Single layer wall polychloroethylene mute drainpipe
Technical field
The invention belongs to a kind of gutter, specifically, relating to a kind of tube wall is the polychloroethylene mute gutter of the remarkable reduction draining noise of individual layer.
Background technology
The UPVC gutter is with its cheapness, attractive in appearance, installation and maintenance convenience, and application life is longer, extensively adopts in the whole world.But it has a fatal weakness, highrise building or even middle level building, and noise is very big during draining, influences the room peace and quiet, sometimes people is waken up with a start from the dreamland of sweetness.Face of noise, we have done many effort, have developed UPVC foamed sandwich pipe, real wall UPVC inside spin noise reduction pipe, empty wall UPVC inside spin noise reduction pipe, eddy flow denoiser, hydrophilic inwall eddy flow denoiser, rigid polyvinyl chloride eddy flow noise reduction tee junction etc. in succession.External Japanese scholar has done many work, has delivered many patents.But show that through noise measuring the noise reduction of these technology is also not obvious, even the noise reduction of UPVC foamed sandwich pipe is not as good as common UPVC gutter.
My company has developed a kind of quiet pipe for this reason, its patent of invention number: ZL 03135574.9.This quiet pipe is a kind of clad pipe wall technique, and the cross section structure of its pipe as shown in Figure 6.2 and 3 is interior exodermis, by polyvinyl chloride resin, impact modifier, modifier, stabilizing agent, sliding agent, active CaCO
3Filler and pigment are formed.This two-layer amount of filler is few, the quality height, and exodermis plays decoration function, and endodermis plays antisepsis.The strength ratio sandwich layer height that this is two-layer can guarantee that this quiet gutter has enough mechanical strengths, to satisfy user's instructions for use.1 is the sound absorption sandwich layer, it except normal recipe that the normal discharge pipe is arranged and, added the sound absorption function filler of capacity.This quiet gutter can make draining noise decline 14~18dB, residual noise 47~51dB.But along with the raising of people's living standard, people are higher to the requirement of quiet gutter in recent years, wish to reach the requirement of national standard of environmental noise of urban area GB3096-93, and the gutter cost requirement reduces.
Summary of the invention
The object of the present invention is to provide a kind of structural pipe wall simple, cheap for manufacturing cost, can significantly reduce draining noise, can reach again to use the higher single layer wall polychloroethylene mute drainpipe of mechanical strength is installed.
A kind of single layer wall polychloroethylene mute drainpipe, its key is: described single layer wall polychloroethylene mute drainpipe tube wall is an individual layer, contain polyvinyl chloride resin 100 weight portions in the raw material of tubing, barium sulfate 150~350 weight portions, haloflex 10~20 weight portions, reach other relevant processing aids, extrude through double screw extruder and form this kind polychloroethylene mute gutter.
Barium sulfate is the function absorbing material, has high soundproof effect, and when consumption was lower than 150 weight portions, the tubing sound-absorbing effect did not reach the requirement of national standard of environmental noise of urban area GB3096-93, and the gutter cost is too high, and market is difficult for accepting.If the barium sulfate consumption surpasses 350 weight portions, the tubing mechanical properties strength is too poor, does not reach the normal mounting instructions for use, and is difficult to shape.Consumption 50~600 weight portions of barium sulfate are preferably 200~350 weight portions.The average grain diameter of barium sulfate is 2~45 μ m, is preferably in about 10 μ m.Particle diameter is greater than 45 μ m, and the plastic hybrid plasticizing is difficult, and the tubing bad mechanical property does not reach and installs and uses requirement.Use blanc fixe (particle diameter 2~3 μ m), the price height, the tubing cost improves.
CPE is a good auxiliary agent of regulating the tubing impact strength, and consumption is 5~50 weight portions, is preferably 10~20 weight portions, and consumption is less than 10 weight portions, and the tubing shock resistance is too low.Consumption is higher than 20 weight portions, and drawing pipe intensity is too low, and cost improves.Also can adopt MBS, ABS, EVA and KM323B replaced C PE as anti-impact modifier,, can improve the cost of material of quiet pipe greatly because of these four kinds of impact modifier prices are very high.
Other relevant processing aids:
What modifier was used is ACR401 0.5~3 weight portion, also can use PA20, PA21, K-125 and K-120N, promotes the polyvinyl chloride resin plasticizing.
