CN101224175A - Permanent Chinese traditional medicine color oil for hair treatment - Google Patents
Permanent Chinese traditional medicine color oil for hair treatment Download PDFInfo
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- CN101224175A CN101224175A CNA2007100364845A CN200710036484A CN101224175A CN 101224175 A CN101224175 A CN 101224175A CN A2007100364845 A CNA2007100364845 A CN A2007100364845A CN 200710036484 A CN200710036484 A CN 200710036484A CN 101224175 A CN101224175 A CN 101224175A
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Abstract
The invention provides a combination for dyeing the hair, including: a first component, the first component includes: 1.2 to 6.8 parts by weight of hair dye component, the hair dye component includes oleum rhododendri daurici, Indigo naturalis or the composition thereof; 5.0 to 6.0 parts by weight of hair leavening agent component; a second component, the second component includes 7.0 to 12.0 parts by weight of oxidant component, and the total weight of the hair dye component, the hair leavening agent component and the oxidant component accounts for 36 to 100 percent by weight of the total weight of the solid content of the composition. The invention further provides the preparation method of the composition. The hair dye component of the invention does not contain p-phenylenediamine and resorcinol, at the same time, the invention has good dyeing performance and dyeing fastness.
Description
Technical field
The present invention relates to a kind of dyeing product, relate to permanent type Chinese herbal medicine color oil for hair treatment particularly.
Background technology
Hair dyeing product is meant to have the cosmetics that change the hair color effect, and this series products mainly is divided into three types (permanent, semipermanent and temporary hair dye) at present.
1, permanent (also claiming oxidized form) hair dye
At present commercially available hair dyeing product mostly is this kind of, be characterized in painted distinctness, anchorage more by force, fugitive color not.To dye the product of hair color, mainly adopt oxidized form dyestuff (based on phenyl amines) in China, dyestuff is bonded on the hair by redox reaction, thus the color of change hair.But, use dyeing to cause that case hypersensitive happens occasionally because aniline dyes has certain toxicity and sensitization.And the degree of untoward reaction is answered the people and different, having gently has heavily, show as very to itch in the part, twinge and with face red spot, edema, pimple, vesicle, severe patient big kitchen can occur, oozes out, erosion, even women's head-ornaments portion large tracts of land edema and even general untoward reaction.Do not substitute and still have safer material at present, therefore still widely-used (seeing also of the description of " safety issue of caused by cosmetics for special use " literary composition) " p-phenylenediamine (PPD) ".For above-mentioned reasons, country's " hygienic standards for cosmetics " has not only stipulated the limit the use of amount of raw material in prescription such as " p-phenylenediamine (PPD) ", and also the regulation dyeing product must reach nontoxic grade standard.
In addition, external document has also been reported the hazardness of p-phenylenediamine (PPD).In US patent 5,599,353 and 5,538,516 have described for toxicologic reason, and the continuous use of p-phenylenediamine (PPD) falls under suspicion, and mainly are because its intensive sensitization potentiality.GB patent disclosure publication GB2,239, some individualities (anaphylaxis crowd) have been described to a phenylenediamine and derivant allergy thereof among the 265A.
2, semi-permanent hairdye
This product mainly with vegetable dyes and mineral dyestuff be raw material (as Flos Impatientis, Galla Chinensis, Flos Carthami, Radix Rubiae, lead acetate, mantoquita, iron salt etc.), by contrast this type of hair dye than permanent type hair dye be difficult for causing human allergy, stimulation degree also a little less than, but the anchorage of its hair dyeing is poor, not only continuous several times could be painted after using, also need frequent use, and color and luster is relatively poor, matt, variable color easily.Use the hair dye of lead acetate, because lead acetate also has bigger toxicity, therefore the use lead acetate has been stipulated to limit the quantity of in country's " hygienic standards for cosmetics ", limiting the quantity of is 1% (in lead).
3, temporary (also claiming direct type) hair dye
This product is a raw material with direct dyestuff mainly, adopts spray or the method that is coated with is painted hair surface, compare permanent and more difficult the generations allergy of semi-permanent hairdye, stimulation degree very weak.But because of its colouring just is attached to hair by stick in the surface, so persistency is poor, color and luster is also matt, dull, can only cover a spot of tip poliosis.Particularly color not only can be taken off on a small quantity along with combing hair, becomes easily infected by medicated clothing, pillow covering towel etc., and color can take off along with the washing of shampoo, promptly wash once send out just once handy, but its frequent color of conversion hair.
The commercially available mainstream product of permanent type hair dye has at present: U.S.A of a specified duration of U.S. source of the L'Oreal of France, the Revlon of the U.S., Japan, the Wella of Germany and this country is a treasured etc.These hair dyeing products all belong to the permanent type oxidation hair-dye, although must meeting China's " hygienic standards for cosmetics ", product reaches nontoxic level, and by the health ministry requirement, the operation instructions of hair dyeing product must indicate " this product contains p-phenylenediamine (PPD), must do hypersensitive test before using " printed words.But, inevitably take place because of the irritated case of using this series products to cause owing to all contain general in the world raw material " p-phenylenediamine (PPD) " in the prescription.
Except the said goods, the patent (02136428.1) of Chinese Shanghai university of communications 2002.02 applications flies fine horse board Chinese medicine rinse " is the non-oxide permanent Chinese medicine rinse of penetrating agent with the Flos Caryophylli " and comes out, more than 4 years, this product has solved the needs that irritated crowd's poliosis dyes hair color, but it has the feature of temporary hair dye:
The product that before the hair dyeing with the Flos Caryophylli is penetrating agent is applied on the hair, heats one hour with hot top;
Then the Chinese herbal medicine hair-dyeing hair-blackening liquor being applied on the hair reuse hot top heats and kept 2 hours;
Must acid special-purpose shampoo be cleaned by hair.
Be not difficult to find out, above process add the comb dye need four～five hours around time, and after 10～15 days fugitive color (it is faster particularly to use neutral shampoo to fade); In addition, because complex operation typically has to go to the baked dyeing hair of the Qu of specialty store, the price comparison costliness.
Chinese medicine beautifying is an important component part of Chinese medicine, and it also is the task of top priority that the science and technology of Chinese medicine further is applied.
The source of Oleum Rhododendri Daurici is the volatile oil that the leaf of ericad Folium Cuculus polioephalus Rhododendron dauricum L. obtains through steam distillation.Usually as the acute and chronic bronchitis of oral medication.The source of Indigo Naturalis is the leaf of cruciferae isatis Isatis indigotica Fort. or dried powder or the agglomerate that stem and leaf makes through processing.Its immersion is external inhibited to anthrax bacillus, pneumobacillus etc.But do not find the report of above-mentioned raw material of Chinese medicine at present as the hair dye component.
