CN101232052A - Dye sensitization solar cell module - Google Patents
Dye sensitization solar cell module Download PDFInfo
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- CN101232052A CN101232052A CN 200810010368 CN200810010368A CN101232052A CN 101232052 A CN101232052 A CN 101232052A CN 200810010368 CN200810010368 CN 200810010368 CN 200810010368 A CN200810010368 A CN 200810010368A CN 101232052 A CN101232052 A CN 101232052A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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Abstract
A dye-sensitized solar cell module, which belongs to the field of photoelectric conversion device technology, comprises a first electrode and a second electrode arranged correspondingly, wherein the peripheries of the first and the second electrodes are sealed to form a sealed cavity, and the cavity is filled with electrolyte; a nano porous semiconductor thin film soaked with a photosensitive material is arranged on the side of the work region of the first electrode; a catalyst layer is arranged on the side of the work region of the second electrode; and at least one of the first and the second electrode is transparent. The sealed structure is characterized in that one or more pinholes are provided on at least one electrode and sealed at the periphery; and a working current is guided to the electrode from the pinholes. The invention can increase the effective working area of the solar cell and lower the permeable corrosion possibility of electrolyte by obviating the protection of a metal gate electrode, thus greatly improving the safety factor of the solar cell and widening the selection range of sealing materials.
Description
Technical field
The present invention relates to a kind of device of opto-electronic conversion, particularly a kind of dye sensitization solar cell module.
Background technology
DSSC, simple in structure, with low cost and photoelectric conversion efficiency is higher receives publicity owing to it.The dye sensitization solar cell module of prior art generally comprises following major part: the electrolyte and the encapsulant of adsorbed first electrode that the nano porous semiconductor film of light-sensitive coloring agent and transparent conductive substrate form, filling with it between relative and isolated second electrode that contains Catalytic Layer, two electrodes.At least comprise a transparency electrode in two electrodes to guarantee the absorption of battery, use transparent conductive substrate to be electro-conductive glass or flexible transparent conducting film usually light.Electrolyte is generally and contains the right organic solution of iodine electricity.
Because semi-conductor electricity has the coarse factor greater than 1000 bigger serface porous membrane structure, can improve the absorption efficiency of dyestuff to light greatly.At present, the photoelectric conversion efficiency of such battery has reached more than 11%.Because in the production of DSSC, not necessarily need to use complicated, extensive manufacturing equipment, avoided the contour energy consumption process of high temperature or high vacuum simultaneously, according to estimates, the production cost of DSSC is that silicon is 1/10～1/5 of solar cell.DSSC becomes possibility as the solar cell of follow-on cheap large-scale production.
Employed transparent conductive substrate in the battery production, be generally the glass substrate or other flexible clear materials that have coated tin-doped indium oxide (ITO) or fluorine doped tin oxide nesa coatings such as (FTO), ITO or FTO layer can be prepared by sputtering method or CVD method.But the resistivity of ITO or FTO is 10
-4～10
-3About Ω cm, be about 100 times of metallic resistance rates such as silver, copper.Therefore, commercially available electrically conducting transparent substrate has higher resistance value, and when being used for DSSC, in the time of particularly large-area battery module, photoelectric conversion efficiency descends obviously.Can consider to reduce the resistance of electrically conducting transparent substrate by the thickness that improves transparency conducting layer (ITO or FTO etc.).But the increase of conductive layer thickness can cause its absorptivity to light to increase, and can reduce the photoelectric conversion efficiency of solar cell equally.
In order to address this problem, method commonly used at present is by metal or other high conductivity material are set as gate electrode in conductive substrates, and area battery is divided into several strip monocells by a large amount of metal gate electrodes, reduce the distance that electronics transmits in conducting film, improve the performance of battery.The metal gate electrode material therefor is generally metals such as silver, copper, nickel, and is prepared by printing or electric plating method.But, other one deck insulation screen must be set, on the surface of metal gate electrode to prevent the corrosion of electrolyte to gate electrode metal.Disclose the preparation method of the inside area battery in parallel of this kind structure as Chinese patent ZL200410014456.X, utilized macromolecular material, polymer binder or glass material or ceramic material to carry out the protection of gate electrode and the sealing of battery.The prominent question that this method is brought comprises several sections: at first, a large amount of gate electrodes that prepare on the transparent substrates and screen have stopped the incident of light, greatly reduce the light utilization efficiency of transparency electrode forms; Document (experimental study of large-area dye-sensitized solar cell, Weng Jian/Xiao Shangfeng/Chen Shuanhong/Dai Songyuan, Acta Physica Sinica; 2007,56 volumes, the 6th phase, 3602-3606) reported the 15 * 20cm battery module that uses said structure, its effective area is 187.2cm only
2, its forms aperture opening ratio only is 62.4%; Secondly, the coating that this screen must be fine and close fully with gate electrode metal, small flaw will make the corrosion of gate electrode generation permeability, causes the inefficacy of entire cell module, and the percent defective of battery is improved greatly; In addition, this method makes the complexity of the internal structure change of battery, is unfavorable for controlling the production cost of battery.
