CN101257128A - Quantum activity colloid accumulator - Google Patents
Quantum activity colloid accumulator Download PDFInfo
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- CN101257128A CN101257128A CNA2007100303521A CN200710030352A CN101257128A CN 101257128 A CN101257128 A CN 101257128A CN A2007100303521 A CNA2007100303521 A CN A2007100303521A CN 200710030352 A CN200710030352 A CN 200710030352A CN 101257128 A CN101257128 A CN 101257128A
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- electrolyte
- lead
- active
- colloid accumulator
- glass fibre
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
The invention relates to accumulator technique field, in particular, a quanta active colloid accumulator, which includes components as follows: an electrode plate composed of a plate grid and active material; said plate grid is a lead base alloy that has main raw materials including lead, stannum, silver, selenium; said active material is PbO powder with oxidation degree 80-95%, granularity 400-800 mesh; an electrolyte that is combined prepared by reacting with gas SiO2 with granularity 8-10 mum assorted by unsaturated Hy-O material as loader, active organic silicon, sulfuric acid, additive, molecular anticoagulant, pure water; an separation cotton made by glass fibre, therein, hole rate of glass fibre is 17-20% time of surface area. The quanta active colloid accumulator has better thermophily, high utilization rate to active material, fine physical characteristic and environmental protection performance that electrolyte is not pollute environment after being deposed, and other material can be re-used.
Description
Technical field
The present invention relates to the battery technology field, a kind of quantum activity colloid accumulator of saying so more specifically.
Background technology
Existing lead acid accumulator generally adopts casting method, and material is divided three classes, and lead-calcium alloy, lead-antimony alloy and plumbous calcium cadmium alloy are made grid, all can't solve the acid-resisting of lead-calcium alloy in practical process, the self discharge of embedding antimony alloy.And the toxicity of plumbous calcium cadmium, in the granularity of also using aspect the active matter about 170 orders, the lead monoxide of oxidizability 72～78% is made lead plaster, and its utilance is up to the theoretical value 42% of active material utilization.Now the medium of storage battery is two kinds of the gelatinous substances of sulfuric acid liquid and silicon dioxide and sulfuric acid combination basically, wherein use sulfuric acid as electrolyte, its technology is made and is not only had the environmental pollution that is difficult to overcome, and in use be subject to topple over, vibrate, jolt influence the generation leakage, produce acid mist in the charging process, cause damage to the instrument that uses battery, equipment, car, ship etc., and the residual acid after scrapping causes pollution without redemption for air, soil, water.The mixing emulsus electrolyte of its silicon dioxide and sulfuric acid though be to have breakthrough aspect environmental protection, also exists internal resistance to increase in actual applications, is easy to generate be full of cracks aquation and the low technical barrier of active matter utilance.On the material of the absorption of adopting electrolyte and anti-short circuit, now generally adopt the low hole of glass fibre every cotton, because fibre diameter and highdensity porosity cause battery impedance to increase, discharge and recharge capacity and reduce, and charging is consumed energy, heating, influenced the physical characteristic of storage battery.So existing storage battery still exists the utilance of active matter, the feature of environmental protection, an a series of industry difficult problem such as physical characteristic.
Summary of the invention
The objective of the invention is to provides a kind of performance and the better battery electrode plate of utilance at the deficiencies in the prior art, and the big porosity of quantum activity electrolyte and ultra-fine fibre glass making makes up and makes quantum activity colloid accumulator every cotton.
For achieving the above object, the present invention is achieved by the following technical solutions:
A kind of quantum activity colloid accumulator comprises following composition:
Battery lead plate: for forming by grid and active matter; Described grid is a lead-containing alloy, and the primary raw material of lead-containing alloy comprises lead, tin, silver, selenium; Described active matter is that oxidizability is 80%～95%, and granularity is 400～800 purpose lead monoxide powder;
Electrolyte: by unsaturated hydrogen-oxygen material is that carrier cooperates aerosil, active organosilicon, sulfuric acid, additive, molecule anticoagulant, pure water reaction to synthesize;
Every cotton: be the cotton of making of glass fibre, wherein the porosity of glass fibre is 17～20% of a surface area.
Unsaturated hydrogen-oxygen material in the described electrolyte is the water class material of the unsaturated combination of hydrogen-oxygen molecular weight.
The granularity of the aerosil in the described electrolyte is 8～10 μ m.
Described additive in electrolyte is a cobaltous sulfate.
In molecule anticoagulant polyvinyl alcohol in the described electrolyte, macrogol, poly-propyl alcohol, the alundum (Al any one.
Sulfuric acid concentration in the described electrolyte is 1.28～1.31 Baume degrees.
