of enzyme solutions is usually from about 10% to about 30% w/w, and final enzyme solutions contains 50 activity to about 200 units/ml of having an appointment usually.The fruit cuticula at room temperature cultivated about 1 hour with enzyme or more than, to break away from the fruit cuticula.After cuticula breaks away from, fully flushing, washing before use.

Whether to form liquid crystal in the cuticula with surfactant/glyphosate formulation in order measuring, aforesaid fruit cuticula to be used with contradistinction system, substrate wherein is the imporosity hydrophobic material, for example Parafilm (parafilm).The fruit cuticula is fixed on the carrier gel agar, and the latter is placed in usually on the mesh support screen of being made up of carbon fiber.Then cuticula/agar/combination of screens is placed on the slide.Also Parafilm is placed on the slide in this manner.

The relevant herbicidal formulations that contains surfactant and glyphosate is deposited on cuticula and the Parafilm.When under the polarised light of 100x magnifying power, observing liquid crystal as mentioned above and begin to form, at room temperature wipe cuticula and Parafilm contrast with hand or the mechanical device that has a foam tip.Usually, the liquid crystal that forms on Parafilm is wiped easily.After the wiping, make Parafilm contrast and fruit cuticula in the middle balance about 24 of the environment of controlled condition (temperature between 20 to about 25 ℃, humidity 50% to 75%) to about 48 hours.

After Parafilm contrast and fruit cuticula reach balance, wipe the zone that preparation deposits with hand or the mechanical device strictness that has a foam tip once more.After the wiping, check under the polarised light of 100x magnifying power that once more the liquid crystal of cuticula and Parafilm forms.If observe micro-texture after the wiping second time, this explanation has liquid crystal formation in the cuticula, because these liquid crystal are not removed by twice wiping.And then, can on the fruit cuticula that shows liquid crystal formation, carry out other wiping, can not be wiped with further confirmation liquid crystal, because they are in the cuticula.After the wiping for the second time, the inventor does not see any liquid crystal and forms in any observed Parafilm contrast.

Usually, only need very small amount of solubilizer to improve the feature of preparation.Usually, the ratio of ethoxylation etheramine surfactants and solubilizer only needs about 50: 1 (weight), and more preferably from about 25: 1, and then more preferably from about 10: 1, most preferably from about 8: 1.Those skilled in the art will recognize that various factors can influence the amount of the solubilizer that need give required feature.The solubilizer that can also in preparation, comprise lower ratio, it may not play the function of solubilizer under this ratio, but will strengthen effect, and for example the ratio of surfactant and solubilizer is about 5: 1, about 4: 1, about 3: 1, about 2: 1 or about 5: 1.

And then the viscosity characteristics of concentrate formulation of the present invention to improve given in the adding of solubilizer.The solubilizer that preferably adds capacity, the viscosity that makes preparation to preparation under 0 ℃ and 45/s shearing rate less than 1000c.p., and then more preferably under 0 ℃ and 45/s shearing rate less than 500c.p., most preferably under 0 ℃ and 45/s shearing rate less than 300c.p..In preferred embodiment, the viscosity of herbicidal formulations of the present invention from 0 ℃ and 45/s shearing rate down about 100c.p. to 0 ℃ with the 45/s shearing rate under about 500c.p..Novel formulation of the present invention only needs a small amount of solubilizer can produce these required viscosity.

Can join alternatively that another kind of composition with further raising weeding validity and relevant herbicidal properties is the salt of dicarboxylic acids or dicarboxylic acids in the Gyphosate herbicice preparation of the present invention.The dicarboxylic acids that is fit to that can join in the herbicidal formulations that comprises glyphosate or its salt or ester and surfactant described herein for example comprises oxalic acid, malonic acid, succinic acid, glutaric acid, maleic acid, adipic acid and fumaric acid, and combination or mixture, its mesoxalic acid is preferred.And, except dicarboxylic acids or what replace dicarboxylic acids is can mix the salt of above-mentioned dicarboxylic acids to herbicidal formulations of the present invention, to improve herbicidal performance.The salt that is fit to for example comprises alkali metal salt (for example sylvite), alkanol amine salt and low-grade alkylamine salt.Preferred salt comprises potassium oxalate, oxalic acid dipotassium, sodium oxalate, oxalic acid disodium, oxalic acid two ammoniums, oxalic acid diethanol amine, oxalic acid dimethylamine, the alkanol amine salt of oxalic acid and the low-grade alkylamine salt of oxalic acid.

The preparation that contains dicarboxylic acids (for example oxalic acid) or dicarboxylate (for example potassium oxalate) contains the dicarboxylic acids/dicarboxylate of capacity usually, to strengthen the effect of gained herbicidal formulations.Usually, the weight ratio of total surfactant and carboxylic acid/carboxylate can be from about 1: 1 to about 50: 1, and more preferably 5: 1 to 40: 1, most preferably from about 5: 1 to about 20: 1.The total surfactant of this ratio and carboxylic acid/carboxylate significantly strengthen the herbicidal performance of gained herbicidal formulations.

Can join in the herbicidal formulations of the present invention and be applicable to glyphosate or its salt or ester with dicarboxylic acids or its salt that improves effect.The glyphosate salt that is fit to comprises those that above enumerate, particularly isopropyl amine salt, sylvite and front three ammonium salt.

The present invention also comprises the method that is used to kill or control weeds or unwanted plant, comprises the following step, and diluent liquid concentrate in suitable quantity of water forms the bucket mix formulation, uses the bucket mix formulation of herbicidally effective amount again to the blade of weeds or unwanted plant.The present invention comprises the method for killing or control weeds or unwanted plant equally, comprises the following step, and dilution solid particle concentrate forms the bucket mix formulation in suitable quantity of water, uses the bucket mix formulation of herbicidally effective amount again to the blade of weeds or unwanted plant.

In the herbicidal methods that uses the present composition, composition is diluted in the water of proper volume, provide and use solution, then according to the blade that ratio is applied to plant of using that is enough to obtain required herbicidal effect.This ratio of using shows with the glyphosate scale of per unit processing area usually, for example restrains acid equivalent per hectare (g a.e./ha).What constitute " required herbicidal effect " is at least 85% control of plant variety usually and for example, is measured according to growth minimizing or lethality after a period of time, and glyphosate is brought into play its whole weeding or phytotoxicity effect to handled plant during this period.According to plant variety and growth conditions, may be as little to a week during this period of time, but under normal circumstances glyphosate is brought into play the time that its whole effects needed at least two weeks.

The selection of the effective amount of application of present composition weeding belongs to common professional of agriculture's skill.Those skilled in the art will recognize that equally given activity composition in individual other plant conditions, weather and growth conditions and the composition and their weight ratio all will influence the weeding validity degree that is reached when enforcement is of the present invention.About the purposes of glyphosate composition, known a lot of information about suitable amount of application.Over 20 years, the use of glyphosate and disclosed use research provides abundant information, and the personnel that are engaged in weeds control can therefrom be chosen in the particular environment condition, be the effective glyphosate amount of application of weeding at specific vegetative stage, to specific kind.

The Herbicidal combinations of glyphosate salt is used to control various plants in the world, it is believed that sylvite does not have different with other salt of glyphosate in this.

Can utilize the annual dicotyledon kind of the particular importance of present composition control to comprise for example piemarker (Abutilon theophrasti) without limitation; lamb's-quarters (Amaranthusspp.); button fruit weeds (Borreria spp.); oilseed rape; canola; (Brassica spp.) such as India mustard; dayflower (Commelina spp.); filaree (Erodiumspp.); sunflower (Helianthus spp.); morning glory (Ipomoea spp.); summer cypress (Kochia scoparia); high mallow (Malva spp.); RHIZOMA FAGOPYRI CYMOSI; (Polygonumspp.) such as knotweed cars; kitchen garden (Portulaca spp.); Russia Ji (Salsola spp.); bur (Sida spp.); wild mustard (Sinapis arvensis) and Siberian cocklebur (Xanthium spp.).

Can utilize the annual monocotyledon kind wild oat (Avena fatua) for example without limitation of the particular importance of present composition control), carpetweed (Axonopus spp.), downy brome (Bromus tectorum), lady's-grass (Digitaria spp.), barnyard grass (Echinochloacrusgallo), eleusine indica (Eleusine indica), annual ryegrass (Loliummultiflorum), rice (Oryza sativa), half clever broomcorn millet (Ottochloa nodosa), bahiagrass (Paspalum notatum), canarygrass (Phalaris spp.), foxtail (Setaria spp.), wheat (Triticum aestivum) and corn (Zea mays).

Can utilize the perennial dicotyledon kind of the particular importance of present composition control to comprise for example argy wormwood (Artemisia spp.), milkweed (Asclepiasspp.), Canadian Ji (Cirsium arvense), field bindweed (Convolvulus arvensis) and elegant jessamine (Pueraria spp.) without limitation.

Can utilize the perennial monocotyledon kind of the particular importance of present composition control to comprise for example Brachiaria (Brachiaria spp.) without limitation, Bermuda grass (Cynodondactylon), yellow nutsedge (Cyperus esculentus), purplenutsedge (C.rotundus), quackgrass (Elymus repens), draw bright grass (Bai Mao (Imperata cylindrica)), English ryegrass (Lolium perenne), big broomcorn millet sheep's hay (Panicum maximum), hairy flowered paspalum (Paspalum dilatatum), reed (Phragmites spp.), stone thatch fat meat and fine grain (Sorghum halepense) and cattail (Typhaspp.).

Other can utilize the perennial plant kind of the particular importance of present composition control to comprise for example gulfweed (Equisetum spp.), bracken (Pteridiumaquilinum), blackberry, blueberry (Rubus spp.) and chaste tree beans (Ulex europaeus) without limitation.

If necessary, the user can mix one or more auxiliary agents when composition is used in preparation with the present composition and thinned water.This analog assistant can comprise other surfactant and/or mineral salt, ammonium sulfate for example, and purpose is further to strengthen the weeding effect.But under most conditions, utilize herbicidal methods of the present invention do not have this analog assistant in the presence of promptly provide acceptable effect.

In the method for utilizing the present composition of special concern, composition is behind dilute with water, be applied to the blade that tolerates the crop plants of glyphosate through genetic transformation or selection, be applied to the weeds of this class crop plants growth of next-door neighbour or the blade of unwanted plant simultaneously.This using method has been controlled weeds or unwanted plant, and is simultaneously harmless to crop plants basically.The crop plants that tolerates glyphosate through genetic transformation or selection comprise that its seed is sold by Monsanto Company or through Monsanto Company permission is sold those, carry Roundup

Trade mark.They comprise the kind of cotton, soybean, canola (canola), beet, wheat and corn without limitation.

Dilution concentrate composition of the present invention in water can prepare plant treatment compositions simply.Plant treatment compositions is applied to blade preferably to be finished by sprinkling, utilizes any routine to be used for the device of spraying liquid, for example nozzle, sprayer etc.The present composition can be used in the intensive cultivation technology, wherein adopts instrument to change the pesticide volume that is applied to the farmland different piece, and this depends on variablees such as specific plant variety, soil constitution.In a kind of embodiment of this class technology, the global positioning system of operating with the sprinkling instrument can be used in composition from aequum to the farmland different piece that use.

Plant treatment compositions is preferably enough rare, sprays to utilize standard agricultural spray appliance easily.Can be from about 10 to about 1000 liters of per hectares (l/ha) or higher about useful sprinkling volume of the present invention, sprinkling is used.

Embodiment

The following example only supplies illustration, does not plan to limit the scope of the invention.Embodiment will understand the present invention better, the variation that its advantage of perception and some are implemented.

Embodiment A: the preparation of glyphosate potassium

Add 1264.1 gram glyphosates to the about 4 liters glass container of capacity, be determined as 95.7%.Place ice/water-bath to cool off in container.Container is equipped with agitator on the liquid, and the diameter of stirring vane approximately is half of container.Add commodity 45% potassium hydroxide solutions (VWRScientific Products).Control adds speed, avoids the obvious boiling of gained solution.Along with the height of agitator is regulated in the variation of liquid volume, guarantee to stir fully.Amount to and add 966.2 gram potassium hydroxide solutions.Add 195.3 gram deionized waters and regulate concentration.Continue to stir about 1 hour.Final yield is 2418.4 grams, and the description weight loss is 7.2 grams.The measured value of being calculated is 50.0% glyphosate or 61% glyphosate potassium, and the degree of neutralization that is calculated is 108%.The pH of 10% deionized water dilution is 4.76.The density of gained solution under 20 ℃ is about 1.4661 grams per milliliters, and therefore the volume of 1000 grams under 20 ℃ is about 682ml.This is equivalent to concentration is about 730 grams per liters.

Embodiment B: the preparation of Comparative formulation and preparation of the present invention

Preparation as described below contains the composition 2-01 to 2-13 of surfactant.Contain glyphosate potassium separately, be used to from the 50%a.e. of the foregoing description A glyphosate potassium formulations prepared from solutions.The preparation Comparative composition contains glyphosate potassium, alkyl polyglycoside and alkoxylated alkylamines surfactant (composition 2.01-2.05), so that duplicate PCT communique No.WO 00/15037 embodiment 1,2,3,7 and 15 described compositions respectively.

Sample preparation: add the glyphosate potassium solution of about 80 grams from embodiment A to 4 ounces of (117ml) jars.To auxiliary agent that wherein adds proper proportion and water.Add small amounts of phosphoric acid to some samples, to regulate pH between 4.9 and 5.1.(Cole-Parmer, Chicago IL) stir, until obtaining single phase with magnetic stirrer with the gained mixture.So at raw material is under the situation about can not mix with magnetic stirrer of viscosity, (USStoneware, Manwah NJ) go up roll extrusion, until surfactant dissolves at roller press to make raw material.The material placement is spent the night, observe and guarantee that it is single phase, and do not contain bubble.

Utilize Mettler DA-300 densitometer to measure density then, calculating concentration is to restrain every liter of expression.

Cloud point is to measure like this, heats a small amount of raw material in vitro, becomes fuzzyly or muddy until solution, removes thermal source then, observes solution becomes clarification because of cooling temperature.The temperature that solution becomes clarification is called cloud point.

At 45 seconds ^-1Shearing rate under, utilize Haake Model VT500 (Haake, Inc., Karlsruhe Germany) the measurement viscosity that suitable MV series cup and vibration sensing system are housed.Temperature is different because of the water-bath that is added.A few sample does not have capacity to utilize, and its viscosity is to utilize small sample adapter (Brookfield Laboratories, Inc., Stoughton, Brookfield Model DV-II measurement Mass.) are housed.

Table 4: be used in the surfactant in the Embodiment C

Embodiment C: representative sample preparation of compositions of the present invention

About 31wt%a.e. glyphosate potassium/10wt% surface activator composition: the 1.550g40wt%a.e. glyphosate potassium aqueous solution is weighed in the bottle.In same bottle, add the 0.200g surfactant.Add the deionized water of capacity to gross weight 2.000g to content then.Mixture was at room temperature stirred 2 hours, check whether formed solution.If there is solution, will at room temperature places for the examination bottle so and spend the night.If still there is solution, will in 50 ℃ of baking ovens, place for 1 week for the examination bottle so.If being separated, the surfactant of being tested is regarded as " compatibility " so in the week.Surfactant shown in all tables 4 is a compatibility under 31%a.e. potassium/10wt% surfactant LOADING RATES.

About 37wt%a.e. glyphosate potassium/12wt% surface activator composition: the 41.1g45wt%a.e. glyphosate potassium aqueous solution is weighed in the container.In same container, add 6.0g surfactant and 2.9g deionized water, gross weight 50.0g.The remainder of scheme is described identical with the 31wt% sample.In table 4, differentiate to being that the surfactant of compatibility is as shown in table 5 below under 37%a.e. potassium/12wt% surfactant LOADING RATES.

About 40wt%a.e. glyphosate potassium/10wt% surface activator composition: the 1.79g45wt%a.e. glyphosate potassium aqueous solution is weighed in the bottle.In same bottle, add the 0.2g surfactant.The remainder of scheme is described identical with the 31wt% sample.In table 4, differentiate to being that the surfactant of compatibility is as shown in table 5 below under 40%a.e. potassium/10wt% surfactant LOADING RATES.

About 45wt%a.e. glyphosate potassium/15wt% surface activator composition: 1.100g solid glyphosate one potassium is weighed in the bottle.In same bottle, add the 0.300g surfactant.Add the capacity deionized water in bottle, final weight is to 2.000g.The remainder of scheme is described identical with the 31wt% sample.In table 4, differentiate to being that the surfactant of compatibility is as shown in table 5 below under 45%a.e. potassium/10wt% surfactant LOADING RATES.

About 31wt%a.e.NH ₄ ⁺Glyphosate/10wt% surface activator composition: 1.48g41.9wt%a.e. glyphosate two aqueous ammoniums (1.7eq) are weighed in the bottle.In same bottle, add 0.2g surfactant and 0.32g deionized water.The remainder of scheme is described identical with 31wt% glyphosate potassium sample.In table 4, differentiate to being that the surfactant of compatibility is as shown in table 5 below under 31%a.e. ammonium/10wt% surfactant LOADING RATES.

About 37wt%a.e.NH ₄ ⁺Glyphosate/12wt% surface activator composition: 1.76g41.9wt%a.e. glyphosate two aqueous ammoniums (1.7eq) are weighed in the bottle.In same bottle, add the 0.2g surfactant.The remainder of scheme is described identical with 31wt% glyphosate potassium sample.In table 4, differentiate to being that the surfactant of compatibility is as shown in table 5 below under 37%a.e. ammonium/12wt% surfactant LOADING RATES.

The compatibility and the viscosity data of embodiment chosen C composition are listed in the table 5.Be understandable that this paper does not report all results of all compatibility tests.Some surfactants of testing (but this paper not report) are even under the 31wt%a.e. LOADING RATES neither compatibility.

The preparation of embodiment D: Alpha-Methyl-ω-(N-methyl octadecane amino) poly-(oxygen-1,2-ethylidene)

The preparation of the intermediate of table 4 Compound C

Seven (oxygen ethylidene) glycol methyl ether tosylates (I):

With seven (oxygen ethylidene) glycol methyl ether (350MW avg., 47g, 1eq., Aldrich) and triethylamine (17.59g 1.3eq.) is dissolved in anhydrous methylene chloride (20ml), is placed under the blanket of nitrogen.(28.16g, anhydrous methylene chloride 1.1eq.) (20ml) solution keep temperature to be lower than 10 ℃ slowly to add p-toluenesulfonyl chloride.After at room temperature stirring 4 hours, filter reaction mixture under reduced pressure removes from filtrate and desolvates, and obtains the orange oil of 64g, yield 95%.

¹H NMR d 7.8(d，2H)，7.5(d，2H)，4.1(t，2H)，3.6-3.4(m，26H)，3.2(s，3H)，2.4(s，3H).

The preparation of table 4 Compound C:

With N-methyl octadecylamine (283MW, 18.49g 2.2eq.) are dissolved in 200ml toluene, add then potash (4.1g, 1eq.).(15g 1eq.), places reaction under the nitrogen then, 80 ℃ of following heated overnight slowly to add tosylate (I) to mixture.From the reaction of finishing, remove solid by the filtration of C salt.Under reduced pressure from filtrate, remove toluene.Crude product is through chromatogram purification, with 80: 5: 1 wash-outs of methylene chloride/ammonium hydroxide.Obtain 16g yellow semi-solid (I I), yield 85%.H NMR，3.6-3.4p(m，26H)，3.3p(s，3H)，2.6p(t，2H)，2.4p(t，2H)，2.2p(s，3H)，1.4p(m，2H)，1.2p(s，30H)，0.8p(t，3H).

Will be noted that, contain glyphosate potassium and do not have alkyl polyglycoside to have remarkable lower viscosity as the general glyphosate potassium salt composite of the present composition of surfactant system component than the similar loading that contains APG.The amplitude of this viscosity advantage is somewhat dependent upon the selection and the concentration of the specific surfactant that is adopted.For example, the complete list of every kind of possible invention embodiment is not planned to become in the front about the explanation of specific implementations of the present invention.Those skilled in the art will recognize that, can modify specific implementations described herein, and still be within the scope of the present invention.

The preparation of embodiment E: surfactant R RR-UUU

Preparation formula (36) or (37) compound

R wherein ¹And R ⁹Be independently have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ²O) _pR ¹³R ²At each m (R ²O), n (R ²O), p (R ²O) and q (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³, R ⁸, R ¹³And R ¹⁵Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁵, R ⁶And R ⁷Be hydrogen independently, have 1 to the alkyl of about 30 carbon atoms or the alkyl or the R of replacement ⁴R ¹⁴Be have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(CH ₂) _zO (R ²O) _pR ³M, n, p and q are from 1 to about 50 mean independently; X is-O-,-N (R ¹⁴)-,-C (O)-,-C (O) O-,-OC (O)-,-N (R ¹⁵) C (O)-,-C (O) N (R ¹⁵)-,-S-,-SO-or-SO ₂-; T is 0 or 1; A-is that agricultural goes up acceptable anion; Y and z are from 0 to about 30 integer independently.

This compound is like this preparation, alkali or lewis acidic in the presence of, the former is diisobutyl aluminium hydride (DIBAL), NaH for example, the latter is BF for example ₃Et ₂O adds compound R by 1: 1 mol ratio to epoxides ¹-XH generates intermediate (91), and reaction process is as follows:

Then via conventional means alkoxylated compounds (91), production (36) compound.In above-mentioned reaction process be-N as if X ⁺R ⁸R ⁹-, then generate compound (37).

The alkyl amino propane diols compound that preparation has formula (36), wherein X is-N (R ¹⁴)-, R ³, R ⁵, R ⁶And R ⁷Be hydrogen, R ²O is an ethylidene, R ⁴Be-CH ₂O (R ²O) _qR ³Use oxirane to carry out alkoxylation.

Table 6

Compound	R ₁	R ₁₄	n+q	Preparation
Compound	R ₁	R ₁₄	n+q	Preparation	1a	C ₁₈H ₃₇	CH ₃	5	384
1b	C ₁₈H ₃₇	CH ₃	10	388	1a	C ₁₈H ₃₇	CH ₃	5	384
1b	C ₁₈H ₃₇	CH ₃	10	388	1c	C ₁₈H ₃₇	CH ₃	15	409
1d	C ₁₈H ₃₇	CH ₃	20	415	1c	C ₁₈H ₃₇	CH ₃	15	409
1d	C ₁₈H ₃₇	CH ₃	20	415	1e	C ₁₈H ₃₇	CH ₃	25	416
1f	C ₁₂H ₂₅	CH ₃	5	387	1e	C ₁₈H ₃₇	CH ₃	25	416
1f	C ₁₂H ₂₅	CH ₃	5	387	1g	C ₁₂H ₂₅	CH ₃	10	389
1h	tallow	H	15	421	1g	C ₁₂H ₂₅	CH ₃	10	389
1h	tallow	H	15	421	1i	tallow	H	23	423
1j	tallow	H	27	427	1i	tallow	H	23	423
1j	tallow	H	27	427	1k	coco	H	23	425
1l	coco	H	30	427	1k	coco	H	23	425

Alkyl amino propanol compounds 2a-c with formula (36) is preparation like this, and wherein X is-N (R ¹⁴)-, R ³, R ⁵, R ⁶And R ⁷Be hydrogen, R ²O is an ethylidene, R ⁴Be-CH ₂OCH ₂C ₆H ₅: make the reaction of amine and benzyl glycidol, alkoxylate benzyl then, the catalytic hydrogenation by routine goes protection again, so that R ⁴Be-CH ₂OR ³Use oxirane to carry out alkoxylation.

Alkyl amino propanol compounds 2d-j with formula (36) is preparation like this, and wherein X is-N (R ¹⁴)-, R ³, R ⁵, R ⁶And R ⁷Be hydrogen, R ²O is an ethylidene, R ⁴Be-CH ₂OR ³: make amine and corresponding glycidol ether reaction, alkoxylate then.Use oxirane to carry out alkoxylation.

Table 7

Compound	R ₁	R ₁₄	R ₃	n	Preparation
Compound	R ₁	R ₁₄	R ₃	n	Preparation	2a	C ₁₈H ₃₇	CH ₃	H	5	640
2b	C ₁₈H ₃₇	CH ₃	H	10	637	2a	C ₁₈H ₃₇	CH ₃	H	5	640
2b	C ₁₈H ₃₇	CH ₃	H	10	637	2c	C ₁₂H ₂₅	CH ₃	H	5	639
2d	C ₁₈H ₃₇	CH ₃	CH ₃	5		2c	C ₁₂H ₂₅	CH ₃	H	5	639
2d	C ₁₈H ₃₇	CH ₃	CH ₃	5		2e	C ₁₈H ₃₇	CH ₃	CH ₃	15
2f	C ₁₈H ₃₇	CH ₃	CH ₃	25		2e	C ₁₈H ₃₇	CH ₃	CH ₃	15
2f	C ₁₈H ₃₇	CH ₃	CH ₃	25		2g	C ₁₂H ₂₅	CH ₃	CH ₃	10	481
2h	C ₁₂H ₂₅	CH ₃	CH ₃	15	483	2g	C ₁₂H ₂₅	CH ₃	CH ₃	10	481
2h	C ₁₂H ₂₅	CH ₃	CH ₃	15	483	2i	C ₁₂H ₂₅	CH ₃	CH ₃	25	485
2j	C ₁₈H ₃₇	CH ₃	Isopropyl alcohol	5		2i	C ₁₂H ₂₅	CH ₃	CH ₃	25	485
2j	C ₁₈H ₃₇	CH ₃	Isopropyl alcohol	5		2k	C ₁₈H ₃₇	CH ₃	Isopropyl alcohol	10
2l	C ₁₂H ₂₅	CH ₃	Isopropyl alcohol	5		2k	C ₁₈H ₃₇	CH ₃	Isopropyl alcohol	10
2l	C ₁₂H ₂₅	CH ₃	Isopropyl alcohol	5		2m	C ₁₂H ₂₅	CH ₃	Isopropyl alcohol	10

Preparation formula (38) or (39) compound

This compound is like this preparation, alkali or lewis acidic in the presence of, the former is diisobutyl aluminium hydride (DIBAL), NaH for example, adds compound R by 1: 2 mol ratio to epoxides ¹-XH generates intermediate (92), and reaction process is as follows:

Then via conventional means alkoxylated compounds (92), production (38) compound.In above-mentioned reaction process be-N as if X ⁺R ⁸R ⁹-, then generate compound (39).

The quantity of the alkylidene oxide that is generated in compound (92) main chain depends on compound R between the stage of reaction ¹The mol ratio of-XH and epoxides.If compound R ¹The molar ratio of-XH and epoxides 1: 3 in this way, the R in the formula (92) so ²Be-CH ₂CH ₂-, m is 2.Alkoxylated compounds as mentioned above then.

Preparation formula (40), (41), (42) and (43) compound

R wherein ¹, R ⁹And R ¹²Be independently have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ²O) _pR ¹³R ²At each m (R ²O), n (R ²O), p (R ²O) and q (R ²O) in the group be C independently ₂-C ₄Alkylidene; R ³, R ⁸, R ¹¹, R ¹³And R ¹⁵Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁵, R ⁶And R ⁷Be hydrogen independently, have 1 to the alkyl of about 30 carbon atoms or the alkyl or the R of replacement ⁴R ¹⁰Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ¹⁴Be have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(CH ₂) _zO (R ²O) _pR ³M, n, p and q are from 1 to about 50 mean independently; X is-O-,-N (R ¹⁴)-,-C (O)-,-C (O) O-,-OC (O)-,-N (R ¹⁵) C (O)-,-C (O) N (R ¹⁵)-,-S-,-SO-or-SO ₂-; T is 0 or 1; A-is that agricultural goes up acceptable anion; Y and z are from 0 to about 30 integer independently.

Formula (40), (41), (42) or (43) compound are preparations like this, and in the presence of alkali, for example diisobutyl aluminium hydride (DIBAL) adds compound R by 1: 1 mol ratio to epoxides ¹-X-(R ²O) _n-XH, as follows:

Then via conventional means alkoxylated compounds (93), production (40) compound.If raw material comprises that (just an X is-N a quaternary ammonium salt ⁺R ⁸R ⁹-), then compound has formula (41) or (42).If (just an X is-N two quaternary ammonium salts in the raw material ⁺R ⁸R ⁹-, another is-N ⁺R ¹¹R ¹²-), production (43) compound then.

Embodiment F: the preparation of formula (28) double structure glucitol (Gemini Glucitols) ZZ, AAA, BBB, CCC

Compound ZZ:

With 1,12-methylamino glucitol dodecane: R=methyl, n=12: 1-deoxidation-1-(methylamino)-D-glucitol (195MW, 15g, 2eq.), 1,12-dibromo-dodecane (328MW, 12.6g, 1eq.), sodium bicarbonate (7.1g, 2.2eq.) and the 120ml anhydrous dimethyl formamide place under the nitrogen atmosphere, 70 ℃ of down heating 17 hours.After reacting completely, remove by filter all unreacted sodium bicarbonates, under reduced pressure from reaction, remove DMF then.Add 400ml ethyl acetate, crude product is precipitated out, mixture is stirred some hrs, from the product that is precipitated, to remove the DMF that contains.Make crude product from 1: 1 solution of methanol, be recrystallized twice, obtain the 6.68g white solid, yield 15%.H NMR300MHz, MeOD ⁴: 1.25-1.4 (broad peak, 16H), 1.5p (quint, 4H), 2.45p (sept., 4H), 2.55p (d, 4H), and 3.6-3.8p (complicated peak, 12H). analyze: C26H58N2O11: theory:: C, 54.3, H, 10.1, N, 4.8. experiment: C, 54.2, H, 9.9, N, 4.5.

Compd A AA

With 1, the own Glucosamine alcohol of 6-propane: R=hexyl, n=3: 1-deoxidation-1-(oneself is amino)-D-glucitol (265MW, 15.76g, 2eq.), 1,3-dibromopropane (202MW, 6.0g, 2eq.), sodium bicarbonate (5.49g, 2.2eq.) and the 180ml anhydrous dimethyl formamide place under the nitrogen, 70 ℃ of down heating 17 hours.After reacting completely, remove by filter all unreacted sodium bicarbonates, under reduced pressure from reaction, remove DMF then.Add 600ml ethyl acetate, crude product is precipitated out, mixture is stirred some hrs, from the product that is precipitated, to remove the DMF that contains.Inclining solvent, spends the night at 80 ℃ of vacuum oven products.It is yellow semi-solid to reclaim 12g, is 90% pure.Promising other purifying and the recrystallization done or chromatogram to make great efforts all be unsuccessful, yield 71%.H NMR 500MHz, MeOD ⁴.0.9p (t, 6H), 1.25-1.4p (broad peak, 12H), 1.55p (quint, 4H), 1.75p (quint, 2H), 2.55-2.75p (complicated peak, 12H), 3.6-3.8p (complicated peak, 12H) .C NMR 50MHz, MeOD ⁴: 13.8p, 22.8p, 25.8p, 26.5p 26.2p, 32.0p, 53.0p, 54.5p, 56.8p, 63.8p, 70.0p, 71.2p, 72.0p, 72.5p.

The 2D-NMR experiment provides decisive node configuration.

Compound C CC

With 1, the own Glucosamine alcohol of 8-octane: R=hexyl, n=8: 1-deoxidation-1-(oneself is amino)-D-glucitol (265MW, 15.0g, 2eq.), 1,8-two bromooctane (262MW, 7.68g, 1eq.), potash (8.56g, 2.2eq.) and the 180ml anhydrous dimethyl formamide place under the nitrogen, 70 ℃ of down heating 20 hours.After reacting completely, remove by filter all unreacted potash, under reduced pressure from reaction, remove DMF then.Add 600ml ethyl acetate, crude product is precipitated out, mixture is stirred some hrs, from the product that is precipitated, to remove the DMF that contains.Inclining solvent, spends the night at 80 ℃ of vacuum oven products.Crude product is dissolved in small amount of methanol, discards all precipitated solid, be further purified.It is yellow semi-solid to reclaim 13.6g, is 90% pure.Yield 38%.

H NMR 300MHz, MeOD ⁴: 0.9p (t, 6H), 1.2-1.4p (broad peak, 18H), 1.4-1.6p (broad peak, 8H), 2.4-2.6p (complicated peak, 12H), 3.55-3.8 (complicated peak, 12H).

Compd B BB

With 1, the hot Glucosamine alcohol of 8-propane: R=octyl group, n=3: 1-deoxidation-1-(hot amino)-D-glucitol (293MW, 6.45g, 2eq.), 1,3-dibromopropane (202MW, 2.2g, 1eq.), sodium bicarbonate (2.0g, 2.2eq.) and the 60ml anhydrous dimethyl formamide place under the nitrogen, 70 ℃ of down heating 17 hours.After reacting completely, remove by filter all unreacted sodium bicarbonates, under reduced pressure from reaction, remove DMF then.Add 200ml ethyl acetate, crude product is precipitated out, mixture is stirred some hrs, from the product that is precipitated, to remove the DMF that contains.Inclining solvent, spends the night at 80 ℃ of vacuum oven products.It is semi-solid to reclaim 8.88g white, is 90% pure.Promising other purifying and the recrystallization done or chromatogram to make great efforts all be unsuccessful, yield 64%.H NMR 600MHz，MeOD ⁴：0.87p(t，6H)，1.2-1.35p(broad，20H)，1.5p(quint，4H)，1.7p(quint.，2H)，2.5-2.7p(complex，12H)，3.6-3.8p(complex，12H).C NMR 600MHz，MeOD ⁴：14.6p，23.7p，24.55p，27.4p，28.6p，30.4p，30.8p，33.0p，54.0p，55，8p，58.2p，64.8p，71.7p，72.5p，73.0p，73.8p.

The 2D-NMR experiment provides decisive node configuration.

Embodiment G: the preparation of formula (23) compound

The preparation alkoxylated amines, wherein this amine has following formula:

In the presence of potassium hydroxide with selected commercial available alcohol ethoxylate (Brij for example ^TM58) handle with toluene sulfochloride, be converted into corresponding tosylate.The gained tosylate then in anhydrous tetrahydro furan (THF), react down at 80 ℃ and to spend the night with suitable alkylamines (for example methylamine, benzylamine, dimethylamine etc.), obtain required product.

Embodiment H: the preparation of formula (25) compound

Be prepared as follows the alkoxylate with following formula many (hydroxy alkyl) amine:

In the presence of potassium hydroxide with selected commercial available alcohol ethoxylate (Brij for example ^TM58) handle with toluene sulfochloride, be converted into corresponding tosylate.The gained tosylate then in the presence of the anhydrous powder sodium bicarbonate, in the absolute ethyl alcohol that refluxes with suitable amine derivative (for example positive alkylated glucamine etc.) reaction one to two day, obtain required product.

Example I: the preparation of formula (74) compound

Be prepared as follows alkoxy quaternary ammonium salt with following formula:

In anhydrous THF, under 50 ℃, formula (73) alkoxylated amines is spent the night with the methyl chloride processing, obtain required product.

Embodiment J: the preparation of formula (32) compound

Be prepared as follows amine oxide:

In methyl alcohol, at room temperature, the alkyl alkoxy dimethylamine is spent the night with hydrogen peroxide oxidation, obtain required product.

Embodiment K: the preparation of formula (72) compound

Be prepared as follows formula (72) guanidine compound:

In methyl alcohol, at room temperature, alkyl alkoxy amine is spent the night with the processing of formamide sulfonic acid, obtain required product.

Other formula (72) compound of preparation as follows:

Product is synthetic like this, with the amine of correspondence chloroethyl isocyanate acidylate, then chloride is replaced with dimethylamine.

Embodiment L: the preparation of formula (78) and (79) compound

Compound (79) is preparation like this, in the ethanol that refluxes, 4-methyl-diaminopropane is gathered (oxygen ethene) tosylate alkylation two days with excessive cetyl, through the DOWEX50WX2-400 ion-exchange resin purification, with the ethanolic solution wash-out of 50% dense HCl.

Compound (78) is preparation like this, under the anhydrous powder sodium carbonates' presence, in the ethanol that refluxes, coco amine is used poly-(oxygen ethene) xylene sulfonate alkylation two days.

Embodiment M: the preparation of formula () compound

This compound is preparation like this, and corresponding diamines and two equivalent acyl chloride reactions reduce the gained diamines then with lithium aluminium hydride (LAH).Select as an alternative, this compound can be prepared by the reaction of diamines and two equivalent chain alkyl bromines.Ethoxylation double structure (Gemini) diamines under standard conditions.

Embodiment N: the preparation of formula (26) compound

In the presence of potassium hydroxide, commercial available alcohol ethoxylate is handled with toluene sulfochloride, be converted into corresponding tosylate.Reduction D-glucosamine hydrochloride in the presence of sodium borohydride and water obtains encircling the Glucosamine salt of opening then.In the presence of potash, Glucosamine and the reaction of alkyl ethoxy tosylate obtain required product as follows:

The R=alkyl

Embodiment 0: the preparation of formula () compound

Reduction D-glucosamine hydrochloride obtains encircling the Glucosamine salt of opening in the presence of sodium borohydride and water.Glucosamine salt is neutralized with sodium hydroxide, under reducing condition, reacts, just in the presence of ethanol, 4%Pd/C and 60psig hydrogen, under 40 ℃, obtain required product as follows with the alkyl aldehydes of suitable chain length:

The R=alkyl

Formula (33), (35), (64) and (71) alkoxylated compounds are preparations like this, select commercial available raw material, and for example tertiary amine again by methods known in the art alkoxylate raw material, generates one of alkoxylated compounds.

