CN101323705A - Polynuclear silicon prion high-energy lead-acid battery - Google Patents
Polynuclear silicon prion high-energy lead-acid battery Download PDFInfo
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- CN101323705A CN101323705A CNA2008100979793A CN200810097979A CN101323705A CN 101323705 A CN101323705 A CN 101323705A CN A2008100979793 A CNA2008100979793 A CN A2008100979793A CN 200810097979 A CN200810097979 A CN 200810097979A CN 101323705 A CN101323705 A CN 101323705A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
The invention relates to the power material and equipment field, and provides a polysilane advanced lead-acid battery, in particular to a preparation method of the polysilane and the battery. On the basis of utilizing the advantages of the organic colloidal system and the inorganic colloidal system of the polysilane, the battery provided by the embodiment of the invention has the advantages of large specific heat capacity, wide temperature zone, high specific energy and high capacity, high electrode coupling and collision efficiency and rapid energy transition speed, etc.
Description
Technical field
The present invention relates to electric power material installation field, particularly a kind of polynuclear silicon prion making method and store battery.
Background technology
The exchange of energy will take place in the lead acid cell charge and discharge process on electrode, and the exchange velocity of chemical energy and electric energy is the crux factor of decision energy exchange degree on the electrode.In the energy system of lead acid cell, the electrode outside is to rely on movement of electrons to finish the energy transmission, and electrode interior is to rely on ionic to move to finish the energy transmission.Because electronics is far longer than the translational speed of ion at internal circuit in the translational speed of external circuit, therefore, electrode reaction speed often is subjected to the influence of ion in the internal circuit translational speed.At present the percentage of water loss under the low and hot conditions of loading capacity is high under low, the cold condition of the charging efficiency under the overcast and rainy condition of the energy storage lead acid cell that uses of solar-energy conversion systems.
Summary of the invention
The embodiment of the invention provides a kind of polynuclear silicon prion making method and store battery, realizes that the charge acceptance of store battery strengthens, the low temperature discharge capacity increases and the high temperature percentage of water loss reduces.
Polynuclear silicon prion making method provided by the present invention and store battery embodiment are achieved through the following technical solutions:
A kind of polynuclear silicon prion making method comprises step:
(1), the organosilicon polymer of backbone structure is made the nano level organosilicon polymer;
(2), functional acrylic polymer acid amides and described nano level organosilicon polymer are mixed and made into polymer organic polymer silicon;
(3), in the high-speed mixing still that described polymer organic polymer silicon and aquosity electrolyte sulfuric acid is solution combined, make electrolyte sulfuric acid solution become the water-in-oil-type colloidal state by aquosity, make polymer organic silicon protein;
(4), apply the energy resonance effect for the bound energy of described polymer organic silicon protein molecule, make metastable state polymer organic silicon protein;
(5), in container, sodium hydroxide solution, lithium hydroxide solution and potassium hydroxide solution are mixed, make the ternary alkaline solution;
(6), aerosil is dropped in the described container and to carry out hybrid reaction with described ternary alkaline solution and generate collision property inorganic silicon solution;
(7), will collision property inorganic silicon solution in the cylinder container made and the aquosity electrolyte sulfuric acid solution combined, make compound collision inorganic silicon protein;
(8) will collision property inorganic silicon protein and metastable state polymer organic silicon protein mixed polynuclear silicon prion parent of making in closed reactor;
(9) three kinds of Synergist S-421 95s being added the polynuclear silicon prion parent is in harmonious proportion; The good polynuclear silicon prion parent that will be in harmonious proportion again adds after additive boric acid, phosphoric acid, silicic acid, sulfuric acid mixes; Add the multifunctional modification agent again, in the high-speed mixing still, mix then, make polynuclear silicon prion.
