CN101186479A - Method for preparing ultra-high strength mortar - Google Patents

Method for preparing ultra-high strength mortar Download PDF

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Publication number
CN101186479A
CN101186479A CNA2007101589009A CN200710158900A CN101186479A CN 101186479 A CN101186479 A CN 101186479A CN A2007101589009 A CNA2007101589009 A CN A2007101589009A CN 200710158900 A CN200710158900 A CN 200710158900A CN 101186479 A CN101186479 A CN 101186479A
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percent
cement
water
mortar
defoamer
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CNA2007101589009A
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CN100554208C (en
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徐世烺
高良丽
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Hangzhou Guyiqiang New Material Technology Co ltd
Zhejiang Zhongrui New Material Technology Co ltd
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Dalian University of Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention pertains to the technical field of constructional materials, which relates to a preparation method of super-high-strength mortar. The invention is characterized in that the weight percentages of raw materials and all the components thereof are that: 35 percent to 50 percent of concrete, 5 percent to 15 percent of silicon powder, 25 percent to 35 percent of silica sand, 3 percent to 10 percent of quartz sand, 0.1 percent to 0.2 percent of foam killer, 7 percent to 14 percent of water and water reducing agent is 1.5 percent to 4.5 percent of the sum of the mass of the concrete and the silicon powder (namely, gelled material), and the gross of the components reaches 100 percent; a variable speed stirrer is used for stirring, which is speeded up by changing gear and then positioned on a vibration table or inserted with a vibratory tamper for vibration and the maintenance process of existing concrete with high performance is used for maintenance. The intensity of the super-high-strength mortar of the invention can reach 150MPa and the invention has the advantages of ready availability of raw materials, simple preparation technique, being easy to be realized in construction site and being suitable for engineering.

Description

A kind of preparation method of ultra-high strength mortar
Technical field
The invention belongs to building material technical field, relate to a kind of preparation method of ultra-high strength mortar.
Background technology
The building of some engineering constructions, particularly erosion environment, as the ground of buildingss such as chemical plant, food processing plant, freezer, Heavy Machines Plant and the construction of harbour and ocean platform, radioactive waste storage vessel etc., need the ultra-high strength mortar that great amount of cost is lower, can prepare at the construction field (site).
The preparation of existing domestic and international ultra-high strength mortar, be to adopt levigate portland cement, the silicon ash (or slag, flyash etc.) of ultra-fine grain, meticulous quartz sand (or other high-quality fine aggregate mostly, as Stainless Steel Powder), composition such as water and superplasticizer, during moulding by applying form removal after room temperature leaves standstill 1 day behind certain pressure, use 80 ℃ or above hot water bath maintenance room temperature maintenance several days after a day, again 1 day postcooling of high temperature (about 200 ℃) dry heating curing to the room temperature maintenance to the length of time, ultimate compression strength reaches more than 150 MPas.Though the mortar intensity height of this technology preparation, cost height, complex process are not suitable for engineering and use, and only limit to make the prefabrications such as mould of some instrument, thermoplastic resin at present.
The preparation of a kind of ultra-high strength mortar of document " Tensile properties of fibre-reforced very high strength DSPmortar (Magzine of Concrete Research; 2000; 52; No.2; Apr.; 101~108) " narration improves on technology, and its material is 400~450m by specific surface area 2The white portland cement of/kg, silicon ash, powdery superplasticizer, meticulous quartz sand, water are formed, stir the back 75 hertz of shaking table vibratory compactions, 80 ℃ of hot water bath maintenances are 24 hours after the form removal in 24 hours, again in testing laboratory's condition maintenance to the length of time, making the minimum ultimate compression strength of 75mm * 150mm right cylinder is 150 MPas.This method cost is still high, technology is complicated, still is difficult at the construction field (site) realize; Because being 62.5 cement specific surface area, domestic best label also can only reach 380.6m 2/ kg, the preparation of this mortar also needs import cement.
Because prior art prepares the difficulty of ultra-high strength mortar at the construction field (site), strength on concrete material at present for building is low, degree of compactness is little, and being used for some needs the engineering construction of the strong high compact material of superelevation unsatisfactory.
