CN101310599B - Rice direct seeding field mixed herbicide - Google Patents
Rice direct seeding field mixed herbicide Download PDFInfo
- Publication number
- CN101310599B CN101310599B CN2008100974094A CN200810097409A CN101310599B CN 101310599 B CN101310599 B CN 101310599B CN 2008100974094 A CN2008100974094 A CN 2008100974094A CN 200810097409 A CN200810097409 A CN 200810097409A CN 101310599 B CN101310599 B CN 101310599B
- Authority
- CN
- China
- Prior art keywords
- penoxsuam
- pyrazosulfuron
- mixed herbicide
- agent
- rice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004009 herbicide Substances 0.000 title claims abstract description 63
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 51
- 235000009566 rice Nutrition 0.000 title claims abstract description 51
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 44
- 238000010899 nucleation Methods 0.000 title claims abstract description 12
- 240000007594 Oryza sativa Species 0.000 title description 44
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 8
- 241000209094 Oryza Species 0.000 claims abstract 7
- VXMNDQDDWDDKOQ-UHFFFAOYSA-N Pyrazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C(O)=O)C)=N1 VXMNDQDDWDDKOQ-UHFFFAOYSA-N 0.000 claims description 57
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 238000009736 wetting Methods 0.000 claims description 14
- -1 alkyl ethyl sulfonate Chemical compound 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000000080 wetting agent Substances 0.000 claims description 10
- 230000000740 bleeding effect Effects 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- 235000012216 bentonite Nutrition 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 abstract description 50
- 239000000375 suspending agent Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 6
- 238000009333 weeding Methods 0.000 abstract description 6
- 239000000575 pesticide Substances 0.000 abstract description 4
- BGNQYGRXEXDAIQ-UHFFFAOYSA-N Pyrazosulfuron-ethyl Chemical group C1=NN(C)C(S(=O)(=O)NC(=O)NC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OCC BGNQYGRXEXDAIQ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004563 wettable powder Substances 0.000 abstract 1
- 241000192043 Echinochloa Species 0.000 description 37
- 244000025254 Cannabis sativa Species 0.000 description 36
- 239000000463 material Substances 0.000 description 36
- 239000003814 drug Substances 0.000 description 33
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 19
- 230000003449 preventive effect Effects 0.000 description 18
- 239000000203 mixture Substances 0.000 description 14
- 229920003266 Leaf® Polymers 0.000 description 13
- 239000002131 composite material Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 238000009331 sowing Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 238000012545 processing Methods 0.000 description 9
- 230000002195 synergetic effect Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 241000234653 Cyperus Species 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000005469 granulation Methods 0.000 description 6
- 230000003179 granulation Effects 0.000 description 6
- 230000002401 inhibitory effect Effects 0.000 description 6
- 229940100389 Sulfonylurea Drugs 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 5
- 235000012424 soybean oil Nutrition 0.000 description 5
- 239000003549 soybean oil Substances 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 240000007038 Lindernia dubia Species 0.000 description 4
- 240000000178 Monochoria vaginalis Species 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 230000000857 drug effect Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 229940124530 sulfonamide Drugs 0.000 description 4
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 244000150195 Cyperus longus Species 0.000 description 3
- 235000018109 Cyperus longus Nutrition 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 239000006184 cosolvent Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000005304 joining Methods 0.000 description 3
- 208000037805 labour Diseases 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 3
- 229940073769 methyl oleate Drugs 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- 241001290610 Abildgaardia Species 0.000 description 2
- 239000005472 Bensulfuron methyl Substances 0.000 description 2
- LPXYXBZAXFTFKH-UHFFFAOYSA-N ClC=1C(=C(C(=NC1)C(=O)O)C(=O)O)Cl Chemical compound ClC=1C(=C(C(=NC1)C(=O)O)C(=O)O)Cl LPXYXBZAXFTFKH-UHFFFAOYSA-N 0.000 description 2
- 244000286838 Eclipta prostrata Species 0.000 description 2
- 241001108764 Ludwigia sphaerocarpa Species 0.000 description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
- 241001148683 Zostera marina Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000002420 orchard Substances 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical class CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- NXQDBZGWYSEGFL-UHFFFAOYSA-N Anilofos Chemical compound COP(=S)(OC)SCC(=O)N(C(C)C)C1=CC=C(Cl)C=C1 NXQDBZGWYSEGFL-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005502 Cyhalofop-butyl Substances 0.000 description 1
- TYIYMOAHACZAMQ-CQSZACIVSA-N Cyhalofop-butyl Chemical group C1=CC(O[C@H](C)C(=O)OCCCC)=CC=C1OC1=CC=C(C#N)C=C1F TYIYMOAHACZAMQ-CQSZACIVSA-N 0.000 description 1
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 241000234642 Festuca Species 0.000 description 1
- 241000931143 Gleditsia sinensis Species 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 241000209510 Liliopsida Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 241000091577 Mexicana Species 0.000 description 1
- 241000169076 Monochoria korsakowii Species 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 239000005592 Penoxsulam Substances 0.000 description 1
- SYJGKVOENHZYMQ-UHFFFAOYSA-N Penoxsulam Chemical compound N1=C2C(OC)=CN=C(OC)N2N=C1NS(=O)(=O)C1=C(OCC(F)F)C=CC=C1C(F)(F)F SYJGKVOENHZYMQ-UHFFFAOYSA-N 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000090 biomarker Substances 0.000 description 1
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical group OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 1
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000012364 cultivation method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000000442 meristematic effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 238000000611 regression analysis Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229940117013 triethanolamine oleate Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Abstract
The invention pertains to the technical field of pesticides and relates to a mixed herbicide used in direct-seeding rice fields. The mixed herbicide is characterized in that the mixed herbicide contains penoxsuam and pyrazosulfuron-ethyl and the effective components of the mixed herbicide are as follows according to percentage by weight: 0.1 percent to 50 percent of the penoxsuam and 0.2 percent to 50 percent of the pyrazosulfuron-ethyl. The mixed herbicide can be prepared into an oil-based suspending agent, a water dispersible granule and a wettable powder. The mixed herbicide is used for preventing and weeding weeds in the direct-seeding rice fields with obvious weeding effect, is safe for rice and has wide extension in weeding and obvious synergism.