What stabilizing agent was used is compound lead stabilizer TY208 3~5 weight portions, the also compound lead stabilizer of available other models, organic tin stabilizer, calcium/zinc stabilizer or rare-earth stabilizer.Play heat stabilization, make the fixed quiet gutter polyvinyl chloride resin in process of solid wall polyvinyl chloride not decompose rotten.
That sliding agent is used is calcium stearate (CaSt
2) 0.3~0.8 weight portion, in-lubricant; Stearic acid (HSt) 0.5~1.0 weight portion, inside and outside lubricant agent; Paraffin (WAX) 0.3~0.7 weight portion, external lubricant.
What plasticizing agent was used is DOP (phthalic acid two (the 2-ethyl is own) ester) 2~6 weight portions, also can use DIOP (dioctyl phthalate dibutyl ester) or DBP (dibutyl phthalate (DBP)).Play plasticization and processing modified effect.
Titanium dioxide (TiO
2) 3~5 weight portions, Chinese white has anti-ultraviolet function concurrently.
Test:
1, equipment
The high speed kneader, GRH-300R
Cold mixer, LH-500B
Conical double screw extruder, the hard machine in Willie, Guangdong Co., Ltd makes screw diameter φ 60
Extrusion die
Extrude follow-up equipment (cooling vacuum calibrator, draw-gear, ink jet numbering machine, cutting machine)
2, operating procedure
(1) prescription of pressing table 2 is prepared burden totally 10 batches.
(2) each batch of material gradation is dropped in the high speed kneading pot, high-speed stirred, the mutual frictional heating of material, material rises to 125 ℃ by room temperature, and blowing is in cold mixed pot.
(3) in cold mixed pot, the logical cooling water of cold mixed pot chuck, hot batch mixing is reduced to 40 ℃ of dischargings by 125 ℃, and cold burden is placed in the hopper stand-by.
(4) cold burden drops into the double screw extruder hopper
(5) material in the hopper is sent extruder barrel to by reinforced screw rod
(6) material is in barrel, and the barrel outer wall has the electric heater heating, adds conical double-screw and shears mutually, and material becomes plasticizing by powder and melts body.
(7) plasticizing is melted body and is extruded into the heat pipe embryo through squeezing pipe mold.
(8) the heat pipe embryo enters the vacuum cooled calibrator under traction drives
(9) coding is in related text such as the specification of being printed tubing on the pipe of cooling by ink jet numbering machine, trade mark, dates of manufacture.
(10) traction is by draw-gear at the uniform velocity traction synchronously.
(11) cut, continuous tubing is sawn into the length of customer requirement by cast-cutting saw
(12) check
(13) packing is in the polythene film bag of manually tubing being packed into
(14) warehouse-in
3, main technologic parameters
Heat is mixed drop temperature: 125 ± 2 ℃
Cold mixed drop temperature:<40 ℃
Barrel temperature: 180 ± 2 ℃ in 1 district
178 ± 2 ℃ in 2 districts
175 ± 2 ℃ in 3 districts
170 ± 2 ℃ in 4 districts
Adapter sleeve temperature: 165 ± 2 ℃
Mold temperature: 1 section (die body) 170 ± 2 ℃
2 sections (die body) 175 ± 2 ℃
3 sections (mouthful mould) 180 ± 2 ℃
Extruder engine speed 18 ± 2rpm
Main frame torque (being the main frame electric current) 40~50A
Reinforced screw speed 15 ± 2rpm
Interpretation is in table 2.
Preparation technology's flow chart as shown in Figure 5.