Therefore, how to seek the important topic that the succedaneum of " p-phenylenediamine (PPD) " and the problem of Color preferably of reaching become those skilled in the art's research.
Summary of the invention
The objective of the invention is to obtain a kind of p-phenylenediamine (PPD) and resorcinol of not containing, have the good dyeability and the hair dye of dyefastness simultaneously.
Another object of the present invention is to obtain the permanent type Chinese herbal medicine color oil for hair treatment that a kind of compositions of the present invention makes.
A further object of the invention is to obtain a kind of preparation method of permanent type Chinese herbal medicine color oil for hair treatment of the present invention.
A further object of the invention is to obtain the method for a kind of bleaching and dyeing human or animal hair, uses first component of the present invention and second component simultaneously to hair, and described first component and second component retention time on hair is 30～60 minutes.
The present invention has a purpose to be to obtain a kind of Oleum Rhododendri Daurici or the purposes of Indigo Naturalis in addition, and it is used to prepare the permanent type hair dyeing product.
In a first aspect of the present invention, a kind of compositions that is used to have hair dyed is provided, it comprises:
First component, described first component comprises: stain component 1.2～6.8 weight portions, described stain component comprises Oleum Rhododendri Daurici, Indigo Naturalis or its combination; Hair bulking agent component 5.0～6.0 weight portions;
Second component, described second component comprises oxidant constituents 7.0～12.0 weight portions,
The gross weight of described stain component, hair bulking agent component, oxidant constituents accounts for 36～100 weight % of compositions solid content gross weight.
Preferably, the weight ratio of described first component and second component is 0.5: 1～1.5: 1.More preferably, the weight ratio of described first component and second component is 0.8: 1～1.2: 1.
In a preferred embodiment of the present invention, described stain component is selected from the combination of Oleum Rhododendri Daurici and Indigo Naturalis, and the weight ratio of described Oleum Rhododendri Daurici and Indigo Naturalis is between 2: 1～4.2: 1; Or
Described hair bulking agent component is selected from ammonium hydroxide; Or
Described oxidant constituents is selected from hydrogen peroxide.
In a preferred embodiment of the present invention, described first component also comprises:
Antiallergic component 0.3～2 weight portion, described antiallergic component Xuan Zi Herba Siegesbeckiae, the Fructus Kochiae, Folium Hibisci Mutabilis or its combination, and/or
Dyeing auxiliaries component 0.2～0.8 weight portion, described dyeing auxiliaries component is selected from Oleum Cinnamomi, tallowseed oil, Folium Ginkgo or its combination.
Preferably, the mixture of described antiallergic component Xuan Zi Herba Siegesbeckiae, the Fructus Kochiae, Folium Hibisci Mutabilis, the weight ratio of each component is in (0.3～0.6) in the described mixture: (0.3～0.6): between (0.4～0.8).
Preferably, described dyeing auxiliaries component is selected from the mixture of tallowseed oil and Folium Ginkgo, and the weight ratio of each component is in (0.3～0.5) in the described mixture: between (0.2～0.3).
In a preferred embodiment of the present invention, described first component also comprises: first diluent, first stabilizing agent, first thickening agent, first surface activating agent, first emulsifying agent or its combination.
Preferably, described first thinner composition is selected from water, 2-propanol, 1,2-dihydroxypropane or its combination.
Preferably, described first stabilizing agent is selected from disodiumedetate, ascorbic acid or its combination.
Preferably, described first thickening agent is selected from cis 9-octadecenoic acid, C
16～18Alcohol, white oil or its combination.
Preferably, described first surface activating agent is selected from sodium lauryl sulphate.
Preferably, described first emulsifying agent is selected from glyceryl monostearate.
In a preferred embodiment of the present invention, described second component also comprises: second diluent, second stabilizing agent, second thickening agent, second surface activating agent, second emulsifying agent or its combination.
Preferably, described second diluent is selected from water.
Preferably, described second stabilizing agent is selected from tetrasodium phosphate.
Preferably, described second thickening agent is selected from dimethicone, C
16～18Alcohol, white oil or its combination.
Preferably, described second surface activating agent is selected from sodium lauryl sulphate.
Preferably, described second emulsifying agent is selected from glyceryl monostearate.
The permanent type Chinese herbal medicine color oil for hair treatment that the present invention provides a kind of compositions of the present invention to make on the other hand.
Further aspect of the present invention provides a kind of preparation method of permanent type Chinese herbal medicine color oil for hair treatment of the present invention, and it may further comprise the steps:
(i) provide the mixture of first component and second component separately,
Wherein said first component comprises: stain component 1.2～6.8 weight portions, and described stain component is selected from Oleum Rhododendri Daurici, Indigo Naturalis or its combination; Hair bulking agent component 5.0～6.0 weight portions;
Described second component comprises oxidant constituents 7.0～12.0 weight portions,
The gross weight of described stain component, hair bulking agent component, oxidant constituents accounts for 36～100 weight % of compositions solid content gross weight;
(ii) first component mixture that step (i) is obtained and second component mixture carry out independent packaging separately, obtain described permanent type Chinese herbal medicine color oil for hair treatment.
In a preferred embodiment of the present invention, first component described in the step (i) is mixed under 90 ℃～95 ℃ temperature and is obtained described first component mixture; Or
Described second component is mixed under 90 ℃～95 ℃ temperature and is obtained described second component mixture.
A further aspect of the invention provides the method for a kind of bleaching and dyeing human or animal hair, uses first component of the present invention and second component simultaneously to hair, and described first component and second component retention time on hair is 30～60 minutes.
The present invention has an aspect that a kind of Oleum Rhododendri Daurici or the purposes of Indigo Naturalis are provided in addition, and it is used to prepare the permanent type hair dyeing product.
The specific embodiment
The inventor is through extensive and deep research, by improving preparation technology, select for use the synthetic additive of multi-flavor herbaceous plant (Chinese herbal medicine) compound recipe to replace " p-phenylenediamine (PPD) ", " resorcinol " application in prescription, combine the advantage of permanent type hair dye, semi-permanent hairdye and temporary pattern hair dye, make in use safe, effective, the easy to use possibility that becomes of hair dyeing product.