Embodiment P: the formation test of anisotropy aggregation and/or liquid crystal

Utilize whether surfactant forms liquid crystal in liquid crystal outside anisotropy aggregation, the cuticula and/or the cuticula in the presence of glyphosate the whole bag of tricks that is used to measure disclosed herein, the inventor forms the anisotropy aggregation with regard to the exhibiting high surface activating agent and/or liquid crystal is tested.Utilize the surfactant of the some of glyphosate isopropyl amine preparation test in the presence of glyphosate, and in the glyphosate potassium preparation, tested other surfactants.Following table is set forth the result of a large amount of tests.

Hetoxol CS20/Trymeen 6617	N	Y	Y
Hetoxol CS20/Trymeen 6617	N	Y	Y	Hetoxol CS20+Duoquat T-50	NT	NT	N
Hetoxol CS20+Arquad C-50	NT	NT	Y	Hetoxol CS20+Duoquat T-50	NT	NT	N
Hetoxol CS20+Arquad C-50	NT	NT	Y	Hetoxol CS20+ chlorination lauryl choline	NT	NT	Y
Hetoxol CS25+Ethomeen T25	Y	Y	Y	Hetoxol CS20+ chlorination lauryl choline	NT	NT	Y
Hetoxol CS25+Ethomeen T25	Y	Y	Y	Hetoxol CS15+Ethomeen T25	NT	Y	Y
Hetoxol CS20+Ethomeen T20	Y	Y	Y	Hetoxol CS15+Ethomeen T25	NT	Y	Y
Hetoxol CS20+Ethomeen T20	Y	Y	Y	Hetoxoi CS25+Ethomeen T20	Y	Y	Y
Hetoxol CS15+ chlorination lauryl choline	NT	NT	Y	Hetoxoi CS25+Ethomeen T20	Y	Y	Y
Hetoxol CS15+ chlorination lauryl choline	NT	NT	Y	Brij 78+Ethomeen T20	Y	Y	Y
Brij 78+Ethomeen T25	Y	Y	Y	Brij 78+Ethomeen T20	Y	Y	Y
Brij 78+Ethomeen T25	Y	Y	Y	Brij 78+Ethoquad T20	Y	Y	Y
Brij 78+Ethoquad T25	Y	Y	Y	Brij 78+Ethoquad T20	Y	Y	Y
Brij 78+Ethoquad T25	Y	Y	Y	Neodol 1-9/Ethomeen T/25	N	N	N
Agrimul PG 2069/Ethomeen T/25	N	N	N	Neodol 1-9/Ethomeen T/25	N	N	N
Agrimul PG 2069/Ethomeen T/25	N	N	N	Tergitol 15-S-9/Ethomeen T/25	N	N	N
Tergitol 15-S-12/Ethomeen T/25	N	N	N	Tergitol 15-S-9/Ethomeen T/25	N	N	N
Tergitol 15-S-12/Ethomeen T/25	N	N	N	Tergitol 15-S-15/Ethomeen T/25	N	N	N
Procol LA 10+Ethoquad T25	NT	NT	N	Tergitol 15-S-15/Ethomeen T/25	N	N	N
Procol LA 10+Ethoquad T25	NT	NT	N	Procol LA 12+Ethoquad T25	NT	NT	N
Procol La 15+Ethoquad T25	NT	NT	Y	Procol LA 12+Ethoquad T25	NT	NT	N
Procol La 15+Ethoquad T25	NT	NT	Y	Hetoxol CS20+PEG 7 dimethylammonium chloride	NT	NT	Y
Hetoxol CS20+PEG 22 dimethylammonium chloride	NT	Y	Y	Hetoxol CS20+PEG 7 dimethylammonium chloride	NT	NT	Y
Hetoxol CS20+PEG 22 dimethylammonium chloride	NT	Y	Y	Plurafac A38+Ethomeen T25	Y	Y	Y
Plurafac A38+Ethoquad T25	Y	Y	Y	Plurafac A38+Ethomeen T25	Y	Y	Y
Plurafac A38+Ethoquad T25	Y	Y	Y	Plurafac A38+Ethomeen T20	Y	Y	Y
Plurafac A38+Ethoquad T20	Y	Y	Y	Plurafac A38+Ethomeen T20	Y	Y	Y
Plurafac A38+Ethoquad T20	Y	Y	Y	Hetoxol CS20+Gemlnl 10-2-10	NT	NT	Y
Hetoxol CS20+Gemini 10-3-10	NT	NT	Y	Hetoxol CS20+Gemlnl 10-2-10	NT	NT	Y
Hetoxol CS20+Gemini 10-3-10	NT	NT	Y	Hetoxol CS 20+Gemini 10-4-10	NT	NT	Y

Hetoxol CS 20+Gemini 14-2-14	NT	NT	Y
Hetoxol CS 20+Gemini 14-2-14	NT	NT	Y	Hetoxol CS 20+Gemini 14-3-14	NT	NT	Y
Sad+Ethomeen T25	NT	NT	N	Hetoxol CS 20+Gemini 14-3-14	NT	NT	Y
Sad+Ethomeen T25	NT	NT	N	Capric acid+Ethomeen T25	NT	NT	N
Lauric acid+Ethomeen T25	NT	NT	N	Capric acid+Ethomeen T25	NT	NT	N
Lauric acid+Ethomeen T25	NT	NT	N	Myristic acid+Ethomeen T25	NT	NT	N
Palmitic acid+Ethomeen T25	NT	NT	Y	Myristic acid+Ethomeen T25	NT	NT	N
Palmitic acid+Ethomeen T25	NT	NT	Y	Oleic acid+Ethomeen T25	NT	NT	N
Lecithin+Ethomeen T25	N	N	Y	Oleic acid+Ethomeen T25	NT	NT	N
Lecithin+Ethomeen T25	N	N	Y	Lecithin+Ethoquad T25	N	N	Y
Lecithin+Ethomeen T20	N	N	Y	Lecithin+Ethoquad T25	N	N	Y
Lecithin+Ethomeen T20	N	N	Y	Lecithin+Ethoquad T20	N	N	Y
Lecithin+Fluorad FC 754	N	N	Y	Lecithin+Ethoquad T20	N	N	Y
Lecithin+Fluorad FC 754	N	N	Y	Lecithin+Hetoxol CS20	NT	Y	Y
Lecithin+Hetoxol CS25	NT	Y	Y	Lecithin+Hetoxol CS20	NT	Y	Y
Lecithin+Hetoxol CS25	NT	Y	Y	Fluowet PL 80+Ethomeen T25	N	N	N
Ethoquad C12+Tergitol 15-S-7	N	N	N	Fluowet PL 80+Ethomeen T25	N	N	N
Ethoquad C12+Tergitol 15-S-7	N	N	N	Ethoquad T12+Tergitol 15-S-7	N	N	N
Ethoquad C12+Tergitol 15-S-9	N	N	N	Ethoquad T12+Tergitol 15-S-7	N	N	N
Ethoquad C12+Tergitol 15-S-9	N	N	N	Ethoquad T12+Tergitol 15-S-9	N	N	N
Ethoquad C12+Tergitol 15-S-12	N	N	N	Ethoquad T12+Tergitol 15-S-9	N	N	N
Ethoquad C12+Tergitol 15-S-12	N	N	N	Ethoquad T12+Tergitol 15-S-12	N	N	N
Ethoquad C12+Tergitol 15-S-15	N	N	N	Ethoquad T12+Tergitol 15-S-12	N	N	N
Ethoquad C12+Tergitol 15-S-15	N	N	N	Ethoquad C12+Arosurf 66 E10	NT	N	N
Ethoquad T12+Arosurf 66 E10	NT	N		Ethoquad C12+Arosurf 66 E10	NT	N	N
Ethoquad T12+Arosurf 66 E10	NT	N		Surfactant mixture in the glyphosate potassium preparation:	LC intr a	LC epi	AA
Ethoquad C12+Tergitol 15-S-7	NT	Y	Y	Surfactant mixture in the glyphosate potassium preparation:	LC intr a	LC epi	AA
Ethoquad C12+Tergitol 15-S-7	NT	Y	Y	Ethoquad T12+Tergitol 15-S-7	NT	Y	Y
Ethoquad C12+Tergltol 15-S-9	NT	Y	Y	Ethoquad T12+Tergitol 15-S-7	NT	Y	Y
Ethoquad C12+Tergltol 15-S-9	NT	Y	Y	Ethoquad T12+Tergitol 15-S-9	NT	Y	Y

Ethoquad C12+Tergitol 15-S-12	NT	Y	Y
Ethoquad C12+Tergitol 15-S-12	NT	Y	Y	Ethoquad T12+Tergitol 15-S-12	NT	Y	Y
Ethoquad C12+Tergitol 15-S-15	NT	Y	Y	Ethoquad T12+Tergitol 15-S-12	NT	Y	Y
Ethoquad C12+Tergitol 15-S-15	NT	Y	Y	Ethoquad T12+Tergitol 15-S-15	NT	Y	Y
Ethoquad C12+Arosurf 66 E10	NT	Y	Y	Ethoquad T12+Tergitol 15-S-15	NT	Y	Y
Ethoquad C12+Arosurf 66 E10	NT	Y	Y	Ethoquad T12+Arosurf 66 E10	NT	Y	Y

C _wIt is alkyl with w carbon atom

X ^-It is cl anion

EO is an oxygen ethene

AA is the anisotropy aggregation

LC intra is a liquid crystal in the cuticula

LC epi is the outer liquid crystal of cuticula

Y is a "Yes"

N is a "No"

NT is not test (N.T.)

NA is non-availability (just not having trade name)

Especially preferred weed killer herbicide be N-phosphonomethylglycine (glyphosate), it salt, adduct or ester or in plant tissue, be converted into glyphosate or the compound of glyphosate ion be provided.Be summarized in U.S. Patent No. 4,405 according to the operable glyphosate salt of the present invention, in 531, be incorporated herein by reference.Glyphosate salt generally is made up of alkali metal, halogen, organic amine or ammonia, includes but not limited to following.Single, two and three alkali metal salts of potassium, lithium and sodium.The salt of alkaline earth metals calcium, barium and magnesium.The salt of other metals comprises copper, manganese, nickel and zinc.Fluorine, chlorine, bromine and iodine single, two and trihalid salt.Single ammonium, alkyl and phenyl ammonium salt comprise list, two and ternary form, comprise ammonium, first ammonium, second ammonium, third ammonium, fourth ammonium and aniline.Alkylamine salt comprises list, two and ternary form, comprises methylamine, ethamine, propylamine, butylamine, methylbutylamine, stearylamine and beef tallow amine.Alkenyl amine salt based on ethene, propylene or butylene.The ring-type organic amine salt comprises pyridine, piperidines, morpholine, pyrrolidines and picoline.Alkyl sulfonium salt, i.e. first sulfonium, second sulfonium, third sulfonium and fourth sulfonium.Other salt comprise sulfoxonium, methoxyl group methylamine and phenoxyethylamine.Preferred glyphosate salt comprises potassium (single, two and ternary form), sodium (single, two and ternary form), ammonium, trimethylammonium, isopropylamine, MEA and trimethylsulfonium.

Because the herbicidal derivative thing of commercial most important N-phosphonomethylglycine is its some salt, describes in further detail and can be used for glyphosate composition of the present invention so put up with this class salt.These salt are known, and comprise ammonium, IPA, alkali metal (for example single, two and tripotassium salt) and trimethyl sulfonium salt.The salt of N-phosphonomethylglycine is commercial significant, and partly cause is that they are water miscible.Just now cited salt is non-ordinary water dissolubility, allows high concentrated solution using local dilution thus.According to the inventive method that relates to glyphosate herbicidal, use glyphosate and other the aqueous solution that contain herbicidally effective amount to plant leaf blade according to component of the present invention.A kind of like this aqueous solution can obtain like this, with the dilution of dense glyphosate salt solution with water, perhaps drying (being particle, powder, tablet or agglomerate) glyphosate formulation is dissolved or is dispersed in the water.

Should be by being enough to produce the ratio of required biological effect to plant administration of exogenous chemicals.These are used ratio and show with the scale of the exogenous chemical product of per unit processing area usually, for example restrain per hectare (g/ha).Constitute " required effect " because of research, exploitation, sell and use the standard and the practice of exogenous chemical product of particular types different.For example, under the situation of weed killer herbicide, often utilize the per unit area amount of application of control 85% plant variety to define the effective ratio of coml, " control " reduces according to growth or dead the measurement.

Weeding validity is one of biological effect that can be strengthened by the present invention." weeding validity " used herein relates to measuring of any observable plant growing control, can comprise one or more following effects: kill (1), (2) suppress growth, breeding or propagation and (3) and remove, destroy or eliminate appearance and the activity of plant.

Weeding efficacy data described herein is with percentage report " inhibitory action ", abide by the standard method in this area, its plant compared with the plant of being untreated of reflection is dead and growth reduces visual assessment result is undertaken and is write down these observations by the technical staff through specialized training.In all cases, in any experiment or test, undertaken all by single-minded technical staff and suppress the percentage assessment.This class measurement depends on Monsanto Company, and is reported in the process of its weed killer herbicide business by it.

The selection that biology is effectively used ratio with regard to specific exogenous chemical product belongs to common professional of agriculture's skill.Those skilled in the art will recognize that equally individual other plant conditions, weather and growth conditions and specific exogenous chemical product and choice of formulation thereof all will influence the effect that is reached when enforcement is of the present invention.Can be used for using ratio and can depending on all above-mentioned conditions of used exogenous chemical product.About the purposes of the inventive method with regard to glyphosate herbicidal, known a lot of about suitably using the information of ratio.Over 20 years, the use of glyphosate and disclosed use research provides abundant information, and the personnel that are engaged in weeds control can therefrom be chosen in the particular environment condition, be that the effective glyphosate of weeding is used ratio at specific vegetative stage, to specific kind.

The Herbicidal combinations of glyphosate or derivatives thereof is used to control various plants in the world.Can use this based composition of herbicidally effective amount to plant, can control following one effectively and belong to or the one or more plant varieties that belong to more, but be not limited to these: abutilon, Amaranthus, artemisia, milkweed, Avena, carpetweed belongs to, Borreria, Brachiaria, mustard belongs to, Brome, chenopodium belongs to, Cirsium, dayflower belongs to, japanese bearbind belongs to, Cynodon, Cyperus, knotgrass, Echinochloa, (standing grain ginseng) belongs to, lyme grass belongs to, Equisetum, (Niu Long) the ox seedling belongs to, Helianthus, Imperata Cyrillo, Ipomoea, Kochia, lolium temulentum belongs to, mallow, Oryza, half clever Panicum, Echinochloa, Paspalum, Phalaris, reed belongs to, Polygonum, Portulaca, Cyclosorus, Pueraria lobota belongs to, rubus, Salsola, setaria, chrysanthemum harvest spp, Brassicas, Panicum, Triticum, cattail pollen belongs to, the chaste tree Macroptilium, Xanthium and Zea.

The kind of the suitable glyphosate composition of particular importance is for example following without limitation:

Annual broad leaved plant:

Piemarker (Abutilon theophrasti)

Lamb's-quarters (Amaranthus spp.)

Button fruit weeds (Borreria spp.)

Oilseed rape, canola, India mustard etc. (Brassica spp.)

Dayflower (Commelina spp.)

filaree(Erodium spp.)

Sunflower (Helianthus spp.)

Morning glory (Ipomoea spp.)

Summer cypress (Kochia scoparia)

High mallow (Malva spp.)

RHIZOMA FAGOPYRI CYMOSI, knotweed car etc. (Polygonum spp.)

Kitchen garden (Portulaca spp.)

Russia Ji (Salsola spp.)

Bur (Sida spp.)

Wild mustard (Sinapis arvensis)

Siberian cocklebur (Xanthium spp.)

Annual spire plant:

Wild oat (Avena fatua))

Carpetweed (Axonopus spp.)

Downy brome (Bromus tectorum)

Lady's-grass (Digitaria spp.)

Barnyard grass (Echinochloa crusgallo)

Eleusine indica (Eleusine indica)

Annual ryegrass (Lolium multiflorum)

Rice (Oryza sativa)

Half clever broomcorn millet (Ottochloa nodosa)

bahiagrass(Paspalum notatum)

canarygrass(Phalaris spp.)

Foxtail (Setaria spp.)

Wheat (Triticum aestivum)

Corn (Zea mays)

Perennial broad leaved plant:

Argy wormwood (Artemisia spp.)

Milkweed (Asclepias spp.)

Canada Ji (Cirsium arvense)

Field bindweed (Convolvulus arvensis)

Elegant jessamine (Pueraria spp.)

Perennial spire plant:

Brachiaria (Brachiaria spp.)

Bermuda grass (Cynodon dactylon)

yellow nutsedge(Cyperus esculentus)

purple nutsedge(C.rotundus)

Quackgrass (Elymus repens)

Draw bright grass (Bai Mao (Imperata cylindrica))

English ryegrass (Lolium perenne)

Big broomcorn millet sheep's hay (Panicum maximum)

Hairy flowered paspalum (Paspalum dilatatum)

Reed (Phragmites spp.)

Stone thatch fat meat and fine grain (Sorghum halepense)

Cattail (Typha spp.)

Other perennial plants:

Gulfweed (Equisetum spp.)

Bracken (Pteridium aquilinum)

Blackberry, blueberry (Rubus spp.)

Chaste tree beans (Ulex europaeus)

Thereby method of the present invention can be used for any above-mentioned kind because of it relates to glyphosate herbicidal.

In greenhouse test, exogenous chemical product ratio is usually less than the normal level of significance in the farmland, and validity is proved to be the indication of farmland consistency of performance under normal usage rate.But, even in most promising composition, in single greenhouse test, can not show the performance that has strengthened sometimes.Set forth as this paper embodiment, the mode of enhancing appears in a series of greenhouse tests; When differentiating so a kind of mode, this is the strong evidence that can be used for the biological humidification in farmland.

The present composition can be applied to plant by sprinkling, utilizes any routine to be used for the means of spraying liquid, for example nozzle, atomizer etc.The present composition can be used in the intensive cultivation technology, wherein adopts instrument to change the exogenous chemical product amount that is applied to the farmland different piece, and this depends on variablees such as specific plant variety, soil constitution.In a kind of embodiment of this class technology, the global positioning system of operating with the sprinkling instrument can be used in composition from aequum to the farmland different piece that use.

Composition is preferably enough rare when being applied to plant, sprays to utilize standard agricultural spray appliance easily.It is different because of a large amount of factors that the present invention preferably uses ratio, comprises type and the concentration and the related plant variety of active component.Can be used for by sprinkling use use the ratio of waterborne compositions to blade can be from about 25 to about 1000 liters of per hectares (l/ha).The aqueous solution preferably use ratio about 50 to about 300l/ha scope.

A lot of exogenous chemical product (comprising glyphosate herbicidal) must be absorbed by the plant living tissue, and transposition in plant, and purpose is to produce required biology (for example weeding) effect.Therefore, the mode of importantly using Herbicidal combinations is not answered the normal function of excessive damage and too fast interruption plant local organization, and reduces metathesis.But, the local damage of limited extent may be inessential at it on to the influence of the biological effectiveness of some exogenous chemical product, perhaps or even useful.

The following example is set forth a large amount of present compositions.The concentrate composition of a lot of glyphosates has reliable and sufficient weeding validity in greenhouse test, to guarantee under various application conditions the agricultural experiment effect to various weeds.

Except cited excipient composition, the spray composition of embodiment 1-70 also contains exogenous chemical product, for example glyphosate potassium.The amount of exogenous chemical product provides required gram per hectare (g/ha) ratio through selecting when using by the sprinkling volume of 93l/ha.Every kind of composition is all used some exogenous chemical product ratios.Therefore, unless indication is arranged in addition, when the test spray composition, the concentration of exogenous chemical product is directly proportional with exogenous chemical product ratio, and is constant but the concentration of excipient composition keeps under different exogenous chemical product ratios.

Concentrate composition is test like this, dilutes, dissolves or be dispersed in the water, forms spray composition.From the spray composition of concentrate preparation, the concentration of excipient composition changes along with the exogenous chemical product at these.

In following explanation embodiments of the invention, greenhouse and agricultural experiment have been carried out, to estimate the relative weeding validity of glyphosate composition.For the contrast purpose, comprise following composition:

Composition 139: the aqueous solution by 570g/l glyphosate IPA salt is formed, and does not add surfactant.

Composition 554: the aqueous solution by the 725g/l glyphosate potassium is formed, and does not add surfactant.

Composition 754: the aqueous solution and surfactant by 50 weight % glyphosate IPA salt are formed.This preparation is sold by Monsanto Company, and trade mark is ROUNDUP

Composition 360: the aqueous solution and surfactant by 41 weight % glyphosate IPA salt are formed.This preparation is sold by Monsanto Company, and trade mark is ROUNDUP

Composition 280: the aqueous solution and 120g/l ethoxylation etheramine surfactants (M121) by 480g a.e./l glyphosate IPA salt are formed.

Composition 560: the aqueous solution and 135g/l ethoxylation etheramine surfactants (M121) by 540g a.e./l glyphosate potassium are formed.

Composition 553: form by beef tallow amine, 74g/l polyoxyethylene 10EO cetyl ether and 12g/l myristyl dimethylamine oxide that the aqueous solution and the 111g/l ethoxylation quaternary surfactant class of 360g a.e./l glyphosate IPA salt has 25EO.

Composition 318: (9EO) alcohol alkoxylates, 97g/l ethoxylation (10EO) beef tallow amine and 85g/l n-octyl amine are formed by the aqueous solution of 487g a.e./l glyphosate potassium and 65g/l ceteth (2PO).

Composition 765: form by the aqueous solution of 472g a.e./l glyphosate potassium and 117g/l coco amine 5EO, 52g/l isostearoyl 10EO and 13g/l coco amine.

In example composition, use various proprietary excipient.They can differentiate as follows:

Index	Trade name	Manufacturer	The chemistry explanation
Index	Trade name	Manufacturer	The chemistry explanation	1816E	1816E15PA		(C16- 18)O(CH2CH2O)15(CH2)3NH2
AE10	Arosurf 66E- 10	Witco	Ethoxylation branched alkyl 10EO	1816E	1816E15PA		(C16- 18)O(CH2CH2O)15(CH2)3NH2
AE10	Arosurf 66E- 10	Witco	Ethoxylation branched alkyl 10EO	AGN68	DF 68(89)	Agnique	Silicon oil foam killer
APG67	APG 2067		Alkyl polyglycoside C8-10 alkyl and 1.7 glucose groups	AGN68	DF 68(89)	Agnique	Silicon oil foam killer
APG67	APG 2067		Alkyl polyglycoside C8-10 alkyl and 1.7 glucose groups	APG69	APG 2069		Alkyl polyglycoside C8-10 alkyl and 1.6 glucose groups
AR41	Arphos HE- 6641	Witco	C4EO3 phosphoric acid	APG69	APG 2069		Alkyl polyglycoside C8-10 alkyl and 1.6 glucose groups
AR41	Arphos HE- 6641	Witco	C4EO3 phosphoric acid	ARMC	Armeen C		Mixed C 8-16 (cocounut oil) kiber alkyl amine
ARO66	Arosurf 66 E10	Witco	PEG-20 iso stearyl ether	ARMC	Armeen C		Mixed C 8-16 (cocounut oil) kiber alkyl amine
ARO66	Arosurf 66 E10	Witco	PEG-20 iso stearyl ether	ARQ27	Arquad T- 27W		27% solution of chlorination butter trimethylammonium
ARQ37	Arquad 1237W		Chlorination cocounut oil trimethylammonium (37% aqueous solution)	ARQ27	Arquad T- 27W		27% solution of chlorination butter trimethylammonium
ARQ37	Arquad 1237W			ARQ50	Arquad C-50	Akzo	Chlorination cocounut oil trimethylammonium
B1A	B-2050-01A		Ethoxylation C16-18 straight chain alcohol 9.4EO	ARQ50	Arquad C-50	Akzo	Chlorination cocounut oil trimethylammonium
B1A	B-2050-01A		Ethoxylation C16-18 straight chain alcohol 9.4EO	B1B	B-2050-01B		Alkoxylate C16-18 straight chain alcohol 9.4EO+2.2PO
B1C	B-2050-01C		Alkoxylate C16-18 straight chain alcohol 9.4EO+4.2PO	B1B	B-2050-01B		Alkoxylate C16-18 straight chain alcohol 9.4EO+2.2PO
B1C	B-2050-01C		Alkoxylate C16-18 straight chain alcohol 9.4EO+4.2PO	B1F	B-2050-01F		Alkoxylate C16-18 straight chain alcohol 9.6EO+4.4PO
BRI35	Brij 35		Ethoxylation (23EO) lauryl ether	B1F	B-2050-01F		Alkoxylate C16-18 straight chain alcohol 9.6EO+4.4PO

BRI56	Brij 56		Polyoxyethylene (10EO) cetyl ether
BRI56	Brij 56		Polyoxyethylene (10EO) cetyl ether	BRI58	Brij 58		Polyoxyethylene (20EO) cetyl ether ether
BRI78	Brij 78		Ethoxylation (20EO) stearyl ether	BRI58	Brij 58		Polyoxyethylene (20EO) cetyl ether ether
BRI78	Brij 78		Ethoxylation (20EO) stearyl ether	CETAC			Chlorination cetyl trimethylammonium
DUO50	Duoquat T-50	Akzo	The alkyl diamine quaternary salt	CETAC			Chlorination cetyl trimethylammonium
DUO50	Duoquat T-50	Akzo	The alkyl diamine quaternary salt	EA175		Tomah	EO ether amine
ED175		Tomah	EO two-ether amine	EA175		Tomah	EO ether amine
ED175		Tomah	EO two-ether amine	EMC42	Emcol CC42	Witco	Polypropylene glycol-40 chlorination diethyl ammonium
EMUL	Emulgin L	Cognis	Cetereth 2 propoxylates 9 ethoxylates	EMC42	Emcol CC42	Witco	Polypropylene glycol-40 chlorination diethyl ammonium
EMUL	Emulgin L	Cognis	Cetereth 2 propoxylates 9 ethoxylates	ETH12	Ethomeen C12	Akzo	Ethoxylation coco amine 2EO
ETH15	Ethomeen T/15	Akzo	Ethoxylated tallow amine 5EO	ETH12	Ethomeen C12	Akzo	Ethoxylation coco amine 2EO
ETH15	Ethomeen T/15	Akzo	Ethoxylated tallow amine 5EO	ETH25	Ethomeen T/25	Akzo	15EO butter ethoxylation chlorination quaternary ammonium
EXP0A	EXP B 2030-A		Cocounut oil 15EO benyl quaternary salt	ETH25	Ethomeen T/25	Akzo	15EO butter ethoxylation chlorination quaternary ammonium
EXP0A	EXP B 2030-A		Cocounut oil 15EO benyl quaternary salt	EXP0B	EXP B 2030-B		Butter 15EO benyl quaternary salt
EXP0C	EXP B 2030- C		N, N-C16 dimethyl 14EO benyl quaternary salt	EXP0B	EXP B 2030-B		Butter 15EO benyl quaternary salt
EXP0C	EXP B 2030- C		N, N-C16 dimethyl 14EO benyl quaternary salt	EXP86	Experimental 5880-86B		Propoxylation C16-18 alcohol 10.4P0
GEN2	Genamin T200NF AV 01/37-2	Clariant	Monosubstituted ethoxy alkylamine C18NMe (EO) 7H	EXP86	Experimental 5880-86B		Propoxylation C16-18 alcohol 10.4P0
GEN2	Genamin T200NF AV 01/37-2	Clariant	Monosubstituted ethoxy alkylamine C18NMe (EO) 7H	GEN3	Genamin T200NF AV 01/37-3	Clariant	Monosubstituted ethoxy alkylamine C18NMe (EO) 15H

GEN4	Genamin T200NF AV 01/37-4	Clariant	Monosubstituted ethoxy alkylamine C18NMe (EO) 23H
GEN4	Genamin T200NF AV 01/37-4	Clariant	Monosubstituted ethoxy alkylamine C18NMe (EO) 23H	HET20	Hetoxol CS20		Ethoxylation (20EO) C16-C18 ether
INT00	Intermediate PF 8000	Witco	Phosphate tridecanol+4EO (C13) O (CH2CH2) 4 (PO (OH2))	HET20	Hetoxol CS20		Ethoxylation (20EO) C16-C18 ether
INT00	Intermediate PF 8000	Witco	Phosphate tridecanol+4EO (C13) O (CH2CH2) 4 (PO (OH2))	L770	Silwet L-77	Witco	Seven methyl trisiloxanes 7EO methyl ethers
LF700	Plurafac LF700	BASF	Alkoxylate C16-C18 alkyl	L770	Silwet L-77	Witco	Seven methyl trisiloxanes 7EO methyl ethers
LF700	Plurafac LF700	BASF	Alkoxylate C16-C18 alkyl	M117	MON 59117		Ethoxylated ether amine
M121	MON 58121	Huntsman Surfonic AGM550	(C12-14)O(CHCH3CH2)O- (CHCH3CH2)N(EO)x(EO)y x+y ＝5	M117	MON 59117		Ethoxylated ether amine
M121	MON 58121	Huntsman Surfonic AGM550	(C12-14)O(CHCH3CH2)O- (CHCH3CH2)N(EO)x(EO)y x+y ＝5	M128	MON78128		The preparation of 480g a.e./l glyphosate MEA and 120g/l M121
M368	MON 78368		357g a.e./l glyphosate IPA and 57g/l EMUL, the preparation of 85g/l ethoxylation (10EO) beef tallow amine and 57g/l n-octyl amine	M128	MON78128
M368	MON 78368			M619	MON68619		360g a.e./l glyphosate IPA and 70g/l ETH25, the preparation of 46 g/l BRI56 and 23g/l CETAC
M620	MON68620		360g a.e./l glyphosate IPA and 83g/l ETH25, the preparation of 56 g/l BRI56 and 27g/l CETAC	M619	MON68619
M620	MON68620			MPE01	MPEAE		EO-ether amine

MT13	M-T4513-2	Tomah	C14-15 dimethyl ether amine 13EO
MT13	M-T4513-2	Tomah	C14-15 dimethyl ether amine 13EO	NEO25	Neo 25-9		Ethoxylated alcohol with C12-15 hydrophobic group and 9EO
NO13	Nopar 13	Exxon	Routine paraffin wax	NEO25	Neo 25-9		Ethoxylated alcohol with C12-15 hydrophobic group and 9EO
NO13	Nopar 13	Exxon	Routine paraffin wax	OA		Fluka	Octylame
PG069	APG-2069	Agrimul APG	C9-C11 alkyl ether glucosides	OA		Fluka	Octylame
PG069	APG-2069	Agrimul APG	C9-C11 alkyl ether glucosides	S01			Cetyl-20 (oxygen ethylidene) dimethylamine
S02			Cetyl-12 (oxyalkylene)-3-amino-third-1-amine	S01			Cetyl-20 (oxygen ethylidene) dimethylamine
S02			Cetyl-12 (oxyalkylene)-3-amino-third-1-amine	S03			Cetyl/octadecyl (oxygen propylidene)-nine (oxyalkylene)-dimethylamine
S04			Butter-two (oxygen propylidene)-nine (oxyalkylene)-dibutyl amine	S03
S04				S05			Butter-two (oxygen propylidene)-nine (oxyalkylenes)-3 '-amino-propylamine
S06			Butter-two (oxygen propylidene)-nine (oxyalkylene)-N-methyl-aminoglucoses	S05
S06				S07			Cetyl-five (oxygen propylidene)-20 (oxyalkylene)-dimethylamine
S08			Tridecyl-six (oxyalkylene)-three (oxygen propylidene)-dimethylamine	S07
S08				S09			N-methyl octadecyl Glucosamine alcohol
S10			Cetyl-20 (oxyalkylene)-dimethylamine	S09			N-methyl octadecyl Glucosamine alcohol

S11	Cetyl-20 (oxyalkylene)-Tris
S11	Cetyl-20 (oxyalkylene)-Tris	S12	Cetyl-20 (oxyalkylene)-methylamine
S13	Cetyl-ten (oxyalkylene)-N-methyl-aminoglucose	S12	Cetyl-20 (oxyalkylene)-methylamine
S13	Cetyl-ten (oxyalkylene)-N-methyl-aminoglucose	S14	1-deoxidation-1-(octadecyl amino)-D-glucitol
S15	Butter-two (oxygen propylidene)-nine (oxyalkylene)-N-methyl-aminoglucoses	S14	1-deoxidation-1-(octadecyl amino)-D-glucitol
S15		S16	N-dodecyl aminoglucose
S17	N-methyl octadecylamine glucitol	S16	N-dodecyl aminoglucose
S17	N-methyl octadecylamine glucitol	S18	N, N-dimethyl stearyl glucitol chloro amido quaternary salt
S19	The ethoxylation cetanol	S18	N, N-dimethyl stearyl glucitol chloro amido quaternary salt
S19	The ethoxylation cetanol	S20	N-methyl dodecyl Glucosamine alcohol
S21	N, N-dimethyl dodecyl glucitol chloro amido quaternary salt	S20	N-methyl dodecyl Glucosamine alcohol
S21	N, N-dimethyl dodecyl glucitol chloro amido quaternary salt	S22	10EO isotridecyl phosphate (60% monoesters)
S23	The n-hexyl aminoglucose	S22	10EO isotridecyl phosphate (60% monoesters)
S23	The n-hexyl aminoglucose	S24	The dodecyl aminoglucose
S39	Eicosane-1,20-two (chlorination trimethylammonium)	S24	The dodecyl aminoglucose
S39	Eicosane-1,20-two (chlorination trimethylammonium)	S40	Dodecane-1,12-two (chlorination trimethylammonium)
S41	Hexadecane-1,16-two (chlorination trimethylammonium)	S40	Dodecane-1,12-two (chlorination trimethylammonium)
S41	Hexadecane-1,16-two (chlorination trimethylammonium)	S42	N, N-octyl group glucitol 1,3-propane
S43	N, N-dodecyl glucitol 1,3-propane	S42	N, N-octyl group glucitol 1,3-propane

S44	N, N-hexyl glucitol 1,3-propane
S44	N, N-hexyl glucitol 1,3-propane	S45	N, N '-dioctyl-1,3-diaminopropanes eight (oxyalkylene)
S46	N, N '-two (dodecyl)-1,3-diaminopropanes 20 (oxyalkylene)	S45	N, N '-dioctyl-1,3-diaminopropanes eight (oxyalkylene)
S46	N, N '-two (dodecyl)-1,3-diaminopropanes 20 (oxyalkylene)	S47	N, N '-didecyl-1,3-diaminopropanes ten (oxyalkylene)
S48	N, N '-didecyl-1,3-diaminopropanes 18 (oxyalkylene)	S47	N, N '-didecyl-1,3-diaminopropanes ten (oxyalkylene)
S48	N, N '-didecyl-1,3-diaminopropanes 18 (oxyalkylene)	S49	N, N '-two (dodecyl)-1,3-diaminopropanes ten (oxyalkylene)
S50	N, N '-two (dodecyl)-1,3-diaminopropanes 20 (oxyalkylene)	S49	N, N '-two (dodecyl)-1,3-diaminopropanes ten (oxyalkylene)
S50	N, N '-two (dodecyl)-1,3-diaminopropanes 20 (oxyalkylene)	S51	Dodecyl-four (oxyalkylene) Tris
S52	Three (methylols), N-dodecyl aminomethane	S51	Dodecyl-four (oxyalkylene) Tris
S52	Three (methylols), N-dodecyl aminomethane	S53	Dodecyl-four (oxyalkylene) dimethylamine
S54	Cetyl-ten (oxyalkylene) dimethylamine	S53	Dodecyl-four (oxyalkylene) dimethylamine
S54	Cetyl-ten (oxyalkylene) dimethylamine	S55	Dodecyl-four (oxyalkylene) chlorination trimethylammonium
S56	Cetyl-ten (oxyalkylene) chlorination trimethylammonium	S55	Dodecyl-four (oxyalkylene) chlorination trimethylammonium
S56	Cetyl-ten (oxyalkylene) chlorination trimethylammonium	S57	Cetyl-20 (oxyalkylene) chlorination trimethylammonium
S58	Monosubstituted ethoxy alkylamine C18NMe (EO) 7.5H	S57	Cetyl-20 (oxyalkylene) chlorination trimethylammonium

S59	Monosubstituted ethoxy alkylamine C18NMe (EO) 11H
S59	Monosubstituted ethoxy alkylamine C18NMe (EO) 11H	S60	N-methyl dodecyl Glucosamine alcohol
S61	Ethoxylation cetanol (10EO)	S60	N-methyl dodecyl Glucosamine alcohol
S61	Ethoxylation cetanol (10EO)	S62	Cetyl-ten (oxyalkylene)-tris
S65	Hot Glucosamine alcohol	S62	Cetyl-ten (oxyalkylene)-tris
S65	Hot Glucosamine alcohol	S66	Dodecyl-four (oxyalkylene) methylamine
S67	Cetyl-ten (oxyalkylene) methylamine	S66	Dodecyl-four (oxyalkylene) methylamine
S67	Cetyl-ten (oxyalkylene) methylamine	S68	Cetyl-20 (oxyalkylene) methylamine
S71	Two-[N-cetyl-ten (oxyalkylene)-propylidene] chlorination two ammoniums	S68	Cetyl-20 (oxyalkylene) methylamine
S71		S72	Two-[N-cetyl-20 (oxyalkylene)-propylidene-chlorination two ammoniums
S73	3-(N-dodecyl-methylamino)-1,2-propane diols-five (oxyalkylene)	S72
S73		S74	3-(N-dodecyl-methylamino)-1,2-propane diols-ten (oxyalkylene)
S75	3-(N-methyl-octadecyl amino)-1,2-propane diols-five (oxyalkylene)	S74
S75		S76	3-(N-methyl-octadecyl amino)-1,2-propane diols-ten (oxyalkylene)
S77	Cetyl/octadecyl-two (oxygen propylidene)-nine (oxyalkylene)-dimethylamine	S76

