CN101310827B - Activated charcoal gas cleaning method and device thereof - Google Patents

Activated charcoal gas cleaning method and device thereof Download PDF

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CN101310827B
CN101310827B CN2008101008043A CN200810100804A CN101310827B CN 101310827 B CN101310827 B CN 101310827B CN 2008101008043 A CN2008101008043 A CN 2008101008043A CN 200810100804 A CN200810100804 A CN 200810100804A CN 101310827 B CN101310827 B CN 101310827B
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张开元
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Beijing SPC Environment Protection Tech Co Ltd
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Abstract

本发明提供了一种脱硫、脱硝效率高、节约能耗、且床层阻力小、吸收塔内空间利用率高、建造成本低的活性焦炭气体净化方法及其装置。所述装置包括位于吸收塔上部的总进料口、气体总出口,吸收塔下部的总出料口、气体总进口,以及位于吸收塔内的活性焦炭床层,活性焦炭床层为倾斜的,其与垂直线之间呈一夹角α。所述方法步骤如下:使气体通过气体总进口进入活性焦炭床层,在倾斜式床层内气体自下方至上方流动;同时使活性焦炭通过总进料口进入活性焦炭床层,在倾斜式床层内活性焦炭自上方至下方流动;气体和活性焦炭之间形成充分的斜对流接触后,气体从气体总出口排出,吸附饱和后的活性焦炭自总出料口排出。

Figure 200810100804

The invention provides an activated coke gas purification method and device thereof, which have high desulfurization, high denitrification efficiency, energy saving, low bed resistance, high space utilization rate in an absorption tower, and low construction cost. The device comprises a total feed inlet at the upper part of the absorption tower, a total gas outlet, a total discharge port at the bottom of the absorption tower, a total gas inlet, and an activated coke bed located in the absorption tower. The activated coke bed is inclined, It forms an angle α with the vertical line. The steps of the method are as follows: the gas enters the activated coke bed through the gas inlet, and the gas flows from the bottom to the top in the inclined bed; at the same time, the activated coke enters the activated coke bed through the main inlet, and the gas flows in the inclined bed. The activated coke in the layer flows from top to bottom; after sufficient oblique convective contact is formed between the gas and the activated coke, the gas is discharged from the gas outlet, and the saturated activated coke is discharged from the outlet.

Figure 200810100804

Description

一种活性焦炭气体净化方法及装置A method and device for purifying activated coke gas

技术领域 technical field

本发明涉及一种活性焦炭气体净化方法及装置。 The invention relates to an activated coke gas purification method and device.

背景技术 Background technique

活性焦干法脱硫、脱硝技术常应用于工业燃煤锅炉烟气净化,也用于化工、冶金、玻璃、制药等领域的吸收塔内气体的净化处理。 Activated coke dry desulfurization and denitrification technology is often used in the purification of flue gas from industrial coal-fired boilers, and also in the purification of gas in absorption towers in the fields of chemical industry, metallurgy, glass, and pharmaceuticals.

<活性焦炭脱硫技术发展情况> <Development of Activated Coke Desulfurization Technology>

活性焦炭脱硫技术是上世纪60年代发展起来,以物理-化学吸附原理为基础的干法脱硫、脱硝技术,具有吸附容量大、吸附过程和催化转换快的优点。吸附过二氧化硫的活性焦炭再生后可重复使用,再生后的二氧化硫还可制成硫酸、液体二氧化硫或单质硫等副产品。在欧美、日本等国家,这项技术经过多年的研究已经有了在很多领域的商业化应用,活性焦吸附法是德国BF公司在1967年开发的,而后日本三井住友引进该技术(其方案为错流吸收技术),由德国BF公司演变而来的WKV公司针对错流技术的缺点进行改进,发明了目前国际上主流的对流吸收技术。 Activated coke desulfurization technology was developed in the 1960s. It is a dry desulfurization and denitrification technology based on the principle of physical-chemical adsorption. It has the advantages of large adsorption capacity, fast adsorption process and catalytic conversion. Activated coke that has adsorbed sulfur dioxide can be reused after regeneration, and the regenerated sulfur dioxide can also be made into by-products such as sulfuric acid, liquid sulfur dioxide or elemental sulfur. In Europe, America, Japan and other countries, this technology has been commercialized in many fields after years of research. The activated coke adsorption method was developed by the German BF company in 1967, and then Japan Mitsui Sumitomo introduced this technology (the scheme is Cross-flow absorption technology), WKV company, which evolved from German BF company, improved the shortcomings of cross-flow technology and invented the current international mainstream convection absorption technology.

<活性焦炭脱硫技术工作原理> <Working principle of activated coke desulfurization technology>

活性焦属炭系吸附剂,具有活性炭的特性。即活性焦本身即是吸附剂,又是催化剂,同时还可以用作催化剂载体。烟气经过活性焦吸附塔时,烟气中的SO2、NOX、O2、H2O及通入的NH3被吸附在活性焦孔隙中。在活性焦催化作用下,SO2和O2及H2O发生反应,最后以H2SO4形式附着在活性焦孔隙中;NO与O2及NH3反应生成N2,NO2与NH3反应生成N2,从而达到脱除燃煤烟气中SO2和NOX的目的。 Activated coke is a carbon-based adsorbent with the characteristics of activated carbon. That is, activated coke itself is not only an adsorbent, but also a catalyst, and can also be used as a catalyst carrier. When the flue gas passes through the activated coke adsorption tower, SO 2 , NO X , O 2 , H 2 O in the flue gas and NH 3 fed in are adsorbed in the pores of the active coke. Under the catalysis of active coke, SO 2 reacts with O 2 and H 2 O, and finally attaches in the pores of active coke in the form of H 2 SO 4 ; NO reacts with O 2 and NH 3 to form N 2 , and NO 2 and NH 3 The reaction produces N 2 , so as to achieve the purpose of removing SO 2 and NO X in the coal-fired flue gas.

