CN101265675A - Environment friendly-type amortizing packaging material and method for making same - Google Patents

Environment friendly-type amortizing packaging material and method for making same Download PDF

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Publication number
CN101265675A
CN101265675A CNA2007100086892A CN200710008689A CN101265675A CN 101265675 A CN101265675 A CN 101265675A CN A2007100086892 A CNA2007100086892 A CN A2007100086892A CN 200710008689 A CN200710008689 A CN 200710008689A CN 101265675 A CN101265675 A CN 101265675A
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waste
flax
packaging material
leather
fiber pulp
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CN101265675B (en
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黄彪
杨建华
陈学榕
江茂生
黄六莲
戴达松
林冠烽
廖益强
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Fujian Agriculture and Forestry University
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Fujian Agriculture and Forestry University
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Abstract

The invention provides an environmental friendly cushion packaging material and a preparation method thereof, and includes slicing processing of the leather solid waste, microfibrillar processing, preparation of the waste of flax core granule, fluffing and mixing of the leather slurry, the flax core granules and the plant fiber slurry, moulding and drying processing of a wet blank. The environmental friendly cushion packaging material has the advantages of low comprehensive cost, non-pollution in the production process and good cushion performance of the product, and hopefully becomes the novel environmental friendly cushion packaging material instead of EPS and EPE.

