CN101244015A - Beauty treatment preparation containing ethenyl pyrrolidone/acrylic acid copolymer - Google Patents

Beauty treatment preparation containing ethenyl pyrrolidone/acrylic acid copolymer Download PDF

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CN101244015A
CN101244015A CNA2007101527303A CN200710152730A CN101244015A CN 101244015 A CN101244015 A CN 101244015A CN A2007101527303 A CNA2007101527303 A CN A2007101527303A CN 200710152730 A CN200710152730 A CN 200710152730A CN 101244015 A CN101244015 A CN 101244015A
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acid
weight
ester
preparation
right amount
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CN101244015B (en
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S·维亚拉
A·克劳森
C·施托贝克
M·特施
K·斯库博什
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Beiersdorf AG
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Beiersdorf AG
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Abstract

The invention discloses a cosmetic preparation, which comprises a). One or a plurality of water soluble UV barrier filtering agents selected from compound 2-phenylbenzimidazole-5-sulfonic acid and the sodium salt, the potassium salt, the triethanolamine salt and phenylene-1,4-dual- (2- benzimidazoyl) -3,3',5,5'-tetrasulfonic acid and the sodium salt, the potassium salt and the triethanolamine salt; b). Copolymer for vinyl pyrrolidone and acrylic.

Description

The cosmetic formulation that contains vinyl pyrrolidone/acrylic copolymer
The present invention relates to contain the sunscreen of vinyl pyrrolidone/acrylic copolymer.
For many years, abandon enervated pale and be tending towards " the brown skin of fitness campaign " this trend and do not interrupt.In order to obtain this effect, people are exposed under the sunlight their skin, because like this can be owing to forming the generation that melanin causes color.But the ultraviolet radiation of sunlight also can produce detrimental effect to skin.Except acute damage (sun burns), accepting excessive UAB zone UV light (wavelength: will produce long-term damage, for example higher risk that causes skin carcinoma during 280-320nm) irradiation.In addition, (wavelength: excessive effect 320-400nm) can cause the elasticity of connective tissue and collagen fiber to be weakened for UVB-and UVA-ray.This will cause a large amount of phototoxicities and photoallergic reaction and cause skin aging in advance.
Therefore, will develop a series of shading mediums that can be used in the cosmetic formulation for protecting skin.This UVA-and UVB-filtering agent are all listed in most of industrial countries in the manifest of permitting import, for example the adnexa 7 of cosmetics regulation.
But many commercially available sunscreen all can't be avoided, and this preparation of prior art all has a series of defectives.
Contain and be selected from chemical compound group 2-Phenylbenzimidazole-5-sulfonic acid and sodium salt, potassium salt and tri ethanol ammonium salt or phenylene-1,4-two-(2-benzimidazolyl)-3,3 ', 5,5 '-the water solublity UV-shading filtering agent of tetrasulfonic acid and sodium salt, potassium salt and tri ethanol ammonium salt and have the very preparation of polyelectrolyte content therefrom, be difficult to be mixed with emulsion form.This emulsion according to prior art also just by in conjunction with multiple thickening agent or by using and the emulsifier system of especial manufacture and stably making reluctantly at each prescription.So the preparation that so makes has the character of non-beauty treatment usually.These emulsions have the outward appearance of Lycoperdon polymorphum Vitt character.When from storage container, taking out, can form filament and on skin, can feel to be clamminess and uncomfortable.
Therefore task of the present invention is to overcome the defective of prior art.In addition, task also is to develop the stable beauty treatment emulsion (or dispersion liquid) that has high level water solublity UV shading filtering agent based on electrolytical, and it can have good sensation on being used for skin the time.
Be surprised to find, this task solves by the cosmetic formulation that contains following component: a) one or more are selected from chemical compound 2-Phenylbenzimidazole-5-sulfonic acid and sodium salt, potassium salt and tri ethanol ammonium salt and phenylene-1,4-two-(2-benzimidazolyl)-3,3 ', 5,5 '-the water solublity UV shading filtering agent of tetrasulfonic acid and sodium salt, potassium salt and tri ethanol ammonium salt, b) vinyl pyrrolidone and acrylic acid copolymer.
Preparation of the present invention can stably be prepared with the emulsifying agent and/or the coemulsifier (for example aliphatic alcohol) of less amount astoundingly.Partly, preparation (emulsion/dispersion liquid) even can abandon coemulsifier (aliphatic alcohol) and stably make.
According to the present invention advantageously, it is the water solublity UV shading filtering agent of 0.1 to 20 weight % that preparation of the present invention is contained in total formulation weight concentration, and according to the present invention preparation of the present invention to be contained in total formulation weight amount concentration be the water solublity UV shading filtering agent of 0.1 to 10 weight %.
According to the present invention advantageously, preparation of the present invention being contained is that 0.1 to 10 weight % and preferred concentration are vinyl pyrrolidone and the acrylic acid copolymer of 0.1 to 5 weight % in total formulation weight concentration respectively.
Preferred implementation of the present invention is characterised in that water solublity UV shading filtering agent is 1: 15 to 15: 1 to the weight ratio of copolymer.
In category of the present invention, advantageously, make crosslinking copolymers of the present invention with pentaerythritol triallyl ether.In this embodiment, the present invention preferably makes polymer contain the vinyl pyrrolidone of 25-80 weight %, the acrylic acid of 20-80 weight % and the pentaerythritol triallyl ether of 0.4-2 weight %.
