CN101285142A - Magnesium-lithium-samarium alloy and preparation method thereof by fused salt electrolysis - Google Patents
Magnesium-lithium-samarium alloy and preparation method thereof by fused salt electrolysis Download PDFInfo
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- CN101285142A CN101285142A CNA2008100646259A CN200810064625A CN101285142A CN 101285142 A CN101285142 A CN 101285142A CN A2008100646259 A CNA2008100646259 A CN A2008100646259A CN 200810064625 A CN200810064625 A CN 200810064625A CN 101285142 A CN101285142 A CN 101285142A
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Abstract
The invention provides a Mg Li -Samarium alloy and a method for preparing the same through fusion electrolysis. The method uses MgCl2+LiCl+KCl+KF as an electrolyte system in an electrolytic furnace, then adds anhydrous Sm2O3 powders to heat up to a melting temperature of 680 DEG C or anhydrous SmCl3 powders to heat up to a melting temperature of 630 DEG C, using metal molybdenum (Mo) as a cathode and graphite as an anode at an electrolysis temperature of between 630 and 810 DEG C, and adopts a sinking cathode method, in which a cathodic current density is 6.4 to16.0A/cm<2>,an anodic current density is 0.5A/cm<2> and a cell voltage is 5.1-8.4V, so as to deposit a Mg-Li-Sm alloy nearby the cathode in a fused-salt electrolysis cell after electrolyzing for 40 to 120 minutes. The method does not use metallic magnesium, metal lithium, or metallic samarium, but uses metal compound as raw materials to directly prepare the Mg-Li-Sm alloy through the fusion electrolysis method, thereby having the advantages of greatly shortening production flow and reducing the energy consumption and production cost due to the simple process with low temperature electrolysis.
Description
(1) technical field
What the present invention relates to is a kind of alloy, specifically a kind of magnesium-lithium-samarium alloy.The invention still further relates to a kind of preparation method of magnesium-lithium-samarium alloy.
(2) background technology
Magnesium alloy has that proportion is low, specific tenacity is high, easily process and premium properties such as recovery, and good damping shock absorption and capability of electromagnetic shielding, is widely used in automobile, aerospace industry.In the magnesium alloy, the Mg-Li alloy is a lightest present alloy, and the density of its binary alloy only is 1.3～1.59g/cm
3, but its specific tenacity is also more much higher than aluminium alloy.Li adds among the Mg, its density is descended, and its processing characteristics is improved greatly, therefore receives the concern of investigator and industry member, and obtained certain application in aerospace field.The Mg-Li alloy also has own particular performances except the characteristic that possesses general magnesium alloy: alloy density is very low, is unique magnesium alloy system that is lower than magnesium matrix density, even can be lower than the density of water.Along with the increase of Li content, the transformation by close-packed hexagonal (hcp) → close-packed hexagonal+body-centered cubic → body-centered cubic (bcc), the plastic making excellent property of alloy will take place in the structure of alloy.The Mg-Li alloy has low density, high specific strength, is easy to much attractive especially advantages such as processing.
The production method of magnesium lithium alloy mainly contains following several: to the method for mixing, cathode alloy method, liquid cathode method, coelectrodeposition method.
(1) to the method for mixing: under the state of melting of metal, MAGNESIUM METAL and metallic lithium are formed mixing by a certain percentage.This method metal loss is big, the cost height, and work situation is poor, and the metal segregation is serious.
(2) cathode alloy method: MAGNESIUM METAL is put in the electrolyzer as negative electrode, and lithium salts is an ionogen, and lithium is separated out also and the magnesium cathode alloyization in electrolytic process, thereby forms magnesium lithium alloy.What this method was used is the high MAGNESIUM METAL of price, the cost height.And the composition of alloy be difficult to control, have segregation phenomena.
(3) liquid cathode method: as negative electrode, magnesium salts is as ionogen with the liquid metal lithium, and magnesium is separated out and and lithium cathode alloyization in electrolytic process.This method is mainly produced master alloy and mother alloy.