Term of the present invention " hair " can be grown on the live body, or from non-living body material (for example wig sheath, wig).Hair of the present invention can be from mammal, preferably from the mankind's hair.
Term of the present invention " solid content " is meant that described content does not comprise thinner composition.For example, the implication of compositions solid content gross weight is the weight summation of the component beyond the compositions thinner composition.
Below describe in detail to various aspects of the present invention:
First component
The stain component
Stain component of the present invention is selected from Oleum Rhododendri Daurici, Indigo Naturalis or its combination.Preferably, described stain component is selected from Oleum Rhododendri Daurici and Indigo Naturalis mixture.
Stain components contents of the present invention preferably is 1.2～6.8 weight portions.In preferred implementation of the present invention, when being converted into percentage by weight, 8～18 weight % of the stain ingredients constitute first component solid content gross weight (not comprising diluent) of the present invention.Preferably described stain component is selected from Oleum Rhododendri Daurici and Indigo Naturalis mixture, and then its weight ratio is preferably between 2: 1～4.2: 1.For example, Oleum Rhododendri Daurici is 3.6～5.0 weight portions, and Indigo Naturalis is 1.2～1.8 weight portions.
Preferably, stain of the present invention adopts diluent to dilute fully mixing of back before use.
Stain component of the present invention does not contain p-phenylenediamine (PPD) and resorcinol, has good dyeability and dyefastness simultaneously.Therefore the toxicity that exists in the prior art and the contradiction between the dyeability have been solved.
Hair bulking agent component
Hair bulking agent component of the present invention is used to make the hair fiber swelling and helps stain and oxidant to penetrate into hair.
Hair bulking agent component of the present invention is not particularly limited, only otherwise purpose of the present invention is produced restriction or the health that influences human body gets final product.For example, specifically be to be selected from ammonium hydroxide.
Hair bulking agent components contents of the present invention preferably is (this moment, stain preferably was 1.2～6.8 weight portions) between 5.0～6.0 weight portions.In preferred implementation of the present invention, when being converted into percentage by weight, 9～16 weight % of hair bulking agent ingredients constitute first composition weight of the present invention (not comprising diluent).
The antiallergic component
Can add the antiallergic composition among the present invention.Described antiallergic component is Xuan Zi Herba Siegesbeckiae, the Fructus Kochiae, Folium Hibisci Mutabilis or its combination preferably.
Preferably, the mixture of described antiallergic component Xuan Zi Herba Siegesbeckiae, the Fructus Kochiae, Folium Hibisci Mutabilis.
The content of antiallergic composition of the present invention is (this moment, stain preferably was 1.2～6.8 weight portions) between 0.3～2 weight portion.In preferred implementation of the present invention, when being converted into percentage by weight, 0.5～5.3 weight % of antiallergic ingredients constitute first composition weight of the present invention (not comprising diluent).For example ， Herba Siegesbeckiae 0.3～0.6 weight portion, the Fructus Kochiae 0.3～0.6 weight portion, Folium Hibisci Mutabilis 0.4～0.8 weight portion or its combination.
Preferably, the mixture of described antiallergic component Xuan Zi Herba Siegesbeckiae, the Fructus Kochiae, Folium Hibisci Mutabilis, and in the described mixture weight ratio of each component in (0.3～0.6): (0.3～0.6): between (0.4～0.8).
The dyeing auxiliaries component
In the stain of the present invention, can add dyeing auxiliaries.Described dyeing auxiliaries can be natural dyeing auxiliaries or synthetic dyeing auxiliaries.Can decide and select natural, synthetic dyeing auxiliaries or the two combination for use on the body constitution of tinter.
Preferably, described natural dyeing auxiliaries component preferably is selected from Oleum Cinnamomi, tallowseed oil, Folium Ginkgo or its combination.More preferably be that described natural dyeing auxiliaries component is selected from the mixture of tallowseed oil and Folium Ginkgo.
Described synthetic dyeing auxiliaries preferably is selected from the p-methylaminophenol hydrochlorate.
The content of dyeing auxiliaries composition of the present invention is between 0.1～1.3 weight portion (this moment, stain preferably was 1.2～6.8 weight portions) preferably.In preferred implementation of the present invention, when being converted into percentage by weight, 0.1～3.5 weight % of dyeing auxiliaries ingredients constitute first composition weight of the present invention (not comprising diluent).For example contain tallowseed oil (or Oleum Cinnamomi) 0.3～0.5 weight portion, Folium Ginkgo 0.2～0.3 weight portion, p-methylaminophenol hydrochlorate 0.1～0.5 weight portion or its combination specifically.
When described dyeing auxiliaries was selected from the mixture of tallowseed oil and Folium Ginkgo, the weight ratio of each component was 0.3～0.5 in the described mixture: between 0.2～0.3.
Dyeing auxiliaries composition of the present invention makes the dyefastness of stain component increase greatly.It can guarantee that stain of the present invention is keeping more than one month after the colouring.
First thinner composition
The kind of diluent of the present invention is not particularly limited, as long as make various components fully disperse.Generally be selected from the material miscible and harmless to skin with water.Comprise the monohydric alcohol of water, C1～C20 or polyhydric alcohol and their ether (for example glycerol and with the ether of monohydric alcohol and dihydroxylic alcohols), for example water, ethanol, 2-propanol, normal propyl alcohol, butanols, propylene glycol, 1 particularly, 2-dihydroxypropane, ethylene glycol monoethyl ether or its mixture.Can select according to the dissolubility of component particularly.
Preferably, the thinner composition of described first component is selected from water, 2-propanol, 1,2-dihydroxypropane or its combination.For example, Indigo Naturalis, Oleum Rhododendri Daurici be at 2-propanol, 1, and 2-dihydroxypropane or its combination exist down, 2-propanol, 1 preferably, and 2-dihydroxypropane mixed solvent is to dilute; Herba Siegesbeckiae, the Fructus Kochiae, Folium Ginkgo, Folium Hibisci Mutabilis water in the presence of surfactant dilutes.
The content of thinner composition is not particularly limited, only otherwise purpose of the present invention is produced restriction to get final product.Comprise 1 of the 2-propanol of the water of 40～60 weight portions, 4.0～6.0 weight portions, 4.0～6.0 weight portions, 2-dihydroxypropane or its combination.For example specifically, the Oleum Rhododendri Daurici of 3.6～5.0 weight portions adopts the water of 40～60 weight portions; Or the mixture of Indigo Naturalis 1.2～1.8 weight portion, Herba Siegesbeckiaes 0.3～0.6 weight portion, the Fructus Kochiae 0.3～0.6 weight portion, Folium Hibisci Mutabilis 0.4～0.8 weight portion is with 1 of the 2-propanol of 4.0～6.0 weight portions, 4.0～6.0 weight portions, and 2-dihydroxypropane mixed solvent is as diluent.