S78	1-hydroxyl-3-(N-methyl-octadecyl amino)-propan-2-ol-five (oxyalkylene)
S78		S79	1-hydroxyl-3-(N-methyl-octadecyl amino)-propan-2-ol-nine (oxyalkylene)
S80	1-hydroxyl-3-(N-methyl-dodecyl amino)-propan-2-ol-five (oxyalkylene)	S79
S80		S81	Cetyl-ten (oxyalkylene)-hydroxy ethylene amine
S82	Cetyl-ten (oxyalkylene)-2 '-methylamino-ethylidene-N-methyl-amine	S81	Cetyl-ten (oxyalkylene)-hydroxy ethylene amine
S82		S83	Cetyl-ten (oxyalkylene)-2 '-dimethylamino-ethylidene-N-methyl-amine
S84	Cetyl-ten (oxyalkylene)-3 '-amine-2 '-hydroxyl propylamine	S83
S84	Cetyl-ten (oxyalkylene)-3 '-amine-2 '-hydroxyl propylamine	S85	Ethoxylation methyl stearylamine 7.5EO 7.5EO
S86	Ethoxylation methyl stearylamine 5.9EO 5.9EO	S85	Ethoxylation methyl stearylamine 7.5EO 7.5EO
S86	Ethoxylation methyl stearylamine 5.9EO 5.9EO	S87	Ethoxylation methyl stearylamine 11EO 11EO
S88	(C4H9)2N(CH2)3NH2	S87	Ethoxylation methyl stearylamine 11EO 11EO
S88	(C4H9)2N(CH2)3NH2	S89	(C4H9)2N(CH2)3NMe2
S90	(C4H9)2N+(I-)(CH2)3N+Me3(I-)	S89	(C4H9)2N(CH2)3NMe2
S90	(C4H9)2N+(I-)(CH2)3N+Me3(I-)	S91	20 (oxyalkylene) cetyl-N, N dimethylamine

S92			Butter-20 (oxyalkylene)-dimethylamine
S92			Butter-20 (oxyalkylene)-dimethylamine	S93			Butter-25 (oxyalkylene)-dimethylamine
S94			Butter-20 (oxyalkylene)-Tris	S93			Butter-25 (oxyalkylene)-dimethylamine
S94			Butter-20 (oxyalkylene)-Tris	S95			Butter-25 (oxyalkylene)-Tris
S96			Ten (oxyalkylene) cetyl-N, N dimethylamine	S95			Butter-25 (oxyalkylene)-Tris
S96			Ten (oxyalkylene) cetyl-N, N dimethylamine	S97			Ten (oxyalkylene) eicosyl-N, N dimethylamine
S98			Cetyl-20 (oxyalkylene)-N-methyl-lauryl amine	S97			Ten (oxyalkylene) eicosyl-N, N dimethylamine
S98			Cetyl-20 (oxyalkylene)-N-methyl-lauryl amine	S99			Two-(cocounut oil amino)-20 (oxyalkylene)
S100			3-butter amino-1,2-propane diols-15 (oxyalkylene)	S99			Two-(cocounut oil amino)-20 (oxyalkylene)
S100			3-butter amino-1,2-propane diols-15 (oxyalkylene)	S101			3-butter amino-1,2-propane diols-23 (oxyalkylene)
S102			3-butter amino-1,2-propane diols-27 (oxyalkylene)	S101			3-butter amino-1,2-propane diols-23 (oxyalkylene)
S102			3-butter amino-1,2-propane diols-27 (oxyalkylene)	S103			3-cocounut oil amino-1,2-propane diols-23 (oxyalkylene)
S104			3-cocounut oil amino-1,2-propane diols-30 (oxyalkylene)	S103			3-cocounut oil amino-1,2-propane diols-23 (oxyalkylene)
S104			3-cocounut oil amino-1,2-propane diols-30 (oxyalkylene)	SC85	SC1485	Albermarle	Myristyl dimethylamine oxide 8
SUR10	Surfonic L12- 10	Huntsman	C10-12 alcohol ethoxylate 10EO	SC85	SC1485	Albermarle	Myristyl dimethylamine oxide 8
SUR10	Surfonic L12- 10	Huntsman	C10-12 alcohol ethoxylate 10EO	SUR12	Surfonic L12- 12	Huntsman	C10-12 alcohol ethoxylate 12EO

SUR50	Surfonic AGM-50	Huntsman	Alkyl ether amine
SUR50	Surfonic AGM-50	Huntsman	Alkyl ether amine	SUR6	Surfonic L12- 6	Huntsman	C10-12 alcohol ethoxylate 6EO
SUR9	Surfonic TDA- 9	Huntsman	Tridecyl alcohol 9EO	SUR6	Surfonic L12- 6	Huntsman	C10-12 alcohol ethoxylate 6EO
SUR9	Surfonic TDA- 9	Huntsman	Tridecyl alcohol 9EO	T003A	B-1910-03A		Beef tallow amine+10EO
T003B	B-1910-03B		Beef tallow amine+15EO	T003A	B-1910-03A		Beef tallow amine+10EO
T003B	B-1910-03B		Beef tallow amine+15EO	T003C	B-1910-03C		Beef tallow amine+20EO
T003D	B-1910-03D		Beef tallow amine+25EO	T003C	B-1910-03C		Beef tallow amine+20EO
T003D	B-1910-03D		Beef tallow amine+25EO	T003E	B-1910-03E		Beef tallow amine+30EO
T23E2	T23E1PAE2	Tomah	Have the ether amine of C12-13 straight chain alcohol hydrophobic group, have 1EO and 2EO on the amine, C12-13O (OCH2CH2) CH2CH2CH2-N (EO) x (EO) y x=y=2	T003E	B-1910-03E		Beef tallow amine+30EO
T23E2	T23E1PAE2	Tomah		T23E5	T23E1PAE5	Tomah	Have the ether amine of C12-13 straight chain alcohol hydrophobic group, have 1EO and 5EO on the amine, C12-13O (OCH2CH2) CH2CH2CH2N (E O) x (EO) y x=y=5
TAM12	Tomadol 25- 12		C12-C15 alcohol ethoxylate (11.9EO) (11.9EO)	T23E5	T23E1PAE5	Tomah
TAM12	Tomadol 25- 12		C12-C15 alcohol ethoxylate (11.9EO) (11.9EO)	TED5	E-D-17-5	Tomah	C13O(CH2)3N(EO)x(CH2)3N(EO) y(EO)z x+y+z＝5
TER9	Tergitol 15S- 9		Ethoxylation (9EO) C11-15 secondary alcohol	TED5	E-D-17-5	Tomah	C13O(CH2)3N(EO)x(CH2)3N(EO) y(EO)z x+y+z＝5
TER9	Tergitol 15S- 9		Ethoxylation (9EO) C11-15 secondary alcohol	TPA0E	DPA-400E	Tomah	The PEG400 (NH2) that is converted into diether amine is 3O (CH2CH2) n (CH2) 3-(NH2) (CH2)

TPAE6	NDPA-14-E6	Tomah	Be converted into symmetrical diether amine and with the hexamethylene glycol (Tomah NDPA) of 6EO ethoxylation with 6EO
TPAE6	NDPA-14-E6	Tomah		TQ14	Q14-M3	Tomah	Chlorination trimethyl isodecyl oxygen base propylamine (season ether amine)
TQ17	Q17-M3	Tomah	The different tridecane oxygen of chlorination trimethyl base propylamine (season ether amine)	TQ14	Q14-M3	Tomah
TQ17	Q17-M3	Tomah		VAR02	Varonic K-202	Witco	Ethoxylation coco amine 2EO
VAR05	Varonic K-205	Witco	Ethoxylation coco amine 5EO	VAR02	Varonic K-202	Witco	Ethoxylation coco amine 2EO
VAR05	Varonic K-205	Witco	Ethoxylation coco amine 5EO	WEX5	Experimental B1910-5	Witco	N-dodecyloxy propyl group-1,3-diaminopropanes 3.4EO
WEX6	Experimental B1910-6	Witco	N-dodecyloxy propyl group-1,3-diaminopropanes 6.1EO	WEX5	Experimental B1910-5	Witco	N-dodecyloxy propyl group-1,3-diaminopropanes 3.4EO
WEX6	Experimental B1910-6	Witco	N-dodecyloxy propyl group-1,3-diaminopropanes 6.1EO	WEX7	Experimental B1910-7	Witco	N-dodecyloxy propyl group-1,3-diaminopropanes 9.5EO
WIT05	Witcamine TAM 105	Witco	Ethoxylated tallow amine 10EO	WEX7	Experimental B1910-7	Witco	N-dodecyloxy propyl group-1,3-diaminopropanes 9.5EO
WIT05	Witcamine TAM 105	Witco	Ethoxylated tallow amine 10EO	WIT305	Witcamine TAM 305	Witco	Coco amine 5EO
WIT60	Witcamine TAM 60		Ethoxylated tallow amine 6EO	WIT305	Witcamine TAM 305	Witco	Coco amine 5EO
WIT60	Witcamine TAM 60		Ethoxylated tallow amine 6EO	WIT80	Witcamine TAM 80	Witco	Ethoxylated tallow amine 8EO

Unless indication is arranged in addition, the water-based spray composite is preparation like this, and surfactant is mixed with an amount of glyphosate potassium, and the latter adds as 47.5% (w/w) a.e. solution.Place 55 ℃ to 60 ℃ water-baths to reach about 30 minutes composition, until the homogeneous solution that obtains clarifying.In some composition, before mixing, surfactant is melted.

Following method is used for the experimental example composition, and to measure weeding validity, other has except the indication.

With shown in the seed of plant variety place 88mm ²In the soil mixture in jar, soil mixture through sterilization, is pressed 3.6kg/m in advance in advance ³Ratio imposes 14-14-14 NPK slow release fertilizer.Jar is placed in the greenhouse that has grou1ndwater irrigation.Be unearthed an about week of back, reduce thickness of sowing as required, comprise and remove any unhealthy or unusual plant, to produce a series of uniform test tanks.

In the greenhouse, keep plant during test duration, to survive, accept illumination in 14 hours every day at least.If natural daylight is not enough to satisfy daily requirement, adopt intensity about 475 little Einsteinian artificial lights to remedy difference.Illumination temperature is not accurately control, but average about 29 ℃ by day, on average about 21 ℃ at night.During whole test, use the grou1ndwater irrigation plant, to guarantee sufficient soil moisture level.

Experimental program according to completely random makes jar be subjected to different processing, and is sextuplicate.One group of jar is unprocessed, as reference, can estimate the effect of processing subsequently.

The track sprayer that the 9501E nozzle is equipped with in utilization is used glyphosate composition, and nozzle is through calibration, the sprayed volume of 93 liters of per hectares of release (l/ha) under 165 kPas of (kPa) pressure.After the processing, jar is put back to the greenhouse, until evaluation.

Processing is to utilize rare waterborne compositions to carry out.Can directly make spray composite, perhaps the concentrate composition of dilute with water preformulation from each composition.

About the evaluation of weeding validity, by all plants in single-minded technical staff's checkout facility, his record controls percentage, this is to compare the visual measures that gained is handled validity at every turn with the plant of being untreated.0% control rate represents there is not effect, and 100% control rate represents that all plants are dead fully.The control % value of being reported is represented the average of each all replicate tests of handling.

Embodiment 1

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 1a.

Table 1a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	734A9M	K	30	S16	4.5	PG069	5.5
734B3K	K	30	S60	4.7	PG069	5.3	734A9M	K	30	S16	4.5	PG069	5.5
734B3K	K	30	S60	4.7	PG069	5.3	734C1A	K	30	S21	5.0	PG069	5.0
734D6O	K	30			PG069	10.0	734C1A	K	30	S21	5.0	PG069	5.0
734D6O	K	30			PG069	10.0	734E9D	K	4.3	S16	1.4
734F2H	K	30	S60	10.0			734E9D	K	4.3	S16	1.4
734F2H	K	30	S60	10.0			734G9 W	K	30	S21	10.0

Plantation piemarker (Abutilon theophrasti, ABUTH)) and Japanese millet (Echinochloa crus-galli, var.frumentae ECHCF) are handled according to above-mentioned standard method.Use table 1a composition and Comparative composition 139,553 and 360.Get all replicate tests average of each processing, the result is shown in table 1b and 1c.

Table 1b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	62.5	75.8	80.8
360	45.0	81.7	85.0	91.7	139	0	62.5	75.8	80.8
360	45.0	81.7	85.0	91.7	553	64.2	85.0	85.8	90.0
734A9M	0	60.8	77.5	84.2	553	64.2	85.0	85.8	90.0
734A9M	0	60.8	77.5	84.2	734B3K	0	63.3	80.8	83.3
734C1A	17.5	74.2	80.8	84.2	734B3K	0	63.3	80.8	83.3
734C1A	17.5	74.2	80.8	84.2	734D6O	10.0	61.7	78.3	71.7
734E9D	30.8	68.3	81.7	83.3	734D6O	10.0	61.7	78.3	71.7
734E9D	30.8	68.3	81.7	83.3	734F2H	41.7	75.8	83.3	85.8
734G9W	30.0	79.2	84.2	87.5	734F2H	41.7	75.8	83.3	85.8

Table 1c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	40.8	45.8	62.5
360	56.7	77.5	80.0	90.8	139	0	40.8	45.8	62.5
360	56.7	77.5	80.0	90.8	553	64.2	79.2	87.5	89.2
734A9M	53.3	71.7	83.3	87.5	553	64.2	79.2	87.5	89.2
734A9M	53.3	71.7	83.3	87.5	734B3K	35.8	70.8	85.5	89.2
734C1A	23.3	73.3	78.3	86.5	734B3K	35.8	70.8	85.5	89.2
734C1A	23.3	73.3	78.3	86.5	734D6O	44.2	74.2	75.8	47.5
734E9D	24.2	66.7	68.3	73.3	734D6O	44.2	74.2	75.8	47.5
734E9D	24.2	66.7	68.3	73.3	734F2H	16.7	54.2	68.3	73.3
734G9W	12.5	59.2	67.5	71.7	734F2H	16.7	54.2	68.3	73.3

ABUTH and ECHCF result: the weeding validity that composition 734F2H and 734G9W are similar to piemarker (ABUTH) performance and Comparative composition 360.

Embodiment 2

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 2a.

Table 2a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	736A4D	K	30	S16	2.6	S22	7.4
736B7S	K	30	S09	2.8	S22	7.2	736A4D	K	30	S16	2.6	S22	7.4
736B7S	K	30	S09	2.8	S22	7.2	736C8B	K	30	S18	3.0	S22	7.0
736D5V	K	30			S22	10.0	736C8B	K	30	S18	3.0	S22	7.0
736D5V	K	30			S22	10.0	734E1D	K	4.3	S16	1.4
734F9A	K	30	S09	10.0			734E1D	K	4.3	S16	1.4
734F9A	K	30	S09	10.0			734G3K	K	30	S18	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 2a composition and Comparative composition 554,553 and 360.Get all replicate tests average of each processing, the result is shown in table 2b and 2c.

Table 2b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	8.3	41.7	55.8
360	0	58.3	81.7	86.7	554	0	8.3	41.7	55.8
360	0	58.3	81.7	86.7	553	26.3	83.3	89.2	94.2
736A4D	0	25	52.5	61.7	553	26.3	83.3	89.2	94.2
736A4D	0	25	52.5	61.7	736B7S	0	45	65.8	74.2
736C8B	4.2	31.7	65	80.8	736B7S	0	45	65.8	74.2
736C8B	4.2	31.7	65	80.8	736D5V	0	5.8	50.8	64.2
734E1D	0	32.5	66.7	75.8	736D5V	0	5.8	50.8	64.2
734E1D	0	32.5	66.7	75.8	734F9A	0	44.2	68.3	77.5
734G3K	0	42.5	70	78.3	734F9A	0	44.2	68.3	77.5

Table 2c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	8.3	18.3	39.2
360	10.8	71.7	75	79.2	554	0	8.3	18.3	39.2
360	10.8	71.7	75	79.2	553	30	71.7	79.2	91.7
736A4D	13.3	46.7	65	69.2	553	30	71.7	79.2	91.7
736A4D	13.3	46.7	65	69.2	736B7S	0	58.3	67.5	70
736C8B	0	58.3	66.7	75.8	736B7S	0	58.3	67.5	70
736C8B	0	58.3	66.7	75.8	736D5V	0	26.7	53.3	67.5
734E1D	46.7	63.3	70	71.7	736D5V	0	26.7	53.3	67.5
734E1D	46.7	63.3	70	71.7	734F9A	3.3	48.3	55.8	70
734G3K	0	28.3	62.5	68.3	734F9A	3.3	48.3	55.8	70

ABUTH and ECHCF result: all compositions all show the weeding validity that is weaker than Comparative composition 360 and 553 to ABUTH and ECHCF.

Embodiment 3

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 3a.

Table 3a

Composition	Salt	g/l	Component 1	g/l	Component 2	g/l
Composition	Salt	g/l	Component 1	g/l	Component 2	g/l	664A5A	K	540	M121	135.02
687A1J	K	540	M121	101.26	S23	33.75	664A5A	K	540	M121	135.02
687A1J	K	540	M121	101.26	S23	33.75	687B8S	K	540	M121	89.92	S23	44.96
687C8L	K	540	M121	67.50	S23	67.50	687B8S	K	540	M121	89.92	S23	44.96
687C8L	K	540	M121	67.50	S23	67.50	688D3F	K	540	M121	101.27	S24	33.76
688E2M	K	540	M121	89.91	S24	44.96	688D3F	K	540	M121	101.27	S24	33.76
688E2M	K	540	M121	89.91	S24	44.96	688F9D	K	540	M121	67.51	S24	67.51
360		360					688F9D	K	540	M121	67.51	S24	67.51
360		360					754		445

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 3a composition and Comparative composition 139,554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 3b and 3c.

Table 3b:ABUTH control %

Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha
Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha	139	16.7	40.0	61.7	73.3
554	9.2	30.0	47.5	60.0	139	16.7	40.0	61.7	73.3
554	9.2	30.0	47.5	60.0	360	66.7	71.7	92.7	96.3
664A5A	35.0	42.5	74.2	86.8	360	66.7	71.7	92.7	96.3
664A5A	35.0	42.5	74.2	86.8	687A1J	21.7	40.0	55.0	82.5
687B8S	21.7	31.7	73.3	78.3	687A1J	21.7	40.0	55.0	82.5
687B8S	21.7	31.7	73.3	78.3	687C8L	15.8	43.3	68.3	70.0
688D3F	26.7	36.7	60.0	68.3	687C8L	15.8	43.3	68.3	70.0
688D3F	26.7	36.7	60.0	68.3	688E2M	18.3	43.3	51.7	73.3
688F9D	10.0	31.7	49.2	76.7	688E2M	18.3	43.3	51.7	73.3
688F9D	10.0	31.7	49.2	76.7	754	58.3	61.7	83.3	89.3

Table 3c:ECHCF control %

Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha
Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha	139	12.5	43.3	44.2	65.8
554	6.7	26.7	50.0	53.3	139	12.5	43.3	44.2	65.8
554	6.7	26.7	50.0	53.3	360	79.2	90.0	99.2	99.2
664A5A	65.0	83.3	97.0	98.3	360	79.2	90.0	99.2	99.2
664A5A	65.0	83.3	97.0	98.3	687A1J	60.0	81.7	88.2	99.2
687B8S	53.3	75.0	90.7	97.8	687A1J	60.0	81.7	88.2	99.2
687B8S	53.3	75.0	90.7	97.8	687C8L	55.8	70.0	87.5	97.7
688D3F	63.3	81.7	96.2	98.7	687C8L	55.8	70.0	87.5	97.7
688D3F	63.3	81.7	96.2	98.7	688E2M	60.0	80.8	96.2	93.3
688F9D	61.7	75.0	93.8	98.7	688E2M	60.0	80.8	96.2	93.3
688F9D	61.7	75.0	93.8	98.7	754	61.7	86.7	92.3	100.0

Embodiment 4

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 4a.

Table 4a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	735A18H	K	4.3	S16	0.5	S19	6.7
738A9J	K	30	S17	4.0	S19	6.0	735A18H	K	4.3	S16	0.5	S19	6.7
738A9J	K	30	S17	4.0	S19	6.0	738B4H	K	30	S18	4.2	S19	5.8
735D16X	K	4.3			S19	1.4	738B4H	K	30	S18	4.2	S19	5.8
735D16X	K	4.3			S19	1.4	734E19H	K	4.3	S16	1.4
737C13A	K	4.3	S17	1.4			734E19H	K	4.3	S16	1.4
737C13A	K	4.3	S17	1.4			737D6G	K	30	S18	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 4a composition and Comparative composition 554,360 and 553.Get all replicate tests average of each processing, the result is shown in table 4b and 4c.

Table 4b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	13.3	30.8	58.3
360	10.0	78.3	85.0	92.5	554	0	13.3	30.8	58.3
360	10.0	78.3	85.0	92.5	553	64.2	82.5	95.0	97.2
735A18H	25.8	57.5	78.3	87.5	553	64.2	82.5	95.0	97.2
735A18H	25.8	57.5	78.3	87.5	738A9J	16.7	63.3	80.0	86.7
738B4H	25.8	68.3	81.7	87.5	738A9J	16.7	63.3	80.0	86.7
738B4H	25.8	68.3	81.7	87.5	735D16X	17.5	74.2	85.0	86.7
734E19H	15.0	42.5	70.8	81.7	735D16X	17.5	74.2	85.0	86.7
734E19H	15.0	42.5	70.8	81.7	737C13A	16.7	38.3	68.3	77.5
737D6G	10.0	53.3	77.5	83.3	737C13A	16.7	38.3	68.3	77.5

Table 4c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	0	19.2	28.3
360	20.8	71.7	81.7	89.2	554	0	0	19.2	28.3
360	20.8	71.7	81.7	89.2	553	65.8	75.0	84.2	90.5
735A18H	61.7	64.2	69.2	75.0	553	65.8	75.0	84.2	90.5
735A18H	61.7	64.2	69.2	75.0	738A9J	30.0	65.0	72.5	78.3
738B4H	53.3	69.2	73.3	81.3	738A9J	30.0	65.0	72.5	78.3
738B4H	53.3	69.2	73.3	81.3	735D16X	38.3	40.0	65.0	70.8
734E19H	13.3	55.8	65.0	69.2	735D16X	38.3	40.0	65.0	70.8
734E19H	13.3	55.8	65.0	69.2	737C13A	69.2	30.0	69.2	59.2
737D6G	15.0	66.7	73.3	70.8	737C13A	69.2	30.0	69.2	59.2

Embodiment 5

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 5a.

Table 5a

Compound	Salt	g/l	Component 1	g/l	Component 2	g/l
Compound	Salt	g/l	Component 1	g/l	Component 2	g/l	734A9D	K	30	S16	4.5	PG069	5.5
734B7Y	K	30	S09	4.7	PG069	5.3	734A9D	K	30	S16	4.5	PG069	5.5
734B7Y	K	30	S09	4.7	PG069	5.3	734C9X	K	30	S18	5.0	PG069	5.0
734D3J	K	30			PG069	10.0	734C9X	K	30	S18	5.0	PG069	5.0
734D3J	K	30			PG069	10.0	734E5G	K	4.3	S16	1.4
734F8D	K	30	S09	10.0			734E5G	K	4.3	S16	1.4
734F8D	K	30	S09	10.0			734G3H	K	30	S18	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 5a composition and Comparative composition 139,360 and 553.Get all replicate tests average of each processing, the result is shown in table 5b and 5c.

Table 5b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	62.5	75.8	80.8
360	45.0	81.7	85.0	91.7	139	0	62.5	75.8	80.8
360	45.0	81.7	85.0	91.7	553	64.2	85.0	85.8	90.0
734A9D	0	60.8	77.5	84.2	553	64.2	85.0	85.8	90.0
734A9D	0	60.8	77.5	84.2	734B7Y	0	63.3	80.8	83.3
734C9X	17.5	74.2	80.8	84.2	734B7Y	0	63.3	80.8	83.3
734C9X	17.5	74.2	80.8	84.2	734D3J	10.0	61.7	78.3	71.7
734E5G	30.8	68.3	81.7	83.3	734D3J	10.0	61.7	78.3	71.7
734E5G	30.8	68.3	81.7	83.3	734F8D	41.7	75.8	83.3	85.8
734G3H	30.0	79.2	84.2	87.5	734F8D	41.7	75.8	83.3	85.8

Table 5c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	40.8	45.8	62.5
360	56.7	77.5	80.0	90.8	139	0	40.8	45.8	62.5
360	56.7	77.5	80.0	90.8	553	64.2	79.2	87.5	89.2
734A9D	53.3	71.7	83.3	87.5	553	64.2	79.2	87.5	89.2
734A9D	53.3	71.7	83.3	87.5	734B7Y	35.8	70.8	85.5	89.2
734C9X	23.3	73.3	78.3	86.5	734B7Y	35.8	70.8	85.5	89.2
734C9X	23.3	73.3	78.3	86.5	734D3J	44.2	74.2	75.8	47.5
734E5G	24.2	66.7	68.3	73.3	734D3J	44.2	74.2	75.8	47.5
734E5G	24.2	66.7	68.3	73.3	734F8D	16.7	54.2	68.3	73.3
734G3H	12.5	59.2	67.5	71.7	734F8D	16.7	54.2	68.3	73.3

ABUTH and ECHCF result: the weeding validity that composition 734F8D and 734G3H performance and Comparative composition 360 are similar.

Embodiment 6

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 6a.

Table 6a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	627A5F	K	30	S42	10.0
627B8U	K	30	S43	10.0	627A5F	K	30	S42	10.0
627B8U	K	30	S43	10.0	627C9Z	K	30	S44	10.0
627D4W	K	30	S45	10.0	627C9Z	K	30	S44	10.0
627D4W	K	30	S45	10.0	627E7V	K	30	S46	10.0
627F3K	K	30	S47	10.0	627E7V	K	30	S46	10.0
627F3K	K	30	S47	10.0	627G8M	K	30	S48	10.0
627H2X	K	30	S49	10.0	627G8M	K	30	S48	10.0
627H2X	K	30	S49	10.0	627I3E	K	30	S50	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.

Use table 6a composition and Comparative composition 554,754 and 553.Get all replicate tests average of each processing, the result is shown in table 6b and 6c.

Table 6b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	12.5	26.7	60.0
754	0	76.7	85.8	90.8	554	0	12.5	26.7	60.0
754	0	76.7	85.8	90.8	553	55.8	84.2	91.7	95.7
627A5F	8.3	45.8	55.0	74.2	553	55.8	84.2	91.7	95.7
627A5F	8.3	45.8	55.0	74.2	627B8U	3.3	54.2	77.5	87.5
627C9Z	0	21.7	52.5	81.7	627B8U	3.3	54.2	77.5	87.5
627C9Z	0	21.7	52.5	81.7	627D4W	22.5	66.7	87.5	89.2
627E7V	28.3	62.5	80.0	89.2	627D4W	22.5	66.7	87.5	89.2
627E7V	28.3	62.5	80.0	89.2	627F3K	5.8	70.8	87.5	90.8
627G8M	10.0	75.0	81.7	90.8	627F3K	5.8	70.8	87.5	90.8
627G8M	10.0	75.0	81.7	90.8	627H2X	5.0	60.8	84.2	84.5
627I3E	18.3	71.7	86.7	91.7	627H2X	5.0	60.8	84.2	84.5

Table 6c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	0	3.3	4.2
754	0	66.7	70.8	77.5	554	0	0	3.3	4.2
754	0	66.7	70.8	77.5	553	29.2	72.5	82.5	87.5
627A5F	5.0	39.2	49.2	52.5	553	29.2	72.5	82.5	87.5
627A5F	5.0	39.2	49.2	52.5	627B8U	1.7	30.8	54.2	67.5
627C9Z	1.7	60.0	66.7	74.2	627B8U	1.7	30.8	54.2	67.5
627C9Z	1.7	60.0	66.7	74.2	627D4W	37.5	65.8	66.7	74.2
627E7V	22.5	59.2	71.7	73.3	627D4W	37.5	65.8	66.7	74.2
627E7V	22.5	59.2	71.7	73.3	627F3K	42.5	70.0	73.3	78.3
627G8M	47.5	69.2	70.8	72.5	627F3K	42.5	70.0	73.3	78.3
627G8M	47.5	69.2	70.8	72.5	627H2X	34.2	65.8	73.3	80.0
627I3E	36.7	68.3	73.3	76.7	627H2X	34.2	65.8	73.3	80.0

ABUTH and ECHCF result: the weeding validity that composition 627D4W and 627I3E performance and Comparative composition 754 are similar.

Embodiment 7

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 7a.

Table 7a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l	449A2Q	K	540	ETH12	45.00	WIT60	45.00	TAM12	45.00
449B8 W	K	540	ETH12	33.75	WIT60	50.63	TAM12	50.63	449A2Q	K	540	ETH12	45.00	WIT60	45.00	TAM12	45.00
449B8 W	K	540	ETH12	33.75	WIT60	50.63	TAM12	50.63	450C7U	K	540	ETH12	33.75	WIT60	45.00	TAM12	56.25
450D4C	K	540	ETH12	33.75	WIT60	56.25	TAM12	45.00	450C7U	K	540	ETH12	33.75	WIT60	45.00	TAM12	56.25
450D4C	K	540	ETH12	33.75	WIT60	56.25	TAM12	45.00	451E6H	K	540	ETH12	33.75	WIT60	61.25	TAM12	45.00
456A3B	K	480	ETH12	53.33	ETH15	53.33	TAM12	53.33	451E6H	K	540	ETH12	33.75	WIT60	61.25	TAM12	45.00
456A3B	K	480	ETH12	53.33	ETH15	53.33	TAM12	53.33	456B2O	K	480	ETH12	40.00	ETH15	60.00	TAM12	60.00
457C9S	K	480	ETH12	40.00	ETH15	53.33	TAM12	66.67	456B2O	K	480	ETH12	40.00	ETH15	60.00	TAM12	60.00
457C9S	K	480	ETH12	40.00	ETH15	53.33	TAM12	66.67	457D1A	K	480	ETH12	40.00	ETH15	66.67	TAM12	53.33
360	IPA	360							457D1A	K	480	ETH12	40.00	ETH15	66.67	TAM12	53.33
360	IPA	360							754	IPA	445	TAM105	509	INT00	2.24
554	K	725							754	IPA	445	TAM105	509	INT00	2.24

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 7a composition and Comparative composition 554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 7b and 7c.

Table 7b:ABUTH control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	554	40.0	67.0	80.0	80.4
360	81.0	89.0	97.0	98.0	554	40.0	67.0	80.0	80.4
360	81.0	89.0	97.0	98.0	754	83.0	90.0	96.2	98.2
449A2Q	78.0	83.0	90.0	95.6	754	83.0	90.0	96.2	98.2
449A2Q	78.0	83.0	90.0	95.6	449B8W	78.0	84.0	91.0	98.2
450C7U	79.0	85.0	92.0	96.2	449B8W	78.0	84.0	91.0	98.2
450C7U	79.0	85.0	92.0	96.2	450D4C	77.0	82.0	92.0	96.2
451E6H	74.0	79.0	91.0	95.0	450D4C	77.0	82.0	92.0	96.2
451E6H	74.0	79.0	91.0	95.0	456A3B	77.0	81.0	93.0	96.2
456B2O	77.0	88.0	94.0	96.4	456A3B	77.0	81.0	93.0	96.2
456B2O	77.0	88.0	94.0	96.4	457C9S	76.0	84.0	93.0	97.4
457D1A	74.0	81.0	89.0	97.0	457C9S	76.0	84.0	93.0	97.4

Table 7c:ECHCF control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	554	44.0	54.0	57.0	62.0
360	85.0	97.0	99.6	99.8	554	44.0	54.0	57.0	62.0
360	85.0	97.0	99.6	99.8	754	83.0	95.0	99.8	99.0
449A2Q	85.0	93.0	95.2	98.2	754	83.0	95.0	99.8	99.0
449A2Q	85.0	93.0	95.2	98.2	449B8W	90.6	97.4	98.0	99.6
450C7U	83.0	91.2	96.6	98.4	449B8W	90.6	97.4	98.0	99.6
450C7U	83.0	91.2	96.6	98.4	450D4C	85.0	94.0	99.0	99.2
451E6H	89.0	89.0	95.8	99.6	450D4C	85.0	94.0	99.0	99.2
451E6H	89.0	89.0	95.8	99.6	456A3B	87.0	98.4	97.8	99.4
456B2O	84.0	95.0	98.2	99.6	456A3B	87.0	98.4	97.8	99.4
456B2O	84.0	95.0	98.2	99.6	457C9S	84.0	94.6	97.2	98.2
457D1A	83.0	94.6	95.4	99.4	457C9S	84.0	94.6	97.2	98.2

ABUTH and ECHCF result: generally speaking, the effect of this routine preparation slightly is weaker than 754 and 360 standards.

Embodiment 8

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 8a.

Table 8a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	721L9G	K	30	S51	3.0	RH010	7.0
721M7M	K	30	S51	5.0	INT00	5.0	721L9G	K	30	S51	3.0	RH010	7.0
721M7M	K	30	S51	5.0	INT00	5.0	721N3W	K	30	S52	2.2	RH010	7.8
721O9U	K	30	S52	3.8	INT00	6.2	721N3W	K	30	S52	2.2	RH010	7.8
721O9U	K	30	S52	3.8	INT00	6.2	721E2V	K	30	S51	10.0
721F5C	K	30	S52	10.0			721E2V	K	30	S51	10.0
721F5C	K	30	S52	10.0			721A8K	K	30			RH010	10.0
721B3N	K	30			INT00	10.0	721A8K	K	30			RH010	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 8a composition and Comparative composition 553,139 and 360.Get all replicate tests average of each processing, the result is shown in table 8b and 8c.

Table 8b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	30.8	71.7	84.2
360	13.3	82.5	88.3	92.3	139	0	30.8	71.7	84.2
360	13.3	82.5	88.3	92.3	553	57.5	85.8	90.8	94.7
721L9G	5.8	47.5	71.7	81.7	553	57.5	85.8	90.8	94.7
721L9G	5.8	47.5	71.7	81.7	721M7M	13.3	43.3	75	83.3
721N3W	1.7	57.5	80.8	85	721M7M	13.3	43.3	75	83.3
721N3W	1.7	57.5	80.8	85	721O9U	6.7	48.3	76.7	80.8
721E2V	12.5	56.7	80	88.3	721O9U	6.7	48.3	76.7	80.8
721E2V	12.5	56.7	80	88.3	721F5C	5.8	62.5	73.3	85
721A8K	10.8	31.7	64.2	84.2	721F5C	5.8	62.5	73.3	85
721A8K	10.8	31.7	64.2	84.2	721B3N	0	28.3	58.3	80

Table 8c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	45.8	64.2	67.5
360	70	87.5	94.2	98.7	139	0	45.8	64.2	67.5
360	70	87.5	94.2	98.7	553	71.7	84	94.5	95.8
721L9G	61.7	68.3	79.8	92.8	553	71.7	84	94.5	95.8
721L9G	61.7	68.3	79.8	92.8	721M7M	35.8	70	71.7	76.7
721N3W	43.3	66.7	74.2	80.8	721M7M	35.8	70	71.7	76.7
721N3W	43.3	66.7	74.2	80.8	721O9U	18.3	67.5	72.5	81.7
721E2V	66.7	80	92.3	99.8	721O9U	18.3	67.5	72.5	81.7
721E2V	66.7	80	92.3	99.8	721F5C	50	70	81.7	93.3
721A8K	35.8	70	74.2	82.5	721F5C	50	70	81.7	93.3
721A8K	35.8	70	74.2	82.5	721B3N	0	60.8	75.8	73.3

ABUTH and ECHCF result: generally speaking, this routine preparation is effective not as 360 standards.

Embodiment 9

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 9a.

Table 9a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l	6226D	K	480	M121	160.0
5603F	K	540	M121	135.0					6226D	K	480	M121	160.0
5603F	K	540	M121	135.0					2398A	K	480	M121	120.0
6761A	K	480	ETH12	64.0	WIT80	64.0	INT00	32.0	2398A	K	480	M121	120.0
6761A	K	480	ETH12	64.0	WIT80	64.0	INT00	32.0	6773B	K	480	ETH12	48.0	WIT80	48.0	INT00	24.0
7679V	K	510	1816E	5.0	ARQ37	1.5			6773B	K	480	ETH12	48.0	WIT80	48.0	INT00	24.0
7679V	K	510	1816E	5.0	ARQ37	1.5			7678V	K	510	1816E	5.0	ARQ37	1.5
360	IPA	360							7678V	K	510	1816E	5.0	ARQ37	1.5
360	IPA	360							754	IPA	445
554	K	725							754	IPA	445

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 9a composition and Comparative composition 554,139 and 360.Get all replicate tests average of each processing, the result is shown in table 9b and 9c.