Beneficial effect of the present invention: quantum activity colloid accumulator of the present invention replaces battery lead plate that existing storage battery uses and sulfuric acid or other colloidal electrolytes and every cotton, no matter make up this storage battery by it makes in the corresponding technology of its feature of environmental protection, can adapt to purposes and require different all types of storage batterys to make, the superiority of its technological synthesis index especially shows:
1, forms by grid and active matter; Described grid is a lead-containing alloy, and the primary raw material of lead-containing alloy comprises lead, tin, silver, selenium; Described active matter is that oxidizability is 80%～95%, and granularity is 400～800 purpose lead monoxide powder, and it mainly is to improve density metal, can bear the ability of big electric current, can accept the large current charge of 1C～2C;
2, active matter is that oxidizability is 80%～95%, and granularity is that 400～800 purpose lead monoxide powder are made lead plaster, improves electrochemical respond, makes the utilance of its theoretical active matter surpass 50%, increases the specific energy of battery;
3, electrolyte is that carrier cooperates ultra-fine aerosil by unsaturated hydrogen-oxygen material, active organosilicon, sulfuric acid, additive, the molecule anticoagulant, the pure water reaction is synthetic, the hydrogen-oxygen molecule is under the undersaturated condition reducing molecular weight in the use, when molecular structure is unbalanced, it is extremely unstable that molecule is rotated in this process the hydrogen-oxygen molecule round proton always, when combining with other material, the hydrogen-oxygen molecule spreads with the molecular structure change of other material and with its micel refinement at once, reach Nano grade, make it present the characteristic of nano material, thereby reach activation purpose with other material, self discharge is little, and full charging keeps still can using more than 1 year;
4, be the cotton of making of glass fibre every cotton, wherein the porosity of glass fibre is 17～20% of a surface area, increases in thread refinement porosity, reduce impedance and save the energy, improve and discharge and recharge capacity, 20 times～30 times discharges of available rated capacity, the physical characteristic of raising storage battery;
5, electrolyte environmentally safe after the good environmental protection battery is thrown aside, the renewable use of other material;
6, low every cotton percentage of water loss, be fit to the maintenance-free battery structure;
7, thermophily is good, and scope is wide, still can normally use under-45 ℃～+ 65 ℃ environment, under the working condition that difference requires, still can keep the ability and the forceful electric power bit recovery power of dark cycle charge-discharge.
Embodiment
The present invention includes following constituent:
Battery lead plate: form by grid and active matter; Described grid is a lead-containing alloy, and the primary raw material of lead-containing alloy comprises lead, tin, silver, selenium; Described active matter is that oxidizability is 80%～95%, and granularity is 400～800 purpose lead monoxide powder;
Electrolyte: for being that carrier cooperates ultra-fine aerosil, active organosilicon, sulfuric acid, additive, molecule anticoagulant, pure water reaction synthetic by unsaturated hydrogen-oxygen material;
Every cotton: be the cotton of making of glass fibre, wherein the porosity of glass fibre is 17～20% of a surface area.
Above-mentioned material in actual use, battery lead plate is made up of grid and active matter, the serve as reasons synthetic lead-containing alloy of metal of lead, tin, silver, selenium etc. of described grid; It mainly is to improve density metal, can bear the ability of big electric current, can accept the large current charge of 1C～2C, described active matter is that oxidizability is 80%～95%, granularity is 400～800 purpose lead monoxide powder, is then reached by the lead monoxide of the above high oxidation degree of 400 orders and improves electrochemical respond, improves the utilance of active matter, make the utilance of its theoretical active matter surpass 50%, increase the specific energy of battery.Electrolyte is that the water class material of the unsaturated combination of hydrogen-oxygen molecular weight is a main carrier by the material of unsaturated hydrogen-oxygen molecular structure then, at first be 10 μ m aerosils with particle diameter, active organosilicon disperses, and is that sulfuric acid, cobaltous sulfate, polyvinyl alcohol agent and the pure water of 1.31 Baume degrees reacts combination again with concentration then.Electrolyte formula hydrogen-oxygen molecule in actual use is under the undersaturated condition reducing molecular weight, when molecular structure is unbalanced, it is extremely unstable that the hydrogen-oxygen molecule is rotated in this process the hydrogen-oxygen molecule round proton always, when combining with other material, the hydrogen-oxygen molecule spreads with the molecular structure change of other material and with its micel refinement at once and presents the characteristic of nano material, and reaches the activation purpose with other material.Battery then adopt 17～20% of its porosity surface area of cotton that ultra-fine fibre glass makes every cotton, increase in thread refinement porosity, reduce impedance and save the energy, improve and discharge and recharge capacity, 20 times～30 times discharges of available rated capacity, improve the physical characteristic of storage battery, and it is low every cotton percentage of water loss, be fit to the maintenance-free battery structure, the cooperation of described three kinds of materials is formed, and makes storage battery improve the utilance of active matter, improves the adaptability that energy-conserving and environment-protective and various ambient temperature thereof are used, electrolyte environmentally safe after battery is thrown aside, and the renewable use of other material.Thermophily of the present invention is good, still can normally use under-45 ℃～+ 65 ℃ environment, under the working condition that difference requires, still can keep the ability and the forceful electric power bit recovery power of dark cycle charge-discharge.And surmount the physical characteristic and the electrochemical function of current storage battery.