Preferred implementation of the present invention is characterized in that preparation exists with emulsion form, preferably the form of O/W-emulsion.
According to the present invention, the concentration of emulsifier system is preferably 0.01-6 weight % in preparation, in the gross weight of preparation.
According to the present invention, preferred preparation of the present invention also contain one or more other be selected from the UV-filtering agent of following chemical compound group: 1,4-two (the 2-oxo-bornenyl methyl of 10-sulfo--3-)-benzene and salt thereof; 2,2 '-methylene-two-(6-(2H-benzotriazole-2-yl)-4-(1,1,3, the 3-tetramethyl butyl)-phenol); 2-(2H-benzotriazole-2-yl)-4-methyl-6-[2-methyl-3-[1,3,3,3-tetramethyl-1-[(trimethyl silyl) the oxygen base] the disiloxane base] propyl group]-phenol; 3-(4-methylbenzene methylene) Camphora; 3-benzylidene Camphora; Ethylhexyl salicylate; The Terephthalidene Dicamphor Sulfonic Acid; 4-(dimethylamino)-benzoic acid (2-ethylhexyl) ester; 4-(dimethylamino) benzoic acid-pentyl ester; 4-methoxybenzene methylene malonic acid two (2-ethylhexyl) ester; 4-methoxy cinnamic acid (2-ethylhexyl) ester; 4-methoxy cinnamic acid isopentyl ester; 2-hydroxyl 4-methoxy benzophenone; 2-hydroxyl-4-methoxyl group-4 '-the methyldiphenyl ketone; 2,2 '-dihydroxy-4-methoxy benzophenone; 2-(4 '-diethylamino-2 '-hydroxy benzoyl)-hexyl-benzoate; 4-(tert-butyl group)-4 '-methoxy dibenzoyl methane; High menthyl salicylate; 2-ethylhexyl-2 hydroxybenzoic acid ester; 2-ethylhexyl-2-cyano group-3,3-diphenylacrylate ester; Dimethyl polysiloxane diethylbenzene methylene malonate (Dimethicodiethylbenzalmalonat); 3-(4-(2,2-di ethoxy carbonyl vinyl)-phenoxy group) acrylic)-methoxyl group siloxanes/dimethyl siloxane-copolymer; 2,4-two-{ [4-(2-ethyl-hexyloxy)-2-hydroxyl]-phenyl }-6-(4-methoxyphenyl)-1,3,5-triazines (INCI: two-ethyl hexyl oxy phenol methoxyphenyl triazine); Dioctyl butyl amide triazinone (INCI: diethylhexyl-butyramide triazinone); 2,4-two-[5-1-(dimethyl propyl) benzoxazol-2-base-(4-phenyl)-imino group]-6-(2-ethylhexyl)-imino group-1,3,5-triazines (CAS 288254-16-0); 4,4 ', 4 " (1,3; 5-triazine-2,4,6-three basic three imino groups)-three-benzoic acid-three (2-ethyl hexyl ester) (all right: 2,4; 6-three-[anilino--(right-carbonyl-2 '-ethyl-1 '-hexyloxy]-1,3,5-triazines (INCI: the ethylhexyl triazinone)); 2,4,6-terphenyl-4-base-1,3,5-triazines; Merocyanine; Titanium dioxide; Zinc oxide.Its concentration counts 0.01 to 40 weight % with total formulation weight and preferred concentration is 1 to 30 weight %.
According to the present invention, pigment (titanium dioxide, zinc oxide) can be advantageously surface treated (" through applying "), for example should form or keep hydrophilic, both sexes or hydrophobic characteristic at this.This surface treatment process can be, according to known method with pigment with the hydrophilic of dilution and/hydrophobic inorganic and/or organic coating applies.In category of the present invention, various face coats also can contain water.
The inorganic surfaces coating can be by aluminium oxide (Al in category of the present invention 2O 3), aluminium hydroxide Al (OH) 3Or hydrated alumina (is also referred to as: vanadine, CAS number: 1333-84-2), sodium hexameta phosphate (NaPO 3) 6, Polymeric sodium metaphosphate. (NaPO 3) n, silicon dioxide (SiO 2) (be also referred to as tripoli, CAS number: 7631-86-9), barium sulfate (BaSO 4) or ferrum oxide (Fe 2O 3) form.This inorganic surfaces coating can be separately, combination and/or exist in combination with organic-containing materials.
Organic face coat can be by the aluminium stearate of plant or animal in category of the present invention, the stearic acid of plant or animal, lauric acid, dimethyl polysiloxane (being also referred to as Dimethicone), methyl polysiloxane (Methicone), Simethicone (a kind of is the dimethyl polysiloxane of 200 to 350 dimethyl siloxane units and the mixture that silica gel constitutes by average chain length) or alginic acid.This organic face coat can be separately, combination and/or exist in combination with inorganic materials.
According to the present invention advantageously, preparation of the present invention does not contain UVINUL MBC95.
Preferred implementation of the present invention is characterized in that, it is other water soluble salts of 0.001 to 10 weight % that preparation contains in total formulation weight concentration.
