CN101185898B - Method for preparing ceramsite catalyst for ozone catalytic oxidation - Google Patents
Method for preparing ceramsite catalyst for ozone catalytic oxidation Download PDFInfo
- Publication number
- CN101185898B CN101185898B CN200710032553A CN200710032553A CN101185898B CN 101185898 B CN101185898 B CN 101185898B CN 200710032553 A CN200710032553 A CN 200710032553A CN 200710032553 A CN200710032553 A CN 200710032553A CN 101185898 B CN101185898 B CN 101185898B
- Authority
- CN
- China
- Prior art keywords
- haydite
- catalyst
- ozone
- nuclear
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 69
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 10
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title description 58
- 230000003647 oxidation Effects 0.000 title description 23
- 238000007254 oxidation reaction Methods 0.000 title description 23
- 239000002994 raw material Substances 0.000 claims abstract description 33
- 238000002360 preparation method Methods 0.000 claims abstract description 20
- 238000006385 ozonation reaction Methods 0.000 claims abstract description 16
- 230000000694 effects Effects 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 10
- 238000005245 sintering Methods 0.000 claims abstract description 7
- 230000008569 process Effects 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 18
- 230000008961 swelling Effects 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 13
- 239000005995 Aluminium silicate Substances 0.000 claims description 12
- 235000012211 aluminium silicate Nutrition 0.000 claims description 12
- 239000010881 fly ash Substances 0.000 claims description 12
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 12
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 7
- 229960003558 almasilate Drugs 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- HZVVJJIYJKGMFL-UHFFFAOYSA-N almasilate Chemical group O.[Mg+2].[Al+3].[Al+3].O[Si](O)=O.O[Si](O)=O HZVVJJIYJKGMFL-UHFFFAOYSA-N 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 4
- -1 Fe4O3 Inorganic materials 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 abstract 1
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 238000006555 catalytic reaction Methods 0.000 description 11
- 239000002351 wastewater Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 6
- PIEXSEDEFNIKCT-UHFFFAOYSA-N dialuminum magnesium dioxido(oxo)silane hydrate Chemical group O.[Mg++].[Al+3].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O PIEXSEDEFNIKCT-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 3
- 235000021168 barbecue Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 206010028400 Mutagenic effect Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 231100000243 mutagenic effect Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003403 water pollutant Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
Abstract
The invention discloses a preparation method of haydite catalyst for catalytic ozonation. The method comprises the preparation of the haydite raw material nuclear, and the coating and the sintering process of the catalyst on the haydite raw material nuclear. The coating of the catalyst on the haydite raw material is used for crushing one or a plurality of the composite catalyst activity component(s) of MnO, MnO2, TiO2, CoO, Co3O4, Fe2O3, Fe4O3, and FeO into particles with the diameter of 0.1-1mm and being mixed with the raw materials produced by the haydites to produce 3-4mm haydites for coating catalyst. The haydite catalyst for catalytic ozonation is made. After being mixed, the catalyst and the haydite raw material are loaded on the original haydite raw material nuclear with high adhesion strength, and meanwhile the once sintering molding guarantees the high utilization ratio of the catalyst, and the prepared haydite catalyst can be used repeatedly, thus reducing secondary pollutionand operation cost of ozonation.
Description
Technical field
The present invention relates to the catalytic ozonation catalyst, be specifically related to a kind of preparation method who is used for the ceramsite catalyst of catalytic ozonation.Use this ceramsite catalyst and can improve ozone, thereby handle waste water, contaminated source water efficiently, particularly contain the waste water of refractory organic organic oxidation efficiency in the waste water.
Background technology
Ozone has extremely strong oxidation susceptibility, and its oxidability is only second to fluorine, is higher than chlorine and potassium permanganate.Based on the strong oxidizing property of ozone, but and in water, decompose voluntarily in the short time, there is not secondary pollution, be desirable water treatment green oxidation medicament.
At present, obtained application aspect ozone technology many in water treatment field.Ozone not only has very strong sterilization, the little pollution organic substance in all right oxidation removal water, and these micropollutants are difficult to biodegradable often, and ozone oxidation is comparatively thorough, less generation accessory substance.And when in the traditional water treatment process, using chlorine or clorox as disinfectant and oxidant, can produce some poisonous and hazardous DBPs, as organic halogens such as chloroforms, that many research reports proof organic halogens have is carcinogenic, teratogenesis, mutagenic effect.