Table 9b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	139	0	17.5	50.0	68.3
554	0	0.8	37.5	55.0	139	0	17.5	50.0	68.3
554	0	0.8	37.5	55.0	360	23.3	65.0	80.0	90.0
754	30.0	68.3	80.0	90.8	360	23.3	65.0	80.0	90.0
754	30.0	68.3	80.0	90.8	6226D	16.7	57.5	78.3	85.0
5603F	8.3	45.0	66.7	77.5	6226D	16.7	57.5	78.3	85.0
5603F	8.3	45.0	66.7	77.5	2398A	11.7	50.0	65.8	73.3
6761A	12.5	60.0	71.7	76.7	2398A	11.7	50.0	65.8	73.3
6761A	12.5	60.0	71.7	76.7	6773B	5.0	56.7	65.0	73.3
7679V	18.3	65.3	80.0	83.3	6773B	5.0	56.7	65.0	73.3
7679V	18.3	65.3	80.0	83.3	7678V	25.0	72.5	77.5	80.8

Table 9c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	139	35.0	45.0	55.8	65.0
554	20.0	39.2	49.2	60.8	139	35.0	45.0	55.8	65.0
554	20.0	39.2	49.2	60.8	360	66.7	76.7	92.	93.0
754	63.3	77.5	86.7	92.5	360	66.7	76.7	92.	93.0
754	63.3	77.5	86.7	92.5	6226D	64.2	79.2	90.0	92.8
5603F	65.8	73.3	84.2	85.0	6226D	64.2	79.2	90.0	92.8
5603F	65.8	73.3	84.2	85.0	2398A	61.7	62.5	80.0	84.2
6761A	65.0	75.0	87.5	93.0	2398A	61.7	62.5	80.0	84.2
6761A	65.0	75.0	87.5	93.0	6773B	63.3	68.3	88.2	88.8
7679V	61.7	66.7	67.5	74.2	6773B	63.3	68.3	88.2	88.8
7679V	61.7	66.7	67.5	74.2	7678V	55.0	62.5	70.8	85.0

ABUTH and ECHCF result: generally speaking, this routine preparation is effective not as 360 and 754 standards.But, 622 and 676 preparations approach 360 and 754 standards on performance.

Embodiment 10

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 10a.

Table 10a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	761A4S	K	4.3	S10	0.0	S61	1.4
761B2X	K	4.3	S10	0.3	S61	1.1	761A4S	K	4.3	S10	0.0	S61	1.4
761B2X	K	4.3	S10	0.3	S61	1.1	761C6Q	K	30	S10	4.0	S61	6.0
765L1D	K	30	S10	5.0	S61	5.0	761C6Q	K	30	S10	4.0	S61	6.0
765L1D	K	30	S10	5.0	S61	5.0	761E9N	K	30	S10	6.0	S61	4.0
761F4D	K	30	S10	8.0	S61	2.0	761E9N	K	30	S10	6.0	S61	4.0
761F4D	K	30	S10	8.0	S61	2.0	761G8S	K	30	S10	10.0	S61	0.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 10a composition and Comparative composition 554,553 and 360.Get all replicate tests average of each processing, the result is shown in table 10b and 10c.

Table 10b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	11.7	62.5	69.2
360	17.5	78.3	85.8	91.3	554	0.0	11.7	62.5	69.2
360	17.5	78.3	85.8	91.3	553	65.8	88.3	93.2	98.2
761A4S	39.2	73.3	83.3	90.0	553	65.8	88.3	93.2	98.2
761A4S	39.2	73.3	83.3	90.0	761B2X	51.7	80.0	89.2	94.5
761C6Q	62.5	85.8	92.5	95.8	761B2X	51.7	80.0	89.2	94.5
761C6Q	62.5	85.8	92.5	95.8	765L1D	70.8	85.8	89.7	95.3
761E9N	69.2	85.8	90.0	94.5	765L1D	70.8	85.8	89.7	95.3
761E9N	69.2	85.8	90.0	94.5	761F4D	77.5	89.2	92.2	94.8
761G8S	74.2	86.7	91.5	96.0	761F4D	77.5	89.2	92.2	94.8

Table 10c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	0.0	5.0	33.3
360	25.0	70.8	80.8	84.2	554	0.0	0.0	5.0	33.3
360	25.0	70.8	80.8	84.2	553	64.2	78.3	85.0	83.3
761A4S	0.0	57.5	68.3	72.5	553	64.2	78.3	85.0	83.3
761A4S	0.0	57.5	68.3	72.5	761B2X	3.3	65.8	71.7	74.2
761C6Q	29.2	71.7	76.7	78.3	761B2X	3.3	65.8	71.7	74.2
761C6Q	29.2	71.7	76.7	78.3	765L1D	23.3	75.0	75.0	82.5
761E9N	37.5	74.2	77.5	81.7	765L1D	23.3	75.0	75.0	82.5
761E9N	37.5	74.2	77.5	81.7	761F4D	51.7	75.8	80.0	83.3
761G8S	60.0	75.0	82.5	85.0	761F4D	51.7	75.8	80.0	83.3

Embodiment 11

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 11a.

Table 11a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	105A3S	K	30	NEO25	5	SUR50	5
105B7N	K	30	NEO25	5	SUR50	5	105A3S	K	30	NEO25	5	SUR50	5
105B7N	K	30	NEO25	5	SUR50	5	106A8X	K	30	TER9	5	SUR50	5
106B6N	K	30	SUR9	5	SUR50	5	106A8X	K	30	TER9	5	SUR50	5
106B6N	K	30	SUR9	5	SUR50	5	106C6Y	K	30	SUR6	5	SUR50	5
106D8E	K	30	SUR10	5	SUR50	5	106C6Y	K	30	SUR6	5	SUR50	5
106D8E	K	30	SUR10	5	SUR50	5	106E9R	K	30	SUR12	5	SUR50	5
767	K	510					106E9R	K	30	SUR12	5	SUR50	5
767	K	510					360	IPA	360
754	IPA	445	TAM105	5.9	INT00	2.24	360	IPA	360
754	IPA	445	TAM105	5.9	INT00	2.24	554	K	725

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 11a composition and Comparative composition 554,139,754 and 360.Get all replicate tests average of each processing, the result is shown in table 11b and 11c.

Table 11b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	139	10.0	75.0	80.0	85.0
554	5.0	65.8	75.0	84.2	139	10.0	75.0	80.0	85.0
554	5.0	65.8	75.0	84.2	360	70.0	82.5	89.2	90.0
754	67.5	84.2	87.5	92.5	360	70.0	82.5	89.2	90.0
754	67.5	84.2	87.5	92.5	105A3S	77.5	86.7	91.3	93.0
105B7N	68.3	84.2	86.7	92.7	105A3S	77.5	86.7	91.3	93.0
105B7N	68.3	84.2	86.7	92.7	106A8X	75.8	82.5	89.2	91.7
106B6N	75.8	86.7	87.5	94.7	106A8X	75.8	82.5	89.2	91.7
106B6N	75.8	86.7	87.5	94.7	106C6Y	68.3	80.8	85.0	90.8
106D8E	73.3	84.2	84.2	87.5	106C6Y	68.3	80.8	85.0	90.8
106D8E	73.3	84.2	84.2	87.5	106E9R	71.7	82.5	89.2	90.0
767	75.0	82.5	85.0	90.0	106E9R	71.7	82.5	89.2	90.0

Table 11c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	139	47.5	50.8	55.8	69.2
554	43.3	50.0	57.5	67.5	139	47.5	50.8	55.8	69.2
554	43.3	50.0	57.5	67.5	360	65.0	79.7	91.5	97.7
754	58.3	75.0	81.5	97.0	360	65.0	79.7	91.5	97.7
754	58.3	75.0	81.5	97.0	105A3S	60.0	82.5	89.7	97.0
105B7N	59.2	81.7	82.5	98.0	105A3S	60.0	82.5	89.7	97.0
105B7N	59.2	81.7	82.5	98.0	106A8X	57.5	88.0	93.7	93.7
106B6N	64.2	82.3	87.5	89.2	106A8X	57.5	88.0	93.7	93.7
106B6N	64.2	82.3	87.5	89.2	106C6Y	61.7	85.3	91.8	96.2
106D8E	63.3	71.7	88.2	98.0	106C6Y	61.7	85.3	91.8	96.2
106D8E	63.3	71.7	88.2	98.0	106E9R	65.0	80.8	96.8	99.2
767	59.2	63.3	74.2	92.7	106E9R	65.0	80.8	96.8	99.2

ABUTH and ECHCF result: all preparations of this example are through measuring, and are effective equally with standard 754 and 360.

Embodiment 12

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 12a.

Table 12a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l	476A4H	K	480	ETH12	40.0	ETH15	60.0	SUR9	60.0
476B6V	K	480	ETH12	40.0	ETH15	53.3	SUR9	53.3	476A4H	K	480	ETH12	40.0	ETH15	60.0	SUR9	60.0
476B6V	K	480	ETH12	40.0	ETH15	53.3	SUR9	53.3	477C9S	K	540	ETH12	33.8	ETH15	50.6	SUR9	50.6
477D2M	K	480	ETH12	64.0	WIT60	32.0	INT00	32.0	477C9S	K	540	ETH12	33.8	ETH15	50.6	SUR9	50.6
477D2M	K	480	ETH12	64.0	WIT60	32.0	INT00	32.0	478E6Y	K	480	ETH12	48.0	WIT60	24.0	INT00	24.0
478F1H	K	540	ETH12	60.75	WIT05				478E6Y	K	480	ETH12	48.0	WIT60	24.0	INT00	24.0
478F1H	K	540	ETH12	60.75	WIT05				360	IPA	360
754	IPA	445	TAM105	5.9	INT00	2.24			360	IPA	360
754	IPA	445	TAM105	5.9	INT00	2.24			554	K	725

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 12a composition and Comparative composition 554,139,754 and 360.Get all replicate tests average of each processing, the result is shown in table 12b and 12c.

Table 12b:ABUTH control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	139	0.0	1.7	65.0	81.7
554	0.0	6.7	665.0	68.3	139	0.0	1.7	65.0	81.7
554	0.0	6.7	665.0	68.3	360	73.3	81.7	83.3	91.7
754	50.0	71.7	83.3	90.0	360	73.3	81.7	83.3	91.7
754	50.0	71.7	83.3	90.0	476A4H	21.7	63.3	80.0	83.3
476B6V	60.0	65.0	75.0	86.7	476A4H	21.7	63.3	80.0	83.3
476B6V	60.0	65.0	75.0	86.7	477C9S	53.3	66.7	78.3	85.0
477D2M	56.7	60.0	85.0	85.0	477C9S	53.3	66.7	78.3	85.0
477D2M	56.7	60.0	85.0	85.0	478E6Y	53.3	66.7	81.7	85.0
478F1H	36.7	68.3	81.7	83.3	478E6Y	53.3	66.7	81.7	85.0

Table 12c:ECHCF control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	139	16.7	33.3	55.0	65.0
554	5.0	11.7	45.0	56.7	139	16.7	33.3	55.0	65.0
554	5.0	11.7	45.0	56.7	360	65.0	71.7	88.3	91.0
754	63.3	65.0	85.0	90.0	360	65.0	71.7	88.3	91.0
754	63.3	65.0	85.0	90.0	476A4H	61.7	66.7	75.0	83.3
476B6V	65.0	70.0	76.7	94.3	476A4H	61.7	66.7	75.0	83.3
476B6V	65.0	70.0	76.7	94.3	477C9S	46.7	66.7	81.7	88.3
477D2M	53.3	63.3	70.0	75.0	477C9S	46.7	66.7	81.7	88.3
477D2M	53.3	63.3	70.0	75.0	478E6Y	58.3	68.3	76.7	81.7
478F1H	61.7	78.3	90.0	95.0	478E6Y	58.3	68.3	76.7	81.7

ABUTH and ECHCF result: all preparations of this example are through measuring, and overall efficacy is similar each other.About ABUTH, there are not preparation and 360 and 754 standards effective equally.About ECHCF, 476F1H is similar with 754 standards to 360 with the 476B6V preparation.

Embodiment 13

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 13a.

Table 13a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	649A7J	K	30	S71	10.0
649B4B	K	30	S72	10.0	649A7J	K	30	S71	10.0
649B4B	K	30	S72	10.0	649C9X	K	30	S56	10.0
649D2W	K	4.3	S97	1.4	649C9X	K	30	S56	10.0
649D2W	K	4.3	S97	1.4	649E7A	K	30	S71	5.0
649F8C	K	30	S72	5.0	649E7A	K	30	S71	5.0
649F8C	K	30	S72	5.0	649G6M	K	30	S56	5.0
649H2V	K	30	S71	5.0	649G6M	K	30	S56	5.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 13a composition and Comparative composition 554,553 and 754.Get all replicate tests average of each processing, the result is shown in table 13b and 13c.

Table 13b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	0.0	9.2	28.3
754	0.0	0.0	80.0	80.8	554	0.0	0.0	9.2	28.3
754	0.0	0.0	80.0	80.8	553	10.0	55.0	87.5	91.7
649A7J	35.8	57.5	80.8	90.0	553	10.0	55.0	87.5	91.7
649A7J	35.8	57.5	80.8	90.0	649B4B	50.0	70.8	89.2	94.2
649C9X	34.2	60.8	81.7	85.0	649B4B	50.0	70.8	89.2	94.2
649C9X	34.2	60.8	81.7	85.0	649D2W	29.2	71.7	82.5	88.3
649E7A	48.3	49.2	78.3	89.2	649D2W	29.2	71.7	82.5	88.3
649E7A	48.3	49.2	78.3	89.2	649F8C	48.2	63.3	88.3	88.3
649G6M	59.2	44.2	80.0	84.2	649F8C	48.2	63.3	88.3	88.3
649G6M	59.2	44.2	80.0	84.2	649H2V	71.7	60.8	90.0	86.7

Table 13c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	0.0	16.7	6.7
754	0.0	42.5	80.0	81.7	554	0.0	0.0	16.7	6.7
754	0.0	42.5	80.0	81.7	553	57.5	65.8	81.7	86.7
649A7J	15.0	52.5	75.0	85.8	553	57.5	65.8	81.7	86.7
649A7J	15.0	52.5	75.0	85.8	649B4B	47.5	61.5	79.2	79.2
649C9X	8.3	23.3	70.0	75.0	649B4B	47.5	61.5	79.2	79.2
649C9X	8.3	23.3	70.0	75.0	649D2W	6.7	64.2	77.5	79.2
649E7A	0.0	16.7	62.5	75.8	649D2W	6.7	64.2	77.5	79.2
649E7A	0.0	16.7	62.5	75.8	649F8C	23.3	32.5	78.3	80.0
649G6M	5.0	20.0	53.3	72.5	649F8C	23.3	32.5	78.3	80.0
649G6M	5.0	20.0	53.3	72.5	649H2V	16.7	31.7	73.3	81.7

ABUTH and ECHCF result: the active ingredient about ABUTH is 649B4B, is standard 553 about the active ingredient of ECHCF.

Embodiment 14

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 14a.

Table 14a

Composition	Salt	Active	g/l
Composition	Salt	Active	g/l	M121		Surfactant (etheramine surfactants system)	100
139	IPA		570	M121		Surfactant (etheramine surfactants system)	100
139	IPA		570	554	K		725

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 14a composition and Comparative composition 139 and 554.Get all replicate tests average of each processing, the result is shown in table 14b and 14c.

Table 14b:ABUTH control %

Glyphosate formulation	Surfactant M121 (wt.%)	75g a.e./ha	100g a.e./ha	150g a.e./ha
Glyphosate formulation	Surfactant M121 (wt.%)	75g a.e./ha	100g a.e./ha	150g a.e./ha	139	0	10.8	12.5	57.5
554	0	0	0	21.7	139	0	10.8	12.5	57.5
554	0	0	0	21.7	139	0.05％	51.7	69.2	79.2
139	0.1％	62.5	75.0	83.3	139	0.05％	51.7	69.2	79.2
139	0.1％	62.5	75.0	83.3	139	0.2％	50.0	62.5	79.2
139	0.5％	57.5	75.8	79.2	139	0.2％	50.0	62.5	79.2
139	0.5％	57.5	75.8	79.2	139	1.0％	56.7	77.5	79.2
139	5.0％	23.3	30.0	31.7	139	1.0％	56.7	77.5	79.2
139	5.0％	23.3	30.0	31.7	554	0.05％	45.0	59.2	75.8
554	0.1％	45.8	63.3	72.5	554	0.05％	45.0	59.2	75.8
554	0.1％	45.8	63.3	72.5	554	0.2％	56.7	64.2	75.0
554	0.5％	45.8	73.3	77.5	554	0.2％	56.7	64.2	75.0
554	0.5％	45.8	73.3	77.5	554	1.0％	37.5	62.5	77.5
554	5.0％	4.2	9.2	10.0	554	1.0％	37.5	62.5	77.5

Table 14c:ECHCF control %

Glyphosate formulation	Surfactant M121 (wt.%)	75g a.e./ha	100g a.e./ha	150g a.e./ha
Glyphosate formulation	Surfactant M121 (wt.%)	75g a.e./ha	100g a.e./ha	150g a.e./ha	139	0	5.0	7.5	31.7
554	0	0.0	5.8	13.3	139	0	5.0	7.5	31.7
554	0	0.0	5.8	13.3	139	0.05％	60.0	69.2	85.0
139	0.1％	65.0	68.3	84.2	139	0.05％	60.0	69.2	85.0
139	0.1％	65.0	68.3	84.2	139	0.2％	70.8	87.0	98.5
139	0.5％	70.8	90.7	89.7	139	0.2％	70.8	87.0	98.5
139	0.5％	70.8	90.7	89.7	139	1.0％	60.8	65.0	83.3
139	5.0％	30.0	31.7	35.0	139	1.0％	60.8	65.0	83.3
139	5.0％	30.0	31.7	35.0	554	0.05％	33.3	55.0	65.8
554	0.1％	40.8	42.5	63.3	554	0.05％	33.3	55.0	65.8
554	0.1％	40.8	42.5	63.3	554	0.2％	40.0	64.2	73.3
554	0.5％	33.3	56.7	70.0	554	0.2％	40.0	64.2	73.3
554	0.5％	33.3	56.7	70.0	554	1.0％	7.5	40.8	63.3
554	5.0％	1.7	2.5	5.8	554	1.0％	7.5	40.8	63.3

ABUTH and ECHCF result: the surfactant M121 that contrasts every kind of glyphosate IPA and K salt shows that this surfactant system is more effectively strengthened IPA.Under about the every kind test ratio of IPA, notice overall higher effect to K salt.As if about every kind of glyphosate salt, the M121 surfactant system reaches its maximum validity in about 0.1% to 0.5% sprayed volume scope, after this working as two kinds of salt all increases surfactant level to 1% or 5%, and effect does not change or reduces.

Embodiment 15

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 15a.

Table 15a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l	387-15G	K	410	VAR05	132.2
387-24N	K	476	VAR05	66.2	117	66.2			387-15G	K	410	VAR05	132.2
387-24N	K	476	VAR05	66.2	117	66.2			387-32C	K	488	VAR05	66.7	APG67	66.7
387-48N	K	490	VAR05	33.5	117	13.4	APG67	100. 4	387-32C	K	488	VAR05	66.7	APG67	66.7
387-48N	K	490	VAR05	33.5	117	13.4	APG67	100. 4	387-59A	K	484	VAR05	33.5	117	40.2	APG67	100. 4
387-67X	K	487	VAR02	49.6	117	66.1	APG67	16.5	387-59A	K	484	VAR05	33.5	117	40.2	APG67	100. 4
387-67X	K	487	VAR02	49.6	117	66.1	APG67	16.5	387-75G	K	544	VAR02	16.6	117	66.5	APG67	49.9
387-98C	K		VAR02	40.8	117	81.6	APG67	13.6	387-75G	K	544	VAR02	16.6	117	66.5	APG67	49.9

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 15a composition and Comparative composition 554,360,139 and 754.Get all replicate tests average of each processing, the result is shown in table 15b and 15c.

Table 15b:ABUTH control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	139	39.0	59.0	79.0	85.0
554	27.0	30.0	72.0	78.0	139	39.0	59.0	79.0	85.0
554	27.0	30.0	72.0	78.0	360	80.0	80.0	88.0	91.0
754	79.0	81.0	88.0	90.0	360	80.0	80.0	88.0	91.0
754	79.0	81.0	88.0	90.0	387-15G	78.0	78.0	88.0	91.0
387-24N	77.0	80.0	84.0	89.0	387-15G	78.0	78.0	88.0	91.0
387-24N	77.0	80.0	84.0	89.0	387-32C	74.0	79.0	83.0	88.0
387-48N	76.0	78.0	84.0	87.0	387-32C	74.0	79.0	83.0	88.0
387-48N	76.0	78.0	84.0	87.0	387-59A	66.0	80.0	85.0	87.0
387-67X	69.0	74.0	83.0	86.0	387-59A	66.0	80.0	85.0	87.0
387-67X	69.0	74.0	83.0	86.0	387-75G	67.0	78.0	87.0	87.0
387-98C	67.0	80.0	85.0	86.0	387-75G	67.0	78.0	87.0	87.0

Table 15c:ECHCF control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	139	10.0	25.0	42.0	62.0
554	10.0	11.0	30.0	44.0	139	10.0	25.0	42.0	62.0
554	10.0	11.0	30.0	44.0	360	72.0	82.0	89.6	91.0
754	71.0	74.0	91.8	90.6	360	72.0	82.0	89.6	91.0
754	71.0	74.0	91.8	90.6	387-15G	68.0	78.0	93.6	96.0
387-24N	68.0	81.0	89.8	93.0	387-15G	68.0	78.0	93.6	96.0
387-24N	68.0	81.0	89.8	93.0	387-32C	68.0	72.0	74.0	96.8
387-48N	64.0	70.0	83.0	87.6	387-32C	68.0	72.0	74.0	96.8
387-48N	64.0	70.0	83.0	87.6	387-59A	69.0	70.0	78.0	91.2
387-67X	70.0	74.0	79.0	82.8	387-59A	69.0	70.0	78.0	91.2
387-67X	70.0	74.0	79.0	82.8	387-75G	68.0	74.0	80.8	87.8
387-98C	66.0	72.0	Free of data	Free of data	387-75G	68.0	74.0	80.8	87.8

ABUTH and ECHCF result: about ABUTH and ECHCF, the 387-15G preparation is similar to 360 and 754 standards on effect.The 387-24N preparation is time maximum effectively preparation about ABUTH and ECHCF.About 387-98C, 300 and 400g/ha under mistake spray, therefore do not collect data.

Embodiment 16

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 16a.

Table 16a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l	387- 13M	K	410	VAR05	132. 2
387-25F	K	476	VAR05	66.2	117	66.2			387- 13M	K	410	VAR05	132. 2
387-25F	K	476	VAR05	66.2	117	66.2			387-38C	K	488	VAR05	66.7	APG67	66.7
387-63J	K	484	VAR02	49.6	117	66.1	APG67	16. 5	387-38C	K	488	VAR05	66.7	APG67	66.7
387-63J	K	484	VAR02	49.6	117	66.1	APG67	16. 5	387-96F	K	544	VAR02	40.8	117	81.6	APG67	13. 6
387-89D	K	483	ETH12	66.0	117	66			387-96F	K	544	VAR02	40.8	117	81.6	APG67	13. 6
387-89D	K	483	ETH12	66.0	117	66			387- 108U	K	544	ETH12	40.8	117	81.6	APG67	13. 6
387- 116Y	K	543	ETH12	54.3	117	81.4			387- 108U	K	544	ETH12	40.8	117	81.6	APG67	13. 6
387- 116Y	K	543	ETH12	54.3	117	81.4			360	IPA	360
754	IPA	445	WIT05	5.9	INT00	2.24			360	IPA	360
754	IPA	445	WIT05	5.9	INT00	2.24			554	K	725

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 16a composition and Comparative composition 554,139,360 and 754.Get all replicate tests average of each processing, the result is shown in table 16b and 16c.

Table 16b:ABUTH control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	139	5.0	70.0	79.0	82.0
554	8.0	65.0	77.0	80.0	139	5.0	70.0	79.0	82.0
554	8.0	65.0	77.0	80.0	360	78.0	84.0	88.0	92.0
754	80.0	84.0	87.0	91.0	360	78.0	84.0	88.0	92.0
754	80.0	84.0	87.0	91.0	387-13M	60.0	83.0	84.0	88.0
387-25F	54.0	75.0	82.0	86.0	387-13M	60.0	83.0	84.0	88.0
387-25F	54.0	75.0	82.0	86.0	387-38C	22.0	69.0	80.0	83.0
387-63J	65.0	68.0	80.0	81.0	387-38C	22.0	69.0	80.0	83.0
387-63J	65.0	68.0	80.0	81.0	387-96F	26.0	40.0	80.0	81.0
387-89D	13.0	54.0	81.0	81.0	387-96F	26.0	40.0	80.0	81.0
387-89D	13.0	54.0	81.0	81.0	387-108U	50.0	64.0	79.0	82.0
387-116Y	55.0	65.0	81.0	82.0	387-108U	50.0	64.0	79.0	82.0

Table 16c:ECHCF control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	139	14.0	38.0	55.0	61.0
554	14.0	36.0	55.0	65.0	139	14.0	38.0	55.0	61.0
554	14.0	36.0	55.0	65.0	360	64.0	71.0	91.8	93.8
754	62.0	69.0	82.0	93.0	360	64.0	71.0	91.8	93.8
754	62.0	69.0	82.0	93.0	387-13M	66.0	81.6	89.0	87.8
387-25F	66.0	72.0	83.8	85.8	387-13M	66.0	81.6	89.0	87.8
387-25F	66.0	72.0	83.8	85.8	387-38C	64.0	67.0	81.0	80.6
387-63J	63.0	67.0	75.6	86.2	387-38C	64.0	67.0	81.0	80.6
387-63J	63.0	67.0	75.6	86.2	387-96F	62.0	63.0	76.0	81.0
387-89D	61.0	66.0	76.0	82.2	387-96F	62.0	63.0	76.0	81.0
387-89D	61.0	66.0	76.0	82.2	387-108U	62.0	63.0	73.0	85.0
387-116Y	65.0	65.0	78.0	85.0	387-108U	62.0	63.0	73.0	85.0

ABUTH and ECHCF result: about ECHCF, the 387-13M preparation is similar to 360 and 754 standards on effect.The 387-25F preparation is that time maximum is effective.About ABUTH, it is effective that this experiment does not have preparation to resemble standard 360 and 754.

Embodiment 17

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 17a.

Table 17a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	488A6Y	K	4.3	855	1.4
488B5G	K	30	855	10.0	488A6Y	K	4.3	855	1.4
488B5G	K	30	855	10.0	488C7U	K	30	855	10.0
488D5H	K	30	855	10.0	488C7U	K	30	855	10.0
488D5H	K	30	855	10.0	488E4J	K	30	855	10.0
488F2Z	K	30	855	10.0	488E4J	K	30	855	10.0
488F2Z	K	30	855	10.0	488G8Q	K	4.3	855	1.4
488H7M	K	30	855	10.0	488G8Q	K	4.3	855	1.4
488H7M	K	30	855	10.0	488I5T	K	30	855	12.0
488J3T	IPA	4.3	139	1.4	488I5T	K	30	855	12.0
488J3T	IPA	4.3	139	1.4	488K9S	IPA	30	139	10.0
488L3A	IPA	30	139	10.0	488K9S	IPA	30	139	10.0
488L3A	IPA	30	139	10.0	488M5S	IPA	30	139	10.0
488N7Z	IPA	30	139	10.0	488M5S	IPA	30	139	10.0
488N7Z	IPA	30	139	10.0	488O8T	IPA	30	139	10.0
488P9H	IPA	4.3	139	1.4	488O8T	IPA	30	139	10.0
488P9H	IPA	4.3	139	1.4	488Q7G	IPA	30	139	10.0
488R3E	IPA	30	139	12.0	488Q7G	IPA	30	139	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 17a composition and Comparative composition 139,553 and 360.Get all replicate tests average of each processing, the result is shown in table 17b and 17c.

Table 17b:ABUTH control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	0.0	14.2	50.0	85.8
360	0.0	55.0	90.8	99.5	139	0.0	14.2	50.0	85.8
360	0.0	55.0	90.8	99.5	553	42.5	82.5	95.3	99.7
488A6Y	1.7	72.5	85.8	90.8	553	42.5	82.5	95.3	99.7
488A6Y	1.7	72.5	85.8	90.8	488B5G	0.0	63.3	70.0	93.0
488C7U	5.8	29.2	66.7	92.7	488B5G	0.0	63.3	70.0	93.0
488C7U	5.8	29.2	66.7	92.7	488D5H	6.7	56.7	52.5	94.5
488E4J	5.0	51.7	80.8	93.0	488D5H	6.7	56.7	52.5	94.5
488E4J	5.0	51.7	80.8	93.0	488F2Z	16.7	55.0	87.0	88.2
488G8Q	16.7	72.5	91.7	99.2	488F2Z	16.7	55.0	87.0	88.2
488G8Q	16.7	72.5	91.7	99.2	488H7M	15.0	42.5	85.0	95.8
488I5T	17.5	62.5	82.5	97.8	488H7M	15.0	42.5	85.0	95.8
488I5T	17.5	62.5	82.5	97.8	488J3T	11.7	59.2	85.8	99.2
488K9S	37.5	27.5	81.7	92.7	488J3T	11.7	59.2	85.8	99.2
488K9S	37.5	27.5	81.7	92.7	488L3A	0.0	30.8	75.0	91.3
488M5S	8.3	13.3	55.8	88.3	488L3A	0.0	30.8	75.0	91.3
488M5S	8.3	13.3	55.8	88.3	488N7Z	6.7	26.7	80.8	89.8
488O8T	1.7	50.0	89.2	95.0	488N7Z	6.7	26.7	80.8	89.8
488O8T	1.7	50.0	89.2	95.0	488P9H	16.7	39.2	84.2	99.0
488Q7G	10.8	29.2	89.2	95.3	488P9H	16.7	39.2	84.2	99.0
488Q7G	10.8	29.2	89.2	95.3	488R3E	8.3	45.0	87.5	97.0

Table 17c:ECHCF control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400ga.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400ga.e./ha	139	0.0	6.7	51.7	71.7
360	52.5	69.2	83.3	95.8	139	0.0	6.7	51.7	71.7
360	52.5	69.2	83.3	95.8	553	60.8	73.3	90.0	96.7
488A6Y	48.3	67.5	79.2	95.5	553	60.8	73.3	90.0	96.7
488A6Y	48.3	67.5	79.2	95.5	488B5G	18.3	54.2	70.8	81.7
488C7U	0.0	30.0	65.0	75.0	488B5G	18.3	54.2	70.8	81.7
488C7U	0.0	30.0	65.0	75.0	488D5H	0.0	31.7	63.3	75.8
488E4J	19.2	60.0	70.0	80.8	488D5H	0.0	31.7	63.3	75.8
488E4J	19.2	60.0	70.0	80.8	488F2Z	13.3	55.0	74.2	88.3
488G8Q	38.3	64.2	85.8	98.3	488F2Z	13.3	55.0	74.2	88.3
488G8Q	38.3	64.2	85.8	98.3	488H7M	44.2	72.5	93.2	97.3
488I5T	34.2	62.5	73.3	92.5	488H7M	44.2	72.5	93.2	97.3
488I5T	34.2	62.5	73.3	92.5	488J3T	25.0	50.0	83.3	98.2
488K9S	37.5	60.8	73.3	87.5	488J3T	25.0	50.0	83.3	98.2
488K9S	37.5	60.8	73.3	87.5	488L3A	3.3	19.2	66.7	75.8
488M5S	3.3	44.2	65.0	75.0	488L3A	3.3	19.2	66.7	75.8
488M5S	3.3	44.2	65.0	75.0	488N7Z	5.0	55.0	72.5	91.7
488O8T	5.0	56.7	68.3	90.7	488N7Z	5.0	55.0	72.5	91.7
488O8T	5.0	56.7	68.3	90.7	488P9H	50.8	68.3	87.5	100.0
488Q7G	54.2	71.7	79.2	98.3	488P9H	50.8	68.3	87.5	100.0
488Q7G	54.2	71.7	79.2	98.3	488R3E	36.7	44.2	70.8	93.2

ABUTH and ECHCF result: generally speaking best preparation is 553 standards, because it all more has activity than all for test preparation.The preparation that contains sylvite is tending towards having higher activity than the IPA salt of correspondence.

Embodiment 18

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 18a.

Table 18a

Comp.	Salt	g/l	Component 1	wt.％	Component 2	wt.％
Comp.	Salt	g/l	Component 1	wt.％	Component 2	wt.％	863A9W	IPA	62	MS10	2.00％
863B8M	IPA	62	MS10	1.00％	HET20	1.00％	863A9W	IPA	62	MS10	2.00％
863B8M	IPA	62	MS10	1.00％	HET20	1.00％	863C4G	IPA	62	DUO50	1.00％
863D6S	IPA	62	DUO50	0.50％	HET20	1.00％	863C4G	IPA	62	DUO50	1.00％
863D6S	IPA	62	DUO50	0.50％	HET20	1.00％	863E2N	IPA	62	ARQ50	1.00％
863F7X	IPA	62	ARQ50	0.50％	HET20	1.00％	863E2N	IPA	62	ARQ50	1.00％
863F7X	IPA	62	ARQ50	0.50％	HET20	1.00％	863G3B	IPA	62			HET20	2.00％

Plantation piemarker (ABUTH) is handled according to above-mentioned standard method.Use table 18a composition and Comparative composition 139 and 360.Two result of the tests are shown in table 18b.

Table 18b:ABUTH control %

Composition	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha
Composition	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	139	0	3.3	60	75	0	5	51.7	76.7
360	1	53.3	86.3	98.3	1.7	48.3	91.7	95.3	139	0	3.3	60	75	0	5	51.7	76.7
360	1	53.3	86.3	98.3	1.7	48.3	91.7	95.3	863A9W	3.3	60	81.7	87.7	1.7	60	83.7	87.7
863B8M	3.3	61.7	93	98.7	1.7	65	93	97.7	863A9W	3.3	60	81.7	87.7	1.7	60	83.7	87.7
863B8M	3.3	61.7	93	98.7	1.7	65	93	97.7	863C4G	3.3	5	73.3	82.7	0	23.3	71.7	82.7
863D6S	1.7	58.3	88.3	94.3	0	61.7	92.3	98.3	863C4G	3.3	5	73.3	82.7	0	23.3	71.7	82.7
863D6S	1.7	58.3	88.3	94.3	0	61.7	92.3	98.3	863E2N	45	33.3	75	85.7	36.7	33.3	73.3	88
863F7X	0	61.7	86.7	97.3	1.7	66.7	87.3	98.3	863E2N	45	33.3	75	85.7	36.7	33.3	73.3	88
863F7X	0	61.7	86.7	97.3	1.7	66.7	87.3	98.3	863G3B	1.7	61.7	85	90	5	63.3	79.3	95

ABUTH result: the 863E2N preparation shows best effect, and is more effective than 360 standards under 100ae g/ha ratio.Under 200ae g/ha, about ABUTH, 863B8M, 863F7X and 863G3B are more effective than 360 standards.

Embodiment 19

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 19a.

Table 19a

Comp.	Salt	g/l	Component 1	wt.％	Component 2	wt.％
Comp.	Salt	g/l	Component 1	wt.％	Component 2	wt.％	348A2 W	IPA	62	HET20	2.00％
348B6M	IPA	62			S89	2.00％	348A2 W	IPA	62	HET20	2.00％
348B6M	IPA	62			S89	2.00％	348C9X	IPA	62	HET20	1.75％	S89	0.25％
863D6V	IPA	62			S88	2.00％	348C9X	IPA	62	HET20	1.75％	S89	0.25％
863D6V	IPA	62			S88	2.00％	348E2N	IPA	62	HET20	1.70％	S88	0.30％
348F2S	IPA	62			S90	2.00％	348E2N	IPA	62	HET20	1.70％	S88	0.30％
348F2S	IPA	62			S90	2.00％	348G4K	IPA	62	HET20	1.40％	S90	0.60％

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 19a composition and Comparative composition 139 and 360.The result of two tests is shown in table 19b and 19c.

Table 19b:ABUTH control %

Composition	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha
Composition	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	139	5	28.3	56.7	60	50	45	65	66.7
360	60	81	87.7	95	56.7	83.3	93.7	94.3	139	5	28.3	56.7	60	50	45	65	66.7
360	60	81	87.7	95	56.7	83.3	93.7	94.3	348A2W	70	85	93	95	71.7	81.7	95	93.7
348B6M	0	45	68.3	65	5	38.3	68.3	66.7	348A2W	70	85	93	95	71.7	81.7	95	93.7
348B6M	0	45	68.3	65	5	38.3	68.3	66.7	348C9X	68.3	90	93.3	94.3	70	84	92	94.3
863D6V	5	46.7	66.7	70	6.7	51.7	68.3	70	348C9X	68.3	90	93.3	94.3	70	84	92	94.3
863D6V	5	46.7	66.7	70	6.7	51.7	68.3	70	348E2N	71.7	85	92	96.3	73.3	85	95.7	95.7
348F2S	5	41.7	65	63.3	46.7	61.7	78.3	80	348E2N	71.7	85	92	96.3	73.3	85	95.7	95.7
348F2S	5	41.7	65	63.3	46.7	61.7	78.3	80	348G4K	70	81.7	93.7	95.7	58.3	81.7	83.3	93.7

Table 19c:ECHCF control %

Composition	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha
Composition	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	100 a.e. g/ha	200 a.e. g/ha	300 a.e. g/ha	400 a.e. g/ha	139	16.7	36.7	36.7	43.3	23.3	35	40	41.7
360	38.3	45	81.7	83.3	40	65	83.3	86.7	139	16.7	36.7	36.7	43.3	23.3	35	40	41.7
360	38.3	45	81.7	83.3	40	65	83.3	86.7	348A2W	36.7	40	75	80	46.7	48.3	63.3	81.7
348B6M	26.7	30	41.7	53.3	15	43.3	41.7	48.3	348A2W	36.7	40	75	80	46.7	48.3	63.3	81.7
348B6M	26.7	30	41.7	53.3	15	43.3	41.7	48.3	348C9X	28.3	53.3	71.7	78.3	31.7	50	73.3	86.7
863D6V	25	36.7	38.3	48.3	23.3	40	41.7	46.7	348C9X	28.3	53.3	71.7	78.3	31.7	50	73.3	86.7
863D6V	25	36.7	38.3	48.3	23.3	40	41.7	46.7	348E2N	45	38.3	81.7	83.3	30	63.3	78.3	88.3
348F2S	33.3	36.7	43.3	43.3	33.3	38.3	43.3	48.3	348E2N	45	38.3	81.7	83.3	30	63.3	78.3	88.3
348F2S	33.3	36.7	43.3	43.3	33.3	38.3	43.3	48.3	348G4K	38.3	43.3	78.3	86.7	30	50	60	86.7

ABUTH and ECHCF result: 348A2W, 348C9X, 348E2N and 348G4K preparation and standard 360 provide higher control level, about ABUTH all for the examination ratios under, about ECHCF 300 and the 400aeg/ha ratio under.