First stabilizing agent
Stabilizing agent of the present invention is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.
Preferably, the stabilizing agent in described first component is selected from disodiumedetate, ascorbic acid or its combination.
The content of stabilizer component of the present invention is between 0.2～0.8 weight portion (this moment, stain preferably was 1.2～6.8 weight portions) preferably.In preferred implementation of the present invention, when being converted into percentage by weight, stabilizer component of the present invention accounts for 0.3～2.2 weight % of first composition weight (not comprising diluent).
First thickening agent
Thickening agent of the present invention is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.For example, thickening agent of the present invention is selected from cis 9-octadecenoic acid, dimethicone, white oil, oleic acid, spermol, oleyl alcohol, sodium chloride, spermaceti/stearyl alcohol, stearyl alcohol, sodium alginate, arabic gum, cellulose derivative (for example sodium salt of methylcellulose or carboxymethyl cellulose or acrylate copolymer) and other various animal oil and vegetable oil.
Preferably, the thickening agent in described first component is selected from cis 9-octadecenoic acid, C
16～C18Alcohol (is also referred to as C
16～C8Oleyl alcohol) or the white oil compositions.
The content of thickening agent component of the present invention is between 4～26 weight portions (this moment, stain preferably was 1.2～6.8 weight portions) preferably.In preferred implementation of the present invention, when being converted into percentage by weight, thickener component of the present invention accounts for 7～69 weight % of first composition weight (not comprising diluent).For example, C
16～C
18Alcohol 10～12 weight portions, cis 9-octadecenoic acid 4～6 weight portions, white oil 5～8 weight portion mixture are as thickening agent.
The first surface activating agent
Surfactant of the present invention is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.Comprise cation, anion, nonionic, zwitterionic surfactant and composition thereof.
Be applicable to that anion surfactant of the present invention comprises alkyl sulfate; the alkyl sulfate of ethoxylation; alkyl glycerol base ether sulfonic acid ester; methyl-acyl taurine salt; fat acidyl glycine salt; the N-acyl glutamate; acyl-hydroxyethyl sulfonate; alkyl sulfo succinate; the alkyl ethoxy sulfosuccinate; α-alpha-sulfonated fatty acid; their salt and/or their ester; alkyl ethoxy carboxylate; alkyl phosphate; ethoxylated alkyl phosphate ester; alkyl sulfate; acyl sarcosinates and fatty acid/protein condensation substance and composition thereof.The alkyl of above-mentioned surfactant and/or the chain length of acyl group are C
12～C
22, be preferably C
12～C
18, C more preferably
12～C
18
Ionic surfactant pack is drawn together C
12～C
14List/the diglycollic amide of fatty acid, Olestra surfactant.
Preferably, the surfactant in described first component is selected from sodium lauryl sulphate.
The content of surface active agent composition of the present invention is not particularly limited, for example between 1～2 weight portion (this moment stain preferably be 1.2～6.8 weight portions) particularly.In preferred implementation of the present invention, when being converted into percentage by weight, surface active agent composition of the present invention accounts for 1.8～5.4 weight % of first composition weight (not comprising diluent).
First emulsifying agent
The present invention can add emulsifying agent to form the paste product.
Emulsifying agent of the present invention is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.For example, adopt glyceryl monostearate as emulsifying agent.
The content of emulsifier component of the present invention is not particularly limited, for example between 1～2 weight portion (this moment stain preferably be 1.2～6.8 weight portions) particularly.In preferred implementation of the present invention, when being converted into percentage by weight, emulsifier component of the present invention accounts for 1.8～5.4 weight % of first composition weight (not comprising diluent).
Second component
Oxidant constituents
Oxidant of the present invention does not have particular restriction, only otherwise goal of the invention of the present invention is produced restriction and harmless getting final product.Oxidant can be inorganic or organic oxidizing agent.
The usually preferred inorganic peroxy agent of inorganic oxidizer of the present invention.The inorganic peroxy agent normally can produce the inorganic peroxide of peroxide in aqueous solution.These inorganic peroxy oxidants should be applied in the colouring compositions safely and effectively, for example comprise particularly: hydrogen peroxide, inorganic base metal peroxide such as sodium metaperiodate, perbromic acid sodium and sodium peroxide, the alkali metal salt of one-level inorganic perhydrate salts oxide such as perboric acid, percarbonic acid, peroxophosphoric acid, mistake silicic acid, persulfuric acid etc.As required, can use the mixture of two or more inorganic peroxy oxidants.
Organic oxidizing agent of the present invention is the organic peroxy acid oxidant preferably, it has following formula: R-C (O) OOH, and R representative is saturated or undersaturated, replacement or unsubstituted, the alkyl with 1～14 carbon atom of straight or branched, aryl or aralkyl.
Preferably, the organic peroxy oxidant can be dissolved in the aqueous solution.These organic peroxy agent should be applied in the colouring compositions safely and effectively; for example comprise particularly: peracetic acid, mistake n-nonanoic acid, nonyl-amido are crossed oxy hexanoic acid (NAPCA), benzylhydroperoxide, hexane sulfonyl Perpropionic Acid, N; N-phthalyl amido peroxide caproic acid, one is crossed nonyl amide, diacyl and four acyl peroxides, especially diperoxy dodecanedioic acid, diperoxy tetracosandioic acid and the diperoxy hexadecandioic acid (hexadecane diacid) and the derivant thereof of succinic acid, pelargonyl group oxybenzoic acid, dodecane diacyl one benzylhydroperoxide, peroxide adipic acid.
Preferably, described oxidant constituents is selected from hydrogen peroxide.
The parts by weight of oxidant of the present invention are between 7～12 weight portions (this moment, stain preferably was 1.2～6.8 weight portions) preferably.In preferred implementation of the present invention, when being converted into percentage by weight, oxidant constituents of the present invention accounts for 19～57 weight % of second composition weight (not comprising diluent).
Second thinner composition
The kind of diluent of the present invention is not particularly limited, as long as it is also harmless to make various components fully disperse.Generally be selected from the material miscible and harmless to skin with water.
Preferably, the thinner composition of described second component is selected from water.