Chinese patent CN1755948A and CN1674303A also disclose similar structure, and the content of its patent disclosure is quoted at this.
Summary of the invention
The purpose of this invention is to provide a kind of dye sensitization solar cell module structure; dye sensitization solar cell module of the present invention has been avoided the preparation and the protection of gate electrode; thereby make battery module have bigger effective area, enlarged the range of choice of material simultaneously.
Another object of the present invention has provided a kind of large tracts of land parallel/series DSSC.
The following technical scheme of the concrete employing of the present invention:
A kind of dye sensitization solar cell module comprises first electrode, second electrode, and first electrode and the second electrode relative spacing are provided with, and the periphery sealing forms the cavity of sealing, is filled with electrolyte in described cavity; The described first electrode working region one side is provided with nano porous semiconductor film, and described nano porous semiconductor film is impregnated with light-sensitive coloring agent, and the described second electrode working region one side is provided with catalyst layer; Described first electrode and second electrode have at least one to be transparent; It is characterized in that, be provided with one or more apertures at least on an electrode, the periphery sealing of aperture will be drawn the operating current of electrode in described aperture.
The present invention can be provided with aperture on an electrode therein, and the electrode of perforate can be a transparency electrode, also can be opaque electrode.The substrate of transparency electrode generally is an electro-conductive glass, may reduce its mechanical and physical performance after considering the difficulty of perforate in the above and perforate, and therefore, the present invention preferably reserves aperture on opaque electrode, and concrete technical scheme is:
Described first electrode and second electrode have one to be opaque, only are provided with one or more apertures on opaque electrode.Described opaque electrode is corrosion resistant plate, titanium plate, nickel plate, carbon plate, nickel-clad steel plate, nickel plating iron plate, titanizing iron plate, titanizing steel plate, stainless steel-plastics compounded plate.
Should think like this, as long as possess simultaneously: the good conductor that 1) is electricity; 2) material that can tolerate electrolytical corrosion all can be used as opaque electrode.
Battery modular structure of the present invention also can be that two electrodes all are transparent, at this moment, when only on an electrode, reserving aperture, preferential technical scheme is: described first electrode and second electrode all are transparent, only an electrode is provided with one or more apertures therein, be provided with the conducting film isolated island in each aperture, the conducting film isolated island connects with apertured electrodes is electric, draws operating current respectively on aperture inner conductive film isolated island and back electrode.
The conducting film isolated island be set be that to draw operating current convenient in order to make, (for example: the size of aperture is enough big in some cases, can draw operating current easily), the present invention also can be provided with like this: described first electrode and second electrode all are transparent, only an electrode is provided with one or more apertures therein, aperture is in when sealing, and apertured electrodes reserves enough areas and is used for projected current, and another utmost point of battery is drawn operating current in aperture.
The present invention also can be provided with aperture at two electrodes, and concrete technical scheme is:
All be provided with aperture on two electrodes, the aperture position on two electrodes staggers; Preferred scheme is: all be provided with aperture on two electrodes, the aperture on two electrodes is tangent, and the cross section of periphery sealing is a slotted hole.The advantage of this scheme is: the effective area of waste is minimum, and sealing is convenient.
Should think like this, as long as can in aperture, will draw easily on the position setting principle of aperture to the operating current of electrode.
Consider the factors such as area of battery module, described battery module can be provided with 1 (or 1 pair) aperture, and preferred scheme is that a plurality of apertures are set, its arrangement mode be rule or its arrangement mode be irregular.
