Summary of the invention
The objective of the invention is for solving existing pottery that can use and kitchen glassware on electromagnetic oven, heat transfer efficiency is low when using on electromagnetic oven, and the problem that waste of energy is big provides a kind of pottery pot and preparation method thereof that is used on the electromagnetic oven.
Pottery pot of the present invention comprises pottery pot body, nickel dam, copper mesh, stainless steel substrates and annular solder, the bottom surface of pottery pot body is provided with ground floor groove and second layer groove, the bottom surface and the periphery of ground floor groove and second layer groove are coated with nickel dam, copper mesh be fitted in nickel dam below, the annular solder is arranged on the bottom surface of second layer groove, and between nickel dam and copper mesh, stainless steel substrates be fitted in copper mesh and annular solder below.
Preparation method of the present invention realizes by following steps: one, with adhesive plaster the side of pottery pot body is wrapped earlier; Two, with the bottom surface and the peripheral oil removing of ground floor groove and second layer groove, ceramic bottom of pot body is put into acetone soln soaked 15-25 minute, put into absolute alcohol solution again and soaked 5-15 minute, clean after the oil removing with distilled water flushing; Three, bottom surface and the periphery with ground floor groove and second layer groove carries out chemical roughen, ceramic bottom of pot body is put into roughening solution to be soaked 20-30 minute, roughening solution is to add 18-22ml hydrofluoric acid and 34-38ml nitric acid in a small amount of distilled water, rise solution with distilled water diluting to 1-1.5 again, clean after the alligatoring with distilled water flushing; Four, bottom surface and the periphery with ground floor groove and second layer groove carries out sensitization, ceramic bottom of pot body is put into sensitized solution to be soaked 10-15 minute, during the preparation sensitized solution, earlier stannous chloride 10-15g is dissolved in the 30-50ml hydrochloric acid, slowly is diluted to 1-1.5 with distilled water again and rises solution, if slight white precipitate is arranged, can use, if a large amount of white precipitates need reconfigure, wash with distilled water after the sensitization; Five, bottom surface and the periphery of ground floor groove 22 with second layer groove activated, ceramic bottom of pot body is put into activated solution to be soaked 15-20 minute, activated solution is that the 0.25-0.5g palladium bichloride is put into 5-15ml hydrochloric acid, rise solution with distilled water diluting to 1-1.5 again, the activation back is washed with distilled water; Six, bottom surface and the periphery with ground floor groove and second layer groove reduces, ceramic bottom of pot body is put into reducing solution to be soaked 3-5 minute, reducing solution is to rise in the distilled water at 1-1.5 that to add the 5-10g inferior sodium phosphate formulated, and the reduction back is washed with distilled water; Seven, bottom surface and the periphery with ground floor groove and second layer groove carries out chemical nickel plating, ceramic bottom of pot body is put into chemical plating fluid, chemical plating fluid is that nickelous sulfate 24-36g, inferior sodium phosphate 20-35g, boric acid 12-16g, lactic acid 12-16ml, anhydrous sodium acetate 30-40g, sodium fluoride 0.8-1.2g and ammonium molybdate 8-12mg are dissolved in the distilled water, is made into 1-1.5 with distilled water and rises solution; The glass container of pottery pot body and chemical plating fluid of packing into is put into 75-85 ℃ water bath with thermostatic control environment, and chemical Ni-plating layer forms gradually, and the chemical plating time is 1-1.5 hour, washes with distilled water after the chemical plating; Eight, tear the adhesive plaster of pot body side surface off, use the distilled water wash clean, will plate the ground floor groove of nickel dam with hair-dryer again and the bottom surface and the periphery of second layer groove dries up; Nine, copper mesh is fitted tightly below nickel dam; Ten, oxide-film is removed with sand papering in annular solder surface, oil removing is cleaned with acetone in the stainless steel substrates surface, remove surface film oxide with sand papering again, after the polishing annular solder and stainless steel substrates are cleaned up with absolute alcohol, select for use soldering flux to be coated on the nickel dam and stainless steel substrates of annular solder and second layer groove floor and side; 11, annular solder is placed on the bottom surface of second layer groove, again stainless steel substrates be fitted in copper mesh and annular solder below; 12, the above-mentioned pot body that assembles is put into resistance furnace to be welded, make the temperature in the resistance furnace be raised to 350 ℃~400 ℃ with per second 18-22 ℃ programming rate from room temperature, make annular solder fusing, the wetting second layer groove floor of annular solder liquid after the fusing and the nickel dam and the stainless steel substrates of side, be incubated 10-20 minute then, make resistance furnace temperature drop to 45-55 ℃ with per second 8-12 ℃ cooling rate again, at this moment, the annular solder liquid of fusing solidifies, simultaneously that the nickel dam of stainless steel substrates and second layer groove floor and side is welded together, encapsulation has been finished in whole cooker body bottom surface, from resistance furnace, take out the pottery pot body after encapsulating, with the brazing flux of distilled water flush away pottery pot surface.
