CN101186134A - Thermal barrier coating and preparation method thereof - Google Patents
Thermal barrier coating and preparation method thereof Download PDFInfo
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- CN101186134A CN101186134A CNA2007101448072A CN200710144807A CN101186134A CN 101186134 A CN101186134 A CN 101186134A CN A2007101448072 A CNA2007101448072 A CN A2007101448072A CN 200710144807 A CN200710144807 A CN 200710144807A CN 101186134 A CN101186134 A CN 101186134A
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- nickel
- barrier coating
- thermal barrier
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- base superalloy
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Abstract
The invention provides a heat barrier coat and the preparation method, which relates to a coat and the preparation method. The invention solves the problems of the prior art of relative sliding and dropping of material interface parallel to the nickel-based high-temperature alloy layer direction under high temperature and longitudinal cracking of the heat barrier coat vertical to the nickel-based high-temperature alloy layer direction. The heat barrier coat consists of an external ceramic layer (1) and an internal combination layer (5); wherein, the internal combination layer (5) consists of a nickel-based high-temperature alloy layer (4) and a bonding layer (2) connected on the external surface of the nickel-based high-temperature alloy layer (4); the bonding layer (2) consists of nickel 3-d structure (3) and yttria stable zirconia; wherein, the nickel 3-d structure is honeycomb-shape nickel space structure. The preparation method is that the external surface of the nickel-based high-temperature alloy layer (4) is electrically deposited, thus obtaining the nickel 3-d structure connected with the external surface, and the yttria stable zirconia sol is sprayed to obtain the bonding layer (2) through calcination; finally, the heat barrier coat is obtained by preparing the ceramic layer (1) on the bonding layer (2).
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof.
Background technology
Thermal barrier coating has been widely used in various fields such as Aeronautics and Astronautics, fuel gas generation, metallurgy, naval vessel, chemical industry and automobile making.Therefore development of science and technology will develop high-performance, highly reliable, long-life thermal barrier coating energetically to operating temperature, the service life of hot-end component having proposed more and more higher requirement.Traditional thermal barrier coating is normally formed by ceramic surface with in conjunction with bottom.The thermal barrier coating structure mainly can be divided into double-decker, sandwich construction and gradient-structure.Because the complexity and the diversity of thermal barrier coating service condition often cause thermal barrier coating to lose efficacy.Existing thermal barrier coating lost efficacy and is summarized as follows: occur the vertical penetrating crack perpendicular to the surface in the ceramic topcoats, cause the surface layer fracture, thermal barrier coating lost efficacy; Occur being parallel to the transversal crack on surface in the ceramic topcoats, part surface layer peeling, peel off, thermal barrier coating destroys; Ceramic topcoats/oxide-film/tie-layer interface place, the interface cracking of ceramic topcoats/oxide-film and oxide-film/tie-layer interface cracking cause thermal barrier coating to destroy; Tack coat/basal body interface cracking, thermal barrier coating is whole to come off.From the above, the failure mode of thermal barrier coating is to be parallel to material interface on the matrix direction to slide relatively and come off and perpendicular to the longitudinal cracking of the thermal barrier coating on the matrix direction.The principal element that influences the thermal barrier coating inefficacy is that the thermal coefficient of expansion between coating material does not match; The variation of the oxidation of metal and the composition that causes thereof under the high temperature; The phase transformation of material.
Summary of the invention
The present invention seeks to slide relatively and come off and, and a kind of thermal barrier coating and preparation method thereof is provided perpendicular to the problem of the longitudinal cracking of the thermal barrier coating on the nickel base superalloy layer direction in order to solve the material interface that is parallel under the high temperature in the prior art on the nickel base superalloy layer direction.
Thermal barrier coating of the present invention is made up of external ceramic layer and inner binder course, and wherein inner binder course is made up of nickel base superalloy layer and the tack coat that is connected nickel base superalloy layer outer surface, and tack coat is made up of nickel three-dimensional structure and yttria-stabilized zirconia; Wherein the nickel three-dimensional structure is cellular nickel space structure.