The content of thinner composition is not particularly limited, only otherwise purpose of the present invention is produced restriction to get final product.For example, the water of 60～80 weight portions is as diluent (corresponding to the parts by weight of oxidant, they are between 7～12 weight portions).
Second stabilizing agent
Stabilizing agent of the present invention is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.
Preferably, the stabilizing agent in described second component is selected from tetrasodium phosphate or tetrasodium pyrophosphate, more preferably is tetrasodium phosphate.Described tetrasodium phosphate can play stable effect to hydrogen peroxide.
The content of stabilizer component of the present invention is preferably at (parts by weight of oxidant are preferably between 7～12 weight portions at this moment) between 0.01～0.05 weight portion.
Second thickening agent
Thickening agent of the present invention is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.For example, thickening agent of the present invention is selected from cis 9-octadecenoic acid, dimethicone, white oil, oleic acid, spermol, oleyl alcohol, sodium chloride, spermaceti/stearyl alcohol, stearyl alcohol, sodium alginate, arabic gum, cellulose derivative (for example sodium salt of methylcellulose or carboxymethyl cellulose or acrylate copolymer) and other various animal oil and vegetable oil.
Preferably, the thickening agent in described second component is selected from C
16～C
18Alcohol, dimethicone, white oil or its compositions.
The content of thickening agent component of the present invention is at (parts by weight of oxidant are preferably between 7～12 weight portions at this moment) between 2～20 weight portions.For example, C
16～C
18The mixture of alcohol 5～8 weight portions, white oil 5～8 weight portions, dimethicone 2～4 weight portions is as thickening agent.
The second surface activating agent
The kind of the surfactant in second component and first group categories are seemingly.
Preferably, the surfactant in described second component is selected from sodium lauryl sulphate.
The content of second surface active agent component of the present invention is not particularly limited, for example particularly at (parts by weight of oxidant are preferably between 7～12 weight portions at this moment) between 1～2 weight portion.In preferred implementation of the present invention, when being converted into percentage by weight, surface active agent composition of the present invention accounts for 2.7～9.1 weight % of second composition weight (not comprising diluent).
Second emulsifying agent
The present invention can add emulsifying agent to form the paste product.
Emulsifying agent of the present invention is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.For example, adopt glyceryl monostearate as emulsifying agent.
The content of second emulsifier component of the present invention is not particularly limited, for example particularly at (parts by weight of oxidant are preferably between 7～12 weight portions at this moment) between 1～2 weight portion.In preferred implementation of the present invention, when being converted into percentage by weight, emulsifier component of the present invention accounts for 2.7～9.1 weight % of second composition weight (not comprising diluent).
Essence
Randomly can contain essence in first component of the present invention and/or second component, described essence is not particularly limited, only otherwise goal of the invention of the present invention is exerted an influence and harmless getting final product.
For example particularly the content of essence of the present invention in the parts by weight of oxidant (this moment preferably between 7～12 weight portions) between 0.1～0.3 weight portion.
Other optional materials
Other optional materials be can also add in first component of the present invention and second component, protein and polypeptide and derivant thereof comprised; Antiseptic, for example benzoic acid, sodium benzoate; Antioxidant, for example EDTA, sodium sulfite, hydroquinone, sodium sulfite, sodium metabisulfite and TGA, sodium dithionite, arabo-ascorbic acid and other sulfur alcohol; Humidizer, for example hyaluronic acid, chitin etc.
The content of other optional materials is not particularly limited, only otherwise goal of the invention of the present invention is produced restriction and harmless getting final product.The sodium sulfite (this moment, stain preferably was 1.2～6.8 weight portions) that for example, can contain 0.4～0.5 weight portion among the present invention.
Compositions
In the compositions of the present invention, the weight ratio of described first component and second component is preferably 0.5: 1～and 1.5: 1.More preferably, the weight ratio of described first component and second component is 0.8: 1～1.2: 1.
The gross weight of described stain component, hair bulking agent component, oxidant constituents accounts for 36～100 weight % of compositions solid content gross weight.
Particularly in an embodiment of the invention, the present invention is achieved through the following technical solutions:
First ingredients weight parts:
1, C
16～18Alcohol 10.0～12.0
2, glyceryl monostearate 1.0～2.0
3, cis 18 (carbon) alkene-9-acid 4.0～6.0
4, water 40.2～58.6
5, the 2-propanol 4.0～6.0
6, ammonium hydroxide 5.0～6.0
7,1,2-dihydroxypropane 4.0～6.0
8, sodium sulfite 0.4～0.5
9, the EDTA disodium 0.2～0.3
10, ascorbic acid 0.2～0.4
11, sodium lauryl sulphate 1.0～2.0
12, white oil 5.0～8.0
13, essence 0.2～0.5
14, to first (base) amino-phenol hydrochlorate 0.1～0.5*
15, Oleum Rhododendri Daurici 3.6～5.0*
16, Indigo Naturalis 1.2～1.8*
17, tallowseed oil 0.3～0.5*
18, Folium Ginkgo 0.2～0.3*
19, Folium Hibisci Mutabilis 0.4～0.8
20,, Herba Siegesbeckiae 0.3～0.6
21, the Fructus Kochiae 0.3～0.6
Second ingredients weight parts:
1, hydrogen peroxide 7.0～12.0
2, C
16～18Alcohol 5.0～8.0
3, glyceryl monostearate 1.0～2.0
4, water 63.65～78.89
5, white oil 5.0～8.0
6, dimethicone 2.0～4.0
7, sodium lauryl sulphate 1.0～2.0
8, tetrasodium phosphate 0.01～0.05
9, essence 0.1～0.3
Below preparation method of the present invention is described in detail:
Preparation method
Method of the present invention may further comprise the steps:
(i) provide the mixture of first component and second component separately,
Wherein said first component comprises: stain component 1.2～6.8 weight portions, and described stain component is selected from Oleum Rhododendri Daurici, Indigo Naturalis or its combination; Hair bulking agent component 5.0～6.0 weight portions;
Described second component comprises oxidant constituents 7.0～12.0 weight portions,
The gross weight of described stain component, hair bulking agent component, oxidant constituents accounts for 36～100 weight % of compositions solid content gross weight;
(ii) first component mixture that step (i) is obtained and second component mixture carry out independent packaging separately, obtain described permanent type Chinese herbal medicine color oil for hair treatment.