The embodiment of the invention also provides the store battery of the above-mentioned polynuclear silicon prion solution of a kind of usefulness as electrolytic solution,
The cell body of described store battery adopts engineering plastics, and described battery separator is the beta glass fibre barrier film;
The anode plate grid of described store battery is the low calcium type Pb-Ca-Sn-Al alloy of high tin, and the negative electrode grid of described store battery is middle tin high-calcium type Pb-Ca-Sn-Al alloy;
The anode diachylon of described store battery also adds 0.5% type material antimonous oxide, and the cathode lead plaster of described store battery is joined and also added 0.15 ‰ selenium powder;
The electrolytic solution of described store battery is polynuclear silicon prion electrolytic solution.
Technique scheme has following beneficial effect: the polynuclear silicon prion that embodiment of the invention making method provides is on the basis of the advantage of organic colloidal state system of performance and inorganic colloidal state system, and the store battery that the embodiment of the invention is provided has ratio of specific heat to be held greatly, and the temperate zone is wide; The specific energy height, capacity is big; Electrode even summation collision efficiency height, energy transformation speed is fast etc.
Embodiment
Technical scheme is for a better understanding of the present invention described embodiment provided by the invention below in detail.
This polynuclear silicon prion making method comprises step:
(1), the organosilicon polymer of backbone structure is made the nano level organosilicon polymer, specifically comprise: utilize pharmaceutical equipment, the applying nano technology will (c-Si-o-) organosilicon polymer of n backbone structure be made the nano level organosilicon polymer of 5-10nm.This nano level organosilicon polymer is the ball type homopolymerization reticulated structure with high dispersion, and this reticulated structure can be for a plurality of dimensions make it to have good hydrophilicity and ratio of specific heat and hold to embedding different types of hydroxyl functional group in the space.
(2), functional acrylic polymer acid amides and described nano level organosilicon polymer are mixed and made into polymer organic polymer silicon, specifically comprise: in closed reactor with functional acrylic polymer acid amides (M 〉=3,000,000) and nano level (C-Si-O-) n organosilicon polymer mixing 20min, make polymer organic polymer silicon, and make the polycrystalline state in the mixture in the mesoscopic structure aspect, carry out energy distribution effectively by the grafting functional functional group method, and making polymkeric substance macromolecular chain side group form the various active group, this various active group comprises helping and oozes group, the low-resistance group, complexing group etc.
(3), in the high-speed mixing still that described polymer organic polymer silicon and aquosity electrolyte sulfuric acid is solution combined, make electrolyte sulfuric acid solution become the water-in-oil-type colloidal state by aquosity, make polymer organic silicon protein.
(4), apply the energy resonance effect for the bound energy of described polymer organic silicon protein molecule, make metastable state polymer organic silicon protein, specifically comprise: utilize perturbation resonance energy generation systems to apply the energy resonance effect for the bound energy of polymer organic silicon protein molecule, make the bound energy of described polymer organic silicon protein molecule be energized into metastable state, make metastable state polymer organic silicon protein by ground state.This metastable state is gathered the increased activity with thing organosilicon protein cluster, and the energy of solution increases, and by the energy resonance effect, electrolytical ion has become " order state " by " state of disarray " simultaneously, makes ionic strength increase.
(5), in container, sodium hydroxide solution, lithium hydroxide solution and potassium hydroxide solution are mixed, make the ternary alkaline solution, the concentration of described sodium hydroxide solution, lithium hydroxide solution and potassium hydroxide solution is volumetric molar concentration, in container with sodium hydroxide solution, lithium hydroxide solution and the potassium hydroxide solution of described concentration according to 1.2: 1.0: 1.0 mixed, make the ternary alkaline solution.
(6), aerosil dropped in the described container carries out hybrid reaction with described ternary alkaline solution and generate collision property inorganic silicon solution, specifically comprise: carry out hybrid reaction in molar ratio with the ternary alkaline solution in will the aerosil input cylinder container made of 1.3%-1.5% amount and generate collision property inorganic silicon solution.