<目前活性焦脱硫技术的两种形式> <Current Two Forms of Activated Coke Desulfurization Technology>

目前活性焦干法烟气脱硫、脱硝技术中存在的两种形式:一种是错流吸附技术,另一种是对流吸附技术。两种技术的吸附原理如下: At present, there are two forms of activated coke dry flue gas desulfurization and denitrification technology: one is cross-flow adsorption technology, and the other is convective flow adsorption technology. The adsorption principle of the two technologies is as follows:

图1是错流吸附技术结构原理图,吸收塔顶部设有新鲜吸附剂进口24,吸收塔底部设有吸附饱和的吸附剂出口25,吸收塔左侧设有气体进口26,吸收塔右侧设有气体出口27。如图中所示,可将吸收塔内的吸附剂划分为三个区域,靠近气体进口26一侧的区域28内是吸附饱和度大的吸附剂;靠近气体出口27一侧附近、以及新鲜吸附剂进口24附近的区域29内是较为新鲜的吸附剂;靠近吸收塔下部的区域30内是吸附饱和的吸附剂。 Fig. 1 is the structural schematic diagram of cross-flow adsorption technology, the top of the absorption tower is provided with fresh adsorbent inlet 24, the bottom of the absorption tower is provided with the adsorbent outlet 25 of adsorption saturation, the left side of the absorption tower is provided with gas inlet 26, and the right side of the absorption tower is provided with There is a gas outlet 27 . As shown in the figure, the adsorbent in the absorption tower can be divided into three regions, the adsorbent with high adsorption saturation in the region 28 near the gas inlet 26 side; near the gas outlet 27 side, and fresh adsorption The area 29 near the agent inlet 24 is relatively fresh adsorbent; the area 30 near the lower part of the absorption tower is the adsorbent saturated with adsorption.

错流吸附技术的发展相对较早,气体在吸收塔侧面自左至右通过吸收塔,活性焦自上而下通过吸收塔,二者错流接触。优点是:进气面积大、气体在塔内空速低,床层阻力小,由于塔内不用设置进气、出气空间、活性焦储料和下料空间,因此吸收塔内空间利用率大。缺点:烟气从侧面进入活性焦床层,靠近烟气进口的活性焦首先发生吸附反应并最先达到饱和,烟气由左往右移动,活性焦的吸附饱和量依次减少,总的分布情况是活性焦的吸附饱和量从左往右依次减少,从上往下依次增大,在靠近烟气出口处一侧的活性焦吸附量较少,从而使排出的活性焦中含有一部分没有吸附完全的活性焦,这样部分新鲜的活性焦被排出,并送去再生,从而使活性焦循环量加大,循环量的加大也使耗电量和破损量加大,再生燃气量加大,造成能量浪费,另外由于下部的活性焦吸附量饱和量较大,脱硫效率较低,上面的活性焦由于比较新鲜,脱硫效率较高,而气体出口的总的脱硫、脱硝效率为上下位置效率的平均值,因此其脱硫、脱硝效率不如对流吸附效率高。 The development of cross-flow adsorption technology is relatively early. The gas passes through the absorption tower from left to right on the side of the absorption tower, and the active coke passes through the absorption tower from top to bottom, and the two are in cross-flow contact. The advantages are: large air intake area, low gas velocity in the tower, and small bed resistance. Since there is no need for air intake, air outlet space, active coke storage and feeding space in the tower, the space utilization rate in the absorption tower is large. Disadvantages: The flue gas enters the activated coke bed from the side, the activated coke near the flue gas inlet first undergoes adsorption reaction and reaches saturation first, the flue gas moves from left to right, the adsorption saturation of activated coke decreases in turn, the overall distribution The adsorption saturation of activated coke decreases from left to right, and increases from top to bottom. The adsorption of activated coke on the side near the flue gas outlet is less, so that some of the activated coke discharged is not fully adsorbed. In this way, part of the fresh active coke is discharged and sent for regeneration, so that the circulation of active coke is increased, and the increase of circulation also increases the power consumption and damage, and the amount of regeneration gas increases, resulting in Energy is wasted. In addition, due to the large saturation of the activated coke in the lower part, the desulfurization efficiency is low. The upper active coke is relatively fresh, so the desulfurization efficiency is higher, and the total desulfurization and denitrification efficiency of the gas outlet is the average of the efficiencies of the upper and lower positions. value, so its desulfurization and denitrification efficiency is not as high as that of convective adsorption.

图2是对流吸附技术结构原理图。吸收塔顶部设有新鲜吸附剂进口24,吸收塔底部设有吸附饱和后的吸附剂放料口39,吸收塔下部设有气体进口26,吸收塔上部设有气体出口27,吸收塔内设有吸附剂床层33。如图所示的设备上还包括:活性焦吸附剂储仓31,吸附剂均匀分布装置32,吸附剂出料口和气体进口分布器34,吸附剂下料装置35,气体进口密封隔板36,出料控制器37,出料储仓38。 Figure 2 is a schematic diagram of the structure of the convective adsorption technology. The top of the absorption tower is provided with a fresh adsorbent inlet 24, the bottom of the absorption tower is provided with an adsorbent discharge port 39 after adsorption saturation, the lower part of the absorption tower is provided with a gas inlet 26, the upper part of the absorption tower is provided with a gas outlet 27, and the absorption tower is provided with Adsorbent bed 33. The equipment shown in the figure also includes: activated coke adsorbent storage bin 31, adsorbent uniform distribution device 32, adsorbent outlet and gas inlet distributor 34, adsorbent feeding device 35, gas inlet sealing partition 36 , a discharge controller 37, a discharge storage bin 38.

