CN101272823A - Long-acting cosmetic compositions and its use method and production method - Google Patents
Long-acting cosmetic compositions and its use method and production method Download PDFInfo
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- CN101272823A CN101272823A CNA200580051713XA CN200580051713A CN101272823A CN 101272823 A CN101272823 A CN 101272823A CN A200580051713X A CNA200580051713X A CN A200580051713XA CN 200580051713 A CN200580051713 A CN 200580051713A CN 101272823 A CN101272823 A CN 101272823A
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Abstract
There is a cosmetic composition that has an anhydrous gel phase having a gellant and an organic solvent, an aqueous phase having a hydrophilic film former and water, and a wax phase having a wax and a hydrophilized lanolin derivative. The anhydrous gel phase, the aqueous phase, and the wax phase are substantially homogeneously admixed. The hydrophilized lanolin derivative is present in an amount sufficient to adsorb the aqueous phase. There is also a method of imparting curl, length, thickness, and/or color to eyelashes. There is further a process for making a cosmetic composition.
Description
Background of invention
1. invention field
The present invention relates to make-up composition, it can provide long lasting wear resistance and excellent waterproofness.More specifically, the present invention relates to a kind of make-up composition, particularly a kind of be used for eyelashes dye the eyelashes compositions, it provides long lasting wear resistance, makes eyelashes bending and outstanding water proofing property.More specifically, the present invention relates to provide the compositions of the film of basic waterproof for skin or eyelashes.
2. description of related art
The general use of women dyed eyelashes gave prominence to and strengthened eyelashes with compositions outward appearance.This enhancing can comprise color or tone, and volume is thickness and length and curling giving.The eyelashes that dye that will be used for eyelashes are mixed with water and anhydrous form with compositions.
Waterborne compositions generally mixes the hydrophilic film agent giving crimping eyelash, increase the eyelashes volume and to make long eyelashes, and improves wear resistance.The shortcoming of mixing the waterborne compositions of hydrophilic film agent is that they are not that long lasting and easy water is removed.When eyelashes are exposed to natural environment, for example, in the time of in rainy day or the dampness, maybe when swimming, clean or when having a bath, this becomes a kind of important disadvantages.
Anhydrous composition typically contains wax, and their function is to increase the volume of eyelashes and make compositions water-fast.The shortcoming of anhydrous composition is that they can not make eyelashes higher degree ground curl, and defile easily.
Need have a kind of eyelashes compositions of dying, it provides the benefit and the advantage of aqueous and anhydrous formulation.Also need a kind of eyelashes compositions of dying, it makes eyelashes have long-acting wear resistance, anti-curling with water-fast.
The invention summary
An object of the present invention is to have a kind of make-up composition, it provides long-acting wear resistance and outstanding resistance to water.
An object of the present invention is to have a kind of eyelashes compositions of dying, it provides long-acting wear resistance and outstanding resistance to water.
One object of the present invention also is to have a kind of eyelashes compositions of dying, and it provides curling of excellent degree for eyelashes, increases volume effect and lengthening.
A further purpose of the present invention also is to have dyes the eyelashes compositions, and it provides the resistance to water of height.
According to these and other objects of the present invention, a kind of make-up composition is provided, particularly a kind of being suitable as dyed the make-up composition that eyelashes use with compositions.Said composition comprise contain gellant and organic solvent anhydrous gel mutually, contain the water of hydrophilic film agent and water, and contain the wax phase of the lanolin derivative of wax and hydrophiling.Anhydrous gel phase, water and wax phase are mixed basically equably.The lanolin derivative of hydrophiling exists with the amount that is enough to adsorb water.
Further, provide a kind of crimping eyelash and/or method of colouring of making according to these and other objects of the present invention.This method comprises and is applied to step on the eyelashes with dying eyelashes with the compositions part, wherein this dye eyelashes with compositions comprise a) contain gellant, organic solvent and coloring agent or pigment anhydrous gel mutually; B) contain the water of hydrophilic film agent and water; And c) contains the wax phase of the lanolin derivative of wax and hydrophiling.Anhydrous gel phase, water and wax phase are mixed basically equably.The lanolin derivative of hydrophiling exists with the amount that is enough to adsorb water.