So-called " water soluble salt " is interpreted as the salt of the present invention at the salt that dissolves 1g under 20 ℃ in 100g water at least.
The water of preparation of the present invention can advantageously contain conventional beauty aids, the alcohol of those of particularly low C-number for example, preferred alcohol and/or isopropyl alcohol, glycol or the polyhydric alcohol and their ether of low C number, preferably butanediol, ethohexadiol, hexanediol, pentanediol, propylene glycol, 2-methyl-prop-1,3-glycol, glycerol, ethylene glycol, ethylene glycol monoethyl ether or-monobutyl ether, propylene glycol monomethyl ether ,-single ether or-monobutyl ether, diethylene glycol monomethyl ether or-single ether and similar products, polymer, foam stabiliser.
Preparation of the present invention advantageously contains one or more film former.In category of the present invention, film former is various compositions and material that have following performance characteristic: if in film former is water-soluble or the solvent that other are suitable and then solution is coated on the skin, then it will form the film that one deck has safeguard function in fact after solvent evaporates.
Useful especially is makes film former be selected from polymer based on polyvinyl pyrrolidone (PVP).
Figure S2007101527303D00041
Particularly preferably be the copolymer of polyvinyl pyrrolidone, for example PVP-hexadecene copolymer and PVP-eicosylene copolymer, they can trade name Antaron V216 and Antaron V220 buy from GAFChemicals Cooperation company.
Other aggregate into membrane also advantageously, the kayexalate of buying from NationalStarch and Chemical Corp. company with trade name Flexan 130 for example, and/or the polyisobutylene of buying with trade name Rewopal PIB 1000 from Rewo company.Other suitable polymers are such as polyacrylamide (Seppigel 305), polyvinyl alcohol, PVP, PVP/VA copolymer, Polyethylene Glycol.Use castor oil hydrogenated dimerization dilinoleic acid ester (CAS 646054-62-8 also advantageously, INCI HydrogenatedCastor Oil Dimer Dilinoleate), it can be buied from Kokyu AlcoholKogyo company by trade name Risocast DA-H, perhaps also has PPG-3 benzyl ether myristinate (CAS 403517-45-3), it can be buied from Croda Chemicals company by trade name Crodamol STS, and the Dermacryl 79 of NationalStarch company (acrylate/octyl acrylamide copolymer).
The oil phase of preparation of the present invention advantageously is selected from polar oil, for example be selected from lecithin class and fatty acid triglyceride, promptly full and/or unsaturated side chain and/or unbranched and chain length are 8 to 24, the triglyceride of the alkyl carboxylic acid of preferred especially 12 to 18 C atoms.Fatty acid triglyceride can for example advantageously be selected from synthetic, semi-synthetic and natural oil, for example Cortex cocois radicis triglyceride, olive oil, sunflower oil, soybean oil, Oleum Arachidis hypogaeae semen, Oleum Brassicae campestris, almond oil, Petiolus Trachycarpi oil, Oleum Cocois, Oleum Ricini, wheat germ oil, grape-pip oil, Ji oil (Distel  l), Folium Salicis Babylonicae vegetable oil, macadimia nut oil and similar or the like.
In addition, the advantageously for example natural wax in animal and plant source, for example Cera Flava and other insect waxes and berry wax, Adeps Bovis seu Bubali resin and/or lanoline (Wollwachs) according to the present invention.
In category of the present invention, it is that the alkyl carboxylic acid of 3 to 30 C atoms and saturated and/or unsaturated side chain and/or unbranched and chain length are the ester that the alcohol of 3 to 30 C atoms forms that other favourable polar oil compositions can also be selected from by saturated and/or unsaturated side chain and/or unbranched and chain length, and to be selected from by aromatic carboxylic acid and saturated and/or unsaturated side chain and/or unbranched and chain length be the ester that the alcohol of 3 to 30 C atoms forms.Therefore, these ester oils can advantageously be selected from phenylethyl benzoate, octyl palmitate, the coconut oil monooctyl ester, the isostearic acid monooctyl ester, myristic acid octyl group dodecyl ester, octyldodecanol, the different pelargonate of 16/octadecyl, isopropyl myristate, isopropyl palmitate, isopropyl stearate, acid isopropyl, n-butyl stearate, the just own ester of lauric acid, oleic acid ester in the positive last of the ten Heavenly stems, the different monooctyl ester of stearic acid, stearic acid ester in the different ninth of the ten Heavenly Stems, isononyl isononanoate, Palmic acid 2-Octyl Nitrite, lauric acid 2-Octyl Nitrite, stearic acid 2-hexyl ester in the last of the ten Heavenly stems, Palmic acid 2-octyl group dodecyl ester, the enanthic acid stearyl, oleic acid oleic alcohol ester, the erucic acid oil alcohol ester, oleic acid two dodecenyl succinic esters, erucic acid two dodecenyl succinic esters, stearic acid three decyl ester, trimellitic acid three decyl ester and synthetic, the mixture of these semi-synthetic and natural esters is as Jojoba oil.
In addition, oil phase can advantageously be selected from dialkyl ether and dialkyl carbonate, advantageously such as two decoyl ethers (Cetiol OE) and/or two decoyl carbonic esters, for example can buy with trade name Cetiol CC from Cognis company.
