CN101318098B - Phase-change adsorption air dehumidifier - Google Patents

Phase-change adsorption air dehumidifier Download PDF

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Publication number
CN101318098B
CN101318098B CN2008101200372A CN200810120037A CN101318098B CN 101318098 B CN101318098 B CN 101318098B CN 2008101200372 A CN2008101200372 A CN 2008101200372A CN 200810120037 A CN200810120037 A CN 200810120037A CN 101318098 B CN101318098 B CN 101318098B
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phase
air
change
change adsorption
cavity
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CN101318098A (en
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王厉
骆菁菁
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Zhejiang Sci Tech University ZSTU
Zhejiang University of Science and Technology ZUST
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Zhejiang Sci Tech University ZSTU
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Abstract

The invention disclose a phase-transition absorption air dehumidifying device, which comprises consists a phase-transition reactor (1) in which a cavity (12) is arranged; wherein, a top opening (11) and a bottom opening (13) of the phase-transition reactor (1) are both communicated with the cavity (12); the top opening (11) is separately connected with an outlet pipe for processed air (61) and an inlet pipe for regenerated air (62) in a sealed way; the bottom opening (13) is separately connected with an inlet pipe for processed air (63) and an outlet pipe (64) for regenerated air in a sealed way; the other end of the inlet pipe for regenerated air (62) is connected with a heater for regenerated air (8); an inlet manifold for heat medium (81) and an outlet manifold for heat medium (82) are respectively arranged on the heater for regenerated air (8); an inner-cooling ventilation pipeline (2) is arranged in the cavity (12). The application of the device of the invention to the dehumidification provides good dehumidification effect, and can ensure that the temperature at the outlet for processed air is low.