Still, provide a kind of preparation to dye the eyelashes method for compositions further according to these and other objects of the present invention.The method comprising the steps of a) mixes organic solvent with the preparation anhydrous gel with gellant; B) wax phase that at elevated temperatures the lanolin derivative mixing of wax and hydrophiling is melted with preparation; C) wax phase and the gel phase with fusing mixes with preparation gel/wax mixture; D) hydrophilic film agent and water are mixed with the preparation water; E) randomly that fiber is mixed with water; And f) at elevated temperatures water and gel/wax mixture are mixed to make compositions.
According to these and other objects of the present invention, provide a kind of eyelashes compositions of dying.Said composition comprises organic solvent, is used for the gellant of organic solvent, the lanolin derivative of hydrophilic film agent, water, wax and hydrophiling, and they are all mixed basically equably.The amount of adsorbed water and hydrophilic film agent exists the lanolin derivative of hydrophiling to be enough to basically.
According to these and other objects of the present invention, provide a kind of make-up composition.Said composition comprises organic solvent, is used for the lanolin derivative of gellant, hydrophilic film agent, water, wax and the hydrophiling of organic solvent, and they are all mixed basically equably.The amount of adsorbed water and hydrophilic film agent exists the lanolin derivative of hydrophiling to be enough to basically.
Detailed Description Of The Invention
Be surprisingly found out that a kind of make-up composition can provide the resistance to water of long lasting wear resistance and excellent degree.
In fact have been found that make-up composition of the present invention can not remove with soap and water basically, need to use makeup removing ointment to remove this product usually from skin or eyelashes based on organic solvent.From skin or from the suitable product that eyelashes are removed goods of the present invention is Avon Products, the Perfect Wear Make-up Remover that Inc sells.Because as above to define product composition of the present invention is water-proof, so consumer can be applied to facial moisturizer on skin or the eyelashes on the said composition, and can not make dirty, wipes or defile.In addition, inclement weather comprises that high humility can not produce considerable influence to the said composition that is applied on skin or the eyelashes.
The applicant finds further that compositions of the present invention is long-term the reservation, and is retained on skin or the eyelashes at least 10 hours, preferred about 12 hours or longer, and most preferably from about 16 hours or longer.Therefore, compositions of the present invention satisfies the industrial requirements of " whole day reservation ".When dying eyelashes and use compositions, such compositions is particularly preferred.
Except as otherwise noted, all percentage ratios as herein described all are based on the effective dose of constituent, account for the percentage ratio of total composition weight.
This make-up composition is the homogeneous mixture that hereinafter is called three kinds of premixs of anhydrous gel phase, wax phase and water basically.During in describe constituting these three kinds of premixs of make-up composition each, use term " phase " not to be meant that this make-up composition is a heterogeneous compositions, and be meant that every kind of premix has the composition and property of itself uniqueness.
Anhydrous gel phase premix contains organic solvent and gellant.The wax phase premix contains the lanolin derivative of wax and hydrophiling.The water premix contains hydrophilic film agent and water.Each prepares respectively mutually, and gel phase and wax phase are mixed, and subsequently water is mixed with said mixture, to form basically compositions uniformly." even basically " is meant that compositions of the present invention is equivalent to single-phase liquid, can not make the composition that uses in its preparation produce considerable grumeleuse under normal situation about using, it is solidified or ooze out.
Said composition can be used in combination hydrophilic film agent (oil-resisting) and wax mutually.Said composition provides the advantage of moisture and anhydrous (cerul) goods, that is, eyelashes are curled to heavens, increases the resistance to water of volume and excellent degree.The hydrophilic film agent can form film on the surface of eyelashes, give curling of the required degree of eyelashes.The hydrophilic film agent is soluble or dispersible in water.
The hydrophilic film agent preferably is selected from water miscible cation type polymer, anionic polymer and non-ionic polyalcohol.Useful hydrophilic film agent includes but not limited to, acrylic compounds (esters of acrylic acid), polyacrylate, acrylamide polymer and copolymer thereof and quaternary ammonium salt, urethanes, polyurethane, polyester, polysaccharide, polyamide, polyimides, polyhydric alcohol, polyethers, cellulose family, protein, polyamino acid, is derived from rosiny ester, latex class and combination in any thereof.
Particularly preferred hydrophilic film agent is a cation type polymer.Useful cation type polymer includes but not limited to, methylol chitosan, hydroxyethyl-cellulose, polyquaternary ammonium salt-4, polyquaternary ammonium salt-5, polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, polyquaternary ammonium salt-22 and any combination thereof.Polyquaternary ammonium salt-the 7th, most preferred.Polyquaternary ammonium salt-the 7th, the ammonium salt of acrylamide/dimethyl diallyl ammonium chloride copolymer is sold with the trade name of Salcare Super 7 by Ciba Specialty Chemicals.