Description
Technical field the invention belongs to chemical pesticide, is specifically related to a kind of complex weedicide that is used to prevent and kill off rice direct-seeding Tanaka weeds.
Background technology is according to FAO (Food and Agriculture Organization of the United Nation), about 50,000 kinds of whole world weeds sum, wherein there are 8000 kinds to be farmland weed, and harm about 250 kinds of staple food crop, according to statistics in 1972, the whole world reaches 20,400,000,000 dollars because of crop smothering causes crop failure every year, this shows that the harm of crop smothering is on the rise, becomes the key factor that influences crop yield.Use chemical herbicide not only can save large quantities of labours, raise labour productivity, and make that weeds obtain removing between the seedling that common mechanical is difficult to remove, make mechanization further perfect, traditional tillage and cultivation method also is improved.Therefore, the research of chemical herbicide and application more and more are subject to people's attention, and according to relevant department of the United Nations statistics, the sales volume of chemical herbicide proportion in the pesticide producing amount increases year by year, and the area of using weed killer herbicide is also in continuous expansion.From american agriculture production operation process: artificial weeding accounts for 50%, and weeding by machine accounts for 40%, and chemical weed control accounts for 55%, and visible chemical weed control is occupied an leading position in agricultural, and it is necessary researching and developing novel, efficient chemical herbicide.The use of agricultural chemicals plays an important role for the volume increase of world food and the improvement of people's living standard.Along with the development of agricultural cience and farming techniques, the use of chemical agent has become one of mode of increasing crop yield.
In recent years, Direct-seeding Rice is owing to saving of labor, abridged edition, reduce the generation of stripe virus disease seedling stage, and the spontaneous cultivated area of peasant is increasing, and the increasing transplant fields that replace are promoted rapidly in a lot of areas, but crop smothering is the major obstacle that influences its high yield, stable yields.The reason that crop smothering is on the rise is: direct sowing rice field is because growth is big for the space of weed growth early stage, and the rice field alternation of wetting and drying also helps weeds to be taken place, and this makes the crop smothering problem particularly outstanding.On the other hand, because rice paddy seed is very responsive to weed killer herbicide when sprouting, therefore can be of less types at the weed killer herbicide that use in live field, probe into direct sowing rice field safety, weed killer herbicide is particularly important efficiently.
The barnyard grass grass is the topmost monocotyledon weed of paddy field, and damaging range is often extensive from south to north African, generally occurs in each period of paddy growth, and its control is the main difficult problem of paddy field prevention and control of weeds always.At present, the topmost closed soil type control of paddy field barnyard grass grass with medicament main component has butachlor, the third careless amine, cauline leaf is handled low age barnyard grass grass weed killer herbicide main component anilofos, molinate, cauline leaf is handled above the average age for marriage barnyard grass grass weed killer herbicide main component dichloro quinolinic acid etc., but more or less there are a little problems in these weed killer herbicides, as the recessive drug injury problem of acetamide-group herbicides to rice seedling, most of cauline leafs processing remove the barnyard grass agent can only prevent and treat 2-3 leaf age barnyard grass grass in the past, dichloro quinolinic acid can be prevented and treated above the average age for marriage barnyard grass grass but paddy rice be existed the risk of poisoning, these remove the barnyard grass agent in the continuous use of China for many years in addition, and decline of a lot of local reflection drug effects even discovery barnyard grass grass have produced resistance to it.Bensulfuron-methyl and pyrazosulfuron are the main weed killer herbicides of domestic and international direct sowing rice field control nutgrass flatsedge and broad leaved weed, but because long-term use continuously, rice field main weeds such as difformed galingale herb, firefly Lin, arrowhead, Monochoria korsakowii, Monochoria vaginalis, Procumbent Falsepimpernel resistance in various degree occurred to sulfonylurea herbicides such as bensulfuron-methyls.In a word, market demand is to rice safety, can prevent and treat the weed killer herbicide of above the average age for marriage barnyard grass grass and resistance barnyard grass grass again.Under such background, The Dow Agrosciences, LLC. has introduced China in 2005 with rice outstanding person (penoxsuam) 25g/L oil-suspending agent just.This medicament has good control efficiency to above the average age for marriage barnyard grass grass, but the use cost of this medicament is higher, has limited the large tracts of land of this medicament and has used.Therefore, the use that with penoxsuam and another kind of mixture of herbicides, improve drug effect, reduce usage amount, enlarges this medicament is a urgent problem in producing at present.
(5,8-dimethoxy (1,2,4) triazole-(1,5-C) pyrimidine-2-base)-6-trifluoromethyl-benzene sulfanilamide (SN) belongs to triazolopyrimidine sulfonamides herbicide to penoxsuam (penoxsulam) chemical name: 2-(2,2-difluoro ethoxy)-N-.Work by suppressing the acetyl-lactic acid ester synzyme, medicine absorbs via grass cutting blade, leaf sheath or root, conducts to meristematic tissue, causes weed growth to stop, and yellow is dead then.Be used to prevent and treat the rice direct seeding field annual weed, to barnyard grass grass super-high-efficient, but to the anti-heterodyne of part grassy weed, nutgrass flatsedge and broadleaved herb.This medicament action target is acetolactate synthestase (ALS), the weeds of anti-sulfonylurea herbicide significantly are lower than other sulfonylurea medicaments the cross resistance level of triazolopyrimidine sulfonamides herbicide according to the literature, and the activity of weeding of penoxsuam and other ALS inhibitor also have notable difference, so penoxsuam is the comparatively ideal weed killer herbicide of control weeds in paddy field.
