CN101269722A - Super-slide type biaxial tension polypropylene thin film for easy-quit package retraction tobacco - Google Patents
Super-slide type biaxial tension polypropylene thin film for easy-quit package retraction tobacco Download PDFInfo
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- CN101269722A CN101269722A CNA2008100200093A CN200810020009A CN101269722A CN 101269722 A CN101269722 A CN 101269722A CN A2008100200093 A CNA2008100200093 A CN A2008100200093A CN 200810020009 A CN200810020009 A CN 200810020009A CN 101269722 A CN101269722 A CN 101269722A
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Abstract
The invention relates to a super-smooth type dual-direction extension polypropylene film used by a retractable cigarette with the package easy to be taken down, comprising a structure of an upper layer, an intermediate layer and a lower layer. The upper layer is added with macromolecular silicone accounting for 1 to 3 percent Mw (namely more than 100,000) of the total weight of polypropylene biopolymer basal material as lubricant and 0.1 to 0.5 percent of cross-link methyl acrylate as anti-adhesiveness agent. The intermediate layer is added with hydrogen oil resin accounting for 10 to 30 percent of the total weight of the polypropylene basal material as erection strengthening agent and 0.2-1.0 percent of alkyl (C14-18) double (2-hydroxyethyl group) amine as anti-static agent. The lower layer is added with macromolecular silicone accounting for 1 to 3 percent Mw (namely more than 100,000) of the total weight of polypropylene triopolymer basal material as lubricant and 0.1 to 0.5 percent of cross-link methyl acrylate as anti-adhesiveness agent. The film has small internal friction and good erection and static electricity prevention, and can enable the cigarette package to be easily taken down from the film.
Description
Technical field
The present invention relates to a kind of cigarette film, especially relate to the easy return-charge retraction tobacco of a kind of super smooth type Biaxially oriented polypropylene film.Belong to field of packaging material.
Background technology
Cigarette is a high-end product in the Biaxially oriented polypropylene product with film always.Because it is the package speed of cigarette machine is very fast, very high with the requirement of film to cigarette.Film will have: the ability of outer good smooth performance, higher shrinkage percentage, good optical property, good various cigarette machines of adaptation.Raising along with people's living standard, people pay attention to the external packing of product more, the up-to-date technology of packing industry is also in continuous progress, present cigarette increases attractive in appearance with technology such as having adopted epoxy resin glazing, radium-shine paperboard, multiple film paperboard on the paperboard mostly, and the cigarette of using before is all bigger with the film internal friction, after above-mentioned in addition paperboard and the shrink film packing adsorption effect is arranged, tobacco bale is difficult to withdraw from from film, and using to people makes troubles.
Summary of the invention
The objective of the invention is to overcome above-mentioned deficiency, provide a kind of internal friction very little (≤0.13N/m) the easy return-charge retraction tobacco of super smooth type Biaxially oriented polypropylene film.
The object of the present invention is achieved like this: the easy return-charge retraction tobacco of a kind of super smooth type Biaxially oriented polypropylene film, be divided into upper epidermis, interlayer and following top layer three-decker, upper epidermis is to be base material with the binary polypropylene copolymer, interlayer is to be base material with the polypropylene, following top layer is to be base material with the ternary polypropylene copolymer, it is characterized in that:
The polymeric silicone (Mw 〉=100000) that adding accounts for binary polypropylene copolymer base material total weight 1～3% in upper epidermis binary polypropylene copolymer base material is as slipping agent, and adding accounts for the cross-linked acrylic acid methyl esters of binary polypropylene copolymer base material total weight 0.1～0.5% as antiseize agent;
The C5 hydrogenated petroleum resin that adding accounts for polypropylene-base layer material total weight 10～30% in interlayer polypropylene-base layer material is as intensity strengthening agent, and adding accounts for polypropylene-base layer material total weight 0.2～0.5% alkyl (C14-18) two (2-ethylol) amine as antistatic additive;
The polymeric silicone (Mw 〉=100000) that adding accounts for ternary polypropylene copolymer base material total weight 1～3% in the ternary polypropylene copolymer base material of following top layer is as slipping agent, and adding accounts for the cross-linked acrylic acid methyl esters of ternary polypropylene copolymer base material total weight 0.1～0.5% as antiseize agent.