The transparency electrode of described solar module adopts electro-conductive glass or is covered with the conducting film of layer of transparent on the surface of transparent plastic substrate; The general material of described conducting film is tin-doped indium oxide (ITO), fluorine doped tin oxide (FTO), ZnO-Ga
2O
3, ZnO-Al
2O
3Perhaps SnO
2-Sb
2O
3Deng, described conducting film can be prepared by sputtering method, CVD method or other technologies.
The material of described nano porous semiconductor film is the metal oxide of Ti, Nb, Zn, Sn, Ta, W, Ni, Fe, Cr, V, Pm, Zr, Sr, In, Ir, La, Mo, Mg, Al, Y, Sc, Sm, Ga or its mixture.Film thickness can be between 0.1 micron to 1 millimeter, and its preparation method is identical with prior art;
Described catalyst layer material be Pt, Ru, Pd, Rh, Ir, Os, WO
3, TiO
2, graphite or their mixture, its preparation method is identical with prior art;
Described electrolyte solution is a kind of in liquid electrolyte, ionic liquid electrolyte, based solid electrolyte, polymer dielectric, the solid electrolyte;
Described sealing is the encapsulant that adopt to be fit to and selects for use suitable encapsulating method to carry out, and thermoplastic polymer film for example is as Surlyn.Thermoplastic polymer film is arranged between two substrates, and by the mode of vacuum hotpressing first and second electrodes is sealed.Also can use other high polymer binder, for example silicon rubber, polyurethane rubber, UV solidify glue, or glass material or ceramic material sealing.
Battery module of the present invention can adopt the series connection of following technical scheme or and be unified into area battery, specifically:
A kind of large tracts of land series/parallel DSSC comprises first substrate, it is characterized in that, first substrate is whole plank frame, and a plurality of element cells zone is set on first substrate; First substrate as first electrode of element cell or second electrode be oppositely arranged on the element cell zone electrode is formed aforesaid element cell module, element cell module electric connecting mode each other is a serial or parallel connection; Described first substrate and element cell zone have at least one to be transparent to electrode.
Described first substrate and element cell zone have one to be opaque to electrode, the material of opaque section is a kind of in corrosion resistant plate, titanium plate, nickel plate, carbon plate, nickel-clad steel plate, nickel plating iron plate, titanizing iron plate, titanizing steel plate, the stainless steel-plastics compounded plate.Perhaps
Described first substrate and element cell zone all be transparent to electrode.
Conducting film between the element cell of the present invention disconnects by laser ablation, chemical corrosion or other prior art and being electrically connected.
Method for making of the present invention specifically comprises the steps:
1) on transparent conductive substrate or corrosion resistant metal substrate, according to the size that designs, carry out the preparation of preformed hole by commentaries on classics, mill, punching press, laser ablation or additive method after, electrode base board is rinsed well;
2) on first electrode base board, prepare nanometer or semiconductor porous film material and sintering by silk screen printing or spraying or sputter or other film plating process, make in nanometer or the semiconductor porous film evenly absorbing dye by dipping;
3) on second electrode base board, prepare Catalytic Layer by silk screen printing or spraying or sputter or other film plating process;
4) around preformed hole and the peripheral position of electrode, by printing or spraying or push or additive method evenly places desired location to encapsulant, two electrode base boards are closed and seal;
5) electrolyte is injected by vacuum or manual method, and the sealing hand-hole;
6) with lead or other electric conducting materials, through the electrode preformed hole, be connected on the electric current leading point of another electrode by bonding or welding or additive method, electric current is drawn.
Be another electrode relative to electrode described in the present invention with apertured electrodes.
Compared with prior art, the invention has the advantages that:
1) the present invention can increase the effective work of battery area greatly, and according to the preparation precision, the aperture opening ratio of its forms is 85%～95%;
2) DSSC of the present invention is made simply, has avoided using and protecting of metal gate electrode, has reduced the possibility of electrolyte osmosis corrosion, and the coefficient of safety of battery is improved greatly;
3) the present invention has enlarged the range of choice of encapsulant.
Description of drawings
Fig. 1 is the front view of embodiment 1;
Fig. 2 is that the A of Fig. 1 is to the cross-section structure enlarged diagram;
Fig. 3 is the cross-sectional view of embodiment 2;
Fig. 4 is the cross-sectional view of embodiment 3;
Fig. 5 is the perspective view of embodiment 4;
Fig. 6 is the cross-sectional view of embodiment 4;
Fig. 7 is the structural representation of embodiment 5;
Fig. 8 is the rearview of embodiment 6;
Fig. 9 is the front view of embodiment 7;
Figure 10 is the rearview of embodiment 7;
Figure 11 is the rearview of embodiment 8.
