CN101270486B - Electrolytic deposition metal peeling method and bending apparatus using the method - Google Patents

Electrolytic deposition metal peeling method and bending apparatus using the method Download PDF

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CN101270486B
CN101270486B CN2007101960770A CN200710196077A CN101270486B CN 101270486 B CN101270486 B CN 101270486B CN 2007101960770 A CN2007101960770 A CN 2007101960770A CN 200710196077 A CN200710196077 A CN 200710196077A CN 101270486 B CN101270486 B CN 101270486B
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electrolytic deposition
deposition metal
negative plate
make
gap
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CN101270486A (en
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牧公一
金田贵光
上野明
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Nippon Mining and Metals Co Ltd
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Abstract

The invention provides an electrolytically deposited metal stripping method and curving device using the same which makes a dependable insertion of a shovel as it is hindered by closing the clearance between a negative plate and electrolytically deposited metal caused by the opened electrolytically deposited metal re-jointing with the negative plate closely. Its characteristics is that, a curving process for opening and outward bending the upper side of the electrolytically deposited metal is set up before a stripping process of inserting the shovel (35) between the electrolytically deposited metal (2) and the negative plate (1), the curving device (10) comprises: a lower guider (21) for maintaining lower side of the negative plate from two sides thereof; an upper guider (25) which is mounted at upper side of the negative plate and mounts the part to be curved near the surface of the electrolytically deposited metal; a pushing component (23) for pushing a part adjacent to a central part of the negative plate from left to right; and a curving component (29) for bending the upper side to ensure an easy insertion into a clearance of the shovel.