Description

Phase-change adsorption air dehumidifier
Technical field
The present invention relates to a kind of air dehumidifier, particularly a kind of phase-change adsorption air dehumidifier.
Background technology
The temperature of air, humidity are two important parameters that air-conditioning process need be controlled, the 20%-40% of dehumidifying energy consumption duty adjusting system energy consumption; Traditional cooling and dehumidifying method supply water temperature is low, and cold engine efficiency is low, and dehumidifying back air themperature is low, also needs heat again for reaching ventilation state point, causes irreversible loss serious.So people have been developed temperature, humidity is separated control technology, promptly airborne water vapour is removed by special dehumidification system, and air-conditioning system is only born the sensible heat of handling air.Generally this class dehumidification system is divided into solution dehumidification system, ADSORPTION IN A FIXED BED dehumidification system and runner absorption type dehumidification system three major types, they all belong to equilibrium separation process.Wherein, the ADSORPTION IN A FIXED BED dehumidification system have system simple, implement easily, moving component is few, the exchange of gas-solid caloic fully, characteristics that irreversible loss is little, have bigger using value.The ADSORPTION IN A FIXED BED dehumidification system can be divided into internally cooled and heat insulation-type two classes.The characteristics of internally cooled system are to install cooling coil in adsorbent bed, take away the heat that absorption latent heat and regenerative process produce; It has, and volume is little, the advantage of continuously-running, but shortcoming is that system's complex structure, running gear are more.The heat insulation-type internal system is not established cooling coil, and it is divided into two kinds of continuous operation mode and gap mode of operations again.Work as running hours, adopt two handover operations, another bed dehumidifying during a bed regeneration; Its shortcoming be when regeneration system accumulated a large amount of heat energy, switch to dehumidification mode after, the heat that major part is accumulated will be born by processed air, and its outlet temperature is significantly increased, and increase the weight of the processing burden of follow-up link.When working for the gap, adsorbent needs regular replacing and regeneration separately, and owing to there is not interior cold-working usefulness, the heat of adsorption that adsorption process produces will make bed temperature raise gradually, thereby reduced the steam potential difference between adsorbent and the air, finally influenced effect on moisture extraction.This shows that processed air exit temp height and effect on moisture extraction are low to be two big major defects of heat insulation-type fixed adsorption bed.
Summary of the invention
It is good and can guarantee the phase-change adsorption air dehumidifier that processed air exit temp is low that the technical problem to be solved in the present invention provides a kind of effect on moisture extraction.
In order to solve the problems of the technologies described above, the invention provides a kind of phase-change adsorption air dehumidifier, establish the phase transformation adsorptive reactor of cavity in comprising, the open top of phase transformation adsorptive reactor and bottom opening all are connected with cavity; Sealing links to each other with the regeneration air blast pipe with processed air discharge pipe respectively in open top, and sealing links to each other bottom opening with the regeneration air discharge pipe with processed air blast pipe respectively; The other end of regeneration air blast pipe links to each other with regenerated air heater, is respectively equipped with heat medium enter hose and heat medium produce hose on the regenerated air heater; Interior cold air pipeline is positioned at described cavity, and the sidewall that the phase transformation adsorptive reactor is all passed in the import of described interior cold air pipeline and outlet is connected with the external world.
Improvement as phase-change adsorption air dehumidifier of the present invention: fill the mixture of forming by the particle of adsorbent and phase-change material in the cavity.
Further improvement as phase-change adsorption air dehumidifier of the present invention: the phase transition temperature of phase-change material is a normal temperature.
Further improvement as phase-change adsorption air dehumidifier of the present invention: on processed air discharge pipe, regeneration air blast pipe, processed air blast pipe, regeneration air discharge pipe, heat medium enter hose and heat medium produce hose, be respectively equipped with stop valve.
Further improvement as phase-change adsorption air dehumidifier of the present invention: the import of interior cold air pipeline is sealing with the outlet and the sidewall of phase transformation adsorptive reactor and links to each other.
Further improvement as phase-change adsorption air dehumidifier of the present invention: the outlet of interior cold air pipeline is positioned at the top of import.
Further improvement as phase-change adsorption air dehumidifier of the present invention: import is provided with the insulation door I that is movably connected with import, and outlet is provided with and exports the insulation door II that is movably connected.
Further improvement as phase-change adsorption air dehumidifier of the present invention: interior cold air pipeline is the Z type.