Pyrazosulfuron (pyrazosulfuron-ethyl) chemical name is: 5-(4,6-dimethoxypyridin base-2-carbamyl amine sulphonyl)-1-methylpyrazole base-4-Ethyl formate, belong to sulfonylurea herbicide, and be a kind of selectivity inner sucting conduction type weed killer herbicide.Can be absorbed by root of weeds and blade, and conduction rapidly in vivo, it is synthetic to suppress weeds amino acid, makes the very fast stasi of its bud and root.Be mainly used in transplanting rice field, rice seedling bed and direct sowing rice field and prevent and kill off annual weed and part perennial weeds such as Monochoria vaginalis, mexicana, Procumbent Falsepimpernel, fescue, difformed galingale herb.The barnyard grass grass there is strong inhibitory action, broad leaved weed is had special efficacy.To rice safety.Preceding or the seedling post processing of bud, preventive effect is very high, its active bensulfuron-methyl that surpasses.But the preventive effect to the barnyard grass grass is relatively poor.
By pertinent literature retrieval, domestic relevant patent documentation and the report that penoxsuam and pyrazosulfuron are arranged respectively.Application number is that 200680004602.8 patent of invention discloses the penoxsuam as turfgrass, vineyard and orchard ground weed killer herbicide, is used for controlling broad leaved weed and nutgrass flatsedge in turfgrass and vine and the bottom surface, orchard.Application number is that 200510117353.0 patent of invention discloses pyrazosulfuron and the composite a kind of weed killer herbicide made of cyhalofop-butyl.Pyrazosulfuron is compared with other sulfonylurea herbicides, and outstanding feature is that broad leaved weed is had special efficacy, and active high.Penoxsuam and pyrazosulfuron list are a lot of not enough with existing, it is wide inadequately to kill the grass spectrum, two kinds of weed killer herbicide lists are with all there being the part weeds not prevent and kill off, single higher with the penoxsuam cost, when the peasant uses in the mixing of two kinds of preparations, grasp all being difficult on using method, operation, the consumption, the dispenser that leads to errors exerts an influence to paddy rice.Barnyard grass grass generating capacity in recent years heightens, and main cause is that general rice field weed killer herbicide commonly used is invalid to it.Penoxsuam is to barnyard grass grass preventive effect excellence, but penoxsuam is to the anti-heterodyne of Procumbent Falsepimpernel, false loosestrife and Eclipta prostrata.Pyrazosulfuron has only inhibitory action to the barnyard grass grass.Can replenish mutually after penoxsuam and pyrazosulfuron be mixed and enlarge herbicidal spectrum, remedy penoxsuam to Procumbent Falsepimpernel, false loosestrife and Eclipta prostrata preventive effect shortcoming on the low side as pyrazosulfuron.Through the demonstration checking, penoxsuam and pyrazosulfuron complex weedicide just can be annihilated for 1 time the multiple main weeds dispenser in rice field, to rice seedling safety, are worth promoting.Therefore, we carry out penoxsuam and pyrazosulfuron composite, are used for preventing and treating grassy weed, nutgrass flatsedge and the broad leaved weeds such as above the average age for marriage barnyard grass grass of direct sowing rice field.
Summary of the invention the objective of the invention is to the shortcoming at prior art, provides that a kind of herbicidal effect is good, broad weed-killing spectrum, security performance height, production-increasing function is remarkable, dispenser is convenient, toxicity is low complex weedicide.
The technical scheme that realizes the object of the invention is:
A kind of complex weedicide contains penoxsuam and pyrazosulfuron.
Above-mentioned complex weedicide contains penoxsuam 0.1%～50%, pyrazosulfuron 0.2%～50%.
Above-mentioned complex weedicide, its oil suspending agent constituent and percentage by weight thereof are: penoxsuam 0.1%～30%, pyrazosulfuron 0.2%～20%, wetting agent 0.2%～8%, dispersant 0.1%～10%, stabilizing agent 0.2%～6%, thickener 0.2%～5%, antifreezing agent 0.05%～4%, defoamer 0.2%～5%, cosolvent 1%～6%, solvent 1%～90%.Each component sum is 100%.
Said herbicidal composition, its water-dispersible granules constituent and percentage by weight thereof are: penoxsuam 0.5%～15%, pyrazosulfuron 0.2%～20%, wetting agent 1%～20%, dispersant 1%～15%, spreader-sticker 1%～5%, stabilizing agent 0%～2%, bleeding agent 1%～10%, filler 10%～80%.Each component sum is 100%.
Above-mentioned complex weedicide, its wetting powder constituent and percentage by weight thereof are: penoxsuam 0.5%～20%, pyrazosulfuron 0.2%～25%, wetting agent 1%～10%, dispersant 1%～20%, spreader-sticker 0.1%～10%, bleeding agent 1%～15%, filler 5%～85%.Each component sum is 100%.
Wetting agent described in the above-mentioned complex weedicide is that neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, aliphatic alcohol sulfate, alkylaryl sulfonates, naphthalene sulfonic acid-formaldehyde condensation product, phenethyl phenol polyethenoxy ether, Nonyl pheno base ether, tea are withered, among the Chinese honey locust etc. one or more.
Dispersant described in the above-mentioned complex weedicide is one or more in lignosulfonates, alkylbenzenesulfonate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, Nonyl pheno base ether, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and the polycarboxylic acid.
Spreader-sticker described in the above-mentioned complex weedicide is one or more in polyvinyl alcohol, alkyl diphenyl ether disulphonic acid sodium, poly-trisiloxanes, the triethanolamine oleate.
Stabilizing agent described in the above-mentioned complex weedicide be in epoxidized vegetable oil such as epoxidized linseed, the epoxidized soybean oil one or more.