Description

A kind of environment friendly-type amortizing packaging material and preparation method thereof
Affiliated technical field the present invention relates to a kind of amortizing packaging material and preparation method thereof, and particularly relating to a kind of is amortizing packaging material of raw material and preparation method thereof with leather and waste of flax
Background technology
At present, a large amount of packaging material that use mostly are foamed plastics such as EPS and EPE on the domestic and international market, these packings are big serious " white pollution " owing to its non-degradable brings, eliminate " white pollution ", seek new degradable packaging material, become a common research topic of countries in the world.
Since 1998, area such as Europe, the U.S., Japan, Korea S, Australia and the country industrial products of forbidding foam (EPS) packing of all making laws enter, improve perhaps that several times environmental protection tax limits and superseded bubble wrap material enters as packaged products, form so-called " Green Trade Barrier " according to the statistics made by the departments concerned, owing to there is not green package " passport ", the whole nation has 7,400,000,000 dollars commodity export to be obstructed every year, brings enormous economic loss to China.
Main substitute products are paper mould shockproof inner lining packing articles at present, its antidetonation impact resistance is significantly less than the EPS material, the impact resistance that resists into of these product goods mainly is that geometry by goods guarantees, owing to be subjected to the influence of mould structure and processing, the development of goods is subjected to very big restriction, can only make small-sized packaging cushion, still adopt the EPS foam plastic product and make the packaging cushion of large-scale household appliances and fill, this technical barrier rice so far can effectively be solved, from promoting Product Green environmental protection package image, reduce discarded object reclaiming utilization, avoid " green " consideration of trade barrier angle, research, exploitation, produce, promote and use " green package " material and goods, be the task of top priority, and had profound significance.
In addition, the subject matter that leather industry faced is the produced pollution and to the significant wastage of resource.In the process hides process, only there is the material of raw material tare weight 20% to be converted into the leather that can sell, remaining has all abandoned as discarded object.This has wasted good raw material skin resource on the one hand, also environment has been caused great harm on the other hand.It is reported that China produces 1,400,000 tons leather corner discarded object every year approximately, these solid waste are to cause one of with serious pollution key factor of leather industry.Since the eighties in 20th century, because the restriction of the environmental regulation of developed country's increasingly stringent, reduce gradually in the place that can be used for the landfill solid waste, pollution abatement costs is expensive day by day, developed country shifts its with serious pollution industry gradually to developing country, people have also actively developed the research and the application work of solid leather wastes resource.
China is process hides big country, particularly because China has the labour and the advanced advantages such as tanning technology of abundant raw material skin resource, cheapness, the machining center and the commerce trading center that have now developed into world's leather, though this provides opportunity for China's foreign exchange earning, has also brought serious pollution in leather industry simultaneously.According to incompletely statistics, leathers about 11,000,000,000 (standard of amounting to into is opened) such as China annual processing pig, ox, sheep, the leather corner scurf refuse amount of generation is huge.Therefore, make full use of leather resource, make the solid leather wastes resource, and do not exchange temporary transient economic development at the cost of the environment for, become severe challenge and inevitable choice that China's leather industry development faces.Sustainable development is wanted in Chinese leather industry, just must eliminate and pollute, and the comprehensive utilization of leather solid waste is exactly one of them aspect.Therefore, " tanning waste resource " become one of important topic of domestic and international concern.
Summary of the invention
One of purpose of the present invention is to provide a kind of amortizing packaging material of totally biodegradable;
Another object of the present invention just provides a kind of purposes of environmental-friendly leather solid waste, when solving the leather castoff pollution, realizes the comprehensive utilization of leather castoff.
Technical scheme of the present invention is achieved in that
A kind of environment friendly-type amortizing packaging material of the present invention is a raw material with waste of flax slug particle, collagenous fibres, string, and through mixing slurry, moulding is made after the oven dry formation hydrogen bonded.
A kind of environment friendly-type amortizing packaging material of the present invention, the weight ratio of its contained each component of raw material is: waste of flax slug particle: collagenous fibres: string=(50~95): (5~20): (0-30).More than each weight ratio of constituents all in butt.
The preparation method of a kind of environment friendly-type amortizing packaging material of the present invention may further comprise the steps:
(1) slicing treatment is about to the big fragment that the leather solid waste is cut into 1cm * 1cm~5cm * 5cm, preferred 1cm * 1cm~3cm * 3cm, and impurity is removed in washing, and is standby; Perhaps, the leather fragment of cleaning is placed cooking liquor boiling 20~50min of 60~120 ℃, and be more preferably boiling 30~40min in 80~100 ℃ cooking liquor, the residual soup of water flush away is standby afterwards; Described cooking liquor is that the content of steaming preparation is 1~6%, and liquor ratio is 1: 10~1: 40 a soup, and is more preferably: the content of steaming preparation is 2~3%, and liquor ratio is 1: 15~1: 25; Described steaming preparation is CaO or NaOH or Ca (OH) 2, or MgO or Mg (OH) 2, or NH 3NH 2O or HCl or H 2SO 4Wherein, CaO, NaOH, Ca (OH) 2, MgO, Mg (OH) 2Be solid, NH 3NH 2O, HCl, H 2SO 4Be liquid; Described liquor ratio is the volume of cooking liquor and the ratio of the weight of the leather-solid waste that calculates by dry weight;
(2) step (1) gained leather fragment is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 10~120rpm, and disk mill gap is 0.05mm~1.2mm; Preferred feed screw rotating speed is 60~80rpm, and disk mill gap is 0.3mm~0.8mm;
