CN101195534A - Method for producing porcelain granule light weight aggregate with sewage sludge - Google Patents
Method for producing porcelain granule light weight aggregate with sewage sludge Download PDFInfo
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- CN101195534A CN101195534A CNA2007103020115A CN200710302011A CN101195534A CN 101195534 A CN101195534 A CN 101195534A CN A2007103020115 A CNA2007103020115 A CN A2007103020115A CN 200710302011 A CN200710302011 A CN 200710302011A CN 101195534 A CN101195534 A CN 101195534A
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Abstract
A method for preparing ceramsite light aggregate by utilizing sludge belongs to solid waste treatment, proposal and resource technical field, which produces dry sludge through thermal drying dehydrated mud cake whose moisture percentage is 75-85%, wherein the dry sludge is broken and sieved through 45 mm screen, 18-25% fly ash by mass of the dry sludge is charged to stir, the stirred hybrid material is injected in the powder tablet compressing machine to squeeze and mould under the pressure of 8 Mpa to obtain ceramsite light aggregate blank, the blank is heated to 350 DEG C and is stayed for 20 min in order to lead to volatilize and exhaust completely and is calcined under the temperature of 1080-1100 DEG C for 30 min and is cooled to indoor temperature naturally, and then the ceramsite light aggregate is obtained. The invention for processing living sewage and sludge improves strength of the calcined product, and saves the calcined energy consumption greatly. The obtained ceramsite light aggregate is compact in uranium face, light in weight, high in strength, and satisfies national standard GB/T17431.2-1998, which can be used in the projects such as buildings, roads, bridges and the like.
Description
Technical field
The present invention relates to a kind of method of utilizing mud to prepare porcelain granule light weight aggregate, relate in particular to the resource technology of producing the light skeletal haydite with municipal dewatered sludge mummification sintering, belong to solid waste disposal and dispose and the resource technology field.
Background technology
Municipal sludge contains abundant organism, and calorific value is up to more than the 3000kcal/kg; Its inorganic components and clay are similar, are a kind of good natural resourcess.Ban use of today of clay system building materials in Energy resources growing tension, country, utilize the mud substitute for clay to produce the class clay inorganic components that the building materials light skeletal has utilized the high heating value and the mud of mud simultaneously, turn waste into wealth, innoxious, minimizing that meets that China solid waste disposal disposes and resource utilization principle will have vast potential for future development.The mud system of utilization building materials light skeletal also has effects such as curing heavy metal and removal stench by the high temperature sintering effect.
The method of utilizing municipal dewatered sludge sintering to produce the light skeletal haydite begins the someone from the end of the eighties in last century to be studied, and existing many pieces of public technology bibliographical informations.In the prior art that has disclosed, report that (application number: 200510010579.0) the sludge drying sintering prepares the building porcelain granule light skeletal, but exist the mud admixture than the shortcomings such as clay that low, a large amount of use country bans use of, be not suitable for mass disposal disposing sludge and Sustainable development.Also have report (application number: 02104109.1) the secondary pollution specific aim research of sewage sludge sintering process heavy metal control, but also exist high sintering temperature, high admixture than clay, hang down admixture than shortcomings such as mud.Produce building materials along with country bans use of clay, have concurrently high mud admixture than, the innovative technology of admixture clay is not present research direction.
Summary of the invention
At existing process sludge admixture than low, sintering temperature is high and admixture the drawbacks such as clay that ban use of of country, the invention provides a kind ofly under the prerequisite that guarantees porcelain granule light weight aggregate product building materials performance, with mud be main raw material, 1080-1100 ℃ of low-temperature sintering of admixture clay do not produced light skeletal haydite method.And in using, sintered products the heavy metal stripping does not take place to second environmental pollution.
A kind of method of utilizing mud to prepare porcelain granule light weight aggregate, this method may further comprise the steps:
A, the dehydrated sludge cake of 75～85% water ratio is carried out heated drying obtain dewatered sludge;
B, with the described dewatered sludge fragmentation of step (1), sieved 45mm sieve;
C, will step (2) add the flyash of dewatered sludge quality 18～25% in the dewatered sludge after the screening, stir;
D, the mixing material after step (3) stirred inject powder compressing machine 8MPa extrusion molding and obtain the porcelain granule light weight aggregate blank;
E, sintering: earlier described shaping blank is heated to 350 ℃ and stopped 20 minutes, makes the organism eliminating of fully volatilizing; Under 1080～1100 ℃ of conditions, carried out roasting 30 minutes then;
F, naturally cool to room temperature, promptly obtain described porcelain granule light weight aggregate product.