对流吸附技术是让烟气从底部向上均匀穿过活性焦床层,新鲜的活性焦从顶部向下流动和气体对流接触,从而使床层中的活性焦吸附饱和量由下到上依次减小,吸附饱和的活性焦首先被排出,对于同一平面上的活性焦的吸附量大小是相同的,因此活性焦下降的速度也几乎是一样的,从而使活性焦的利用率大大提高,而且由于床层的厚度是均匀的,烟气进气也均匀,烟气各点的阻力大小也是均匀的,烟气和活性焦的接触时间也基本相同,床层越高接触时间越长,脱硫效率也就越高,最高可达99%以上。在活性焦的循环量上由于对流技术中塔内各点的下料量是一样的,塔出口的活性焦颗粒几乎都是饱和的,也就是说吸附同样多的SO2,对流技术用的活性焦相对较少,排出的活性焦也就少,即循环量小,系统较为节能。缺点是:由于烟气在底部进入吸收塔,进气面积较小,气体在塔内空速高,床层阻力大,同时在塔内需要留有进气空间、出气空间、活性焦储料仓、活性焦下料仓,因此对流吸收塔内空间利用率低。 The convective adsorption technology is to let the flue gas pass through the active coke bed evenly from the bottom up, and the fresh active coke flows down from the top to contact with the gas convection, so that the adsorption saturation of the active coke in the bed decreases from bottom to top. , the activated coke saturated with adsorption is discharged first, and the adsorption capacity of the activated coke on the same plane is the same, so the rate of decline of the activated coke is almost the same, so that the utilization rate of the activated coke is greatly improved, and because the bed The thickness of the layer is uniform, the flue gas intake is also uniform, the resistance of each point of the flue gas is also uniform, and the contact time between the flue gas and the activated coke is basically the same. The higher, the highest can reach more than 99%. In terms of the circulating amount of active coke, since the feeding amount of each point in the tower is the same in the convection technology, the active coke particles at the outlet of the tower are almost saturated, that is to say, the same amount of SO 2 is adsorbed, and the active coke used in the convection technology The coke is relatively less, and the active coke discharged is less, that is, the circulation volume is small, and the system is more energy-saving. The disadvantages are: because the flue gas enters the absorption tower at the bottom, the air intake area is small, the air velocity in the tower is high, and the bed resistance is large. , Active coke lower silo, so the space utilization rate in the convective absorption tower is low.

对流吸附技术是在错流吸附技术之后发展的吸附技术,其优点是吸附效率高、活性炭利用率高;其缺点是建造工艺复杂、建造成本高。由于采用对流吸附技术的活性焦床层多为平面形状,其占地面积较大,建设时需要更多的钢材等材料;由于吸附面为平面,活性焦回收部分需要设置多个阀门和管线,结构复杂,钢材使用量大,也容易出现故障。一般在同样烟气处理量的情况下,采用对流吸附技术的建造成本大约是采用错流吸附技术的建造成本的一倍。例如,建设一个吸附能力为220万标准立方烟气量的吸附设备,采用对流吸附技术的建造成本大约是4.2亿元,采用错流吸附技术的建造成本大约2.08亿元。 Convective adsorption technology is an adsorption technology developed after cross-flow adsorption technology. Its advantages are high adsorption efficiency and high utilization of activated carbon; its disadvantages are complex construction process and high construction cost. Since the active coke bed layer using convective adsorption technology is mostly planar, it occupies a large area and requires more steel and other materials during construction; since the adsorption surface is flat, multiple valves and pipelines need to be installed in the active coke recovery part. The structure is complex, the amount of steel used is large, and it is also prone to failure. Generally, under the same flue gas treatment capacity, the construction cost of the convective adsorption technology is about twice that of the cross-flow adsorption technology. For example, to build an adsorption equipment with an adsorption capacity of 2.2 million standard cubic flue gas, the construction cost of using convective adsorption technology is about 420 million yuan, and the construction cost of using cross-flow adsorption technology is about 208 million yuan.

发明内容Content of invention

本发明所要解决的技术问题在于,提供了一种脱硫、脱硝效率高、节约能耗、且床层阻力小、吸收塔内空间利用率高、建造成本低的活性焦炭气体净化方法及其装置。 The technical problem to be solved by the present invention is to provide a method and device for purifying activated coke gas with high desulfurization and denitrification efficiency, energy saving, low bed resistance, high space utilization rate in the absorption tower, and low construction cost.

为解决上述技术问题,本发明采用以下技术方案: In order to solve the problems of the technologies described above, the present invention adopts the following technical solutions:

一种活性焦炭气体净化装置,包括位于吸收塔上部的总进料口、气体总出口,吸收塔下部的总出料口、气体总进口,以及位于吸收塔内的活性焦炭床层,所述的活性焦炭床层为倾斜的,其与水平面的垂直线之间呈一夹角α。所述的活性焦炭床层通过层流隔板被分隔为多个倾斜单元活性焦炭床层。所述单元活性焦炭床层的下方设置有单元气体进口,所述单元气体进口与气体总进口之间设有进口气体通道;所述单元活性焦炭床层的上方设置有单元气体出口,所述单元气体出口与气体总出口之间设有出口气体通道;所述单元活性焦炭床层的上方设置有单元进料口,所述单元进料口通过单元进料口通道与总进料口相连接;所述单元活性焦炭床层的下方设置有单元出料口,所述单元出料口通过单元出料口通道与总出料口相连接。 An activated coke gas purification device, comprising a total feed inlet at the upper part of the absorption tower, a total gas outlet, a total discharge port at the lower part of the absorption tower, a total gas inlet, and an activated coke bed located in the absorption tower. The activated coke bed is inclined, forming an angle α between it and the vertical line of the horizontal plane. The activated coke bed is divided into a plurality of inclined unit activated coke beds through laminar flow partitions. A unit gas inlet is arranged below the unit activated coke bed, and an inlet gas passage is arranged between the unit gas inlet and the gas total inlet; a unit gas outlet is arranged above the unit activated coke bed, and the unit gas outlet is arranged above the unit activated coke bed. An outlet gas channel is provided between the gas outlet and the total gas outlet; a unit feed port is arranged above the unit activated coke bed, and the unit feed port is connected to the total feed port through a unit feed port channel; A unit discharge port is arranged below the unit activated coke bed, and the unit discharge port is connected to the general discharge port through a channel of the unit discharge port.

进一步,所述单元进料口通道与总进料口之间设置有储料仓。 Further, a storage bin is arranged between the unit feed port channel and the general feed port.

进一步,所述单元活性焦炭床层的上方设置有单元进料口,所述单元进料口通过单元进料口通道与主进料通道相连接,主进料通道与总进料口相连接。 Further, a unit feed port is provided above the unit activated coke bed, and the unit feed port is connected to the main feed channel through the unit feed port channel, and the main feed channel is connected to the general feed port.

进一步,所述主进料口通道与总进料口之间设置有储料仓。 Further, a storage bin is arranged between the main feeding port channel and the main feeding port.