Bleeding agent described in the above-mentioned complex weedicide is one or more in sorbitan fatty acid ester APEO, aliphatic alcohol polyethenoxy base ether or the Nonyl pheno base ether.
Thickener described in the above-mentioned complex weedicide be polyvinyl alcohol, carboxymethyl cellulose or xanthans etc. one or more.
Antifreezing agent described in the above-mentioned complex weedicide is one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite.
Defoamer described in the above-mentioned complex weedicide is silicone based, as Si18, S-29, FZ-880 etc. one or more.
Cosolvent described in the above-mentioned complex weedicide is one or more in methyl alcohol, ethanol, acetone, DMF, acetonitrile, methyl-sulfoxide, pyrrolidones, the trichloroethanes.
Solvent described in the above-mentioned complex weedicide is one or more in soybean oil, rapeseed oil, cottonseed oil, Semen Ricini oil, turpentine oil, enriching vegetable oil, sunflower oil, paraffin oil, methyl oleate, the senior fatty hydrocarbon ils of methyl naphthalene.
Filler described in the above-mentioned complex weedicide is one or more in kaolin, bentonite, talcum powder, precipitated calcium carbonate, white carbon, diatomite, potter's clay, attapulgite, atlapulgite, the gypsum.
Above-mentioned complex weedicide, its described formulation can be oil suspending agent, water-dispersible granules, wetting powder.
The production method of above-mentioned complex weedicide oil suspending agent is: in proportion penoxsuam, the former medicine of pyrazosulfuron are joined in the reactor with wetting agent, dispersant, stabilizing agent, thickener, antifreezing agent, defoamer, cosolvent, solvent, stirred 2 hours, open baiting valve at the bottom of the still, material is injected sand mill to be ground, material fineness after the grinding reaches 98% by discharging behind 325 mesh standard sieves, material is put in the high-shear emulsifying still again, promptly gets herbicidal composition oil suspending agent of the present invention after the emulsification.
The production method of above-mentioned complex weedicide wetting powder is: in proportion penoxsuam, pyrazosulfuron are joined in the tapered mixer with wetting agent, dispersant, spreader-sticker, bleeding agent, filler and mix more than 2 hours, mixed material joined in the airslide disintegrating mill pulverize, material after the pulverizing joins in the tapered mixer again and mixed 2 hours, mixed material fineness reaches 98% by 325 mesh standard sieves, require to detect according to product quality, require to make the wetting powder that meets standard-required according to product standard.
The production method of above-mentioned complex weedicide water-dispersible granules is: in proportion penoxsuam, pyrazosulfuron are joined in the tapered mixer with wetting agent, dispersant, spreader-sticker, stabilizing agent, bleeding agent, filler and mix more than 2 hours, mixed material joined in the airslide disintegrating mill pulverize, material after the pulverizing joins in the tapered mixer again and mixed 2 hours, mixed material fineness reaches 98% by 325 mesh standard sieves, obtains wetting powder.Then with wetting powder and quantitative purified water; add in the kneader simultaneously and mediate; make the material of shaping; put this material in Squeezinggranulator granulation at last, the product after the granulation carries out drying in 54 ℃ of baking ovens, dried material; use 10 orders and 60 purpose standard screens to sieve; get the middle material of two sieves, require to detect, require to make the water-dispersible granules that meets standard-required according to product standard according to product quality.
The advantage that the present invention has: carry out two kinds of weed killer herbicides composite, not only herbicidal effect is good, to rice safety, with strong complementarity, and broad weed-killing spectrum, pyrazosulfuron have remedied penoxsuam to part broad-leaved section weeds, sedge weed and part perennial weed weak effect or invalid substantially shortcoming, and be effective to the most main weeds of rice direct seeding field, comprise barnyard grass grass, annual nutgrass flatsedge and many broad leaved weeds, wherein the control efficiency to the barnyard grass grass is particularly outstanding.Improved the lasting period greatly and killed the grass spectrum, above the average age for marriage barnyard grass grass has been had splendid preventive effect.Also significantly reduce cost, only needed a drug, just can prevent and treat the harm of multiple grassy weed, sedge weed and broad leaved weed, and obvious effect of increasing production, excellent rice safety, formulation advanced person, absorb rapidly, resistance of rainwater washing against, social benefit is outstanding.Therefore, penoxsuam and pyrazosulfuron are composite will to be a kind of novelty, practical novel formulation, and this compositely also has a certain practicality simultaneously.
We adopt the interaction between equivalent collimation method evaluation penoxsuam and the pyrazosulfuron to description of drawings in embodiment.Utilize dosage logarithm-probability value method to calculate ED
90Value is drawn ED
90Equivalent line, and by ED
90Equivalent line is estimated two kinds of weed killer herbicide correlations, and obtains best ratio range.
Employed former medicine, auxiliary agent are other producers' purchases in embodiment following examples.
Embodiment 1
With the former medicine of 1.0kg penoxsuam, 5.1kg the former medicine of pyrazosulfuron, the 6kg neopelex, the 6kg polyoxyethylene nonylphenol ether, the 3kg epoxidized soybean oil, 1.5kg carboxymethyl cellulose, 2kg ethylene glycol, 0.5kgS-29 defoamer, 4kg ethanol, the 35.45kg methyl oleate, the 35.45kg soybean oil joins reactor together, stirred 2 hours, open baiting valve at the bottom of the still, material is injected sand mill grind, the material fineness after the grinding reaches 98% by discharging behind 325 mesh standard sieves, material is put in the high-shear emulsifying still again, promptly gets herbicidal composition oil suspending agent of the present invention after the emulsification.