Table 1 test recipe and performance
Numbering |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
10 |
Polyvinyl chloride resin |
100 |
100 |
100 |
100 |
100 |
100 |
100 |
100 |
100 |
100 |
CPE |
5 |
7 |
10 |
10 |
10 |
15 |
20 |
30 |
40 |
50 |
ACR |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
Ty208 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
CaSt
2 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
HSt |
0.8 |
0.8 |
0.8 |
0.8 |
0.8 |
0.8 |
0.8 |
0.8 |
0.8 |
0.8 |
WAx |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
D0P |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
TiO
2 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
4.0 |
BaSO
4 |
50 |
100 |
150 |
200 |
250 |
300 |
350 |
400 |
500 |
600 |
Product mass-energy |
Noise (de) |
Sound source |
70 |
70 |
70 |
70 |
70 |
70 |
70 |
70 |
70 |
70 |
Noise |
60 |
55 |
50 |
40 |
35 |
30 |
30 |
28 |
25 |
|
Noise reduction |
10 |
15 |
20 |
30 |
35 |
40 |
40 |
42 |
45 |
|
|
Impact strength (20 ℃, J) |
42 |
41 |
40 |
38 |
35 |
30 |
25 |
18 |
12 |
|
Hot strength (25 ℃, MPa) |
40 |
35 |
32 |
30 |
30 |
25 |
21 |
14 |
10 |
|
Elongation at break (%) |
10.07 |
8.05 |
6.17 |
3.25 |
2.69 |
1.09 |
0.91 |
0.42 |
0.22 |
|
Density (g/cm
3)
|
1.608 3 |
1.875 5 |
2.1864 |
2.3141 |
2.4592 |
2.5015 |
2.5100 |
2.603 1 |
2.6533 |
|
Cost of production |
Be higher than common tube |
It is logical to be higher than general pipe |
Market can be accepted |
Market can be accepted |
The field can be accepted in market |
Market can be accepted |
Market can be accepted |
Do not estimate cost |
Do not estimate cost |
Be difficult to shape |
The data of table 2 show;
No. 1, good mechanical property, cost of production is higher than common UPVC gutter, density is similar with the high UPVC gutter (nonstandard pipe) of filling, noise reduction and the common high UPVC gutter of filling are similar, do not reach the national standard of environmental noise of urban area minimum requirements at night (main line of communication road two lateral areas night be 55dB), cost of production is much higher than common UPVC gutter.
No. 2, better mechanical property, cost of production is higher than common UPVC gutter, density is higher than the high UPVC gutter (nonstandard pipe) of filling, noise reduction is better than the common high UPVC of filling gutter, has reached the national standard of environmental noise of urban area minimum requirements at night (main line of communication road two lateral areas night be 55dB).
No. 3, better mechanical property, cost of production be a little more than common UPVC gutter, and density is filled the UPVC pipe far above height, and noise reduction reaches national urban environment noise standard class two zone territory and requires (mix commercial area night be 50dB).
No. 4, mechanical performance can be satisfied instructions for use, cost of production is filled common UPVC gutter a little more than height, density improves greatly, noise reduction improves greatly, requirement (hospital, sanatorium, the hotel in National Environmental noise region permission standard 0 class zone have been reached, night 40dB), that is to say that it has reached whole requirements of this national standard.
No. 5, mechanical performance can be satisfied instructions for use, and cost of production is filled out common UPVC gutter a little more than height, and density improves greatly, and noise reduction improves greatly, require also low than national standard.
No. 6, mechanical performance can be satisfied instructions for use, and cost of production is filled out common UPVC gutter a little more than height, and density is higher than No. 5, and noise reduction is not worse than No. 5, require also lowly than national standard, have reached the indignant thought of " quiet " in the people's lives.
No. 7, mechanical performance are weaker, and particularly impact strength is exempted from can use by force, and processing characteristics is weaker, and density is higher, and noise reduction is better, has reached the indignant thought of " quiet " in the people's lives.Cost of production is lower.But, preferably increase some anti-impact modifiers in the prescription in order to reach satisfied market effect.
No. 8, proportion are bigger, and noise reduction is better, but mechanical performance reduces, and can not satisfy and install and use requirement, and difficulty of processing is big.
No. 9, noise reduction increase, but a nearly step of mechanical performance reduce, difficulty of processing strengthens.
No. 10, be difficult to shape.