The present invention is by add polymeric silicone and cross-linked acrylic acid methyl esters in upper epidermis and following top layer base material, to improve the smooth property and the antistick characteristic of film.The internal friction of film is accomplished below the 0.13N/m, reached tobacco bale and bar bag withdraw from promptly " easily return-charge " from film purpose by reducing internal friction; Also, add alkyl (C14-18) two (2-ethylol) amine to improve the antistatic property of film by in the interlayer base material, adding hydrogenated petroleum resin to improve the deflection of film.
To sum up, internal friction of the present invention is little, and deflection and antistatic property are good.Tobacco bale is withdrawed from from film at an easy rate.
The specific embodiment
The easy return-charge retraction tobacco of the super smooth type Biaxially oriented polypropylene film that the present invention relates to is divided into upper epidermis, interlayer and following top layer three-decker, and the percentum that each component accounts for this layer total weight in each layer is respectively:
Upper epidermis (0.5 μ-1.0 μ): binary polypropylene copolymer 96.5～98.9%, its initial temperature are 108 ℃.Polymeric silicone (Mw 〉=100000) 1%～3% and cross-linked acrylic acid methyl esters 0.1～0.5%.
Interlayer: polypropylene 69.8～89.9%, C5 hydrogenated petroleum resin 10～30%, alkyl (C14-18) two (2-ethylol) amine 0.2～1.0%.
Following top layer (0.5 μ～1.0 μ): ternary polypropylene copolymer 96.5～98.9%, its initial temperature are 100 ℃.Polymeric silicone (Mw 〉=100000) 1～3% and cross-linked acrylic acid methyl esters 0.1～0.5%.
Product shrinkage percentage of the present invention: outside the friction coefficient≤0.16N/m, interior≤0.13N/m,
Vertically, laterally 〉=8%;
Modulus of elasticity 〉=2900.
Claims (1)
1, the easy return-charge retraction tobacco of a kind of super smooth type Biaxially oriented polypropylene film, be divided into upper epidermis, interlayer and following top layer three-decker, upper epidermis is to be base material with the binary polypropylene copolymer, interlayer is to be base material with the polypropylene, following top layer is to be base material with the ternary polypropylene copolymer, it is characterized in that:
The polymeric silicone that adding accounts for binary polypropylene copolymer base material total weight 1～3%Mw 〉=100000 in upper epidermis binary polypropylene copolymer base material is as slipping agent, and adding accounts for the cross-linked acrylic acid methyl esters of binary polypropylene copolymer base material total weight 0.1～0.5% as antiseize agent;
The hydrogenated petroleum resin that adding accounts for polypropylene-base layer material total weight 10～30% in interlayer polypropylene-base layer material is as intensity strengthening agent, and adding accounts for alkyl (C14-18) two (2-ethylol) amine of polypropylene-base layer material total weight 0.2～1.0% as antistatic additive;
The polymeric silicone that adding accounts for ternary polypropylene copolymer base material total weight 1～3%Mw 〉=100000 in the ternary polypropylene copolymer base material of following top layer is as slipping agent, and adding accounts for the cross-linked acrylic acid methyl esters of ternary polypropylene copolymer base material total weight 0.1～0.5% as antiseize agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2008100200093A CN100551788C (en) | 2008-03-20 | 2008-03-20 | The easy return-charge retraction tobacco of Biaxially oriented polypropylene film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2008100200093A CN100551788C (en) | 2008-03-20 | 2008-03-20 | The easy return-charge retraction tobacco of Biaxially oriented polypropylene film |