Description

Electrolytic deposition metal stripping means and this method are used makes bending apparatus
Technical field
The present invention relates to electrolytic deposition metal stripping means and the employed bending apparatus of making thereof, more particularly, relate to a kind of from by electrorefining electrodeposit in its surface the negative plate of metal peel off the electrolytic deposition metal stripping means and the employed bending apparatus of making thereof of electrolytic deposition metal.
Background technology
Use for example electrolytic copper refining of electrolytic etching of metal refining that permanent cathode (PC) carries out in ISA (permanent stainless steel cathode) mode, being positive plate alternating impregnating that the negative plate and the blister copper of a plurality of stainless steel manufacturings are cast switches in storage has the electrolyzer of electrolytic solution, thereby makes electrolytic copper 2 electrodeposits on the two sides of negative plate.Afterwards, electrodeposit is peeled off with stripping off device at the lip-deep electrolytic copper 2 of negative plate and obtain finished product.Specifically, as shown in Figure 1, negative plate 1 is the plate-shaped member that stainless steel is made, and intercalation has the sheath 5 that synthetic resins is made on its both sides, and the end is provided with cross bar 4 thereon.In addition, be provided with two windows 3,3 in the bottom of cross bar 4, hang in this window 3,3, can put it into electrolyzer and from electrolyzer, take out and carry by the hook that makes not shown electrode plate transportation apparatus.The negative plate 1 of stainless steel manufacturing is very solid and can reuse, and has the advantage that is not easy to be short-circuited when carrying out electrorefining owing to having good planarity, thereby is widely adopted in recent years.In addition, 2 two of electrolytic coppers that strip down from two faces of negative plate 1 respectively are one group to be carried with e Foerderanlage, for guaranteeing that its planarity carries out temper pressure processing to it, carry out ripple processing again and make and form wavy concavo-convexly on the electrolytic copper, make finished product like this and provided.
In the past, for example peeling off of electrolytic deposition metal carried out shown in TOHKEMY 2006-274299 communique (patent documentation 1) like that.That is, the negative electrode edges of boards that will raise up from electrolyzer are carried after the limit cleans in the purge chamber, move with the transfer machine to be put on the handling machinery that traverses.Afterwards, as shown in Figure 2, make negative plate 1 on the pedestal 120 of stripping off device, keep upright state (Fig. 2 (a)), the both sides of anticathode plate 1 with pusher 36 from about push (Fig. 2 (b)), thereby make negative plate 1 and electrolytic deposition metal 2 the two generation distortion difference and between negative plate 1 and electrolytic deposition metal 2, produce gap (deflection), to cut a hole shovel 35 and insert (Fig. 2 (c)) and downward cutter among this gap, make electrolytic deposition metal 2 peel off (cutter shovel) from negative plate 1, sectional fixture 37 on the electrolytic deposition metal 2 that strips down, with its with pedestal 120 contacted bottoms be that fulcrum is pulled (breaking branch (down end) off with the fingers and thumb) down, thereby electrolytic deposition metal 2 is stripped down (Fig. 2 (d)) from negative plate 1.Can't under isolating situation on the negative plate, to carry out once more cocked " turnover (flappling) " pulled down again of electrolytic deposition metal being separated the two through breaking that the branch electrolytic deposition metal does not rupture off with the fingers and thumb.
As above-mentioned existing stripping off device, for example open in TOHKEMY 2001-81591 communique (patent documentation 2).This stripping off device comprises: will be installed in the insulating sheath stripping assembly that the part of the insulating sheath on the end of negative plate disassembles; Be inserted into from the position at that part of insulating sheath place that disassembles between the negative plate that is fixed on the certain position and the electrolytic deposition metal and make the end edge portion of electrolytic deposition metal separate the chisel that is set as the state of dehiscing from negative plate; And be adsorbed on the electrolytic deposition metal and a plurality of vacuum suck pads that electrolytic deposition metal is moved to direction of delaminate.Its principle of work is, chisel is pressed between the end edge portion of negative plate surface and electrolytic deposition metal, utilizes the wedge effect of wedge-like chisel that electrolytic deposition metal is peeled off from negative plate, makes the end edge portion of electrolytic deposition metal be the state of dehiscing.The electrolytic deposition metal that is the state of dehiscing is carried out sticking with a plurality of vacuum suck pads it is drawn back (turnover) from negative plate, thereby finish peeling off of electrolytic deposition metal.
But, up to now, the pedestal of mounting negative plate all is tabular, thereby when peeling off electrolytic deposition metal, negative plate can only reach 90 ° with respect to the negative plate maximum by breaking the angle that the branch operation pulls electrolytic deposition metal down off with the fingers and thumb, sometimes electrolytic deposition metal can't be stripped down fully by one-stop operation, and must carry out once again and even repeatedly turnover.Though through once and even repeatedly turning down and can from negative plate electrolytic deposition metal be stripped down, the carrying out of turnover need correspondingly expend more times, exist the shortcoming of the treatment capacity minimizing of unit time.Specifically, peeling off of electrolytic deposition metal can be do not finished, a slice can be finished in then about 7 seconds if do not turn down just.Therefore, 4000~5000 lift-off processing can be on average carried out in about operation of 8~10 hours in a day.Once turnover among a series of overburden operations will approximately expend 2 seconds, if thereby a slice negative plate carried out several turnover repeatedly, then one day processing sheet number reduces, and will have influence on operating efficiency.
For this reason, the applicant has invented following electrolytic deposition metal stripping off device and has carried out patent application, promptly, a kind of electrolytic deposition metal stripping off device is provided, wherein, both sides at the pedestal of mounting negative plate are provided with jut, contact with this jut by the lower side surface that makes the electrolytic deposition metal of peeling off along with the lodging of negative plate, make the rising wood of electrolytic deposition metal lodge at least than jut more by the position of downside, electrolytic deposition metal is separated from described negative plate, like this, do not need to turn down, can make deflection, the cutter shovel, break a series of operations that grade when negative plate is peeled off electrolytic deposition metal off with the fingers and thumb and once finish (Japanese Patent Application 2006-266326 number).
[patent documentation 1] TOHKEMY 2006-274299 communique
[patent documentation 2] TOHKEMY 2001-81591 communique
As mentioned above, the stripping off device according to the electrolytic deposition metal of the application's applicant invention needn't turn down, thereby realize efficiently peeling off of electrolytic deposition metal.