Adopting the fine or not key of ozonation technology effect is the oxidability of ozone and the use amount of ozone.Traditional ozonation technology is lower to the utilization rate of ozone, thereby lower to the hardly degraded organic substance clearance.Therefore, ozone is carried out catalysis, improve the oxidation utilization rate of ozone, it is the focus of studying at present that its oxidability is improved.At present the ozone catalytic agent of reported in literature is based on homogeneous phase, and promptly the catalyst wiring solution-forming adds in the waste water, feeds ozone then and carries out catalytic reaction, and catalyst is that the form with ionic state exists.Though this liquid catalyst can improve the oxidability of ozone, exist catalyst to reuse, easily cause secondary pollution, increase the shortcomings such as difficulty of subsequent treatment.And can manufacture a kind of catalyst of solid, make its oxidation that catalytic action preferably be arranged to the ozone in the waste water, in the process of water treatment, these solid catalysts are retained in always and play catalysed oxidn in the ozone catalytic reactor, do not need follow-up separating measure, its actual application value will be arranged.
The preparation of at present heterogeneous ozone catalytic agent, the method that is adopted is, one or more are compound by a certain percentage soluble in water will to have the metal nitrate of catalytic activity or sulfate, add carrier then, add alkaline matter, make these metallic salts form precipitation of hydroxide.Mix then, the washing and filtering carrier, baking is at last fired and is equipped with, because such preparation method is attached to carrier surface with catalyst, there is a large amount of byproducts of reaction in the preparation process, can't need removes by washing attached to the catalyst of carrier surface in a large number simultaneously, cause bigger waste.In addition and since catalyst be by baking attached to carrier surface, so its adhesive strength is relatively poor, repeatedly uses the turnover rate of rear catalyst bigger, and because such production method complex steps, difficultly realizes large-scale industrial production.
Summary of the invention
The objective of the invention is to overcome the shortcoming of prior art, has the solid constituent of catalytic activity as its raw materials for production by in the haydite production process, adding, the ceramsite catalyst that the preparation catalytic ozonation is used, to improve the ozone oxidation ability, and improve the hardly degraded organic substance ability in the water of removing, reduce the operating cost of ozone oxidation water treatment.
Purpose of the present invention is achieved through the following technical solutions:
A kind of preparation method who is used for the ceramsite catalyst of catalytic ozonation comprises the steps and process conditions:
(1) gets the raw materials ready and the preparation of haydite materials nuclear: flyash, kaolin and swelling agent is standby as the haydite raw materials for production, and part haydite raw materials for production are prepared the haydite materials nuclear that particle diameter is 1-1.5mm by the sugar-coat draft machine, described swelling agent is an Almasilate;
(2) catalyst is to the coating of haydite materials nuclear: with MnO, MnO
2, TiO
2, CoO, Co
3O
4, Fe
2O
3Being ground into particle diameter with one or more compound catalyst activity compositions among the FeO is 0.1-1mm, mixes with the haydite raw materials for production of step (1), and mixture is loaded on the haydite materials nuclear, generates the haydite of the coated catalysts of 3-4mm; The weight that described catalyst activity composition accounts for total production haydite materials is 5%-30%;
(3) sintering: the haydite of step (2) coated catalysts at 1000-1200 ℃ of sintering, is made the ceramsite catalyst that is used for catalytic ozonation.
For further realizing purpose of the present invention, the particle diameter of described haydite raw materials for production is 1-3mm.Described catalyst activity composition is MnO, MnO
2, TiO
2, CoO or Co
3O
4In one or more.Described sintering temperature is 1100-1200 ℃.By weight percentage, described flyash, kaolin and swelling agent respectively account for the ratio of haydite raw materials for production and are: 45～60%, 25～40%, 15～20%.
Flyash, kaolin, swelling agent are the haydite raw materials for production of using always.
The catalyst active component that is used for catalytic ozonation is MnO, MnO
2, TiO
2, CoO, Co
3O
4, Fe
2O
3, one or more are compound among the FeO, the carrier of catalyst is a haydite.MnO, MnO
2, TiO
2, CoO, Co
3O
4, Fe
2O
3, one or more kinds raw material (flyash, kaolin, swelling agent) compound and that produce haydite mixes among the FeO, loads on securely on the little haydite nuclear of not baking again, finally baking molding together prepares ozone oxidation catalyst.This catalyst had both played the effect that improves the ozone oxidation ability when carrying out catalytic reaction, be difficult for again running off and cause secondary pollution to waste water.
