CN101235553A - Fused mass directly spinning production method for core-skin structure ultraviolet resistant function fiber - Google Patents

Fused mass directly spinning production method for core-skin structure ultraviolet resistant function fiber Download PDF

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Publication number
CN101235553A
CN101235553A CNA2007101913271A CN200710191327A CN101235553A CN 101235553 A CN101235553 A CN 101235553A CN A2007101913271 A CNA2007101913271 A CN A2007101913271A CN 200710191327 A CN200710191327 A CN 200710191327A CN 101235553 A CN101235553 A CN 101235553A
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China
Prior art keywords
core
skin
melt
spinning
ultraviolet function
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Pending
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CNA2007101913271A
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Chinese (zh)
Inventor
辛婷芬
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Shenghong Group Co Ltd
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Shenghong Group Co Ltd
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Application filed by Shenghong Group Co Ltd filed Critical Shenghong Group Co Ltd
Priority to CNA2007101913271A priority Critical patent/CN101235553A/en
Publication of CN101235553A publication Critical patent/CN101235553A/en
Pending legal-status Critical Current

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  • Artificial Filaments (AREA)

Abstract

The invention relates to a method for producing fiber with skin-core structure and anti-ultraviolet function by melt direct spinning, in particular relates to a production method for producing the fiber with skin-core structure and anti-ultraviolet function by adopting melt of the direct spinning and the melt produced by twin-screw to pass through a compound spinning box and a core-skin compound component, wherein the direct spinning melt is a core layer, wherein the proportion by weight of the skin-core is 2:8- 6:4, the formulation of percentage by weight of the skin-layer material is that: the skin-core polymerized substance is 75-85%, the anti-ultraviolet function nanometer powder is 15-25%, and the coupling agent is 0.2-4%, wherein the skin-layer material is 100% polymerized substance. Preceding the production by adopting the compound spinning box and the compound spinning method, the method has the advantages of utilizing the conventional device, simple technology, easy operation, low cost, and convenient industrialized popularization and application.

Description

A kind of fused mass directly spinning is produced the method for skin-core structure uvioresistant function fiber
Technical field
The present invention relates to functional chemical fibre manufacturing technology, exactly is the method that a kind of fused mass directly spinning is produced skin-core structure uvioresistant function fiber, belongs to chemical fiber field
Background technology
At present, the kind of domestic functional fiber and the mode of production thereof have a lot, sum up to get up to comprise: production technology is spun in the twin-screw section; Though a little methods such as island composite algorithm production technology also can production performance functional fibre preferably, all have weak point.Twin-screw method and island composite algorithm production procedure are long, complex procedures, and technique controlling difficulty is big, and the product physical and chemical performance is inhomogeneous
Summary of the invention
At the deficiencies in the prior art, the technical problem that quasi-solution of the present invention is determined has provided a kind of manufacture method of new uvioresistant function fiber.
The objective of the invention is to design a kind of functional fiber with skin-core structure, the core-skin volume ratio is 2: 8~6: 4; The percentage by weight prescription of its cortex material is: cortex polymer 75~85%, anti-ultraviolet function nanometer powder (inorganic nano ultraviolet light screener) 15~25%, coupling agent 0.2~4%; Its core layer material is 100% polymer
The object of the present invention is achieved like this:
1 makes the cortex material melt: after by the prescription of described cortex material cortex polymer anti-ultraviolet function nanometer powder and coupling agent evenly being mixed, under 180~290 ℃ of temperature, extrude through twin-screw, obtain the cortex melt;
2 with the method injection composite component of above-mentioned cortex melt by the frequency conversion metering; Another melt inlet of composite component directly is connected with the measuring pump of melt Direct Spinning
3 compounding flux spray from the spinnerets of composite component, and melt spins production procedure and carries out the uvioresistant function fiber that spinning silk winding makes skin-core structure of the present invention routinely then
Anti-ultraviolet function nanometer powder particle diameter of the present invention should be the following fine particle of 45nm
High polymer of the present invention includes but not limited to high polymers such as PET, PBT, PTT, and the high poly-high polymer of described core-skin is identical.
Uvioresistant function kinetodesma of the present invention is owing to adopted core-sheath composite structure, in fact its core-skin layer is equivalent to section and spins functional fibre, and its sandwich layer is because of being identical with the most component of cortex, thereby can solve qualitative compatibling problem, lamination can not occur.Simultaneously, make, can also solve the not wide old trouble of other composite spinning method technology fine setting property by the multiple unit tube structural reform.
The present invention uses conventional equipment, and technology is simple, and processing ease is with low cost, is convenient to industrialization promotion and uses.
The specific embodiment
Below provide 1 specific embodiment of the present invention:
Get 78 parts of dried PET sections (weight, down together); Average grain diameter is that 35nm and surface treated model are 20 parts in the nano ultraviolet screener powder of ZO-WP015, and 2 parts of coupling agents after abundant mixing, are extruded through twin-screw under 286 ℃ and produced the cortex melt; Fiber core-skin weight ratio by 3: 7 spins out uvioresistant function PET long filament with the melt Direct Spinning mode of production.
ZO-WP015 nano ultraviolet screener powder is produced by the positive nano material in Shanghai, Shanghai Co., Ltd, and its Main Ingredients and Appearance is compounds such as ZnO, TiO2.
The following table of product proterties:
Outward appearance White powder
Solid content 15%
Dissolubility Be scattered in water
Ionic Nonionic
PH value Neutral
Products characteristics:
◎ Environmental Safety, environmentally safe have no side effect to human body;
◎ good hand feeling and washability;
The uvioresistant effect of ◎ high-efficient and lasting (rate of ultraviolet shield can reach more than 95%).
Using method: the percentage by 2%~5% adds