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| CN101269722A true CN101269722A (en) | 2008-09-24 |
| CN100551788C CN100551788C (en) | 2009-10-21 |
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| CNB2008100200093A Active CN100551788C (en) | 2008-03-20 | 2008-03-20 | The easy return-charge retraction tobacco of Biaxially oriented polypropylene film |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102085735A (en) * | 2010-11-09 | 2011-06-08 | 浙江大东南包装股份有限公司 | Multifunctional BOPP (Biaxially-oriented Polypropylene) cigarette packaging film and manufacture method thereof |
| CN102153810A (en) * | 2011-01-25 | 2011-08-17 | 云梦县德邦实业有限责任公司 | PP film stiffness increasing agent |
| CN103009748A (en) * | 2012-12-25 | 2013-04-03 | 海南赛诺实业有限公司 | Low-friction and biaxially oriented polypropylene heat-sealing membrane and manufacturing method thereof |
| CN103331974A (en) * | 2013-07-11 | 2013-10-02 | 中山百能思塑料科技有限公司 | Aging-stable, high-gloss, low-haze and ultra-smooth BOPP film |
| CN111688319A (en) * | 2020-05-26 | 2020-09-22 | 安徽国风塑业股份有限公司 | BOPP film for in-film labeling and preparation method thereof |
| CN112123906A (en) * | 2020-08-12 | 2020-12-25 | 安徽国风塑业股份有限公司 | Curl-free BOPP (biaxially-oriented Polypropylene) matt film and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2541365Y (en) * | 2002-06-13 | 2003-03-26 | 海南现代企业股份有限公司 | Special coating film of substituting cigarette case package |
| CN1201922C (en) * | 2003-01-30 | 2005-05-18 | 江苏中达新材料集团股份有限公司 | Method for preparing thin film to pack cigarette packages without paper box by two-way stretching polypropylene sheet, squeezing and heat sealing procedures |
| CN2592553Y (en) * | 2003-02-21 | 2003-12-17 | 河南塑胶股份有限公司 | Heat-shrinkable packing composite film for cigarette |
-
2008
- 2008-03-20 CN CNB2008100200093A patent/CN100551788C/en active Active
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102085735A (en) * | 2010-11-09 | 2011-06-08 | 浙江大东南包装股份有限公司 | Multifunctional BOPP (Biaxially-oriented Polypropylene) cigarette packaging film and manufacture method thereof |
| CN102085735B (en) * | 2010-11-09 | 2013-03-27 | 浙江大东南包装股份有限公司 | Multifunctional BOPP (Biaxially-oriented Polypropylene) cigarette packaging film and manufacture method thereof |
| EP2639061A1 (en) * | 2010-11-09 | 2013-09-18 | Zhejiang Great Southeast Packaging Co. Ltd. | Multifunctional bopp cigarette packaging film and manufacturing method thereof |
| EP2639061A4 (en) * | 2010-11-09 | 2014-06-11 | Zhejiang Great Southeast Packaging Co Ltd | Multifunctional bopp cigarette packaging film and manufacturing method thereof |
| CN102153810A (en) * | 2011-01-25 | 2011-08-17 | 云梦县德邦实业有限责任公司 | PP film stiffness increasing agent |
| CN103009748A (en) * | 2012-12-25 | 2013-04-03 | 海南赛诺实业有限公司 | Low-friction and biaxially oriented polypropylene heat-sealing membrane and manufacturing method thereof |
| CN103009748B (en) * | 2012-12-25 | 2015-02-18 | 海南赛诺实业有限公司 | Low-friction and biaxially oriented polypropylene heat-sealing membrane and manufacturing method thereof |
| CN103331974A (en) * | 2013-07-11 | 2013-10-02 | 中山百能思塑料科技有限公司 | Aging-stable, high-gloss, low-haze and ultra-smooth BOPP film |
| CN103331974B (en) * | 2013-07-11 | 2016-02-24 | 中山北化高分子材料有限公司 | A kind of aging stability type high glaze, low haze, super cool sliding BOPP film |
| CN111688319A (en) * | 2020-05-26 | 2020-09-22 | 安徽国风塑业股份有限公司 | BOPP film for in-film labeling and preparation method thereof |
| CN112123906A (en) * | 2020-08-12 | 2020-12-25 | 安徽国风塑业股份有限公司 | Curl-free BOPP (biaxially-oriented Polypropylene) matt film and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN100551788C (en) | 2009-10-21 |
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