But, such problem takes place sometimes, promptly, after between negative plate 1 and electrolytic deposition metal 2, having produced the gap by deflection (Fig. 2 (b)), the actual cutter shovel that inserts carries out before the peeling off of electrolytic deposition metal, electrolytic deposition metal can fit tightly with negative plate again, causes being used for inserting the gap of cutting a hole shovel and makes up.So, can't cut a hole shovel and have to send this battery lead plate back to the deflection operation again, this is to cause one of reason that operating efficiency reduces.Peeling off of electrolytic deposition metal can be finished a slice in generally about 7 seconds.Therefore, about operation of 8~10 hours in a day on average can be finished 4000~5000 lift-off processing, and one day processing sheet number will reduce if a slice negative plate expends the extra time, and nature will have influence on operating efficiency.
Summary of the invention
For this reason, the objective of the invention is, a kind of electrolytic deposition metal stripping means and the employed bending apparatus of making thereof are provided, can prevent the electrolytic deposition metal of having dehisced again and the negative plate problem that fits tightly, cause the gap between negative plate and the electrolytic deposition metal to make and hinder the insertion of cutter shovel up, thereby can insert reliably by the cutter shovel.
In order to address the above problem, technical scheme 1 described the present invention is a kind of electrolytic deposition metal stripping means, from by electrorefining electrodeposit in its surface the negative plate of metal peel off this electrolytic deposition metal, it is characterized in that, cutting a hole that shovel inserts between electrolytic deposition metal and the negative plate before the stripping process of peeling off, be provided with and make curved operation, make in the curved operation at this, the upper side that makes electrolytic deposition metal is crooked laterally and make and dehisce between this upper side and the negative plate, thereby guarantees to be used for the gap that makes the cutter shovel be easy to insert.
For addressing the above problem, technical scheme 2 described the present invention, in technical scheme 1 described electrolytic deposition metal stripping means, it is characterized in that, in making curved operation, there is the following portion of the both certain portions guider of lower side of the negative plate of metal to keep to being positioned in electrodeposit on the pedestal from both sides, and, should make curved part corresponding to the upper side of electrolytic deposition metal, the position that separates slight gap on the surface from electrolytic deposition metal is provided with upper deflector, by near the central part of electrolytic deposition metal from about push with push part, make and produce the gap between electrolytic deposition metal and the negative plate, to make turn of bilge spare and insert in this gap, make that the upper side of electrolytic deposition metal is the fulcrum bending with the upper deflector, thereby guarantee to be used for making cutter to shovel the gap that is easy to insert.
For addressing the above problem, technical scheme 3 described the present invention, that uses in technical scheme 1 or 2 described electrolytic deposition metal stripping meanss makes bending apparatus, it is characterized in that, comprise: lower deflector has both certain portions of lower side of the negative plate of electrolytic deposition metal to keep from both sides to being positioned in electrodeposit on the pedestal; Upper deflector, corresponding to be positioned in electrodeposit on the pedestal have electrolytic deposition metal negative plate upper side should make curved part, be configured in from the surface of electrolytic deposition metal and separate on the position of slight gap; Push part, near the central part of negative plate that is positioned in electrodeposit on the pedestal and has electrolytic deposition metal from about push, the two is dehisced and produce the gap between them thereby make electrolytic deposition metal and negative plate; And make turn of bilge spare, and be inserted into by making in the two gap of dehiscing to form of electrolytic deposition metal and negative plate, make that the upper side of electrolytic deposition metal is the fulcrum bending with the upper deflector, thereby guarantee to be used for making cutter to shovel the gap that is easy to insert.
According to electrolytic deposition metal stripping means of the present invention, before will cutting a hole the stripping process of peeling off between shovel insertion electrolytic deposition metal and the negative plate, thereby it is crooked laterally and make the curved operation of making of dehiscing to guarantee to be used for to make gap that the cutter shovel is easy to insert between this upper side and the negative plate to be provided with the upper side that makes electrolytic deposition metal, therefore, have and the cutter shovel can be inserted between negative plate and the electrolytic deposition metal reliably, the effect that the operation of cutter shovel is carried out continuously.
In addition, according to the bending apparatus of making of the present invention, there are both certain portions of lower side of the negative plate of electrolytic deposition metal to keep with lower deflector to being positioned in electrodeposit on the pedestal from both sides, and, corresponding to being positioned in electrodeposit on the pedestal upper side of the negative plate of electrolytic deposition metal is arranged, should make curved part, the position that separates slight gap on the surface from electrolytic deposition metal is provided with upper deflector, by near the central part of negative plate that is positioned in electrodeposit on the pedestal and has electrolytic deposition metal from about push with push part, make electrolytic deposition metal and negative plate the two dehisce and between them, produce the gap, to make turn of bilge spare inserts in this gap, the upper side that makes electrolytic deposition metal is the fulcrum bending with the upper deflector, thereby guarantee to be used for making cutter to shovel the gap that is easy to insert, thereby have the effect that the gap after dehiscing can not be made up.Therefore, the operation of cutter shovel can not hindered and can be carried out continuously.
Description of drawings
Fig. 1 is the approximate three-dimensional map that the negative plate that electrolytic deposition metal is arranged is separated out on the surface.
Fig. 2 is the explanatory view that the overburden operation that utilizes existing stripping off device to carry out is showed.
Fig. 3 is the front view of an embodiment making bending apparatus involved in the present invention.
Fig. 4 is a side-view of making bending apparatus shown in Figure 3.
Fig. 5 is an A-A sectional view of making bending apparatus shown in Figure 3.
Fig. 6 (a)~(e) is the explanatory view that the operation of making in the curved operation is showed.
Fig. 7 is the schema of an embodiment of electrolytic deposition metal stripping means involved in the present invention.
Description of reference numerals
1 negative plate
2 electrolytic deposition metals
3 windows
4 cross bars
5 sheaths
10 make bending apparatus
11 bases
12 pillars
13 crossbeams
20 pedestals
21 lower deflector
23 push part
The 23a hydro-cylinder
25 upside guiders
29 make turn of bilge spare
The 29a hydro-cylinder
The 29b guide rod
30 stripping off devices
35 cutter shovels
36 pushers
37 anchor clamps
G ground
Embodiment
Below, electrolytic deposition metal stripping means involved in the present invention and the employed bending apparatus of making thereof are elaborated in conjunction with the accompanying drawings.Fig. 3 is the front view of an embodiment making bending apparatus involved in the present invention, and Fig. 4 is its side-view, and Fig. 5 is its A-A sectional view.