Advantage of the present invention is: one, the present invention has realized ceramic pot body bottom surface metallization, and stainless steel substrates is connected with the soldering of pottery pot body bottom surface, and joint is solid and reliable, combination is tight, and the heat transfer efficiency height has been saved the energy.Two, adopt pottery to do a pot body, because pottery is an Inorganic Non-metallic Materials, harmful substances such as the not leaded and cadmium of pottery, pottery is gone back acid and alkali-resistance, not perishable, so the present invention can make the nutrition in the food not be decomposed, has kept the genuineness in the food.Three, the present invention has energy-saving and environmental protection, safe and reliable advantage concurrently.Three, the present invention not only can be placed on the electromagnetic oven and use, and can be placed on the micro-wave oven and use, long service life, and the efficient height, and also production method is simple, and cost is low.
The specific embodiment
The specific embodiment one: present embodiment is described in conjunction with Fig. 1, present embodiment comprises pottery pot body 2, nickel dam 4, copper mesh 5, stainless steel substrates 6 and annular solder 7, the bottom surface of pottery pot body 2 is provided with ground floor groove 22 and second layer groove 23, ground floor groove 22 is coated with nickel dam 4 with the bottom surface and the periphery of second layer groove 23, copper mesh 5 be fitted in nickel dam 4 below, annular solder 7 is arranged on the bottom surface of second layer groove 23, and between nickel dam 4 and copper mesh 5, stainless steel substrates 6 be fitted in copper mesh 5 and annular solder 7 below.The bottom surface of pottery pot body 2 is the plane, and two layers of groove that pottery pot body 2 bottom surfaces are provided with can make the copper mesh 5 in the ground floor groove 22 can fit tightly with stainless steel substrates 6 in the second layer groove 23, to alleviate welding stress, have strengthened heat transfer efficiency simultaneously.The present invention also contains pot cover 1, and pot cover 1 is arranged on the upper port of pottery pot body 2, and pot cover 1 is a glass cover, and pot cover 1 is provided with pore 11, and the periphery of pot cover 1 is embedded with bound edge 12.Pore 11 can reduce the pressure in the pottery pot body 2, is packed with bound edge 12 at the periphery of pot cover 1 and can prevents pot cover 1 distortion.During cooking, food and water are placed in the pottery pot body 2, then pottery pot body 2 is placed on the electromagnetic oven, utilize the magnetic field induction eddy current heating principle of electromagnetic oven, when running into the stainless steel substrates 6 of ceramic pot bottom, produce countless little eddy current and make stainless steel substrates 6 heating at a high speed, heat is passed to nickel coating 4 and copper mesh 5, and then make the heating of whole bottom of pot body, just can come by all good food of cooking excellent aroma very soon.
The specific embodiment two: in conjunction with Fig. 1 present embodiment is described, the inner chamber base angle of the pottery pot body 2 of present embodiment is a round-corner transition 8.This design goes out the food that is bonded at pottery pot body 2 base angles easily clearly.