(4) coelectrodeposition method: the deposition potential of magnesium lithium differs about 0.9V, and gap is too big, can cause to separate out Mg and do not separate out Li.Manage to reduce Mg
2+Ionic deposition potential, rising Li
+The ionic deposition potential can adopt following method to realize Mg
2+, Li
+The ion coelectrodeposition: 1. be conducting electrolyte with KCl, MgCl in the melt that a large amount of KCl exist
2Activity can reduce significantly, reduce Mg to reach
2+The purpose of ionic deposition potential; Current density during 2. by the raising fused salt electrolysis reaches Mg
2+After the ionic limit current density, cause Mg
2+The ionic deposition potential moves to negative rapidly, reaches Li
+Ion reductive current potential just can reach the Mg-Li codeposition.3. at the beginning of the electrolysis, generation be Mg, so Li
+On Mg, deposit, on Mg-Li, deposit thereupon.And Li
+When on Mg (Mg-Li alloy), separating out very big depolarisation effect is arranged, make Li
+Deposition potential helps generating the Mg-Li alloy to shuffling.
The liquid cathode method is used wider in rare metal is smelted, and this method is widely used in producing magnesium base master alloy." method of low temperature sinking liquid cathode electrolytic preparation magnesium rare earth intermediate alloy " of number of patent application 200510017229.7 for example, this method adopt content of rare earth be the magnesium-lanthanum-praseodymium-cerium master alloy of 5～8wt% as initial sinking liquid cathode, produce magnesium-(8～30) wt% lanthanum praseodymium cerium master alloy 700-900 ℃ of following electrolysis than high rare-earth content.The composite cathode method is also used to some extent simultaneously, " preparation method of composite cathode fused salt electrolysis rare-earth and Mg master alloy " of application number 200510119117.2 for example: in same electrolyzer, come-up liquid magnesium negative electrode, sink liquid high concentration rare earth magnesium negative electrode and the vertical surperficial intermediate concentration rare earth magnesium liquid cathode coexistence of non-consumable, electrochemical deposition occurs in three-dimensional cathode surface simultaneously, electrolytic preparation rare-earth and Mg master alloy.
(3) summary of the invention
The object of the present invention is to provide a kind of flowability and processing characteristics to be improved, the magnesium-lithium-samarium alloy of plasticity, wear resistance and good corrosion resistance.The present invention also aims to provide a kind of without MAGNESIUM METAL, metallic lithium, also without rare earth metal, technology is simple, can improve the flowability and the processing characteristics of alloy, improve the intensity of alloy, plasticity, the fused salt electrolysis preparation method thereof of the magnesium-lithium-samarium alloy of wear resistance and erosion resistance.
Magnesium-lithium-samarium alloy of the present invention by weight ratio is: the magnesium of lithium 7.2～56.4%, samarium 0.3～2.1% and surplus is formed.
Magnesium-lithium-samarium alloy of the present invention is to adopt such method to prepare: in electrolytic furnace, with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and each electrolytical quality proportioning is 6～13.3%, 39.8～44.5%, 39.8～44.5%, 4.8～7.1%, presses MgCl again
21～4% of weight adds anhydrous Sm
2O
3Be heated to 680 ℃ of fusions, perhaps press MgCl
21～4% of weight adds anhydrous SmCl
3Powder is heated to 630 ℃ of fusions, is negative electrode with the metal molybdenum, and graphite is anode, and under 630～810 ℃ of the electrolysis temperatures, cathode current density is 6.4～16.0A/cm
2, anodic current density 0.5A/cm
2, bath voltage 5.1～8.4V, the electrolysis through 40～120 minutes deposits the Mg-Li-Sm alloy at fused-salt bath near negative electrode.
300 ℃, 600 ℃ dryings 24 hours, KF was by KF2H respectively for LiCl among the present invention, KCl
2Through the dehydration preparation, dehydration temperaturre is 130～180 ℃ to O at vacuum drying oven.