The suitable water-soluble, film-forming anionic polymer acrylamide copolymer that to be SEPPIC sell with the title of Sepigel 501, acrylate/EHA copolymer, acrylate copolymer are (for example, by Rohm ﹠amp; The Aculyn 33 that Haas sells), acrylate/nvp copolymer and sodium acrylate copolymer.
Suitable non-ionic water-soluble film forming polymer is polyurethane-1, polyimides-1 and adipic acid/PPG-10 copolymer.Preferred polyimides-the 1st, the Aquaflex that ISP sells.
The hydrophilic film agent exists with the amount of curling that is enough to form film and give the required degree of eyelashes on the surface of skin or eyelashes.Preferably, the hydrophilic film agent is arrived about 5wt% for about 0.1wt%.More preferably, the hydrophilic film agent is arrived about 2wt% for about 0.1wt%.Most preferably based on the gross weight of compositions, the hydrophilic film agent is arrived about 1wt% for about 0.1wt%.
This make-up composition contains one or more above-mentioned wax.Suitable wax comprises known any wax in the cosmetic field, for example is derived from animal, plant, mineral and synthetic those waxes.Suitable wax includes but not limited to, rice bran wax, Brazil wax, ouricury wax, candelilla wax, montan wax, sugarcane wax, ceresine, Tissuemat E, Cera Flava, microwax or its combination in any.
The melting range of suitable wax is about 60 ℃ to about 110 ℃, preferred about 70 ° to about 90 ℃, the scope of needle penetration be about 1 to about 40, preferred about 3 arrive about 25, most preferably from about 5 to about 20.The needle penetration of wax is determined according to ASTM D 1321.The mixture of preferred hard wax and soft wax has mixed melting point and the needle penetration in preferable range.The mixture of Brazil wax, Cera Flava, ceresine and microwax most preferably.
In said composition, the amount of existing wax can increase the volume of eyelashes effectively and make compositions have resistance to water.Preferably, based on the gross weight of compositions, wax exists to about 35wt% with about 2wt%.More preferably, wax exists to about 30wt% with about 5wt%.Most preferably, based on the gross weight of compositions, wax exists to about 20wt% with about 10wt%.
Said composition contains the lanolin derivative of hydrophiling.The lanolin derivative of hydrophiling has enough hydrophobicitys, makes when the two is mixed, and it can be miscible with (fusing) wax.On the other hand, lanolin derivative is enough hydrophilic, makes it play adsorbent, to separate and keep water in wax, comprises the hydrophilic film agent, makes water be separated into discontinuous phase basically in wax and does not produce and be separated.The lanolin derivative of hydrophiling is with the functionalized lanoline of substituent group, to strengthen its hydrophilic degree (with respect to non-functionalized lanoline).The lanolin derivative of hydrophiling is functionalized to enough degree, so that it can bring into play the effect of effective absorbent.
The lanolin derivative of useful hydrophiling includes but not limited to, hydroxylated lanolin, hydrogenated lanolin, PEG-10 hydrogenated lanolin, acetylated lanolin, lanolin alcohol, lanolin fatty acid, PPG-2 lanoline ether and any combination thereof.Preferred hydroxylated lanolin is the OHlan that Amerchol company sells.
The amount of the lanolin derivative of hydrophiling is enough to adsorb water.The amount of the lanolin derivative of required hydrophiling will depend on the such factor of amount such as hydrophilic with the water that will adsorb of lanolin derivative.Typically, the lanolin derivative of hydrophiling arrives about 10wt% for about 0.1wt%.More typically, the lanolin derivative of hydrophiling arrives about 5wt% for about 0.5wt%.The most typically, based on the gross weight of compositions, the lanolin derivative of hydrophiling arrives about 4wt% for about 1wt%.
Said composition contains gellant.The function of gellant is to form anhydrous gel mutually with organic solvent in compositions.Preferred gellant is a clay.Useful clay includes but not limited to, bentonite, Strese Hofmann's hectorite., Kaolin and Montmorillonitum, and they are all widely in commercial sale.Particularly preferred gellant is a distearyl dimethylamine Strese Hofmann's hectorite., is sold with the title of Bentone 38V by Rheox.Suitable non-clay gellant comprises alkene/styrol copolymer, for example Versagel M and Versagel MC (buying from Penreco), Gel Base (buying from BrooksIndustries) and Allyl carbonate.