Further improvement as phase-change adsorption air dehumidifier of the present invention: phase-change material can select for use resin capsule to be packaged into the typing energy storage materials of phase change of the paraffin wax/high density polyethylene (HDPE) of particle; Adsorbent can be selected silica gel for use.
Further improvement as phase-change adsorption air dehumidifier of the present invention: regenerated air heater is for being provided the heater of heat by solar thermal collection system.
Phase-change adsorption air dehumidifier of the present invention, fixedly the processed air themperature of adsorption and dehumidification system is high and remove the low shortcoming of humidity effect can to overcome traditional heat insulation-type.The present invention is by adding a certain amount of normal temperature phase-change material in adsorbent, the water vapour absorption latent heat of being emitted in can the absorption portion course of reaction makes the temperature in the phase transformation adsorptive reactor comparatively stable, thereby improves the effect on moisture extraction of phase transformation adsorptive reactor; Phase-change material can also cool off processed air simultaneously, prevents that it is overheated.The interior cold air pipeline that is provided with in the phase transformation adsorptive reactor in the cooling procedure of phase transformation adsorptive reactor, is opened the thermal insulating door thermally insulated door that is positioned at its import and export and then can be formed the gravity-flow ventilation path; Under hot pressing function, cool ambient air enters the cold air pipeline that is arranged in phase transformation adsorptive reactor cavity, and the tube wall by interior cold air pipeline and phase transformation adsorptive reactor carry out the sensible heat exchange, reduces the temperature in the cavity gradually, makes adsorbent have adsorption capacity again; When night, environment temperature was low, phase-change material then became solid-state, again cold-storage.Therefore, the meaning of cold air pipeline not only is to finish whole working cycles in being provided with in the cavity, and key is to make dehydrating unit of the present invention have the ability that makes full use of surrounding air sensible heat cold.
In the present invention, phase-change material is combined with adsorbent; In adsorption process,, can stablize the adsorbent bed temperature, improve dehumidification rate, prevent that processed air is overheated by the phase-change material heat absorption.The absorption back adds thermal desorption by regeneration air.Afterwards, rely on the interior cold air pipeline that is arranged in the phase transformation adsorptive reactor, utilize the hot pressing ventilation to introduce surrounding air and cool off suction phase transformation adsorptive reactor; When environment temperature is low (as night), unnecessary cold is then stored by phase-change material, thereby makes the sufficiently cooled back of phase-change material cold-storage become solid-state again.Therefore, phase-change adsorption air dehumidifier of the present invention is carried out gap work, and a complete dehumidifying circulation comprises these 3 processes of absorption, desorption and cooling.Generally, daytime absorption, at dusk and night desorption, cooling.Therefore, phase-change adsorption air dehumidifier of the present invention is particularly suitable for the big area of day and night temperature.
Phase-change adsorption air dehumidifier of the present invention has the distinguishing feature that is different from traditional ADSORPTION IN A FIXED BED dehumidification system.Promptly compare internally cooled, the present invention does not need external refrigeration recirculated water; Compare heat insulation-type, the present invention has the interior cold measure of decalescence.The present invention has overcome the shortcoming of internally cooled and heat insulation-type simultaneously thus, and has had both advantages concurrently.
Phase-change adsorption air dehumidifier of the present invention, whole system simple structure, novelty, running gear is few, implements easily, can prevent that processed air is overheated, and effect on moisture extraction is good; And it utilizes gravity-flow ventilation to cool off, and regenerated air heater also can be connected with solar thermal collection system, and energy-saving effect is remarkable.
Description of drawings
Below in conjunction with accompanying drawing the specific embodiment of the present invention is described in further detail.
Fig. 1 is the structural representation of phase-change adsorption air dehumidifier of the present invention;
Fig. 2 is the A-A cross-sectional schematic of Fig. 1.
The specific embodiment
Fig. 1 and Fig. 2 establish the phase transformation adsorptive reactor 1 of cavity 12 in conjunction with having provided a kind of phase-change adsorption air dehumidifier in comprising, the open top 11 of phase transformation adsorptive reactor 1 and bottom opening 13 all are connected with cavity 12.Processed air discharge pipe 61 links to each other with open top 11 sealings, is provided with stop valve I 71 on processing air discharge pipe 61.One end of regeneration air blast pipe 62 links to each other with open top 11 sealings, and the other end links to each other with regenerated air heater 8, is provided with stop valve II 72 on regeneration air blast pipe 62; Be respectively equipped with heat medium enter hose 81 and heat medium produce hose 82 on this regenerated air heater 8, for the ease of saving the energy, regenerated air heater 8 is selected the heater that heat is provided by solar thermal collection system for use; On heat medium enter hose 81, be provided with stop valve V75, on heat medium produce hose 82, be provided with stop valve VI76.Processed air blast pipe 63 links to each other with bottom opening 13 sealings, is provided with stop valve III73 on processed air blast pipe 63.Regeneration air discharge pipe 64 links to each other with bottom opening 13 sealings, is provided with stop valve IV74 on regeneration air discharge pipe 64.