The illustrated bending apparatus 10 of making is arranged in the stripping off device operation before of peeling off electrolytic deposition metal 2, substantially by erectting 4 pillars 12 being provided with on the base 11 that is arranged on the ground G and the crossbeam 13 that they link up in the horizontal direction being formed skeleton construction, in the substantial middle of this framework, being provided with has the pedestal 20 of the negative plate 1 of electrolytic deposition metal 2 with the upright state mounting with electrodeposit.In addition, on the top that is close to pedestal 20, about two places be provided with lower deflector 21 respectively.Lower deflector 21 can move up by the right and left at Fig. 4 under the driving of not shown hydro-cylinder, to the lower side that is positioned in the negative plate 1 on the pedestal 20 from about clamp and keep securely.
In addition, at the upper side of lower deflector 21, about two places be provided with push part 23 respectively, can near the substantial middle portion that is positioned in the negative plate 1 on the pedestal 20 from about push.As shown in Figure 5, push part 23 can move up by the right and left at Fig. 5 under the driving of hydro-cylinder 23a, near the substantial middle portion of anticathode plate 1 with push part 23 from about push and the upper side that makes electrolytic deposition metal 2 is peeled off and dehisced from negative plate 1, make the turn of bilge spare 29 of making described later can insert during this dehisces.In addition, as shown in Figure 5, push part 23 can be carried out angular setting with respect to the negative plate 1 that is positioned on the pedestal 20 with respect to travel direction in ± 10 ° angular range.
Have again, in the upper side of push part 23, about two places be provided with upper deflector 25 respectively.Upper deflector 25 can move up by the right and left at Fig. 4 under the driving of not shown hydro-cylinder, be positioned at the negative plate 1 that is positioned on the pedestal 20 upper side, should make near the curved part.And, be inserted in the formed gap by making the turn of bilge spare 29 of making described later, electrolytic deposition metal 2 is contacted with upper deflector 25, thereby the top of electrolytic deposition metal 2 is that the fulcrum bending is made curved with upper deflector 25.Thus, can prevent that electrolytic deposition metal 2 from fitting tightly with negative plate 1 again.
On the crossbeam 13 of the more upper side of pedestal 20, be provided with to be inserted into and make turn of bilge spare 29 in the upper side gap that between negative plate 1 and electrolytic deposition metal 2, produces by the pushing of push part 23.Be inserted into by the pushing of push part 23 in the upper side gap that between negative plate 1 and electrolytic deposition metal 2, produces making turn of bilge spare 29, can make electrolytic deposition metal 2 upper side with upper deflector 25 be fulcrum crooked laterally make curved, thereby the gap that guarantees to be used for to make the cutter shovel of stripping off device to be easy to insert.Thus, can prevent that electrolytic deposition metal from fitting tightly with negative plate again and the generation of such a case is made in the gap that causes inserting cutter shovel up.
Make turn of bilge spare 29 and be installed in lower side to the guide rod 29b of the mobile channeling conduct of above-below direction, guide rod 29b forms in the mode that can move up and down under the driving of hydro-cylinder 29a.Thus, make that making turn of bilge spare 29 can move up and down.Make turn of bilge spare 29 and be that terminad comes to a point gradually, the cross section leg-of-mutton wedge shape that roughly meets at right angles,, make the upper side bending of electrolytic deposition metal 2 by being inserted in the gap between electrolytic deposition metal 2 and the negative plate 1 and pressurization down pushes.Like this, make the upper side bending that turn of bilge spare 29 will make electrolytic deposition metal 2, thereby preferably form by mechanically resistant material.Form by SUS304 in the present embodiment.
To describe in conjunction with a preferred implementation of electrolytic deposition metal stripping means involved in the present invention for the principle of work of making bending apparatus 10 that as above constitutes.Fig. 6 is the summary side elevation of making in each curved operation, and Fig. 7 is the schema of a preferred implementation of electrolytic deposition metal stripping means involved in the present invention.
At first, after negative plate 1 cleaned in not shown purge chamber, be transported to by not shown e Foerderanlage and make bending apparatus 10 (step S0).Be positioned on the pedestal 20 being transported to the negative plate 1 of making bending apparatus 10, the driving by not shown hydro-cylinder keeps (Fig. 6 (a)) (step S1) with lower deflector 21 from both sides to its underpart side.
Afterwards, make upper deflector 25 be moved in the driving of not shown hydro-cylinder the negative plate 1 that is positioned on the pedestal 20 the left and right sides upper side, should make near the curved part.
Then, drive push part 23 with hydro-cylinder 23a and near the substantial middle portion of negative plate 1, alternately move (Fig. 6 (b)), push respectively from the left and right sides (step S2).Thus, the upper side that makes electrolytic deposition metal 2 is peeled off and is dehisced from negative plate 1.Afterwards, move to the lower side, make and make turn of bilge spare 29 and be inserted in the part of dehiscing (Fig. 6 (c)) with hydro-cylinder 29a drive leader 29b.Be that terminad comes to a point gradually, the cross section leg-of-mutton wedge shape that roughly meets at right angles owing to make turn of bilge spare 29, so push by being inserted in the portion of dehiscing between electrolytic deposition metal 2 and the negative plate 1 and pressurizeing downwards, make the upper side of electrolytic deposition metal 2 contact with upper deflector 25, the top of electrolytic deposition metal 2 is that curved (step S3) made in the fulcrum bending with upper deflector 25.Thus, can prevent that electrolytic deposition metal 2 from fitting tightly with negative plate 1 again.The negative plate of making after curved operation is finished 1 is sent into (Fig. 6 (d)) in the stripping off device 30 then, cut a hole shovel, break these a series of operations of branch (Fig. 6 (e)) off with the fingers and thumb.Through making curved operation, the upper bend of electrolytic deposition metal 2 and dehiscing, thereby can have any obstruction ground and do not cut a hole the shovel operation, from negative plate 1, reliably electrolytic deposition metal 2 is stripped down (step S4).
As mentioned above, according to electrolytic deposition metal stripping means involved in the present invention and the employed bending apparatus of making thereof, thereby the electrolytic deposition metal after can preventing to dehisce again and negative plate fits tightly and cause the gap between negative plate and the electrolytic deposition metal to make the problem that hinders the insertion of cutting a hole shovel up, the cutter shovel can be inserted reliably, therefore, the operation of cutter shovel can be carried out without hindrance continuously.
More than have been described in detail with regard to preferred implementation of the present invention, but the present invention is not limited to related specific embodiment, and is unquestionable, can also carry out various modification and change in the aim scope of the present invention that claims are put down in writing.