Claims (5)

1, the present invention relates to the method that a kind of fused mass directly spinning is produced skin-core structure uvioresistant function fiber, it is characterized in that: its technological process is as follows:
Figure S2007101913271C00011
The described melt A that directly spins is for including but not limited to high polymers such as PET, PBT, PTT
Described melt B is to adopt anti-ultraviolet function nanometer powder, high polymer blend that coupling agent is identical with melt A to extrude the melt of making by twin-screw.
2, as the described method of claim one, it is characterized in that: core-skin weight percentages prescription is 2: 8~6: 4.
3, as the described method of claim one, it is characterized in that A is a sandwich layer, B is a cortex.
4, as the described method of claim one: it is characterized in that: cortex high polymer 75~85%, anti-ultraviolet function nanometer powder 15~25%, coupling agent 0.2~4%.
5, the production technology of uvioresistant function fiber according to claim 1 is characterized in that: anti-ultraviolet function nanometer powder particle diameter should be the following fine particle of 45nm.
CNA2007101913271A 2007-12-18 2007-12-18 Fused mass directly spinning production method for core-skin structure ultraviolet resistant function fiber Pending CN101235553A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2007101913271A CN101235553A (en) 2007-12-18 2007-12-18 Fused mass directly spinning production method for core-skin structure ultraviolet resistant function fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2007101913271A CN101235553A (en) 2007-12-18 2007-12-18 Fused mass directly spinning production method for core-skin structure ultraviolet resistant function fiber

Publications (1)

Publication Number Publication Date
CN101235553A true CN101235553A (en) 2008-08-06

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Country Status (1)

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CN (1) CN101235553A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710790A (en) * 2013-12-30 2014-04-09 厦门翔鹭化纤股份有限公司 Antistatic, antibacterial and graphene-reinforced composite polyester fiber and preparation method thereof
CN104499089A (en) * 2014-12-10 2015-04-08 滨州东方地毯有限公司 Modified polypropylene fiber and preparation method thereof
CN104963014A (en) * 2015-06-01 2015-10-07 吴江市海成纺织有限公司 Anti-perspective PTT fiber and preparation method thereof
CN104963012A (en) * 2015-06-01 2015-10-07 吴江市海成纺织有限公司 Anti-perspective PBT fiber and preparation method thereof
CN112796005A (en) * 2020-12-30 2021-05-14 盐城工学院 Sheath-core type two-component anti-static anti-ultraviolet fiber and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710790A (en) * 2013-12-30 2014-04-09 厦门翔鹭化纤股份有限公司 Antistatic, antibacterial and graphene-reinforced composite polyester fiber and preparation method thereof
CN104499089A (en) * 2014-12-10 2015-04-08 滨州东方地毯有限公司 Modified polypropylene fiber and preparation method thereof
CN104963014A (en) * 2015-06-01 2015-10-07 吴江市海成纺织有限公司 Anti-perspective PTT fiber and preparation method thereof
CN104963012A (en) * 2015-06-01 2015-10-07 吴江市海成纺织有限公司 Anti-perspective PBT fiber and preparation method thereof
CN104963012B (en) * 2015-06-01 2017-09-05 吴江市海成纺织有限公司 A kind of anti-perspective PBT fibers and preparation method thereof
CN104963014B (en) * 2015-06-01 2017-09-05 吴江市海成纺织有限公司 A kind of anti-perspective ptt fiber and preparation method thereof
CN112796005A (en) * 2020-12-30 2021-05-14 盐城工学院 Sheath-core type two-component anti-static anti-ultraviolet fiber and preparation method thereof
CN112796005B (en) * 2020-12-30 2023-05-23 盐城工学院 Sheath-core type double-component anti-static reactance ultraviolet fiber and preparation method thereof

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Open date: 20080806