A kind of preparation method of thermal barrier coating realizes according to the following steps: one, with the nickel base superalloy plate successively with drying up behind acetone, methyl alcohol and the ultra-pure water ultrasonic cleaning 15~25min; Two, with concentration be the polystyrene colloid solution of 0.2~0.8mol/L, be sprayed at a side surface of the nickel base superalloy plate that cleans up behind ultrasonic dispersion 15~25min, at room temperature leave standstill 24~30h, obtain the nickel base superalloy that one side has polystyrene moulding; Three, electro-deposition: pure nickel just very, negative electrode has the nickel base superalloy of polystyrene moulding for one side, and electrolyte ph is 3~5, adopts dc source, and electro-deposition is that 0.04~0.06A, temperature are to carry out under 30~60 ℃ the condition at electric current; Four, after the electro-deposition negative electrode is taken out, put under 580~620 ℃ of conditions and calcine 1~3h, obtain the nickel base superalloy that surface deposition has the nickel three-dimensional structure; Five, in proportion with 90~94 moles of ZrOCl
26H
2O, 6~10 moles of Y (NO
3)
36H
2O and 106~110 moles of citric acids are soluble in water as solute, and getting total concentration of solutes is the solution of 0.01~0.06mol/L, stir down at 60~80 ℃ then, obtain yttria-stabilized zirconia colloidal sol; Six, yttria-stabilized zirconia colloidal sol is sprayed at the nickel base superalloy surface that surface deposition has the nickel three-dimensional structure, dry 22~26h under 30~50 ℃ of temperature then, put into Muffle furnace again, heating rate with 2 ℃/min, be warmed up to 500~700 ℃ of sintering 1~3h, be cooled to room temperature, get binder course; Seven, on binder course, prepare ceramic layer, get thermal barrier coating.
The invention has the advantages that tack coat is made up of nickel three-dimensional structure and yttria-stabilized zirconia, nickel base superalloy layer and tack coat are combined closely, the deep bundle of " root " that a large amount of nickel three-dimensional structures goes out just as the nickel base superalloy layer growth is in yttria-stabilized zirconia, strengthened the anti-shear ability that is parallel to the nickel base superalloy layer, guaranteed to be parallel under the high temperature material interface on the matrix direction and do not produce relative slip and come off; Micropore in the yttria-stabilized zirconia can hinder the heat conduction of material, alleviated the release of the residual stress under the preparation state, the stress that thermal expansion does not match and phase transformation is produced has been played abirritation, effectively prevented problem perpendicular to the longitudinal cracking of the thermal barrier coating on the nickel base superalloy layer direction.
Description of drawings
Fig. 1 is the structural representation of thermal barrier coating of the present invention, Fig. 2 is the structural representation of inner binder course 5, Fig. 3 is the stereoscan photograph that one side used in the specific embodiment five has the nickel base superalloy of polystyrene moulding, and Fig. 4 is the stereoscan photograph of nickel three-dimensional structure in the specific embodiment 11.
The specific embodiment
The specific embodiment one: the present embodiment thermal barrier coating is made up of external ceramic layer 1 and inner binder course 5, wherein inner binder course 5 is made up of nickel base superalloy layer 4 and the tack coat 2 that is connected nickel base superalloy layer 4 outer surface, and tack coat 2 is made up of nickel three-dimensional structure 3 and yttria-stabilized zirconia; Wherein nickel three-dimensional structure 3 is cellular nickel space structure.
The specific embodiment two: present embodiment and the specific embodiment one are different is that nickel three-dimensional structure 3 in the tack coat 2 is connected in nickel base superalloy 4 outer surfaces by electro-deposition.Other is identical with the specific embodiment one.
The specific embodiment three: present embodiment and the specific embodiment one are different is that the thickness of tack coat (2) is 30~60 μ m.Other is identical with the specific embodiment one.
The specific embodiment four: present embodiment and the specific embodiment one are different is that the thickness of tack coat (2) is 45 μ m.Other is identical with the specific embodiment one.
The specific embodiment five: a kind of thermal barrier coating of present embodiment and preparation method thereof is realized according to the following steps: one, with the nickel base superalloy plate successively with drying up behind acetone, methyl alcohol and the ultra-pure water ultrasonic cleaning 15~25min; Two, with concentration be the polystyrene colloid solution of 0.2~0.8mol/L, be sprayed at a side surface of the nickel base superalloy plate that cleans up behind ultrasonic dispersion 15~25min, at room temperature leave standstill 24~30h, obtain the nickel base superalloy that one side has polystyrene moulding 6; Three, electro-deposition: pure nickel just very, negative electrode has the nickel base superalloy of polystyrene moulding 6 for one side, and electrolyte ph is 3~5, adopts dc source, and electro-deposition is that 0.04~0.06A, temperature are to carry out under 30~60 ℃ the condition at electric current; Four, after the electro-deposition negative electrode is taken out, put under 580~620 ℃ of conditions and calcine 1~3h, obtain the nickel base superalloy that surface deposition has the nickel three-dimensional structure; Five, in proportion with 90~94 moles of ZrOCl
26H
2O, 6~10 moles of Y (NO
3)
36H
2O and 106~110 moles of citric acids are soluble in water as solute, and getting total concentration of solutes is the solution of 0.01~0.06mol/L, stir down at 60~80 ℃ then, obtain yttria-stabilized zirconia colloidal sol; Six, yttria-stabilized zirconia colloidal sol is sprayed at the nickel base superalloy surface that surface deposition has the nickel three-dimensional structure, dry 22~26h under 30~50 ℃ of temperature then, put into Muffle furnace again, heating rate with 2 ℃/min, be warmed up to 500~700 ℃ of sintering 1~3h, be cooled to room temperature, get binder course 5; Seven, preparation ceramic layer 1 on binder course 5 gets thermal barrier coating.