Summary of the invention
Purpose of the present invention is to provide a kind of preparation method of ultra-high strength mortar, and this mortar is with low cost, is convenient to the working-yard preparation, and its intensity can reach 140-150 MPa (MPa), engineering construction that can the strong high compact material of dealing with various requirements superelevation.
A kind of preparation method of ultra-high strength mortar, it is characterized in that raw material is cement, silicon ash, silica sand, quartz sand, defoamer, water and water reducer, the mass percent of its each component is: cement 35%~50%, silicon ash 5%~15%, silica sand 25%~35%, quartz sand 3%~10%, defoamer 0.1%~0.2%, water 7%~14%, water reducer are 1.5%~4.5% of cement and silicon ash (being gelling material) quality sum, and the each component total amount satisfies 100%;
In the above-mentioned materials, cement is the silicate cement of label 62.5,62.5R, 52.5,52.5R, and the fineness of silica sand is 20~40 orders, and the fineness of quartz sand is 100~200 orders, defoamer is tricresyl phosphate tincture ester or SP-202 series water-based defoamer, and water reducer is a polycarboxylate dehydragent;
Stirring the method for making this ultra-high strength mortar is: adopt the speed change stirrer, in 80 rev/mins~350 rev/mins scopes, promote stirring velocity by shelves, churning time is 10 to 25 minutes, and the mortar that stirs is poured in the mould, places on the shaking table or insert vibrating spear vibration 2~10 minutes; Maintenance process is: when building-site is constructed, adopt existing high performance concrete maintenance process, and the promptly preceding 3 days every 1-2 hour back overlay film that waters, water the back overlay film sooner or later to the length of time every day after 3 days; When making in laboratory, overlay film form removal after about 24 hours is put into the normal-temperature water maintenance to the length of time.
Adopt building trade to make concrete or mortar shaking table or vibrating spear commonly used, 50 hertz of the domestic general employings of vibrational frequency; In building-site construction, when mould more maybe can't be mobile, can adopt the vibrating spear vibration.
Prior art adopts the high temperature maintenance, is in order to promote the volcanic ash effect, thereby improves intensity.Consider the field conduct difficulty, the present invention is conceived to stirring technique, improve and just on macroscopic scale, reached uniform stirring in the past, adopt the speed change stirrer, by the shelves speedup, reach the even of microscopic scale by high-speed stirring, promoted the extent of hydration of cement, thereby improved intensity, realized preparing ultra-high strength mortar with conventional maintenance process maintenance.
Mortar standardized component of the present invention carries out the cubic compressive strength experiment by GB/T 50081-2002 chapter 6, and intensity can reach 140-150Mpa, about 2.4 gram per centimeters of density 3
Except silicate cement, also can adopt other kind cement such as ordinary Portland cement, Portland blast, Portland pozzolana cement, Portland fly ash cement, composite Portland cement of same numeral (being same intensity) to make ultra-high strength mortar of the present invention, the major ingredient of these cement is similarly Portland clinker.When adopting other kind cement, can be with reference to silicate cement mass percent of the present invention, and the volume of other mineral mixing materials in this kind cement, determine the mass percent of this kind cement in mortar.
The present invention has the following advantages:
1, good fluidity, flawless, pore is few and little, the internal structure densification, molded surface is smooth, the intensity height, the value of its strength/density and steel quite, have impermeability and resistance to abrasion preferably.
2, selected materials is mass-produced commercially available prod, and starting material are easy to get.
3, with respect to other ultra-high strength mortars, preparation technology of the present invention is simple and be easy to realize in that engineering construction is on-the-spot, is suitable for through engineering approaches.
Embodiment
Below in conjunction with embodiment technical scheme of the present invention is further described.All whipping steps all adopt the speed change stirrer, and standard cube body mortar specimen is adopted in strength test, and its curing age is 28 days, carry out the cubic compressive strength experiment by GB/T 50081-2002 chapter 6.