Embodiment 20

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 20a.

Table 20a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	471A5W	IPA	30	S40	2.3	BRI35	7.7
471B9X	IPA	30	S41	2.6	BRI35	7.4	471A5W	IPA	30	S40	2.3	BRI35	7.7
471B9X	IPA	30	S41	2.6	BRI35	7.4	471C3N	IPA	30	S39	2.9	BRI35	7.1
471D7S	IPA	30	S40	2.3	BRI35	7.7	471C3N	IPA	30	S39	2.9	BRI35	7.1
471D7S	IPA	30	S40	2.3	BRI35	7.7	471E8C	IPA	30	S41	2.6	BRI35	7.4
471F4A	IPA	30	S39	2.9	BRI35	7.1	471E8C	IPA	30	S41	2.6	BRI35	7.4

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 20a composition and Comparative composition 139 and 360.Get all replicate tests average of each processing, the result is shown in table 20b and 20c.

Table 20b:ABUTH control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	5.0	58.3	85.0	90.8
360	10.0	74.2	91.5	99.5	139	5.0	58.3	85.0	90.8
360	10.0	74.2	91.5	99.5	471A5W	16.7	67.5	90.0	97.3
471B9X	20.0	40.8	85.8	98.7	471A5W	16.7	67.5	90.0	97.3
471B9X	20.0	40.8	85.8	98.7	471C3N	11.7	72.5	90.8	99.0
471D7S	51.7	85.8	94.7	99.7	471C3N	11.7	72.5	90.8	99.0
471D7S	51.7	85.8	94.7	99.7	471E8C	46.7	83.3	92.2	99.2
471F4A	65.0	86.7	95.2	100.0	471E8C	46.7	83.3	92.2	99.2

Table 20c:ECHCF control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	33.3	55.8	66.7	75.0
360	68.3	74.2	83.3	99.5	139	33.3	55.8	66.7	75.0
360	68.3	74.2	83.3	99.5	471A5W	67.5	73.3	89.2	99.8
471B9X	60.0	70.0	80.0	95.0	471A5W	67.5	73.3	89.2	99.8
471B9X	60.0	70.0	80.0	95.0	471C3N	65.0	42.5	88.3	99.2
471D7S	60.8	76.7	79.2	93.2	471C3N	65.0	42.5	88.3	99.2
471D7S	60.8	76.7	79.2	93.2	471E8C	56.7	73.3	88.8	100.0
471F4A	67.5	73.3	80.0	99.0	471E8C	56.7	73.3	88.8	100.0

ABUTH and ECHCF result: generally speaking best preparation is 471D7S and 471F4A.471D7S and 471F4A provide the activity bigger than 360 standards to ABUTH, provide the activity similar to 360 standards to ECHCF.The 471E8C preparation also provides better more active than standard 360 to ABUTH.

Embodiment 21

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 21a.

Table 21a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	471C3Q	IPA	30	S39	7.1	BRI35	2.9
471F6W	IPA	30	S39	7.1	BRI78	2.9	471C3Q	IPA	30	S39	7.1	BRI35	2.9
471F6W	IPA	30	S39	7.1	BRI78	2.9	457C2M	IPA	30	S39	7.0	BRI58	3.0
471A8C	IPA	30	S40	7.7	BRI35	2.3	457C2M	IPA	30	S39	7.0	BRI58	3.0
471A8C	IPA	30	S40	7.7	BRI35	2.3	471D7A	IPA	30	S40	7.7	BRI78	2.3
457A9J	IPA	30	S40	7.5	BRI58	2.5	471D7A	IPA	30	S40	7.7	BRI78	2.3
457A9J	IPA	30	S40	7.5	BRI58	2.5	480A2K	IPA	30			BRI35	10.0
480B3V	IPA	30			BRI78	10.0	480A2K	IPA	30			BRI35	10.0
480B3V	IPA	30			BRI78	10.0	480C6N	IPA	30			BRI58	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 21a composition and Comparative composition 139 and 360.Get all replicate tests average of each processing, the result is shown in table 21b and 21c.

Table 21b:ABUTH control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	3.3	69.2	81.7	92.7
360	42.5	86.7	94.3	99.0	139	3.3	69.2	81.7	92.7
360	42.5	86.7	94.3	99.0	457A9J	55.8	85.8	91.3	99.2
457C2M	68.3	87.5	94.2	99.2	457A9J	55.8	85.8	91.3	99.2
457C2M	68.3	87.5	94.2	99.2	471A8C	62.5	83.3	90.0	98.5
471C3Q	46.7	79.2	92.5	96.2	471A8C	62.5	83.3	90.0	98.5
471C3Q	46.7	79.2	92.5	96.2	471D7A	63.3	88.3	96.5	99.2
471F6W	75.8	88.3	94.3	100.0	471D7A	63.3	88.3	96.5	99.2
471F6W	75.8	88.3	94.3	100.0	480A2K	50.8	82.5	89.7	97.0
480B3V	58.3	88.3	94.7	99.2	480A2K	50.8	82.5	89.7	97.0
480B3V	58.3	88.3	94.7	99.2	480C6N	54.2	83.3	92.8	98.0

Table 21c:ECHCF control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	12.5	65.0	56.7	73.3
360	65.0	77.5	85.5	98.2	139	12.5	65.0	56.7	73.3
360	65.0	77.5	85.5	98.2	457A95	65.8	75.0	77.5	96.7
457C2M	68.3	78.3	80.8	99.0	457A95	65.8	75.0	77.5	96.7
457C2M	68.3	78.3	80.8	99.0	471A8C	57.5	73.3	80.8	95.8
471C3Q	59.2	72.5	84.2	93.3	471A8C	57.5	73.3	80.8	95.8
471C3Q	59.2	72.5	84.2	93.3	471D7A	66.7	71.7	78.3	94.2
471F6W	60.0	72.5	90.0	96.7	471D7A	66.7	71.7	78.3	94.2
471F6W	60.0	72.5	90.0	96.7	480A2K	65.8	75.0	86.7	99.8
480B3V	62.5	72.5	84.2	97.3	480A2K	65.8	75.0	86.7	99.8
480B3V	62.5	72.5	84.2	97.3	480C6N	48.3	71.7	89.2	100.0

Embodiment 22

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 22a.

Table 22a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	623A8W	K	30	S10	10.0
623B3M	K	30	S11	10.0	623A8W	K	30	S10	10.0
623B3M	K	30	S11	10.0	623C6J	K	4.3	S91	1.4
623D2S	K	30	S07	10.0	623C6J	K	4.3	S91	1.4
623D2S	K	30	S07	10.0	623E9J	K	30	S92	10.0
623F7G	K	30	S93	10.0	623E9J	K	30	S92	10.0
623F7G	K	30	S93	10.0	623G3E	K	30	S94	10.0
623H9R	K	30	S95	10.0	623G3E	K	30	S94	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 22a composition and Comparative composition 554,754 and 553.Get all replicate tests average of each processing, the result is shown in table 22b and 22c.

Table 22b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	4.2	22.5	55.8
754	0.0	56.7	79.2	85.8	554	0.0	4.2	22.5	55.8
754	0.0	56.7	79.2	85.8	553	31.7	79.2	90.8	94.5
623A8W	57.5	85.8	90.8	95.5	553	31.7	79.2	90.8	94.5
623A8W	57.5	85.8	90.8	95.5	623B3M	31.7	73.3	90.0	90.8
623C6J	25.8	29.2	66.7	75.8	623B3M	31.7	73.3	90.0	90.8
623C6J	25.8	29.2	66.7	75.8	623D2S	36.7	82.5	90.0	96.5
623E9J	65.0	87.5	91.7	95.0	623D2S	36.7	82.5	90.0	96.5
623E9J	65.0	87.5	91.7	95.0	623F7G	72.5	90.0	93.3	96.8
623G3E	55.2	80.8	87.5	93.2	623F7G	72.5	90.0	93.3	96.8
623G3E	55.2	80.8	87.5	93.2	623H9R	62.5	83.3	92.5	93.3

Table 22c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	0.0	47.5	48.3
754	8.3	65.0	71.7	76.7	554	0.0	0.0	47.5	48.3
754	8.3	65.0	71.7	76.7	553	45.8	71.7	74.2	76.7
623A8W	46.7	67.5	72.5	71.7	553	45.8	71.7	74.2	76.7
623A8W	46.7	67.5	72.5	71.7	623B3M	40.8	69.2	72.5	74.2
623C6J	1.7	54.2	66.7	71.7	623B3M	40.8	69.2	72.5	74.2
623C6J	1.7	54.2	66.7	71.7	623D2S	36.7	65.0	72.5	75.8
623E9J	50.0	70.8	75.0	75.8	623D2S	36.7	65.0	72.5	75.8
623E9J	50.0	70.8	75.0	75.8	623F7G	25.8	64.2	73.3	75.8
623G3E	42.5	68.3	70.8	75.0	623F7G	25.8	64.2	73.3	75.8
623G3E	42.5	68.3	70.8	75.0	623H9R	34.2	70.0	74.2	76.7

ABUTH and ECHCF result: about the most activated preparation that ABUTH tested is 623F7G.About ECHCF, the activity of some preparations quite.

Embodiment 23

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 23a.

Table 23a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	755A8W	K	4.3	S96	1.4
755B7V	K	4.3	S91	1.4			755A8W	K	4.3	S96	1.4
755B7V	K	4.3	S91	1.4			757A3R	K	4.3	S97	1.4
755D9Z	K	4.3	S96	0.7	S19	0.7	757A3R	K	4.3	S97	1.4
755D9Z	K	4.3	S96	0.7	S19	0.7	755E1H	K	4.3	S91	0.7	S19	0.7
755F6S	K	4.3	S97	0.9	S19	0.5	755E1H	K	4.3	S91	0.7	S19	0.7
755F6S	K	4.3	S97	0.9	S19	0.5	755G8E	K	4.3			S19	1.4

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 23a composition and Comparative composition 554,360 and 553.Get all replicate tests average of each processing, the result is shown in table 23b and 23c.

Table 23b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	49.2	70.0	80.8
360	40.0	81.7	89.2	90.0	554	0.0	49.2	70.0	80.8
360	40.0	81.7	89.2	90.0	553	72.5	87.5	90.0	92.0
755A8W	23.3	66.7	79.2	84.2	553	72.5	87.5	90.0	92.0
755A8W	23.3	66.7	79.2	84.2	755B7V	3.3	62.5	78.3	85.0
757A3R	39.2	76.7	83.3	85.8	755B7V	3.3	62.5	78.3	85.0
757A3R	39.2	76.7	83.3	85.8	755D9Z	38.3	81.7	85.0	87.5
755E1H	58.3	80.0	85.0	85.0	755D9Z	38.3	81.7	85.0	87.5
755E1H	58.3	80.0	85.0	85.0	755F6S	54.2	75.8	85.8	86.7
755G8E	7.5	10.0	3.3	1.7	755F6S	54.2	75.8	85.8	86.7

Table 23c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0.0	6.7	37.5	43.3
360	35.8	69.2	75.8	80.8	554	0.0	6.7	37.5	43.3
360	35.8	69.2	75.8	80.8	553	65.8	72.5	81.7	85.8
755A8W	0.0	58.3	69.2	72.5	553	65.8	72.5	81.7	85.8
755A8W	0.0	58.3	69.2	72.5	755B7V	5.0	52.5	71.7	74.2
757A3R	6.7	42.5	67.5	70.0	755B7V	5.0	52.5	71.7	74.2
757A3R	6.7	42.5	67.5	70.0	755D9Z	0.0	62.5	71.7	74.2
755E1H	11.7	54.2	70.8	72.5	755D9Z	0.0	62.5	71.7	74.2
755E1H	11.7	54.2	70.8	72.5	755F6S	1.7	57.5	70.8	76.7
755G8E	0.0	0.0	0.0	0.0	755F6S	1.7	57.5	70.8	76.7

ABUTH and ECHCF result: have most about ABUTH and ECHCF tested active and effectively preparation be standard 360 and 553.

Embodiment 24

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 24a.

Table 24a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	469A7S	K	30	S65	10.0
469B3M	K	30	S98	10.0	469A7S	K	30	S65	10.0
469B3M	K	30	S98	10.0	469A8A	K	30	S20	10.0
469D2N	K	30	S09	10.0	469A8A	K	30	S20	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 24a composition and Comparative composition 139 and 360.Get all replicate tests average of each processing, the result is shown in table 24b and 24c.

Table 24b:ABUTH control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	0.0	50.0	71.7	90.8
360	33.3	70.0	88.0	99.0	139	0.0	50.0	71.7	90.8
360	33.3	70.0	88.0	99.0	469A7S	2.5	48.3	73.3	93.2
469B3M	4.2	49.2	78.3	93.3	469A7S	2.5	48.3	73.3	93.2
469B3M	4.2	49.2	78.3	93.3	469A8A	10.0	67.5	84.2	97.7
469D2N	10.8	70.8	88.	97.5	469A8A	10.0	67.5	84.2	97.7

Table 24c:ECHCF control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	10.0	46.7	55.8	70.8
360	49.2	77.5	98.3	97.5	139	10.0	46.7	55.8	70.8
360	49.2	77.5	98.3	97.5	469A7S	25.8	50.8	66.7	75.8
469B3M	24.2	57.5	62.5	75.8	469A7S	25.8	50.8	66.7	75.8
469B3M	24.2	57.5	62.5	75.8	469A8A	27.5	51.7	72.5	79.2
469D2N	49.2	65.8	75.8	92.8	469A8A	27.5	51.7	72.5	79.2

ABUTH and ECHCF result: about ECHCF, all are better than 139 standards for test preparation.About ABUTH, four kinds of preparations of being tested have three kinds to be better than 139 standards.360 standards all are the most activated preparations to ABUTH and ECHCF.

Embodiment 25

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 25a.

Table 25a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	659B6S	K	480.00	MPE01	120.0
659C8Q	K	480.00	EA175	120.0			659B6S	K	480.00	MPE01	120.0
659C8Q	K	480.00	EA175	120.0			659D4B	K	480.00	ED175	120.0
664B7E	K	480.00	EA175	108.0	ED175	12.0	659D4B	K	480.00	ED175	120.0
664B7E	K	480.00	EA175	108.0	ED175	12.0	664A3G	K	480.00	EA175	96.0	ED175	24.0
662C1R	K	480.00	EA175	90.0	ED175	30.0	664A3G	K	480.00	EA175	96.0	ED175	24.0
662C1R	K	480.00	EA175	90.0	ED175	30.0	662D9S	K	480.00	EA175	60.0	ED175	60.0
360	K	480.00	EA175				662D9S	K	480.00	EA175	60.0	ED175	60.0
360	K	480.00	EA175				754	K	480.00	EA175
560	K	480.00	EA175	121	135		754	K	480.00	EA175

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 25a composition and Comparative composition 754,560 and 360.Get all replicate tests average of each processing, the result is shown in table 25b and 25c.

Table 25b:ABUTH control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	754	14.2	81.7	85.8	90.8
360	48.3	80.0	88.3	90.0	754	14.2	81.7	85.8	90.8
360	48.3	80.0	88.3	90.0	560	40.0	74.2	85.0	89.2
659B6S	24.2	72.5	81.7	85.8	560	40.0	74.2	85.0	89.2
659B6S	24.2	72.5	81.7	85.8	659C8Q	10.0	73.3	80.8	85.0
659D4B	23.3	69.2	82.5	84.2	659C8Q	10.0	73.3	80.8	85.0
659D4B	23.3	69.2	82.5	84.2	664B7E	12.5	75.0	82.5	85.8
664A3G	61.7	76.7	82.5	86.7	664B7E	12.5	75.0	82.5	85.8
664A3G	61.7	76.7	82.5	86.7	662C1R	43.3	79.2	82.5	85.0
662D9S	74.2	79.2	81.7	85.0	662C1R	43.3	79.2	82.5	85.0

Table 25c:ECHCF control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	754	5.0	58.3	72.5	79.2
360	13.3	58.3	72.5	80.0	754	5.0	58.3	72.5	79.2
360	13.3	58.3	72.5	80.0	560	15.0	55.8	64.2	68.3
659B6S	15.0	51.7	60.0	64.2	560	15.0	55.8	64.2	68.3
659B6S	15.0	51.7	60.0	64.2	659C8Q	22.5	53.3	65.0	67.5
659D4B	27.5	60.0	59.2	66.7	659C8Q	22.5	53.3	65.0	67.5
659D4B	27.5	60.0	59.2	66.7	664B7E	26.7	55.0	62.5	70.0
664A3G	34.2	52.5	60.0	67.5	664B7E	26.7	55.0	62.5	70.0
664A3G	34.2	52.5	60.0	67.5	662C1R	32.5	55.0	66.7	70.8
662D9S	35.0	55.0	66.7	72.5	662C1R	32.5	55.0	66.7	70.8

ABUTH and ECHCF result: about overall performance, 662D9S preparation 360 standards no better than on effect.

Embodiment 26

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 26a.

Table 26a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	206A2W	IPA	480.00	T003A	120.0
206B4G	MEA	480.00	T003A	120.0	206A2W	IPA	480.00	T003A	120.0
206B4G	MEA	480.00	T003A	120.0	206C8S	K	480.00	T003A	120.0
206D3N	IPA	480.00	T003B	120.0	206C8S	K	480.00	T003A	120.0
206D3N	IPA	480.00	T003B	120.0	206E7X	MEA	480.00	T003B	120.0
206F1A	IPA	480.00	T003C	120.0	206E7X	MEA	480.00	T003B	120.0
206F1A	IPA	480.00	T003C	120.0	206G9A	MEA	480.00	T003C	120.0
206H6N	IPA	480.00	T003D	120.0	206G9A	MEA	480.00	T003C	120.0
206H6N	IPA	480.00	T003D	120.0	206I2D	IPA	480.00	T003E	120.0
360	IPA	360			206I2D	IPA	480.00	T003E	120.0
360	IPA	360			754	IPA	445	WIT05	5.9
280	IPA	480	M121	120	754	IPA	445	WIT05	5.9
280	IPA	480	M121	120	128	MEA	480	M121	120

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 26a composition and Comparative composition 754,128 and 280.Get all replicate tests average of each processing, the result is shown in table 26b and 26c.

Table 26b:ABUTH control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	754	30.0	80.0	86.0	96.0
206A2W	0.0	67.0	81.0	84.0	754	30.0	80.0	86.0	96.0
206A2W	0.0	67.0	81.0	84.0	206B4G	1.0	70.0	81.0	84.0
206C8S	60.	68.0	82.0	84.0	206B4G	1.0	70.0	81.0	84.0
206C8S	60.	68.0	82.0	84.0	206D3N	8.0	60.0	82.0	84.0
206E7X	17.0	73.0	82.0	84.0	206D3N	8.0	60.0	82.0	84.0
206E7X	17.0	73.0	82.0	84.0	206F1A	22.0	71.0	81.0	85.0
206G9A	33.0	76.0	82.0	85.0	206F1A	22.0	71.0	81.0	85.0
206G9A	33.0	76.0	82.0	85.0	206H6N	21.0	75.0	83.0	87.0
206I2D	26.0	66.0	83.0	86.0	206H6N	21.0	75.0	83.0	87.0
206I2D	26.0	66.0	83.0	86.0	128	42.0	82.0	86.0	93.0
280	38.0	80.0	86.0	92.0	128	42.0	82.0	86.0	93.0

Table 26c:ECHCF control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	754	52.0	84.0	91.4	97.2
206A2W	26.0	63.0	71.0	80.0	754	52.0	84.0	91.4	97.2
206A2W	26.0	63.0	71.0	80.0	206B4G	29.0	60.0	73.0	85.0
206C8S	48.0	68.0	70.0	82.0	206B4G	29.0	60.0	73.0	85.0
206C8S	48.0	68.0	70.0	82.0	206D3N	26.0	55.0	70.0	88.0
206E7X	55.0	63.0	73.0	86.0	206D3N	26.0	55.0	70.0	88.0
206E7X	55.0	63.0	73.0	86.0	206F1A	46.0	61.0	79.0	86.0
206G9A	57.0	66.0	75.0	83.0	206F1A	46.0	61.0	79.0	86.0
206G9A	57.0	66.0	75.0	83.0	206H6N	38.0	63.0	78.0	89.6
206I2D	51.0	62.0	71.0	85.0	206H6N	38.0	63.0	78.0	89.6
206I2D	51.0	62.0	71.0	85.0	128	59.0	88.0	97.4	99.8
280	60.0	85.0	97.8	97.6	128	59.0	88.0	97.4	99.8

ABUTH and ECHCF result: all resemble standard 754,128 and 280 effective to the weeds of being tested for test preparation.

Embodiment 27

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 27a.

Table 27a

Comp.	Salt	g/l	Compt. 1	g/l	Compt .2	g/l	Compt. 3	g/l
Comp.	Salt	g/l	Compt. 1	g/l	Compt .2	g/l	Compt. 3	g/l	616A5F	K	540	NDPA	135.0
664A6H	K	540	M121	135.0					616A5F	K	540	NDPA	135.0
664A6H	K	540	M121	135.0					615C3M	K	540	ETH12	45.1	WIT60	45.1	SUR12	45.1
615D2M	K	540	ETH12	54.0	WIT60	54.0	SUR12	54.0	615C3M	K	540	ETH12	45.1	WIT60	45.1	SUR12	45.1
615D2M	K	540	ETH12	54.0	WIT60	54.0	SUR12	54.0	615E1F	K	540	ETH12	67.5	WIT60	67.5	SUR12	27.0
615F8C	K	540	ETH12	54.0	WIT60	54.0	SUR12	27.0	615E1F	K	540	ETH12	67.5	WIT60	67.5	SUR12	27.0
615F8C	K	540	ETH12	54.0	WIT60	54.0	SUR12	27.0	616G3S	K	540	ETH12	67.5	WIT05	67.5
360		360	ETH12						616G3S	K	540	ETH12	67.5	WIT05	67.5
360		360	ETH12						754		445	ETH12

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 26a composition and Comparative composition 360,754,139 and 554.Get all replicate tests average of each processing, the result is shown in table 27b and 27c.

Table 27b:ABUTH control %

Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha
Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha	139	5.8	30.8	60.0	74.2
554	11.7	19.2	46.7	60.0	139	5.8	30.8	60.0	74.2
554	11.7	19.2	46.7	60.0	360	43.3	64.2	89.7	90.8
616A5F	30.0	36.7	65.0	65.0	360	43.3	64.2	89.7	90.8
616A5F	30.0	36.7	65.0	65.0	664A6H	25.0	50.0	70.0	75.8
615C3M	48.3	50.0	76.7	81.7	664A6H	25.0	50.0	70.0	75.8
615C3M	48.3	50.0	76.7	81.7	615D2M	29.2	55.0	78.3	81.7
615E1F	16.7	45.0	70.0	70.8	615D2M	29.2	55.0	78.3	81.7
615E1F	16.7	45.0	70.0	70.8	615F8C	23.3	43.3	66.7	81.7
616G3S	16.7	36.7	72.5	767	615F8C	23.3	43.3	66.7	81.7
616G3S	16.7	36.7	72.5	767	754	30.0	65.0	84.2	90.5

Table 27c:ECHCF control %

Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha
Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha	139	30.8	33.3	39.2	56.7
554	15.0	33.3	37.5	55.0	139	30.8	33.3	39.2	56.7
554	15.0	33.3	37.5	55.0	360	81.7	95.5	98.8	99.2
616A5F	40.0	45.0	62.5	69.2	360	81.7	95.5	98.8	99.2
616A5F	40.0	45.0	62.5	69.2	664A6H	65.0	75.8	93.8	95.2
615C3M	73.3	77.5	86.7	93.5	664A6H	65.0	75.8	93.8	95.2
615C3M	73.3	77.5	86.7	93.5	615D2M	62.5	86.7	98.0	98.0
615E1F	75.0	91.2	93.2	99.0	615D2M	62.5	86.7	98.0	98.0
615E1F	75.0	91.2	93.2	99.0	615F8C	75.8	85.0	97.3	98.8
616G3S	77.5	91.5	96.3	99.2	615F8C	75.8	85.0	97.3	98.8
616G3S	77.5	91.5	96.3	99.2	754	72.5	87.5	98.0	99.0

ABUTH and ECHCF result: this test does not have preparation to resemble 360 and 754 standards effective to ABUTH.615C3M and 615D2M are that effect is best for test preparation to ABUTH.

Embodiment 28

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 28a.

Table 28a

Comp.	Salt	g/l	Comp t.1	g/l	Compt .2	g/l	Compt .3	g/l	Co mpt. 4	g/l
Comp.	Salt	g/l	Comp t.1	g/l	Compt .2	g/l	Compt .3	g/l	Co mpt. 4	g/l	5606H	K	540	M121	135
1289M	ME A	480	M121	120							5606H	K	540	M121	135
1289M	ME A	480	M121	120							2687J	K	540	ETH1 2	54	WIT05	81	AGN6 8	0.27
2693C	K	540	ETH1 2	81	WIT05	54	AGN6 8	0.27			2687J	K	540	ETH1 2	54	WIT05	81	AGN6 8	0.27
2693C	K	540	ETH1 2	81	WIT05	54	AGN6 8	0.27			2704X	K	540	ETH1 2	61	WIT05	74	AGN6 8	0.27	CIT 1	3. 7
2716B	K	480	ETH1 2	48	WIT80	48	AGN6 8	0.27	INT 00	24	2704X	K	540	ETH1 2	61	WIT05	74	AGN6 8	0.27	CIT 1	3. 7
2716B	K	480	ETH1 2	48	WIT80	48	AGN6 8	0.27	INT 00	24	2724C	K	540	ETH1 2	61	WIT05	74	AGN6 8	0.27
4598H	K	480	M121	121			GLYC	51	CIT 01	3. 5	2724C	K	540	ETH1 2	61	WIT05	74	AGN6 8	0.27
4598H	K	480	M121	121			GLYC	51	CIT 01	3. 5	4603D	K	540	M121	135					CIT 01	4
5633S	K	540	ETH1 2	60.8	WIT05	74. 3	ARO6 6		GLY C	10 2	4603D	K	540	M121	135					CIT 01	4
5633S	K	540	ETH1 2	60.8	WIT05	74. 3	ARO6 6		GLY C	10 2	7655R	K	472	ARM C		WIT30 5
360		360									7655R	K	472	ARM C		WIT30 5
360		360									754		445	WIT0 5	5.9	INT00	2.2 4

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 28a composition and Comparative composition 360 and 754.Get all replicate tests average of each processing, the result is shown in table 28b and 28c.

Table 28b:ABUTH control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	754	41.7	80.0	85.0	88.3
360	36.7	80.0	88.3	94.3	754	41.7	80.0	85.0	88.3
360	36.7	80.0	88.3	94.3	5606H	5.0	78.3	81.7	86.7
1289M	26.7	81.7	85.0	88.3	5606H	5.0	78.3	81.7	86.7
1289M	26.7	81.7	85.0	88.3	2687J	0.0	76.7	81.7	83.3
2693C	0.0	73.3	81.7	81.7	2687J	0.0	76.7	81.7	83.3
2693C	0.0	73.3	81.7	81.7	2704X	0.0	75.0	76.7	80.0
2716B	0.0	60.0	76.7	81.7	2704X	0.0	75.0	76.7	80.0
2716B	0.0	60.0	76.7	81.7	2724C	3.3	60.0	78.3	81.7
4598H	20.0	78.3	81.7	88.3	2724C	3.3	60.0	78.3	81.7
4598H	20.0	78.3	81.7	88.3	4603D	1.7	73.3	80.0	88.3
5633S	1.7	66.7	80.0	83.3	4603D	1.7	73.3	80.0	88.3
5633S	1.7	66.7	80.0	83.3	7655R	1.7	71.7	80.0	88.3

Table 28c:ECHCF control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	754	31.7	68.3	73.3	75.0
360	43.3	66.7	75.0	76.7	754	31.7	68.3	73.3	75.0
360	43.3	66.7	75.0	76.7	5606H	26.7	70.0	71.7	71.7
1289M	48.3	70.0	71.7	75.0	5606H	26.7	70.0	71.7	71.7
1289M	48.3	70.0	71.7	75.0	2687J	20.0	65.0	68.3	70.0
2693C	20.0	63.3	66.7	70.0	2687J	20.0	65.0	68.3	70.0
2693C	20.0	63.3	66.7	70.0	2704X	16.7	63.3	66.7	70.0
2716B	26.7	58.3	65.0	70.0	2704X	16.7	63.3	66.7	70.0
2716B	26.7	58.3	65.0	70.0	2724C	30.0	65.0	68.3	70.0
4598H	23.3	70.0	73.3	71.7	2724C	30.0	65.0	68.3	70.0
4598H	23.3	70.0	73.3	71.7	4603D	30.0	66.7	70.0	71.7
5633S	25.0	60.0	65.0	70.0	4603D	30.0	66.7	70.0	71.7
5633S	25.0	60.0	65.0	70.0	7655R	26.7	70.0	71.7	75.0

ABUTH and ECHCF result: about ABUTH, it is effective that this test does not have preparation to resemble standard 360 and 754.But, about ECHCF, most of preparations are similar to standard 754.

Embodiment 29

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 29a.

Table 29a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	553	IPA	360	BR156	6.4	ETH25	9.6
M368	IPA	31	EUMU	4.9	TAM05	7.4	553	IPA	360	BR156	6.4	ETH25	9.6
M368	IPA	31	EUMU	4.9	TAM05	7.4	M318	K	37	EUMU	4.9	TAM80	7.4
992A6H	K	480	EUMU	4.9	TAM80	7.4	M318	K	37	EUMU	4.9	TAM80	7.4
992A6H	K	480	EUMU	4.9	TAM80	7.4	99283D	K	480	B1A	4.9	TAM80	7.4
992C7X	K	480	B1B	4.9	TAM80	7.4	99283D	K	480	B1A	4.9	TAM80	7.4
992C7X	K	480	B1B	4.9	TAM80	7.4	992D1G	K	480	B1C	4.9	TAM80	7.4
992E5R	K	480	B1F	4.9	TAM80	7.4	992D1G	K	480	B1C	4.9	TAM80	7.4
992E5R	K	480	B1F	4.9	TAM80	7.4	992F3E	K	480	EXP86	4.9	TAM80	7.4

Plantation piemarker (ABUTH) is handled according to above-mentioned standard method.Use table 29a composition and Comparative composition 553,554 and 754.Get all replicate tests average of each processing, the result is shown in table 29b.

Table 29b:ABUTH control %

Composition	75g a.e./ha	125g a.e./ha	175g a.e./ha	250g a.e./ha
Composition	75g a.e./ha	125g a.e./ha	175g a.e./ha	250g a.e./ha	553	13.3	65	82.5	88.3
754	0	26.7	51.7	80	553	13.3	65	82.5	88.3
754	0	26.7	51.7	80	M318	6.7	48.3	70	79.2
554	0	0	0	1.7	M318	6.7	48.3	70	79.2
554	0	0	0	1.7	M368	0	14.2	65	77.5
992A6H	19.2	35.8	64.2	75	M368	0	14.2	65	77.5
992A6H	19.2	35.8	64.2	75	992B3D	8.3	55	65	84.2
992C7X	20	56.7	70.8	81.7	992B3D	8.3	55	65	84.2
992C7X	20	56.7	70.8	81.7	992D1G	0	38.3	69.2	79.2
992E5R	19.2	52.5	77.5	83.3	992D1G	0	38.3	69.2	79.2
992E5R	19.2	52.5	77.5	83.3	992F3E	1.7	55.8	70	84.2

ABUTH result: in this test, 553 standards are the best preparations of effect.The activity of M318 is weaker than 553 standards, is better than M368 and 754.M368 and 754 is similar on performance.

Embodiment 30

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 30a.

Table 30a

Comp.	Salt	g/l	Component 1	wt. ％	Component 2	wt.％
Comp.	Salt	g/l	Component 1	wt. ％	Component 2	wt.％	553	IPA	360	BRI56	6.4	ETH25	9.6
M620	IPA	360	BRI56	4.8	ETH25	7.2	553	IPA	360	BRI56	6.4	ETH25	9.6
M620	IPA	360	BRI56	4.8	ETH25	7.2	M619	IPA	360	BRI56	4	ETH25	6
968A7F	K	480	EMUL	4.8	WIT80	7.2	M619	IPA	360	BRI56	4	ETH25	6
968A7F	K	480	EMUL	4.8	WIT80	7.2	968B4R	K	480	EXP86	4.8	WIT80	7.2
968C9S	K	480	EMUL	4.8	WIT05	7.2	968B4R	K	480	EXP86	4.8	WIT80	7.2
968C9S	K	480	EMUL	4.8	WIT05	7.2	968D3E	K	480	EXP86	4.8	WIT05	7.2
968E6V	K	480	EMUL	4.8	EMC42	7.2	968D3E	K	480	EXP86	4.8	WIT05	7.2
968E6V	K	480	EMUL	4.8	EMC42	7.2	968F2A	K	480	EXP86	4.8	EMC42	7.2
968G5J	K	480		12	EMC42	6	968F2A	K	480	EXP86	4.8	EMC42	7.2

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 30a composition and Comparative composition 553,554 and 360.Get all replicate tests average of each processing, the result is shown in table 30b and 30c.

Table 30b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	554	0	16	63	70
360	70	79	85	90	554	0	16	63	70
360	70	79	85	90	553	78	83	90	94
M620	73	82	88	90	553	78	83	90	94
M620	73	82	88	90	M619	73	80	89	94
968A7F	69	70	78	84	M619	73	80	89	94
968A7F	69	70	78	84	968B4R	69	78	82	93
968C9S	58	75	81	88	968B4R	69	78	82	93
968C9S	58	75	81	88	968D3E	73	79	88	94
968E6V	60	69	80	81	968D3E	73	79	88	94
968E6V	60	69	80	81	968F2A	63	76	83	88
968G5J	37	53	76	79	968F2A	63	76	83	88

Table 30c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	554	0	6	15	24
360	44	56	73	81.6	554	0	6	15	24
360	44	56	73	81.6	553	54	70	77	82.8
M620	50	62	73	85.8	553	54	70	77	82.8
M620	50	62	73	85.8	M619	51	67	79	91.6
968A7F	36	57	59	62	M619	51	67	79	91.6
968A7F	36	57	59	62	968B4R	39	55	63	75
968C9S	40	56	55	68	968B4R	39	55	63	75
968C9S	40	56	55	68	968D3E	34	56	64	71
968E6V	20	47	58	66	968D3E	34	56	64	71
968E6V	20	47	58	66	968F2A	22	46	56	58
968G5J	14	41	55	58	968F2A	22	46	56	58

ABUTH and ECHCF result: in this test, the best preparation of performance generally speaking is 968B4R.

Embodiment 31

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 31a.

Table 31a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	730A0A	K	30	S2	10
730C7U	K	30	S1	10			730A0A	K	30	S2	10
730C7U	K	30	S1	10			730D7C	K	30	1816E	10
487H3K	K	4.3	S2	0.7	BRI56	0.7	730D7C	K	30	1816E	10
487H3K	K	4.3	S2	0.7	BRI56	0.7	487I2W	K	4.3	S1	0.9	BRI56	0.5
487L99I	K	4.3	1816E	0.8	BRI56	0.6	487I2W	K	4.3	S1	0.9	BRI56	0.5
487L99I	K	4.3	1816E	0.8	BRI56	0.6	496C7Y	K	30	Eth25	5.8	BRI56	4.2
730E8J	K	30	Eth25	10			496C7Y	K	30	Eth25	5.8	BRI56	4.2
730E8J	K	30	Eth25	10			731A9T	K	4.3			BRI56	1.4

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 31a composition and Comparative composition 139,553 and 360.Get all replicate tests average of each processing, the result is shown in table 31b and 31c.