Have following advantage and beneficial effect with respect to prior art the present invention:
The present invention utilizes conventional production method to make haydite nuclear earlier, can improve its intensity, has saved the consumption of producing the catalyst raw material simultaneously, has reduced production cost.The solid-state ceramsite catalyst of the present invention's preparation, because catalyst and haydite materials mixing back loading are on original haydite materials nuclear, because its material is close, so its adhesive strength height, by once sintered moulding, guaranteed the high usage of this catalyst simultaneously, the ceramsite catalyst of preparation can be reused, thereby the minimizing secondary pollution reduces ozone oxidation operating cost.Simultaneously catalyst has been saved the production stage and the production cost of general ozone heterogeneous catalysis as one of raw material of haydite preparation, can realize large-scale industrial production.
This invention can be handled water separately, also can with the additive method coupling.Ozone can more effectively be removed organic pollution in the water through after the catalyst, and its oxidability is significantly improved, thereby has reduced the dosage of ozone, has saved operating cost; By catalyst is contained the haydite of catalyst activity component as the feedstock production top layer of carrier haydite, can greatly improve catalyst utilization, reduce catalyst production cost, reduce the catalyst loss rate, prevent secondary pollution.
The specific embodiment
In order to understand technical characterstic of the present invention better,, need to prove that embodiment is not a limiting the scope of the invention below in conjunction with the present invention being further described by embodiment.
Embodiment 1
The raw material that utilizes flyash, kaolin, swelling agent to produce as haydite earlier, swelling agent is an Almasilate, prepares the haydite materials nuclear that particle diameter is 1-1.5mm by the sugar-coat draft machine.By weight percentage, the ratio that flyash, kaolin and swelling agent respectively account for is: 50%, 35%, 15%.In the raw material of preparation haydite, add the MnO that accounts for its raw materials mixed weight 10% again
2With 10%Fe
2O
3, it is 0.1-1mm that these two kinds of metal oxides are crushed to particle diameter, mixes.Re-using model is YK60-160 sugar-coat draft machine, mixture is wrapped in not securely on the little haydite nuclear of baking, generates the not haydite of barbecue of 3-4mm, final baking molding together, and the condition that baking is burnt is 1000 degree, prepares ozone oxidation catalyst.Utilize the daily wastewater from chemical industry of ozone oxidation advanced treating, the ozone dosage is O
3: COD=0.5: 1, COD is reduced to 90mg/L by original 120mg/L, adds ozone catalytic agent catalysis, and under same ozone dosage, COD drops to 60mg/L, and treatment effeciency improves 25%.
Embodiment 2
The raw material that utilizes flyash, kaolin, swelling agent to produce earlier as haydite, swelling agent is an Almasilate, by model is that YK60-160 sugar-coat draft machine prepares the haydite materials nuclear that particle diameter is 1.5-2mm, by weight percentage, the ratio that flyash, kaolin and swelling agent respectively account for is: 60%, 25%, 15%.At raw material nuclear before baking is burnt, in the raw material of preparation haydite, add to account for and be respectively 5% MnO, MnO with its raw materials mixed
2, TiO
2, CoO, Co
3O
4, these four kinds of metal oxides are ground into Powdered, mix.Re-use the sugar-coat draft machine, mixture is wrapped in not securely on the little haydite nuclear of baking, generate the not haydite of barbecue of 4-5mm, final baking molding together, the condition that baking is burnt is 1100 degree, prepares ozone oxidation catalyst.Utilize ozone Oxidation Treatment chemical plant phenol wastewater, the ozone dosage is O
3: phenol=1, COD is reduced to 340mg/L by original 540mg/L, adds ozone catalytic agent catalysis, and under same ozone dosage, COD drops to 160mg/L, and treatment effeciency improves 35%.
Embodiment 3
The raw material that utilizes flyash, kaolin, swelling agent to produce earlier as haydite, swelling agent is that Almasilate is that YK60-160 sugar-coat draft machine prepares the haydite materials nuclear that particle diameter is 2-2.5mm by model, by weight percentage, the ratio that flyash, kaolin and swelling agent respectively account for is: 45%, 40%, 20%.At raw material nuclear before baking is burnt, in the raw material of preparation haydite, add to account for and be respectively 15% MnO with its raw materials mixed
2, Co
3O
4, Fe
2O
3These three kinds of metal oxides are pulverized, mixed.Re-use the sugar-coat draft machine, it is wrapped on little haydite nuclear of end baking securely, generate the not haydite of barbecue of 5-8mm, final baking molding together, the condition that baking is burnt is 1200 degree, prepares ozone oxidation catalyst.Utilize ozone Oxidation Treatment harbour washing of tanks waste water, the ozone dosage is O3: COD=1, and COD is reduced to 1200mg/L by original 1600mg/L, add ozone catalytic agent catalysis, under same ozone dosage, COD drops to 900mg/L, and treatment effeciency improves 19%.