Embodiment 1, mortar raw material and each component raw material per-cent are: silicate cement (P.II 62.5) 35%, silicon ash 13%, silica sand (20~40 order) 35%, quartz sand (the mark fineness is 150 orders) 6%, defoamer (SP-202) 0.2%, water 9.6%, polycarboxylate dehydragent (Sika-III) is 2.5% of cement and silicon ash (being gelling material) quality sum, promptly 1.2% of total amount.
When stirring raw material, promote stirring velocity by shelves in 80 rev/mins~350 rev/mins scopes, churning time is 15 minutes, the mortar that stirs is poured in the mould, placed on the shaking table and vibrate 5 minutes, vibrational frequency is 50Hz, overlay film to 24 hour is put into the normal-temperature water maintenance after the form removal.
After tested, 28 of this mortar days ultimate compression strength is 148.3MPa.
Embodiment 2, mortar raw material and each component raw material per-cent are: silicate cement (P.II 62.5R) 42%, silicon ash 15%, silica sand (20~40 order) 25%, quartz sand (the mark fineness is 150 orders) 5.5%, defoamer (SP-202) 0.2%, water 10.3%, polycarboxylate dehydragent (Sika-III) is 3.5% of cement and silicon ash (being gelling material) quality sum, promptly 2.0% of total amount.
When stirring raw material, promote stirring velocity by shelves in 80 rev/mins~350 rev/mins scopes, churning time is 25 minutes, the mortar that stirs is poured in the mould, placed on the shaking table and vibrate 10 minutes, vibrational frequency is 50 Hz, overlay film to 24 hour is put into the normal-temperature water maintenance after the form removal.
After tested, 28 of this mortar days ultimate compression strength is 158.8MPa.
Embodiment 3, mortar raw material and each component raw material per-cent are: silicate cement (P.II 62.5) 40.8%, silicon ash 5%, silica sand (20~40 order) 35%, quartz sand (the mark fineness is 100~200 orders) 10%, defoamer (SP-202) 0.1%, water 7%, polycarboxylate dehydragent (Sika-III) is 4.5% of cement and silicon ash (being gelling material) quality sum, promptly 2.1% of total amount.
When stirring raw material, promote stirring velocity by shelves in 80 rev/mins~350 rev/mins scopes, churning time is 20 minutes, the mortar that stirs is poured in the mould, placed on the shaking table and vibrate 6 minutes, vibrational frequency is 50Hz, overlay film to 24 hour is put into the normal-temperature water maintenance after the form removal.
After tested, 28 of this mortar days ultimate compression strength is 149.2MPa.
Embodiment 4, mortar raw material and each component raw material per-cent are: silicate cement (P.II 52.5R) 50%, silicon ash 10%, silica sand (20~40 order) 25%, quartz sand (the mark fineness is 150 orders) 3%, defoamer (tricresyl phosphate tincture ester) 0.1%, water 11%, polycarboxylate dehydragent (Sika-III) is 1.5% of cement and silicon ash (being gelling material) quality sum, promptly 0.9% of total amount.
When stirring raw material, promote stirring velocity by shelves in 80 rev/mins~350 rev/mins scopes, churning time is 23 minutes, the mortar that stirs is poured in the mould, placed on the shaking table and vibrate 8 minutes, vibrational frequency is 50Hz, overlay film to 24 hour is put into the normal-temperature water maintenance after the form removal.
After tested, 28 of this mortar days ultimate compression strength is 157.6MPa.
Embodiment 5, mortar raw material and each component raw material per-cent are: silicate cement (P.II 52.5) 45%, silicon ash 5%, silica sand (20~40 order) 30%, quartz sand (the mark fineness is 150 orders) 10%, defoamer (tricresyl phosphate tincture ester) 0.2%, water 8.8%, polycarboxylate dehydragent (Sika-III) is 2.0% of cement and silicon ash (being gelling material) quality sum, promptly 1.0% of total amount;
When stirring raw material, promote stirring velocity by shelves in 80 rev/mins~350 rev/mins scopes, churning time is 10 minutes, the mortar that stirs is poured in the mould, placed on the shaking table and vibrate 2 minutes, vibrational frequency is 50Hz, overlay film to 24 hour is put into the normal-temperature water maintenance after the form removal.
