CN101234327B - Filter material additive and its preparation - Google Patents
Filter material additive and its preparation Download PDFInfo
- Publication number
- CN101234327B CN101234327B CN2008100080725A CN200810008072A CN101234327B CN 101234327 B CN101234327 B CN 101234327B CN 2008100080725 A CN2008100080725 A CN 2008100080725A CN 200810008072 A CN200810008072 A CN 200810008072A CN 101234327 B CN101234327 B CN 101234327B
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- CN
- China
- Prior art keywords
- nano material
- oleic acid
- glyceryl triacetate
- cigarette
- filter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000463 material Substances 0.000 title claims abstract description 74
- 239000000654 additive Substances 0.000 title claims description 43
- 230000000996 additive effect Effects 0.000 title claims description 43
- 238000002360 preparation method Methods 0.000 title description 6
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims abstract description 112
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 68
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 68
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000005642 Oleic acid Substances 0.000 claims abstract description 68
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 68
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000001087 glyceryl triacetate Substances 0.000 claims abstract description 56
- 235000013773 glyceryl triacetate Nutrition 0.000 claims abstract description 56
- 229960002622 triacetin Drugs 0.000 claims abstract description 56
- 239000002086 nanomaterial Substances 0.000 claims description 99
- 238000012986 modification Methods 0.000 claims description 67
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 63
- 230000004048 modification Effects 0.000 claims description 61
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 30
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 23
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 15
- 238000001914 filtration Methods 0.000 abstract description 35
- 239000000126 substance Substances 0.000 abstract description 7
- -1 oleic acid modified silicon dioxide Chemical class 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 235000019504 cigarettes Nutrition 0.000 description 59
- DXBHBZVCASKNBY-UHFFFAOYSA-N 1,2-Benz(a)anthracene Chemical compound C1=CC=C2C3=CC4=CC=CC=C4C=C3C=CC2=C1 DXBHBZVCASKNBY-UHFFFAOYSA-N 0.000 description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 29
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 28
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 22
- 229920006221 acetate fiber Polymers 0.000 description 19
- 241000208125 Nicotiana Species 0.000 description 14
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 14
- 239000007789 gas Substances 0.000 description 13
- 239000000377 silicon dioxide Substances 0.000 description 13
- 239000000779 smoke Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 239000004408 titanium dioxide Substances 0.000 description 12
- 239000002105 nanoparticle Substances 0.000 description 11
- 230000000391 smoking effect Effects 0.000 description 11
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- 239000003546 flue gas Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003480 eluent Substances 0.000 description 6
- 230000036541 health Effects 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 5
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 5
- 229960002715 nicotine Drugs 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- BXYPVKMROLGXJI-JTQLQIEISA-N 3-[(2s)-1-nitrosopiperidin-2-yl]pyridine Chemical compound O=NN1CCCC[C@H]1C1=CC=CN=C1 BXYPVKMROLGXJI-JTQLQIEISA-N 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 4
- 238000003556 assay Methods 0.000 description 4
- 125000005605 benzo group Chemical group 0.000 description 4
- 229940049706 benzodiazepine Drugs 0.000 description 4
- 238000004587 chromatography analysis Methods 0.000 description 4
- 239000011285 coke tar Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 4
- 238000001031 gas chromatography-thermal energy analyser Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000011269 tar Substances 0.000 description 4
- LUBXLGUQZVKOFP-UHFFFAOYSA-N 9-phenylanthracene Chemical compound C1=CC=CC=C1C1=C(C=CC=C2)C2=CC2=CC=CC=C12 LUBXLGUQZVKOFP-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 239000011668 ascorbic acid Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000002137 ultrasound extraction Methods 0.000 description 3