Ozone oxidation catalyst in the foregoing description carries out organic pollution in the O3 catalytic oxidation water by joining in the ozone catalytic reaction unit.The ozone catalytic reaction unit is by water distribution system, catalytic reaction layer, outlet system, tail gas absorber is formed, wherein water distribution system is realized by water-locator is set above the filter plate, be full of solid-phase catalyst above the filter plate and form catalytic reaction layer, outlet system loads filter screen and makes that the carrier of band catalyst is not taken out of, and tail gas absorber is collected reaction back residual ozone.The ozone of collecting can be used in other oxidation operation, if ozone is not recycled, then by the ozone tail gas destructor ozone is handled, and pollutes to prevent that ozone from overflowing.Its technological process is that ozone makes air water mix via gas absorber earlier, enter the ozone catalytic reaction unit then, through water distribution system, make water fully contact with ozone, catalyst, catalyst ozone oxidation water pollutant then, improve the removal ability of ozone, thereby save the ozone dosage, reduce water treatment operating cost pollutant.
The ozone catalytic reactor can be divided into two kinds of up flow type (water from the bottom up flow) and downflow systems (water is mobile from top to bottom) according to water (flow) direction, can adjust according to actual engineering.
The technological parameter of this catalytic reactor is as follows: catalyst is full of catalyst reaction device, reserves the protection height of 0.2-1m above, is beneficial to the expansion of up flow type reaction time catalizer layer; Waste water and ozone enter catalytic reactor rapidly after mixing, with time of contact of catalyst be 5～60min.
The material of reactor is made with the material of anti-ozone corrosion, as stainless steel, glass, polytetrafluoroethylene (PTFE) etc.
As mentioned above, can realize the present invention preferably.
Claims (3)
1. preparation method who is used for the ceramsite catalyst of catalytic ozonation is characterized in that comprising the steps and process conditions:
(1) get the raw materials ready and the preparation of haydite materials nuclear: flyash, kaolin and swelling agent is standby as the haydite raw materials for production, and part haydite raw materials for production are prepared the haydite materials nuclear that particle diameter is 1-1.5mm by the sugar-coat draft machine; Described swelling agent is an Almasilate;
(2) catalyst is to the coating of haydite materials nuclear: with MnO, MnO
2, TiO
2, CoO, Co
3O
4, Fe
2O
3Being ground into particle diameter with one or more compound catalyst activity compositions among the FeO is 0.1-1mm, mixes with the haydite raw materials for production of step (1), and mixture is loaded on the haydite materials nuclear, generates the haydite of the coated catalysts of 3-4mm; The weight that described catalyst activity composition accounts for total production haydite materials is 5%-30%;
(3) sintering: the haydite of step (2) coated catalysts at 1000-1200 ℃ of sintering, is made the ceramsite catalyst that is used for catalytic ozonation.
2. the preparation method who is used for the ceramsite catalyst of catalytic ozonation according to claim 1 is characterized in that described catalyst activity composition is MnO, MnO
2, TiO
2, CoO or Co
3O
4In one or more.