进一步,所述单元活性焦炭床层的下方设置有单元出料口,所述多个单元出料口可分为若干小组,各组单元出料口通过单元出料口通道与一级出料通道相连接,所述的多个一级出料通道通过二级出料通道与总出料口相连接。 Further, a unit discharge port is arranged below the unit activated coke bed, and the plurality of unit discharge ports can be divided into several groups, and each group of unit discharge ports passes through the unit discharge port channel and the primary discharge channel. The multiple primary discharge channels are connected to the total discharge port through the secondary discharge channels.

进一步,根据单元活性焦炭床层的数量,在二级出料通道与总出料口之间设置三级出料通道或三级以上的出料通道。 Further, according to the number of unit activated coke beds, a tertiary discharge channel or more than three discharge channels are set between the secondary discharge channel and the total discharge port.

进一步,所述单元活性焦炭床层的上下两底面之间的垂直距离为H,所述单元活性焦炭床层的单元进气口和单元出气口所在的两个侧面之间的水平投影距离为L,所述垂直距离H与水平投影距离L的比值范围是:0.4≤H:L≤2。 Further, the vertical distance between the upper and lower bottom surfaces of the unit activated coke bed is H, and the horizontal projection distance between the two sides where the unit air inlet of the unit activated coke bed and the unit gas outlet are located is L , the ratio range of the vertical distance H to the horizontal projection distance L is: 0.4≤H:L≤2.

进一步,所述夹角α的范围是:35°≤α≤65°。 Further, the range of the included angle α is: 35°≤α≤65°.

进一步,所述的单元气体进口上设有进气口挡料装置;进气口挡料装置与水平面垂直方向成45度角,进气口挡料装置由位于单元气体进口四周的挡板构成。 Further, the gas inlet of the unit is provided with an air inlet retaining device; the air inlet retaining device is at an angle of 45 degrees to the vertical direction of the horizontal plane, and the air inlet retaining device is composed of baffles located around the unit gas inlet.

进一步,所述的单元气体出口上设有出气口挡料装置;出气口挡料装置与水平面垂直方向成45度角,出气口挡料装置由位于单元气体出口四周的挡板构成。  Further, the gas outlet of the unit is provided with a gas outlet blocking device; the gas outlet blocking device is at an angle of 45 degrees to the vertical direction of the horizontal plane, and the gas outlet blocking device is composed of baffles located around the unit gas outlet. the

一种活性焦炭气体净化方法,将吸收塔内的活性焦炭床层设置为倾斜的,所述活性焦炭床层的上方设置有气体总出口,总进料口,所述单元活性焦炭床层的下方设置有气体总进口、总出料口,所述方法步骤如下: A method for purifying activated coke gas, wherein the activated coke bed in the absorption tower is set to be inclined, the top of the activated coke bed is provided with a total gas outlet, a total feed port, and the unit below the activated coke bed A total gas inlet and a total discharge port are provided, and the steps of the method are as follows:

使气体通过气体总进口进入活性焦炭床层,在倾斜式床层内气体自下方至上方流动; The gas enters the activated coke bed through the gas inlet, and the gas flows from bottom to top in the inclined bed;

同时使活性焦炭通过总进料口进入活性焦炭床层,在倾斜式床层内活性焦炭自上方至下方流动; At the same time, the activated coke enters the activated coke bed through the total feed port, and the activated coke flows from top to bottom in the inclined bed;

气体和活性焦炭之间形成充分的斜对流接触后,气体从气体总出口排出,吸附饱和后的活性焦炭自总出料口排出。 After sufficient oblique convective contact is formed between the gas and the activated coke, the gas is discharged from the gas outlet, and the activated coke after adsorption saturation is discharged from the outlet.

进一步,用层流隔板将活性焦炭床层分隔为多个倾斜的单元活性焦炭床层,所述单元活性焦炭床层的上方设置有单元气体出口,单元进料口,所述单元活性焦炭床层的下方设置有单元气体进口、单元出料口,所述方法步骤如下: Further, the activated coke bed is separated into a plurality of inclined unit activated coke beds with a laminar flow partition, and a unit gas outlet and a unit feed port are arranged above the unit activated coke bed, and the unit activated coke bed The lower part of the layer is provided with a unit gas inlet and a unit outlet, and the steps of the method are as follows:

使气体通过单元进气口进入每个单元活性焦炭床层,在倾斜式单元床层内气体自下方至上方流动; The gas enters the activated coke bed of each unit through the unit inlet, and the gas flows from bottom to top in the inclined unit bed;

同时使活性焦炭通过单元进料口进入每个单元活性焦炭床层,在倾斜式单元床层内活性焦炭自上方至下方流动; At the same time, activated coke enters each unit activated coke bed through the unit feed port, and the activated coke flows from top to bottom in the inclined unit bed;

气体和活性焦炭之间形成充分的斜对流接触后,气体从单元气体出口排出,吸附饱和后的活性焦炭自单元出料口排出。 After sufficient oblique convective contact is formed between the gas and activated coke, the gas is discharged from the gas outlet of the unit, and the activated coke after adsorption saturation is discharged from the outlet of the unit.

本发明采用层流式吸附技术,与错流吸附技术相比,发明中的技术方案的吸附效率有明显的提高,而建设成本却相差不大。同采用对流吸附技术相比,本发明中的技术方案在同样吸附效率的情况下,建设成本只是采用对流吸附技术的一半左右,并且节省钢材、空间利用率高、节省占地面积。例如,建设一个吸附能力为220万标准立方烟气量的吸附设备,采用对流吸附技术的建造成本大约是4.2亿元,采用本发明技术方案的建造成本大约为3.0亿元,可以节省1.2亿元,约节约费用30%。 The invention adopts the laminar flow adsorption technology, and compared with the cross-flow adsorption technology, the adsorption efficiency of the technical solution in the invention is obviously improved, but the construction cost is not much different. Compared with the convective adsorption technology, under the same adsorption efficiency, the construction cost of the technical solution in the present invention is only about half of that of the convective adsorption technology, and it saves steel, has high space utilization rate, and saves floor area. For example, to build an adsorption device with an adsorption capacity of 2.2 million standard cubic flue gas, the construction cost of adopting convective adsorption technology is about 420 million yuan, and the construction cost of adopting the technical solution of the present invention is about 300 million yuan, which can save 120 million yuan , saving about 30% of the cost.