Embodiment
Embodiment 1
As shown in Figure 1, 2, a kind of dye sensitization solar cell module, comprise: first electrode, second electrode, first electrode comprises opaque substrate 11, working region one side of opaque substrate 11 is provided with catalyst layer 16, and the material of opaque substrate 11 is for being that corrosion resistant plate, titanium plate, nickel plate, carbon plate, nickel-clad steel plate, nickel plating iron plate, titanizing iron plate, titanizing steel plate, stainless steel-plastics compounded plate are a kind of; Second electrode comprises transparent substrate 12, is covered with conducting film 15 on the transparent substrate 12, and its working region one side is provided with nano porous semiconductor film 17, and nano porous semiconductor film 17 is impregnated with light-sensitive coloring agent, and the material of transparent substrate 12 is glass or transparent plastic.
First electrode and the second electrode relative spacing are provided with, and the periphery sealing forms the cavity 18 of sealing, is filled with electrolyte in cavity 18.
Be provided with aperture 13 at opaque substrate 11; Aperture 13 peripheries are drawn the operating current on second electrode in aperture with encapsulant 14 sealings by electric current leading point 19.
Embodiment 2
As shown in Figure 3, battery module and embodiment 1 structure are basic identical, and just first electrode and second electrode all are transparent, and the material of the substrate 23 of first electrode is transparent plastic or glass, aperture 13 is set on first electrode, and aperture 13 peripheries seal with encapsulant 14; Adopt the disconnected conducting film isolated island 21 that forms of prior art 15 etchings of the conducting film on the substrate 12 in aperture, adopt electric conducting material 22 that conducting film isolated island 21 is connected with conducting film 15 on first electrode base sheet 11; Draw the operating current of two electrodes respectively from aperture inner conductive film isolated island 21, the second electrode current leading point 19.
Embodiment 3
As shown in Figure 4, battery module and embodiment 1 structure are basic identical, and just first electrode and second electrode all are transparent, and the material of the substrate 23 of first electrode is transparent plastic or glass, aperture 13 is set on first electrode, and aperture 13 peripheries seal with encapsulant 14; The operating current of first electrode utilizes conductor material 41 directly electric current to be drawn by aperture 13; Operating current on second electrode is drawn by electric current leading point 19.
Embodiment 4
Shown in Fig. 5,6, battery module and embodiment 1 structure are basic identical, just all are provided with a plurality of apertures on first and second electrodes, and the aperture on two electrodes is tangent, and the cross section of periphery sealing 14 is a slotted hole;
As shown in Figure 6, at first electrode aperture 13 is set, aperture 33 is set on second electrode, aperture 13 and 33 is tangent, and second electrode from aperture 13, first electrode in the aperture 33 are drawn operating current.
Embodiment 5
As shown in Figure 7, battery modular structure is substantially the same manner as Example 4, is being staggeredly located of aperture 13 and 33.
Embodiment 6
As shown in Figure 8, a kind of large tracts of land DSSC in parallel, comprise first substrate 51, a plurality of element cells zone 54 is set on first substrate 51, first substrate 51 is as the transparency electrode of each element cell, each element cell zone 54 to one or more aperture 53 is set on the electrode 52, are a kind of in corrosion resistant plate, titanium plate, nickel plate, nickel-clad steel plate, nickel plating iron plate, titanizing iron plate, titanizing steel plate, the stainless steel-plastics compounded plate to electrode 52.Electric connecting mode between the element cell 54 is in parallel.
The cross-section structure of element cell 54 is as among the embodiment 1 to 3 as described in any.
Embodiment 7
Shown in Fig. 9,10, a kind of large tracts of land DSSC in parallel, comprise first substrate 62, a plurality of element cells zone 64 is set on first substrate 62, described second substrate 62 is opaque, and material is to be a kind of in corrosion resistant plate, titanium plate, nickel plate, nickel-clad steel plate, nickel plating iron plate, titanizing iron plate, titanizing steel plate, the stainless steel-plastics compounded plate.All there is pair electrode 61 in each element cell zone 64, with first substrate 62 relative to electrode 61 on one or more aperture 63 is set, in aperture 63, the operating current of second electrode 61 is drawn.Electric connecting mode between the element cell 64 is in parallel.