The present invention adopt be that magnesium lithium electrolytic codeposition of nickel legal system is got magnesium lithium alloy.Compare with background technology, also without metallic lithium, but the method that all to adopt metallic compound be raw material by fused salt electrolysis is through direct preparation magnesium-lithium-samarium alloy of one step of electrolysis without MAGNESIUM METAL.Reduced production cost without metal.And can obtain the different Mg-Li-Sm alloys of forming by conditions such as control ionogen proportioning, electrolysis time, temperature, current densities, alloy compositions can be the magnesium of lithium 7.2～56.4%, samarium 0.3～2.1% and surplus.A whole set of technology is simple, to equipment require lowly, experiment condition is realized easily.Energy consumption is low, pollutes little.
The Mg-Li alloy need have good over-all properties as structured material, and desire improves alloy material intensity and don't too sacrifices its premium properties, can adopt the method for adding rare earth element.It is reported that rare earth joins the machining property and the physicals that can effectively change magnesium alloy in the magnesium alloy, purify impurity, can form intermetallic compound with the metal that is the solute state in the magnesium alloy.Improve the flowability and the processing characteristics of alloy, improved the intensity of magnesium alloy, plasticity, wear resistance, erosion resistance.
The present invention adopts the method for adding rare earth element Sm, exploitation Mg-Li-Sm alloy.
It is simple to the invention provides a kind of technology, the magnesium-lithium-samarium alloy preparation method that production cost is low.Characteristics of the present invention are: (1) also without rare earth metal, is raw material but all adopt metallic compound promptly without MAGNESIUM METAL and lithium, adopts fused salt electrolysis directly to prepare magnesium-lithium-samarium alloy, therefore Production Flow Chart is shortened greatly, and technology is simple; (2) electrolysis temperature of the present invention low (630～810 ℃) well below the fusing point of metal Sm (1072 ℃), therefore, can prolong the work-ing life of equipment, saves the energy, reduces production costs.
(4) description of drawings
Accompanying drawing is scanning electron microscope (SEM) photo and face scanning (EPMA) photo of the alloy sample of preparation in the example 5.
Wherein: Fig. 1 is the SEM photo; Fig. 2 is 002 an EDS collection of illustrative plates; Fig. 3 is the face scanning (Mg K) that magnesium distributes in the alloy; Fig. 4 is the face scanning (Sm L) that samarium distributes in the alloy.
(5) embodiment
For example the present invention is done in more detail below and describe.
Embodiment 1: with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 6.0%, 44.5%, 44.5%, 5.0%, presses MgCl again
23.3% of weight adds solid SmCl
3Powder is a negative electrode with inert metal molybdenum (Mo), and graphite is anode, under 630 ℃ of the electrolysis temperatures, takes cathode method, and pole span is 4cm, and cathode current density is 9.5A/cm
2, anodic current density 0.5A/cm
2, bath voltage 5.6～5.8V, the electrolysis through 40 minutes deposits the Mg-Li-Sm alloy at fused-salt bath near negative electrode, and the content of magnesium, lithium, samarium is respectively: 43.3%, 56.4%, 0.3%.
Embodiment 2: with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 6.0%, 44.5%, 44.5%, 5.0%, presses MgCl again
23.3% of weight adds solid SmCl
3Powder is a negative electrode with inert metal molybdenum (Mo), and graphite is anode, under 660 ℃ of the electrolysis temperatures, takes cathode method, and pole span is 4cm, and cathode current density is 6.4A/cm
2, anodic current density 0.5A/cm
2, bath voltage 5.0～5.3V, the electrolysis through 40 minutes deposits the Mg-Li-Sm alloy at fused-salt bath near negative electrode, and the content of magnesium, lithium, samarium is respectively: 59.6%, 39.5%, 0.9%
Embodiment 3: with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 6.0%, 44.5%, 44.5%, 5.0%, presses MgCl again
23.3% of weight adds solid Sm
2Cl
3Powder is a negative electrode with inert metal molybdenum (Mo), and graphite is anode, under 660 ℃ of the electrolysis temperatures, takes cathode method, and pole span is 4cm, and cathode current density is 12.7A/cm
2, anodic current density 0.5A/cm
2, bath voltage 8.0～8.4V, the electrolysis through 40 minutes deposits the Mg-Li-Sm alloy near fused-salt bath and negative electrode, and the content of magnesium, lithium, samarium is respectively: 45.5%, 54.0%, 0.5%.