Claims (2)

1. electrolytic deposition metal stripping means, from by electrorefining electrodeposit in its surface the negative plate of metal peel off this electrolytic deposition metal,
Cutting a hole that shovel inserts between electrolytic deposition metal and the negative plate before the stripping process of peeling off, be provided with and make curved operation, make in the curved operation at this, the upper side that makes described electrolytic deposition metal is crooked laterally and make and dehisce between this upper side and the described negative plate, thereby guarantee to be used for making described cutter to shovel the gap that is easy to insert, it is characterized in that
Make in the curved operation described,
There is the following portion of the both certain portions guider of lower side of the negative plate of metal to keep to being positioned in electrodeposit on the pedestal from both sides, and, should make curved part corresponding to the upper side of electrolytic deposition metal, the position that separates slight gap on the surface from this electrolytic deposition metal is provided with upper deflector, by near the central part of described electrolytic deposition metal from about push with push part, make and produce the gap between electrolytic deposition metal and the negative plate, to make turn of bilge spare inserts in this gap, make that the upper side of electrolytic deposition metal is the fulcrum bending with described upper deflector, thereby guarantee to be used for making described cutter to shovel the gap that is easy to insert.
2. that uses in the electrolytic deposition metal stripping means that a kind is put down in writing as claim 1 makes bending apparatus, it is characterized in that,
Comprise:
Lower deflector has both certain portions of lower side of the negative plate of electrolytic deposition metal to keep from both sides to being positioned in electrodeposit on the pedestal;
Upper deflector, corresponding to be positioned in electrodeposit on the pedestal have electrolytic deposition metal negative plate upper side should make curved part, be configured in from the surface of described electrolytic deposition metal and separate on the position of slight gap;
Push part, near the central part of negative plate that is positioned in electrodeposit on the pedestal and has electrolytic deposition metal from about push, the two is dehisced and produce the gap between them thereby make electrolytic deposition metal and negative plate;
And make turn of bilge spare, be inserted into by making in the two described gap of dehiscing to form of described electrolytic deposition metal and described negative plate, make that the upper side of electrolytic deposition metal is the fulcrum bending with described upper deflector, thereby guarantee to be used for making described cutter to shovel the gap that is easy to insert.
CN2007101960770A 2007-03-20 2007-11-30 Electrolytic deposition metal peeling method and bending apparatus using the method Active CN101270486B (en)