The amount of gellant is enough to form anhydrous gel mutually with organic solvent in said composition.Gellant is preferably about 0.5wt% to about 20wt%, most preferably is about 2wt% to about 5wt%.
The function of organic solvent is to form anhydrous gel mutually with gellant.Organic solvent also can be used for the dissolving wax component in formed compositions.Useful organic solvent includes but not limited to, Fancol ID (for example, the Permethyl 99A of Presperse Inc.), isoparaffin (for example, the solvent of selling with the trade name of Isopar), octadecane, annular dimethyl polysiloxane and combination thereof.
The anhydrous gel that exists in said composition provides waterproof coating on eyelashes and skin, demonstrate excellent in water resistance or water proofing property.When using, said composition is the form of gel.But because solvent comprises water and organic solvent evaporation, what stay on eyelashes or skin is wax shape film.Wax shape film produces with the water-soluble, film-forming hydrophilic polymer and a kind ofly is difficult to be disposed by water and film that wear resistance is very strong.When dying the eyelashes agent, because the contraction of film former after the solvent evaporation, said composition can provide the substantial benefit of volume and curling aspect.
The flash-point of this organic solvent is at least 30 ℃, preferred about 35 ℃ to about 90 ℃, most preferably from about 40 ℃ to about 60 ℃ (as recording) by ASTM D 6450 or ASTM D93.
Based on the gross weight of compositions, organic solvent arrives about 80wt% for about 5wt%, and more preferably from about 20wt% is to about 50wt%.
The said composition preferably water content in compositions is about 0.5 to about 25wt%.More preferably, based on the gross weight of compositions, the water content of said composition is about 15wt% or littler.Water is solvent or the diluent as the hydrophilic film agent.The hydrophilic film agent typically can provide soft and flexible film, and this film demonstrates good contractility, therefore can make crimping eyelash when water (with other volatile material) evaporates.
This make-up composition contains one or more pigment, pearling agent and/or coloring agent (this three is interchangeable term).Useful pigment and/or coloring agent comprise known any material in the cosmetic field.Also can carry out coating and surface treatment and dye light or the gloss of eyelashes with compositions display with enhancing.The example of useful pigment comprises titanium dioxide, zinc oxide, ferrum oxide, chromic oxide, high barba hispanica and Muscovitum; Organic pigment comprises barium, strontium, calcium or aluminum color lake, ultramarine and carbon black; Coloring agent comprises D﹠amp; C Green#3, D﹠amp; C Yellow#5 and D﹠amp; C Blue#1.Can or carry out surface treatment with one or more bulking agents coating pigment and/or coloring agent so that its be dispersed in water or the wax phase or this biphase in.Preferred pigment and/or coloring agent are with dimethicone instrument alcohol.
Pigment/pigment/colorant can exist with 1 to about 25wt.% the amount that accounts for compositions in said composition, and the gross weight that is preferably based on compositions is about 1 to about 15wt.% amount.
Optional one or more hydrophobicitys (resistance to water) film former that contains of said composition is to form film.The hydrophobic film-forming agent includes but not limited to, polyolefin, polyvinyl pyrrolidone polymers and copolymer, polyethylene, poly-alkyl, polystyrene, triglyceride, epoxy resin, Lac or its combination in any.Preferred hydrophobic film-forming agent is pentaerythritol abietate and polyvinylpyrrolidone/icosa alkene copolymer.In the above-mentioned wax some, for example Cera Flava, Brazil wax, ceresine and microwax also have the function of hydrophobic film-forming agent.The hydrophobic film-forming agent can be incorporated in anhydrous gel phase and/or the wax phase.
Compositions of the present invention is chosen wantonly and is contained a lot of fibers.When using this to dye eyelashes and use compositions, fiber is positioned on the surface of eyelashes.Fiber has increased the volume of eyelashes, has promptly increased its thickness and length.Fiber can be any known type in the cosmetic field, can be natural or synthetic.Thermoplastic fibre, for example those fibers of polyethylene, polypropylene or nylon are preferred.For reaching visual effect, fiber can be painted or surface treated.Fiber can be joined anhydrous gel, wax or water arbitrarily mutually in, but preferably join aqueous phase.