Embodiment 2
With the former medicine of 1.0kg penoxsuam, 6.2kg former medicine of pyrazosulfuron and 12kg neopelex, the 10kg sodium lignin sulfonate, the 2kg polyvinyl alcohol, 2kg lauryl alcohol polyethylene glycol oxide base ether, 33.4kg kaolin, 33.4kg bentonite, joining together in the tapered mixer mixes more than 2 hours, mixed material joined in the airslide disintegrating mill pulverize, material after the pulverizing joins in the tapered mixer again and mixed 2 hours, and mixed material fineness reaches 98% by 325 mesh standard sieves, obtains wetting powder.Then with wetting powder and 20kg purified water; add in the kneader simultaneously and mediate; make the material of shaping; put this material in Squeezinggranulator granulation at last; product after the granulation carries out drying in 54 ℃ of baking ovens, dried material uses 10 orders and 60 purpose standard screens to sieve; get the middle material of two sieves, make water-dispersible granules.
Embodiment 3
With the former medicine of 1.2kg penoxsuam, 3.5kg former medicine of pyrazosulfuron and 10kg neopelex, the 8kg sodium lignin sulfonate, the 4kg polyvinyl alcohol, 5kg Nonyl pheno base ether, 34.15kg kaolin, 34.15kg bentonite, joining together in the tapered mixer mixes more than 2 hours, mixed material joined in the airslide disintegrating mill pulverize, material after the pulverizing joins in the tapered mixer again and mixed 2 hours, and mixed material fineness reaches 98% by 325 mesh standard sieves, obtains wetting powder.
Embodiment 4
With the former medicine of 1.2kg penoxsuam, 5.0kg the former medicine of pyrazosulfuron, the 12kg neopelex, the 8kg polyoxyethylene nonylphenol ether, 3.5kg epoxidized soybean oil, 1.5kg carboxymethyl cellulose, 2kg glycerine, the 1kgS-29 defoamer, 5kg acetone, the 60.8kg methyl oleate joins reactor together, stirred 2 hours, open baiting valve at the bottom of the still, material is injected sand mill grind, the material fineness after the grinding reaches 98% by discharging behind 325 mesh standard sieves, material is put in the high-shear emulsifying still again, promptly gets herbicidal composition oil suspending agent of the present invention after the emulsification.
Embodiment 5
With the former medicine of 1.1kg penoxsuam, former medicine of 6kg pyrazosulfuron and 12kg neopelex, the 9kg sodium lignin sulfonate, 3.5kg polyvinyl alcohol, 2.5kg lauryl alcohol polyethylene glycol oxide base ether, 35kg kaolin, 30.9kg bentonite, joining together in the tapered mixer mixes more than 2 hours, mixed material joined in the airslide disintegrating mill pulverize, material after the pulverizing joins in the tapered mixer again and mixed 2 hours, and mixed material fineness reaches 98% by 325 mesh standard sieves, obtains wetting powder.Then with wetting powder and 18kg purified water; add in the kneader simultaneously and mediate; make the material of shaping; put this material in Squeezinggranulator granulation at last; product after the granulation carries out drying in 54 ℃ of baking ovens, dried material uses 10 orders and 60 purpose standard screens to sieve; get the middle material of two sieves, make water-dispersible granules.
Be composite synergistic effect and the best ratio range of whether producing of checking penoxsuam and pyrazosulfuron, we adopt the interaction between equivalent collimation method evaluation penoxsuam and the pyrazosulfuron.Give birth to surveying object is the barnyard grass grass, and the cauline leaf spraying is handled after barnyard grass grass 3 leaves respectively are provided with bud under the dosage, and 4 repetitions are established in each processing, and other establishes blank.Single agent penoxsuam is provided with 0.25,0.50,1.0,2,4,8g ai.hm
-2Totally 6 processing; Single agent pyrazosulfuron is provided with 2.0,4.0,6.0,8.0,10.0,12.0g ai.hm
-2Totally 6 processing, again with two each dosage of medicament composite in twos respectively be 36 processing that are mixed.The acrial part fresh weight is respectively handled in the 20d weighing behind medicine, asks the fresh weight inhibiting rate.Utilize dosage logarithm-probability value method to calculate ED then
90Value, and draw ED
90Equivalent line is by ED
90Equivalent line is estimated two kinds of weed killer herbicide correlations, and obtains best ratio range.
Table 1 penoxsuam and the agent of pyrazosulfuron list and composite processing are to the fresh weight inhibiting rate of barnyard grass grass
Penoxsuam suppresses ED to the fresh weight of barnyard grass grass under the table 2 pyrazosulfuron quantitative Treatment
90Value
| Pyrazosulfuron g ai.hm -2 | Regression equation (y=) | Correlation coefficient (r) | ED90(g?ai.hm -2) |
| 0 | Y＝0.739x+5.1664 | 0.9775 | 32.29 |
| 2 | Y＝0.8756x+5.3406 | 0.9747 | 11.88 |
| 4 | y＝0.8598x+5.5503 | 0.9238 | 7.09 |
| 6 | y＝0.7736x+5.6946 | 0.9419 | 5.74 |
| 8 | Y＝0.7198x+5.8402 | 0.9428 | 5.10 |
| 10 | y＝0.654+5.9729 | 0.9049 | 3.93 |
| 12 | y＝0.6393x+6.0985 | 0.9262 | 1.93 |
Pyrazosulfuron suppresses ED to the fresh weight of barnyard grass grass under the table 3 penoxsuam quantitative Treatment
90Value
| Penoxsuam g ai.hm -2 | Regression equation (y=) | Correlation coefficient (r) | ED 90(g?ai.hm -2) |
| 0 | y＝1.08x+4.1876 | 0.9661 | 86.86 |
| 0.25 | Y＝1.0007x+4.4093 | 0.9953 | 74.29 |
| 0.50 | Y＝1.1509x+4.6598 | 0.9245 | 25.65 |
| 1.0 | Y＝1.006x+5.0983 | 0.9706 | 15.00 |
| 2.0 | Y＝1.0574x+5.2063 | 0.9787 | 13.22 |
| 4.0 | Y＝0.626x+5.7352 | 0.9732 | 7.46 |
| 8.0 | Y＝0.6146x+5.843 | 0.9635 | 5.17 |
By table 1 as seen, each fresh weight inhibiting rate of handling the barnyard grass grass improves along with the increase of dosage.Data in the his-and-hers watches 1 are carried out dose-response regression analysis processing, obtain different proportionings and handle following fresh weight inhibiting rate (ED to the barnyard grass grass