The interior cold air pipeline 2 of Z type is positioned at cavity 12, and the lower end of Z type is the import 21 of interior cold air pipeline 2, and the upper end of Z type is the outlet 22 of interior cold air pipeline 2; Therefore export 22 tops that are positioned at import 21.
The import 21 of interior cold air pipeline 2 and outlet 22 sidewalls that all pass phase transformation adsorptive reactor 1 are connected with the external world, and this import 21 all links to each other with the sidewall sealing of phase transformation adsorptive reactor 1 with outlet 22; Like this, just can guarantee that the cavity 12 of phase transformation adsorptive reactor 1 becomes the working environment of a sealing.In import 21, be provided with the insulation door I4 that is movably connected with import 21, in outlet 22, be provided with and export the 22 insulation door II5 that are movably connected.
In the cavity 12 of phase transformation adsorptive reactor 1, filling by adsorbent and phase transition temperature is the mixture 3 that the phase-change material of normal temperature is formed, and this adsorbent and phase-change material are graininess; Adsorbent can be selected silica gel particle for use, and the silica gel particle size is 2mm~5mm; Phase-change material can be selected paraffin wax/high density polyethylene (HDPE) fixed phase change energy-accumulation material for use, and utilizes resin capsule to be packaged into particle, and this granular size is 2mm~10mm.During actual the use, can set the amount ratio of adsorbent and phase-change material as required; The weight ratio that for example can set silica gel and paraffin wax/high density polyethylene (HDPE) fixed phase change energy-accumulation material is 1: 4; Above-mentioned both have formed mixture 3 after mixing by this weight ratio, and this mixture 3 has filled up whole cavity 12.
Phase-change adsorption air dehumidifier of the present invention, the course of work is specific as follows:
1), absorption:
The insulation door I 4 that is positioned at import 21 places of cold air pipeline 2 all keeps closing with the insulation door II5 that is positioned at outlet 22 places; Stop valve I71 and stop valve III73 open, and stop valve II72 and stop valve IV74 close.
Processed air enters the bottom of the cavity 12 of phase transformation adsorptive reactor 1 by processed air blast pipe 63 under the promotion of extraneous blower fan; Slowly flow then, and accept the processing of the mixture 3 formed by adsorbent and phase-change material to the top of cavity 12; Discharge from processed air discharge pipe 61 at last.It is adsorbed that processed airborne part steam is adsorbed agent, thereby reduced the air water capacity; The heat of adsorption of emitting during water recovery is born jointly by phase-change material, adsorbent and processed air.
When the outlet water capacity of processed air and import were basic identical, when promptly whole phase-change adsorption air dehumidifier can't dehumidify work again, adsorption process finished.Just carry out following desorption work then.
2), desorption
Keep closing insulation door I4 and insulation door II5, close stop valve I71 and stop valve III73, open stop valve II72 and stop valve IV74.
Under the promotion of extraneous blower fan and through the regeneration air after regenerated air heater 8 heat treated, enter the top of cavity 12 by regeneration air blast pipe 62, slowly flow to the bottom of cavity 12, finally discharge from regeneration air discharge pipe 64.To the adsorbent processing of regenerating, along with the carrying out of regenerative process, the water capacity of adsorbent reduces this regeneration air and temperature increases in cavity 12.Can come the heating efficiency of regenerated air heater 8 is regulated by stop valve V75 on the adjusting heat medium enter hose 81 and the stop valve VI76 on the heat medium produce hose 82, thereby the temperature after regeneration air is heated is regulated in realization.Generally speaking, the temperature of the regeneration air after the adjusting heating is 100 ℃~120 ℃.
When regeneration air outlet water capacity and import water capacity are basic identical, the regenerative process end.Just carry out following cooling work then.
3), cooling
Keep closing stop valve I71 and stop valve III73, close stop valve II72 and stop valve IV74, open insulation door I4 and insulation door II5.
Under the hot pressing function in cavity 12, in entering from import 21, surrounding air in the cold air pipeline 2, discharges from exporting 22 at last; Carry out the sensible heat exchange by adsorbent in interior cold air pipeline 2 tube walls and the cavity 12 and phase-change material, thereby take away the heat of adsorbent and phase-change material.
When this cooling procedure proceeded to night, because environment temperature further reduces, the phase change material cool storage in the inner chamber became solid-state, and the cooling regenerative process finishes.
Afterwards, close insulation door I4 and insulation door II5, the cavity 12 of phase transformation adsorptive reactor 1 is kept and extraneous state of thermal isolation.By the time entered next working cycles again in second day, and promptly adsorbed successively again, desorption and these 3 steps of cooling.
At last, it is also to be noted that what more than enumerate only is a specific embodiment of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.