The present invention adopts sintering method to handle sanitary sewage mud, it be simultaneously a kind of be the method that main raw material is made the light skeletal haydite with mud.The light skeletal haydite is to be formed by dewatered sludge and two kinds of feedstock production of flyash, and wherein the water ratio of dewatered sludge is between 75-85%; Dewatered sludge is at first carried out drying, broken, sieved the 45mm sieve after, the flyash that adds dewatered sludge quality 18-25% mixes, 8MPa extrusion molding, 350 ℃ of preheating 20min, fire 30min become product under 1080-1100 ℃ of condition.
Fusible salts contg height in the mud, melt temperature is low, compares leca and lytag, and the required sintering temperature of sludge ceramsite is low, has saved sintering energy consumption greatly.
The requirement of strength of sewage sludge sintering product is the principal element of restriction mud admixture ratio, and its reason mainly is that organic volatilization causes that the mud voidage is big, product strength is low in the mud.Add flyash and can effectively fill the sintered products internal voids, reduce porosity.Organic content accounts for mud contents on dry basis＜65% and item can obtain qualified product in this technology controlling and process dewatered sludge.
Flyash contains high content silicon, aluminium component, adds flyash and can also promote high-strength crystal generations mutually such as gehlenite, mullite and aluminum phosphate, further improves the intensity of sintered products.
Light skeletal ceramic product of the present invention is uranium face, the high-strength light that there is one deck densification on microvoid structure, surface that scarlet, inside have sealing, satisfies 800 grades of building materials requirements of light skeletal haydite of GB GB/T17431.2-1998 fully.In addition, use the present invention to produce the light skeletal ceramic product, the heavy metal in the raw material is difficult for separating out, thereby this product can be used in engineerings such as house, road surface, bridge.
Description of drawings
Fig. 1 is a sludge drying sintering process schema of the present invention.
Fig. 2 sintered products haydite synoptic diagram in kind.
Fig. 3 sintered products haydite internal pore structure scanning electron figure.
Heavy metal fixed rate figure in Fig. 4 sintering process.
Embodiment
Below in conjunction with embodiment municipal sludge drying sintering process of the present invention is further described.
With Beijing sewage work mechanical dehydration mud is example.This sewage work is primarily aimed at city domestic sewage, adopts traditional A/A/O returned sluge denitrification biological denitrogenation dephosphorization process, the mixing sludge of preliminary sedimentation tank and second pond through gravity concentrate+obtain dewatered sludge behind the mechanical dehydration, its fundamental characteristics is shown in Table 1.As shown in Table 1: mud is without digestion process, and organic content is very high, is unfavorable for the sintering processes of mud; The calorific value of mud butt is very high, reaches the calorific value of low grade coal, is fit to heat-treat; Because sewage is mainly derived from sanitary sewage, so heavy metal content is lower; The inorganic components and the clay of mud are similar.
Table 1 mud sample fundamental characteristics
| Project | Numerical value | Project | Numerical value | ||
| Water ratio/% | 80.6 | Organic content/% (accounting for butt) | 60.9 | ||
| Calorific value/kcal/kg (butt) | 3610 | Inorganic chemistry composition/% | SiO2 | 24.37 | |
| Heavy metal content/(mg/kg) | As | 21.4 | Al2O3 | 7.95 | |
| Cd | 3.4 | Fe2O3 | 6.09 | ||
| Cr | 16 | CaO | 10.68 | ||
| Cu | 84.56 | MgO | 10.69 | ||
| Ni | 13.32 | P2O5 | 32.98 | ||
| Pb | 979.6 | Na2O | 0.34 | ||
| Zn | 400.8 | K2O | 5.33 | ||
Fig. 1 is a sludge drying sintering process schema of the present invention.
Embodiment 1:
The flyash addition accounts for 18% of dewatered sludge quality in the present embodiment, 1080 ℃ of sintering temperatures.Preparation method's step is as follows:
A, at first dewatered sludge is carried out heated drying, adopted 180 ℃ of dryings of paddle-dryer 2 hours, obtain the dewatered sludge of water ratio＜10%;
The 45mm sieve is pulverized, sieved to b, Universalpulverizer;
C, add the flyash of dewatered sludge quality 18%, and, mix with cement paste stirrer stirring 5min according to the proportioning raw materials of this technology;
D, powder compressing machine 8MPa extrusion molding obtain light skeletal haydite blank;
E, 350 ℃ of preheating 20min, the purpose of preheating mainly is to reduce organic content in the blank, avoids sintering process blank cracking; 1080 ℃ of sintering 30min;
Obtain product behind f, the naturally cooling.