Said composition can contain one or more optional ingredients.Useful optional member includes but not limited to that plant extract, chelating agen, depigmenting agent, lubricant, firming agent, aromatic, wetting agent, polishing material be three isostearoyl polyglyceryl-3 dimer dilinoleic acid esters, humidizer, antiseptic, stabilizing agent, surfactant and vitamin for example.
This make-up composition can present the form of a lot of different products.Suitable product includes but not limited to, mascara, eyeliner, rouge and lip pomade/lip gloss.
In compositions of the present invention, keep anhydrous gel phase, wax phase and do not have the ratio of water, so that the final eyelashes that dye are this three's homogeneous mixture basically with compositions.In this respect, for water provides enough water, with the agent of dissolving hydrophilic film, the latter can provide the needed benefit that makes crimping eyelash of dying eyelashes with compositions.Wax phase comprises hydrophilicity lanolin, and it has enough hydrophilic so that the water in the compositions keeps evenly.Anhydrous gel provides the physical form of its gel for compositions.Although there is the hydrophilic film agent, wax phase provides a kind of water-proof coating with wear resistance and height of height with adsorbed water.
Based on the gross weight of compositions, no water accounts for the 70wt% of said composition to 95wt%, and preferably about 78wt% is to 90wt%.Wax phase accounts for about 4wt% to about 25wt%, and preferably about 10wt% is to about 20wt%.Water accounts for about 1wt% to about 25wt%, and preferably about 5wt% is to about 15wt%.
Of the present invention another is characterised in that preparation, and this dyes the eyelashes method for compositions.This method generally has the following step: form anhydrous gel, form wax phase, add anhydrous gel to form gel/wax mixture and add the water that contains the hydrophilic film agent in gel/wax mixture in wax phase.By being mixed with one or more gellant, one or more organic solvents prepare anhydrous gel.Randomly, can also for example poly methyl methacrylate (PMMA), Silicon stone and aluminium distearate and coloring agent join in the anhydrous gel with hydrophobicity (resistance to water) film former, filler and bulking agent.By with the lanolin derivative of one or more waxes and hydrophiling in the temperature that raises, preferably about 170-175 °F down mixing prepare wax phase.Randomly, also antiseptic and polishing material can be joined in the wax phase.In gel phase, add wax phase and mix with the fusing form.By being mixed with water, the hydrophilic film agent prepares water.Randomly, fiber and filler can be joined aqueous phase.Water is heated to the temperature of rising, and in the temperature that raises, joins in gel/wax mixture under preferred about 120 °F.Should be understood that above-mentioned disclosed temperature can change according to the physical property of wax.
Be embodiments of the invention below.
Embodiment
| Component | Compositions 1 (wt％) a，b | Compositions 2 (wt％) a，b | Compositions 3 (wt％) a，b |
| No water | |||
| Fancol ID | 60 | 50 | 35 |
| Pentaerythritol abietate | 5 | 6 | 8 |
| Bentonite 38V 1 | 1 | 2 | 5 |
| Allyl carbonate | 1 | 1.2 | 2 |
| Silicon stone | 5 | 2 | |
| PMMA | 10 | ||
| Wax phase | |||
| Brazil wax | 5 | 4 | 5 |
| Cera Flava | 5 | 4 | 4 |
| Ceresine | 2 | 1.5 | 4 |
| Microwax | 1 | 1.5 | 3 |
| Antiseptic | 0.9 | 0.9 | 0.9 |
| Hydroxylated lanolin 2 | 4 | 3.6 | 5 |
| Pigment | 4 | 6 | 6 |
| Fiber (nylon) | 0.5 | 0.9 | 0.8 |
| TPDD 6 | 1.5 | 1.5 | 1.5 |
| Hydrogenated polydecene 7 | 1.2 | 1.2 | 1.2 |
| Water | |||
| Hydrophilic polymer | 1.2 3 | 0.5 4 | 0.8 5 |
| Distilled water | Q.S. | Q.S. | Q.S. |
| 100％ | 100％ | 100％ |
aPercentage ratio is based on the basis of " can accept ", has marked the active matter that can accept in the material on footnote.If do not mark, active matter is 100%.
bThe percentage by weight of total composition
1Elementis Specialties, the distearyl dimethylamine Strese Hofmann's hectorite. of Inc
2The OHlan of Amerchol Corp
3Polyimides-1 can use the Aquaflex XL-30 (aqueous dispersions of 30% active matter) of ISP.