(3) the waste of flax core of peeling is crushed to 0.1cm~1cm with pulverizer after, preferred 0.5cm~0.8cm puts it into the 10min~90min that pulls an oar in the beater, is more preferably making beating 30min~50min, after the water elimination is standby;
(4) choosing beating degree is 8 ° of SR~50 ° SR, better is 15 ° of SR~30 ° SR; The screening value is 0.5mm~8mm, better is the plant fiber pulp of 1mm~3mm, and is standby;
(5) collagen fiber pulp, waste of flax slug particle, plant fiber pulp and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt): plant fiber pulp (in butt)=(5~20): (50~95): (0~30), and above-mentioned three kinds of solid mixtures (in butt): water=1: (10~40), the time of discongesting is 5min~30min;
(6) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (5); Described mould is pressed the configuration design of amortizing packaging material packaging product.
(7) the wet base with institute's moulding in the step (6) is positioned over 50 ℃~150 ℃, be more preferably dry by the fire in 100 ℃~150 ℃ the baking oven to moisture content be 5%~20%, preferred 10%~15% gets final product.
In a kind of environment friendly-type amortizing packaging material preparation method's of the present invention step (1), can be directly the leather-solid waste after the washing be sent into high concentration plate mill carries out fibrillation and dissociates, also can earlier leather-solid waste be placed after the cooking liquor boiling washing again to remove residual soup, the purpose that boiling is handled is to make leather-solid waste to be ground to be moistened fully to rise, make the energy consumption of disc mill reduce greatly and the yield of screened stock improves, and then enhance productivity.
The size that the waste of flax core is pulverized the back particle is very big to the shock-absorbing capacity influence of gained padded coaming, and so rule is generally speaking arranged: the waste of flax slug particle is big more, and its buffering effect is good more; It is in order to make the particle surface can brooming, particle surface functional group to be exposed fully that the waste of flax slug particle is put into purpose that beater pulls an oar, and this helps it and the combining of string and collagenous fibres.
String in the component is meant timber or non-wood plant fibre raw material, and wood fiber raw material is mainly softwood and broadleaf, " the three surplus things " that wherein also comprises them, be logging residue, producing material residue, industrial wood waste, and shrub and rattan class, also comprise the useless fibrous raw material of pulp and paper industry etc.; The non-wood plant fibre raw material mainly is meant bamboo class and crop stalk and slag bits fibrid raw material.And the quality of fiber quality we weigh with fibre separation index and fibre fractionation value, wherein fibre separation index is meant the separated degree of fiber in the fine process of separating, and the water filtering performance of slurry can reflect the degree that fiber is separated to a certain extent, it is fibre separation index, utilize this correlation of slurry water filtering performance and fibre separation index in the production just, measure fibre separation index indirectly by the water filtering performance of measuring slurry; Usually fibre separation index or slurry water filtering performance can reflect stock quality, but it often can only represent an aspect of slurry character, therefore, give the separated fiber quality situation of supplement Analysis by test fibre fractionation value again, and so-called screening value be exactly stay in the slurry section in or the shared percentage of fibre weight by all size screen cloth.So the beating degree of string is 8 ° of SR~50 ° SR among the present invention, better be 15 ° of SR~30 ° SR, the screening value is 0.5mm~8mm, better is 1mm~3mm.
Three big components (collagenous fibres, string, waste of flax slug particle) are mixed in fluffer, discongest; The time of discongesting should be controlled at 5~30min, and is preferably at 10~20min, and might to cause mixing slurry inhomogeneous because the time is too short, and overlong time can cause the decline of production efficiency.
The moisture content of finished product also has considerable influence to the shock-absorbing capacity of this product, in general, and in 5%~20% moisture content scope, the moisture content of product is high more, its buffering effect is good more, but considers the influence of packaging material to packed article, and the moisture content that we select product is 10%~15%.
Advantage of the present invention is:
1. whole process of production does not have any gelatin substance of interpolation, but utilizes the functional group of component self to form hydrogen bonded, and this makes this production process not have any pollution, and is easy to degraded behind this invention product abandonment, belongs to environmentally friendly product.
2. this products material aboundresources, and cheap comprehensively claims that this is low, and damping, buffering is effective, and market application foreground is good.The present invention is expected to replace the bubble wrap materials such as EPS, EPE that use on the market.
3. the used leather of this production is the leftover bits and pieces that factory discards, and belongs to waste recycle, has played great function to alleviating environmental pressure.
Specific embodiment is described in further details a kind of environment friendly-type amortizing packaging material of the present invention and preparation method thereof below in conjunction with specific embodiment:
Embodiment 1: a kind of preparation method of environment friendly-type amortizing packaging material may further comprise the steps:
(1) slicing treatment is about to the leather solid waste and is cut into 1cm * 1cm~2cm * 2cm fragment, and impurity is removed in washing, and is standby;
(2) step (1) gained leather fragment is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 10~30rpm, and disk mill gap is 0.05mm~0.2mm;
(3) the waste of flax core of peeling is crushed to 0.1cm~0.5cm with pulverizer after, put it into the 10min~30min that pulls an oar in the beater, after with the water elimination, the wet waste of flax slug particle of gained is standby;
(4) choosing beating degree is 8 ° of SR~50 ° SR, and the screening value is the China fir slurry of 0.5mm~8mm, and is standby;
(5) collagen fiber pulp, waste of flax slug particle, plant fiber pulp and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt): plant fiber pulp (in butt)=(5~20): (50~95): (0~30), and above-mentioned three kinds of solid mixtures (in butt): water=1: (10~40), the time of discongesting is 5min~15min;
(6) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (5);
(7) the wet base of institute's moulding in the step (6) is positioned over to dry by the fire in 50 ℃ of baking ovens to moisture content be 5% to get final product.