Embodiment 4: with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 7.8%, 43.7%, 43.7%, 4.8%, presses MgCl again
23.7% of weight adds solid Sm
2O
3Powder is a negative electrode with inert metal molybdenum (Mo), and graphite is anode, under 780 ℃ of the electrolysis temperatures, takes cathode method, and pole span is 4cm, and cathode current density is 12.7A/cm
2, anodic current density 0.5A/cm
2, bath voltage 6.0～6.9V through electrolysis in 90 minutes, deposits the Mg-Li-Sm alloy near fused-salt bath and negative electrode, and the content of magnesium, lithium, samarium is respectively: 78.9%, 19.1%, 2.0%.
Embodiment 5: with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 13.3%, 39.8%, 39.8%, 7.1%, presses MgCl again
23.3% of weight adds solid Sm
2O
3Powder is a negative electrode with inert metal molybdenum (Mo), and graphite is anode, under 810 ℃ of the electrolysis temperatures, takes cathode method, and pole span is 4cm, and cathode current density is 16.0A/cm
2, anodic current density 0.5A/cm
2, bath voltage 5.1～6.0V through electrolysis in 120 minutes, deposits the Mg-Li-Sm alloy near fused-salt bath and negative electrode, and the content of magnesium, lithium, samarium is respectively: 90.7%, 7.2%, 2.1%.
In above embodiment as can be seen: the constant Mg content (example 1 and example 5) that can obviously improve in the alloy of all the other conditions of input amount that strengthens magnesium chloride; It is constant to add all the other conditions of high current density, helps separating out of metallic lithium, can improve the content (example 2 and example 3) of lithium in the alloy, prolongs electrolysis time and helps separating out of rare earth samarium, the loss of electrolysis temperature too high meeting increasing the weight of lithium.
Accompanying drawing 1 is scanning electron microscope (SEM) photo and face scanning (EPMA) photo of the alloy sample of preparation in the example 5.SEM attaches power spectrum (EDS) 002 in sample has been carried out ultimate analysis, and its result shows have rare earth samarium to exist in the alloy, matches with the plasma mass analytical data.Can be clearly seen that in the EPMA face scanned photograph: the distribution of MAGNESIUM METAL and rare earth samarium is uniformly in the alloy, the segregation-free phenomenon.
Claims (10)
1. magnesium-lithium-samarium alloy, it is characterized in that: by weight ratio be: the magnesium of lithium 7.2～56.4%, samarium 0.3～2.1% and surplus is formed.
2. magnesium-lithium-samarium alloy according to claim 1 is characterized in that: its weight ratio consists of: magnesium 43.3%, lithium 56.4% and samarium 0.3%
3. magnesium-lithium-samarium alloy according to claim 1 is characterized in that: its weight ratio consists of: magnesium 59.6%, lithium 39.5% and samarium 0.9%.
4. magnesium-lithium-samarium alloy according to claim 1 is characterized in that: its weight ratio consists of: magnesium 78.9%, lithium 19.1% and samarium 2.0%.
5. magnesium-lithium-samarium alloy according to claim 1 is characterized in that: its weight ratio consists of: magnesium 90.7%, lithium 7.2% and samarium 2.1%.
6. a fused salt electrolysis prepares the method for magnesium-lithium-samarium alloy, it is characterized in that: in electrolytic furnace, with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and each electrolytical quality proportioning is 6～13.3%, 39.8～44.5%, 39.8～44.5%, 4.8～7.1%; Press MgCl again
21～4% of weight adds anhydrous Sm
2O
3Powder is heated to 680 ℃ of fusions, perhaps presses MgCl
21～4% of weight adds anhydrous SmCl
3Powder is heated to 630 ℃ of fusions, is negative electrode with the metal molybdenum, and graphite is anode, and under 630～810 ℃ of the electrolysis temperatures, cathode current density is 6.4～16.0A/cm
2, anodic current density 0.5A/cm
2, bath voltage 5.1～8.4V, the electrolysis through 40～120 minutes deposits the Mg-Li-Sm alloy at fused-salt bath near negative electrode.