4Polyquaternary ammonium salt-7 can use the SalcareSuper 7 (30% active matter) of Ciba Specialty Chemicals.
5Acrylate copolymer can use the Daitosol 5000AD (aqueous dispersions of 30% active matter) of Daito Kasei.
6The three isostearoyl polyglyceryl-3 dimer dilinoleic acid esters that Scher Chemicals as Schercemol PTID sells.
7Shamrock Technologies, the Ceraflow E that Inc makes
Propylene carbonate solvent is heated to about 170-175 °F, and Bentone 38V clay and pentaerythritol abietate are sneaked into.Mix pigment, filler (Silicon stone and PMMA) then to obtain anhydrous gel premix mutually.Several waxes are heated to more than their fusing point to about 75-80 ℃ and also under agitation add antiseptic and hydroxylated lanolin, TPDD hydrogenated polydecene.Under this temperature, the wax phase premix joined anhydrous gel phase premix then.Mixture is cooled to 65-70 ℃.The preparation water comprises adding hot water and hydrophilic film agent to about 65-70 ℃, joins in the mixture, and stirs 10 minutes.Then mixture is cooled to room temperature.
Above-mentioned composition can be applied on the eyelashes so that it curls, extends, thickens with painted.
Should be understood that foregoing description only is an explanation of the present invention.Those skilled in the art can make different alternative and changes and not break away from the present invention.Therefore, this invention is intended to comprise that all these substitute, change and change, they all drop in the scope of appended claim.
Claims (26)
1. make-up composition comprises:
The anhydrous gel that contains gellant and organic solvent mutually;
The water that contains hydrophilic film agent and water;
The wax phase that contains the lanolin derivative of wax and hydrophiling,
Wherein anhydrous gel phase, water and wax phase mix basically equably, and the lanolin derivative of wherein hydrophiling exists with the amount that is enough to adsorb water.
2. the compositions of claim 1, wherein the hydrophilic film agent is selected from cation type polymer, anionic polymer and non-ionic polyalcohol.
3. the compositions of claim 2, wherein the hydrophilic film agent is a cation type polymer.
4. the compositions of claim 3, wherein cation type polymer is selected from polyquaternary ammonium salt-4, polyquaternary ammonium salt-5, polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, polyquaternary ammonium salt-22 and any combination thereof.
5. the compositions of claim 2, wherein the hydrophilic film agent is an anionic polymer, is selected from acrylamide copolymer, acrylate/EHA copolymer, acrylate copolymer, acrylate/nvp copolymer, sodium acrylate copolymer and any combination thereof.
6. the compositions of claim 2, wherein the hydrophilic film agent is a non-ionic polyalcohol, is selected from polyurethane-1, polyimides-1, adipic acid/PPG-10 copolymer and any combination thereof.
7. the compositions of claim 1, wherein based on the gross weight of compositions, the hydrophilic film agent is arrived about 2wt% for about 0.1wt%.
8. the compositions of claim 1, wherein based on the gross weight of compositions, the hydrophilic film agent is arrived about 1.5wt% for about 0.1wt%.
9. the compositions of claim 1, wherein based on the gross weight of compositions, the hydrophilic film agent is arrived about 1wt% for about 0.1wt%.
10. the compositions of claim 1, wherein the lanolin derivative of hydrophiling is selected from hydroxylated lanolin, hydrogenated lanolin, acetylated lanolin, PEG-10 hydrogenated lanolin, acetylated lanolin, lanolin alcohol, lanolin fatty acid, PPG-2 lanoline ether and any combination thereof.
11. the compositions of claim 10, wherein the lanolin derivative of hydrophiling is a hydroxylated lanolin.
12. the compositions of claim 1, wherein based on the gross weight of compositions, the lanolin derivative of hydrophiling arrives about 10wt% for about 0.1wt%.
13. the compositions of claim 1, wherein based on the gross weight of compositions, the lanolin derivative of hydrophiling arrives about 5wt% for about 0.5wt%.
14. the compositions of claim 1, wherein based on the gross weight of compositions, the lanolin derivative of hydrophiling arrives about 4wt% for about 1wt%.
15. the compositions of claim 1, wherein wax is selected from Cera Flava, Brazil wax, microwax, ceresine and combination thereof.