Table 31b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	60	73.8	80
360	40	80	92	91.3	139	0	60	73.8	80
360	40	80	92	91.3	553	50	82.5	93.3	90
730A0A	62.5	81.3	91.3	94.8	553	50	82.5	93.3	90
730A0A	62.5	81.3	91.3	94.8	730C7U	78.8	90	97.8	96
730D7C	72.5	87.5	97.8	96	730C7U	78.8	90	97.8	96
730D7C	72.5	87.5	97.8	96	487H3K	52.5	77.5	90	92.5
487I2W	60	80	95.8	95.8	487H3K	52.5	77.5	90	92.5
487I2W	60	80	95.8	95.8	487L9I	68.8	80	92.5	88.8
496C7Y	66.3	82.5	92.5	88.8	487L9I	68.8	80	92.5	88.8
496C7Y	66.3	82.5	92.5	88.8	730E8J	53.8	80	91.3	91.3
731A9T	5	73.8	86.3	90	730E8J	53.8	80	91.3	91.3

Table 31c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	26.3	62.5	63.8	71.3
360	63.8	81.3	85	97.5	139	26.3	62.5	63.8	71.3
360	63.8	81.3	85	97.5	553	66.3	78.8	86.3	94.8
730A0A	65	81.3	80	93.5	553	66.3	78.8	86.3	94.8
730A0A	65	81.3	80	93.5	730C7U	68.8	80	93.8	92.5
730D7C	67.5	77.5	88.8	92.3	730C7U	68.8	80	93.8	92.5
730D7C	67.5	77.5	88.8	92.3	487H3K	62.5	77.5	80	87.3
487I2W	61.3	88.3	85	94.8	487H3K	62.5	77.5	80	87.3
487I2W	61.3	88.3	85	94.8	487L9I	62.5	76.3	91.3	87.5
496C7Y	62.5	78.8	82.5	95	487L9I	62.5	76.3	91.3	87.5
496C7Y	62.5	78.8	82.5	95	730E8J	62.5	78.8	84.8	87.5
731A9T	21.3	73.8	76.3	76.3	730E8J	62.5	78.8	84.8	87.5

ABUTH and ECHCF result: in this experiment, composition 730C7U is the most activated preparation, show the weeding validity that is better than Comparative composition 360 about piemarker (ABUTH) under all ratios, performance is similar to the weeding validity of Comparative composition 360 about grass (ECHCF).Performance is similar to the weeding validity of Comparative composition 360 to composition 730A0A about grass (ECHCF), but is better than the weeding validity of Comparative composition under the height ratio about piemarker (ABUTH) performance.

Embodiment 32

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 32a.

Table 32a

Comp.	Salt	％	Component 1	％	Component 2	％
Comp.	Salt	％	Component 1	％	Component 2	％	553	K	31	BRI56	6.4	Eth25	9.6
966A7A	K	39		12	WIT80	6	553	K	31	BRI56	6.4	Eth25	9.6
966A7A	K	39		12	WIT80	6	966B2 W	K	36.9		12	WIT80	5
966C5T	K	36.9		12	WIT80	5	966B2 W	K	36.9		12	WIT80	5
966C5T	K	36.9		12	WIT80	5	966D8J	K	36.9		12	WIT80	5

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 32a composition and Comparative composition 360,553,554,560,754 and 765.Get all replicate tests average of each processing, the result is shown in table 32b and 32c.

Table 32b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	554	21.7	10	67.5	66.7
360	60.8	75	81.7	88.3	554	21.7	10	67.5	66.7
360	60.8	75	81.7	88.3	754	29.2	72.5	81.7	84.2
553	67.5	76.7	88.3	90	754	29.2	72.5	81.7	84.2
553	67.5	76.7	88.3	90	560	29.2	64.2	78.3	81.7
765	30.8	69.2	79.2	86.7	560	29.2	64.2	78.3	81.7
765	30.8	69.2	79.2	86.7	966A7A	3.3	50.8	76.7	80
966B2W	47.5	73.3	80	83.3	966A7A	3.3	50.8	76.7	80
966B2W	47.5	73.3	80	83.3	966C5T	14.2	64.2	75	80
966D8J	35	65.8	79.2	80.8	966C5T	14.2	64.2	75	80

Table 32c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	554	5	5	20	35
360	37.5	54.2	59.2	75.8	554	5	5	20	35
360	37.5	54.2	59.2	75.8	754	20	55	59.2	72.5
553	50	65	74.2	78.3	754	20	55	59.2	72.5
553	50	65	74.2	78.3	560	30	51.7	55.8	65
765	36.7	54.2	60	66.7	560	30	51.7	55.8	65
765	36.7	54.2	60	66.7	966A7A	8.3	52.5	55.8	66.7
966B2W	34.2	58.3	59.2	65	966A7A	8.3	52.5	55.8	66.7
966B2W	34.2	58.3	59.2	65	966C5T	8.3	53.3	54.2	64.2
966D8J	34.2	52.5	57.5	70.8	966C5T	8.3	53.3	54.2	64.2

Embodiment 33

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 33a.

Table 33a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	487A2Q	K	30	S53	10
487B4R	K	30	S54	10	487A2Q	K	30	S53	10
487B4R	K	30	S54	10	487C7U	K	30	S10	10
487D9I	K	30	S55	10	487C7U	K	30	S10	10
487D9I	K	30	S55	10	487E8Y	K	30	S56	10
487F0P	K	30	S57	10	487E8Y	K	30	S56	10
487F0P	K	30	S57	10	487G4E	K	30	1816E	10
496A5T	K	30	ETH25	10	487G4E	K	30	1816E	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 33a composition and Comparative composition 139,553 and 360.Get all replicate tests average of each processing, the result is shown in table 33b and 33c.

Table 33b:ABUTH control %

Composition	50g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha	139	0	9.2	50.8	61.7
360	0	54.2	80	82.5	139	0	9.2	50.8	61.7
360	0	54.2	80	82.5	553	8.3	75	84.2	85.8
487A2Q	0	39.2	68.3	73.3	553	8.3	75	84.2	85.8
487A2Q	0	39.2	68.3	73.3	487B4R	27.5	75	82.5	85
487C7U	25.8	70.8	79.2	80	487B4R	27.5	75	82.5	85
487C7U	25.8	70.8	79.2	80	487D9I	0	54.2	77.5	80.8
487E8Y	11.7	69.2	76.7	80.8	487D9I	0	54.2	77.5	80.8
487E8Y	11.7	69.2	76.7	80.8	487F0P	0	71.7	80.8	85.8
487G4E	15.8	63.3	80	82.5	487F0P	0	71.7	80.8	85.8
487G4E	15.8	63.3	80	82.5	496A5T	0	32.5	73.3	76.7

Table 33c:ECHCF control %

Composition	50g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	150g a.e./ha	200g a.e./ha	139	0	44.2	65	64.2
360	48.3	68.3	72.5	77.5	139	0	44.2	65	64.2
360	48.3	68.3	72.5	77.5	553	64.2	68.3	78.3	80
487A2Q	65.8	70.8	74.2	79.2	553	64.2	68.3	78.3	80
487A2Q	65.8	70.8	74.2	79.2	487B4R	64.2	70	74.2	75.8
487C7U	64.2	69.2	73.3	75	487B4R	64.2	70	74.2	75.8
487C7U	64.2	69.2	73.3	75	487D9I	65.8	66.7	75.8	85
487E8Y	63.3	69.2	73.3	79.2	487D9I	65.8	66.7	75.8	85
487E8Y	63.3	69.2	73.3	79.2	487F0P	64.2	66.7	72.5	76.7
487G4E	64.2	66.7	69.2	74.2	487F0P	64.2	66.7	72.5	76.7
487G4E	64.2	66.7	69.2	74.2	496A5T	49.2	65.8	73.3	76.7

ABUTH and ECHCF result: composition 487B4R performance is similar to the weeding validity of Comparative composition 553; In the experiment to ABUTH, composition 487B4R and Comparative composition 553 all are the most activated compositions.

Embodiment 34

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 34a.

Table 34a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	732A3Q	K	30	S66	10
732B3R	K	30	S67	10	732A3Q	K	30	S66	10
732B3R	K	30	S67	10	732C9T	K	30	S68	10
730A5R	K	30	S10	10	732C9T	K	30	S68	10
730A5R	K	30	S10	10	730B5X	K	30	S54	10
730C1P	K	30	S53	10	730B5X	K	30	S54	10
730C1P	K	30	S53	10	487E2I	K	30	S56	10
487F7S	K	30	S57	10	487E2I	K	30	S56	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 34a composition and Comparative composition 139,553 and 360.Get all replicate tests average of each processing, the result is shown in table 34b and 34c.

Table 34b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	8.3	53.3	62.5	73.3
360	31.7	74.2	85.8	90.3	139	8.3	53.3	62.5	73.3
360	31.7	74.2	85.8	90.3	553	44.2	74.2	84.2	92.7
732A3Q	24.2	61.7	76.7	84.2	553	44.2	74.2	84.2	92.7
732A3Q	24.2	61.7	76.7	84.2	732B3R	50.8	75	86.7	91.7
732C9T	53.3	81.7	88.3	92.5	732B3R	50.8	75	86.7	91.7
732C9T	53.3	81.7	88.3	92.5	730A5R	13.3	64.2	78.3	85
730B5X	57.5	77.5	89.2	93.8	730A5R	13.3	64.2	78.3	85
730B5X	57.5	77.5	89.2	93.8	730C1P	70.8	83.3	91.7	92.5
487E2I	61.7	74.2	87.5	91.3	730C1P	70.8	83.3	91.7	92.5
487E2I	61.7	74.2	87.5	91.3	487F7S	65	81.7	90.8	94.7

Table 34c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	42.5	50.8	60
360	50.8	80.8	82.5	89.2	139	0	42.5	50.8	60
360	50.8	80.8	82.5	89.2	553	60	75.8	80.8	88.3
732A3Q	61.7	81.7	85	92.2	553	60	75.8	80.8	88.3
732A3Q	61.7	81.7	85	92.2	732B3R	58.3	77.5	83.3	93.3
732C9T	65	82.5	86.7	95.7	732B3R	58.3	77.5	83.3	93.3
732C9T	65	82.5	86.7	95.7	730A5R	64.2	79.2	82.5	93
730B5X	58.3	75	80	89.2	730A5R	64.2	79.2	82.5	93
730B5X	58.3	75	80	89.2	730C1P	59.2	75.8	84.2	90.8
487E2I	57.5	80	80	86.7	730C1P	59.2	75.8	84.2	90.8
487E2I	57.5	80	80	86.7	487F7S	66.7	78.3	85	85.8

ABUTH and ECHCF result: in the experiment to piemarker (ABUTH), composition 730C1P is the most activated composition; Under two kinds of minimum ratios, composition 730C9T performance is better than the weeding validity of Comparative composition 360 and Comparative composition 553.Composition 732C9T is to the most activated composition of barnyard grass (ECHCF); Composition 732C9T performance is better than the weeding validity of Comparative composition 360.

Embodiment 35

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 35a.

Table 35a

Comp.	Salt	％	Component 1	％	Component 2	％	Component 3	％
Comp.	Salt	％	Component 1	％	Component 2	％	Component 3	％	554	IPA	0	BRI56	6.4	ETH25	9.6	SC85	1.0
368	IPA	0	EMUL	4.9	WIT05	6	OA	6.5	554	IPA	0	BRI56	6.4	ETH25	9.6	SC85	1.0
368	IPA	0	EMUL	4.9	WIT05	6	OA	6.5	318	K	0	EMUL	4.9	WIT05	5	OA	6.5
905A3Z	K	36.9	LF700	4.0	WIT05	5	OA	6.5	318	K	0	EMUL	4.9	WIT05	5	OA	6.5
905A3Z	K	36.9	LF700	4.0	WIT05	5	OA	6.5	905B6N	K	36.9	LF700	5.0	WIT05	5	OA	6.5
905C5B	K	36.9	LF700	4.0	EXPB2	6	OA	6.5	905B6N	K	36.9	LF700	5.0	WIT05	5	OA	6.5
905C5B	K	36.9	LF700	4.0	EXPB2	6	OA	6.5	905D3D	K	36.9	LF700	5.0	EXPB2	5	OA	6.5
905E0L	K	36.9	EXPB2	4.0	WIT05	6	OA	6.5	905D3D	K	36.9	LF700	5.0	EXPB2	5	OA	6.5
905E0L	K	36.9	EXPB2	4.0	WIT05	6	OA	6.5	905F8M	K	36.9	EXPB2	4.0	EXPB2	6	OA	6.5

Plantation piemarker (ABUTH) is handled according to above-mentioned standard method.Use table 35a composition and Comparative composition 368,318,553,754 and 765.Get all replicate tests average of each processing, the result is shown in table 35b.

Table 35b:ABUTH control %

Composition	75g a.e./ha	125g a.e./ha	175g a.e./ha	250g a.e./ha
Composition	75g a.e./ha	125g a.e./ha	175g a.e./ha	250g a.e./ha	554	3.3	9.2	25.8	45.8
754	11.7	60	68.3	67.5	554	3.3	9.2	25.8	45.8
754	11.7	60	68.3	67.5	553	50.8	66.7	70.8	66.7
368	15	45	67.5	60	553	50.8	66.7	70.8	66.7
368	15	45	67.5	60	318	21.7	59.2	70	64.2
905A3Z	12.5	40.8	60	55	318	21.7	59.2	70	64.2
905A3Z	12.5	40.8	60	55	905B6N	15.8	25.8	55	64.2
905C5B	23.3	20.8	60	60	905B6N	15.8	25.8	55	64.2
905C5B	23.3	20.8	60	60	905D3D	19.2	25	59.2	61.7
905E0L	41.7	48.3	60	58.3	905D3D	19.2	25	59.2	61.7
905E0L	41.7	48.3	60	58.3	905F8M	5	39.2	57.5	67.5

ABUTH result: in this experiment, the weeding validity that Comparative composition 553 behaves oneself best.

Embodiment 36

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 36a.

Table 36a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	767H2R	K	30	S1	10
610B4S	K	30	S62	10	767H2R	K	30	S1	10
610B4S	K	30	S62	10	610C7V	K	30	S13	10
610D9J	K	30	S2	10	610C7V	K	30	S13	10
610D9J	K	30	S2	10	610E8Z	K	30	S81	10
610F0Q	K	30	S82	10	610E8Z	K	30	S81	10
610F0Q	K	30	S82	10	610G4F	K	30	S83	10
610H5U	K	30	S84	10	610G4F	K	30	S83	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 36a composition and Comparative composition 553,554 and 754.Get all replicate tests average of each processing, the result is shown in table 36b and 36c.

Table 36b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	6.7	60.8	61.7
754	8.3	68.3	86.7	91.7	554	0	6.7	60.8	61.7
754	8.3	68.3	86.7	91.7	553	63.3	83.3	90.8	94.5
767H2R	70.8	86.7	92.5	95.7	553	63.3	83.3	90.8	94.5
767H2R	70.8	86.7	92.5	95.7	610B4S	26.7	70.8	87.5	88.3
610C7V	42.5	64.2	83.3	84.2	610B4S	26.7	70.8	87.5	88.3
610C7V	42.5	64.2	83.3	84.2	610D9J	9.2	62.5	79.2	85
610E8Z	42.5	77.5	87.5	90.8	610D9J	9.2	62.5	79.2	85
610E8Z	42.5	77.5	87.5	90.8	610F0Q	21.7	73.3	84.2	86.7
610G4F	61.7	74.2	88.3	90	610F0Q	21.7	73.3	84.2	86.7
610G4F	61.7	74.2	88.3	90	610H5U	11.7	59.2	78.3	89.2

Table 36c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	6.7	28.3	46.7
754	5.0	70	71.7	75.8	554	0	6.7	28.3	46.7
754	5.0	70	71.7	75.8	553	54.2	71.7	77.5	85.8
767H2R	51.7	69.2	73.3	77.5	553	54.2	71.7	77.5	85.8
767H2R	51.7	69.2	73.3	77.5	610B4S	40.0	70	75.8	75.8
610C7V	25.0	68.3	73.3	75.8	610B4S	40.0	70	75.8	75.8
610C7V	25.0	68.3	73.3	75.8	610D9J	28.3	67.5	74.2	75.8
610E8Z	54.2	72.5	75	83.3	610D9J	28.3	67.5	74.2	75.8
610E8Z	54.2	72.5	75	83.3	610F0Q	53.3	71.7	75	80
610G4F	59.2	74.2	76.7	75	610F0Q	53.3	71.7	75	80
610G4F	59.2	74.2	76.7	75	610H5U	21.7	70.8	75.8	74.2

ABUTH and ECHCF result: in the experiment to piemarker (ABUTH), composition 767H2R and composition 553 are the most activated compositions.Composition 553 is to the most activated composition of barnyard grass (ECHCF).Under low ratio, composition 610E8Z and composition 610G4F are better than the activity of Comparative composition 754 to piemarker (ABUTH) and barnyard grass (ECHCF) performance.

Embodiment 37

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 37a.

Table 37a

Comp.	Salt t	g/l	Component 1	g/l
Comp.	Salt t	g/l	Component 1	g/l	760A3G	K	30	S73	10
760B7I	K	30	S74	10	760A3G	K	30	S73	10
760B7I	K	30	S74	10	760C4J	K	30	S75	10
760D4R	K	30	S76	10	760C4J	K	30	S75	10
760D4R	K	30	S76	10	761G5H	K	30	S01	10
741A6P	K	30	S77	10	761G5H	K	30	S01	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 37a composition and Comparative composition 553,554 and 360.Get all replicate tests average of each processing, the result is shown in table 37b and 37c.

Table 37b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	14.2	54.2	65.8
360	3.3	78.3	87.5	90	554	0	14.2	54.2	65.8
360	3.3	78.3	87.5	90	553	55.8	85	89.2	96.3
760A3G	34.2	59.2	74.2	81.7	553	55.8	85	89.2	96.3
760A3G	34.2	59.2	74.2	81.7	760B7I	23.3	60	74.2	79.2
760C4J	50.8	65.8	80.8	82.5	760B7I	23.3	60	74.2	79.2
760C4J	50.8	65.8	80.8	82.5	760D4R	40	72.5	83.3	85.8
761G5H	80.8	89.2	92.5	94.2	760D4R	40	72.5	83.3	85.8
761G5H	80.8	89.2	92.5	94.2	741A6P	41.7	75.8	84.2	87.5

Table 37c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	3.3	18.3	45.8
360	16.7	70.8	70.8	75	554	0	3.3	18.3	45.8
360	16.7	70.8	70.8	75	553	36.7	75	79.2	84.2
760A3G	15.8	67.5	67.5	75.8	553	36.7	75	79.2	84.2
760A3G	15.8	67.5	67.5	75.8	760B7I	11.7	62.5	70	75
760C4J	20	77.5	77.5	78.3	760B7I	11.7	62.5	70	75
760C4J	20	77.5	77.5	78.3	760D4R	13.3	73.3	72.5	74.2
761G5H	55.8	73.3	75.8	76.7	760D4R	13.3	73.3	72.5	74.2
761G5H	55.8	73.3	75.8	76.7	741A6P	50	75.8	75.8	77.5

Under higher rate, composition 553 is to the most activated composition of barnyard grass (ECHCF).

Embodiment 38

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 38a.

Table 38a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	603A7A	K	30	S74	10
603B2W	K	30	S75	10	603A7A	K	30	S74	10
603B2W	K	30	S75	10	603C5T	K	30	S76	10
603D8J	K	30	S77	10	603C5T	K	30	S76	10
603D8J	K	30	S77	10	603E8I	K	30	S78	10
603F6Y	K	30	S79	10	603E8I	K	30	S78	10
603F6Y	K	30	S79	10	603G0P	K	30	S80	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 38a composition and Comparative composition 553,554 and 360.Get all replicate tests average of each processing, the result is shown in table 38b and 38c.

Table 38b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	21.7	43.3	58.3
754	0	61.7	85.8	80.0	554	0	21.7	43.3	58.3
754	0	61.7	85.8	80.0	553	30	78.3	87.5	92.0
603A7A	3.3	35.0	70.8	80.8	553	30	78.3	87.5	92.0
603A7A	3.3	35.0	70.8	80.8	603B2W	8.3	18.3	62.5	70.8
603C5T	5.0	47.5	68.3	70.8	603B2W	8.3	18.3	62.5	70.8
603C5T	5.0	47.5	68.3	70.8	603D8J	28.3	50.8	76.7	88.3
603E8I	44.2	50.0	65.8	82.5	603D8J	28.3	50.8	76.7	88.3
603E8I	44.2	50.0	65.8	82.5	603F6Y	45.0	68.3	76.7	85.0
603G9O	40.8	45.8	66.7	75.0	603F6Y	45.0	68.3	76.7	85.0

Table 38c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	554	0	0	13.3	19.2
754	3.3	68.3	72.5	83.8	554	0	0	13.3	19.2
754	3.3	68.3	72.5	83.8	553	56.7	74.2	80.0	99.0
603A7A	20.8	63.3	67.5	74.2	553	56.7	74.2	80.0	99.0
603A7A	20.8	63.3	67.5	74.2	603B2W	27.5	60.8	70.8	75.0
603C5T	45.0	70.8	75.0	80.8	603B2W	27.5	60.8	70.8	75.0
603C5T	45.0	70.8	75.0	80.8	603D8J	47.5	70.8	81.7	95.8
603E8I	41.7	72.5	81.7	95.5	603D8J	47.5	70.8	81.7	95.8
603E8I	41.7	72.5	81.7	95.5	603F6Y	30.0	70.8	78.3	90.5
603G9O	11.7	65.0	70.0	77.5	603F6Y	30.0	70.8	78.3	90.5

ABUTH and ECHCF result: about piemarker (ABUTH) and barnyard grass (ECHCF), composition 553 all is the most activated composition.

Embodiment 39

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 39a.

Table 39a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	721H0A	K	30	S54	4.2	RH010	5.8
721I7U	K	30	S54	6.2	INT00	3.8	721H0A	K	30	S54	4.2	RH010	5.8
721I7U	K	30	S54	6.2	INT00	3.8	721J7C	K	30	S56	4.4	RH010	5.6
721K3K	K	30	S56	6.2	INT00	3.8	721J7C	K	30	S56	4.4	RH010	5.6
721K3K	K	30	S56	6.2	INT00	3.8	721C2W	K	30	S54	10
721D9I	K	30	S56	10			721C2W	K	30	S54	10
721D9I	K	30	S56	10			721A7Y	K	30			RH010	10
721B8J	K	30			INT00	10	721A7Y	K	30			RH010	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 39a composition and Comparative composition 139,360 and 553.Get all replicate tests average of each processing, the result is shown in table 39b and 39c.

Table 39b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	50.8	56.7	70	75.8
360	29.2	70	85	90	139	50.8	56.7	70	75.8
360	29.2	70	85	90	553	41.7	78.3	86.7	94.7
721H0A	27.5	67.5	80.8	86.7	553	41.7	78.3	86.7	94.7
721H0A	27.5	67.5	80.8	86.7	721I7U	32.5	73.3	80	85.8
721J7C	22.5	68.3	80	85	721I7U	32.5	73.3	80	85.8
721J7C	22.5	68.3	80	85	721K3K	16.7	73.3	84.2	86.7
721C2W	50.8	75	87.5	88.3	721K3K	16.7	73.3	84.2	86.7
721C2W	50.8	75	87.5	88.3	721D9I	35.8	75	85.8	88.3
721A7Y	19.2	65	75.8	75.8	721D9I	35.8	75	85.8	88.3
721A7Y	19.2	65	75.8	75.8	721B8J	0	53.3	75.8	73.3

Table 39c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	30	48.3	64.2	62.5
360	58.3	73.3	81.7	84.2	139	30	48.3	64.2	62.5
360	58.3	73.3	81.7	84.2	553	69.2	75	80	84.2
721H0A	63.3	70.8	77.5	80	553	69.2	75	80	84.2
721H0A	63.3	70.8	77.5	80	721I7U	62.5	73.3	76.7	83.3
721J7C	63.3	73.3	78.3	78.3	721I7U	62.5	73.3	76.7	83.3
721J7C	63.3	73.3	78.3	78.3	721K3K	62.5	72.5	80	83.3
721C2W	65	75	78.3	79.2	721K3K	62.5	72.5	80	83.3
721C2W	65	75	78.3	79.2	721D9I	64.2	74.2	75.8	80
721A7Y	29.2	62.5	70	70	721D9I	64.2	74.2	75.8	80
721A7Y	29.2	62.5	70	70	721B8J	10	63.3	65.8	70

ABUTH and ECHCF result: about piemarker (ABUTH) and barnyard grass (ECHCF), composition 553 is the most activated composition in this experiment.The weeding validity that composition 721C2W and 721D9I proof and Comparative composition 360 are suitable.

Embodiment 40

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 40a.

Table 40a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	721H7S	K	30	S54	4.2	RH010	5.8
721I2I	K	30	S54	6.2	INT00	3.8	721H7S	K	30	S54	4.2	RH010	5.8
721I2I	K	30	S54	6.2	INT00	3.8	721J1P	K	30	S56	4.4	RH010	5.6
721K5X	K	30	S56	6.2	INT00	3.8	721J1P	K	30	S56	4.4	RH010	5.6
721K5X	K	30	S56	6.2	INT00	3.8	721C5R	K	30	S54	10
721D9T	K	30	S56	10			721C5R	K	30	S54	10
721D9T	K	30	S56	10			721A3R	K	30			RH010	10
721B3Q	K	30			INT00	10	721A3R	K	30			RH010	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 40a composition and Comparative composition 139,360 and 553.Get all replicate tests average of each processing, the result is shown in table 40b and 40c.

Table 40b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300ga.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300ga.e./ha	139	0	14.2	60.8	68.3
360	48.3	79.2	88.3	93.7	139	0	14.2	60.8	68.3
360	48.3	79.2	88.3	93.7	553	60.8	89.7	92.5	95.5
721P7S	26.7	66.7	79.2	84.2	553	60.8	89.7	92.5	95.5
721P7S	26.7	66.7	79.2	84.2	721Q2I	4.2	65.8	80	82.5
721H1P	19.5	70	79.2	84.2	721Q2I	4.2	65.8	80	82.5
721H1P	19.5	70	79.2	84.2	721I5X	11.7	68.3	80.8	85
721G5R	46.7	69.2	83.3	90	721I5X	11.7	68.3	80.8	85
721G5R	46.7	69.2	83.3	90	721C9T	63.3	86.7	90	94.8
721A3R	5	32.5	61.7	74.2	721C9T	63.3	86.7	90	94.8
721A3R	5	32.5	61.7	74.2	721B3Q	0	8.3	44.2	59.2

Table 40c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	31.7	31.7	35.8
360	33.3	79.2	92.5	97.3	139	0	31.7	31.7	35.8
360	33.3	79.2	92.5	97.3	553	60.8	93.3	96.7	98.7
721P7S	20	59.2	81.7	88	553	60.8	93.3	96.7	98.7
721P7S	20	59.2	81.7	88	721Q2I	39.2	70.8	82.3	90.8
721H1P	1.7	55	70	80.8	721Q2I	39.2	70.8	82.3	90.8
721H1P	1.7	55	70	80.8	721I5X	5.8	50.8	69.2	78.3
721G5R	28.3	72.5	83.2	88.3	721I5X	5.8	50.8	69.2	78.3
721G5R	28.3	72.5	83.2	88.3	721C9T	40.8	61.7	84.2	95.8
721A3R	0	41.7	59.2	69.2	721C9T	40.8	61.7	84.2	95.8
721A3R	0	41.7	59.2	69.2	721B3Q	0	10.8	30	37.5

ABUTH and ECHCF result: in the experiment to piemarker (ABUTH), composition 721C9T and composition 553 are the most activated compositions.Composition 553 is to the most activated composition of barnyard grass (ECHCF).

Embodiment 41

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 41a.

Table 41a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	721H2Q	K	30	S54	4.2	RH010	5.8
721I4R	K	30	S54	6.2	INT00	3.8	721H2Q	K	30	S54	4.2	RH010	5.8
721I4R	K	30	S54	6.2	INT00	3.8	721J7U	K	30	S56	4.4	RH010	5.6
721K9I	K	30	S56	6.2	INT00	3.8	721J7U	K	30	S56	4.4	RH010	5.6
721K9I	K	30	S56	6.2	INT00	3.8	721C8Y	K	30	S54	10
721D0P	K	30	S56	10			721C8Y	K	30	S54	10
721D0P	K	30	S56	10			721A4E	K	30			RH010	10
721B5T	K	30			INT00	10	721A4E	K	30			RH010	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 41a composition and Comparative composition 754,360,554 and 139.Get all replicate tests average of each processing, the result is shown in table 41b and 41c.

Table 41b:ABUTH control %

Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	150g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha		0	14.2	60.8	68.3
360	48.3	79.2	88.3	93.7		0	14.2	60.8	68.3
360	48.3	79.2	88.3	93.7	553	60.8	89.7	92.5	95.5
721P2Q	26.7	66.7	79.2	84.2	553	60.8	89.7	92.5	95.5
721P2Q	26.7	66.7	79.2	84.2	721Q4R	4.2	65.8	80	82.5
721H7U	19.5	70	79.2	84.2	721Q4R	4.2	65.8	80	82.5
721H7U	19.5	70	79.2	84.2	721I9I	11.7	68.3	80.8	85
721G8Y	46.7	69.2	83.3	90	721I9I	11.7	68.3	80.8	85
721G8Y	46.7	69.2	83.3	90	721C0P	63.3	86.7	90	94.8
721A4E	5	32.5	61.7	74.2	721C0P	63.3	86.7	90	94.8
721A4E	5	32.5	61.7	74.2	721B5T	0	8.3	44.2	59.2

Table 41c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	139	0	31.7	31.7	35.8
360	33.3	79.2	92.5	97.3	139	0	31.7	31.7	35.8
360	33.3	79.2	92.5	97.3	553	60.8	93.3	96.7	98.7
721P2Q	20	59.2	81.7	88	553	60.8	93.3	96.7	98.7
721P2Q	20	59.2	81.7	88	721Q4R	39.2	70.8	82.3	90.8
721H7U	1.7	55	70	80.8	721Q4R	39.2	70.8	82.3	90.8
721H7U	1.7	55	70	80.8	721I9I	5.8	50.8	69.2	78.3
721G8Y	28.3	72.5	83.2	88.3	721I9I	5.8	50.8	69.2	78.3
721G8Y	28.3	72.5	83.2	88.3	721C0P	40.8	61.7	84.2	95.8
721A4E	0	41.7	59.2	69.2	721C0P	40.8	61.7	84.2	95.8
721A4E	0	41.7	59.2	69.2	721B5T	0	10.8	30	37.5

ABUTH and ECHCF result: in the experiment to piemarker (ABUTH), composition 721C0P and composition 553 are the most activated compositions.Composition 553 is to the most activated composition of barnyard grass (ECHCF).

Embodiment 42

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 42a.

Table 42a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l	643G5J	K	540	M121	111.4	EA	23.6
652A9K	K	540	ETH12	54.0	WIT60	54.0	INT00	27.0	643G5J	K	540	M121	111.4	EA	23.6
652A9K	K	540	ETH12	54.0	WIT60	54.0	INT00	27.0	652B8S	K	540	ETH12	54.0	WIT80	54.0	INT00	27.0
651E2D	K	540	ETH12	54.0	WIT60	54.0	INT00	30.0	652B8S	K	540	ETH12	54.0	WIT80	54.0	INT00	27.0
651E2D	K	540	ETH12	54.0	WIT60	54.0	INT00	30.0	650C7S	K	540	ETH12	54.0	WIT60	54.0	AR41	32.0
651H9E	K	540	ETH12	54.0	WIT60	54.0	AR41	24.0	650C7S	K	540	ETH12	54.0	WIT60	54.0	AR41	32.0
651H9E	K	540	ETH12	54.0	WIT60	54.0	AR41	24.0	649G2S	K	540	ETH12	54.0	WIT80	54.0	AR41	27.0
360		360							649G2S	K	540	ETH12	54.0	WIT80	54.0	AR41	27.0
360		360							754		445

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 42a composition and Comparative composition 139,553,360 and 754.Get all replicate tests average of each processing, the result is shown in table 42b and 42c.

Table 42b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	643G5J	50.8	69.2	82.5	96.7
652A9K	48.3	76.7	84.2	97.7	643G5J	50.8	69.2	82.5	96.7
652A9K	48.3	76.7	84.2	97.7	652B8S	50.0	71.7	83.3	97.7
651E2D	65.8	78.3	88.3	94.2	652B8S	50.0	71.7	83.3	97.7
651E2D	65.8	78.3	88.3	94.2	650C7S	39.2	72.5	75.0	89.2
651H9E	52.5	69.2	80.8	92.8	650C7S	39.2	72.5	75.0	89.2
651H9E	52.5	69.2	80.8	92.8	649G2S	55.8	63.3	80.0	89.7
139	18.3	46.7	65.0	86.7	649G2S	55.8	63.3	80.0	89.7
139	18.3	46.7	65.0	86.7	554	5.8	38.3	47.5	71.7
360	60.8	85.0	88.8	98.8	554	5.8	38.3	47.5	71.7
360	60.8	85.0	88.8	98.8	754	55.8	79.7	91.0	96.7

Table 42c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	643G5J	96.0	99.7	99.8	99.8
652A9K	89.5	99.5	99.8	99.8	643G5J	96.0	99.7	99.8	99.8
652A9K	89.5	99.5	99.8	99.8	652B8S	87.8	96.2	97.8	100.0
651E2D	80.8	96.5	99.5	100.0	652B8S	87.8	96.2	97.8	100.0
651E2D	80.8	96.5	99.5	100.0	650C7S	84.0	99.5	96.0	100.0
651H9E	93.0	98.3	97.5	99.8	650C7S	84.0	99.5	96.0	100.0
651H9E	93.0	98.3	97.5	99.8	649G2S	92.8	95.2	98.0	100.0
139	21.7	47.5	60.0	85.5	649G2S	92.8	95.2	98.0	100.0
139	21.7	47.5	60.0	85.5	554	26.7	52.5	65.8	70.0
360	98.3	99.7	100.0	100.0	554	26.7	52.5	65.8	70.0
360	98.3	99.7	100.0	100.0	754	89.5	98.8	99.7	100.0

ABUTH and ECHCF result: composition 652A9K, 652B8S and 651E2D slightly are better than composition 650C7S, 651H9E and 649G2S to ABUTH.The performance of these compositions slightly is weaker than composition 360.

Embodiment 43

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 43a.

Table 43a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	127A3K	K	540	TPAE6	9.9
127B4S	K	540	TPAE6	9.91	127A3K	K	540	TPAE6	9.9
127B4S	K	540	TPAE6	9.91	129A8D	K	540	TPAE6	13.23
129B7W	K	540	TPAE6	13.20	129A8D	K	540	TPAE6	13.23
129B7W	K	540	TPAE6	13.20	129D2D	K	540	TED5	12.51
140A3G	K	540	TPA0E	9.97	129D2D	K	540	TED5	12.51
140A3G	K	540	TPA0E	9.97	140C5L	K	540	T23E5	9.89
560		540			140C5L	K	540	T23E5	9.89
560		540			754		445
360		360			754		445

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 43a composition and Comparative composition 560,754 and 350.Get all replicate tests average of each processing, the result is shown in table 43b and 43c.

Table 43b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	127A3K	15	55	78.3	82.5
127B4S	15	68.3	74.2	80	127A3K	15	55	78.3	82.5
127B4S	15	68.3	74.2	80	129A8D	8.3	55.8	70	82.5
129B7W	20.8	56.7	75.8	81.7	129A8D	8.3	55.8	70	82.5
129B7W	20.8	56.7	75.8	81.7	129D2D	0.8	43.3	78.3	86.7
140A3G	2.5	55	69.2	80.8	129D2D	0.8	43.3	78.3	86.7
140A3G	2.5	55	69.2	80.8	140C5L	35	69.2	82.5	82.5
560	33.3	70	80	85.8	140C5L	35	69.2	82.5	82.5
560	33.3	70	80	85.8	754	55	77.5	84.2	91.7
360	35	79.2	84.2	90	754	55	77.5	84.2	91.7

Table 43c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	127A3K	51.7	50	57.5	57.5
127B4S	43.3	50	53.3	57.5	127A3K	51.7	50	57.5	57.5
127B4S	43.3	50	53.3	57.5	129A8D	17.5	51.7	50.8	60
129B7W	39.2	51.7	59.2	48.3	129A8D	17.5	51.7	50.8	60
129B7W	39.2	51.7	59.2	48.3	129D2D	51.7	58.3	60.8	67.5
140A3G	45	51.7	57.5	59.2	129D2D	51.7	58.3	60.8	67.5
140A3G	45	51.7	57.5	59.2	140C5L	58.3	61.7	65.8	78.3
560	52.5	60	61.7	69.2	140C5L	58.3	61.7	65.8	78.3
560	52.5	60	61.7	69.2	754	60	62.5	69.2	85.8
360	57.5	68.3	80	94.7	754	60	62.5	69.2	85.8

ABUTH and ECHCF result: composition 140C5L shows the weeding validity that is similar to Comparative composition 560 to piemarker (ABUTH), proves the weeding validity that barnyard grass (ECHCF) is higher than Comparative composition 560.Composition 129D2D be to the piemarker performance the most weak one of, but barnyard grass is similar to composition 560.Surfactant is increased to 13.2% (composition 129A8D and 129B7W) from 9.9% (composition 127A3K and 127B4S) performance is had no significant effect.

Embodiment 44

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 44a.

Table 44a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	572A7S	K	475	TQ14	8.99
572B3L	K	437	TQ17	8.42	572A7S	K	475	TQ14	8.99
572B3L	K	437	TQ17	8.42	572C2J	K	434	WIT05	3.28
574A3B	K	479	WEX7	8.95	572C2J	K	434	WIT05	3.28
574A3B	K	479	WEX7	8.95	574B6C	K	479	WEX6	9.07
574C1U	K	479	WEX5	9.09	574B6C	K	479	WEX6	9.07
574C1U	K	479	WEX5	9.09	360AD	K	360	L770	100
139		570			360AD	K	360	L770	100
139		570			360		360

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 44a composition and Comparative composition 139 and 360.Get all replicate tests average of each processing, the result is shown in table 44b and 44c.

