CN101186334A - Method for preparing lightfastness titanium dioxide - Google Patents
Method for preparing lightfastness titanium dioxide Download PDFInfo
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- CN101186334A CN101186334A CNA2007101910235A CN200710191023A CN101186334A CN 101186334 A CN101186334 A CN 101186334A CN A2007101910235 A CNA2007101910235 A CN A2007101910235A CN 200710191023 A CN200710191023 A CN 200710191023A CN 101186334 A CN101186334 A CN 101186334A
- Authority
- CN
- China
- Prior art keywords
- titanium dioxide
- value
- add
- decorative paper
- lightfastness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 29
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 7
- 239000011574 phosphorus Substances 0.000 claims abstract description 7
- 239000012266 salt solution Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003513 alkali Substances 0.000 claims abstract description 4
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 150000003754 zirconium Chemical class 0.000 claims abstract description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 3
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 11
- 238000011417 postcuring Methods 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 6
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 159000000013 aluminium salts Chemical class 0.000 claims description 3
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims description 2
- 235000010215 titanium dioxide Nutrition 0.000 claims 15
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims 2
- 239000000243 solution Substances 0.000 abstract description 15
- 230000014759 maintenance of location Effects 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 5
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 description 5
- 230000000176 photostabilization Effects 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000001117 sulphuric acid Substances 0.000 description 5
- 235000011149 sulphuric acid Nutrition 0.000 description 5
- 238000010792 warming Methods 0.000 description 4
- MNEIPOIFQCXXGM-UHFFFAOYSA-M O.O.O.[OH-].[Na+] Chemical compound O.O.O.[OH-].[Na+] MNEIPOIFQCXXGM-UHFFFAOYSA-M 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000630 rising effect Effects 0.000 description 3
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 1
- 230000002186 photoactivation Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- -1 sodium aluminates Chemical class 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Landscapes
- Paper (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The invention relates to a preparation method for producing titanium dioxide, and is used in such fields as decorative paper, etc., in particular relating to a preparation method for producing a light resistance titanium dioxide. The method includes the following steps: a. rutile titanium dioxide is added with deionized water and dispersant to prepare slurry, then the PH value of the slurry is regulated less than 4; b. zirconium salt solution is added with the weight being 0.3-1.5 percent of the weight of the titanium dioxide; c. alkali solution is added at 50-70 DEG C and the PH value is modulated to 7-8.5, then a compound of phosphorus is added with the weight being 1-2 percent of the weight of the titanium dioxide and the PH value is controlled at 8-10 while the temperature of the slurry is controlled at 60-80 DEG C; d. aluminum salt solution and corresponding neutralization reagent are added and the PH value is maintained at 8-10, and after curing, the needed titanium dioxide is achieved through filtration, washing, drying and smashing. The invention has the advantage of improving the retention of the titanium dioxide in the decorative paper and the light resistance of the decorative paper.
Description
Technical field
The present invention relates to a kind of preparation method who is used for the titanium dioxide in fields such as decorative paper, specifically is a kind of preparation method of lightfastness titanium dioxide.
Background technology
Titanium dioxide is a kind of white pigment of performance brilliance, can be widely used in fields such as coating, plastics, papermaking, printing ink, catalyzer and the cosmetics of super quality.In paper industry, decorative paper is a titanium dioxide large usage quantity occasion, consumption can reach 20-45%, be widely used in decorative sheet, laminated flooring, office and furniture with surface lining etc., these occasions require must use to be had the weather resistance and the anti-xanthochromia ability titanium dioxide of getting well and processes, to satisfy the fast light heat-stable performance of decorative paper.
Surface treatment can change the surface property of titanium dioxide, covers the photoactivation point on titanium dioxide surface, stops titanium dioxide organism direct and in the dispersion medium to contact, to improve its weathering resistance.Common sial superpacket coating method is to add dispersion agent in tio_2 suspension, make slurry then at a certain temperature, mix with treatment agents such as water glass and sodium aluminates, regulate the pH value, make silicon oxide and precipitation of alumina in titanium dioxide particulate surface, filter then, wash, dry, the comminution by gas stream titanium dioxide product after obtaining coating.Because the SiO of product surface
2The difficult control of the compactness extent of coating layer, its photostabilization of using in decorative paper also is affected.