90), regression equation etc. (see Table 2, table 3).Under the pyrazosulfuron quantitative Treatment, penoxsuam is to the ED of the fresh weight inhibition of barnyard grass grass
90Value reduces (table 2) with the raising of pyrazosulfuron dosage, and under the penoxsuam quantitative Treatment, pyrazosulfuron is to the ED of barnyard grass grass fresh weight inhibition equally
90Value improves with penoxsuam dosage and reduces.(table 3)
Dosage with pyrazosulfuron is abscissa, and the dosage of penoxsuam is that ordinate is figure.Pyrazosulfuron and the agent of penoxsuam list are to the ED of barnyard grass grass on the connection coordinate
90Be worth resulting straight line and be the summation action line of these two kinds of herbicide mixtures, promptly theoretical equivalent line.Then with 12 composite ED
90Value is marked on the coordinate diagram, removes the curve that marginal point is formed by connecting, and is exactly the ED of the composite processing of penoxsuam and pyrazosulfuron to the barnyard grass grass
90The equivalence line chart.(seeing Figure of description Fig. 1)
As seen from Figure 1, the ED of each hybrid combining
90Value is estimated principle according to equivalent collimation method all below theoretical equivalent line, illustrates that these two medicaments use with in designing dosage range, and the barnyard grass grass is had certain synergistic effect.And the synergistic effect between (25.65,3) two equivalent line coordinate points is the most obvious in (4,4.96), i.e. penoxsuam 3-4.96g ai.hm
-2With pyrazosulfuron 4-25.65g ai.hm
-2Ratio range reach best synergistic effect.
By give birth to surveying of equivalent collimation method, we find that penoxsuam and pyrazosulfuron are composite in certain ratio range, and obvious synergistic effect is arranged, and can reduce the mu dosage of penoxsuam greatly, saving cost, raising drug effect.We choose 5 kinds of proportionings (example 1-5) and make various formulations in the ratio range of synergistic effect is arranged, and carry out field trial, further verify the synergistic effect after composite of penoxsuam and pyrazosulfuron.
We carry out field trial with prescription 5 by picked at random prescription 3, and the test site is located at the Nanchang, carries out at direct sowing rice field, weeds in field has barnyard grass grass, difformed galingale herb during test, leaf age is the two leaves leaf phases one heart stage to four, and broad leaved weed is a Monochoria vaginalis etc., and leaf age is that two leaves are to tri-leaf period.Test is handled and is adopted spray-on process, drains water in field before the dispenser, and 24h pours water after the dispenser, and keeps shoaling layer 5-7d.Medicine for examination has prescription 3, prescription 5,2.5% penoxsuam, 10% pyrazosulfuron, investigation method: leaf look, the growing way of 3d, 5d, 15d range estimation paddy rice behind the medicine, observe the safety of medicament to paddy rice; When results, survey and produce, and investigation plant height, spike length, unit are spike number and thousand kernel weight.The preventive effect investigation adopts the every sub-district of chessboard method to get 5 points, area 0.2m
2, the strain preventive effect is calculated in 20d, 35d investigation after medication, adds the fresh weight preventive effect of surveying weeds when investigating for the last time.
Table 4 penoxsuam pyrazosulfuron is to the strain preventive effect (20d) of direct sowing rice field weeds
Annotate: data are the mean value of 3 repetitions in the table, strain number: be the average strain number of unit are.
Table 5 penoxsuam pyrazosulfuron is to the strain preventive effect (35d) of direct sowing rice field weeds
Annotate: data are the mean value of 3 repetitions in the table, strain number: be the average strain number of unit are.
Table 6 penoxsuam pyrazosulfuron is to the fresh weight preventive effect (35d) of direct sowing rice field weeds
Annotate: data are 3 mean values that repeat, fresh weight: the average weeds fresh weight of unit are.
From above-mentioned data as can be seen, the effect that the preventive effect when penoxsuam and pyrazosulfuron complex preparation control barnyard grass grass, nutgrass flatsedge, Monochoria vaginalis etc. all is higher than single agent far away when using.Behind the medicine during 30d strain preventive effect and the fresh weight preventive effect to the barnyard grass grass all reach 100%, also more than 90%, and the strain preventive effect less than 60% of all the other two kinds of single-dose agent, fresh weight preventive effect be less than 70% to the preventive effects of all the other weeds, the difference performance between each is handled is extremely remarkable.And from data as can be seen, 30d behind the medicine, penoxsuam pyrazosulfuron complex preparation can keep good control efficiency, and the preventive effect of all the other single-dose agent has obviously begun to descend.Therefore, penoxsuam pyrazosulfuron complex preparation has not only improved drug effect, and prolonged the lasting period, all there have been significant raising quick-acting and lasting period that this complex preparation is described than single agent, use this complex preparation, can reduce the use cost of peasant household greatly, have the effect that a drug solves the multiple weeds in rice field.
3d, 5d, 15d observe the growing state of paddy rice behind the medicine, do not find leaf color and the abnormal plant of growing way when each investigation, illustrate that complex preparation is safe to paddy rice.Because penoxsuam pyrazosulfuron complex preparation can effectively be prevented and kill off various weeds, can not cause weeds contentions nutrition, cover phenomenon such as paddy rice photosynthesis, therefore the paddy rice seedling leaf color of respectively handling the sub-district is emerald green, stem is sturdy, and plant height is apparently higher than CK (clear water processing) sub-district.