本发明中净化处理的气体,可以是工业燃煤产生的烟气,也可以其它需要净化的气体。 The gas to be purified in the present invention can be flue gas produced by industrial coal combustion, or other gases that need to be purified.

本发明的有益效果是: The beneficial effects of the present invention are:

同时具有对流吸附技术和错流吸附技术的优点,脱硫、脱硝效率高、床层阻力小、活性焦吸收饱和度大、循环量小损耗小、再生能耗低、吸收塔内空间利用率高、建造成本低。 At the same time, it has the advantages of convective adsorption technology and cross-flow adsorption technology, high desulfurization and denitrification efficiency, small bed resistance, large absorption saturation of activated coke, small circulation volume and small loss, low regeneration energy consumption, high space utilization rate in the absorption tower, Low construction cost.

附图说明 Description of drawings

图1是错流吸附技术结构原理图; Figure 1 is a schematic diagram of the cross-flow adsorption technology structure;

图2是对流吸附技术结构原理图; Figure 2 is a schematic diagram of the convective adsorption technology structure;

图3是本发明实施例一的结构示意图; Fig. 3 is a schematic structural view of Embodiment 1 of the present invention;

图4是本发明实施例一沿A-A方向左视图; Fig. 4 is a left view along the direction A-A of Embodiment 1 of the present invention;

图5是本发明实施例一沿B-B方向右视图; Fig. 5 is a right view along the B-B direction of Embodiment 1 of the present invention;

图6是本发明实施例一的进气口挡料装置结构示意图; Fig. 6 is a schematic structural view of the air inlet stopper device according to Embodiment 1 of the present invention;

图7是本发明实施例一的出气口挡料装置结构示意图; Fig. 7 is a schematic structural view of the air outlet blocking device according to Embodiment 1 of the present invention;

图8是本发明实施例一单元活性焦炭床层结构比例示意图; Fig. 8 is a schematic diagram of the proportion of a unit activated coke bed structure in the embodiment of the present invention;

图9是本发明实施例二的进料结构示意图; Fig. 9 is a schematic diagram of the feed structure of Embodiment 2 of the present invention;

图10是本发明实施例三的出料结构示意图; Fig. 10 is a schematic diagram of the discharge structure of Embodiment 3 of the present invention;

附图中,各标号所代表的部件列表如下: In the accompanying drawings, the list of parts represented by each label is as follows:

1、单元进料口  2、单元活性焦炭床层  3、单元气体进口  4、单元出料口  5、单元排料口 6、气体总进口  7、进口气体通道 8、储料仓  9、气体总出口  10、单元气体出口 11、封板12、层流隔板  13、出气口挡料装置  14、进气口挡料装置  15、排料口推料器   16、总进料口  17、单元进料口通道  18、单元出料口通道  19、出口气体通道  20、总出料口  21、主进料通道  22、一级出料通道  23、二级进料通道  24、新鲜吸附剂进口  25、吸附饱和的吸附剂出口  26、气体进口  27、气体出口  28、吸附饱和度大的吸附剂  29、较为新鲜的吸附剂  30、吸附饱和的吸附剂  31、活性焦吸附剂储仓  32、吸附剂均匀分布装置  33、吸附剂床层  34、吸附剂出料口和气体进口气体分布器  35、吸附剂下料装置  36、气体进口密封隔板车  37、出料控制器  38、出料储仓  39、吸附饱和后的吸附剂放料口 1. Unit inlet 2. Unit activated coke bed 3. Unit gas inlet 4. Unit outlet 5. Unit discharge port 6. Gas inlet 7. Inlet gas channel 8. Storage bin 9. Gas outlet 10. Unit gas outlet 11. Sealing plate 12. Laminar flow partition 13. Air outlet stopper device 14. Air inlet stopper device 15. Discharge port pusher 16. Total feed port 17. Unit feed port Channel 18, unit outlet channel 19, outlet gas channel 20, total outlet 21, main feed channel 22, primary discharge channel 23, secondary feed channel 24, fresh adsorbent inlet 25, adsorption saturated Adsorbent outlet 26, gas inlet 27, gas outlet 28, adsorbent with high adsorption saturation 29, relatively fresh adsorbent 30, saturated adsorbent 31, activated coke adsorbent storage bin 32, adsorbent uniform distribution device 33 , Adsorbent bed 34. Adsorbent outlet and gas inlet gas distributor 35. Adsorbent feeding device 36. Gas inlet sealing partition car 37. Discharge controller 38. Discharge storage bin 39. After adsorption saturation Adsorbent discharge port

具体实施方式 Detailed ways

以下结合附图对本发明的原理和特征进行描述,所举实例只用于解释本发明,并非用于限定本发明的范围。 The principles and features of the present invention are described below in conjunction with the accompanying drawings, and the examples given are only used to explain the present invention, and are not intended to limit the scope of the present invention.

如图3所示,吸收塔的顶部设置有总进料口16,总进料口的下方设有储料仓8,储料仓8内存放有新鲜的活性焦炭,吸收塔上部设置有气体总出口9,吸收塔的底部设置有总出料口20、气体总进口6。 As shown in Figure 3, the top of the absorption tower is provided with a total feed port 16, and the bottom of the total feed port is provided with a storage bin 8, fresh activated coke is stored in the storage bin 8, and the upper part of the absorption tower is provided with a gas collector. Outlet 9, the bottom of the absorption tower is provided with a total discharge port 20 and a total gas inlet 6.

吸收塔内设置有活性焦炭床层,活性焦炭床层为倾斜的,活性焦炭床层由多个倾斜的单元活性焦炭床层2构成,每个单元活性焦炭床层2之间通过层流隔板12而被分隔开来。各单元活性焦炭床层2之间相互平行,每个单元活性焦炭床层2与垂直线之间的夹角为45°,也可以将单元活性焦炭床层2与垂直线之间的夹角α设置成范围是35°≤α≤65°的其它角度,以保证活性焦炭能靠重力向下流动。 There is an activated coke bed in the absorption tower, the activated coke bed is inclined, and the activated coke bed is composed of a plurality of inclined unit activated coke beds 2, and each unit activated coke bed 2 is passed through a laminar flow partition 12 were separated. Each unit activated coke bed 2 is parallel to each other, and the angle between each unit activated coke bed 2 and the vertical line is 45°, and the angle α between the unit activated coke bed 2 and the vertical line can also be It is set to other angles in the range of 35°≤α≤65° to ensure that the activated coke can flow downward by gravity.