Table 44b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	572A7S	2	19	43	72
572B3L	6	31	51	79	572A7S	2	19	43	72
572B3L	6	31	51	79	572C2J	2	18	59	78
574A3B	3	13	40	60	572C2J	2	18	59	78
574A3B	3	13	40	60	574B6C	0	12	38	62
574C1U	8	38	51	73	574B6C	0	12	38	62
574C1U	8	38	51	73	360AD	85	88	90	93
139	0	9	11	39	360AD	85	88	90	93
139	0	9	11	39	360	11	68	79	86

Table 44c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	572A7S	17	36	48	56
572B3L	18	43	49	64	572A7S	17	36	48	56
572B3L	18	43	49	64	572C2J	43	60	64	71
574A3B	22	45	53	68	572C2J	43	60	64	71
574A3B	22	45	53	68	574B6C	28	44	55	63
574C1U	23	43	48	65	574B6C	28	44	55	63
574C1U	23	43	48	65	360AD	76	82	80	85
139	10	28	35	43	360AD	76	82	80	85
139	10	28	35	43	360	31	57	67	77

ABUTH and ECHCF result: about the control of barnyard grass, composition 360AD provides the weeding validity of highest level.Composition 572A7S, 572B3L, 572C2J, 574A3B, 574B6C, 574C1U and 360 proofs are weaker than the piemarker control action of composition 360AD.

Embodiment 45

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 45a.

Table 45a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	612A1S	K	30	S01	10.0
612B8I	K	30	S02	10.0	612A1S	K	30	S01	10.0
612B8I	K	30	S02	10.0	612C7Y	K	30	S03	10.0
612D4P	K	30	S04	10.0	612C7Y	K	30	S03	10.0
612D4P	K	30	S04	10.0	612E3X	K	30	S05	10.0
612F0P	K	30	S06	10.0	612E3X	K	30	S05	10.0
612F0P	K	30	S06	10.0	612G5G	K	30	S07	10.0
612H5T	K	30	S08	10.0	612G5G	K	30	S07	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 45a composition and Comparative composition 554,754 and 553.Get all replicate tests average of each processing, the result is shown in table 45b and 45c.

Table 45b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha	554	0.0	0.0	10.0	30.8
754	0.0	67.5	85.0	89.2	554	0.0	0.0	10.0	30.8
754	0.0	67.5	85.0	89.2	553	25.8	85.0	90.0	92.5
612A1S	74.2	88.3	90.0	90.8	553	25.8	85.0	90.0	92.5
612A1S	74.2	88.3	90.0	90.8	612B8I	0.0	26.7	81.7	84.2
612C7Y	8.3	76.7	86.7	90.0	612B8I	0.0	26.7	81.7	84.2
612C7Y	8.3	76.7	86.7	90.0	612D4P	27.5	80.0	88.3	90.8
612E3X	16.7	63.3	85.8	87.5	612D4P	27.5	80.0	88.3	90.8
612E3X	16.7	63.3	85.8	87.5	612F0P	17.5	81.7	88.3	89.2
612G5G	65.0	85.0	91.7	90.8	612F0P	17.5	81.7	88.3	89.2
612G5G	65.0	85.0	91.7	90.8	612H5T	0.0	5.8	61.7	54.2

Table 45c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha	554	0.0	1.7	13.3	24.2
754	0.0	57.5	69.2	72.5	554	0.0	1.7	13.3	24.2
754	0.0	57.5	69.2	72.5	553	25.8	70.8	76.7	88.8
612A1S	52.5	70.0	70.0	76.7	553	25.8	70.8	76.7	88.8
612A1S	52.5	70.0	70.0	76.7	612B8I	21.7	65.0	69.2	71.7
612C7Y	34.2	70.8	71.7	72.5	612B8I	21.7	65.0	69.2	71.7
612C7Y	34.2	70.8	71.7	72.5	612D4P	22.5	66.7	70.8	70.8
612E3X	13.3	67.5	69.2	73.3	612D4P	22.5	66.7	70.8	70.8
612E3X	13.3	67.5	69.2	73.3	612F0P	28.3	69.2	70.0	70.8
612G5G	15.0	66.7	70.0	70.8	612F0P	28.3	69.2	70.0	70.8
612G5G	15.0	66.7	70.0	70.8	612H5T	0.0	8.3	5.0	35.0

ABUTH and ECHCF result: to the most activated preparation of piemarker is 612A1S.To the most activated preparation of barnyard grass is 553.

Embodiment 46

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 46a.

Table 46a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	607A3G	K	30	S09	10.0
607B7I	K	30	S10	10.0	607A3G	K	30	S09	10.0
607B7I	K	30	S10	10.0	607C4J	K	30	S11	10.0
607D4R	K	30	S12	10.0	607C4J	K	30	S11	10.0
607D4R	K	30	S12	10.0	607E5H	K	30	S13	10.0
607F6P	K	4.3	S14	1.4	607E5H	K	30	S13	10.0
607F6P	K	4.3	S14	1.4	607G7O	K	30	S15	10.0

Plantation piemarker (ABUTH) and barnyard grass (ECHCF) are handled according to above-mentioned standard method.Use table 46a composition and Comparative composition 554,754 and 553.Get all replicate tests average of each processing, the result is shown in table 46b and 46c.

Table 46b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha	554	0.0	0.0	0.0	12.5
754	0.0	32.5	80.8	84.2	554	0.0	0.0	0.0	12.5
754	0.0	32.5	80.8	84.2	553	0.0	74.2	89.2	93.3
607A3G	0.0	0.0	30.8	64.2	553	0.0	74.2	89.2	93.3
607A3G	0.0	0.0	30.8	64.2	607B7I	64.2	81.7	89.2	90.0
607E5H	24.2	22.5	56.7	70.0	607B7I	64.2	81.7	89.2	90.0
607E5H	24.2	22.5	56.7	70.0	607F6P	10.0	1.7	30.8	40.8
607G7O	44.2	30.0	62.5	78.3	607F6P	10.0	1.7	30.8	40.8

Table 46c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225a.e./ha	300g a.e./ha	554	0.0	0.0	15.0	27.5
754	0.0	28.3	70.0	72.5	554	0.0	0.0	15.0	27.5
754	0.0	28.3	70.0	72.5	553	1.7	66.7	80.0	83.3
607A3G	0.0	10.8	55.0	67.5	553	1.7	66.7	80.0	83.3
607A3G	0.0	10.8	55.0	67.5	607B7I	5.0	67.5	73.3	74.2
607E5H	8.3	61.7	70.8	74.2	607B7I	5.0	67.5	73.3	74.2
607E5H	8.3	61.7	70.8	74.2	607F6P	0.0	0.0	29.2	54.2
607G7O	0.0	65.0	72.5	73.3	607F6P	0.0	0.0	29.2	54.2

ABUTH and ECHCF result: composition 607B7I is the most activated to piemarker, and composition 607A3G is more effective than 607F6P to piemarker and barnyard grass.

Embodiment 47

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 47a.

Table 47a

Comp.	Salt	g/l	Component 1	g/l
Comp.	Salt	g/l	Component 1	g/l	487A7S	K	30	S53	10.0
487B2I	K	30	S54	10.0	487A7S	K	30	S53	10.0
487B2I	K	30	S54	10.0	487C1P	K	30	501	10.0
487D5X	K	30	555	10.0	487C1P	K	30	501	10.0
487D5X	K	30	555	10.0	487E5R	K	30	556	10.0
487F9T	K	30	557	10.0	487E5R	K	30	556	10.0
487F9T	K	30	557	10.0	487G3R	K	30	1816E	10.0
496A3Q	K	30	ETH25	10.0	487G3R	K	30	1816E	10.0

Plantation piemarker (ABUTH) and barnyard grass (ECHCF) are handled according to above-mentioned standard method.Use table 47a composition and Comparative composition 139,360 and 553.Get all replicate tests average of each processing, the result is shown in table 47b and 47c.

Table 47b:ABUTH control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	0.0	22.5	80.8	91.7
360	51.7	88.3	95.0	99.5	139	0.0	22.5	80.8	91.7
360	51.7	88.3	95.0	99.5	553	71.7	93.3	96.8	98.7
487A7S	42.5	70.0	91.7	97.3	553	71.7	93.3	96.8	98.7
487A7S	42.5	70.0	91.7	97.3	487B2I	80.0	94.2	96.3	97.8
487C1P	87.5	92.5	97.8	98.7	487B2I	80.0	94.2	96.3	97.8
487C1P	87.5	92.5	97.8	98.7	487D5X	80.0	90.8	96.2	98.0
487E5R	84.2	90.0	97.5	98.3	487D5X	80.0	90.8	96.2	98.0
487E5R	84.2	90.0	97.5	98.3	487F9T	85.0	90.0	96.7	99.7
487G3R	84.2	94.2	97.7	99.3	487F9T	85.0	90.0	96.7	99.7
487G3R	84.2	94.2	97.7	99.3	496A3Q	61.7	90.8	96.7	99.5

Table 47c:ECHCF control %

Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	50g a.e./ha	100g a.e./ha	200g a.e./ha	400g a.e./ha	139	0.0	56.7	68.3	88.3
360	64.2	89.2	98.3	100.0	139	0.0	56.7	68.3	88.3
360	64.2	89.2	98.3	100.0	553	75.0	88.3	99.3	100.0
487A7S	68.3	86.7	100.0	100.0	553	75.0	88.3	99.3	100.0
487A7S	68.3	86.7	100.0	100.0	487B2I	67.5	84.2	97.5	100.0
487C1P	67.5	81.7	100.0	100.0	487B2I	67.5	84.2	97.5	100.0
487C1P	67.5	81.7	100.0	100.0	487D5X	67.5	87.5	98.3	100.0
487E5R	67.5	82.5	98.2	100.0	487D5X	67.5	87.5	98.3	100.0
487E5R	67.5	82.5	98.2	100.0	487F9T	72.5	91.7	97.5	100.0
487G3R	63.3	85.0	99.7	100.0	487F9T	72.5	91.7	97.5	100.0
487G3R	63.3	85.0	99.7	100.0	496A3Q	67.5	94.2	97.5	100.0

ABUTH and ECHCF result: all compositions except that 487A7S all are better than the activity of Comparative composition 360,553 and 139 to piemarker (ABUTH) performance.

Embodiment 48

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 48a.

Table 48a

Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l
Comp.	Salt	g/l	Component 1	g/l	Component 2	g/l	Component 3	g/l	031F3Z	K	485	Gen2	9.0	Eth12	7.0
031K6N	K	485	Gen2	5.0	Eth12	6.0	Gen4	3.0	031F3Z	K	485	Gen2	9.0	Eth12	7.0
031K6N	K	485	Gen2	5.0	Eth12	6.0	Gen4	3.0	031M5B	K	485	Gen2	5.0	Eth12	6.0	Gen3	3.0
031N3D	K	485	Gen2	10.0	Eth12	7.0			031M5B	K	485	Gen2	5.0	Eth12	6.0	Gen3	3.0
031N3D	K	485	Gen2	10.0	Eth12	7.0			031S0L	K	485	Gen2	4.0	Eth12	6.0	Gen4	2.0
265	K	391	S58	10.0					031S0L	K	485	Gen2	4.0	Eth12	6.0	Gen4	2.0
265	K	391	S58	10.0					769	K	490	S59	7.5	Eth12	6.5
754	IPA	445							769	K	490	S59	7.5	Eth12	6.5

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 48a composition and Comparative composition 139,554 and 754.Get all replicate tests average of each processing, the result is shown in table 48b and 48c.

Table 48b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	400g a.e./ha	554	0.0	0.0	16.7	70.0
139	0.0	15.0	30.0	77.5	554	0.0	0.0	16.7	70.0
139	0.0	15.0	30.0	77.5	754	13.3	78.3	80.0	92.2
031F3Z	8.3	69.2	75.0	85.0	754	13.3	78.3	80.0	92.2
031F3Z	8.3	69.2	75.0	85.0	031K6N	4.2	64.2	75.0	85.0
031M5B	29.2	65.0	73.3	85.0	031K6N	4.2	64.2	75.0	85.0
031M5B	29.2	65.0	73.3	85.0	031N3D	12.5	67.5	75.0	85.0
031S0L	16.7	51.7	74.2	84.2	031N3D	12.5	67.5	75.0	85.0
031S0L	16.7	51.7	74.2	84.2	265	36.7	76.7	80.0	90.8
769	50.8	74.2	75.0	85.8	265	36.7	76.7	80.0	90.8

Table 48c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	400g a.e./ha	554	0.0	3.3	11.7	46.7
139	0.8	19.2	15.0	35.8	554	0.0	3.3	11.7	46.7
139	0.8	19.2	15.0	35.8	754	7.5	50.8	55.0	75.0
031F3Z	25.0	54.2	57.5	73.3	754	7.5	50.8	55.0	75.0
031F3Z	25.0	54.2	57.5	73.3	031K6N	33.3	52.5	55.8	67.5
031M5B	24.2	50.8	55.8	73.3	031K6N	33.3	52.5	55.8	67.5
031M5B	24.2	50.8	55.8	73.3	031N3D	31.7	55.0	60.8	82.5
031S0L	33.3	55.0	55.8	72.5	031N3D	31.7	55.0	60.8	82.5
031S0L	33.3	55.0	55.8	72.5	265	35.0	55.0	57.5	74.2
769	36.7	54.2	57.5	76.7	265	35.0	55.0	57.5	74.2

ABUTH and ECHCF result: composition 265 and 769 pairs of piemarkers (ABUTH) and barnyard grass (ECHCF) performance are similar to the activity of weeding of composition 754.

Embodiment 49

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 49a.

Table 49a

Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l
Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l	015A6D	K	391	S85	131
024A5Q	K	485	S86	131	ETH12	65			015A6D	K	391	S85	131
024A5Q	K	485	S86	131	ETH12	65			024B2L	K	485	S87	91	ETH12	91
024C3M	K	485	S87	65	ETH12	65	S86	65	024B2L	K	485	S87	91	ETH12	91
024C3M	K	485	S87	65	ETH12	65	S86	65	024D1X	K	485	S87	78	ETH12	52	S86	65
024E0P	K	485	S87	91	ETH12	91	Oxalic Acid	13	024D1X	K	485	S87	78	ETH12	52	S86	65

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 49a composition and Comparative composition 139,554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 49b and 49c.

Table 49b:ABUTH control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	015A6D	55	80	86.7	89.2
024A5Q	15.8	76.7	83.3	84.2	015A6D	55	80	86.7	89.2
024A5Q	15.8	76.7	83.3	84.2	024B2L	40	80.7	86.7	88.3
024C3M	0	0	1.7	1.7	024B2L	40	80.7	86.7	88.3
024C3M	0	0	1.7	1.7	024D1X	29.2	80.8	82.5	90
024E0P	75	82.5	91.7	92.5	024D1X	29.2	80.8	82.5	90
024E0P	75	82.5	91.7	92.5	139	0	15	73.3	75.8
554	0.8	20	71.7	80.8	139	0	15	73.3	75.8
554	0.8	20	71.7	80.8	754	45.8	80.8	87.5	90
360	33.3	81.7	87.5	90.8	754	45.8	80.8	87.5	90

Table 49c:ECHCF control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	015A6D	48.3	54.2	59.2	68.3
024A5Q	35	51.7	65	72.5	015A6D	48.3	54.2	59.2	68.3
024A5Q	35	51.7	65	72.5	024B2L	46.7	53.3	62.5	69.2
024C3M	0	0	1.7	1.7	024B2L	46.7	53.3	62.5	69.2
024C3M	0	0	1.7	1.7	024D1X	38.3	55.8	70	77.5
024E0P	50	55	75.8	79.2	024D1X	38.3	55.8	70	77.5
024E0P	50	55	75.8	79.2	139	0	15	73.3	75.8
554	0.8	20	71.7	80.8	139	0	15	73.3	75.8
554	0.8	20	71.7	80.8	754	45.8	80.8	87.5	90
360	33.3	81.7	87.5	90.8	754	45.8	80.8	87.5	90

ABUTH and ECHCF result: composition 024E0P shows the weeding validity that is better than all Comparative composition to ABUTH.Composition 024D1X performance is better than the weeding validity of Comparative composition 139 and 554.Composition 015A6D, 024A5Q and 024B2L proof are better than the weeding validity of Comparative composition 139 and 554.

Embodiment 50

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 50a.

Table 50a

Composition	Salt	g ae/l	Comp.1	g ae/l	Comp.2	g ae/l
Composition	Salt	g ae/l	Comp.1	g ae/l	Comp.2	g ae/l	015B2A	K	391	S85	126
019A7I	K	501	S86	1156	ETH12	65	015B2A	K	391	S85	126
019A7I	K	501	S86	1156	ETH12	65	019B2U	K	481	S85	130	ETH12	65
019C9O	K	481	S87	11004	ETH12	91	019B2U	K	481	S85	130	ETH12	65
019C9O	K	481	S87	11004	ETH12	91	019D1Y	K	497	S87	91	ETH12	91
139		570					019D1Y	K	497	S87	91	ETH12	91
139		570					554		725
360		360					554		725
360		360					754		445

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 50a composition and Comparative composition 139,554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 50b and 50c.

Table 50b:ABUTH control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	015B2A	63.3	80.8	88.3	91.7
019A7I	49.2	80.8	88.3	89.2	015B2A	63.3	80.8	88.3	91.7
019A7I	49.2	80.8	88.3	89.2	019B2U	48.3	80.8	85	85.8
019C9O	61.7	82.5	87.5	92.5	019B2U	48.3	80.8	85	85.8
019C9O	61.7	82.5	87.5	92.5	019D1Y	61.7	80.8	87.5	90.8
139	0	7.5	61.7	75.8	019D1Y	61.7	80.8	87.5	90.8
139	0	7.5	61.7	75.8	554	0	18.3	74.2	79.2
754	61.7	82.5	87.5	88.3	554	0	18.3	74.2	79.2
754	61.7	82.5	87.5	88.3	360	60	82.5	87.5	94.2

Table 50c:ECHCF control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	015B2A	30	55.8	79.2	81.7
019A7I	15.8	55	72.5	87.5	015B2A	30	55.8	79.2	81.7
019A7I	15.8	55	72.5	87.5	019B2U	15.8	55.8	70.8	75
019C9O	37.5	60.8	73.8	86.7	019B2U	15.8	55.8	70.8	75
019C9O	37.5	60.8	73.8	86.7	019D1Y	31.7	58.3	71.7	75.8
139	0.8	6.7	35	52.5	019D1Y	31.7	58.3	71.7	75.8
139	0.8	6.7	35	52.5	554	0.8	28.3	48.3	55.8
754	6.7	55.8	69.2	70	554	0.8	28.3	48.3	55.8
754	6.7	55.8	69.2	70	360	10.8	55.8	76.7	80

ABUTH and ECHCF result: all compositions all show the weeding validity that is better than composition 139 and 554.

Embodiment 51

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 51a.

Table 51a

Comp.	Salt	g ae/l	Comp. 1	w/w	Comp. 2	w/w	Comp. 3	w/w
Comp.	Salt	g ae/l	Comp. 1	w/w	Comp. 2	w/w	Comp. 3	w/w	265C1	K	391	S85	10％
765T5	K	473	ARO66	4％	VAR05	9.0％	ARMC	1.0％	265C1	K	391	S85	10％
765T5	K	473	ARO66	4％	VAR05	9.0％	ARMC	1.0％	677I9	K	480	WIT80	48g/l	ETH12	48g/l	INT00	24 g/l
769R5	K	490	S87	7.5％	ETH12	6.5％			677I9	K	480	WIT80	48g/l	ETH12	48g/l	INT00	24 g/l
769R5	K	490	S87	7.5％	ETH12	6.5％			767A2	K	510	1816E	5.0％	ARQ3 7	1.5％
560W3	K	540	M121	9.9％					767A2	K	510	1816E	5.0％	ARQ3 7	1.5％
560W3	K	540	M121	9.9％					563P5	K	540	ETH12	60.8 g/l

Composition 677I9 and 563P5 contain 102g/l ethylene glycol in addition.

At Fredericksburg, Texas sprays table 51a composition and Comparative composition 754, is sprayed on the high henbit of 2-3 inch (LAMAM), and this is a kind of common therophytes in winter, uses ROUNDUP usually Handle.Get all replicate tests average of each processing, the result is shown in table 51b.

Table 51b

Comp.	315g/ha	420g/ha	526g/ha	631g/ha	736g/ha
Comp.	315g/ha	420g/ha	526g/ha	631g/ha	736g/ha	265C1	62.3	59	65.3	69.8	73
765T5	58.5	64.8	69.8	74	76.8	265C1	62.3	59	65.3	69.8	73
765T5	58.5	64.8	69.8	74	76.8	677I9	61.3	59.3	69	74.8	76.8
769R5	55.3	67.3	70.3	77	76	677I9	61.3	59.3	69	74.8	76.8
769R5	55.3	67.3	70.3	77	76	767A2	57.3	57.3	65.8	71	73
560C6	60	62	72.3	73.8	82	767A2	57.3	57.3	65.8	71	73
560C6	60	62	72.3	73.8	82	563W3	60.8	61	65.3	68.5	75.8
754P5	54.5	62.8	66.3	67	72.8	563W3	60.8	61	65.3	68.5	75.8

Embodiment 52

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 52a.

Table 52a

Comp.	Salt	g/l	Comp. 1	g/l	Comp. 2	g/l	Comp. 3	g/l	Comp 4	g/l
Comp.	Salt	g/l	Comp. 1	g/l	Comp. 2	g/l	Comp. 3	g/l	Comp 4	g/l	560	K	540	M121	13 5
968D1I	K	480	ETH1 2	48	WIT80	48	INT00	24	No13	7	560	K	540	M121	13 5
968D1I	K	480	ETH1 2	48	WIT80	48	INT00	24	No13	7	959C2J	K	480	ETH1 2	48	WIT80	48	INT00	24
959D4E	K	480	ETH1 2	48	WIT05	48	INT00	24	glycol	33	959C2J	K	480	ETH1 2	48	WIT80	48	INT00	24
959D4E	K	480	ETH1 2	48	WIT05	48	INT00	24	glycol	33	478E2U	K	480	ETH1 2	48	WIT05	48	INT00	24	glycol	12 0
960G9Z	K	540	ETH1 2	61	WIT05	74					478E2U	K	480	ETH1 2	48	WIT05	48	INT00	24	glycol	12 0
960G9Z	K	540	ETH1 2	61	WIT05	74					960H3C	K	540	ETH1 2	61	WIT05	74			glycol	34
478F6K	K	540	ETH1 2	61	WIT05	74			glycol	10 2	960H3C	K	540	ETH1 2	61	WIT05	74			glycol	34
478F6K	K	540	ETH1 2	61	WIT05	74			glycol	10 2	960I4X	K	540	ETH1 2	68	WIT05	68
960J8J	K	540	ETH1 2	68	WIT05	68			glycol	34	960I4X	K	540	ETH1 2	68	WIT05	68
960J8J	K	540	ETH1 2	68	WIT05	68			glycol	34	693N0L	K	540	ETH1 2	68	WIT05	68			glycol	10 2
164B1H	K	540	SUR5 0	10 0	Citric Acid	4					693N0L	K	540	ETH1 2	68	WIT05	68			glycol	10 2
164B1H	K	540	SUR5 0	10 0	Citric Acid	4					187A7Y	K	484	SUR5 0	91	Citric Acid	3
360	IP A	360									187A7Y	K	484	SUR5 0	91	Citric Acid	3
360	IP A	360									754	IP A	445	WIT05	5. 9	INT00	2

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 52a composition and Comparative composition 554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 52b and 52c.

Table 52b:ABUTH control %

Comp.	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Comp.	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	968D1I	33.3	76.7	86.7	90
959C2J	55	81.7	88.3	90	968D1I	33.3	76.7	86.7	90
959C2J	55	81.7	88.3	90	959D4E	61.7	80	88.3	90
478E2U	43.3	80	90	90	959D4E	61.7	80	88.3	90
478E2U	43.3	80	90	90	960G9Z	36.7	83.3	88.3	90
960H3C	46.7	80	90	93.3	960G9Z	36.7	83.3	88.3	90
960H3C	46.7	80	90	93.3	478F6K	36.7	80	90	95
960I4X	65	80	90	91.7	478F6K	36.7	80	90	95
960I4X	65	80	90	91.7	960J8J	28.3	83.3	85	90
693N0L	5	76.7	85	90	960J8J	28.3	83.3	85	90
693N0L	5	76.7	85	90	164B1H	26.7	78.3	86.7	93.3
187A7Y	16.7	75	90	93	164B1H	26.7	78.3	86.7	93.3
187A7Y	16.7	75	90	93	360	50	85	88.3	91.7
754	75	88.3	91.7	96	360	50	85	88.3	91.7
754	75	88.3	91.7	96	560	50	85	88.3	91.7

Table 52c:ECHCF control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	968D1I	30	56.7	75	78.3
959C2J	48.3	61.7	68.3	75	968D1I	30	56.7	75	78.3
959C2J	48.3	61.7	68.3	75	959D4E	16.7	63.3	70	73.3
478E2U	30	60	78.3	81.7	959D4E	16.7	63.3	70	73.3
478E2U	30	60	78.3	81.7	960G9Z	48.3	63.3	85	90
960H3C	45	70	85	85	960G9Z	48.3	63.3	85	90
960H3C	45	70	85	85	478F6K	20	65	73.3	81.7
960I4X	40	75	76.7	97	478F6K	20	65	73.3	81.7
960I4X	40	75	76.7	97	960J8J	50	66.7	80	91
693N0L	46.7	66.7	85.0	85.0	960J8J	50	66.7	80	91
693N0L	46.7	66.7	85.0	85.0	164B1H	13.3	58.3	71.7	83.3
187A7Y	43.3	66.7	78.3	90	164B1H	13.3	58.3	71.7	83.3
187A7Y	43.3	66.7	78.3	90	360	53.3	81.7	91	97
754	43.3	75	95	97.7	360	53.3	81.7	91	97
754	43.3	75	95	97.7	560	41.7	65	71.7	89.3

360 and 754 standards are better than preparation in this test.The adding of two pure and mild citric acids is very little to the influence of effect.

Embodiment 53

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 53a.

Table 53a

Comp.	Salt	g a.e./l	Comp.1	g/l	Comp.2	g/l
Comp.	Salt	g a.e./l	Comp.1	g/l	Comp.2	g/l	354A4E	K	460	MT13	0.8	ETH15	0.5
354B5Y	K	460	MT13	0.9	ETH12	0.4	354A4E	K	460	MT13	0.8	ETH15	0.5
354B5Y	K	460	MT13	0.9	ETH12	0.4	354C2W	K	460	MT13	1	ETH12	0.3
354D4E	K	480	MT13	1	ETH12	0.3	354C2W	K	460	MT13	1	ETH12	0.3
354D4E	K	480	MT13	1	ETH12	0.3	354E9O	K	480	MT13	0.8	ETH12	0.4
354F4R	K	480	MT13	0.7	ETH12	0.2	354E9O	K	480	MT13	0.8	ETH12	0.4

Plantation piemarker (ABUTH) is handled according to above-mentioned standard method.Use table 53a composition and Comparative composition 139,554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 53b.

Table 53b:ABUTH control %

Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha
Composition	100g a.e./ha	200g a.e./ha	300g a.e./ha	400g a.e./ha	354A4E	2.5	46.7	62.5	77.5
354B5Y	0.8	38.3	58.3	76.7	354A4E	2.5	46.7	62.5	77.5
354B5Y	0.8	38.3	58.3	76.7	354C2W	2.5	45	69.2	80
354D4E	0.8	50	60	75	354C2W	2.5	45	69.2	80
354D4E	0.8	50	60	75	354E9O	2.5	34.2	57.5	70.8
354F4R	1.7	31.7	55	67.5	354E9O	2.5	34.2	57.5	70.8
354F4R	1.7	31.7	55	67.5	554	7.5	8.3	12.5	38.3
139	5.8	2.5	12.5	33.3	554	7.5	8.3	12.5	38.3
139	5.8	2.5	12.5	33.3	754	1.7	47.5	61.7	81.7
360	2.5	47.5	68.3	85	754	1.7	47.5	61.7	81.7

There are four kinds in six kinds of preparations and on effect, are similar to 754 and 360 standards.All the other the two kinds effects to piemarker only slightly are weaker than standard.

Embodiment 54

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 54a.

Table 54a

Comp.	Salt	g a.e./l	Comp.1	g/l
Comp.	Salt	g a.e./l	Comp.1	g/l	131A	IPA	570	M818	0.5
131B	IPA	570	M818	1	131A	IPA	570	M818	0.5
131B	IPA	570	M818	1	131C	IPA	570	M818	2
131D	IPA	570	M818	5	131C	IPA	570	M818	2
131D	IPA	570	M818	5	131E	IPA	570	M818	10
131F	IPA	570	M818	50	131E	IPA	570	M818	10
131F	IPA	570	M818	50	554A	K	725	M818	0.5
554B	K	725	M818	1	554A	K	725	M818	0.5
554B	K	725	M818	1	554C	K	725	M818	2
554D	K	725	M818	5	554C	K	725	M818	2
554D	K	725	M818	5	554E	K	725	M818	10
554F	K	725	M818	50	554E	K	725	M818	10

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 54a composition and Comparative composition 139 and 554.Get all replicate tests average of each processing, the result is shown in table 54b and 54c.

Table 54b:ABUTH control %

Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha
Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	131A	51.7	69.2	79.2
131B	62.5	75	83.3	131A	51.7	69.2	79.2
131B	62.5	75	83.3	131C	50	62.5	79.2
131D	57.5	75.8	79.2	131C	50	62.5	79.2
131D	57.5	75.8	79.2	131E	56.7	77.5	79.2
131F	23.3	30	31.7	131E	56.7	77.5	79.2
131F	23.3	30	31.7	554A	45	59.2	75.8
554B	45.8	63.3	72.5	554A	45	59.2	75.8
554B	45.8	63.3	72.5	554C	56.7	64.2	75
554D	45.8	73.3	77.5	554C	56.7	64.2	75
554D	45.8	73.3	77.5	554E	37.5	62.5	77.5
554F	4.2	9.2	10.0	554E	37.5	62.5	77.5
554F	4.2	9.2	10.0	139	10.8	12.5	57.5
554	0	0	21.7	139	10.8	12.5	57.5

Table 54c:ECHCF control %

Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha
Composition	75g a.e./ha	100g a.e./ha	150g a.e./ha	131A	60	69.2	65
131B	65	68.3	84.2	131A	60	69.2	65
131B	65	68.3	84.2	131C	70.8	87	98.5
131D	70.8	90.7	89.7	131C	70.8	87	98.5
131D	70.8	90.7	89.7	131E	60.8	65	83.3
131F	30	31.7	35	131E	60.8	65	83.3
131F	30	31.7	35	554A	33.3	55	65.8
554B	40.8	42.5	63.3	554A	33.3	55	65.8
554B	40.8	42.5	63.3	554C	40	64.2	73.3
554D	33.3	56.7	70	554C	40	64.2	73.3
554D	33.3	56.7	70	554E	7.5	40.8	63.3
554F	1.7	2.5	5.8	554E	7.5	40.8	63.3
554F	1.7	2.5	5.8	139	5	7.5	31.7
554	0	5.8	31.7	139	5	7.5	31.7

Embodiment 55

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 55a.

Table 55a

Comp.	Salt	g a.e./l	Comp.1	g/l	Comp.2	g/l
Comp.	Salt	g a.e./l	Comp.1	g/l	Comp.2	g/l	434F4T	K	480	M121	90	ARQ27	30
434G7U	K	480	M121	90	ARQ27	60	434F4T	K	480	M121	90	ARQ27	30
434G7U	K	480	M121	90	ARQ27	60	434H8I	K	480	M121	90	APG69	60
434I2Q	K	480	M121	90	APG69	30	434H8I	K	480	M121	90	APG69	60
434I2Q	K	480	M121	90	APG69	30	434J7Y	K	480	M121	120	APG69	30
767E3	K	510	1816E	50	ARQ13	18.5	434J7Y	K	480	M121	120	APG69	30
767E3	K	510	1816E	50	ARQ13	18.5	754	IPA	445
360	IPA	360	WIT05	5.9			754	IPA	445
360	IPA	360	WIT05	5.9			554	K	725			INT00	2.2

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 55a composition and Comparative composition 139,554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 55b and 55c.

Table 55b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	434F4T	55	60.8	79.2	85
434G7U	45	72.5	82.5	86.7	434F4T	55	60.8	79.2	85
434G7U	45	72.5	82.5	86.7	434H8I	46.7	66.7	82.5	86.7
434I2Q	48.3	70	81.7	86.7	434H8I	46.7	66.7	82.5	86.7
434I2Q	48.3	70	81.7	86.7	434J7Y	56.7	66.7	81.7	90
767E3	69.2	80.8	85	97.7	434J7Y	56.7	66.7	81.7	90
767E3	69.2	80.8	85	97.7	754	75	80.8	84.2	95
360	72.5	80	85	94.2	754	75	80.8	84.2	95
360	72.5	80	85	94.2	554	33.3	41.7	68.3	77.5
139	37.5	50.8	75	81.7	554	33.3	41.7	68.3	77.5

Table 55c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	434F4T	68.3	82.5	87.5	92.7
434G7U	67.5	86.7	89.8	96.2	434F4T	68.3	82.5	87.5	92.7
434G7U	67.5	86.7	89.8	96.2	434H8I	67.5	82.5	90.5	95.8
434I2Q	66.7	85.8	92.8	99.2	434H8I	67.5	82.5	90.5	95.8
434I2Q	66.7	85.8	92.8	99.2	434J7Y	75	79.2	95.5	98.5
767E3	67.5	79.2	83.3	86.3	434J7Y	75	79.2	95.5	98.5
767E3	67.5	79.2	83.3	86.3	754	73.3	81.7	90	97.2
360	71.7	87.8	94.8	96.8	754	73.3	81.7	90	97.2
360	71.7	87.8	94.8	96.8	554	30	49.2	58.3	62.5
139	31.7	55.8	63.3	65.8	554	30	49.2	58.3	62.5

About the control of piemarker, there is not the K salt pref to be better than composition 360 or composition 754.

Embodiment 56

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 56a.

Table 56a

Comp.	Salt	g a.e./l	Comp.1	g/l	Comp.2	g/l
Comp.	Salt	g a.e./l	Comp.1	g/l	Comp.2	g/l	734A2D	K	30	S16	4.5	PG069	5.5
737A5Y	K	30	S20	5.2	PG069	4.8	734A2D	K	30	S16	4.5	PG069	5.5
737A5Y	K	30	S20	5.2	PG069	4.8	737B4X	K	30	S21	5.5	PG069	4.5
734D6J	K	30			PG069	10.0	737B4X	K	30	S21	5.5	PG069	4.5
734D6J	K	30			PG069	10.0	734E1A	K	4.3	S16	1.4
737C9D	K	4.3	S20	1.4			734E1A	K	4.3	S16	1.4
737C9D	K	4.3	S20	1.4			737D6H	K	30	S21	10.0

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 56a composition and Comparative composition 139,554,754 and 360.Get all replicate tests average of each processing, the result is shown in table 56b and 56c.

Table 56b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	734A2D	0	35	57.5	70
737A5Y	1.7	20	57.5	72.5	734A2D	0	35	57.5	70
737A5Y	1.7	20	57.5	72.5	737B4X	0	36.7	65	75.8
734D6J	0	35.8	60.8	72.5	737B4X	0	36.7	65	75.8
734D6J	0	35.8	60.8	72.5	734E1A	0	45	66.7	79.2
737C9D	0	46.7	70.8	77.5	734E1A	0	45	66.7	79.2
737C9D	0	46.7	70.8	77.5	737D6H	0	46.7	75.8	77.5
554	0	0	40.8	58.3	737D6H	0	46.7	75.8	77.5
554	0	0	40.8	58.3	360	0	75.8	82.5	88.3
553	29.2	81.7	89.2	94.8	360	0	75.8	82.5	88.3

Table 56c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	734A2D	10.8	70	75	80.8
737A5Y	10	66.7	68.3	75	734A2D	10.8	70	75	80.8
737A5Y	10	66.7	68.3	75	737B4X	18.3	65	66.7	74.2
734D6J	11.7	65	70	71.7	737B4X	18.3	65	66.7	74.2
734D6J	11.7	65	70	71.7	734E1A	17.5	60	67.5	70
737C9D	0	35	52.5	71.7	734E1A	17.5	60	67.5	70
737C9D	0	35	52.5	71.7	737D6H	8.3	64.2	66.7	69.2
554	0	1.7	9.2	24.2	737D6H	8.3	64.2	66.7	69.2
554	0	1.7	9.2	24.2	360	36.7	70	83.3	84.2
553	65	75.8	87.2	90.8	360	36.7	70	83.3	84.2

All contain independent aminoglucose or with the preparation of PG069 combination the activity of piemarker and barnyard grass all are weaker than composition 360.

Embodiment 57

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 57a.

Table 57a

Comp.	Salt	％(w/w)	Comp.1	g/l	Comp.2	g/l
Comp.	Salt	％(w/w)	Comp.1	g/l	Comp.2	g/l	663B8K	K	37.2	PG069	12.8	ETH12	3.5
663C3M	K	34.2	PG069	17.4	ETH12	3.8	663B8K	K	37.2	PG069	12.8	ETH12	3.5
663C3M	K	34.2	PG069	17.4	ETH12	3.8	564A0B	K	34.2	PG069	11.9	ETH12	7.7
568B7J	K	34.2	PG069	15	ETH121	0.8	564A0B	K	34.2	PG069	11.9	ETH12	7.7
568B7J	K	34.2	PG069	15	ETH121	0.8	568C2V	K	34	PG069	14	ETH15	3.8
568A4L	K	34.2	PG069	9.6	ETH15	7.6	568C2V	K	34	PG069	14	ETH15	3.8

1. also contain 3%Eth25

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 57a composition and Comparative composition 318,765,754.Get all replicate tests average of each processing, the result is shown in table 57b and 57c.