Embodiment 2: a kind of preparation method of environment friendly-type amortizing packaging material may further comprise the steps:
(1) slicing treatment is about to the leather solid waste and is cut into 4cm * 4cm~5cm * 5cm fragment, and impurity is removed in washing, and is standby;
(2) step (1) gained leather is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 80~120rpm, and disk mill gap is 0.6mm~1.2mm;
(3) with the peeling the waste of flax core be crushed to 0.6cm~1cm with pulverizer after, put it into the 60min~90min that pulls an oar in the beater, after with the water elimination, the waste of flax slug particle that must wet is standby;
(4) choosing beating degree is 12~25 ° of SR, and the screening value is the bamboo pulp of 1~2mm, and is standby;
(5) collagen fiber pulp, waste of flax slug particle, plant fiber pulp and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt): plant fiber pulp (in butt)=(5~20): (50~95): (0~30), and above-mentioned three kinds of solid mixtures (in butt): water=1: (10~40), the time of discongesting is 20min~30min;
(6) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (5);
(7) the wet base of institute's moulding in the step (6) is positioned over to dry by the fire in 150 ℃ of baking ovens to moisture content be 15%~20% to get final product.
Embodiment 3: a kind of preparation method of environment friendly-type amortizing packaging material may further comprise the steps:
(1) slicing treatment is about to the leather solid waste and is cut into 2cm * 2cm~3cm * 3cm fragment, and washing places 60~120 ℃ of cooking liquor boiling 20~50min after removing impurity, and residual alkali is removed in washing then, and described cooking liquor is: steaming preparation H 2SO 41~3%, liquor ratio is 1: 20~1: 40;
(2) the leather fragment after step (1) boiling is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 30~60rpm, and disk mill gap is 0.4mm~0.8mm;
(3) the waste of flax core of peeling is crushed to 0.3cm~0.7cm with pulverizer after, put it into the 20min~60min that pulls an oar in the beater, after with the water elimination, the wet waste of flax slug particle of gained is standby;
(4) choosing beating degree is 20~30 ° of SR, and the screening value is the masson s pine pulp of 3~5mm, and is standby;
(5) collagen fiber pulp, waste of flax slug particle, plant fiber pulp and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt): plant fiber pulp (in butt)=(5~20): (50~95): (0~30), and above-mentioned three kinds of solid mixtures (in butt): water=1: (10~40), the time of discongesting is 10min~20min;
(6) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (5);
(7) the wet base of institute's moulding in the step (6) is positioned over to dry by the fire in 100~125 ℃ of baking ovens to moisture content be 10~20% to get final product.
Embodiment 4: a kind of preparation method of environment friendly-type amortizing packaging material may further comprise the steps:
(1) slicing treatment, be about to the leather solid waste and be cut into 3cm * 3cm~4cm * 4cm fragment, washing is removed impurity and is placed on boiling 30~40min in 80~100 ℃ of cooking liquors, and residual alkali is removed in washing then, described cooking liquor is: steaming preparation NaOH2~3%, liquor ratio are 1: 15~1: 25.
(2) the leather fragment after step (1) boiling is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 60~80rpm, and disk mill gap is 0.8mm~1.2mm;
(3) the waste of flax core of peeling is crushed to 0.5cm~1cm with pulverizer after, put it into the 30min~60min that pulls an oar in the beater, after with the water elimination, the wet waste of flax slug particle of gained is standby;
(4) choosing beating degree is 15~30 ° of SR, and the screening value is the rice straw pulp of 1~5mm, and is standby;
(5) collagen fiber pulp, waste of flax slug particle, plant fiber pulp and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt): plant fiber pulp (in butt)=(5~20): (50~95): (0~30), and above-mentioned three kinds of solid mixtures (in butt): water=1: (10~40), the time of discongesting is 25min~30min;
(6) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (5);
(7) the wet base of institute's moulding in the step (6) is positioned over to dry by the fire in 80 ℃~120 ℃ baking ovens to moisture content be 10%~15% to get final product.
Embodiment 5: a kind of preparation method of environment friendly-type amortizing packaging material may further comprise the steps:
(1) slicing treatment, be about to the leather solid waste and be cut into 3cm * 3cm~5cm * 5cm fragment, washing is removed impurity and is placed on boiling 20~50min in 60~120 ℃ of cooking liquors, residual acid is removed in washing then, described cooking liquor is: steaming preparation HCl 2~6%, liquor ratio is: 1: 10~1: 40.
(2) the leather fragment after step (1) boiling is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 60~80rpm, and disk mill gap is 0.6mm~0.8mm;
(3) the waste of flax core of peeling is crushed to 0.5cm~1cm with pulverizer after, put it into the 30min~60min that pulls an oar in the beater, after with the water elimination, the wet waste of flax slug particle of gained is standby;
(4) choosing beating degree is 12~25 ° of SR, and the screening value is the secondary stock of 2~5mm, and is standby;
(5) collagen fiber pulp, waste of flax slug particle, plant fiber pulp and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt): plant fiber pulp (in butt)=(5~20): (50~95): (0~30), and above-mentioned three kinds of solid mixtures (in butt): water=1: (10~40), the time of discongesting is 25min~30min;
(6) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (5);
(7) the wet base of institute's moulding in the step (6) is positioned over to dry by the fire in 80 ℃~120 ℃ baking ovens to moisture content be 10%~15% to get final product.
Embodiment 6: a kind of preparation method of environment friendly-type amortizing packaging material may further comprise the steps:
(1) slicing treatment is about to the leather solid waste and is cut into 1cm * 1cm~3cm * 3cm fragment, and impurity is removed in washing, and is standby;
(2) step (1) gained leather fragment is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 60~80rpm, and disk mill gap is 0.3mm~0.8mm;
(3) the waste of flax core of peeling is crushed to 0.5cm~0.8cm with pulverizer after, put it into the 30min~50min that pulls an oar in the beater, after with the water elimination, the wet waste of flax slug particle of gained is standby;
(4) collagen fiber pulp, waste of flax slug particle and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt)=(5~20): (80~95), and above-mentioned solid mixture (in butt): water=1: (10~40), and the time of discongesting is 10min~20min;
(5) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (4);
(6) the wet base of institute's moulding in the step (5) is positioned over to dry by the fire in 100 ℃~150 ℃ baking ovens to moisture content be 10%~15% to get final product.