(7), will collision property inorganic silicon solution in the cylinder container made and the aquosity electrolyte sulfuric acid solution combined, make compound collision inorganic silicon protein;
(8) will collision property inorganic silicon protein and metastable state polymer organic silicon protein mixed polynuclear silicon prion parent of making in closed reactor, specifically comprise: will collision property inorganic silicon protein and metastable state polymer organic silicon protein 1: 2.5 by volume mixed polynuclear silicon prion parent of making in closed reactor, wherein: the available silicon content of described polynuclear silicon prion parent is 0.29-0.3%wt, and colloidal particle size remains on the 10nm order of magnitude.
(9) three kinds of Synergist S-421 95s being added the polynuclear silicon prion parent is in harmonious proportion; The good polynuclear silicon prion parent that will be in harmonious proportion again adds after additive boric acid, phosphoric acid, silicic acid, sulfuric acid mixes; Add the multifunctional modification agent again, in the high-speed mixing still, mix then, make polynuclear silicon prion, specifically comprise: denseness control-released agent, deflocculant and function permeate agent are added the polynuclear silicon prion parent by 0.1～0.15 ‰ be in harmonious proportion; The good polynuclear silicon prion parent that will be in harmonious proportion again added 1: 2: 3 in molar ratio: after 4 boric acid that prepare, phosphoric acid, silicic acid, sulfuric acid mix; (EDTA 100-500PPM), many benzene nucleus (condensed ring) quinone benzene (to strengthen ion migration speed, reducing internal resistance) or tartaric acid controlled release, mixed system 2 hours then in the high-speed mixing still, make polynuclear silicon prion electrolytic solution to add 0.15～0.2 ‰ ethylenediamine tetraacetic acid (EDTA) again.
The embodiment of the invention also provides the store battery of a kind of polynuclear silicon prion that is made with aforesaid method as electrolytic solution, and the cell body of this store battery adopts engineering plastics, and this battery separator is the beta glass fibre barrier film;
The anode plate grid of this store battery is the low calcium type Pb-Ca-Sn-Al alloy of high tin, and the content of each composition of the low calcium type Pb-Ca-Sn-Al alloy of this high tin is: Ca is 0.06%, and Sn is 1.50%, and Al is 0.03%; The negative electrode grid of described store battery is middle tin high-calcium type Pb-Ca-Sn-Al alloy; The content of each composition of tin high-calcium type Pb-Ca-Sn-Al alloy is in being somebody's turn to do: Ca is 0.10%, and Sn is 0.80%, and Al is 0.03%.
The anode diachylon prescription of described store battery also adds 0.5% type material antimonous oxide except that normal additive, the cathode lead plaster prescription of described store battery also adds 0.15 ‰ selenium powder except that normal additive; The electrolytic solution of described store battery is polynuclear silicon prion electrolytic solution.
The making method of this store battery comprises:
(1) cell body of this store battery adopts the ABS engineering plastics, and physical dimension can be 402mm * 171mm * 217mm;
(2) dividing plate of this store battery adopts beta glass fibre (AGM) barrier film;
(3) anode plate grid of this store battery adopts high tin to hang down calcium type Pb-Ca-Sn-Al alloy;
Wherein: Ca content is 0.06%;
Sn content is 1.50%;
Al content is 0.03%.
(4) tin high-calcium type Pb-Ca-Sn-Al alloy during the negative pole of this store battery adopts;
Wherein: Ca content is 0.10%;
Sn content is 0.80%;
Al content is 0.03%.
(5) the anode diachylon prescription of this store battery adds 0.5% type material antimonous oxide except that normal additive;
(6) the cathode lead plaster prescription of this store battery adds 0.15 ‰ selenium powder except that normal additive;
(7) this store battery produces the 12V100Ah lead acid cell according to normal grid, pole plate and store battery assembling production technique;
(8) polynuclear silicon prion electrolytic solution is filled at normal temperatures in the 12V100Ah lead acid cell monomer, the amount of pouring into 15ml/Ah charges after leaving standstill 5h.
(9) by the method for charging normal store battery is charged to complete state-of-charge.