Embodiment 2:
The flyash addition accounts for 25% of dewatered sludge quality in the present embodiment, 1100 ℃ of sintering temperatures.Preparation method's step is as follows:
A, at first dewatered sludge is carried out heated drying, adopted 180 ℃ of dryings of paddle-dryer 2 hours, obtain the dewatered sludge of water ratio＜10%;
The 45mm sieve is pulverized, sieved to b, Universalpulverizer;
C, add the flyash of dewatered sludge quality 25%, and, mix with cement paste stirrer stirring 5min according to the proportioning raw materials of this technology;
D, powder compressing machine 8MPa extrusion molding obtain light skeletal haydite blank;
E, 350 ℃ of preheating 20min, the purpose of preheating mainly is to reduce organic content in the blank, avoids sintering process blank cracking; 1100 ℃ of sintering 30min;
Obtain product behind f, the naturally cooling.
Embodiment 3:
The flyash addition accounts for 20% of dewatered sludge quality in the present embodiment, 1090 ℃ of sintering temperatures.Preparation method's step is as follows:
A, at first dewatered sludge is carried out heated drying, adopted 180 ℃ of dryings of paddle-dryer 2 hours, obtain the dewatered sludge of water ratio＜10%;
The 45mm sieve is pulverized, sieved to b, Universalpulverizer;
C, add the flyash of dewatered sludge quality 20%, and, mix with cement paste stirrer stirring 5min according to the proportioning raw materials of this technology;
D, powder compressing machine 8MPa extrusion molding obtain light skeletal haydite blank;
E, 350 ℃ of preheating 20min, the purpose of preheating mainly is to reduce organic content in the blank, avoids sintering process blank cracking; 1090 ℃ of sintering 30min;
Obtain product behind f, the naturally cooling.
Fig. 2 sintered products haydite synoptic diagram in kind.Fig. 3 sintered products haydite internal pore structure scanning electron figure.
Building materials performance and heavy metal fixed characteristic to the sintering ceramsite product carries out analytical test below.
The building materials performance measurement of product the results are shown in shown in the following table 2.
Table 2 ceramic product mechanics performance determining result
| Sequence number | Project name | The self-control haydite | (GB/T17431.2-1998) 800 grades of haydite standards |
| 1 2 3 4 5 6 7 8 9 10 | Grain type tap density (kg/m 3) maximum particle diameter (mm) cylindrical compress strength (MPa) strength mark water-intake rate (%) silt content (%) loss on ignition (%) sulfide and sulphate content (press SO 3Meter, %) grain composition | Broken stone type 719-745 14.8-15.4 6.17-6.59 40 1.7-2.9 1.07-0.83 2.8-3.1 0.49-0.72 are qualified | 800 ranks 16.2＞6.0 〉=35≤8.0≤3.0≤5.0≤1.0 slightly |
This test-results shows that the sludge ceramsite product for preparing according to the technology of the present invention process program has reached " light-weight aggregate and test method thereof " (GB/T17431.2-1998) 800 grades of haydite standards, can do the load-bearing light skeletal.
Heavy metal fixed effect in the ceramisite sintered process is seen shown in Figure 4.The fixed rate of heavy metal is all more than 60% except that Pb, and as seen, sintering process is fine to the fixed effect of heavy metal.After Pb and a small amount of other heavy metal volatilization, spray charcoal absorption and sack cleaner and hold back method and can be effectively controlled by being provided with.
Leach liquor test-results to this sintered products is shown in Table 3.
Table 3 ceramic product leaching test result
| Project | GB5085.3-1996 Hazardous wastes judging standard (mg/L) | GB 3838-2002 surface water environment quality III class water quality standard (mg/L) | Mud leach liquor (mg/L) before the sintering | Sintered products leach liquor (mg/L) |
| The total chromium-copper of plumbous (in total lead) cadmium (in total cadmium) and compound (in total copper) nickel and compound (in total nickel) arsenic and compound (in total arsenic) zinc and compound (in total zinc) thereof | 3 0.3 10 50 10 1.5 50 | 0.05 0.05 0.05 1 - 0.05 1 | 0.0873 0.3204 0.3457 0.1582 0.0248 0.0564 1.8928 | 0.029-0.046 0.001-0.009 0.022-0.041 0.058-0.067 0.009-0.011 0.001-0.003 0.279-0.348 |
This test-results also shows: according to technical solution of the present invention, use the sewage treatment plant dewater sludge haydite that high temperature sintering drew behind drying and other treatment, a small amount of flyash of admixture, the leach liquor standard that heavy metal concentration (GB5085.3-1996) is stipulated far below " Hazardous wastes judging standard-leaching toxicity is differentiated " in its leach liquor, also satisfy the requirement of surface water III class water quality standard, illustrate that process roasting haydite is fine to the fixed effect of heavy metal, meet the condition of recycling.
