CN101314099A - Absorbent charcoal adsorber - Google Patents

Absorbent charcoal adsorber Download PDF

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Publication number
CN101314099A
CN101314099A CNA2008100623971A CN200810062397A CN101314099A CN 101314099 A CN101314099 A CN 101314099A CN A2008100623971 A CNA2008100623971 A CN A2008100623971A CN 200810062397 A CN200810062397 A CN 200810062397A CN 101314099 A CN101314099 A CN 101314099A
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China
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active carbon
absorbent charcoal
charcoal adsorber
shitosan
anion
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CNA2008100623971A
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CN101314099B (en
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徐贤庚
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Abstract

The invention relates to an active carbon adsorption device, comprising active carbon and an adsorption tank, wherein, the adsorption tank consists of an outer cylinder and an inner cylinder which is embedded in the outer cylinder; the wall of the outer cylinder and the wall of the inner cylinder are provided with a venthole respectively; an anion distribution pipe is arranged between the outer cylinder and the inner cylinder, and is connected with an anion generator; and the active carbon is distributed around the anion distribution pipe. The invention generates anions through adopting the anion generator, and timely performs oxidation, activation, decomposition and regeneration on adsorption saturated active carbon by the anions, so the active carbon can always perform adsorption. The active carbon prepared by the method has capability of strongly adsorbing formaldehyde and benzene harmful gas.

Description

A kind of absorbent charcoal adsorber
(1) technical field
The present invention relates to a kind of absorbent charcoal adsorber.
(2) background technology
Existing absorbent charcoal adsorber is generally adsorption tanks, is filled with active carbon in jar, and active carbon can take place saturated after absorption a period of time.In case adsorb saturatedly, the gas peculiar smell that active carbon has adsorbed can discharge on the contrary, endangers consumer's health (particularly pernicious gas formaldehyde) again, promptly becomes pollution sources on the contrary.In addition, existing activated carbon adsorptive capacity also has much room for improvement.
(3) summary of the invention
Technical problem to be solved by this invention is to provide a kind of never saturated absorbent charcoal adsorber.
Technical problem to be solved by this invention also is to provide a kind of active carbon of high adsorption capacity.
Described absorbent charcoal adsorber comprises active carbon and adsorption tanks, and described adsorption tanks are made up of urceolus and the inner core that is nested in the urceolus, and urceolus and inner core barrel are respectively equipped with passage; Be provided with the anion distributor pipe between urceolus and the inner core, the anion distributor pipe connects anion generator; Active carbon is distributed in around the anion distributor pipe.
Preferably, described inner core cavity is provided with blower fan.Blower fan can promote that air filters absorption by active carbon.
Anion generator of the present invention can produce anion, contact with active carbon through each anion distributor pipe, harmful substance oxidation Decomposition such as the formaldehyde of charcoal absorption, thus the charcoal absorption state becomes unsaturatedly by saturated, and active carbon can continue to be adsorbed with harmful substances.Anion generator can be controlled the working time that produces anion, waits to free to quit work automatically after decomposition finishes.
Preferably, described active carbon adopts following step preparation and gets:
(1) with relative molecular weight be 250000~350000, deacetylation is that 95~99% shitosan is dissolved in the diluted acid, makes chitosan concentration and be 1~5% shitosan acid solution;
(2) add powdered cellulose and stirring, again with alkali lye handle to pH be 8~10, the cohesion shitosan;
(3) dehydration, drying adds the coconut husk powdered carbon then, and granulation forms active carbon of the present invention;
Above-mentioned cellulose: shitosan acid solution: the weight ratio of coconut husk powdered carbon is 3~6: 40~60: 40~50.The active carbon that makes by above-mentioned steps has the ability of powerful absorbing formaldehyde and benzene class pernicious gas.
Preferably, in the described step (1): the shitosan relative molecular weight is 310000, deacetylation is 98%, and diluted acid is a watery hydrochloric acid.
Preferably, the chitosan concentration of shitosan acid solution is 2% in the described step (1).
Preferably, alkali lye is 5%NaOH solution described in the described step (2), with alkali lye handle to pH be 9.The consumption of alkali lye is to reach pH9 for the most suitable.
Preferably, adopt the heated-air drying of centrifugal dehydration and 100 ℃ in the described step (3).
Preferably, described cellulose: shitosan acid solution: the weight ratio of coconut husk powdered carbon is 5: 50: 45.
The present invention produces anion by adopting negative ion generating device, in time will adsorb saturated active carbon by anion and carry out the oxidized activating disintegrating and regeneration, the absorption that active carbon can be continued forever.The active carbon that the inventive method makes has the ability of powerful absorbing formaldehyde and benzene class pernicious gas.
(4) description of drawings
Fig. 1 is the structural representation of the described absorbent charcoal adsorber of embodiment.
(5) specific embodiment
Below by embodiment the present invention is made preferably specific description, but protection scope of the present invention is not limited to this.
With reference to Fig. 1, a kind of absorbent charcoal adsorber comprises active carbon 1 and adsorption tanks, and described adsorption tanks are made up of urceolus 2 and the inner core 3 that is nested in the urceolus 2, and urceolus 2 and inner core 3 barrels are respectively equipped with passage; Be provided with anion distributor pipe 4 between urceolus 2 and the inner core 3, anion distributor pipe 4 connects anion generator 5; Active carbon 1 is distributed in around the anion distributor pipe 5.
Described inner core 3 cavitys are provided with blower fan 6.
Described active carbon adopts following step preparation and gets:
(1) with relative molecular weight be 310000, deacetylation is that 98% shitosan is dissolved in the watery hydrochloric acid, makes chitosan concentration and be 2% shitosan acid solution;
(2) adding powdered cellulose and stirring, is 9 with the 5%NaOH solution-treated to pH again, the cohesion shitosan;
(3) centrifugal dehydration, 100 ℃ of heated-air dryings add the coconut husk powdered carbon then, and granulation forms active carbon of the present invention;
Described cellulose: shitosan acid solution: the weight ratio of coconut husk powdered carbon is 5: 50: 45.