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JP2007072177A JP4294058B2 (en) 2007-03-20 2007-03-20 Electrodeposition metal stripping method and brazing apparatus used therefor

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CN101717973A (en) * 2009-12-23 2010-06-02 江西瑞林装备技术有限公司 Stripping device for stainless steel cathode
JP2012036415A (en) * 2010-08-03 2012-02-23 Mesco Inc Method and apparatus for stripping off laminated article
CN101994134B (en) * 2010-11-25 2013-04-03 三门三友冶化技术开发有限公司 Edge clamping strip correcting device
JP5565337B2 (en) * 2011-02-15 2014-08-06 住友金属鉱山株式会社 Electrodeposition metal stripping device
JP5565342B2 (en) * 2011-03-03 2014-08-06 住友金属鉱山株式会社 Electrodeposition metal peeling apparatus and electrodeposition metal separation apparatus using the same
WO2014103393A1 (en) * 2012-12-28 2014-07-03 三井金属エンジニアリング株式会社 Electrodeposited metal-stripping device and electrodeposited metal-stripping method
JP5974966B2 (en) * 2013-04-17 2016-08-23 住友金属鉱山株式会社 Electrodeposition metal peeling apparatus and electrodeposition metal peeling method
CN106048646B (en) * 2016-08-15 2018-01-23 广西大学 Electrolytic manganese dioxide automates stripping off device
JP7272147B2 (en) * 2019-07-05 2023-05-12 住友金属鉱山株式会社 Electrolytic refining method for non-ferrous metals
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CL2007003882A1 (en) 2008-09-26
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JP4294058B2 (en) 2009-07-08
JP2008231501A (en) 2008-10-02
AU2007237222B2 (en) 2010-04-01

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Address after: No. 10-4, erdingmu, tiger gate, Tokyo port, Japan

Patentee after: JKS Metal Co.,Ltd.

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