Heavy metal content itself is just very low in the mud, can access abundant curing through after the sintering processes, sintered compact mainly should be as roadbed material and building aggregate, meeting and curing moldings such as cement, pitch in the use, and this can also further improve the solidification effect of heavy metal.
Above-mentioned test-results explanation technical solution of the present invention has realized purpose of the present invention.
Claims (1)
1. a method of utilizing mud to prepare porcelain granule light weight aggregate is characterized in that, this method may further comprise the steps:
(1) dehydrated sludge cake of 75～85% water ratio is carried out heated drying and obtain dewatered sludge;
(2) with the described dewatered sludge fragmentation of step (1), sieved 45mm sieve;
(3) with adding the flyash of dewatered sludge quality 18～25% in the dewatered sludge after step (2) screening, stir;
(4) mixing material after step (3) stirring is injected powder compressing machine 8MPa extrusion molding and obtain the porcelain granule light weight aggregate blank;
(5) sintering: earlier described shaping blank is heated to 350 ℃ and stopped 20 minutes, makes the organism eliminating of fully volatilizing; Under 1080～1100 ℃ of conditions, carried out roasting 30 minutes then;
(6) naturally cool to room temperature, promptly obtain described porcelain granule light weight aggregate.
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| CN200710302011A CN100584794C (en) | 2007-12-19 | 2007-12-19 | Method for producing porcelain granule light weight aggregate with sewage sludge |
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| CN200710302011A CN100584794C (en) | 2007-12-19 | 2007-12-19 | Method for producing porcelain granule light weight aggregate with sewage sludge |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671100A (en) * | 2009-09-18 | 2010-03-17 | 罗健泉 | Method for removing heavy metal of activated sludge by solid-phase technique |
| CN102070352A (en) * | 2010-11-22 | 2011-05-25 | 清华大学 | Method for recycling dewatered sludge, channel sediment and fly ash |
| CN102249584A (en) * | 2011-05-17 | 2011-11-23 | 惠州绿润环保科技有限公司 | Lightweight ceramicite prepared from municipal sludge and printing/dyeing sludge |
| CN102875003A (en) * | 2012-11-05 | 2013-01-16 | 天津城市建设学院 | Integrated technology of thermal decomposing, dry distilling and gasifying sludge and preparing of ceramsite |
| CN103319157A (en) * | 2013-07-10 | 2013-09-25 | 扬州大学 | Method for preparing sludge ceramsite by utilizing phase diagram |
| CN104140185A (en) * | 2014-08-06 | 2014-11-12 | 江西省广德环保科技有限公司 | Harmless recycling method for high-iron-chromium sludge |
| CN104496308A (en) * | 2014-12-09 | 2015-04-08 | 西安建筑科技大学 | Polypropylene fiber-sludge haydite concrete as well as preparation and application thereof |
| CN105000763A (en) * | 2015-06-22 | 2015-10-28 | 张萍 | Overall treatment method for sludge |
| CN105174994A (en) * | 2015-08-31 | 2015-12-23 | 宜昌朗天新型建材有限公司 | Method for preparing sludge ceramsite by regenerating pottery sand and flue dust |
| CN105819642A (en) * | 2016-05-03 | 2016-08-03 | 娈疯 | Sludge crystallization solidification treatment technology |
| CN106116194A (en) * | 2016-06-23 | 2016-11-16 | 含山县永帮再生资源利用有限公司 | A kind of waste residue that casts reclaims the high-strength lightweight of preparation |
| CN106242639A (en) * | 2016-08-16 | 2016-12-21 | 中电建水环境治理技术有限公司 | Bed mud carbonization haydite and preparation technology thereof are gushed in lake, river |
| CN106747611A (en) * | 2017-02-14 | 2017-05-31 | 福建师范大学 | A kind of preparation method of the alum sludge base porous ceramic grain of the kitchen garbage that adulterates |