The specific embodiment three: present embodiment is described in conjunction with Fig. 1, the stainless steel substrates 6 of present embodiment is a plate-like, and annular solder 7 is the paper tinsel shape, and annular solder 7 is selected tin silver solder, tin copper solder or SAC solder for use, wherein Yin content is 2%~5%, and the content of copper is 0.7%~5%.Design makes annular solder 7 little with stainless steel substrates 6 welding stress when welding like this, the intensity height.Before the welding annular solder 7 surface finish are removed oxide-film, before the welding oil removing is cleaned with acetone earlier in stainless steel substrates 6 surfaces, surface film oxide is removed in polishing again.
The specific embodiment four: in conjunction with Fig. 1 present embodiment is described, the difference of the present embodiment and the specific embodiment one is that it also contains base 3, is provided with base groove 31 above the base 3, and pottery pot body 2 is arranged in the base groove 31 on the base 3.Base 3 is used to carry pottery pot body 2.Pottery pot body 2 after the cooked food is placed in the base 3, promptly can prevent to scorch desktop, can continue insulation again, plays multi-efficiency.Other composition and annexation are identical with the specific embodiment one.
The specific embodiment five: in conjunction with Fig. 1 present embodiment is described, the preparation method of present embodiment realizes by following steps: one, with adhesive plaster the side of pottery pot body is wrapped earlier; Two, with bottom surface and the peripheral oil removing of ground floor groove 22 with second layer groove 23, ceramic bottom of pot body is put into acetone soln soaked 15-25 minute, put into absolute alcohol solution again and soaked 5-15 minute, clean after the oil removing with distilled water flushing; Three, bottom surface and the periphery with ground floor groove 22 and second layer groove 23 carries out chemical roughen, ceramic bottom of pot body is put into roughening solution to be soaked 20-30 minute, roughening solution is to add 18-22ml hydrofluoric acid and 34-38ml nitric acid in a small amount of distilled water, rise solution with distilled water diluting to 1-1.5 again, clean after the alligatoring with distilled water flushing; Four, bottom surface and the periphery with ground floor groove 22 and second layer groove 23 carries out sensitization, ceramic bottom of pot body is put into sensitized solution to be soaked 10-15 minute, during the preparation sensitized solution, earlier stannous chloride 10-15g is dissolved in the 30-50ml hydrochloric acid, slowly is diluted to 1-1.5 with distilled water again and rises solution, if slight white precipitate is arranged, can use, if a large amount of white precipitates need reconfigure, wash with distilled water after the sensitization; Five, bottom surface and the periphery of ground floor groove 22 with second layer groove 23 activated, ceramic bottom of pot body is put into activated solution to be soaked 15-20 minute, activated solution is that the 0.25-0.5g palladium bichloride is put into 5-15ml hydrochloric acid, rise solution with distilled water diluting to 1-1.5 again, the activation back is washed with distilled water; Six, bottom surface and the periphery of the-layer groove 22 with second layer groove 23 reduced, ceramic bottom of pot body is put into reducing solution to be soaked 3-5 minute, reducing solution is to rise in the distilled water at 1-1.5 that to add the 5-10g inferior sodium phosphate formulated, and the reduction back is washed with distilled water; Seven, bottom surface and the periphery with ground floor groove 22 and second layer groove 23 carries out chemical nickel plating, ceramic bottom of pot body is put into chemical plating fluid, chemical plating fluid is that nickelous sulfate 24-36g, inferior sodium phosphate 20-35g, boric acid 12-16g, lactic acid 12-16ml, anhydrous sodium acetate 30-40g, sodium fluoride 0.8-1.2g and ammonium molybdate 8-12mg are dissolved in the distilled water, is made into 1-1.5 with distilled water and rises solution; The glass container of pottery pot body and chemical plating fluid of packing into is put into 75-85 ℃ water bath with thermostatic control environment, chemical Ni-plating layer forms gradually, the chemical plating time is 1-1.5 hour, because there is the adhesive plaster protection side of pottery pot body, chemical deposit