More preferably be that the water solublity of looking component dilutes earlier or mixes with surfactant; Or mixture carried out heating for dissolving.For example specifically, earlier to carry out heating for dissolving standby with diluent before feeding intake for Indigo Naturalis, Oleum Rhododendri Daurici.Or ， Herba Siegesbeckiae, the Fructus Kochiae, Folium Ginkgo, Folium Hibisci Mutabilis mixture be dissolved in the surfactant under the water effect standbyly before feeding intake earlier, and described diluent for example is 1, the mixed solvent of 2-dihydroxypropane and propanol.
Product of the present invention can optionally be prepared into mastic or foaming body, or the dosage form of other use.
Using method
The method of bleaching of the present invention and dyeing human or animal hair comprises to hair and uses described first component and second component respectively that described first component and second component retention time on hair is 30～60 minutes.
For example, operate according to following steps:
The first step is cleaned hair.
Second step squeezed first component and the second component equivalent (each about 15～30 gram) on comb and combs in hair, kept about 30～60 minutes.
The 3rd step was cleaned hair according to a conventional method and gets final product
The suitable adjustment of ratio that existing invention prescription Chinese herbal medicine ratio is the stain component just can freely be prepared black and other the multiple color of nature.These adjustment modes are simply tested and can be obtained by those skilled in the art.
The invention has the advantages that:
(1) toxicity that exists in the prior art and the contradiction between the dyeability have been solved.For the permanent type dyeing product of hair dyeing, the p-phenylenediamine (PPD) toxicity of particularly poliosis being dyed black hair dyeing product is bigger at present, but there is no better raw material replaces.Though and temporary dyeing product does not contain p-phenylenediamine (PPD), painted color and luster and fastness all can not compare favourably with the phenyl amines stain.
(2) will now invent prescription Chinese herbal medicine ratio is that the ratio of stain component is suitably adjusted and just can freely be prepared its multiple color.
Below in conjunction with specific embodiment, further illustrate the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in and limit the scope of the invention.The experimental technique of unreceipted actual conditions in the following example usually according to normal condition, for example is " the condition that the conditioned disjunction in the smooth organic chemistry handbook of Bel Si (Chemical Industry Press, 1996) is advised according to manufacturer.Ratio and percentage ratio are based on weight, unless stated otherwise.
Embodiment 1
The following component of embodiment 1 is used to prepare permanent type Chinese herbal medicine color oil for hair treatment (following examples 2～5 are similar to Example 1), and it comprises first component and second component, and concrete component is as follows:
The weight portion of first component (g):
1, deionized water 52.9
2, C
16-18Alcohol 11
3, ammonium hydroxide (analytical pure) 5
4,1,2-dihydroxypropane (pharmaceutical grade) 5
5, cis 18 (carbon) alkene-9-acid (chemical pure) 5
6, the 2-propanol 5
7, sodium lauryl sulphate 1
8, disodiumedetate 0.2
9, ascorbic acid 0.2
10, sodium sulfite 0.4
11, essence (fruit type) 0.2
12,, Herba Siegesbeckiae 0.5
13, the Fructus Kochiae 0.5
14, Indigo Naturalis 1.6
15, Folium Ginkgo 0.2
16, Folium Hibisci Mutabilis 0.6
17, Oleum Cinnamomi 0.4
18, Oleum Rhododendri Daurici 4.3
19, glyceryl monostearate 1
20, white oil 5
The weight portion of second component (g):
1, deionized water 71.87
2, C
16-18Alcohol 6
3, hydrogen peroxide 12
4, dimethicone 3
5, sodium lauryl sulphate 1
6, tetrasodium phosphate 0.03
7, glyceryl monostearate 1
8, white oil 5
9, essence 0.1
Embodiment 2
The weight portion of first component (g):
1, deionized water 52.9
2, C
16-18Alcohol 11
3, ammonium hydroxide (analytical pure) 5
4,1,2-dihydroxypropane (pharmaceutical grade) 5
5, cis 18 (carbon) alkene-9-acid (chemical pure) 5
6, the 2-propanol 5
7, sodium lauryl sulphate 1
8, disodiumedetate 0.2
9, ascorbic acid 0.2
10, sodium sulfite 0.4
11, essence (fruit type) 0.2
12,, Herba Siegesbeckiae 0.5
13, the Fructus Kochiae 0.5
14, Indigo Naturalis 5.9
15, Folium Ginkgo 0.2
16, Folium Hibisci Mutabilis 0.6
17, Oleum Cinnamomi 0.4
18, glyceryl monostearate 1
19, white oil 5
The weight portion of second component (g):
1, deionized water 71.87
2, C
16-18Alcohol 6
3, hydrogen peroxide 12
4, dimethicone 3
5, sodium lauryl sulphate 1
6, tetrasodium phosphate 0.03
7, glyceryl monostearate 1
8, white oil 5
9, essence 0.1
Embodiment 3
The weight portion of first component (g)
1, C
16～18Alcohol 10.0
2, glyceryl monostearate 1.0
3, cis 18 (carbon) alkene-9-acid 4.0
4, water 53.6
5, just-propanol 4.0
6, ammonium hydroxide 6.0
7,1,2-dihydroxypropane 6.0
8, sodium sulfite 0.5
9, the EDTA disodium 0.3
10, ascorbic acid 0.4
11, sodium lauryl sulphate 1.0
12, almond oil 5.0
13, essence 0.2
14, to first (base) amino-phenol hydrochlorate 0.1
15, Oleum Rhododendri Daurici 3.6
16, Indigo Naturalis 1.8
17, tallowseed oil 0.5
18, Folium Ginkgo 0.3
19, Folium Hibisci Mutabilis 0.8
20,, Herba Siegesbeckiae 0.6
21, the Fructus Kochiae 0.3
The weight portion of second component (g)
1, hydrogen peroxide 7.0
2, C
16～18Alcohol 5.0
3, glyceryl monostearate 1.0
4, water 75.65
5, olive oil 5.0
6, dimethicone 4.0
7, sodium lauryl sulphate 2.0
8, tetrasodium phosphate 0.05
9, essence 0.3
Embodiment 4
The weight proportion of first component (g)
1, C
16～18Alcohol 12.0
2, glyceryl monostearate 2.0
3, cis 18 (carbon) alkene-9-acid 6.0
4, water 45.2
5, ethylene glycol monoethyl ether 6.0
6, ammonium hydroxide 5.0
7,1,2-dihydroxypropane 4.0
8, sodium sulfite 0.4
9, the EDTA disodium 0.2
10, ascorbic acid 0.2
11, sodium lauryl sulphate 2.0
12, white oil 8.0
13, essence 0.5
14, to first (base) amino-phenol hydrochlorate 0.5
15, Oleum Rhododendri Daurici 5.0
16, Indigo Naturalis 1.2
17, tallowseed oil 0.3
18, Folium Ginkgo 0.2
19, Folium Hibisci Mutabilis 0.4
20,, Herba Siegesbeckiae 0.3
21, the Fructus Kochiae 0.6
The weight proportion of second component (g)
1, peracetic acid 12.0
2, sodium alginate 8.0
3, glyceryl monostearate 2.0
4, water 66.89
5, white oil 8.0
6, dimethicone 2.0
7, sodium lauryl sulphate 1.0
8, sodium phosphate 0.01
9, essence 0.1
Embodiment 5
The weight proportion of first component (g)
1, water 78
2, just-propanol 4.0
3, ammonium hydroxide 6.0
4,1,2-dihydroxypropane 6.0
5, ascorbic acid 0.4
6, essence 0.2
7, Oleum Rhododendri Daurici 3.6
8, Indigo Naturalis 1.8
The weight proportion of second component (g)
1, hydrogen peroxide 7.0
2, water 90.65
3, sodium lauryl sulphate 2.0
4, tetrasodium phosphate 0.05
5, essence 0.3
Embodiment 5
The component of embodiment 1 is carried out the processing method of following steps:
First component
(1), water-soluble components is dropped in the kettle that heating for dissolving obtains mixture under 90 ℃ of temperature.Water-soluble components comprises: deionized water, Herba Siegesbeckiae, the Fructus Kochiae, Folium Ginkgo, Folium Hibisci Mutabilis, sodium lauryl sulphate, disodiumedetate, ascorbic acid, sodium sulfite.