Summary of the invention
Technical problem to be solved by this invention provides a kind of production that can be used in products such as decorative paper, have the preparation method of retention and sunproof lightfastness titanium dioxide preferably.
Method of the present invention may further comprise the steps successively:
A. use not surface treated sulfuric acid process Rutile type Titanium Dioxide, add deionized water and dispersion agent and make the slurry that concentration is about 200-300g/l, regulate below the pH value to 4;
B. add and account for titanium dioxide weight 0.3-1.5% (with ZrO
2Meter) zirconium salt solution, operable zirconates has zirconyl sulfate, basic zirconium chloride etc., and preferred consumption is 0.5-1.0%;
C. under temperature is 50-70 ℃ condition, add alkali lye, regulate the pH value, the slaking regular hour, add and account for titanium dioxide weight 1-2% (with P to 7-8.5
2O
5The compound of phosphorus meter), the available compound comprises phosphoric acid, Sodium hexametaphosphate 99 and phosphoric acid salt etc., preferred consumption is 1-1.5%, the slaking regular hour, regulate the pH value to 8-10, slurry temperature is controlled at 60-80 ℃;
D. add aluminum salt solution and corresponding neutralization reagent, keep the pH value at 8-10, aluminium salt can be selected sodium aluminate, Tai-Ace S 150 etc., and dosage is that the 3-6% of titanium dioxide weight is (with Al
2O
3Meter), adds the post curing certain hour, filter, wash, dry and pulverize and obtain required titanium dioxide.
The invention has the advantages that and to improve the retention of titanium dioxide in decorative paper and the photostabilization of decorative paper.
Embodiment
Embodiment one:
Get scattered concentration and be about slurry about 300g/l, add sulphur acid for adjusting pH value to 3, be warming up to 50 ℃, add and account for titanium dioxide 0.6% (with ZrO
2Meter) zirconyl sulfate solution slowly adds the oxygen sodium hydroxide solution then and regulates slurry pH value to 8, slaking 30 minutes, and adding accounts for titanium dioxide 1.2% (with P again
2O
5Meter) sodium hexametaphosphate solution stirred slaking 20 minutes, readjusted slurry pH value to 9, and rising slurry temperature to 70 ℃ adds simultaneously and accounts for titanium dioxide 4% (with Al
2O
3Meter) sodium aluminate solution and dilute sulphuric acid, maintenances slurry pH value is 9-9.5, adds post curing 30 minutes, regulates pH value to 7, filters, washing, drying and pulverizing, obtains required titanium dioxide.
Embodiment two:
Get scattered concentration and be about slurry about 300g/l, add sulphur acid for adjusting pH value to 4, be warming up to 60 ℃, add and account for titanium dioxide 1.5% (with ZrO
2Meter) zirconium oxychloride solution slowly adds the oxygen sodium hydroxide solution then and regulates slurry pH value to 7, slaking 30 minutes, and adding accounts for titanium dioxide 1% (with P again
2O
5Meter) phosphoric acid solution stirred slaking 20 minutes, readjusted slurry pH value to 8, and rising slurry temperature to 80 ℃ adds simultaneously and accounts for titanium dioxide 3% (with Al
2O
3Meter) sodium aluminate solution and dilute sulphuric acid, maintenances slurry pH value is 8-8.5, adds post curing 30 minutes, regulates pH value to 7, filters, washing, drying and pulverizing, obtains required titanium dioxide.
Embodiment three:
Get scattered concentration and be about slurry about 300g/l, add sulphur acid for adjusting pH value to 3, be warming up to 70 ℃, add and account for titanium dioxide 0.5% (with ZrO
2Meter) zirconyl sulfate solution slowly adds the oxygen sodium hydroxide solution then and regulates slurry pH value to 8.5, slaking 30 minutes, and adding accounts for titanium dioxide 2% (with P again
2O
5Meter) sodium hexametaphosphate solution stirred slaking 20 minutes, readjusted slurry pH value to 9.5, and rising slurry temperature to 80 ℃ adds simultaneously and accounts for titanium dioxide 6% (with Al
2O
3Meter) sodium aluminate solution and dilute sulphuric acid, maintenances slurry pH value is 9.5-10, adds post curing 30 minutes, regulates pH value to 7, filters, washing, drying and pulverizing, obtains required titanium dioxide.