In addition, also the preferred oil composition is selected from Isoeicosane, enanthic acid DOPCP, two sad/didecyl acid propylene glycol esters, caprylic/capric/two glyceryl succinates, dioctyl/didecyl butanediol ester, lactic acid C 12-13-Arrcostab, tartaric acid two C 12-13-Arrcostab, myristyl myristate, neopentanoic acid isodecyl ester, three isostearic acids, six sad/six capric acid dipentaerythritol ester, single isostearic acid propylene glycol ester, tricaprylin, Isosorbide dimethyl ether.The oil phase that particularly advantageously is preparation of the present invention contains a certain amount of benzoic acid C 12-15-Arrcostab or form by it fully.
In addition, favourable oil component is a salicylic acid butyl octyl ester (as buying with trade name Hallbrite BHB from CP Hall company) for example, benzoic acid six decyl ester and benzoic acid butyl octyl ester and their mixture (HallstarAB) and/or naphthalene diacid diethylhexyl ester (the Hallbrite TQ of Symrise company or Corapan TQ).
In the category of the present invention, also can use any mixture of this oil component and wax composition.
In addition, oil phase equally also advantageously contains nonpolar oil, for example be selected from those of side chain and unbranched hydrocarbon and wax, especially preferably mineral oil, vaseline (vaseline), paraffin oil, squalane and Squalene, polyolefin, Parleam, C13-16 isoparaffin, cyclomethicone, simethicone, phenyl front three silicone oil and 2-Methylpentadecane.In polyolefin, poly decene is preferred material.
Preparation of the present invention also can advantageously contain the material that one or more are selected from following silicone elastomer, has improved the resistance to water and/or the shading factor of product since for example using:
(a) silicone elastomer, it contains unit R 2SiO and RSiO 1.5And/or R 3SiO 0.5And/or SiO 2, wherein each radicals R is represented hydrogen, C independently of each other respectively 1-24-alkyl (for example methyl, ethyl, propyl group) or aryl (for example phenyl or tolyl), alkenyl (for example vinyl) and unit R 2SiO is to RSiO 1.5Weight ratio in 1: 1 to 30: 1 scope, select;
(b) insoluble and silicone elastomer in silicone oil with swelling ability, it obtains by organopolysiloxane (1) that contains the hydrogen that connects silicon and the additive reaction that contains the organopolysiloxane (2) of unsaturated aliphatic group, wherein select used consumption part, make the amount of unsaturated aliphatic group of the hydrogen of organopolysiloxane (1) or organopolysiloxane (2)
In 1 to 20mol% scope, when organic polysiloxanes non-annularity and
In 1 to 50mol% scope, when organic polysiloxanes is ring-type.
Advantageously silicone elastomer exists with spherical powder or gel form in category of the present invention.
The silicone elastomer that advantageously exists with the spherical powder form according to the present invention is the material with INCI title simethicone/vinyl-dimethyl silicone oil cross linked polymer, for example can buy with trade name DOW CORNING 9506 Powder from DOW CORNING company.
Special preferred silane elastomer and those are selected from the oil of hydrocarbon, artificial oil, synthetic ester, synthetic ether or their mixture of animal and/or plant origin and also use.
On the one hand, preparation is existed with the form of O/W emulsion.In this case, especially preferably make preparation contain the O/W-emulsifying agent that one or more are selected from following chemical compound group according to the present invention: stearic acid citric acid glyceride, tristerin (self emulsifying), stearic acid, stearate, polyglyceryl-3-methyl glucose distearate, Ceteareth-20, PEG-40 stearate, PEG-100 stearate, stearoyl-glutamic acid sodium and cetyl aromatic sulfuric acid sodium.
On the other hand, according to the present invention advantageously, preparation is existed with the form of W/O emulsion.In this case, especially preferably make preparation contain the W/O-emulsifying agent that one or more are selected from following chemical compound group: polyglyceryl-2-two multi-hydroxy stearic acid esters, PEG-30 two multi-hydroxy stearic acid esters, cetyl simethicone copolyol, polyglyceryl-3-diisopstearate according to the present invention.
Preparation of the present invention can also advantageously contain and has brown material of one's own, and for example dihydroxy acetone and/or melanin derivant and its are 1 weight % to 10 weight % in total formulation weight amount concentration.
In addition, preparation of the present invention can also advantageously contain the protective agent in order to protection mosquito, louse and Aranea and analog.Advantageously such as N; N-diethyl-3-methyl benzamide (trade name: Meta-delphene; " DEET "), dimethyl phthalic acid ester (trade name: Palatinol M; DMP), 1-piperidine carboxylic acid-2-(2-ethoxy)-1-methyl-propyl ester and particularly preferred 3-(N-normal-butyl-N-acetyl group-amino)-ethyl propionate (trade name Insekt Repellent  3535, Merck company buys).Protective agent both can use separately also and can be used in combination.
What can be called wetting agent (humidizer) is that those can give material or the mixture of substances of cosmetic formulation with following character, and promptly they can reduce cuticular aqueous vapor release property (being also referred to as transdermal fluid loss characteristics (TEWL)) and/or the horny layer hydration is played positive impact after applying or being scattered on the skin surface.