Conclusion: take all factors into consideration from pipe performance, noise reduction and cost of production, numbering 3~7th is desirable.The gutter that makes is compared as follows shown in the tabulation 2 with the anti-acoustic capability of domestic and international noise reduction gutter
Table 2 anti-acoustic capability of noise reduction gutter both at home and abroad compares
Sequence number |
Noise reduction pipe title |
Noise margin (dB) |
Noise reduction pipe density (g/cm
3)
|
Data Source |
1 |
Single layer wall polychloroethylene mute drainpipe of the present invention |
30~40 |
2.50 |
University Of Chongqing's materials testing laboratory's examining report on July 21st, 2006 |
2 |
03135574.9 3 layers of quiet gutter φ of compound UPVC of the patent No.: ZL, 110 * 4.5mm |
47~51 |
1.9855 |
ZL 03135574.9 |
3 |
UPVC helical silencing gutter φ 110 * 3.2mm |
53 |
/ |
Acoustic investigation institute of Tongji University test report on October 12nd~19,1996 |
4 |
Common UPVC gutter φ 110 * 3.2mm |
62 |
/ |
Acoustic investigation institute of Tongji University test report on October 12nd~19,1996 |
5 |
Empty wall helix tube φ 110 * 5.5mm gutter |
54 |
/ |
ZL 99213438.2 |
6 |
PVC core layer foaming Drain pipe for building φ 110 * 3.2mm |
58 |
/ |
22~24 pages of " chemical building material " New Building Materials 1996 the 8th phases |
7 |
Japan hush pipe φ 114 * (2+2+3) (each 2mm of interior exodermis, foamed core layer 3mm) |
Noise reduction 16dB |
/ |
Te Kaiping 11-257548 (1999) |
8 |
Japan hush pipe φ 114 * (3+3+9) (interior exodermis is the 3mmPVC pipe, and sandwich layer is a 9mmSBR foaming pipe) |
Noise reduction 21dB |
/ |
Te Kaiping 2000-266246 |
9 |
Japan hush pipe φ 114 * (3+3+25) (interior exodermis is the 3mmPVC pipe, and sandwich layer is 25 a mmEPDM foaming pipe) |
Noise reduction 28dB |
/ |
Te Kaiping 2000-266246 |
10 |
200 parts of BaSO
4Filling φ 150 * 3mm partly takes turns PVC sound-absorbing pipe and wraps in outside the φ 150mmUPVC gutter
|
Noise reduction 4dB |
/ |
Te Kaiping 5-271429 |
11 |
900 parts of BaSO
4Filling φ 150 * 3mm medium-soft PVC sound-absorbing pipe wraps in outside the φ 150mmUPVC gutter
|
Noise reduction 8dB |
|
Te Kaiping 5-271429 |
12 |
The super quiet gutter φ 110 * 4.5mm of north Xinlong board PP |
45 |
1.4~1.9 |
National civil building design technical measures building products selected technology data was 76 pages in 2005. |
13 |
Low-pressure fluid is carried the welding iron pipe |
20~25 |
7.8 |
Data on July 18th, 2006 is detected by the University Of Chongqing materials testing laboratory |
Above-mentioned single layer wall polychloroethylene mute drainpipe is real wall construction, is called real wall polychloroethylene mute gutter.
The inside pipe wall of above-mentioned single layer wall polychloroethylene mute drainpipe also can have the inside spin rib, is called real wall inside spin polychloroethylene mute gutter.
Also can have axial cavity in the tube wall of above-mentioned single layer wall polychloroethylene mute drainpipe, be called sky wall polychloroethylene mute gutter.
Above-mentioned single layer wall polychloroethylene mute drainpipe can also have the inside spin rib by inside pipe wall, has axial cavity in the tube wall simultaneously, is called sky wall inside spin polychloroethylene mute gutter.
Beneficial effect: the single layer wall polychloroethylene mute drainpipe noise reduction greatly improves, and noise can be reduced to 30~40dB, reaches the requirement of national standard of environmental noise of urban area GB3096-93 fully, and tube wall only needs one deck simultaneously; This layer tube wall can reach the new demand of noise reduction, can reach again use mechanical strength; And simplified equipment, investment reduces, and cost reduces greatly.
Description of drawings
Fig. 1 is that tube wall of the present invention is the polychloroethylene mute drain structure schematic diagram of individual layer;
Fig. 2 is a solid wall inside spin polychloroethylene mute drain structure schematic diagram of the present invention;
Fig. 3 is the empty wall polychloroethylene mute of a solid wall of the present invention drain structure schematic diagram;
Fig. 4 is the empty wall inside spin of a solid wall of the present invention polychloroethylene mute drain structure schematic diagram;
Fig. 5 is preparation technology's flow chart of the present invention;
Fig. 6 is the structural representation before improving.
The specific embodiment
Embodiment 1
Single layer wall polychloroethylene mute drainpipe of the present invention, earlier by following mass fraction preparation raw material:
100 parts of polyvinyl chloride resins, 10 parts of CPE, 2.0 parts of ACR, 4.0 parts of TY208, CaSt
20.5 part, 0.8 part of HSt, 0.5 part of WAX, 4.0 parts of DOP, TiO
24.0 part, BaSO
4150 parts.