单元活性焦炭床层2的斜下方设置有均匀分布的单元气体进口3,所述单元气体进口3与气体总进口6之间设有进口气体通道7。单元气体进口3位于吸收塔侧部,烟气通过气体总进口6进入进口气体通道7,然后分别通过单元气体进口3进入单元活性炭床层2。单元活性焦炭床层2的斜上方设置有均匀分布的单元气体出口10,所述单元气体出口10与气体总出口9之间设有出口气体通道19。净化后的气体被集中在出口气体通道19中,由气体总出口9排出。 Uniformly distributed unit gas inlets 3 are arranged obliquely below the unit activated coke bed 2 , and an inlet gas channel 7 is provided between the unit gas inlet 3 and the total gas inlet 6 . The unit gas inlet 3 is located at the side of the absorption tower, and the flue gas enters the inlet gas channel 7 through the gas main inlet 6, and then enters the unit activated carbon bed 2 through the unit gas inlet 3 respectively. Uniformly distributed unit gas outlets 10 are arranged obliquely above the unit activated coke bed 2 , and an outlet gas channel 19 is provided between the unit gas outlet 10 and the gas main outlet 9 . The purified gas is collected in the outlet gas channel 19 and discharged from the gas outlet 9 .

单元活性焦炭床层2的斜上方设置有单元进料口1,单元进料口1通过单元进料口通道17与位于总进料口16下方的储料仓8相连接,也可不设储料仓,即单元进料口直接与总进料口相连接。单元活性焦炭床层2的斜下方设置有单元出料口4,单元出料口4与位于吸收塔底部的总出料口20通过单元出料口通道18相连接,每个单元出料口通道18的末端,即为单元排料口5。 A unit feed port 1 is arranged obliquely above the unit activated coke bed 2, and the unit feed port 1 is connected to the storage bin 8 located below the total feed port 16 through the unit feed port channel 17, or no storage is required. The warehouse, that is, the unit feed port is directly connected with the total feed port. A unit discharge port 4 is arranged obliquely below the unit activated coke bed 2, and the unit discharge port 4 is connected with the total discharge port 20 at the bottom of the absorption tower through the unit discharge port channel 18, and each unit discharge port channel The end of 18 is the unit discharge opening 5.

在单元排料口5上设置有排料控制装置,既排料口推料器15,排料口推料器15是一卸料装置,排料口推料器15移动速度快时下料量就少,移动慢时下料量就多,以此来控制单元排料口5的下料量。当排料口推料器15停在单元排料口5正下方时,单元排料口5停止下料。排料口推料器15可用于控制每个单元活性焦炭床层2出料均匀,避免阻塞或偏流,根据排料口推料器15的推料速度控制每个单元活性焦炭床层2的排料量,并可观察,防止单元活性焦炭床层2因堵塞而不下料。 A discharge control device is arranged on the unit discharge port 5, namely the discharge port pusher 15, the discharge port pusher 15 is a discharge device, and the discharge amount is reduced when the discharge port pusher 15 moves fast. Less, when the movement is slow, the amount of feeding will be more, so as to control the amount of feeding at the discharge port 5 of the unit. When the discharge port pusher 15 stops directly below the unit discharge port 5, the unit discharge port 5 stops blanking. The discharge port pusher 15 can be used to control the uniform discharge of each unit activated coke bed 2, avoid blocking or bias flow, and control the discharge of each unit activated coke bed 2 according to the pushing speed of the discharge port pusher 15. The amount of material can be observed, so as to prevent the unit activated coke bed 2 from being unloaded due to blockage.

封板11在吸收塔的上下两侧,采用平铺的钢板制成,其大小同吸收塔的长和宽相同,它起到密封烟气和支撑塔体的作用。 The sealing plate 11 is made of flat steel plates on the upper and lower sides of the absorption tower, and its size is the same as the length and width of the absorption tower. It plays the role of sealing flue gas and supporting the tower body.

如图4所示,多个单元活性焦炭床层2上下并排分布,每个单元活性焦炭床层2上并列分布着多个单元气体进口3,以及多个单元出料口通道18,单元气体进口3与单元出料口通道18之间呈交错分布。 As shown in Figure 4, a plurality of unit activated coke beds 2 are arranged side by side up and down, and a plurality of unit gas inlets 3 are arranged side by side on each unit activated coke bed 2, and a plurality of unit discharge port passages 18, unit gas inlets 3 and the unit outlet channel 18 in a staggered distribution.

如图5所示,多个单元活性焦炭床层2上下并排分布,每个单元活性焦炭床层2上并列分布着多个单元气体出口10,以及多个单元进料口通道17,单元气体出口10与单元进料口通道17之间呈交错分布。 As shown in Figure 5, a plurality of unit activated coke beds 2 are arranged side by side up and down, and a plurality of unit gas outlets 10 are arranged side by side on each unit activated coke bed 2, and a plurality of unit feed port passages 17, unit gas outlets 10 and the unit feed port channel 17 are distributed in a staggered manner.

如图3所示,单元气体进口3上设有进气口挡料装置14,单元气体出口10上设有出气口挡料装置13。 As shown in FIG. 3 , the unit gas inlet 3 is provided with an air inlet stopper 14 , and the unit gas outlet 10 is provided with an air outlet stopper 13 .

如图6所示,进气口挡料装置14与垂直方向成45度,进气口挡料装置14由位于单元气体进口3四周的挡板构成,其将单元气体进口3的四周包围,进气口挡料装置14可防止活性焦炭在单元气体进口3处漏料。 As shown in Figure 6, the air inlet retaining device 14 is 45 degrees with the vertical direction, and the air inlet retaining device 14 is formed by a baffle plate positioned around the unit gas inlet 3, which surrounds the unit gas inlet 3 to carry out The gas port blocking device 14 can prevent activated coke from leaking at the unit gas inlet 3.