The cross-section structure of element cell 64 is as among the embodiment 1 to 3 as described in any.
Embodiment 8
As shown in figure 11, structure is substantially the same manner as Example 6, just present embodiment is that the mode of connecting connects, conducting film around the element cell on first electrode 71 74 is electrically connected by the prior art disconnection, a plurality of apertures 73 are set on second electrode 72, the electric current that first electrode 71 in each aperture 73 is drawn gathers the back by lead 75 and connects with second electrode 72 ' of adjacent-cell battery.
The cross-section structure of element cell 74 is as among the embodiment 1 to 3 as described in any.
The unit cell structure of large tracts of land series/parallel battery of the present invention also can be the structure of two sides perforate.
The above embodiments of the present invention are can not limit the present invention to explanation of the present invention, in implication suitable with claims of the present invention and any change and the combination in the scope, all should think in the scope of claims.
Claims (10)
1. a dye sensitization solar cell module comprises first electrode, second electrode, and first electrode and the second electrode relative spacing are provided with, and the periphery sealing forms the cavity of sealing, is filled with electrolyte in described cavity; The first electrode working region, one side is provided with nano porous semiconductor film, and described nano porous semiconductor film is impregnated with light-sensitive coloring agent, and the second electrode working region, one side is provided with catalyst layer; Described first electrode and second electrode have at least one to be transparent; It is characterized in that, be provided with one or more apertures at least on an electrode, the periphery sealing of aperture is drawn operating current to electrode in aperture.
2. dye sensitization solar cell module according to claim 1 is characterized in that, has one to be opaque in described first electrode and second electrode, only is provided with one or more apertures on opaque electrode.
3. dye sensitization solar cell module according to claim 2, it is characterized in that described opaque electrode is a kind of in corrosion resistant plate, titanium plate, nickel plate, carbon plate, nickel-clad steel plate, nickel plating iron plate, titanizing iron plate, titanizing steel plate, the stainless steel-plastics compounded plate.
4. dye sensitization solar cell module according to claim 1 is characterized in that, all is provided with aperture on two electrodes, and the aperture position on two electrodes staggers mutually.
5. dye sensitization solar cell module according to claim 4 is characterized in that, all is provided with aperture on two electrodes, and the aperture on two electrodes is tangent, and the cross section of periphery sealing is a slotted hole.
6. dye sensitization solar cell module according to claim 1, it is characterized in that, described first electrode and second electrode all are transparent, only an electrode is provided with one or more apertures therein, in the aperture electrode is provided with the conducting film isolated island, the conducting film isolated island connects with apertured electrodes is electric, from aperture inner conductive film isolated island and to drawing operating current on the electrode respectively.
7. dye sensitization solar cell module according to claim 1, it is characterized in that, described first electrode and second electrode all are transparent, and only an electrode is provided with one or more apertures therein, draw with apertured electrodes with to the electric current of electrode in aperture.
8. a large tracts of land series/parallel DSSC comprises first substrate, it is characterized in that, first substrate is whole plank frame, and a plurality of element cells zone is set on first substrate; First substrate as first electrode of element cell or second electrode be oppositely arranged on the element cell zone electrode is formed element cell module as claimed in claim 1, element cell module electric connecting mode each other is a serial or parallel connection; Described first substrate and element cell zone have at least one to be transparent to electrode.
9. large tracts of land series/parallel DSSC according to claim 8, it is characterized in that, first substrate and element cell zone have one to be opaque to electrode, the material of opaque section is a kind of in corrosion resistant plate, titanium plate, nickel plate, carbon plate, nickel-clad steel plate, nickel plating iron plate, titanizing iron plate, titanizing steel plate, the stainless steel-plastics compounded plate.
10. large tracts of land series/parallel DSSC according to claim 8 is characterized in that, described first substrate and element cell zone all be transparent to electrode.
