CN101255281A - Reactive lemon yellow GG dye and preparation method thereof - Google Patents
Reactive lemon yellow GG dye and preparation method thereof Download PDFInfo
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- CN101255281A CN101255281A CNA2008100233025A CN200810023302A CN101255281A CN 101255281 A CN101255281 A CN 101255281A CN A2008100233025 A CNA2008100233025 A CN A2008100233025A CN 200810023302 A CN200810023302 A CN 200810023302A CN 101255281 A CN101255281 A CN 101255281A
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- dye
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Abstract
The invention provides an active lemon yellow GG dye and preparation method. The active lemon yellow GG dye is formed by coupling 1,3,5-pyrazolone and diazonium salt of ethyl sulfon sulfate aniline compound containing sulfonic group or methyl, methoxyl group, ethyl. The active lemon yellow GG dye has features of uniform painting, bright color, good fastness, less hydrolyzed dye, high fixation ratio, good washing fastness, good stability of alkali and salt proof, widely used in cotton fibre dyeing, discharge dyeing and printing.
Description
Technical field
The present invention relates to a kind of reactive lemon yellow GG dye and preparation method thereof.
Background technology
The reactive yellow 1 of late nineteen nineties invention
#, its structural formula is as follows:
Color and luster is not bright-coloured during this dyeing, fastness is poor, hydrolised dye is many, degree of fixation is not high.
Summary of the invention
The invention provides a kind of reactive lemon yellow GG dye and preparation method thereof for addressing the above problem.
A kind of reactive lemon yellow GG dye of the present invention claims C.I. reactive yellow 15 again, and its structural formula is as follows:
In the formula: (1) R=H, CH
3, OCH
3C
2H
5, OC
2H
5SO
3H etc.
(2)M=Na、K
Active group R is for being converted into the group of vinyl among the present invention, its mixture carries out coupling by the diazonium salt of 1.3.5-pyrazolone and the ethyl sulfonyl sulfate aniline compound that contains sulfonic group or methyl, ethyl, methoxyl group etc. and makes, 0-15 ℃ of coupling temperature, PH=1.5-6.5.
The method that the present invention prepares diazonium salt compares diazonium for the little acid of ice mill.
A kind of reactive lemon yellow GG dye of the present invention and commercially available reactive yellow 1
#Deng comparing, have colouring even, good lifting force, dye yield height, depth is good, degree of fixation is high, compatibleness is good, washing performance is good, process tolerance is good, salt and alkali resistance is good, can dye and stamp, again can discharge.During its simultaneous test data are listed in the table below.
Following standard is adopted in the test of performance index in table:
The general condition regulation that the GB/T2374-1994 dyeing is measured
The measuring method of insolubles content in the GB/T2381-1994 dyestuff
The measuring method of GB/T2383-1980 dyestuff screening fineness
The measuring method of GB/T2386-1980 dye well dyestuff intermediate moisture content
The measuring method of GB/T2388-1980 printing with reactive dye coloured light and intensity
The measuring method of the relative content of hydrolised dye and standard in the GB/T2389-1980 reactive dyestuffs
The measuring method of GB/T2390-1980 reactive dyestuffs pH value
The measuring method of GB/T2393-1980 printing with reactive dye degree of fixation
The measuring method of GB/T2392-1980 reactive dyestuffs thermostability
The mensuration of GB/T3671.1-1996 water-soluble dye solubleness and steady dissolution
The test method of GB/T3920-1997 textiles colour fastness to rubbing
The test method of GB/T3921.4-1997 textiles colour fastness to washing
The test method of GB/T3922-1995 textiles colour fastness to perspiration
GB/T4841.1-1984 1/1 dyeing standard depth colour atla
The test method of the heat-resisting pressure of GB/T6152-1997 textiles (flatiron) fastness
GB/T6678-1986 Chemicals sampling general provisions
GB/T8427-1998 textiles colour fastness to light test method (xenon arc)
The test method of the anti-chloride swimming-pool water colour fastness of GB/T8433-1998 textiles
Specific embodiments:
Embodiment one
(1) takes by weighing 26 parts of 1.3.5-pyrazolones of weight and add 200ml water, pulled an oar 1 hour.