In the present embodiment step 4 calcining of the negative electrode after the electro-deposition can be made polystyrene moulding 6 gasifications.
The specific embodiment six: not being both in the step 1 of the present embodiment and the specific embodiment five dries up behind the ultrasonic cleaning 20min.Other step and parameter are identical with the specific embodiment five.
The specific embodiment seven: the present embodiment and the specific embodiment five not to be both in the step 2 concentration be the polystyrene colloid solution of 0.5mol/L, be sprayed at a side surface of the nickel base superalloy plate that cleans up behind the ultrasonic dispersion 20min, at room temperature leave standstill 27h.Other step and parameter are identical with the specific embodiment five.
The specific embodiment eight: the present embodiment and the specific embodiment five be not both that electrolyte ph is 4 in the step 3, adopt dc source, electro-deposition is that 0.05A, temperature are to carry out under 40 ℃ the condition at electric current.Other step and parameter are identical with the specific embodiment five.
The specific embodiment nine: the electrolyte of using in the step 3 that is not both of the present embodiment and the specific embodiment five is in proportion with 290~310 moles of Ni
2SO
4, 43~47 moles of NiCl and 28~32 moles of H
3BO
3Mix and form.Other step and parameter are identical with the specific embodiment five.
The specific embodiment ten: the electrolyte of using in the step 3 that is not both of the present embodiment and the specific embodiment five is in proportion with 300 moles of Ni
2SO
4, 45 moles of NiCl and 30 moles of H
3BO
3Mix and form.Other step and parameter are identical with the specific embodiment five.
The specific embodiment 11: not being both to put in the step 4 under 600 ℃ of conditions of the present embodiment and the specific embodiment five calcined 2h.Other step and parameter are identical with the specific embodiment five.
The specific embodiment 12: not being both in the step 5 of the present embodiment and the specific embodiment five in proportion with 92 moles of ZrOCl
26H
2O, 8 moles of Y (NO
3)
36H
2O and 108 moles of citric acids are soluble in water as solute, and getting total concentration of solutes is the solution of 0.05mol/L, stir down at 70 ℃ then.Other step and parameter are identical with the specific embodiment five.
The specific embodiment 13: the present embodiment and the specific embodiment five be not both in the step 6 dry 24h under 40 ℃ of temperature, put into Muffle furnace again, with the heating rate of 2 ℃/min, be warmed up to 600 ℃ of sintering 2h.Other step and parameter are identical with the specific embodiment five.
The specific embodiment 14: the ceramic layer 1 for preparing in the step 7 that is not both of the present embodiment and the specific embodiment five is silicon carbide layer, silicon dioxide layer or alumina layer.Other step and parameter are identical with the specific embodiment five.
The specific embodiment 15: not being both of the present embodiment and the specific embodiment five prepares ceramic layer 1 employing EB-PVD technology or magnetron sputtering technique in the step 7.Other step and parameter are identical with the specific embodiment five.
Claims (10)
1. thermal barrier coating, it is characterized in that thermal barrier coating is made up of external ceramic layer (1) and inner binder course (5), wherein inner binder course (5) is made up of nickel base superalloy layer (4) and the tack coat (2) that is connected nickel base superalloy layer (4) outer surface, and tack coat (2) is made up of nickel three-dimensional structure (3) and yttria-stabilized zirconia; Wherein the nickel three-dimensional structure is cellular nickel space structure.
2. a kind of thermal barrier coating according to claim 1 is characterized in that the nickel three-dimensional structure (3) in the tack coat (2) is connected in nickel base superalloy (4) outer surface by electro-deposition.
3. a kind of thermal barrier coating according to claim 1, the thickness that it is characterized in that tack coat (2) are 30~60 μ m.