Claims (9)

1. a phase-change adsorption air dehumidifier is characterized in that: establish the phase transformation adsorptive reactor (1) of cavity (12) in comprising, fill the mixture of being made up of the particle of adsorbent and phase-change material (3) in the described cavity (12); The open top (11) of phase transformation adsorptive reactor (1) and bottom opening (13) all are connected with described cavity (12); Sealing links to each other with regeneration air blast pipe (62) with processed air discharge pipe (61) respectively in open top (11), and sealing links to each other bottom opening (13) with regeneration air discharge pipe (64) with processed air blast pipe (63) respectively; The other end of described regeneration air blast pipe (62) links to each other with regenerated air heater (8), is respectively equipped with heat medium enter hose (81) and heat medium produce hose (82) on the described regenerated air heater (8); Interior cold air pipeline (2) is positioned at described cavity (12), and the sidewall that described phase transformation adsorptive reactor (1) is all passed in the import (21) of described interior cold air pipeline (2) and outlet (22) is connected with the external world.
2. phase-change adsorption air dehumidifier according to claim 1 is characterized in that: the phase transition temperature of described phase-change material is a normal temperature.
3. phase-change adsorption air dehumidifier according to claim 2 is characterized in that: be respectively equipped with stop valve on described processed air discharge pipe (61), regeneration air blast pipe (62), processed air blast pipe (63), regeneration air discharge pipe (64), heat medium enter hose (81) and heat medium produce hose (82).
4. phase-change adsorption air dehumidifier according to claim 3 is characterized in that: the import (21) of cold air pipeline (2) and outlet (22) and the sidewall of phase transformation adsorptive reactor (1) are to seal and link to each other in described.
5. phase-change adsorption air dehumidifier according to claim 4 is characterized in that: the outlet (22) of cold air pipeline (2) is positioned at the top of import (21) in described.
6. phase-change adsorption air dehumidifier according to claim 5, it is characterized in that: described import (21) is provided with the insulation door I (4) that is movably connected with import (21), and outlet (22) is provided with and exports the insulation door II (5) that (22) are movably connected.
7. phase-change adsorption air dehumidifier according to claim 6 is characterized in that: cold air pipeline (2) is the Z type in described.
8. phase-change adsorption air dehumidifier according to claim 7 is characterized in that: described phase-change material is for being packaged into the paraffin wax/high density polyethylene (HDPE) fixed phase change energy-accumulation material of particle with resin capsule, described adsorbent is a silica gel.
9. phase-change adsorption air dehumidifier according to claim 7 is characterized in that: described regenerated air heater (8) is for being provided the heater of heat by solar thermal collection system.
CN2008101200372A 2008-07-15 2008-07-15 Phase-change adsorption air dehumidifier Expired - Fee Related CN101318098B (en)

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Publication number Priority date Publication date Assignee Title
CN102954545B (en) * 2012-10-26 2015-01-21 上海交通大学 Solar dehumidifying air conditioner system with energy storage effect
CN103697544B (en) * 2013-12-26 2017-02-22 南京工业大学 Solution dehumidifying, regenerating and cycling method and special device for same
CN104107619A (en) * 2014-07-25 2014-10-22 西安交通大学 Adsorption bed layer doped with phase change material
CN106693605A (en) * 2017-01-26 2017-05-24 上海聚宸新能源科技有限公司 Adsorptive regeneration device with solid-liquid phase change matters and adsorptive regeneration process
CN110118463A (en) * 2019-06-14 2019-08-13 杨葆 A kind of freezer absorption type defrosting equipment
CN113295243B (en) * 2021-05-18 2023-04-07 安徽金大仪器有限公司 Negative pressure type gas standard detection device based on sonic nozzle

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