16. the compositions of claim 1, wherein based on the gross weight of compositions, wax arrives about 35wt% for about 8wt%.
17. the compositions of claim 1 further comprises coloring agent or pigment.
18. the compositions of claim 1 further comprises fiber.
19. the compositions of claim 1, wherein gellant is a clay.
20. the compositions of claim 19, its medium clay soil is selected from bentonite, Strese Hofmann's hectorite., Kaolin and Montmorillonitum.
21. the compositions of claim 1, wherein based on the gross weight of compositions, gellant arrives about 20wt% for about 0.5wt%.
22. the compositions of claim 1, wherein organic solvent is selected from Fancol ID, Allyl carbonate, isoparaffin and combination thereof.
23. the compositions of claim 1, wherein based on the gross weight of compositions, organic solvent arrives about 80wt% for about 5wt%.
24. one kind makes crimping eyelash and/or method of colouring, comprises being applied on the eyelashes with the compositions part dying eyelashes, wherein this dyes eyelashes and comprises with compositions
Coloring agent or pigment;
The anhydrous gel that contains gellant and organic solvent mutually;
The water that contains hydrophilic film agent and water; With
The wax phase that contains the lanolin derivative of wax and hydrophiling,
Wherein anhydrous gel phase, water and wax phase are mixed basically equably, and the lanolin derivative of wherein hydrophiling exists with the amount that is enough to adsorb water.
25. one kind prepares and dyes the eyelashes method for compositions, comprises
A) organic solvent is mixed with gellant with the preparation anhydrous gel;
B) wax phase that at elevated temperatures the lanolin derivative mixing of wax and hydrophiling is melted with preparation;
C) wax phase and the gel phase with fusing mixes with preparation gel/wax mixture;
D) in the arbitrary steps of step a, b or c, mix pigment or coloring agent.
E) hydrophilic film agent and water are mixed with the preparation water;
F) randomly that fiber is mixed with water;
G) at elevated temperatures water and gel/wax mixture are mixed;
H) cool off the mixture that in step g, obtains.
26. a make-up composition comprises:
Organic solvent;
The gellant that is used for this organic solvent;
The hydrophilic film agent;
Water;
Wax; With
The lanolin derivative of hydrophiling,
Wherein with the lanolin derivative of organic solvent, gellant, hydrophilic film agent, water, wax and hydrophiling uniform mixing basically, wherein the amount of adsorbed water and hydrophilic film agent exists the lanolin derivative of hydrophiling to be enough to basically.
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| CN102596323A (en) * | 2009-10-27 | 2012-07-18 | 宝洁公司 | Methods of coating eyelashes and eyelids with a long-wearing mascara composition |
| CN103379891A (en) * | 2010-10-27 | 2013-10-30 | 宝洁公司 | Semi-permanent mascara compositions |
| CN104224560A (en) * | 2009-10-27 | 2014-12-24 | 宝洁公司 | Long-wear mascara compositions |
| CN106794135A (en) * | 2014-08-28 | 2017-05-31 | 欧莱雅 | Gel-type cosmetic composition with the confining force for improving |
| CN110461300A (en) * | 2017-03-20 | 2019-11-15 | 总和营销服务 | The gelatine composition of biological source |
| CN111278407A (en) * | 2018-02-07 | 2020-06-12 | 株式会社资生堂 | Solid W/O cosmetic composition |
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| CN102596323A (en) * | 2009-10-27 | 2012-07-18 | 宝洁公司 | Methods of coating eyelashes and eyelids with a long-wearing mascara composition |
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| CN103379891A (en) * | 2010-10-27 | 2013-10-30 | 宝洁公司 | Semi-permanent mascara compositions |
| US10034829B2 (en) | 2010-10-27 | 2018-07-31 | Noxell Corporation | Semi-permanent mascara compositions |
| CN106794135A (en) * | 2014-08-28 | 2017-05-31 | 欧莱雅 | Gel-type cosmetic composition with the confining force for improving |
| CN106794135B (en) * | 2014-08-28 | 2020-12-22 | 欧莱雅 | Gel-type cosmetic composition with improved retention |
| US11311465B2 (en) | 2014-08-28 | 2022-04-26 | L'oreal | Gel-type cosmetic composition with improved staying power |
| CN110461300A (en) * | 2017-03-20 | 2019-11-15 | 总和营销服务 | The gelatine composition of biological source |
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