Comparative Examples:
Get scattered concentration and be about slurry about 300g/l, add sodium hydroxide and regulate pH value to 10, be warming up to 80 ℃, adding accounts for titanium dioxide 1% (with SiO
2Meter) sodium silicate solution adds dilute sulphuric acid simultaneously, and the maintenance slurry pH value is 9.5-10, adds post curing 30 minutes, regulates slurry pH value to 8, adds to account for titanium dioxide 3% (with Al again
2O
3Meter) sodium aluminate solution and dilute sulphuric acid, maintenances slurry pH value is 8-8.5, adds post curing 30 minutes, regulates pH value to 7, filters, washing, drying and pulverizing, obtains required titanium dioxide.
Sample after getting 4g and pulverizing and 300g paper pulp filter and copy paper with after 400ml water high-speed stirring is mixed, and paper is dried, and the crucible calcination that places constant weight is calculated retention behind the measurement ash content.The retention of example 1-3 and Comparative Examples is as follows:
The paper of copying is put into ultraviolet accelerated deterioration instrument, is accelerated deterioration 5 hours under 70 ℃ the condition in temperature, and the colour-change Δ E that measures paper weighs the photostabilization of paper, and Δ E is little, and photostabilization is good.The Δ E data of example 1-3 and Comparative Examples are as follows:
This shows, adopt the inventive method that titanium dioxide is carried out surface treatment, can improve retention and the photostabilization of titanium dioxide in decorative paper.
Claims (7)
1. the preparation method of a used for decorative paper lightfastness titanium dioxide, it is characterized in that: this method may further comprise the steps successively,
A. use not surface treated sulfuric acid process Rutile type Titanium Dioxide, add deionized water and dispersion agent and make the slurry that concentration is 200-300g/l, regulate below the pH value to 4;
B. add zirconium salt solution, the add-on of zirconates is with ZrO
2Meter accounts for the 0.3-1.5% of titanium dioxide weight, in temperature is to add alkali lye under 50-70 ℃ the condition, regulates the pH value to 7-8.5, slaking;
C. the compound that adds phosphorus, the compound add-on of phosphorus is with P
2O
5Meter accounts for the 1-2% of titanium dioxide weight, after the slaking, regulates the pH value to 8-10, and slurry temperature is controlled at 60-80 ℃;
D. add aluminum salt solution and corresponding neutralization reagent, keep the pH value at 8-10, the add-on of aluminium salt is with Al
2O
3Meter accounts for the 3-6% of titanium dioxide weight, adds post curing, filters, washs, dry and pulverize and obtain required titanium dioxide.
2. the preparation method of used for decorative paper lightfastness titanium dioxide according to claim 1, it is characterized in that: described step a is, use not surface treated sulfuric acid process Rutile type Titanium Dioxide, add deionized water and dispersion agent and make the slurry that concentration is about 200-300g/l, regulate below the pH value to 3.
3. according to the preparation method of used for decorative paper lightfastness titanium dioxide according to claim 1, it is characterized in that: described step b is, adds zirconium salt solution, and the add-on of zirconates is with ZrO
2Meter accounts for the 0.5-1.0% of titanium dioxide weight, in temperature is to add alkali lye under 50-60 ℃ the condition, regulates the pH value to 7-8.5, slaking.
4. according to the preparation method of used for decorative paper lightfastness titanium dioxide according to claim 1, it is characterized in that: described step c is, adds the compound of phosphorus, and the compound add-on of phosphorus is with P
2O
5Meter accounts for the 1-1.5% of titanium dioxide weight, after the slaking, regulates the pH value to 8-10, and slurry temperature is controlled at 70-80 ℃.
5. according to the preparation method according to claim 1 or 3 described used for decorative paper lightfastness titanium dioxides, it is characterized in that: the zirconates among the step b is zirconyl sulfate or basic zirconium chloride.
6. according to the preparation method according to claim 1 or 4 described used for decorative paper lightfastness titanium dioxides, it is characterized in that: the compound of the phosphorus among the step c is phosphoric acid or Sodium hexametaphosphate 99 or phosphoric acid salt.
7. according to the preparation method of used for decorative paper lightfastness titanium dioxide according to claim 1, it is characterized in that: the aluminium salt in the steps d is sodium aluminate or Tai-Ace S 150.