1, equipment
The high speed kneader, GRH-300R
Cold mixer, LH-500B
Conical double screw extruder, the hard machine in Willie, Guangdong Co., Ltd makes screw diameter φ 60
Extrusion die
Extrude follow-up equipment (cooling vacuum calibrator, draw-gear, ink jet numbering machine, cutting machine)
2, operating procedure as shown in Figure 5
(1) prescription by table 3 prepares material,
(2) each batch of material gradation is dropped in the high speed kneading pot, high-speed stirred, the mutual frictional heating of material, material rises to 125 ℃ by room temperature, and blowing is in cold mixed pot.
(3) in cold mixed pot, the logical cooling water of cold mixed pot chuck, hot batch mixing is reduced to 40 ℃ of dischargings by 125 ℃, and cold burden is placed in the hopper.
(4) cold burden drops into the double screw extruder hopper
(5) material in the hopper is sent extruder barrel to by reinforced screw rod
(6) material is in barrel, and the barrel outer wall has the electric heater heating, adds conical double-screw and shears mutually, and material becomes plasticizing by powder and melts body.
(7) plasticizing is melted body and is extruded into the heat pipe embryo through squeezing pipe mold.
(8) the heat pipe embryo enters the vacuum cooled calibrator under traction drives
(9) coding is in related text such as the specification of being printed tubing on the pipe of cooling by ink jet numbering machine, trade mark, dates of manufacture.
(10) traction is by draw-gear at the uniform velocity traction synchronously.
(11) cut, continuous tubing is sawn into the length of customer requirement by cast-cutting saw
(12) check
(13) packing is in the polythene film bag of manually tubing being packed into
(14) warehouse-in
3, main technologic parameters
Heat is mixed drop temperature: 125 ± 2 ℃
Cold mixed drop temperature:<40 ℃
Barrel temperature: 180 ± 2 ℃ in 1 district
178 ± 2 ℃ in 2 districts
175 ± 2 ℃ in 3 districts
170 ± 2 ℃ in 4 districts
Adapter sleeve temperature: 165 ± 2 ℃
Mold temperature: 1 section (die body) 170 ± 2 ℃
2 sections (die body) 175 ± 2 ℃
3 sections (mouthful mould) 180 ± 2 ℃
Extruder engine speed 18 ± 2rpm
Main frame torque (being the main frame electric current) 40~50A
Reinforced screw speed 15 ± 2rpm
Make as shown in Figure 1, single layer wall polychloroethylene mute drainpipe 1, tube wall are individual layer;
As shown in Figure 2, inwall is provided with the single layer wall polychloroethylene mute drainpipe 1 of inside spin rib 1a, is called solid wall inside spin polychloroethylene mute gutter;
As shown in Figure 3, have the single layer wall polychloroethylene mute drainpipe 1 of axial cavity 1b in the tube wall, be called the empty wall polychloroethylene mute of solid wall gutter;
As shown in Figure 4, inwall is provided with inside spin rib 1a, has the single layer wall polychloroethylene mute drainpipe 1 of axial cavity 1b simultaneously in the tube wall, is called the empty wall inside spin of solid wall polychloroethylene mute gutter.
Embodiment 2
Single layer wall polychloroethylene mute drainpipe of the present invention, BaSO4 is 200 parts in the tubing raw material.All the other are identical with embodiment 1.
Make as shown in Figure 1, single layer wall polychloroethylene mute drainpipe 1, tube wall are individual layer;
As shown in Figure 2, inwall is provided with the single layer wall polychloroethylene mute drainpipe 1 of inside spin rib 1a, is called solid wall inside spin polychloroethylene mute gutter;
As shown in Figure 3, have the single layer wall polychloroethylene mute drainpipe 1 of axial cavity 1b in the tube wall, be called the empty wall polychloroethylene mute of solid wall gutter;
As shown in Figure 4, inwall is provided with inside spin rib 1a, has the single layer wall polychloroethylene mute drainpipe 1 of axial cavity 1b simultaneously in the tube wall, is called the empty wall inside spin of solid wall polychloroethylene mute gutter.
Embodiment 3
Single layer wall polychloroethylene mute drainpipe of the present invention, BaSO4 is 250 parts in the tubing raw material.All the other are identical with embodiment 1.