The polynuclear silicon prion that the making method of the embodiment of the invention provides is on the basis of the advantage of organic colloidal state system of performance and inorganic colloidal state system, and the store battery that the embodiment of the invention is provided has ratio of specific heat to be held greatly, and the temperate zone is wide; The specific energy height, capacity is big; Electrode even summation collision efficiency height, energy transformation speed is fast etc.
More than a kind of polynuclear silicon prion making method and store battery that the embodiment of the invention provided are described in detail, for one of ordinary skill in the art, thought according to the embodiment of the invention, part in specific embodiments and applications all can change, in sum, this description should not be construed as limitation of the present invention.
Claims (10)
1, a kind of polynuclear silicon prion making method is characterized in that, comprises step:
(1), the organosilicon polymer of backbone structure is made the nano level organosilicon polymer;
(2), functional acrylic polymer acid amides and described nano level organosilicon polymer are mixed and made into polymer organic polymer silicon;
(3), in the high-speed mixing still that described polymer organic polymer silicon and aquosity electrolyte sulfuric acid is solution combined, make electrolyte sulfuric acid solution become the water-in-oil-type colloidal state by aquosity, make polymer organic silicon protein;
(4), apply the energy resonance effect for the bound energy of described polymer organic silicon protein molecule, make metastable state polymer organic silicon protein;
(5), in container, sodium hydroxide solution, lithium hydroxide solution and potassium hydroxide solution are mixed, make the ternary alkaline solution;
(6), aerosil is dropped in the described container and to carry out hybrid reaction with described ternary alkaline solution and generate collision property inorganic silicon solution;
(7), will collision property inorganic silicon solution in the cylinder container made and the aquosity electrolyte sulfuric acid solution combined, make compound collision inorganic silicon protein;
(8) will collision property inorganic silicon protein and metastable state polymer organic silicon protein mixed polynuclear silicon prion parent of making in closed reactor;
(9) three kinds of Synergist S-421 95s being added the polynuclear silicon prion parent is in harmonious proportion; The good polynuclear silicon prion parent that will be in harmonious proportion again adds after additive boric acid, phosphoric acid, silicic acid, sulfuric acid mixes; Add the multifunctional modification agent again, in the high-speed mixing still, mix then, make polynuclear silicon prion.
2, polynuclear silicon prion making method as claimed in claim 1 is characterized in that, described step (1) specifically comprises: utilize pharmaceutical equipment, the applying nano technology is made the organosilicon polymer of backbone structure the nano level organosilicon polymer of 5-10nm.
3, polynuclear silicon prion making method as claimed in claim 1, it is characterized in that, described step (2) specifically comprises: in closed reactor with functional acrylic polymer acid amides and nano level organosilicon polymer mixing 20min, make polymer organic polymer silicon, and make the polycrystalline state in the mixture in the mesoscopic structure aspect, carry out energy distribution effectively by the grafting functional functional group method, make polymkeric substance macromolecular chain side group form the various active group.
4, polynuclear silicon prion making method as claimed in claim 1, it is characterized in that, described step (4) specifically comprises: utilize perturbation resonance energy generation systems to apply the energy resonance effect for the bound energy of polymer organic silicon protein molecule, make the bound energy of described polymer organic silicon protein molecule be energized into metastable state, make metastable state polymer organic silicon protein by ground state.
5, polynuclear silicon prion making method as claimed in claim 1, it is characterized in that, the concentration of sodium hydroxide solution, lithium hydroxide solution and potassium hydroxide solution in the described step (5) is volumetric molar concentration, in container with sodium hydroxide solution, lithium hydroxide solution and the potassium hydroxide solution of described concentration according to 1.2: 1.0: 1.0 mixed, make the ternary alkaline solution.
6, polynuclear silicon prion making method as claimed in claim 1, it is characterized in that described step (6) specifically comprises: generate collision property inorganic silicon solution with carrying out hybrid reaction in molar ratio with the ternary alkaline solution in the aerosil input cylinder container made of 1.3%-1.5% amount.