(2), heating for dissolving in the oil-soluble composition oil cauldron (temperature must not be lower than 90 ℃) is obtained mixture.The oil-soluble composition comprises: Oleum Cinnamomi, white oil, C
16～18Alcohol, glyceryl monostearate, cis 18 (carbon) alkene-9-acid.
(3), Oleum Rhododendri Daurici, Indigo Naturalis are dissolved in 1 respectively, in 2-dihydroxypropane and the 2-propanol solvent, obtain Oleum Rhododendri Daurici, Indigo Naturalis solution respectively.
(4), the mixture that successively (1), (2) is obtained sucks in the vacuum response still and fully mixes stirring homogenizing, suction (3) obtains during 65 ℃ of left and right sides Oleum Rhododendri Daurici, Indigo Naturalis solution.Stir, add essence below 50 ℃, add ammonium hydroxide about 35 ℃.
(5), discharging after the assay was approved, canned, obtain the A agent.
Second component:
(1), deionized water, sodium lauryl sulphate, tetrasodium phosphate are dropped into heating (temperature is 90 ℃) in the kettle.
(2), with white oil, dimethicone, C
16～18Alcohol, glyceryl monostearate drop into heating (temperature is 90 ℃) in the oil cauldron.
(3) successively (1), (2) are sucked fully mixing in the vacuum response still, stir homogenizing, add essence below 50 ℃, add hydrogen peroxide about 35 ℃.
(4), discharging after the assay was approved, tinning, obtain the B agent.
During use according to following step:
The first step is cleaned hair
Second step squeezed two doses of equivalent of A, B (each about 15 gram) on comb and combs in hair, kept about 30 minutes.
The 3rd step was cleaned hair and gets final product.
Performance measurement:
(1) dyeability: aspect outward appearance, the saturating dark-brown of natural black, glossy, suitably adding relaxing the bowels with purgatives of warm nature saturation 〉=95%.
(2) dyefastness: kept month, and washed and can not decolour for 5～8 times.
(3) anaphylaxis of this product is measured:
The use result is as shown in table 1::
Table 1 uses result's statistics
| Number of users | Masculinity proportion % | Women's ratio % | Allergic constitution number/number | Allergic symptom example number |
| 476 people | 85 | 15 | 121 | 0 |
Comparative Examples 1 (permanent hair dyeing product)
The weight proportion of first component (g)
1, deionized water 65.5
2, C
16-18Alcohol 10
3, ammonium hydroxide (analytical pure) 6
4,1,2-dihydroxypropane (pharmaceutical grade) 5
5, white oil 5
6, glyceryl monostearate 1.5
7, p-phenylenediamine (PPD) 3.8
8, sodium lauryl sulphate 1
9, disodiumedetate 0.4
10, the p-methylaminophenol hydrochlorate 0.2
11, ascorbic acid 0.6
12, sodium sulfite 0.4
13, essence (fruit type) 0.6
The weight proportion of second component (g):
1, deionized water 78.39
2, C
16-18Alcohol 5
3, hydrogen peroxide 7
4, dimethicone 2
5, sodium lauryl sulphate 1
6, tetrasodium phosphate 0.01
7, white oil 5
8, essence 0.1
9, glyceryl monostearate 1.5
First component:
(1) deionized water, sodium lauryl sulphate, disodiumedetate, ascorbic acid, sodium sulfite are dropped into successively heating for dissolving in the kettle (temperature must not be lower than 90 ℃), obtain mixture.
(2) p-phenylenediamine (PPD), p-methylaminophenol hydrochlorate dyestuff are dissolved in 1, in the 2-dihydroxypropane solvent, obtain mixture.
(3) with white oil, glyceryl monostearate, C
16～18Alcohol drops into heating for dissolving in the oil cauldron (temperature is not less than 90 ℃) successively, obtains mixture.
(4) mixture that successively (1), (3) is obtained sucks in the vacuum response still and fully mixes, and stirs homogenizing, sucks the mixture that (2) obtain in the time of 70 ℃.Add essence below 50 ℃, add ammonium hydroxide about 35 ℃.
(5) discharging after the assay was approved, canned obtains the A agent.
Second component:
(1), deionized water, sodium lauryl sulphate, tetrasodium phosphate are dropped into heating (temperature must not be lower than 90 ℃) in the kettle.
(2), with white oil, dimethicone, C
16～18Alcohol, glyceryl monostearate drop into heating (temperature must not be lower than 90 ℃) in the oil cauldron.
(3), successively (1), (2) are sucked in the vacuum response still and fully mix, stir homogenizing, add essence below 50 ℃, add hydrogen peroxide about 35 ℃.
(4), discharging after the assay was approved, tinning, obtain the B agent.