Table 7 penoxsuam pyrazosulfuron is to the influence of direct sowing rice field tree characteristics, output
Indexs such as the spike number of the plant height of measurement paddy rice, unit are, output during results, can find by the data in the table 7, penoxsuam pyrazosulfuron complex preparation is because effectively anti-except various weeds, make every Biological indicators of paddy rice all will be higher than the sub-district and the clear water check plot of other chemicals treatment, each handles significant difference.Therefore, penoxsuam pyrazosulfuron complex preparation is not only to rice safety, and can significantly improve rice yield, and worth large tracts of land is promoted the use of.
Survey and the test of pesticide effectiveness by giving birth to, determining that penoxsuam and pyrazosulfuron are composite has a significant synergistic effect, new complex preparation not only provides a kind of safe, practical weed killer herbicide for the rice field, and reduce the cost of enterprise and peasant household greatly, solved penoxsuam because of the high-leveled and difficult difficult problem of promoting with large tracts of land of price.Preparation after composite can be made formulation commonly used in the multiple production, and enterprise does not need to purchase new production equipment, just can produce the formulation that all are fit under existing working condition.
Claims (4)
1. rice direct seeding field mixed herbicide, it is characterized in that: described complex weedicide, its water dispersible granules constituent and percentage by weight thereof are: penoxsuam 0.5%～15%, pyrazosulfuron 0.2%～20%, wetting agent 1%～20%, dispersant 1%～15%, spreader-sticker 1%～5%, stabilizing agent 0.2%～5%, bleeding agent 1%～10%, filler 10%～80%, each component sum is 100%.
2. rice direct seeding field mixed herbicide, it is characterized in that: described complex weedicide, its wetting powder constituent and percentage by weight thereof are: penoxsuam 0.5%～20%, pyrazosulfuron 0.2%～25%, wetting agent 1%～10%, dispersant 1%～20%, spreader-sticker 0.1%～10%, bleeding agent 1%～15%, filler 5%～85%, each component sum is 100%.
3. according to claim 1 or the described rice direct seeding field mixed herbicide of claim 2, it is characterized in that: described wetting agent is one or more in neopelex, lauryl sodium sulfate, lignosulfonates, the aliphatic alcohol sulfate; Described dispersant is one or more in lignosulfonates, alkylbenzenesulfonate, alkyl ethyl sulfonate, the alkylnaphthalene sulfonate formaldehyde condensation products; Described stabilizing agent is an epoxidized vegetable oil; Described spreader-sticker is one or more in polyvinyl alcohol, the alkyl diphenyl ether disulphonic acid sodium; Described bleeding agent is one or more in sorbitan fatty acid ester APEO, the aliphatic alcohol polyethenoxy base ether; Described filler is one or more in kaolin, bentonite, talcum powder, precipitated calcium carbonate, diatomite, potter's clay, attapulgite, atlapulgite, the gypsum.
4. rice direct seeding field mixed herbicide according to claim 2 is characterized in that: the fineness of described wetting powder is passed through 325 mesh standard sieves more than 98%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100974094A CN101310599B (en) | 2008-05-26 | 2008-05-26 | Rice direct seeding field mixed herbicide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100974094A CN101310599B (en) | 2008-05-26 | 2008-05-26 | Rice direct seeding field mixed herbicide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101310599A CN101310599A (en) | 2008-11-26 |
| CN101310599B true CN101310599B (en) | 2011-11-23 |
Family
ID=40099594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100974094A Active CN101310599B (en) | 2008-05-26 | 2008-05-26 | Rice direct seeding field mixed herbicide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101310599B (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011094386A2 (en) * | 2010-01-29 | 2011-08-04 | Dow Agrosciences Llc | Synergistic herbicidal composition containing penoxsulam and oxyfluorfen |
| JP5806683B2 (en) * | 2010-02-03 | 2015-11-10 | ダウ アグロサイエンシィズ エルエルシー | Synergistic herbicidal composition containing penox slam and flazasulfuron |
| TWI633842B (en) * | 2010-02-03 | 2018-09-01 | 陶氏農業科學公司 | Synergistic herbicidal composition containing penoxsulam and butachlor |
| CN101785455B (en) * | 2010-02-05 | 2013-03-06 | 深圳诺普信农化股份有限公司 | Pesticide oil suspension agent and preparation method thereof |
| CN101897339B (en) * | 2010-08-20 | 2013-09-11 | 陕西上格之路生物科学有限公司 | Herbicide composition containing cinosulfuron and penoxsulam |
| CN102792956A (en) * | 2011-05-23 | 2012-11-28 | 山东滨农科技有限公司 | Herbicide composition including penoxsulam and azimsulfuron |
| CN102334495A (en) * | 2011-08-31 | 2012-02-01 | 广东中迅农科股份有限公司 | Weeding composition |
| CN103371161B (en) * | 2012-04-28 | 2016-08-03 | 陕西韦尔奇作物保护有限公司 | A kind of Herbicidal combinations containing AC322140 |
| CN103120172A (en) * | 2013-02-04 | 2013-05-29 | 广东中迅农科股份有限公司 | Floating granule for preventing and removing weeds of paddy field |
| CN103210944B (en) * | 2013-04-28 | 2014-11-05 | 江苏龙灯化学有限公司 | Compound herbicide composition |
| CN104012548A (en) * | 2014-05-07 | 2014-09-03 | 广东中迅农科股份有限公司 | Weed control composition containing pyraclonil and penoxsulam |
| CN104814024B (en) * | 2015-04-18 | 2018-05-18 | 广东中迅农科股份有限公司 | A kind of Herbicidal composition for rice field containing piperazine pyrazosulfuron and penoxsuam |
| CN105340920A (en) * | 2015-10-27 | 2016-02-24 | 北京燕化永乐生物科技股份有限公司 | Herbicidal composition |