7, polynuclear silicon prion making method as claimed in claim 1, it is characterized in that, described step (8) specifically comprises: will collision property inorganic silicon protein and metastable state polymer organic silicon protein 1: 2.5 by volume mixed polynuclear silicon prion parent of making in closed reactor, wherein: the available silicon content of described polynuclear silicon prion parent is 0.29-0.3%wt, and colloidal particle size remains on the 10nm order of magnitude.
8, polynuclear silicon prion making method as claimed in claim 1 is characterized in that, described step (9) specifically comprises: denseness control-released agent, deflocculant and function permeate agent are added the polynuclear silicon prion parent by 0.1～0.15 ‰ be in harmonious proportion; The good polynuclear silicon prion parent that will be in harmonious proportion again added 1: 2: 3 in molar ratio: after 4 boric acid that prepare, phosphoric acid, silicic acid, sulfuric acid mix; Add 0.15～0.2 ‰ EDTA, many benzene nucleus quinone benzene or tartaric acid controlled release again, in the high-speed mixing still, mix system 2h then, make polynuclear silicon prion electrolytic solution.
9, a kind of store battery is characterized in that,
The cell body of described store battery adopts engineering plastics, and described battery separator is the beta glass fibre barrier film;
The anode plate grid of described store battery is the low calcium type Pb-Ca-Sn-Al alloy of high tin, and the negative electrode grid of described store battery is middle tin high-calcium type Pb-Ca-Sn-Al alloy;
The anode diachylon of described store battery also adds 0.5% type material antimonous oxide, and the cathode lead plaster of described store battery also adds 0.15 ‰ selenium powder;
The electrolytic solution of described store battery is polynuclear silicon prion electrolytic solution.
10, store battery as claimed in claim 9 is characterized in that, the content of each composition of the low calcium type Pb-Ca-Sn-Al alloy of described high tin is: Ca is 0.06%, and Sn is 1.50%, and Al is 0.03%;
The content of middle each composition of tin high-calcium type Pb-Ca-Sn-Al alloy is: Ca is 0.10%, and Sn is 0.80%, and Al is 0.03%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100979793A CN101323705A (en) | 2008-05-21 | 2008-05-21 | Polynuclear silicon prion high-energy lead-acid battery |
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2008100979793A CN101323705A (en) | 2008-05-21 | 2008-05-21 | Polynuclear silicon prion high-energy lead-acid battery |
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| CN101323705A true CN101323705A (en) | 2008-12-17 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101807723A (en) * | 2010-03-24 | 2010-08-18 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
| CN102931412A (en) * | 2012-11-14 | 2013-02-13 | 徐永生 | Formula of cathode lead plaster of lead-acid storage battery |
| CN103594740A (en) * | 2013-10-24 | 2014-02-19 | 湖南安圣电池有限公司 | Composite colloid comprising organic components and inorganic components for battery container formation |
| CN103594748A (en) * | 2013-10-24 | 2014-02-19 | 湖南安圣电池有限公司 | Internal battery formation method |
-
2008
- 2008-05-21 CN CNA2008100979793A patent/CN101323705A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101807723A (en) * | 2010-03-24 | 2010-08-18 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
| CN101807723B (en) * | 2010-03-24 | 2015-04-08 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
| CN102931412A (en) * | 2012-11-14 | 2013-02-13 | 徐永生 | Formula of cathode lead plaster of lead-acid storage battery |
| CN103594740A (en) * | 2013-10-24 | 2014-02-19 | 湖南安圣电池有限公司 | Composite colloid comprising organic components and inorganic components for battery container formation |
| CN103594748A (en) * | 2013-10-24 | 2014-02-19 | 湖南安圣电池有限公司 | Internal battery formation method |
| CN103594748B (en) * | 2013-10-24 | 2015-09-02 | 湖南安圣电池有限公司 | A kind of container formation method |
| CN103594740B (en) * | 2013-10-24 | 2016-05-18 | 湖南安圣电池有限公司 | A kind of composite colloid for container formation being formed by organic principle and inorganic constituents |
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Open date: 20081217 |