Comparative Examples 2
The using method of commercially available " hair color hall " Chinese medicine rinse product:
The product that before the hair dyeing with the Flos Caryophylli is penetrating agent is applied on the hair, heats one hour with hot top;
Then the Chinese herbal medicine hair-dyeing hair-blackening liquor being applied on the hair reuse hot top heats and kept 2 hours;
Must acid special-purpose shampoo be cleaned by hair.
Be not difficult to find out, above process add the comb dye need four～five hours around time, and after 10～15 days fugitive color (it is faster particularly to use neutral shampoo to fade); In addition, because complex operation typically has to go to the baked dyeing hair of the Qu of specialty store, the price comparison costliness.
Comparative Examples 3 (temporary hair dyeing product)
Weight proportion (g)
1, third butane 49.8
2, ethanol 43
3, the copolymer 4 of poly-acetyl pyrrole alkane ketone-vinylacetate
4, the pearlescent pigment powder 3
5, essence 0.2
(1), successively component 2,3,4,5 is stirred at normal temperatures.
(2), the qualified back discharging of the inspection of semifinished product.
(3), semi-finished product pack into and seal in the aluminium pot, add component 1 again, obtain temporary hair dye.
The time of staying of the temporary hair dye of gained on hair is short, and washing is once promptly faded.
All quote in this application as a reference at all documents that the present invention mentions, just quoted as a reference separately as each piece document.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after having read above-mentioned teachings of the present invention, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Claims (10)
1. compositions that is used to have hair dyed is characterized in that it comprises:
First component, described first component comprises: stain component 1.2～6.8 weight portions, described stain component comprises Oleum Rhododendri Daurici, Indigo Naturalis or its combination; Hair bulking agent component 5.0～6.0 weight portions;
Second component, described second component comprises oxidant constituents 7.0～12.0 weight portions,
The gross weight of described stain component, hair bulking agent component, oxidant constituents accounts for 36～100 weight % of compositions solid content gross weight.
2. compositions as claimed in claim 1 is characterized in that,
Described stain component is selected from the combination of Oleum Rhododendri Daurici and Indigo Naturalis, and the weight ratio of described Oleum Rhododendri Daurici and Indigo Naturalis is between 2: 1～4.2: 1; Or
Described hair bulking agent component is selected from ammonium hydroxide; Or
Described oxidant constituents is selected from hydrogen peroxide.
3. compositions as claimed in claim 1 or 2 is characterized in that, described first component also comprises:
Antiallergic component 0.3～2 weight portion, described antiallergic component Xuan Zi Herba Siegesbeckiae, the Fructus Kochiae, Folium Hibisci Mutabilis or its combination, and/or
Dyeing auxiliaries component 0.2～0.8 weight portion, described dyeing auxiliaries component is selected from Oleum Cinnamomi, tallowseed oil, Folium Ginkgo or its combination.
4. compositions as claimed in claim 1 or 2 is characterized in that, described first component also comprises: first diluent, first stabilizing agent, first thickening agent, first surface activating agent, first emulsifying agent or its combination.
5. compositions as claimed in claim 1 is characterized in that, described second component also comprises: second diluent, second stabilizing agent, second thickening agent, second surface activating agent, second emulsifying agent or its combination.
6. permanent type Chinese herbal medicine color oil for hair treatment that makes as each described compositions of claim 1～5.
7. the preparation method of a permanent type Chinese herbal medicine color oil for hair treatment as claimed in claim 6 is characterized in that, may further comprise the steps:
(i) provide the mixture of first component and second component separately,
Wherein said first component comprises: stain component 1.2～6.8 weight portions, and described stain component is selected from Oleum Rhododendri Daurici, Indigo Naturalis or its combination; Hair bulking agent component 5.0～6.0 weight portions;
Described second component comprises oxidant constituents 7.0～12.0 weight portions,
The gross weight of described stain component, hair bulking agent component, oxidant constituents accounts for 36～100 weight % of compositions solid content gross weight;
(ii) first component mixture that step (i) is obtained and second component mixture carry out independent packaging separately, obtain described permanent type Chinese herbal medicine color oil for hair treatment.
8. preparation method as claimed in claim 7 is characterized in that,
First component described in the step (i) is mixed under 90 ℃～95 ℃ temperature and is obtained described first component mixture; Or
Described second component is mixed under 90 ℃～95 ℃ temperature and is obtained described second component mixture.
9. the method for a bleaching and the human or animal's hair that dyes is characterized in that use simultaneously as claim 1～5 each described first component and second component to hair, described first component and second component retention time on hair is 30～60 minutes.
10. the Oleum Rhododendri Daurici or the purposes of Indigo Naturalis is characterized in that, are used to prepare the permanent type hair dyeing product.
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|---|---|---|---|
| CN2007100364845A CN101224175B (en) | 2007-01-16 | 2007-01-16 | Permanent Chinese traditional medicine color oil for hair treatment |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100364845A CN101224175B (en) | 2007-01-16 | 2007-01-16 | Permanent Chinese traditional medicine color oil for hair treatment |
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| CN101224175B CN101224175B (en) | 2011-01-05 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101711724A (en) * | 2008-10-06 | 2010-05-26 | 工业化学化妆品有限公司 | Fat phase for preparing hair dye, method for preparing fat phase and system for performing the method |
| CN102051826A (en) * | 2010-11-12 | 2011-05-11 | 许昌恒源发制品股份有限公司 | Rapid dyeing assistant for imitation hair and preparation method thereof |
| CN105232421A (en) * | 2015-09-25 | 2016-01-13 | 苏州龙腾万里化工科技有限公司 | Environment-friendly color-changeable hair dye |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062652A (en) * | 1990-12-24 | 1992-07-15 | 战永胜 | The Chinese herbal medicine hair dyed agent |
-
2007
- 2007-01-16 CN CN2007100364845A patent/CN101224175B/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101711724A (en) * | 2008-10-06 | 2010-05-26 | 工业化学化妆品有限公司 | Fat phase for preparing hair dye, method for preparing fat phase and system for performing the method |
| CN102051826A (en) * | 2010-11-12 | 2011-05-11 | 许昌恒源发制品股份有限公司 | Rapid dyeing assistant for imitation hair and preparation method thereof |
| CN102051826B (en) * | 2010-11-12 | 2012-10-03 | 许昌恒源发制品股份有限公司 | Rapid dyeing assistant for imitation hair and preparation method thereof |
| CN105232421A (en) * | 2015-09-25 | 2016-01-13 | 苏州龙腾万里化工科技有限公司 | Environment-friendly color-changeable hair dye |
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| CN101224175B (en) | 2011-01-05 |
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