| CN108500027A (en) * | 2017-02-24 | 2018-09-07 | 永续发展股份有限公司 | High-temperature melting continuous treatment method and equipment for waste |
| CN109053145A (en) * | 2018-10-17 | 2018-12-21 | 沈阳航空航天大学 | A kind of sludge mixing lightweight aggregate and its preparation process |
| CN110229014A (en) * | 2019-06-27 | 2019-09-13 | 上海大学 | A kind of lightweight aggregate and preparation method thereof being prepared using steel mill's sludge |
| CN112960966A (en) * | 2021-03-04 | 2021-06-15 | 中电建水环境科技有限公司 | Method for preparing high-strength lightweight aggregate by using municipal sludge |
| CN113698177A (en) * | 2021-09-28 | 2021-11-26 | 中海油田服务股份有限公司 | Method for preparing sintered ceramsite by utilizing offshore water-based drilling solid phase |
-
2007
- 2007-12-19 CN CN200710302011A patent/CN100584794C/en not_active Expired - Fee Related
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671100A (en) * | 2009-09-18 | 2010-03-17 | 罗健泉 | Method for removing heavy metal of activated sludge by solid-phase technique |
| CN102070352A (en) * | 2010-11-22 | 2011-05-25 | 清华大学 | Method for recycling dewatered sludge, channel sediment and fly ash |
| CN102249584A (en) * | 2011-05-17 | 2011-11-23 | 惠州绿润环保科技有限公司 | Lightweight ceramicite prepared from municipal sludge and printing/dyeing sludge |
| CN102875003A (en) * | 2012-11-05 | 2013-01-16 | 天津城市建设学院 | Integrated technology of thermal decomposing, dry distilling and gasifying sludge and preparing of ceramsite |
| CN103319157A (en) * | 2013-07-10 | 2013-09-25 | 扬州大学 | Method for preparing sludge ceramsite by utilizing phase diagram |
| CN104140185A (en) * | 2014-08-06 | 2014-11-12 | 江西省广德环保科技有限公司 | Harmless recycling method for high-iron-chromium sludge |
| CN104496308A (en) * | 2014-12-09 | 2015-04-08 | 西安建筑科技大学 | Polypropylene fiber-sludge haydite concrete as well as preparation and application thereof |
| CN105000763A (en) * | 2015-06-22 | 2015-10-28 | 张萍 | Overall treatment method for sludge |
| CN105174994A (en) * | 2015-08-31 | 2015-12-23 | 宜昌朗天新型建材有限公司 | Method for preparing sludge ceramsite by regenerating pottery sand and flue dust |
| CN105819642A (en) * | 2016-05-03 | 2016-08-03 | 娈疯 | Sludge crystallization solidification treatment technology |
| CN106116194A (en) * | 2016-06-23 | 2016-11-16 | 含山县永帮再生资源利用有限公司 | A kind of waste residue that casts reclaims the high-strength lightweight of preparation |
| CN106242639A (en) * | 2016-08-16 | 2016-12-21 | 中电建水环境治理技术有限公司 | Bed mud carbonization haydite and preparation technology thereof are gushed in lake, river |
| CN106242639B (en) * | 2016-08-16 | 2018-04-10 | 中电建水环境治理技术有限公司 | Gush bed mud carbonization haydite and its preparation technology in river lake |
| CN106747611A (en) * | 2017-02-14 | 2017-05-31 | 福建师范大学 | A kind of preparation method of the alum sludge base porous ceramic grain of the kitchen garbage that adulterates |
| CN108500027A (en) * | 2017-02-24 | 2018-09-07 | 永续发展股份有限公司 | High-temperature melting continuous treatment method and equipment for waste |
| CN109053145A (en) * | 2018-10-17 | 2018-12-21 | 沈阳航空航天大学 | A kind of sludge mixing lightweight aggregate and its preparation process |
| CN110229014A (en) * | 2019-06-27 | 2019-09-13 | 上海大学 | A kind of lightweight aggregate and preparation method thereof being prepared using steel mill's sludge |
| CN112960966A (en) * | 2021-03-04 | 2021-06-15 | 中电建水环境科技有限公司 | Method for preparing high-strength lightweight aggregate by using municipal sludge |
| CN113698177A (en) * | 2021-09-28 | 2021-11-26 | 中海油田服务股份有限公司 | Method for preparing sintered ceramsite by utilizing offshore water-based drilling solid phase |
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| CN100584794C (en) | 2010-01-27 |
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