| CN106472496A (en) * | 2016-08-29 | 2017-03-08 | 美丰农化有限公司 | A kind of Herbicidal combinations and rice terrace closing weeding float big granula |
| CN107494573A (en) * | 2017-08-07 | 2017-12-22 | 安徽圣丰生化有限公司 | A kind of herbicidal composition of penoxsuam, dichloro quinolinic acid and pyrazosulfuron |
| CN107372545A (en) * | 2017-08-16 | 2017-11-24 | 安徽尚禾沃达生物科技有限公司 | A kind of dispersible oil-suspending agent containing penoxsuam, pyrazosulfuron and cyhalofop-butyl |
| CN108576000A (en) * | 2018-06-05 | 2018-09-28 | 广东中迅农科股份有限公司 | Herbicidal combinations containing furans sulphur humulone and penoxsuam and sulfonylurea herbicide |
| CN108684715A (en) * | 2018-07-05 | 2018-10-23 | 安徽袁粮水稻产业有限公司 | A kind of compounding improvement medicament and preparation method thereof for preventing barnyard grass |
| CN110100835A (en) * | 2019-05-13 | 2019-08-09 | 台州煜农生物科技有限公司 | A kind of mixed herbicidal composite containing trifluoro ketone grass ether and pyrazosulfuron |
| BR112022026529A2 (en) * | 2020-07-25 | 2023-01-31 | Coromandel International Ltd | SYNERGIC HERBICIDIAL FORMULATIONS, PROCESS FOR PREPARING THEM |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007137868A (en) * | 2005-10-19 | 2007-06-07 | Nissan Chem Ind Ltd | Release-controlled particle and preparation containing the particle |
| CN101001523A (en) * | 2004-08-11 | 2007-07-18 | 组合化学工业株式会社 | Agricultural chemical composition |
-
2008
- 2008-05-26 CN CN2008100974094A patent/CN101310599B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101001523A (en) * | 2004-08-11 | 2007-07-18 | 组合化学工业株式会社 | Agricultural chemical composition |
| JP2007137868A (en) * | 2005-10-19 | 2007-06-07 | Nissan Chem Ind Ltd | Release-controlled particle and preparation containing the particle |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101310599A (en) | 2008-11-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101310599B (en) | Rice direct seeding field mixed herbicide | |
| CN103749480B (en) | Paddy field herbicide composition and application | |
| CN102326551B (en) | Weeding composition containing diflufenican | |
| CN104756998A (en) | Metamifop.benzobicylon compound preparation and application thereof | |
| CN103783076B (en) | A kind of mixed herbicide containing glyphosate, two careless ether and methoxone and application thereof | |
| CN104115863A (en) | Weeding composition | |
| CN103828816B (en) | Mixed herbicide containing fenoxaprop-p-ethyl, clodinafop-propargyl and fluroxypyr | |
| CN104054734B (en) | A kind of herbicide for paddy field | |
| CN103262844A (en) | Paddy field weeding composition | |
| CN102754663A (en) | Weeding combination containing anilofos and quinclorac or quinclorac salts and preparation thereof | |
| CN102027981A (en) | Herbicidal composition containing nicosulfuron and clopyralid and application thereof | |
| CN101861868B (en) | Pesticide compound containing penoxsulam and quinclorac and application thereof | |
| CN104273156B (en) | A kind of herbicide composition for wheat field | |
| CN101310601A (en) | Rice direct seeding fields herbicidal compositions | |
| CN103098804A (en) | Single drive type roller press | |
| CN104663697A (en) | Herbicide composition and application thereof | |
| CN104839178A (en) | Weeding composition containing metamifop and florasulam | |
| CN104522023A (en) | Wheat field herbicide composition containing clodinafop-propargyl | |
| CN102907439A (en) | Compound farm herbicide | |
| CN107410321A (en) | A kind of Herbicidal combinations containing fluorochloridone and pyrithiobac-sodium | |
| CN102027903B (en) | Synergetic weeding composite containing cyhalofop-butyl and dicamba and application thereof | |
| CN105076162A (en) | Paddy field weeding composition containing oxyfluorfen and pyraclonil | |
| CN104285997A (en) | Rice stem leaf herbicide containing cyhalofop-butyl, halosulfuron-methyl and fluroxypyr-meptyl | |
| CN103271069A (en) | Compound herbicide | |
| CN104285987B (en) | Compound herbicide and application thereof containing phenmedipham, clethodim and Pendimethalin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Yang Huiying Document name: Notification of Passing Preliminary Examination of the Application for Invention |
|
| C06 | Publication | ||
| PB01 | Publication | ||
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Yang Huiying Document name: Approval notice for cost mitigation |
|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: BEIJING YANHUA YONGLE BIOTECHNOLOGY CO., LTD. Free format text: FORMER NAME: BEIJING YOLOO PESTICIDE CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: 102488 No. 8, Liangxiang Town, Fangshan District, Beijing Patentee after: Beijing Yanhua Yongle Biotechnology Co., Ltd. Address before: 102488 No. 8, Liangxiang Town, Fangshan District, Beijing Patentee before: Beijing Yoloo Pesticide Co., Ltd. |
|
| C56 | Change in the name or address of the patentee | ||
| CP02 | Change in the address of a patent holder |
Address after: 102488, Beijing, Fangshan District Star Street, No. 1 hospital green sail, No. 16, building 8 Patentee after: Beijing Yanhua Yongle Biotechnology Co., Ltd. Address before: 102488 No. 8, Liangxiang Town, Fangshan District, Beijing Patentee before: Beijing Yanhua Yongle Biotechnology Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171219 Address after: 063600 Leting County Economic Development Zone, Tangshan City, Hebei Patentee after: Yanhua Yongle (Leting) Biological Technology Co. Ltd. Address before: 102488, Beijing, Fangshan District Star Street, No. 1 hospital green sail, No. 16, building 8 Patentee before: Beijing Yanhua Yongle Biotechnology Co., Ltd. |