7. a kind of fused salt electrolysis as claimed in claim 6 prepares the method for magnesium-lithium-samarium alloy, it is characterized in that: in electrolytic furnace, with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 6.0%, 44.5%, 44.5%, 5.0%, presses MgCl again
23.3% of weight adds anhydrous SmCl
3Under the powder, 630 ℃ of electrolysis temperatures, cathode current density is 9.5A/cm
2, bath voltage 5.6～5.8V, the electrolysis through 40 minutes deposits the Mg-Li-Sm alloy at fused-salt bath near negative electrode, and the content of magnesium, lithium, samarium is respectively in the alloy: 43.3%, 56.4%, 0.3%
8. a kind of fused salt electrolysis as claimed in claim 6 prepares the method for magnesium-lithium-samarium alloy, it is characterized in that with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 6.0%, 44.5%, 44.5%, 5.0%, presses MgCl again
23.3% of weight adds anhydrous SmCl
3Under the powder, 660 ℃ of electrolysis temperatures, cathode current density is 6.4A/cm
2, bath voltage 5.0～5.3V, the electrolysis through 40 minutes deposits the Mg-Li-Sm alloy at fused-salt bath near negative electrode, and the content of magnesium, lithium, samarium is respectively in the alloy: 59.6%, 39.5%, 0.9%.
9. a kind of fused salt electrolysis as claimed in claim 6 prepares the method for magnesium-lithium-samarium alloy, is characterised in that with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 7.8%, 43.7%, 43.7%, 4.8%, presses MgCl again
23.7% of weight adds anhydrous Sm
2O
3Powder, 780 ℃ of electrolysis temperatures, cathode current density is 12.7A/cm
2, bath voltage 6.0～6.9V through electrolysis in 90 minutes, deposits the Mg-Li-Sm alloy near fused-salt bath and negative electrode, and the content of magnesium, lithium, samarium is respectively: 78.9%, 19.1%, 2.0%.
10. a kind of fused salt electrolysis as claimed in claim 6 prepares the method for magnesium-lithium-samarium alloy, it is characterized in that with MgCl
2+ LiCl+KCl+KF is an electrolyte system, and the mass percent of each composition is respectively 13.3%, 39.8%, 39.8%, 7.1%, presses MgCl again
23.3% of weight adds anhydrous Sm
2O
3Powder, 810 ℃ of electrolysis temperatures, cathode current density is 16.0A/cm
2, bath voltage 5.1-6.0V, the electrolysis through 120 minutes deposits the Mg-Li-Sm alloy near fused-salt bath and negative electrode, and the content of magnesium, lithium, samarium is respectively: 90.7%, 7.2%, 2.1%.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014194745A1 (en) * | 2013-06-04 | 2014-12-11 | 中国科学院过程工程研究所 | Method for preparing magnesium alloy by electrolysis using magnesium chloride hydrate as raw material |
| CN109837561A (en) * | 2017-11-27 | 2019-06-04 | 中国科学院大连化学物理研究所 | A kind of metallic lithium powder and its electrochemical preparation method |
| CN112030193A (en) * | 2020-08-27 | 2020-12-04 | 包头稀土研究院 | Method for reducing segregation of gadolinium-yttrium-magnesium alloy |
-
2008
- 2008-05-30 CN CN200810064625A patent/CN100588731C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014194745A1 (en) * | 2013-06-04 | 2014-12-11 | 中国科学院过程工程研究所 | Method for preparing magnesium alloy by electrolysis using magnesium chloride hydrate as raw material |
| CN109837561A (en) * | 2017-11-27 | 2019-06-04 | 中国科学院大连化学物理研究所 | A kind of metallic lithium powder and its electrochemical preparation method |
| CN112030193A (en) * | 2020-08-27 | 2020-12-04 | 包头稀土研究院 | Method for reducing segregation of gadolinium-yttrium-magnesium alloy |
| CN112030193B (en) * | 2020-08-27 | 2021-11-09 | 包头稀土研究院 | Method for reducing segregation of gadolinium-yttrium-magnesium alloy |
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