Make as shown in Figure 1, single layer wall polychloroethylene mute drainpipe 1, tube wall are individual layer;
As shown in Figure 2, the inwall single layer wall polychloroethylene mute drainpipe 1 that is provided with inside spin rib 1a is called solid wall inside spin polychloroethylene mute gutter;
As shown in Figure 3, have the single layer wall polychloroethylene mute drainpipe 1 of axial cavity 1b in the tube wall, be called the empty wall polychloroethylene mute of solid wall gutter;
As shown in Figure 4, inwall is provided with inside spin rib 1a, has the single layer wall polychloroethylene mute drainpipe 1 of axial cavity 1b simultaneously in the tube wall, is called the empty wall inside spin of solid wall polychloroethylene mute gutter.
Embodiment 4
Single layer wall polychloroethylene mute drainpipe of the present invention, BaSO4 is 250 parts in the tubing raw material; 15 parts of CPE.All the other are identical with embodiment 1.
Can only make as shown in Figure 1, single layer wall polychloroethylene mute drainpipe 1, tube wall are individual layer;
As shown in Figure 2, the inwall single layer wall polychloroethylene mute drainpipe 1 that is provided with inside spin rib 1a is called solid wall inside spin polychloroethylene mute gutter;
As shown in Figure 3, have the single layer wall polychloroethylene mute drainpipe 1 of axial cavity 1b in the tube wall, be called the empty wall polychloroethylene mute of solid wall gutter.
Embodiment 5
Single layer wall polychloroethylene mute drainpipe of the present invention, BaSO4 is 350 parts in the tubing raw material; 20 parts of CPE.All the other are identical with embodiment 1.
Can only make as shown in Figure 1, single layer wall polychloroethylene mute drainpipe 1, tube wall are individual layer.
Comparative Examples 1
Polyvinyl chloride resin is 100 parts in the tubing raw material, 5 parts of CPE, 2.0 parts of ACR, 4.0 parts of TY208, CaSt
20.5 part, 0.8 part of HSt, 0.5 part of WAX, 4.0 parts of DOP, TiO
24.0 part, BaSO
450 parts.By technological process shown in Figure 5, and with embodiment 1 described operating procedure, make single layer wall polychloroethylene mute drainpipe, the data of numbering 1 as can be known from above-mentioned table 1, this kind pipe has good physical and mechanical properties, but noise reduction is undesirable, can not satisfy whole requirements of GB GB3096-93, and cost of material is too high.
Comparative Examples 2
BaSO4 is 100 parts in the tubing raw material; 7 parts of CPE, all the other raw materials are identical with Comparative Examples 1.By technological process shown in Figure 5, and with embodiment 1 described operating procedure, make single layer wall polychloroethylene mute drainpipe, the data of numbering 2 as can be known from above-mentioned table 1, this kind pipe has good physical and mechanical properties, undesirable to Comparative Examples 1 similar same noise reduction, can not satisfy whole requirements of GB GB3096-93, and cost of material is too high.
Comparative Examples 3
BaSO4 is 400 parts in the tubing raw material; 30 parts of CPE, all the other raw materials are identical with Comparative Examples 1.By technological process shown in Figure 5, and with embodiment 1 described operating procedure, make single layer wall polychloroethylene mute drainpipe, the data of numbering 8 as can be known from above-mentioned table 1, this kind pipe noise reduction is fine, can satisfy whole requirements of GB GB3096-93 fully, but physical and mechanical properties is too poor, does not satisfy the requirement of construction and installation and use.And processing characteristics is also poor.
Comparative Examples 4
BaSO4 is 500 parts in the tubing raw material; 40 parts of CPE, all the other raw materials are identical with Comparative Examples 1.By technological process shown in Figure 5, and with embodiment 1 described operating procedure, make single layer wall polychloroethylene mute drainpipe, the data of numbering 9 as can be known from above-mentioned table 1, this kind pipe noise reduction is fine, can satisfy whole requirements of GB GB3096-93 fully, but physical and mechanical properties is too poor, do not satisfy the requirement of construction and installation and use, and processing characteristics is also poor.
Comparative Examples 5
BaSO4 is 600 parts in the tubing raw material; 50 parts of CPE, all the other raw materials are identical with Comparative Examples 1.By technological process shown in Figure 5, and, prepare single layer wall polychloroethylene mute drainpipe with embodiment 1 described operating procedure.From above-mentioned table 1 numbering 10 data as can be known, this prescription processing characteristics is too poor, basic can not squeezing pipe.