Wetting agent (humidizer) useful in category of the present invention is such as glycerol, and lactic acid and/or lactate be sodium lactate particularly, butanediol, propylene glycol, Biosaccaride Gum-1, Glycinesoya, the ethoxy urea, ethyl hexyl oxy glycerol, 2-pyrrolidone-5-carboxylic acid and carbamide.Particularly advantageously be to use in addition and be selected from water solublity and/or can be in water swollen and/or can utilize water and the polymerization humidizer of the polysaccharide of gelatinization.Particularly preferably be, for example, hyaluronic acid, chitosan and/or be rich in the polysaccharide of trehalose, it is compiled in chemical abstracts with registration number 178463-23-5 classification and can for example obtain from SOLABIA S.A. company with trade name Fucogel  1000.Humidizer also can be preferably used as crease-resistant active substance in order to the protecting skin pathological changes, those variations that occur during as skin aging.
In category of the present invention, advantageously make preparation of the present invention contain one or more wetting agents and its total concentration is 0.1 to 30 weight % and preferred 0.5 to 20 weight %, all in the total formulation weight amount.
Cosmetic formulation of the present invention in addition such as non-essential words can also advantageously contain the filler that those for example further improve preparation sensation and beauty treatment performance and for example can give or strengthen skin velvet or silk-like handle.In the category of the present invention, favourable filler is starch and starch derivatives (for example tapioca, PASELLI EASYGEL, ocentyl succinic aluminum-or sodium-starch and similar substance), has not both had pigment that main UV filters does not have coloration yet (for example Bornitrid etc.) and/or Aerosile (CAS 7631-86-9) and/or Talcum.
If use antioxidant as additive or active component, then more can obtain useful especially preparation.According to the present invention, preparation advantageously contains one or more antioxidants.Can use being fit to of the cosmetic applications that is useful on or antioxidant commonly used as favourable but still antioxidant that can choose use wantonly.
Particularly preferably in using water miscible antioxidant in the category of the present invention, for example vitamin, for example ascorbic acid and derivant thereof.
Preferred anti-oxidants also has vitamin E and derivant and vitamin A and derivant thereof.
The amount of antioxidant in the preparation (one or more chemical compounds) is preferably 0.001 to 30 weight %, preferred especially 0.05 to 20 weight %, particularly 0.1 to 10 weight %, with total restatement of preparation.
If vitamin E and/or its derivant are antioxidant, then preferred its concentration separately is selected from the scope of 0.001 to 10 weight %, with total restatement of preparation.
If vitamin A or vitamin A derivative, perhaps the carotene or derivatives thereof is an antioxidant, and then preferred its concentration separately is selected from the scope of 0.001 to 10 weight %, with total restatement of preparation.
Especially preferably make cosmetic formulation contain the cosmetic activity composition, and preferred active component is an antioxidant of can protecting skin resisting Oxidation according to the present invention.
Other preferred active component are natural active matter and/or its derivant in the category of the present invention, for example α-liponic acid, folic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosyl rutin, carnitine, carnosine, natural and/or synthetic isoflavone, creatine, kreatinin, taurine and/or β-alanine and 8-hexadecylene-1,16-dicarboxylic acids (binary acid, CAS 20701-68-2; INCI title in the past is an octadecene diacid) and/or licochalcone A.
Comprise all crease-resistant as is known active component such as flavone glycoside (particularly alpha-glycosyl rutin), coenzyme Q10, the prescription of the present invention of vitamin E and/or derivant and similar substance, be suitable for preventing the not dermatosis of grace attractive in appearance valuably especially, for example those that occur when skin aging are (as drying, coarse and form exsiccant wrinkle, scratch where it itches, return fat (R ü ckfettung) and reduce (after for example having a bath), visible blood vessel enlarges (Teleangiektasien, Cuperosis), cutis laxa and formation wrinkle and little microgroove, partial hyperchromatism, pigment is not enough and pigment disappearance (as senile plaque), mechanical stress resistance poor (for example being chapped from the cold) and similar symptom) and prevention skin fatigue.In addition, they also advantageously are suitable for preventing to form the apparent of drying or coarse skin.
Cosmetic formulation of the present invention can contain just like those beauty aids of usually using in these preparations, and for example antistaling agent, preservation auxiliary agent, complex form agent, antibacterial, spice, inhibition or increase foamy material, have the pigment of dyeing function and other the conventional components in pigment, thickening agent, moistening and/or the material of preserving moisture, the filler that improves dermal sensation, fat, oil, wax or beauty treatment or the dermatology preparation as alcohol, polyhydric alcohol, polymer, foam stabiliser, electrolyte, organic solvent or silicone derivative.
Preferred formulation is used for nursing skin in category of the present invention: they can play the beauty treatment anti-sunlight function, also are used as cosmetics at beauty treatment fields in addition.
Form structure according to it, cosmetic composition can for example be used as protective skin cream, day cream or late frost etc. in category of the present invention.The optional bed material that can also and preferably compositions of the present invention be used as pharmaceutical preparation.
In category of the present invention also preferred for preparation to go out its primary and foremost purpose be not protection sunlight and still contain the cosmetic formulation of a certain amount of UV-protective substance.Therefore, in day cream or cosmetics, sneak into UV-A or UV-B protective substance usually.UV-protective substance and antioxidant and randomly preserving agent also make preparation itself play effectively anti-corrupt protective effect.In addition, cosmetic formulation also can be valuably exists with the form of sunscreen.