Claims (6)
1, a kind of quantum activity colloid accumulator is characterized in that: comprise following composition:
Battery lead plate: for forming by grid and active matter; Described grid is a lead-containing alloy, and the primary raw material of lead-containing alloy comprises lead, tin, silver, selenium; Described active matter is that oxidizability is 80%～95%, and granularity is 400～800 purpose lead monoxide powder;
Electrolyte: by unsaturated hydrogen-oxygen material is that carrier cooperates aerosil, active organosilicon, sulfuric acid, additive, molecule anticoagulant, pure water reaction to synthesize;
Every cotton: be the cotton of making of glass fibre, wherein the porosity of glass fibre is 17～20% of a surface area.
2, a kind of quantum activity colloid accumulator according to claim 1 is characterized in that: the unsaturated hydrogen-oxygen material in the described electrolyte is the water class material of the unsaturated combination of hydrogen-oxygen molecular weight.
3, a kind of quantum activity colloid accumulator according to claim 1 is characterized in that: the particle diameter of the aerosil in the described electrolyte is 8～10 μ m.
4, a kind of quantum activity colloid accumulator according to claim 1 is characterized in that: described additive in electrolyte is a cobaltous sulfate.
5, a kind of quantum activity colloid accumulator according to claim 1 is characterized in that: any one in the molecule anticoagulant polyvinyl alcohol in the described electrolyte, macrogol, poly-propyl alcohol, the alundum (Al.
6, a kind of quantum activity colloid accumulator according to claim 1 is characterized in that: the sulfuric acid concentration in the described electrolyte is 1.28～1.31 Baume degrees.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100303521A CN101257128A (en) | 2007-09-21 | 2007-09-21 | Quantum activity colloid accumulator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100303521A CN101257128A (en) | 2007-09-21 | 2007-09-21 | Quantum activity colloid accumulator |
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| CN101257128A true CN101257128A (en) | 2008-09-03 |
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| CNA2007100303521A Pending CN101257128A (en) | 2007-09-21 | 2007-09-21 | Quantum activity colloid accumulator |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102074745A (en) * | 2010-12-21 | 2011-05-25 | 江苏富思特电源有限公司 | Low-liquid type lead-acid storage battery electrode group manufacturing method |
| CN102569904A (en) * | 2012-02-27 | 2012-07-11 | 超威电源有限公司 | Colloidal electrolyte for starting type battery |
| CN105336956A (en) * | 2014-06-06 | 2016-02-17 | 苏州宝时得电动工具有限公司 | Battery |
| CN106785082A (en) * | 2016-12-02 | 2017-05-31 | 常熟市万隆电源技术研发有限公司 | A kind of high energy efficiency colloid storage battery |
| CN107565174A (en) * | 2017-09-07 | 2018-01-09 | 深圳美能动力科技有限公司 | A kind of two-phase mixtures additive of lead accumulator and preparation method thereof |
-
2007
- 2007-09-21 CN CNA2007100303521A patent/CN101257128A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102074745A (en) * | 2010-12-21 | 2011-05-25 | 江苏富思特电源有限公司 | Low-liquid type lead-acid storage battery electrode group manufacturing method |
| CN102569904A (en) * | 2012-02-27 | 2012-07-11 | 超威电源有限公司 | Colloidal electrolyte for starting type battery |
| CN105336956A (en) * | 2014-06-06 | 2016-02-17 | 苏州宝时得电动工具有限公司 | Battery |
| CN106785082A (en) * | 2016-12-02 | 2017-05-31 | 常熟市万隆电源技术研发有限公司 | A kind of high energy efficiency colloid storage battery |
| CN107565174A (en) * | 2017-09-07 | 2018-01-09 | 深圳美能动力科技有限公司 | A kind of two-phase mixtures additive of lead accumulator and preparation method thereof |
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Open date: 20080903 |