Priority Applications (1)
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CNB2007101910235A CN100546917C (en) | 2007-12-06 | 2007-12-06 | The preparation method of lightfastness titanium dioxide |
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CNB2007101910235A CN100546917C (en) | 2007-12-06 | 2007-12-06 | The preparation method of lightfastness titanium dioxide |
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CN101186334A true CN101186334A (en) | 2008-05-28 |
CN100546917C CN100546917C (en) | 2009-10-07 |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101857736A (en) * | 2010-07-16 | 2010-10-13 | 四川龙蟒钛业股份有限公司 | Production method of high-light-fastness rutile type titanium dioxide |
CN102531049A (en) * | 2010-12-07 | 2012-07-04 | 河南佰利联化学股份有限公司 | Application method of zirconium oxychloride mother solution in hydrolysis |
CN103131212A (en) * | 2013-02-28 | 2013-06-05 | 江苏镇钛化工有限公司 | Preparation method of special titanium dioxide for oily system |
CN105504885A (en) * | 2014-09-26 | 2016-04-20 | 河南佰利联化学股份有限公司 | Preparation method for special rutile titanium dioxide used for papermaking |
CN105738271A (en) * | 2016-02-24 | 2016-07-06 | 中国科学院宁波材料技术与工程研究所 | Test method for light resistance of titanium dioxide |
CN107880591A (en) * | 2017-11-13 | 2018-04-06 | 龙蟒佰利联集团股份有限公司 | A kind of surface modifying method of titanium dioxide |
CN108997790A (en) * | 2018-09-05 | 2018-12-14 | 襄阳龙蟒钛业有限公司 | A kind of high glaze titanium white production method |
CN108997791A (en) * | 2018-09-05 | 2018-12-14 | 襄阳龙蟒钛业有限公司 | A kind of high glaze titanium dioxide |
CN111118882A (en) * | 2019-08-26 | 2020-05-08 | 张昌录 | Ultraviolet-proof fabric |
CN112759948A (en) * | 2020-12-30 | 2021-05-07 | 攀枝花东方钛业有限公司 | Special titanium dioxide for road sign paint and preparation method thereof |
-
2007
- 2007-12-06 CN CNB2007101910235A patent/CN100546917C/en not_active Expired - Fee Related
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101857736A (en) * | 2010-07-16 | 2010-10-13 | 四川龙蟒钛业股份有限公司 | Production method of high-light-fastness rutile type titanium dioxide |
CN101857736B (en) * | 2010-07-16 | 2012-10-10 | 四川龙蟒钛业股份有限公司 | Production method of high-light-fastness rutile type titanium dioxide |
CN102531049A (en) * | 2010-12-07 | 2012-07-04 | 河南佰利联化学股份有限公司 | Application method of zirconium oxychloride mother solution in hydrolysis |
CN102531049B (en) * | 2010-12-07 | 2014-07-23 | 河南佰利联化学股份有限公司 | Application method of zirconium oxychloride mother solution in hydrolysis |
CN103131212A (en) * | 2013-02-28 | 2013-06-05 | 江苏镇钛化工有限公司 | Preparation method of special titanium dioxide for oily system |
CN105504885A (en) * | 2014-09-26 | 2016-04-20 | 河南佰利联化学股份有限公司 | Preparation method for special rutile titanium dioxide used for papermaking |
CN105738271A (en) * | 2016-02-24 | 2016-07-06 | 中国科学院宁波材料技术与工程研究所 | Test method for light resistance of titanium dioxide |
CN107880591A (en) * | 2017-11-13 | 2018-04-06 | 龙蟒佰利联集团股份有限公司 | A kind of surface modifying method of titanium dioxide |
CN108997790A (en) * | 2018-09-05 | 2018-12-14 | 襄阳龙蟒钛业有限公司 | A kind of high glaze titanium white production method |
CN108997791A (en) * | 2018-09-05 | 2018-12-14 | 襄阳龙蟒钛业有限公司 | A kind of high glaze titanium dioxide |
CN111118882A (en) * | 2019-08-26 | 2020-05-08 | 张昌录 | Ultraviolet-proof fabric |
CN112759948A (en) * | 2020-12-30 | 2021-05-07 | 攀枝花东方钛业有限公司 | Special titanium dioxide for road sign paint and preparation method thereof |
CN112759948B (en) * | 2020-12-30 | 2022-05-10 | 攀枝花东方钛业有限公司 | Special titanium dioxide for road sign paint and preparation method thereof |
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