According to the present invention, especially preferably preparation of the present invention is used for protecting skin aging (skin aging of particularly preventing UV to cause) and is used as sunscreen.
Also preferred preparation of the present invention has 5 to 8 pH value according to the present invention.This can regulate by traditional acid, alkali and buffering system and obtain.
As for use, cosmetic formulation of the present invention can with method capacity commonly used on the cosmetology be applied on skin and/or the hair.
Contrast test
A B C D E F
Trade name Raw material m[％] m[％] m[％] m[％] m[％] m[％]
Polyglyceryl-3 methyl glucose distearate 1.5 1.5 1.5 1.5 1.5 1.5
Butyl methoxydibenzoylmethise 2.0 2.0 2.0 2.0 2.0 2.0
Ethylhexyl salicylate 5.0 5.0 5.0 5.0 5.0 5.0
Phenylbenzimidazolesulfonic acid 3.0 3.0 3.0 3.0 3.0
Glycerol 7.0 7.0 7.0 7.0 7.0 7.0
Butanediol dicaprylate/dicaprate 3.0 3.0 3.0 3.0 3.0 3.0
Vinylpyrrolidone and acrylic acid copolymer 1.6 1.6
Pemulen TR 1 The cross linked polymer of acrylate/acrylic acid C10-30 Arrcostab 1.6
Aristoflex AVC Ammonium acryloyldime-thyltaurate// VP copolymer 1.6
Natrosol Plus 330CS Cetyl hydroxyethyl cellulose 1.6
Keltrol F Xanthan gum 1.6
Preserving agent In right amount In right amount In right amount In right amount In right amount In right amount
Nertralizer In right amount In right amount In right amount In right amount In right amount In right amount
Spice In right amount In right amount In right amount In right amount In right amount In right amount
Water Supply 100 Supply 100 Supply 100 Supply 100 Supply 100 Supply 100
25 ℃ of viscosity (Haake VT02) that following mPa*s represents ＞10000 7000 3000
Stability Stable Stable Inhomogeneous Stable Inhomogeneous Inhomogeneous
Outward appearance+sensation Smooth, even, but fine dispersion, and dermal sensation is comfortable Wire drawing is arranged Be clamminess Acinous clearly
Embodiment
Following examples are used with elaboration the present invention, and are not to be to its restriction.All consumption descriptions, umber and percentage composition, if do not specify, weight that all is meant and total amount or in the gross weight of preparation.
The O/W-emulsion
Emulsion A B C D E F G H
Glycerol stearic acid citrate 1.5 1.5 2
Stearic acid Pyrusussuriensis polysaccharide ester 1.0
Polyglyceryl-3-methyl glucose distearate 0.5 1.5 2.5 3.0 1.5
16/stearyl alcohol 2 1.5
Stearyl alcohol 2 1
Cetyl alcohol 3
Vinyl pyrrolidone and acrylic acid copolymer 0.5 1.5 1.0 3.0 1.6 1.5 0.8 2.0
The cross linked polymer of acrylate/acrylic acid C10-30 Arrcostab 0.3
Benzoic acid C 12-15Arrcostab 5 3
Butanediol dicaprylate/dicaprate 10 5 5
The phenethyl benzoate 3
Two decoyl ethers
Octyl group dodecyl alcohol 3 3 5
Two decoyl carbonic esters 5 2
Myristyl myristate 1 2
The caprylic/capric triglyceride 2 2 3
Neopentanoic acid isodecyl ester
2-Methylpentadecane 2
Cyclomethicone 5 3 4
Simethicone 2
Butanediol 2 5 8
Glycerol 2 5 10 5 7.5 4 2
C18-38 acid triglyceride 1
Diethyl hexyloxy phenol methoxyphenyl triazine 2 1 2
Butyl methoxydibenzoylmethise 2.5 3 2 5
Diethylamino oxybenzene formyl hexyl benzene formic acid esters 1 4
The ethylhexyl methoxy cinnamic acid 5 7.5
Ethylhexyl salicylate 4 5
2-hydroxyl-4-methoxy benzophenone 2
Phenylbenzimidazolesulfonic acid 3 2 1 4 2 1.5 4 2
Phenylene-1,4-two-(2-benzimidazolyl)-3,3 ', 5,5 '-tetrasulfonic acid 2 2
The ethylhexyl triazine 2 2 1
Diethylhexyl fourth amino triazine 1
Octadecene diacid 1
Octene succinic acid aluminum starch 1
Octene sodium succinate starch 3 1.5
Tapioca 2 1 3
Alcohol 0.5 3 5
Taurine 0.1 0.2 0.5 0.2
Folic acid 0.01 0.03 0.01 0.02 0.03
Vitamin e acetate 0.2 0.2 0.2 0.3 0.1 0.5
Na 2H 2EDTA 0.1 0.1 0.2 0.2 0.2 0.5
Perfume, preserving agent In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Pigment etc. In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Sodium hydroxide In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Water Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0
The O/W-emulsion
Emulsion I K L M N O P Q