- 108091005944 Cerulean Proteins 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- WDECIBYCCFPHNR-UHFFFAOYSA-N chrysene Chemical compound C1=CC=CC2=CC=C3C4=CC=CC=C4C=CC3=C21 WDECIBYCCFPHNR-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- XKABJYQDMJTNGQ-VIFPVBQESA-N n-nitrosonornicotine Chemical compound O=NN1CCC[C@H]1C1=CC=CN=C1 XKABJYQDMJTNGQ-VIFPVBQESA-N 0.000 description 2
- 238000002414 normal-phase solid-phase extraction Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 235000019505 tobacco product Nutrition 0.000 description 2
- TXVHTIQJNYSSKO-UHFFFAOYSA-N BeP Natural products C1=CC=C2C3=CC=CC=C3C3=CC=CC4=CC=C1C2=C34 TXVHTIQJNYSSKO-UHFFFAOYSA-N 0.000 description 1
- 206010061216 Infarction Diseases 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 206010035664 Pneumonia Diseases 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 206010006451 bronchitis Diseases 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000007574 infarction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010813 internal standard method Methods 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229920005547 polycyclic aromatic hydrocarbon Polymers 0.000 description 1
- 238000004451 qualitative analysis Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
NNK content (ng/ props up) | 59.32? | 60.08? | 53.28? | 54.68? | 77.42? |
NNK reduced rate (%) | 23.4? | 22.4? | 31.2? | 29.4? | -? |
NNK selectivity reduced rate (%) | 22.9? | 29.2? | 38.6? | 38.1? | -? |
Nitrosamine total content (ng/ props up) | 255.4 8? | 247.0 0? | 234.5 2? | 227.7 2? | 356.0 0? |
Nitrosamine reduced rate (%) | 28.2? | 30.6? | 34.1? | 36.0? | -? |
Nitrosamine selectivity reduced rate (%) | 27.7? | 37.4? | 41.5? | 44.7? | -? |
Benzo [a] anthracene content (ng/ props up) | 14.25? | 11.12? | 10.88? | 10.48? | 16.78? |
Benzo [a] anthracene reduced rate (%) | 15.1? | 33.7? | 35.2? | 37.5? | -? |
Benzo [a] anthracene selectivity reduced rate (%) | 14.6? | 40.5? | 42.6? | 46.2? | -? |
Content (ng/ props up) | 24.16? | 21.48? | 21.45? | 20.89? | 28.51? |
Reduced rate (%) | 15.3? | 24.7? | 24.8? | 26.7? | -? |
Selectivity reduced rate (%) | 14.8? | 31.5? | 32.2? | 35.4? | -? |
Benzo [a] pyrene content (ng/ props up) | 8.02? | 6.93? | 6.25? | 6.04? | 10.68? |
Benzo [a] pyrene reduced rate (%) | 24.9? | 35.1? | 41.5? | 43.4? | -? |
Benzo [a] pyrene selectivity reduced rate (%) | 24.4? | 41.9? | 48.9? | 52.1? | -? |
Condensed-nuclei aromatics total content (ng/ props up) | 46.43? | 39.53? | 38.58? | 37.41? | 55.97? |
Condensed-nuclei aromatics reduced rate (%) | 17.0? | 29.4? | 31.1? | 33.2? | -? |
Condensed-nuclei aromatics selectivity reduced rate (%) | 16.5? | 36.2? | 38.5? | 41.9? | -? |
Claims (14)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008100080725A CN101234327B (en) | 2008-03-06 | 2008-03-06 | Filter material additive and its preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008100080725A CN101234327B (en) | 2008-03-06 | 2008-03-06 | Filter material additive and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101234327A CN101234327A (en) | 2008-08-06 |
CN101234327B true CN101234327B (en) | 2011-04-13 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2008100080725A Active CN101234327B (en) | 2008-03-06 | 2008-03-06 | Filter material additive and its preparation |
Country Status (1)
Country | Link |
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CN (1) | CN101234327B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102715655B (en) * | 2011-10-20 | 2014-05-07 | 广西中烟工业有限责任公司 | Cigarette filter stick capable of reducing phenol and crotonaldehyde ingredients in cigarette smoke |
-
2008
- 2008-03-06 CN CN2008100080725A patent/CN101234327B/en active Active
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Publication number | Publication date |
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CN101234327A (en) | 2008-08-06 |
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Free format text: FORMER OWNER: LIU LIKUI Effective date: 20131008 Owner name: LIAONING SIDA TONGHE TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: ZHU YONGFA Effective date: 20131008 |
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Free format text: CORRECT: ADDRESS; FROM: 100084 HAIDIAN, BEIJING TO: 123129 FUXIN, LIAONING PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20131008 Address after: 123129 fluorine chemical District, Fuxin, Liaoning Patentee after: Liaoning four Tonghe Technology Co., Ltd. Address before: 100084 Department of chemistry, Tsinghua University, Beijing, Haidian District Patentee before: Zhu Yongfa Patentee before: Liu Likui |