(2) take by weighing the ethyl sulfonyl sulfate aniline compound that 31 parts of weight contain sulfonic group or methyl, methoxyl group, ethyl etc. and add an amount of frozen water 0 ℃ of making beating 2 hours.Add quantitative hydrochloric acid then, add 6.9 parts of inferior sodium, temperature 5-8 ℃, the blue look of control congo-red test paper, the little orchid of KI test paper, inferior sodium added afterreaction 1 hour, eliminated little excessive nitrous acid before the coupling.
(3) diazonium salt for preparing is joined in the 1.3.5-pyrazolone that is cooled to 5 ℃, slowly regulate PH=5-6.5 with sodium bicarbonate then, temperature 0-5 ℃.Keep PH=5-6.5, temperature 0-5 ℃ of reaction 3-4 hour to diazonium salt disappears.Make the green partially reactive lemon yellow GG of coloured light, claim C.I. reactive yellow 15 again.
Embodiment two
(1) takes by weighing 26 parts of 1.3.5-pyrazolones of weight and add 200ml water, pulled an oar 1 hour.
(2) take by weighing the ethyl sulfonyl sulfate aniline compound that 35 parts of weight contain sulfonic group or methyl, methoxyl group, ethyl etc. and add an amount of frozen water 0 ℃ of making beating 2 hours.Add quantitative hydrochloric acid then, add 6.9 parts of inferior sodium, temperature 5-8 ℃, the blue look of control congo-red test paper, the little orchid of KI test paper, inferior sodium added afterreaction 1 hour, eliminated little excessive nitrous acid before the coupling.
(3) diazonium salt for preparing is joined in the 1.3.5-pyrazolone that is cooled to 5 ℃, slowly regulate PH=3.5-6.5 with sodium bicarbonate then, temperature 5-15 ℃.Keep PH=3.5-6.5, temperature 5-15 ℃ of reaction 3-4 hour to diazonium salt disappears.Coupling makes the red partially reactive lemon yellow GG of coloured light, claims C.I. reactive yellow 15 again.
Claims (6)
2, according to right 1 described a kind of reactive lemon yellow GG dye, it is characterized in that containing ethyl sulfonyl sulfate.
3, according to right 1 described a kind of reactive lemon yellow GG dye, its dyeing characteristic is to contain ethyl sulfone thioesters ester can be converted into the group that contains vinyl.
4, according to the preparation method of the described dyestuff of right 1, be that diazonium salt by 1.3.5-pyrazolone and the ethyl sulfonyl sulfate aniline compound that contains sulfonic group or methyl, methoxyl group, ethyl etc. carries out coupling and makes, its coupling temperature is 10-15 ℃, PH=1.5-6.5.
5,, it is characterized in that its diazonium mode compares diazonium for the little acid of ice mill according to the preparation method of the described dyestuff of claim 4.
6, according to the preparation method of the described dyestuff of claim 4, the dye structure that it is characterized in that its preparation is the mixture of multiple compound.
Priority Applications (1)
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CNA2008100233025A CN101255281A (en) | 2008-04-08 | 2008-04-08 | Reactive lemon yellow GG dye and preparation method thereof |
Applications Claiming Priority (1)
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CNA2008100233025A CN101255281A (en) | 2008-04-08 | 2008-04-08 | Reactive lemon yellow GG dye and preparation method thereof |
Publications (1)
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CN101255281A true CN101255281A (en) | 2008-09-03 |
Family
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CNA2008100233025A Pending CN101255281A (en) | 2008-04-08 | 2008-04-08 | Reactive lemon yellow GG dye and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102504576A (en) * | 2011-09-27 | 2012-06-20 | 青岛双桃精细化工(集团)有限公司 | Preparation method of active dye for brilliant yellow wool |
CN102807772A (en) * | 2011-06-03 | 2012-12-05 | 中国中化股份有限公司 | Wool bright yellow active dye and preparation method thereof |
-
2008
- 2008-04-08 CN CNA2008100233025A patent/CN101255281A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102807772A (en) * | 2011-06-03 | 2012-12-05 | 中国中化股份有限公司 | Wool bright yellow active dye and preparation method thereof |
CN102504576A (en) * | 2011-09-27 | 2012-06-20 | 青岛双桃精细化工(集团)有限公司 | Preparation method of active dye for brilliant yellow wool |
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Open date: 20080903 |