The PEG-40 stearate 1.5 2 0.8 0.5
Tristerin 3.5 2.6 2
The stearoyl sodium hydrogen alpha-aminoglutarate 0.05 0.1 0.2 0.5
16/stearyl alcohol 3
Stearyl alcohol 2
Cetyl alcohol
The copolymer that vinyl pyrrolidone and acrylic acid form 1.6 0.5 1.5 3 2 1.6 0.5 1
Carbomer 0.2 0.3 0.2
Benzoic acid C 12-15Arrcostab 7 3 3 5 1 10
Butanediol dicaprylate/dicaprate 9 3 2 8 10
The phenethyl benzoate 5 2 5
Two decoyl ethers
Octyl group dodecyl alcohol 3 5 2 4
Two decoyl carbonic esters 2
Myristyl myristate 1
The caprylic/capric triglyceride 2
Neopentanoic acid isodecyl ester 3
2-Methylpentadecane 3
Cyclomethicone 5 2
Simethicone 5 2
Glycerol 3 5 5 7 10 2 5 8
Diethyl hexyloxy phenol methoxyphenyl triazine 3 1 2
Butyl methoxydibenzoylmethise 1 2.5 4 3
Polysilicon-15 3 2
The ethylhexyl Methoxycinnamate 2 5 3
Ethylhexyl salicylate 5 3 2
Octocrylene 4
Phenylbenzimidazolesulfonic acid 4 1 2 3 1 0.5 1 2.5
Phenylene-1,4-two-(2-benzimidazolyl)-3,3 ', 5,5 '-tetrasulfonic acid 2 1 3 0.5
The ethylhexyl triazine 2 3
Titanium dioxide 0.5 2
Octene succinic acid aluminum starch 1 5 2 2
Octene sodium succinate starch 2 3
Tapioca 3 2
Alcohol 2 5 4
Folic acid 0.03 0.01 0.03 0.03 0.02
Q10 0.03 0.05
Na 2H 2EDTA 0.1 0.1 0.2 0.1 0.2 0.2 0.2 0.5
Spice, preserving agent In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Pigment etc. In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Sodium hydroxide In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Water Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0
The O/W-emulsion
Emulsion S T U V W X Y Z
16/stearyl alcohol+PEG-40 Oleum Ricini+16/sodium stearyl sulfate 2.5 2.5 3
Tristerin SE 1 1 1.5
16/octodecyl alcohol polyoxyethylene (20) ether 1 0.5 0.5
16/stearyl alcohol
Stearyl alcohol
Cetyl alcohol
Acrylate/acrylic acid C10-30 alkyl ester cross-linked polymer 0.3 0.5 0.3
Vinyl pyrrolidone and acrylic acid copolymer 1.5 1.0 2 3 3 4 1 2.5
Benzoic acid C 12-15Arrcostab 10 5 4 3 2 5
Butanediol dicaprylate/dicaprate 10 5 3 5 8
The phenethyl benzoate 5 2
Two decoyl ethers 2
Octyl group dodecyl alcohol 2 2 1
Two decoyl carbonic esters 2 2
The caprylic/capric triglyceride 3 3
Dermol 105 2 3
Cyclomethicone 4 3
Simethicone 3 2
Glycerol 5 3 2 5 7 1 8 2
VP/ hexadecylene copolymer 1 1
C18-38 acid triglyceride 1 1 1
Two-ethyl hexyl oxy phenol methoxybenzene triazine 2 1
Butyl methoxydibenzoylmethise 5 1 2.5 2.5 2
Homosalate 5 5
The ethylhexyl Methoxycinnamate 5 8 5 5
Diethylamino oxybenzene formyl hexyl benzene formic acid esters 3 2
Octocrylene 8 5 5
Ethylhexyl salicylate 5 3
Phenylbenzimidazolesulfonic acid 3 2 2 2 1 3 2 2
Phenylene-1,4-two-(2-benzimidazolyl)-3,3 ', 5,5 '-tetrasulfonic acid 1 2 2 3 2.5
The ethylhexyl triazine 3 2 2
Diethylhexyl fourth amino triazine 2
2-hydroxyl-4-methoxy benzophenone 2
2,4-two-[5-1 (dimethyl propyl) benzoxazol-2-base-(4-phenyl)-imino group]-6-(2-ethylhexyl)-imino group-1,3,5-triazines 3 1
Titanium dioxide 5 3
Octene succinic acid aluminum starch 2 0.5
Octene sodium succinate starch 1.5 1 0.5
Tapioca 3 1
Alcohol 3 5 4 4 2
Taurine 0.5 0.2 0.6 1 0.1
Vitamin E 1 0.2 0.5 0.3 0.5
Na 2H 2EDTA 0.1 0.1 0.2 0.1 0.1 0.2 0.2 0.5
Spice, preserving agent In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Pigment etc. In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Sodium hydroxide In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
Water Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0 Supply 100.0

Claims (10)

1, cosmetic formulation comprises
A) one or more are selected from chemical compound 2-Phenylbenzimidazole-5-sulfonic acid and sodium salt, potassium salt and tri ethanol ammonium salt and phenylene-1,4-two-(2-benzimidazolyl)-3,3 ', 5,5 '-the water solublity UV shading filtering agent of tetrasulfonic acid and sodium salt, potassium salt and tri ethanol ammonium salt
B) vinyl pyrrolidone and acrylic acid copolymer.
2, cosmetic formulation as claimed in claim 1 is characterized in that, it is the water solublity UV shading filtering agent of 0.1 to 20 weight % that preparation contains in the concentration of total formulation weight amount.