Claims (5)

1. environment friendly-type amortizing packaging material, with waste of flax slug particle, collagenous fibres, string is raw material, it is characterized in that the weight ratio of contained each component of raw material is: waste of flax slug particle: collagenous fibres: string=(50~95): (5~20): (0~30).
2. environment friendly-type amortizing packaging material preparation method is characterized in that may further comprise the steps:
(1) the leather solid waste is cut into 1cm * 1cm~5cm * 5cm fragment, impurity is removed in washing, and is standby;
(2) step (1) gained leather fragment is put into high-density paste mill and is carried out fibrillation and dissociate, after the gained collagen fiber pulp filter of will dissociating do, place the sealing bag equilibrium water conten, standby; Wherein the feed screw rotating speed of disc mill is 10~120rpm, and disk mill gap is 0.05mm~1.2mm;
(3) the waste of flax core of peeling is crushed to 0.1cm~1cm with pulverizer after, put into the beater 10min~90min that pulls an oar, after the water elimination is standby;
(4) choosing beating degree is 8 ° of SR~50 ° SR, and the screening value is the string of 0.5mm~8mm, and is standby;
(5) collagen fiber pulp, waste of flax slug particle, plant fiber pulp and water are mixed in defiberizing machine, discongest; The weight ratio of each raw material is: collagen fiber pulp (in butt): waste of flax slug particle (in butt): plant fiber pulp (in butt)=(5~20): (50~95): (0~30), and above-mentioned three kinds of solid mixtures (in butt): water=1: (10~40), the time of discongesting is 5min~30min;
(6) the drainage moulding in mould of gained mixed slurry will fully be discongested in the step (5);
(7) the wet base of institute's moulding in the step (6) is positioned over to dry by the fire in 50 ℃~150 ℃ the baking oven to moisture content be 5%~20% to get final product.
3. a kind of environment friendly-type amortizing packaging material preparation method according to claim 2, it is characterized in that, step in the claim 2 (1) gained leather fragment is placed cooking liquor boiling 20~50min of 60~120 ℃, the residual soup of water flush away afterwards; Described cooking liquor refers to that the content of steaming preparation is 1~6%, and liquor ratio is 1: 10~1: 40 a soup; Described steaming preparation is CaO or NaOH or Ca (OH) 2, or MgO or Mg (OH) 2, or NH 3NH 2O or HCl or H 2SO 4
4. a kind of environment friendly-type amortizing packaging material preparation method according to claim 3, it is characterized in that, step in the claim 2 (1) gained leather placed cooking liquor boiling 30~40min of 80~100 ℃, described cooking liquor refers to that the content of steaming preparation is 2~3%, and liquor ratio is 1: 15~1: 25 a soup.
5. a kind of environment friendly-type amortizing packaging material according to claim 1 is characterized in that:
(1) the leather solid waste is cut into 1cm * 1cm~3cm * 3cm fragment;
(2) the feed screw rotating speed of disc mill is 60~80rpm, and disk mill gap is 0.3mm~0.8mm;
(3) with the peeling the waste of flax core be crushed to 0.5cm~0.8cm with pulverizer after, the making beating 30min~50min;
(4) choosing beating degree is 15 ° of SR~30 ° SR, and the screening value is the string of 1mm~3mm;
(5) time of discongesting is 10min~20min;
(6) bake out temperature is 100 ℃~150 ℃, to moisture content 10%~15%.
CN2007100086892A 2007-03-12 2007-03-12 Environment friendly-type amortizing packaging material and method for making same Expired - Fee Related CN101265675B (en)