After tested, 28 of this mortar days ultimate compression strength is 143.5MPa.
Embodiment 6, mortar raw material and each component raw material per-cent are: silicate cement (P.II 52.5R) 50%, silicon ash 6.17%, silica sand (20~40 order) 25%, quartz sand (the mark fineness is 150 orders) 3%, defoamer (tricresyl phosphate tincture ester) 0.15%, water 14%, polycarboxylate dehydragent (Sika-III) is 3.0% of cement and silicon ash (being gelling material) quality sum, promptly 1.68% of total amount.
When stirring raw material, promote stirring velocity by shelves in 80 rev/mins~350 rev/mins scopes, churning time is 15 minutes, the mortar that stirs is poured in the mould, insert vibrating spear vibration 10 minutes, vibrational frequency is 50Hz, adopts existing high performance concrete maintenance process maintenance to the length of time.
After tested, 28 of this mortar days ultimate compression strength is 153.8MPa.

Claims (1)

1. the preparation method of a ultra-high strength mortar, it is characterized in that raw material is cement, silicon ash, silica sand, quartz sand, defoamer, water and water reducer, the mass percent of its each component is: cement 35%~50%, silicon ash 5%~15%, silica sand 25%~35%, quartz sand 3%~10%, defoamer 0.1%~0.2%, water 7%~14%, water reducer are 1.5%~4.5% of cement and silicon ash quality sum, and the each component total amount satisfies 100%;
In the above-mentioned materials, cement is the silicate cement of label 62.5,62.5R, 52.5,52.5R, and the fineness of silica sand is 20~40 orders, and the fineness of quartz sand is 100~200 orders, defoamer is tricresyl phosphate tincture ester or SP-202 series water-based defoamer, and water reducer is a polycarboxylate dehydragent;
Adopt the speed change stirrer to stir raw material, promote a stirring velocity by shelves in 80 rev/mins~350 rev/mins scopes, churning time is 10 to 25 minutes, and the mortar that stirs is poured in the mould, places on the shaking table or inserts vibrating spear vibration 2~10 minutes; Maintenance process is: when building-site is constructed, adopt existing high performance concrete maintenance process; When making in laboratory, overlay film form removal after about 24 hours is put into the normal-temperature water maintenance to the length of time.
CNB2007101589009A 2007-12-11 2007-12-11 A kind of preparation method of ultra-high strength mortar Active CN100554208C (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101367634B (en) * 2008-09-28 2011-11-23 刘新发 Method of preparing mortar additive, mortar additive and method for preparing mortar by employing the same
CN102372470A (en) * 2010-08-23 2012-03-14 汪峻峰 Preparation method of high-performance mortar
CN102409822A (en) * 2011-11-04 2012-04-11 张鹏 Heat-insulating decorative composite board and manufacturing method thereof
CN102584132A (en) * 2012-01-03 2012-07-18 安徽万诚达新型材料有限公司 Sealing anchor mortar dry blend for high-speed railway
CN102731044A (en) * 2012-07-10 2012-10-17 上海朗兆公路铁路养护工程技术有限公司 Low-temperature ultrahigh-strength inorganic multi-purpose mortar
CN103601431A (en) * 2013-11-22 2014-02-26 苏州科技学院 Masonry mortar dry powder based on autoclaved fly ash aerated concrete waste
CN105992681A (en) * 2013-12-10 2016-10-05 江原大学校产学协力团 Apparatus for producing rapid-hardening concrete by intermixing and dissipating air in normal concrete and adding early-strength admixture thereto, and method for producing same
EP2543649B1 (en) * 2011-07-06 2018-08-08 Thomas Teichmann Extremely resistant concrete
CN109851303A (en) * 2019-03-06 2019-06-07 唐山北极熊建材有限公司 Corrosion-resistant ultra-high performance concrete of lower shrinkage and preparation method thereof, construction method and application
WO2019153808A1 (en) * 2018-02-08 2019-08-15 中国矿业大学 Construction method for high-ductility masonry wall having reinforced joint mortar layer