Claims (8)

1, a kind of absorbent charcoal adsorber comprises active carbon and adsorption tanks, it is characterized in that described adsorption tanks are made up of urceolus and the inner core that is nested in the urceolus, is respectively equipped with passage on urceolus and the inner core barrel; Be provided with the anion distributor pipe between urceolus and the inner core, the anion distributor pipe connects anion generator; Active carbon is distributed in around the anion distributor pipe.
2, absorbent charcoal adsorber according to claim 1 is characterized in that described inner core cavity is provided with blower fan.
3, absorbent charcoal adsorber according to claim 1 is characterized in that described active carbon adopts the preparation of following step and gets:
(1) with relative molecular weight be 250000~350000, deacetylation is that 95~99% shitosan is dissolved in the diluted acid, makes chitosan concentration and be 1~5% shitosan acid solution;
(2) add powdered cellulose and stirring, again with alkali lye handle to pH be 8~10, the cohesion shitosan;
(3) dehydration, drying adds the coconut husk powdered carbon then, and granulation forms active carbon of the present invention; Above-mentioned cellulose: shitosan acid solution: the weight ratio of coconut husk powdered carbon is 3~6: 40~60: 40~50.
4, absorbent charcoal adsorber according to claim 3 is characterized in that in the described step (1): the shitosan relative molecular weight is 310000, deacetylation is 98%, and diluted acid is a watery hydrochloric acid.
5, absorbent charcoal adsorber according to claim 3 is characterized in that the chitosan concentration of shitosan acid solution in the described step (1) is 2%.
6, absorbent charcoal adsorber according to claim 3 is characterized in that alkali lye is 5%NaOH solution described in the described step (2), with alkali lye handle to pH be 9.
7, absorbent charcoal adsorber according to claim 3 is characterized in that adopting in the described step (3) heated-air drying of centrifugal dehydration and 100 ℃.
8, absorbent charcoal adsorber according to claim 3 is characterized in that described cellulose: the shitosan acid solution: the weight ratio of coconut husk powdered carbon is 5: 50: 45.
CN2008100623971A 2008-05-15 2008-05-15 Absorbent charcoal adsorber Expired - Fee Related CN101314099B (en)

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CN2008100623971A CN101314099B (en) 2008-05-15 2008-05-15 Absorbent charcoal adsorber

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Application Number Priority Date Filing Date Title
CN2008100623971A CN101314099B (en) 2008-05-15 2008-05-15 Absorbent charcoal adsorber

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CN101314099A true CN101314099A (en) 2008-12-03
CN101314099B CN101314099B (en) 2012-06-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103421603A (en) * 2013-09-11 2013-12-04 四川国为制药有限公司 Method for removing dioxin and analogues thereof in fish oil
CN105444287A (en) * 2015-12-21 2016-03-30 天津欧盼科技开发有限公司 Indoor environment purifying equipment
CN112915967A (en) * 2021-03-22 2021-06-08 南京科盛环保技术有限公司 Modified bioactive carbon adsorbent for removing Cr (VI), and preparation method, device and application thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2221737Y (en) * 1994-09-19 1996-03-06 葛杰光 Omnibearing cylindrical air purifier
CN2234578Y (en) * 1995-08-31 1996-09-04 中国人民解放军昆明陆军学院科技开发部 High-voltage electrostatic miniature air purifier
JP2002233727A (en) * 2001-02-09 2002-08-20 ▲国▼和産業株式会社 Air cleaner
JP2001276200A (en) * 2001-03-27 2001-10-09 Sogo Musen:Kk Serving for environmental improvement with filter coping with such gaseous body as air, gas, etc., attachable and detachable by changing forms according to use by mixing sintered grain and powder of chitin chitosan calcium with grain, or powder of bamboo charcoal, and spraying the mixture to cotton, nonwoven fabric, plastic net, metallic net, etc., or laminating the mixture within those nets and giving falling-off preventive treatment to bamboo grain charcoal, bamboo powder charcoal, etc., and chitin chitosan calcium sintered grain, chitin chitosan calcium sintered powder, etc.
CN201231123Y (en) * 2008-05-15 2009-05-06 徐贤庚 Active carbon absorption device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103421603A (en) * 2013-09-11 2013-12-04 四川国为制药有限公司 Method for removing dioxin and analogues thereof in fish oil
CN105444287A (en) * 2015-12-21 2016-03-30 天津欧盼科技开发有限公司 Indoor environment purifying equipment
CN112915967A (en) * 2021-03-22 2021-06-08 南京科盛环保技术有限公司 Modified bioactive carbon adsorbent for removing Cr (VI), and preparation method, device and application thereof

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SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20081203

Assignee: Zhejiang Suichang Xufu Bamboo Charcoal Co., Ltd.

Assignor: Xu Xiangeng

Contract record no.: 2013330000365

Denomination of invention: Activated carbon fiber adsorber

Granted publication date: 20120627

License type: Exclusive License

Record date: 20131211

LICC Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120627

Termination date: 20150515

EXPY Termination of patent right or utility model