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| CN 200810010368 CN101232052A (en) | 2008-02-01 | 2008-02-01 | Dye sensitization solar cell module |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101894674A (en) * | 2010-05-28 | 2010-11-24 | 广东工业大学 | Composite light anode for dye-sensitized solar cell and preparation method thereof |
| CN101950692A (en) * | 2010-09-28 | 2011-01-19 | 彩虹集团公司 | Packaging material and packaging method for dye sensitized solar cell |
| CN101950693A (en) * | 2010-09-30 | 2011-01-19 | 彩虹集团公司 | Dye sensitized solar cell module |
| CN101976611A (en) * | 2010-08-25 | 2011-02-16 | 广东工业大学 | TiO2 nanowire array film light anode and preparation method thereof |
| CN101877282B (en) * | 2009-04-30 | 2012-12-12 | 中国科学院物理研究所 | Dye-sensitized solar cell module and preparation method thereof |
| CN105304331A (en) * | 2014-06-10 | 2016-02-03 | 现代自动车株式会社 | Series/parallel mixed module structure of dye-sensitized solar cell and method of manufacturing the same |
| CN105699436A (en) * | 2016-01-13 | 2016-06-22 | 钟林超 | Exhaust gas detection device based on solar cell high in conversion rate |
| CN110073508A (en) * | 2016-12-07 | 2019-07-30 | 株式会社理光 | Photo-electric conversion element |
| CN110246707A (en) * | 2018-03-06 | 2019-09-17 | 台湾染敏光电股份有限公司 | Encapsulation equipment for dye sensitization solar battery and method |
| CN111883658A (en) * | 2020-07-31 | 2020-11-03 | 中国科学院合肥物质科学研究院 | Perovskite solar cell module and preparation method thereof |
| CN115207147A (en) * | 2021-04-09 | 2022-10-18 | 凌巨科技股份有限公司 | Solar cell module and solar cell display device |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101877282B (en) * | 2009-04-30 | 2012-12-12 | 中国科学院物理研究所 | Dye-sensitized solar cell module and preparation method thereof |
| CN101894674A (en) * | 2010-05-28 | 2010-11-24 | 广东工业大学 | Composite light anode for dye-sensitized solar cell and preparation method thereof |
| CN101894674B (en) * | 2010-05-28 | 2012-11-07 | 广东工业大学 | Composite light anode for dye-sensitized solar cell and preparation method thereof |
| CN101976611A (en) * | 2010-08-25 | 2011-02-16 | 广东工业大学 | TiO2 nanowire array film light anode and preparation method thereof |
| CN101976611B (en) * | 2010-08-25 | 2012-05-23 | 广东工业大学 | TiO2 nanowire array film light anode and preparation method thereof |
| CN101950692A (en) * | 2010-09-28 | 2011-01-19 | 彩虹集团公司 | Packaging material and packaging method for dye sensitized solar cell |
| CN101950693A (en) * | 2010-09-30 | 2011-01-19 | 彩虹集团公司 | Dye sensitized solar cell module |
| CN105304331A (en) * | 2014-06-10 | 2016-02-03 | 现代自动车株式会社 | Series/parallel mixed module structure of dye-sensitized solar cell and method of manufacturing the same |
| CN105699436A (en) * | 2016-01-13 | 2016-06-22 | 钟林超 | Exhaust gas detection device based on solar cell high in conversion rate |
| CN110073508A (en) * | 2016-12-07 | 2019-07-30 | 株式会社理光 | Photo-electric conversion element |
| US11756743B2 (en) | 2016-12-07 | 2023-09-12 | Ricoh Company, Ltd. | Photoelectric conversion element |
| CN110073508B (en) * | 2016-12-07 | 2023-12-26 | 株式会社理光 | Photoelectric conversion element |
| CN110246707A (en) * | 2018-03-06 | 2019-09-17 | 台湾染敏光电股份有限公司 | Encapsulation equipment for dye sensitization solar battery and method |
| CN111883658A (en) * | 2020-07-31 | 2020-11-03 | 中国科学院合肥物质科学研究院 | Perovskite solar cell module and preparation method thereof |
| CN111883658B (en) * | 2020-07-31 | 2023-10-20 | 中国科学院合肥物质科学研究院 | Perovskite solar cell module and preparation method thereof |
| CN115207147A (en) * | 2021-04-09 | 2022-10-18 | 凌巨科技股份有限公司 | Solar cell module and solar cell display device |
| CN115207147B (en) * | 2021-04-09 | 2023-05-02 | 凌巨科技股份有限公司 | Solar cell module and solar cell display device |
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