如图7所示,出气口挡料装置13与垂直方向成45度,出气口挡料装置13由位于单元气体出口10四周的挡板构成,其将单元气体出口10的四周包围,出气口挡料装置13可防止活性焦炭在单元气体出口10处漏料。 As shown in Figure 7, the gas outlet blocking device 13 is 45 degrees with the vertical direction, and the gas outlet blocking device 13 is composed of baffles positioned around the unit gas outlet 10, which surrounds the unit gas outlet 10, and the gas outlet blocking The feeding device 13 can prevent activated coke from leaking at the unit gas outlet 10.

如图8所示,单元活性焦炭床层的上下两底面之间的垂直距离为H,单元活性焦炭床层2位于单元气体进口3、单元气体出口10所在的两个侧面之间的水平投影距离为L,所述垂直距离H与水平投影距离L的比值范围是:0.4≤H:L≤2。 As shown in Figure 8, the vertical distance between the upper and lower bottom surfaces of the unit activated coke bed is H, and the unit activated coke bed 2 is located at the horizontal projection distance between the two sides where the unit gas inlet 3 and the unit gas outlet 10 are located is L, the ratio range of the vertical distance H to the horizontal projection distance L is: 0.4≤H:L≤2.

如图3所示,上述分层式倾斜的单元活性焦炭床层结构,在吸收塔内呈对称式分布。 As shown in Figure 3, the layered inclined unit activated coke bed structure is symmetrically distributed in the absorption tower.

进行脱硫、脱硝时,气体从气体总进口6,经过进口气体通道7,再通过单元气体进口3进入每个单元活性焦炭床层2,在倾斜式床层内气体自斜下方至斜上方流动;新鲜的活性焦炭从总进料口16进入储料仓8,由储料仓8经单元进料口通道17进入每个单元活性焦炭床层2,活性焦炭自斜上方至斜下方流动;气体和活性焦炭之间形成充分的斜对流接触后,净化后的气体从单元气体出口10排出,并被集中在出口气体通道19中,由气体总出口9排出;吸附饱和后的活性焦炭自单元出料口4排出,经过单元出料口通道18,从总出料口20排出。 When performing desulfurization and denitrification, the gas enters the activated coke bed 2 of each unit from the gas inlet 6 through the inlet gas passage 7, and then enters the activated coke bed 2 of each unit through the unit gas inlet 3, and the gas flows from obliquely below to obliquely above in the inclined bed; Fresh activated coke enters the storage bin 8 from the total feed port 16, and enters each unit activated coke bed 2 through the unit feed port channel 17 from the storage bin 8, and the activated coke flows from obliquely above to obliquely below; gas and After sufficient oblique convective contact is formed between the activated cokes, the purified gas is discharged from the unit gas outlet 10, and is concentrated in the outlet gas channel 19, and is discharged from the gas outlet 9; the saturated activated coke is discharged from the unit Port 4 is discharged, through the unit discharge port channel 18, and discharged from the total discharge port 20.

实施例二 Embodiment two

如图9所示,本实施例与实施例一的不同之处在于,进料结构按如下方式设置:单元活性焦炭床层2的上方设置有单元进料口1,单元进料口1通过单元进料口通道17与一主进料通道21相连接,主进料通道21与位于总进料口16下方的储料仓8相连接。 As shown in Figure 9, the difference between this embodiment and Embodiment 1 is that the feed structure is set as follows: a unit feed port 1 is provided above the unit activated coke bed 2, and the unit feed port 1 passes through the unit The feeding port channel 17 is connected with a main feeding channel 21 , and the main feeding channel 21 is connected with the storage bin 8 located below the main feeding port 16 .

实施例三 Embodiment Three

如图10所示,本实施例与实施例一的不同之处在于,出料结构按如下方式设置:单元活性焦炭床层2的下方设置有单元出料口1,多个单元出料口1可分为若干小组,各组单元出料口1通过单元出料口通道18与一级出料通道22相连接,上述的多个一级出料通道22通过二级出料通道23与总出料口20相连接。根据单元活性焦炭床层的数量,还可以在二级出料通道23与总出料口20之间设置三级出料通道或三级以上的出料通道。 As shown in Figure 10, the difference between this embodiment and Embodiment 1 is that the discharge structure is set as follows: a unit discharge port 1 is provided below the unit activated coke bed 2, and a plurality of unit discharge ports 1 It can be divided into several groups, each group of unit outlets 1 is connected with the primary discharge channel 22 through the unit discharge channel 18, and the above-mentioned multiple primary discharge channels 22 are connected with the total discharge channel 23 through the secondary discharge channel 23. The feed port 20 is connected. According to the quantity of the unit activated coke bed, a tertiary discharge channel or more than three discharge channels can also be set between the secondary discharge channel 23 and the total discharge port 20 .

在本发明的各实施例中,每个单元活性焦炭床层设置独立的进料口和出料口以保证每个吸收单元的吸收效率。在每个单元活性焦炭床层内,活性焦炭自斜上方向斜下方流动,气体自斜下方向斜上方流动,逆流接触吸附,每个单元出料口处的吸附剂全部达到吸附饱和状态,每个单元气体出口的气体吸附效率相同,采用侧面进气,进气面积较大、床层阻力较小。本发明同时具有逆流吸附技术和错流吸附技术的优点,脱硫、脱硝效率高、床层阻力小、活性焦吸收饱和度大、循环量小损耗小、再生能耗低、塔内空间利用率高、建造成本低。 In each embodiment of the present invention, each unit activated coke bed is provided with an independent feed inlet and outlet to ensure the absorption efficiency of each absorption unit. In each unit of activated coke bed, activated coke flows from obliquely upward to obliquely downward, gas flows from obliquely downward to upward, countercurrent contact adsorption, and the adsorbent at the outlet of each unit reaches the adsorption saturation state. The gas adsorption efficiency of the gas outlets of each unit is the same, and the side air intake is adopted, the air intake area is larger, and the bed resistance is smaller. The present invention has the advantages of both countercurrent adsorption technology and cross-flow adsorption technology, high desulfurization and denitrification efficiency, small bed resistance, high absorption saturation of activated coke, small circulation volume, low loss, low regeneration energy consumption, and high space utilization rate in the tower , Low construction cost.

以上所述仅为本发明的实施方式,并非因此即限制本发明的专利范围,凡是运用本发明说明书及附图内容所作的等效变换,直接或间接运用在其它相关的技术领域,均同理包括在本发明的专利范围内。 The above is only the embodiment of the present invention, and does not limit the patent scope of the present invention. All equivalent transformations made by using the description of the present invention and the contents of the accompanying drawings are directly or indirectly used in other related technical fields. included in the patent scope of the present invention.