3, the described cosmetic formulation of one of claim as described above is characterized in that it is vinyl pyrrolidone and the acrylic acid copolymer of 0.1 to 10 weight % that preparation contains in total formulation weight amount concentration.
4, the described cosmetic formulation of one of claim as described above is characterized in that water solublity UV shading filtering agent is 1: 15 to 15: 1 to the weight ratio of copolymer.
5, the described cosmetic formulation of one of claim as described above is characterized in that copolymer is crosslinked with pentaerythritol triallyl ether.
6, the described cosmetic formulation of one of claim as described above is characterized in that polymer contains 25-80 weight % vinyl pyrrolidone, 20-80 weight % acrylic acid and 0.4-2 weight % pentaerythritol triallyl ether.
7, the described cosmetic formulation of one of claim as described above is characterized in that preparation exists with emulsion form.
8, the described cosmetic formulation of one of claim as described above is characterized in that, preparation also contains one or more other UV-filtering agent, and it is selected from following chemical compound group: 1, and 4-two (the 2-oxo-bornenyl methyl of 10-sulfo--3-)-benzene and salt thereof; 4-(the bornenyl methyl of 2-oxo-3-) benzene sulfonate; 2-methyl-5-(the bornenyl methyl of 2-oxo-3-) sulfonate; 2,2 '-methylene-two-(6-(2H-benzotriazole-2-yl)-4-(1,1,3, the 3-tetramethyl butyl)-phenol; 2-(2H-benzotriazole-2-yl)-4-methyl-6-[2-methyl-3-[1,3,3,3-tetramethyl-1-[(trimethyl silyl) the oxygen base] the disiloxane base] propyl group]-phenol; 3-(4-methylbenzene methylene) Camphora; 3-benzylidene Camphora; Ethylhexyl salicylate; The Terephthalidene Dicamphor Sulfonic Acid; 4-(dimethylamino)-benzoic acid (2-ethylhexyl) ester; 4-(dimethylamino) benzoic acid-pentyl ester; 4-methoxybenzene methylene malonic acid two (2-ethylhexyl) ester; 4-methoxy cinnamic acid (2-ethylhexyl) ester; 4-methoxy cinnamic acid isopentyl ester; 2-hydroxyl-4-methoxy benzophenone; 2-hydroxyl-4-methoxyl group-4 '-the methyldiphenyl ketone; 2,2 '-dihydroxy-4-methoxy benzophenone; 2-(4 '-diethylamino-2 '-hydroxy benzoyl)-hexyl-benzoate; 4-(tert-butyl group)-4 '-methoxy dibenzoyl methane; High menthyl salicylate; 2-ethylhexyl-2 hydroxybenzoic acid ester; 2-ethylhexyl-2-cyano group-3,3-diphenylacrylate ester; Dimethyl polysiloxane diethylbenzene methylene malonate; 3-(4-(2,2-di ethoxy carbonyl vinyl)-phenoxy group) acrylic)-methoxyl group siloxanes/dimethyl siloxane-copolymer; 2,4-two-{ [4-(2-ethyl-hexyloxy)-2-hydroxyl]-phenyl }-6-(4-methoxyphenyl)-1,3,5-triazines (INCI: two-ethyl hexyl oxy phenol methoxyphenyl triazine); Dioctyl butyl amide triazinone (INCI: diethylhexyl-butyramide triazinone); 2,4-two-[5-1-(dimethyl propyl) benzoxazol-2-base-(4-phenyl)-imino group]-6-(2-ethylhexyl)-imino group-1,3,5-triazines (CAS 288254-16-0); 4,4 ', 4 " (1,3; 5-triazine-2,4,6-three basic three imino groups)-three-benzoic acid-three (2-ethyl hexyl ester) (all right: 2,4; 6-three-[anilino--(right-carbonyl-2 '-ethyl-1 '-hexyloxy)]-1,3,5-triazines (INCI: the ethylhexyl triazinone)); 2,4,6-terphenyl-4-base-1,3,5-triazines; Merocyanine; Titanium dioxide; Zinc oxide, and concentration is counted 0.01 to 40 weight % with total formulation weight.
9, the described preparation of one of claim as described above is characterized in that, preparation also contains salt soluble in water and its concentration in total formulation weight amount 0.001 to 10 weight %.
10, the described preparation of one of claim as described above is characterized in that the not fatty alcohol of preparation.
CN2007101527303A 2007-02-16 2007-02-16 Cosmetic preparation containing vinylpyrrolidone/acrylic acid copolymer Expired - Fee Related CN101244015B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102573995A (en) * 2009-11-05 2012-07-11 莱雅公司 Cosmetic compositions comprising an ester derived from 4-carboxy-2-pyrrolidinone and a merocyanin screening agent

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10355711A1 (en) * 2003-11-26 2005-06-16 Beiersdorf Ag Cosmetic and dermatological emulsions containing creatine and / or creatinine and electrolyte concentrations, an ionic strength of at least 50 mmol / l
US7276230B2 (en) * 2003-12-23 2007-10-02 Avon Products, Inc. Sunscreen compounds and compositions containing same and methods for use thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102573995A (en) * 2009-11-05 2012-07-11 莱雅公司 Cosmetic compositions comprising an ester derived from 4-carboxy-2-pyrrolidinone and a merocyanin screening agent

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