CN110282917A (en) * 2019-07-17 2019-09-27 广西大学 A kind of preparation method of bagasse lime and brick
CN110330297A (en) * 2019-06-26 2019-10-15 武汉理工大学 Solidify sulphoaluminate cement base curing materials and its curing method containing low radioactive waste liquid in high concentration of boric acid
CN110877968A (en) * 2019-11-04 2020-03-13 东北大学 Cement-based composite material using iron tailings and preparation method thereof
CN111099863A (en) * 2019-12-19 2020-05-05 苏州国中新材料研究院有限公司 Carbon fiber reinforced high-strength mortar, preparation method and construction method
CN111896151A (en) * 2020-08-04 2020-11-06 工科思维技术(深圳)有限公司 Preparation method of intelligent building sensor with pressure-sensitive performance
CN117510158A (en) * 2023-11-13 2024-02-06 山东大学 Ultra-high performance concrete and preparation method and application thereof

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101367634B (en) * 2008-09-28 2011-11-23 刘新发 Method of preparing mortar additive, mortar additive and method for preparing mortar by employing the same
CN102372470A (en) * 2010-08-23 2012-03-14 汪峻峰 Preparation method of high-performance mortar
CN102372470B (en) * 2010-08-23 2013-05-08 汪峻峰 Preparation method of high-performance mortar
EP2543649B1 (en) * 2011-07-06 2018-08-08 Thomas Teichmann Extremely resistant concrete
CN102409822A (en) * 2011-11-04 2012-04-11 张鹏 Heat-insulating decorative composite board and manufacturing method thereof
CN102584132A (en) * 2012-01-03 2012-07-18 安徽万诚达新型材料有限公司 Sealing anchor mortar dry blend for high-speed railway
CN102731044A (en) * 2012-07-10 2012-10-17 上海朗兆公路铁路养护工程技术有限公司 Low-temperature ultrahigh-strength inorganic multi-purpose mortar
CN103601431A (en) * 2013-11-22 2014-02-26 苏州科技学院 Masonry mortar dry powder based on autoclaved fly ash aerated concrete waste
CN105992681A (en) * 2013-12-10 2016-10-05 江原大学校产学协力团 Apparatus for producing rapid-hardening concrete by intermixing and dissipating air in normal concrete and adding early-strength admixture thereto, and method for producing same
US10207233B2 (en) 2013-12-10 2019-02-19 Kangwon National University University-Industry Cooperation Foundation Apparatus for producing rapid-hardening concrete by intermixing and dissipating air in normal concrete and adding early-strength admixture thereto, and method for producing same
WO2019153808A1 (en) * 2018-02-08 2019-08-15 中国矿业大学 Construction method for high-ductility masonry wall having reinforced joint mortar layer
CN109851303A (en) * 2019-03-06 2019-06-07 唐山北极熊建材有限公司 Corrosion-resistant ultra-high performance concrete of lower shrinkage and preparation method thereof, construction method and application
CN110330297A (en) * 2019-06-26 2019-10-15 武汉理工大学 Solidify sulphoaluminate cement base curing materials and its curing method containing low radioactive waste liquid in high concentration of boric acid
CN110330297B (en) * 2019-06-26 2021-11-09 武汉理工大学 Sulphoaluminate cement-based curing material for curing low-level waste liquid in high-concentration boric acid and curing method thereof
CN110282917A (en) * 2019-07-17 2019-09-27 广西大学 A kind of preparation method of bagasse lime and brick
CN110877968A (en) * 2019-11-04 2020-03-13 东北大学 Cement-based composite material using iron tailings and preparation method thereof
CN111099863A (en) * 2019-12-19 2020-05-05 苏州国中新材料研究院有限公司 Carbon fiber reinforced high-strength mortar, preparation method and construction method
CN111896151A (en) * 2020-08-04 2020-11-06 工科思维技术(深圳)有限公司 Preparation method of intelligent building sensor with pressure-sensitive performance
CN117510158A (en) * 2023-11-13 2024-02-06 山东大学 Ultra-high performance concrete and preparation method and application thereof

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