Claims (10)

1.一种活性焦炭气体净化装置,包括位于吸收塔上部的总进料口、气体总出口,吸收塔下部的总出料口、气体总进口,以及位于吸收塔内的活性焦炭床层,其特征在于,所述的活性焦炭床层为倾斜的,其与水平面的垂直线之间呈一夹角α,所述的活性焦炭床层通过层流隔板被分隔为多个倾斜单元活性焦炭床层,所述单元活性焦炭床层的下方设置有单元气体进口,所述单元气体进口与气体总进口之间设有进口气体通道;所述单元活性焦炭床层的上方设置有单元气体出口,所述单元气体出口与气体总出口之间设有出口气体通道;所述单元活性焦炭床层的上方设置有单元进料口,所述单元进料口通过单元进料口通道与总进料口相连接;所述单元活性焦炭床层的下方设置有单元出料口,所述单元出料口通过单元出料口通道与总出料口相连接。 1. A kind of activated coke gas purifying device, comprise the total feed inlet that is positioned at absorption tower top, gas total outlet, the total discharge port of absorption tower bottom, gas total inlet, and be positioned at the activated coke bed layer in absorption tower, its It is characterized in that, the described activated coke bed is inclined, and forms an included angle α between it and the vertical line of the horizontal plane, and the described activated coke bed is divided into a plurality of inclined unit activated coke beds by laminar flow partitions layer, the unit gas inlet is arranged below the unit activated coke bed, and an inlet gas channel is arranged between the unit gas inlet and the gas total inlet; a unit gas outlet is arranged above the unit activated coke bed, so An outlet gas channel is provided between the unit gas outlet and the total gas outlet; a unit feed port is arranged above the unit activated coke bed, and the unit feed port communicates with the total feed port through the unit feed port channel Connection; a unit discharge port is provided below the unit activated coke bed, and the unit discharge port is connected to the general discharge port through a channel of the unit discharge port. 2.根据权利要求1所述的活性焦炭气体净化装置,其特征在于,所述单元进料口通道与总进料口之间设置有储料仓。 2. The activated coke gas purification device according to claim 1, characterized in that, a storage bin is arranged between the unit feed port channel and the general feed port. 3.根据权利要求1所述的活性焦炭气体净化装置,其特征在于,所述单元活性焦炭床层的上方设置有单元进料口,所述单元进料口通过单元进料口通道与主进料通道相连接,主进料通道与总进料口相连接。 3. activated coke gas purifying device according to claim 1, is characterized in that, the top of described unit activated coke bed is provided with unit feed port, and described unit feed port passes through unit feed port channel and main feed The feed channel is connected, and the main feed channel is connected with the total feed port. 4.根据权利要求3所述的活性焦炭气体净化装置,其特征在于,所述主进料通道与总进料口之间设置有储料仓。 4. The activated coke gas purification device according to claim 3, characterized in that, a storage bin is arranged between the main feed channel and the main feed port. 5.根据权利要求1所述的活性焦炭气体净化装置,其特征在于,所述单元活性焦炭床层的下方设置有单元出料口,所述多个单元出料口可分为若干小组,各组单元出料口通过单元出料口通道与一级出料通道相连接,所述的多个一级出料通道通过二级出料通道与总出料口相连接。 5. activated coke gas purification device according to claim 1, is characterized in that, the below of described unit activated coke bed is provided with unit outlet, and described multiple unit outlet can be divided into some groups, each The group unit discharge port is connected to the first-stage discharge channel through the unit discharge port channel, and the multiple primary discharge channels are connected to the general discharge port through the secondary discharge channel. 6.根据权利要求5所述的活性焦炭气体净化装置,其特征在于,根据单元活性焦炭床层的数量,在二级出料通道与总出料口之间设置三级出料通道或三级以上的出料通道。 6. The activated coke gas purification device according to claim 5, characterized in that, according to the number of unit activated coke beds, a three-stage discharge channel or a three-stage discharge channel is set between the secondary discharge channel and the total discharge port. above the discharge channel. 7.根据权利要求1所述的活性焦炭气体净化装置,其特征在于,所述单元活性焦炭床层的上下两底面之间的垂直距离为H,所述单元活性焦炭床层的单元进气口和单元出气口所在的两个侧面之间的水平投影距离为L,所述垂直距离H与水平投影距离L的比值范围是:0.4≤H:L≤2。 7. activated coke gas purification device according to claim 1, is characterized in that, the vertical distance between the upper and lower bottom surfaces of the unit activated coke bed is H, and the unit air inlet of the unit activated coke bed The horizontal projection distance between the two sides where the air outlet of the unit is located is L, and the ratio range of the vertical distance H to the horizontal projection distance L is: 0.4≤H:L≤2. 8.根据权利要求1所述的活性焦炭气体净化装置,其特征在于,所述夹角α的范围是:35°≤α≤65°。 8. The activated coke gas purification device according to claim 1, characterized in that, the range of the included angle α is: 35°≤α≤65°. 9.根据权利要求1所述的活性焦炭气体净化装置,其特征在于,所述的单元气体进口上设有进气口挡料装置;进气口挡料装置与水平面垂直方向成45度角,进气口挡料装置由位于单元气体进口四周的挡板构成。 9. The activated coke gas purification device according to claim 1, characterized in that, said unit gas inlet is provided with an air inlet retaining device; the air inlet retaining device forms an angle of 45 degrees with the vertical direction of the horizontal plane, The gas inlet blocking device is composed of baffles located around the unit gas inlet. 10.根据权利要求1所述的活性焦炭气体净化装置,其特征在于,所述的单元气体出口上设有出气口挡料装置;出气口挡料装置与水平面垂直方向成45度角,出气口挡料装置由位于单元气体出口四周的挡板构成。 10. The activated coke gas purification device according to claim 1, characterized in that, said unit gas outlet is provided with a gas outlet blocking device; the gas outlet blocking device forms an angle of 45 degrees with the vertical direction of the horizontal plane, and the gas outlet The blocking device consists of baffles located around the gas outlet of the unit.
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