4. the method for preparing the described a kind of thermal barrier coating of claim 1 is characterized in that a kind of thermal barrier coating prepares according to the following steps: one, with the nickel base superalloy plate successively with drying up behind acetone, methyl alcohol and the ultra-pure water ultrasonic cleaning 15~25min; Two, with concentration be the polystyrene colloid solution of 0.2~0.8mol/L, be sprayed at a side surface of the nickel base superalloy plate that cleans up behind ultrasonic dispersion 15~25min, at room temperature leave standstill 24~30h, obtain the nickel base superalloy that one side has polystyrene moulding (6); Three, electro-deposition: pure nickel just very, negative electrode has the nickel base superalloy of polystyrene moulding (6) for one side, and electrolyte ph is 3~5, adopts dc source, and electro-deposition is that 0.04~0.06A, temperature are to carry out under 30~60 ℃ the condition at electric current; Four, after the electro-deposition negative electrode is taken out, put under 580~620 ℃ of conditions and calcine 1~3h, obtain the nickel base superalloy that surface deposition has the nickel three-dimensional structure; Five, in proportion with 90~94 moles of ZrOCl
26H
2O, 6~10 moles of Y (NO
3)
36H
2O and 106~110 moles of citric acids are soluble in water as solute, and getting total concentration of solutes is the solution of 0.01~0.06mol/L, stir down at 60~80 ℃ then, obtain yttria-stabilized zirconia colloidal sol; Six, yttria-stabilized zirconia colloidal sol is sprayed at the nickel base superalloy surface that surface deposition has the nickel three-dimensional structure, dry 22~26h under 30~50 ℃ of temperature then, put into Muffle furnace again, heating rate with 2 ℃/min, be warmed up to 500~700 ℃ of sintering 1~3h, be cooled to room temperature, get binder course (5); Seven, go up preparation ceramic layer (1) at binder course (5), get thermal barrier coating.
5. the preparation method of a kind of thermal barrier coating according to claim 4, it is characterized in that in the step 2 with concentration being the polystyrene colloid solution of 0.5mol/L, be sprayed at a side surface of the nickel base superalloy plate that cleans up behind the ultrasonic dispersion 20min, at room temperature leave standstill 27h.
6. the preparation method of a kind of thermal barrier coating according to claim 4 is characterized in that electrolyte ph is 4 in the step 3, adopts dc source, and electro-deposition is that 0.05A, temperature are to carry out under 40 ℃ the condition at electric current.
7. the preparation method of a kind of thermal barrier coating according to claim 4 is characterized in that the electrolyte of using in the step 3 is in proportion with 290~310 moles of Ni
2SO
4, 43~47 moles of NiCl and 28~32 moles of H
3BO
3Mix and form.
8. the preparation method of a kind of thermal barrier coating according to claim 4 is characterized in that in the step 5 in proportion with 92 moles of ZrOCl
26H
2O, 8 moles of Y (NO
3)
36H
2O and 108 moles of citric acids are soluble in water as solute, and getting total concentration of solutes is the solution of 0.05mol/L, stir down at 70 ℃ then.
9. the preparation method of a kind of thermal barrier coating according to claim 4 is characterized in that in the step 6 dry 24h under 40 ℃ of temperature, puts into Muffle furnace again, with the heating rate of 2 ℃/min, is warmed up to 600 ℃ of sintering 2h.
10. the preparation method of a kind of thermal barrier coating according to claim 4 is characterized in that the ceramic layer (1) for preparing in the step 7 is silicon carbide layer, silicon dioxide layer or alumina layer.
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CNB2007101448072A CN100562428C (en) | 2007-12-12 | 2007-12-12 | A kind of preparation method of thermal barrier coating |
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CNB2007101448072A CN100562428C (en) | 2007-12-12 | 2007-12-12 | A kind of preparation method of thermal barrier coating |
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CN101186134A true CN101186134A (en) | 2008-05-28 |
CN100562428C CN100562428C (en) | 2009-11-25 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101791880B (en) * | 2009-12-30 | 2012-11-28 | 哈尔滨工业大学 | Cover plate formed by combining metal honeycomb structure and ceramics used for thermal protection system |
CN109576630A (en) * | 2019-01-29 | 2019-04-05 | 常州市讯德电器有限公司 | A kind of preparation method of high-temperature stable thermal barrier coating |
-
2007
- 2007-12-12 CN CNB2007101448072A patent/CN100562428C/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101791880B (en) * | 2009-12-30 | 2012-11-28 | 哈尔滨工业大学 | Cover plate formed by combining metal honeycomb structure and ceramics used for thermal protection system |
CN109576630A (en) * | 2019-01-29 | 2019-04-05 | 常州市讯德电器有限公司 | A kind of preparation method of high-temperature stable thermal barrier coating |
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Effective date of registration: 20190730 Address after: 150000 Heilongjiang Province, Harbin City Economic Development Zone haping Road District Dalian road and Xingkai road junction Patentee after: Harbin University of Technology Robot Group Co., Ltd. Address before: 150001 Harbin, Nangang, West District, large straight street, No. 92 Patentee before: Harbin Institute of Technology |
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