only forms in pot body bottom surface deposition, make ceramic bottom surface form certain thickness nickel dam 4, wash with distilled water after the chemical plating; Eight, tear the adhesive plaster of pot body side surface off, use the distilled water wash clean, the ground floor groove 22 that will plate nickel dam 4 with hair-dryer dries up with the bottom surface and the periphery of second layer groove 23 again; Nine, copper mesh 5 is fitted tightly below nickel dam 4; Ten, oxide-film is removed with sand papering in annular solder 7 surfaces, oil removing is cleaned with acetone in stainless steel substrates 6 surfaces, remove surface film oxide with sand papering again, after the polishing annular solder 7 and stainless steel substrates 6 usefulness absolute alcohols are cleaned up, select for use soldering flux to be coated on the nickel dam 4 and stainless steel substrates 6 of annular solder 7 and second layer groove 23 bottom surfaces and side; 11, annular solder 7 is placed on the bottom surface of second layer groove 23, again stainless steel substrates 6 be fitted in copper mesh 5 and annular solder 7 below; 12, the above-mentioned pot body that assembles is put into resistance furnace to be welded, make the temperature in the resistance furnace be raised to 350 ℃~400 ℃ with per second 18-22 ℃ programming rate from room temperature, make annular solder 7 fusings, annular solder liquid wetting second layer groove 23 bottom surfaces after the fusing and the nickel dam 4 and the stainless steel substrates 6 of side, be incubated 10-20 minute then, make resistance furnace temperature drop to 45-55 ℃ with per second 8-12 ℃ cooling rate again, at this moment, the annular solder liquid of fusing solidifies, simultaneously that the nickel dam 4 of stainless steel substrates 6 and second layer groove 23 bottom surfaces and side is welded together, encapsulation has been finished in whole cooker body bottom surface, from resistance furnace, take out the pottery pot body 2 after encapsulating, with the brazing flux on distilled water flush away pottery pot body 2 surfaces.Above-mentioned steps 5 surface actives are steps the most key in the pretreatment procedure, and its quality is directly connected to the power of the adhesion of the uniformity of coating, coating and pottery pot body 2, is vital link in the chemical deposit technology.In whole nickel process, all use glass container.The model of the soldering flux in the above-mentioned steps 10 is RJ4, removes the effect of oxide-film, increase wetability when soldering flux can play high temperature.
The specific embodiment six: the difference of the present embodiment and the specific embodiment five is that the roughening solution prescription in the step 3 is: hydrofluoric acid 20ml and nitric acid 36ml rise solution with distilled water preparation 1-1.5.The roughening solution of this ratio content can make the alligatoring best results.
The specific embodiment seven: the difference of the present embodiment and the specific embodiment five is that the sensitized solution prescription in the step 4 is: stannous chloride 13g and hydrochloric acid 40ml rise solution with distilled water preparation 1-1.5.The sensitized solution of this ratio content can make the sensitization best results.
The specific embodiment eight: the difference of the present embodiment and the specific embodiment five is that the activated solution prescription in the step 5 is: palladium bichloride 0.35g and hydrochloric acid 10ml rise solution with distilled water preparation 1-1.5.The activated solution of this ratio content can make activation effect the best.
The specific embodiment nine: the difference of the present embodiment and the specific embodiment five is that the reducing solution prescription in the step 6 is: inferior sodium phosphate 8g rises solution with distilled water preparation 1-1.5.The reducing solution of this ratio content can make reduction effect the best.
The specific embodiment ten: the difference of the present embodiment and the specific embodiment five is the chemical nickel-plating solution prescription in the step 7: nickelous sulfate 30g, inferior sodium phosphate 30g, boric acid 14g, lactic acid 14ml, anhydrous sodium acetate 35g, sodium fluoride 1g and ammonium molybdate 10mg prepare 1 liter of solution with distilled water.The chemical nickel-plating solution of this ratio content can make the chemical nickel plating best results.