Table 57b:ABUTH control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	663B8K	0	0	0	0
663C3M	0	0	0	0	663B8K	0	0	0	0
663C3M	0	0	0	0	564A0B	0	0	0	0
568B7J	0.8	0	0	0	564A0B	0	0	0	0
568B7J	0.8	0	0	0	568C2V	0	0	0	0
568A4L	0	0	0	0	568C2V	0	0	0	0
568A4L	0	0	0	0	754	2.5	80	86.7	89.8
765	0	70.8	80.8	85	754	2.5	80	86.7	89.8
765	0	70.8	80.8	85	318	37.5	80	90	89.2
Touchdown IQ	0	30.8	75.8	82.5	318	37.5	80	90	89.2

Table 57c:ECHCF control %

Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Composition	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	663B8K	4.2	0.8	0	2.5
663C3M	0	0.8	0	5	663B8K	4.2	0.8	0	2.5
663C3M	0	0.8	0	5	564A0B	3.3	1.7	1.7	2.5
568B7J	0	0	7.5	0.8	564A0B	3.3	1.7	1.7	2.5
568B7J	0	0	7.5	0.8	568C2V	0	0	0	0
568A4L	0	0	0	0	568C2V	0	0	0	0
568A4L	0	0	0	0	754	1.7	55	62.5	73.3
765	13.3	55	60	65	754	1.7	55	62.5	73.3
765	13.3	55	60	65	318	40.8	55	65	67.5
Touchdown IQ	10	52.5	55.8	60	318	40.8	55	65	67.5

Composition 754,765 and 318 provides than better piemarker of TouchdownIQ and barnyard grass control action.

Embodiment 58

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 58a.

Table 58a

Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp. 3	g/l
Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp. 3	g/l	676F3Z	K	480	ETH12	64	WIT80	64	INT00	32
677P9K	K	480	ETH12	48	WIT80	48	INT00	24	676F3Z	K	480	ETH12	64	WIT80	64	INT00	32
677P9K	K	480	ETH12	48	WIT80	48	INT00	24	678J3C	K	480	ETH12	30	WIT80	66	INT00	24
562A1B	K	480	ETH12	30	WIT05	90			678J3C	K	480	ETH12	30	WIT80	66	INT00	24
562A1B	K	480	ETH12	30	WIT05	90			563I9W	K	540	ETH12	61	WIT05	74
564N6L	K	540	ETH12	68	WIT05	68			563I9W	K	540	ETH12	61	WIT05	74
564N6L	K	540	ETH12	68	WIT05	68			767A2S	K	510			1816E	5	ARQ37	1.5
767B6U	K	510			1816E	5	ARQ37	1.5	767A2S	K	510			1816E	5	ARQ37	1.5
767B6U	K	510			1816E	5	ARQ37	1.5	360	IPA	360
754	IPA	445							360	IPA	360

1. also contain 3%Eth25

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 58a composition and Comparative composition 139,765,754.Get all replicate tests average of each processing, the result is shown in table 58b and 58c.

Table 58b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	676F3Z	68	80	82	88.6
677P9K	38	83	81	87	676F3Z	68	80	82	88.6
677P9K	38	83	81	87	678J3C	32	73	80	87
562A1B	22	63	84	84	678J3C	32	73	80	87
562A1B	22	63	84	84	563I9W	14	64	75	82
564N6L	16	75	82	85	563I9W	14	64	75	82
564N6L	16	75	82	85	767A2S	49	83	86	89
767B6U	70	79	83	89	767A2S	49	83	86	89
767B6U	70	79	83	89	360	73	86	90	95
754	76	84	87	92	360	73	86	90	95
754	76	84	87	92	139	4	38	65	82
554	2	20	57	77	139	4	38	65	82

Table 58c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	676F3Z	66	89.6	98.4	99.2
677P9K	65	85	94.2	99.4	676F3Z	66	89.6	98.4	99.2
677P9K	65	85	94.2	99.4	678J3C	64	78	96.4	98.8
562A1B	66	92	94.6	99.4	678J3C	64	78	96.4	98.8
562A1B	66	92	94.6	99.4	563I9W	64	89.6	96.2	97.2
564N6L	62	90	96.8	98.6	563I9W	64	89.6	96.2	97.2
564N6L	62	90	96.8	98.6	767A2S	52	71	76	87
767B6U	54	74	83	94.8	767A2S	52	71	76	87
767B6U	54	74	83	94.8	360	74	95.8	99.2	99.8
754	65	92.4	97.2	99.6	360	74	95.8	99.2	99.8
754	65	92.4	97.2	99.6	139	15	55	61	69
554	7	43	53	61	139	15	55	61	69

All sylvite preparations all are weaker than composition 360 and composition 754 to the effect of piemarker.Amine and glyphosate ester formulation are to the effect of ECHCF 360 and 754 compositions no better than.

Embodiment 59

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 59a.

Table 59a

Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l
Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l	9831X3	K	30			WIT80	6
989A2 D	K	30			WIT80	6	INT00	1.5	9831X3	K	30			WIT80	6
989A2 D	K	30			WIT80	6	INT00	1.5	9833K9	K	30	ETH12	3	WIT80	3
9834X3	K	30	ETH12	3	WIT80	3	INT00	1.5	9833K9	K	30	ETH12	3	WIT80	3
9834X3	K	30	ETH12	3	WIT80	3	INT00	1.5	989B7 U	K	30	ETH12	6			INT00	1.5
989C3 R	K	30	ETH12		WIT80	6	INT00	1.5	989B7 U	K	30	ETH12	6			INT00	1.5
989C3 R	K	30	ETH12		WIT80	6	INT00	1.5	9835E2	K	30	ETH12	3	ETH15	3	INT00	1.5
9836W 9	K	30	ETH12	3	ETH15	3	INT00	1.5	9835E2	K	30	ETH12	3	ETH15	3	INT00	1.5
9836W 9	K	30	ETH12	3	ETH15	3	INT00	1.5	987A4 G	K	480	ETH12	48	ETH15	48	INT00	24
987B3 F	K	480	ETH12	48	ETH15	48	INT00	24	987A4 G	K	480	ETH12	48	ETH15	48	INT00	24
987B3 F	K	480	ETH12	48	ETH15	48	INT00	24	360	IPA	360
754	IPA	445	WIT05	5.9	INT00	2			360	IPA	360

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 59a composition and Comparative composition 360 and 754.Get all replicate tests average of each processing, the result is shown in table 59b and 59c.

Table 59b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	9831X3	48	81	86	90
989A2D	64	82	87	89	9831X3	48	81	86	90
989A2D	64	82	87	89	9833K9	27	77	83	85
9834X3	30	77	85	85	9833K9	27	77	83	85
9834X3	30	77	85	85	989B7U	0	68	81	83
989C3R	74	81	87	90	989B7U	0	68	81	83
989C3R	74	81	87	90	9835E2	24	75	82	82
9836W9	51	69	82	82	9835E2	24	75	82	82
9836W9	51	69	82	82	987A4G	46	72	81	82
987B3F	36	54	81	81	987A4G	46	72	81	82
987B3F	36	54	81	81	360	57	83	89	91
754	54	83	88	90	360	57	83	89	91

Table 59c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	9831X3	2	55	62	71
989A2D	5	53	62	70	9831X3	2	55	62	71
989A2D	5	53	62	70	9833K9	11	54	59	66
9834X3	2	53	59	61	9833K9	11	54	59	66
9834X3	2	53	59	61	989B7U	2	41	53	60
989C3R	7	53	57	70	989B7U	2	41	53	60
989C3R	7	53	57	70	9835E2	3	44	58	63
9836W9	2	45	56	63	9835E2	3	44	58	63
9836W9	2	45	56	63	987A4G	1	44	57	62
987B3F	4	45	52	59	987A4G	1	44	57	62
987B3F	4	45	52	59	360	1	55	61	75
754	0	55	59	76	360	1	55	61	75

Embodiment 60

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 60a.

Table 60a

Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l
Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l	643G1A	K	540	M121	111	T23E2	24
652A9I	K	540	ETH12	54	WIT80	54	INT00	27	643G1A	K	540	M121	111	T23E2	24
652A9I	K	540	ETH12	54	WIT80	54	INT00	27	652B4R	K	540	ETH12	54	WIT80	54	INT00	27
651E7H	K	540	ETH12	54	WIT80	54	INT00	30	652B4R	K	540	ETH12	54	WIT80	54	INT00	27
651E7H	K	540	ETH12	54	WIT80	54	INT00	30	650C5V	K	540	ETH12	54	WIT80	54	AR41	32
651H3X	K	540	ETH12	54	WIT80	54	AR41	24	650C5V	K	540	ETH12	54	WIT80	54	AR41	32
651H3X	K	540	ETH12	54	WIT80	54	AR41	24	649G6N	K	540	ETH12	54	WIT80	54	AR41	27

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 60a composition and Comparative composition 130,360,554 and 754.Get all replicate tests average of each processing, the result is shown in table 60b and 60c.

Table 60b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	643G1A	50.8	69.2	82.5	96.7
652A9I	48.3	76.7	84.2	97.7	643G1A	50.8	69.2	82.5	96.7
652A9I	48.3	76.7	84.2	97.7	652B4R	50	71.7	83.3	97.7
651E7H	65.8	78.3	88.3	94.2	652B4R	50	71.7	83.3	97.7
651E7H	65.8	78.3	88.3	94.2	650C5V	39.2	72.5	75	89.2
651H3X	52.5	69.2	80.8	92.8	650C5V	39.2	72.5	75	89.2
651H3X	52.5	69.2	80.8	92.8	649G6N	55.8	63.3	80	89.7
139	18.3	46.7	65	86.7	649G6N	55.8	63.3	80	89.7
139	18.3	46.7	65	86.7	554	5.8	38.3	47.5	71.7
360	60.8	85	88.8	98.8	554	5.8	38.3	47.5	71.7
360	60.8	85	88.8	98.8	754	55.8	79.7	91	96.7

Table 60c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	643G1A	96	99.7	99.8	99.8
652A9I	89.5	99.5	99.8	99.8	643G1A	96	99.7	99.8	99.8
652A9I	89.5	99.5	99.8	99.8	652B4R	87.8	96.2	97.8	100
651E7H	80.8	96.5	99.5	100	652B4R	87.8	96.2	97.8	100
651E7H	80.8	96.5	99.5	100	650C5V	84	99.5	96	100
651H3X	93	98.3	97.5	99.8	650C5V	84	99.5	96	100
651H3X	93	98.3	97.5	99.8	649G6N	92.8	95.2	98	100
139	21.7	47.5	60	85.5	649G6N	92.8	95.2	98	100
139	21.7	47.5	60	85.5	554	26.7	52.5	65.8	70
360	98.3	99.7	100	100	554	26.7	52.5	65.8	70
360	98.3	99.7	100	100	754	89.5	98.8	99.7	100

Embodiment 61

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 61a.

Table 61a

Comp.	Salt	％ (W/W)	Comp.1	％ (W/W)	Comp.2	％ (W/W)
Comp.	Salt	％ (W/W)	Comp.1	％ (W/W)	Comp.2	％ (W/W)	484A3G	K	31	AE10	3.6	WIT05	8.4
484B7I	K	36.9	AE10	4.8	WIT05	7.2	484A3G	K	31	AE10	3.6	WIT05	8.4
484B7I	K	36.9	AE10	4.8	WIT05	7.2	484C4J	K	36.9	AE10	6	WIT05	6
484D4R	K	36.9	AE10	7.2	WIT05	4.8	484C4J	K	36.9	AE10	6	WIT05	6
484D4R	K	36.9	AE10	7.2	WIT05	4.8	484E5H	K	36.9	AE10	8.4	WIT05	3.6
484F6P	K	36.9	AE10	12			484E5H	K	36.9	AE10	8.4	WIT05	3.6
484F6P	K	36.9	AE10	12			484G7O	K	36.9			WIT05	12

Plantation piemarker (ABUTH) is handled according to above-mentioned standard method.Use table 61a composition and Comparative composition 553 and 554.Get all replicate tests average of each processing, the result is shown in table 61b.

Table 61b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	484A3G	39.2	75	88.3	89.2
484B7I	55.8	78.3	87.5	88.3	484A3G	39.2	75	88.3	89.2
484B7I	55.8	78.3	87.5	88.3	484C4J	35	75.8	83.3	86.7
484D4R	34.2	75	84.2	90.8	484C4J	35	75.8	83.3	86.7
484D4R	34.2	75	84.2	90.8	484E5H	29.2	70.8	83.3	90.5
484F6P	35.8	26.7	72.5	76.7	484E5H	29.2	70.8	83.3	90.5
484F6P	35.8	26.7	72.5	76.7	484G7O	64.2	80	88.3	88.3
554(725g/l)	0	0	13.3	25	484G7O	64.2	80	88.3	88.3
554(725g/l)	0	0	13.3	25	554(445g/l)	3.3	78.3	85	87.5
553(360g/l)	63.3	84.2	91.7	96	554(445g/l)	3.3	78.3	85	87.5

Embodiment 62

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 62a.

Table 62a

Comp.	Salt	％ (W/W)	Comp.1	％ (W/W)	Comp.2	％(W/W)
Comp.	Salt	％ (W/W)	Comp.1	％ (W/W)	Comp.2	％(W/W)	553	IPA	31	BRI56	6.4	ETH25	9.6
970A3 W	K	31	EXP0A	10			553	IPA	31	BRI56	6.4	ETH25	9.6
970A3 W	K	31	EXP0A	10			970B7U	K	31	EXP0B	10
970C0O	K	31	EXP0C	10			970B7U	K	31	EXP0B	10
970C0O	K	31	EXP0C	10			970D2S	K	31	EXP0A	4	EMUL	6
970E5R	K	31	EXP0B	4	EMUL	6	970D2S	K	31	EXP0A	4	EMUL	6
970E5R	K	31	EXP0B	4	EMUL	6	970F4D	K	31	EXP0C	4	EMUL	6

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 62a composition and Comparative composition 130,360,554 and 754.Get all replicate tests average of each processing, the result is shown in table 62b and 62c.

Table 62b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	970A3W	22.5	51.7	61.7	69.2
970B7U	29.2	55.8	64.2	69.2	970A3W	22.5	51.7	61.7	69.2
970B7U	29.2	55.8	64.2	69.2	970C0O	0.8	18.3	45	66.7
970D2S	12.5	50.8	54.2	68.3	970C0O	0.8	18.3	45	66.7
970D2S	12.5	50.8	54.2	68.3	970E5R	20	52.5	60.8	70.8
970F4D	20.8	47.5	63.3	68.3	970E5R	20	52.5	60.8	70.8
970F4D	20.8	47.5	63.3	68.3	554	0	13.3	45.8	55.8
360	42.5	59.2	73.3	75	554	0	13.3	45.8	55.8
360	42.5	59.2	73.3	75	139	58.3	69.2	75	80.8
754	38.3	60.8	66.7	73.3	139	58.3	69.2	75	80.8

Table 62c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	970A3W	16.7	37.5	42.5	60
970B7U	29.2	35.8	47.5	54.2	970A3W	16.7	37.5	42.5	60
970B7U	29.2	35.8	47.5	54.2	970C0O	10	36.7	41.7	52.5
970D2S	9.2	30	33.3	50	970C0O	10	36.7	41.7	52.5
970D2S	9.2	30	33.3	50	970E5R	12.5	35	40.8	51.7
970F4D	0.8	37.5	44.2	49.2	970E5R	12.5	35	40.8	51.7
970F4D	0.8	37.5	44.2	49.2	554	0	1.7	3.3	13.3
360	16.7	37.5	51.7	60.8	554	0	1.7	3.3	13.3
360	16.7	37.5	51.7	60.8	360	33.3	50.8	54.2	67.5
754	15.8	46.7	47.5	60	360	33.3	50.8	54.2	67.5

Embodiment 63

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 63a.

Table 63a

Comp.	Salt	％ (W/W)	Comp.1	％ (W/W)	Comp.2	％(W/W)
Comp.	Salt	％ (W/W)	Comp.1	％ (W/W)	Comp.2	％(W/W)	553	IPA	31	BRI56	0.4	ETH25	9.6
478A2S	K	36.9	EXP86	3.6	WIT05	8.4	553	IPA	31	BRI56	0.4	ETH25	9.6
478A2S	K	36.9	EXP86	3.6	WIT05	8.4	478B4D	K	36.9	EXP86	4.8	WIT05	7.2
478C8U	K	36.9	EXP86	6	WIT05	6	478B4D	K	36.9	EXP86	4.8	WIT05	7.2
478C8U	K	36.9	EXP86	6	WIT05	6	478D6B	K	36.9	EXP86	7.2	WIT05	4.8
478E2Z	K	36.9	EXP86	8.4	WIT05	3.6	478D6B	K	36.9	EXP86	7.2	WIT05	4.8
478E2Z	K	36.9	EXP86	8.4	WIT05	3.6	478F5J	K	36.9	EXP86	12
478G4M	K	36.9			WIT05	12	478F5J	K	36.9	EXP86	12

Plantation piemarker (ABUTH) is handled according to above-mentioned standard method.Use table 63a composition and Comparative composition 130,360,554 and 754.Get all replicate tests average of each processing, the result is shown in table 63b.

Table 63b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	553	10.8	74.2	84.2	88.3
478A2S	15.8	47.5	78.3	85	553	10.8	74.2	84.2	88.3
478A2S	15.8	47.5	78.3	85	478B4D	17.5	65	80.8	85.8
478C8U	20.8	55.8	79.2	87.5	478B4D	17.5	65	80.8	85.8
478C8U	20.8	55.8	79.2	87.5	478D6B	20.8	55.8	82.5	87.5
478E2Z	14.2	55	79.2	84.2	478D6B	20.8	55.8	82.5	87.5
478E2Z	14.2	55	79.2	84.2	478F5J	0	25.8	56.7	76.7
478G4M	3.3	36.7	59.2	82.5	478F5J	0	25.8	56.7	76.7
478G4M	3.3	36.7	59.2	82.5	554(725g/l)	0	0	0	2.5
754(445g/l)	0	19.2	65	80	554(725g/l)	0	0	0	2.5

EXP86 is similar with WIT05 on the control performance of piemarker.754 effect is weaker than independent WIT05, but is better than independent 86B.All effects of three kinds all are weaker than any mixture.

Embodiment 64

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 64a.

Table 64a

Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l
Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	Comp.3	g/l	622H7	K	480	M121	160
560P2	K	540	M121	135					622H7	K	480	M121	160
560P2	K	540	M121	135					239L8	K	480	M121	120
676Y5	K	480	ETH12	64	WIT80	64	INT00	32	239L8	K	480	M121	120
676Y5	K	480	ETH12	64	WIT80	64	INT00	32	677W2	K	480	ETH12	40	WIT80	48	INT00	24
767K9	K	510	1816E	5	ARQ37	1.5			677W2	K	480	ETH12	40	WIT80	48	INT00	24

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 64a composition and Comparative composition 130,360,554 and 754.Get all replicate tests average of each processing, the result is shown in table 64b and 64c.

Table 64b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	622H7	16.7	57.5	78.3	85
560P2	8.3	45	66.7	77.5	622H7	16.7	57.5	78.3	85
560P2	8.3	45	66.7	77.5	239L8	11.7	50	65.8	73.3
676Y5	12.5	60	71.7	76.7	239L8	11.7	50	65.8	73.3
676Y5	12.5	60	71.7	76.7	677W2	5	56.7	65	73.3
767K9	18.3	65.8	80	83.3	677W2	5	56.7	65	73.3
767K9	18.3	65.8	80	83.3	139	0	17.5	50	68.3
754	30	68.3	80	90.8	139	0	17.5	50	68.3
754	30	68.3	80	90.8	360	23.3	65	80	90
554	0	0.8	37.5	55	360	23.3	65	80	90

Table 64c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	622H7	64.2	79.2	90	92.8
560P2	65.8	73.3	84.2	85	622H7	64.2	79.2	90	92.8
560P2	65.8	73.3	84.2	85	239L8	61.7	62.5	80	84.2
676Y5	65	75	87.5	93	239L8	61.7	62.5	80	84.2
676Y5	65	75	87.5	93	677W2	63.3	68.3	88.2	88.8
767K9	61.7	66.7	67.5	74.2	677W2	63.3	68.3	88.2	88.8
767K9	61.7	66.7	67.5	74.2	139	35	45	55.8	65
754	63.3	77.5	86.7	92.5	139	35	45	55.8	65
754	63.3	77.5	86.7	92.5	360	66.7	76.7	92	93
554	20	39.2	49.2	60.8	360	66.7	76.7	92	93

There do not have the glyphosate potassium salt composite to resemble composition 754 and 360 to be effective.The surfactant ratio of two kinds of sylvite preparations all is 3: 1, approaches two kinds of standards on performance.

Embodiment 65

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 65a.

Table 65a

Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l
Comp.	Salt	g/l	Comp.1	g/l	Comp.2	g/l	656A2D	K	480	VAR05	60	WIT80	60
656B8I	K	480	VAR05	54	WIT80	66	656A2D	K	480	VAR05	60	WIT80	60
656B8I	K	480	VAR05	54	WIT80	66	656C6Y	K	480	VAR05	48	WIT80	72
271A2	K	480	VAR02	48	WIT80	48	656C6Y	K	480	VAR05	48	WIT80	72
271A2	K	480	VAR02	48	WIT80	48	270P0	K	480	VAR02	61	WIT05	74
239R4	K	480	M117	120			270P0	K	480	VAR02	61	WIT05	74
239R4	K	480	M117	120			460U7	K	480	M121	135

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 65a composition and Comparative composition 360 and 754.Get all replicate tests average of each processing, the result is shown in table 65b and 65c.

Table 65b:ABUTH control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	656A2D	22.5	78.3	85	87.5
656B8I	40.8	80	87.5	91.7	656A2D	22.5	78.3	85	87.5
656B8I	40.8	80	87.5	91.7	656C6Y	40.8	81.7	88.3	93.3
271A2	70	80	83.3	90	656C6Y	40.8	81.7	88.3	93.3
271A2	70	80	83.3	90	270P0	58.3	80.8	87.5	89.2
239R4	66.7	76.7	85.8	90.8	270P0	58.3	80.8	87.5	89.2
239R4	66.7	76.7	85.8	90.8	460U7	47.5	80	88.3	91.7
754	32.5	75	87.5	88.3	460U7	47.5	80	88.3	91.7
754	32.5	75	87.5	88.3	360	52.5	75.8	87.5	89.2
M560	24.2	74.2	87.5	91.7	360	52.5	75.8	87.5	89.2
M560	24.2	74.2	87.5	91.7	M128	35	77.5	87.5	92.5
765	36.7	80.8	87.5	93	M128	35	77.5	87.5	92.5

Table 65c:ECHCF control %

Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha
Composition	100g a.e./ha	150g a.e./ha	200g a.e./ha	300g a.e./ha	656A2D	30.8	58.3	61.7	66.7
656B8I	30	51.7	62.5	63.3	656A2D	30.8	58.3	61.7	66.7
656B8I	30	51.7	62.5	63.3	656C6Y	39.2	56.7	60	70
271A2	18.3	51.7	61.7	63.3	656C6Y	39.2	56.7	60	70
271A2	18.3	51.7	61.7	63.3	270P0	31.7	57.5	65	69.2
239R4	15.8	54.2	60	70.8	270P0	31.7	57.5	65	69.2
239R4	15.8	54.2	60	70.8	460U7	40	55.8	60.8	70.8
754	23.3	56.7	61.7	73.3	460U7	40	55.8	60.8	70.8
754	23.3	56.7	61.7	73.3	360	26.7	56.7	65.8	75
M560	20	58.3	58.3	69.2	360	26.7	56.7	65.8	75
M560	20	58.3	58.3	69.2	M128	42.5	60.8	65.8	75
765	43.3	55.8	60	73.3	M128	42.5	60.8	65.8	75

The cloud point of some fluid composition of following mensuration embodiment 66-69.Invisible spectro composition sample is heated in water-bath, until becoming muddy.From water-bath, take out test tube then, stir sample, until becoming clarification with thermometer.Temperature when the record sample becomes clarification is the cloud point for composition.

The percentage of representing in " % " in the following example is with w/w, and other has except the indication.

Embodiment 66

The surfactant that is used among the embodiment 68 is the beef tallow amine ethoxylate Witcamine TAM-60 with 6 moles of ethylene oxide, the beef tallow amine ethoxylate Witcamine TAM-105 that has the beef tallow amine ethoxylate Witcamine TAM-80 of 8 moles of ethylene oxide and have 10 moles of ethylene oxide.

Mix following component, the water-based concentrate composition of preparation embodiment 66:

(1) the glyphosate concentrated aqueous solution of potassium salt form;

(2) surfactant as defined above; With

(3) water.

Through calculating, composition contains 360 grams per liter a.e. (29.0%a.e.) glyphosates and 90 grams per liters (7.25%) surfactant.Measuring the proportion of composition under 20/15.6 ℃ is 1.25.Measure the cloud point of every kind of surface activator composition, as shown in the table.

Surfactant	Cloud point (℃)
Surfactant	Cloud point (℃)	Witcamine TAM-60	＞90
Witcamine TAM-80	＞90	Witcamine TAM-60	＞90
Witcamine TAM-80	＞90	Witcamine TAM-105	＜room temperature

Embodiment 67

The surfactant of experimental example 67 under higher glyphosate potassium LOADING RATES.

Prepare the water-based concentrate composition according to the method that is similar to embodiment 66, contain 450 grams per liter a.e. (34.6%a.e.) glyphosate potassium and 6.92% surfactants.Measuring the proportion of composition under 20/15.6 ℃ is 1.30.Measure the cloud point of every kind of surface activator composition, as shown in the table.

Surfactant	Cloud point (℃)
Surfactant	Cloud point (℃)	Witcamine TAM-60	＞90
Witcamine TAM-80	＞55	Witcamine TAM-60	＞90
Witcamine TAM-80	＞55	Witcamine TAM-105	＜room temperature

Embodiment 68

The surfactant that is used among the embodiment 68 is Ethomeen C/15 (ethoxylation coco amine (15E0)).

Prepare the water-based concentrate composition according to the method that is similar to embodiment 66, contain 606 grams per liter a.e. (29.0%a.e.) glyphosate potassium and 5.05% surfactants.Measuring the proportion of composition under 20/15.6 ℃ is 1.399.The cloud point of measuring composition is 72 ℃.

Embodiment 69

The surfactant that is used among the embodiment 69 is Huntsman Surfonic AGM-550 (M121).

Prepare the water-based concentrate composition according to the method that is similar to embodiment 68, contain 486 grams per liter a.e. (36.6%a.e.) glyphosate potassiums, 22 grams per liter a.i. (1.66%a.i.) glufosinate ammonium salt and 9.16% surfactants.Measuring the proportion of composition under 20/15.6 ℃ is 1.329.The cloud point of measuring composition is 70 ℃.

Embodiment 70

Preparation water-based concentrate composition contains just like glyphosate salt and excipient composition shown in the table 70a.

Table 70a

Comp.	Salt	g/l	Comp.1	g/l
Comp.	Salt	g/l	Comp.1	g/l	675A2L	K	30	S74	1.00
675B9W	K	30	S98	1.00	675A2L	K	30	S74	1.00
675B9W	K	30	S98	1.00	675C1H	K	4.3	S99	0.14
675D4G	K	30	S100	1.00	675C1H	K	4.3	S99	0.14
675D4G	K	30	S100	1.00	675E7Y	K	30	S101	1.00
675F2S	K	30	S102	1.00	675E7Y	K	30	S101	1.00
675F2S	K	30	S102	1.00	675G1U	K	30	S103	1.00
675H9Q	K	30	S104	1.00	675G1U	K	30	S103	1.00
675H9Q	K	30	S104	1.00	554		725
754		445			554		725
754		445			553		360

Plantation piemarker (ABUTH) and Japanese millet (ECHCF) are handled according to above-mentioned standard method.Use table 70a composition and Comparative composition 553 and 554.Get all replicate tests average of each processing, the result is shown in table 70b and 70c.

Table 70b:ABUTH control %

Comp.	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Comp.	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	675A2L	0.0	65.0	80.0	85.0
675B9W	0.0	69.2	85.0	85.0	675A2L	0.0	65.0	80.0	85.0
675B9W	0.0	69.2	85.0	85.0	675C1H	14.2	56.7	82.5	84.2
675D4G	39.2	82.5	90.0	90.8	675C1H	14.2	56.7	82.5	84.2
675D4G	39.2	82.5	90.0	90.8	675E7Y	56.7	82.5	89.2	90.8
675F2S	45.0	79.2	89.2	90.0	675E7Y	56.7	82.5	89.2	90.8
675F2S	45.0	79.2	89.2	90.0	675G1U	42.5	78.3	85.0	90.8
675H9Q	23.3	75.8	87.5	86.7	675G1U	42.5	78.3	85.0	90.8
675H9Q	23.3	75.8	87.5	86.7	554	0.0	0.0	13.3	53.3
754	17.5	80.0	88.3	92.5	554	0.0	0.0	13.3	53.3
754	17.5	80.0	88.3	92.5	553	60.0	86.7	91.7	94.2

Table 70c:ECHCF control %

Comp.	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha
Comp.	75g a.e./ha	150g a.e./ha	225g a.e./ha	300g a.e./ha	675A2L	5.8	58.3	70.8	71.7
675B9W	19.2	67.5	73.3	76.7	675A2L	5.8	58.3	70.8	71.7
675B9W	19.2	67.5	73.3	76.7	675C1H	20.8	65.8	74.2	75.8
675D4G	34.2	65.7	72.5	78.3	675C1H	20.8	65.8	74.2	75.8
675D4G	34.2	65.7	72.5	78.3	675E7Y	28.3	67.5	72.5	75.0
675F2S	33.3	65.8	73.3	75.0	675E7Y	28.3	67.5	72.5	75.0
675F2S	33.3	65.8	73.3	75.0	675G1U	6.7	55.8	67.5	72.5
675H9Q	3.3	58.3	66.7	67.5	675G1U	6.7	55.8	67.5	72.5
675H9Q	3.3	58.3	66.7	67.5	554	0.0	1.7	5.0	30.0
754	22.5	70.8	71.7	75.0	554	0.0	1.7	5.0	30.0
754	22.5	70.8	71.7	75.0	553	50.8	71.7	74.2	78.3

Claims

1, the weeding concentrate of stable storage, it can be diluted by water, the aqueous herbicidal that obtains being applied to plant leaf blade is used mixture, described concentrate comprises the potassium of glyphosate, single ammonium, two ammoniums, sodium, MEA, Dimethyl Ammonium, dimethylamine, n-propylamine, ethamine, ethylenediamine, hexamethylene diamine, sulfoxonium or trimethyl sulfonium salt, every liter of concentration at least 270 gram of glyphosate equivalent, the character of described surfactant and the composition of described concentrate are such, concentrate or described use mixture and be applied to plant after, on described plant leaf blade, form the anisotropy aggregation that comprises described surfactant.

2, the weeding concentrate of stable storage as claimed in claim 1, the character of surface active agent composition and concentration are such described in the wherein said concentrate, use to plant leaf blade described use mixture after, in the plant leaf blade cuticula, form the liquid crystal comprise described surfactant.

3, the concentrate of stable storage as claimed in claim 1, wherein the concentration of glyphosate is from about 400ga.e./L to about 600ga.e./L.

4, the concentrate of the stable storage of claim 1, wherein the viscosity of this concentrate under 0 ℃ and 45/s shearing rate is less than 1000c.p..

5, the concentrate of the stable storage of claim 1, wherein the viscosity of this concentrate under 0 ℃ and 45/s shearing rate is less than 250c.p..

6, can be used for delaying the preparation of plant growing, comprise the aqueous mixture that contains surfactant and glyphosate or its salt or ester, the character of described surfactant and the composition of described preparation are such, after said preparation is applied to plant, on plant leaf blade, form the aggregation that comprises described surfactant

Wherein said surfactant is selected from down group:

(a) have the monoalkoxy amine of following formula:

R wherein ¹It is the alkyl of hydrogen or alkyl or replacement with at least 7 carbon atoms; R ²At each (R ²O) _x(R ²O) _yBe C independently in the group ₂-C ₄Alkylidene; R ³Be to have 2 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁴And R ⁵Be hydrogen independently of one another, have 1 alkyl to the alkyl of about 30 carbon atoms or replacement ,-(R ⁶) _n-(R ²O) _yR ⁷, perhaps R ⁴And R ⁵Constitute the ring of ring-type or heterocycle with the nitrogen-atoms that they connected; R ⁶Be to contain 1 to the alkylene of about 6 carbon atoms or the alkylene of replacement; R ⁷Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; N is 0 or 1; X and y are 1 to about 60 mean independently; If its condition is R ²And R ³At each (R ²O) _xIn the group ethylidene, then R ¹Not unsubstituted alkyl, perhaps if R ⁵Be hydrogen or unsubstituted alkyl, then R ⁴Not hydrogen or unsubstituted alkyl, if R ²And R ³Be isopropylidene, x is 1, then R ¹Not unsubstituted alkyl or R ⁴Be not-(R ²O) _yR ⁷

(b) have two of following formula-many (hydroxy alkyl) amine:

R wherein ¹And R ³Be hydrogen independently or have 1 to the alkyl of about 22 carbon atoms or the alkyl of replacement; R ²Be to have 2 to the alkylene of about 18 carbon atoms or the alkylene of replacement; M and n are from 1 to about 8 integer independently; But if its condition is R ¹And R ³Be methyl, R then ²Not Ya Xinji;

(c) have the alkoxylate triamine of following formula:

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ², R ³, R ⁴And R ⁵Be hydrogen independently, have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ⁸) _s(R ⁷-O) _nR ⁶R ⁶Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁷At each (R ⁷O) _nBe C independently in the group ₂-C ₄Alkylidene; R ⁸Be to have 1 to the alkylene of about 6 carbon atoms or the alkylene of replacement; N is from 1 to about 10 mean, and s is 0 or 1; X and y are 1 to about 4 integer independently; If its condition is R ¹Be alkyl, R ²Be not hydrogen, x is 3 or 4, perhaps R ⁴Be not-(R ⁷-O) _nR ⁶

(d) have the monoalkoxy amine of following formula:

R wherein ¹Be to have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ²Be C ₂-C ₄Alkylidene; R ³Be hydrogen or have 1 straight or branched alkyl to about 4 carbon atoms; R ⁴Be to have 1 straight or branched alkynyl, aryl or aralkyl to about 30 carbon atoms; X is from 1 to about 60 mean; And

(e) following formula: compound:

Or

Or

Or

Or

Or

R wherein ¹, R ⁹And R ¹²Be independently have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(R ²O) _pR ¹³R ²At each (R ²O) _m, (R ²O) _n, (R ²O) _p(R ²O) _qBe C independently in the group ₂-C ₄Alkylidene; R ³, R ⁸, R ¹¹, R ¹³And R ¹⁵Be hydrogen independently or have 1 to the alkyl of about 30 carbon atoms or the alkyl of replacement; R ⁴Be-(CH ₂) _yOR ¹³Or-(CH ₂) _yO (R ²O) _qR ³R ⁵, R ⁶And R ⁷Be hydrogen independently, have 1 to the alkyl of about 30 carbon atoms or the alkyl or the R of replacement ⁴R ¹⁰Be to have 2 to the alkylene of about 30 carbon atoms or the alkylene of replacement; R ¹⁴Be have 1 to the alkyl of the alkyl of about 30 carbon atoms or replacement or-(CH ₂) _zO (R ²O) _pR ³M, n, p and q are from 1 to about 50 mean independently; X is-O-,-N (R ¹⁴)-,-C (O)-,-C (O) O-,-OC (O)-,-N (R ¹⁵) C (O)-,-C (O) N (R ¹⁵)-,-S-,-SO-or-SO ₂-; T is 0 or 1; A-is that agricultural goes up acceptable anion; Y and z are from 0 to about 30 integer independently.

7, the composition of claim 6, wherein glyphosate mainly is the form of its potassium, single ammonium, two ammoniums, sodium, MEA, n-propylamine, ethamine, ethylenediamine, hexamethylene diamine or trimethyl sulfonium salt.

8, the composition of claim 7, wherein glyphosate mainly is the form of sylvite.

9, the composition of claim 8, the content of wherein said glyphosate in the aqueous solution are every liter of compositions of 310 to 600 gram acid equivalents.

10, the composition of claim 9, wherein the content of glyphosate potassium in the aqueous solution is every liter of compositions of 360 to 600 gram acid equivalents.

11, the composition of claim 10, the content of wherein said glyphosate potassium in the aqueous solution are every liter of compositions of 400 to 600 gram acid equivalents.

12, the composition of claim 11, the content of wherein said glyphosate potassium in the aqueous solution are every liter of compositions of 450 to 600 gram acid equivalents.

13, the composition of claim 12, the content of wherein said glyphosate potassium in the aqueous solution are every liter of compositions of 480 to 600 gram acid equivalents.

14, the composition of claim 13, the content of wherein said glyphosate potassium in the aqueous solution are every liter of compositions of 480 to 580 gram acid equivalents.

15, the composition of claim 13, the content of wherein said glyphosate potassium in the aqueous solution are every liter of compositions of 500 to 600 gram acid equivalents.

16, the composition of claim 15, the content of wherein said glyphosate potassium in the aqueous solution are every liter of compositions of 540 to 600 gram acid equivalents.

17, any one composition of claim 9-16, wherein every liter of composition of the total amount of surfactant from 60 to 240 grams.

18, the composition of claim 17, wherein every liter of composition of the total amount of surfactant from 60 to 200 grams.

19, the composition of claim 18, wherein every liter of composition of the total amount of surfactant from 20 to 150 grams.