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Cited By (3)

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CN106256953A (en) * 2016-07-15 2016-12-28 东莞顺裕纸业有限公司 A kind of leather waste joins the method copying the high-strength corrugating medium of OCC waste paper production
CN108708205A (en) * 2018-04-18 2018-10-26 海宁市丁桥镇永畅知识产权服务部 A kind of processing method of leather leftover pieces
CN112761030A (en) * 2020-12-16 2021-05-07 江西中竹生物质科技有限公司 Bamboo pulp foaming material and preparation method thereof

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CN1257089A (en) * 1998-12-16 2000-06-21 东莞市新昆仑实业有限公司 Method for making plant fiber foaming package material
EP1560982A1 (en) * 2002-10-19 2005-08-10 Grenidea Technologies PTE Ltd. Slurry of agricultural fibres and its products
CN1231633C (en) * 2004-05-17 2005-12-14 陕西科技大学 Method for combining living-paper using collagenous fiber and vegetable fiber

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106256953A (en) * 2016-07-15 2016-12-28 东莞顺裕纸业有限公司 A kind of leather waste joins the method copying the high-strength corrugating medium of OCC waste paper production
CN108708205A (en) * 2018-04-18 2018-10-26 海宁市丁桥镇永畅知识产权服务部 A kind of processing method of leather leftover pieces
CN112761030A (en) * 2020-12-16 2021-05-07 江西中竹生物质科技有限公司 Bamboo pulp foaming material and preparation method thereof

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