3. the preparation method who is used for the ceramsite catalyst of catalytic ozonation according to claim 1, it is characterized in that by weight percentage, the ratio that described flyash, kaolin and swelling agent respectively account for the haydite raw materials for production is: 45～60%, 25～40%, 15～20%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710032553A CN101185898B (en) | 2007-12-14 | 2007-12-14 | Method for preparing ceramsite catalyst for ozone catalytic oxidation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710032553A CN101185898B (en) | 2007-12-14 | 2007-12-14 | Method for preparing ceramsite catalyst for ozone catalytic oxidation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101185898A CN101185898A (en) | 2008-05-28 |
| CN101185898B true CN101185898B (en) | 2010-05-19 |
Family
ID=39478644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710032553A Expired - Fee Related CN101185898B (en) | 2007-12-14 | 2007-12-14 | Method for preparing ceramsite catalyst for ozone catalytic oxidation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101185898B (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101811049B (en) * | 2009-02-19 | 2013-03-27 | 中国科学院生态环境研究中心 | Method for preparing honeycomb ceramic catalyst for catalytically ozonizing organic matters in water |
| CN101691254B (en) * | 2009-11-10 | 2012-05-23 | 北京林业大学 | Method for preparing modified bauxite catalyst in ozone heterogeneous catalysis water treatment technology |
| CN102284301A (en) * | 2010-06-18 | 2011-12-21 | 上海牛翼新能源科技有限公司 | Cold catalyst for stably eliminating ozone at room temperature |
| CN103007954B (en) * | 2012-12-21 | 2014-08-06 | 张振慧 | Multi-phase catalytic ozone oxidation catalyst and preparation method thereof |
| CN103331170A (en) * | 2013-06-28 | 2013-10-02 | 华南理工大学 | Ceramsite catalyst containing metallic oxide particles as well as preparation method and application thereof |
| CN104525206B (en) * | 2014-12-04 | 2017-04-12 | 格丰科技材料有限公司 | Porous ozone catalyst for removing COD from waste water and preparation method thereof |
| CN105983402A (en) * | 2015-01-27 | 2016-10-05 | 苏州清然环保科技有限公司 | Preparation method of ozone catalyst and the ozone catalyst |
| CN104926034B (en) * | 2015-06-11 | 2018-03-13 | 武汉钢铁有限公司 | Catalytic ozonation combines biofilter Treatment of Wastewater in Coking technique and device |
| CN105330061B (en) * | 2015-11-09 | 2017-08-15 | 上海纳米技术及应用国家工程研究中心有限公司 | A kind of advanced treatment process of oil field reinjection water |
| CN105478106A (en) * | 2015-11-27 | 2016-04-13 | 广州市华绿环保科技有限公司 | Novel manganese dioxide-loaded ceramic-based catalyst and its preparation method and use |
| CN105498777A (en) * | 2015-12-06 | 2016-04-20 | 苏州科环环保科技有限公司 | Preparation method of metal loaded catalyst with aluminum silicate as carrier |
| CN105536773B (en) * | 2015-12-11 | 2018-01-23 | 上海韬鸿化工科技有限公司 | Substrate catalyst of making pottery and preparation method thereof |
| CN105523624A (en) * | 2016-01-19 | 2016-04-27 | 天津大拇指环境工程有限公司 | Method and system for processing domestic wastewater of offshore oil drilling platforms |
| CN105688930B (en) * | 2016-02-26 | 2018-11-27 | 煤炭科学技术研究院有限公司 | A kind of fly ash base ozone oxidation catalyst and the preparation method and application thereof |
| CN106215946A (en) * | 2016-07-06 | 2016-12-14 | 晓清环保科技股份有限公司 | A kind of ozone catalyst for sewage disposal and preparation thereof and sewage water treatment method |
| CN106902812B (en) * | 2017-03-14 | 2019-04-19 | 南京大学 | A kind of preparation method of the loaded catalyst for heterogeneous catalysis ozonisation |
| CN108160062A (en) * | 2017-12-29 | 2018-06-15 | 北京天园环境工程技术有限公司 | A kind of NGLS types ozone catalyst, preparation method and application |
| KR102130491B1 (en) * | 2019-03-13 | 2020-07-14 | 주식회사 냄새뚝 | Apparatus and method for purifying exhaust gas of ship |
| CN111408381A (en) * | 2020-04-14 | 2020-07-14 | 中国人民大学 | Multi-metal ozone catalyst for removing COD (chemical oxygen demand) and chromaticity of wastewater and preparation method thereof |
| CN112121813B (en) * | 2020-09-15 | 2023-05-30 | 北京山美水美臭氧高科技有限公司 | Alkaline earth metal modified Mn-based ozone oxidation catalyst and application thereof |
| CN113559617B (en) * | 2021-06-18 | 2022-10-18 | 同济大学 | Preparation method and application of active alumina particle loaded manganese oxide composite material |
| CN115142830A (en) * | 2022-08-11 | 2022-10-04 | 安东石油技术（集团）有限公司 | Yield and efficiency increasing method for fracturing and reforming heavy oil reservoir |
| CN116444249A (en) * | 2023-03-06 | 2023-07-18 | 宁波斯蒂罗科技有限公司 | Preparation method of low-cost ozone catalyst ceramsite carrier |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000078680A1 (en) * | 1999-06-21 | 2000-12-28 | Mitsui Engineering & Shipbuilding Co., Ltd. | Method and apparatus for purifying water |
| CN1562798A (en) * | 2004-04-15 | 2005-01-12 | 大连理工大学 | Fe 203/A1 203 catalyzer through high level oxidation to treat organic wastewater, and preparation method |
-
2007
- 2007-12-14 CN CN200710032553A patent/CN101185898B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000078680A1 (en) * | 1999-06-21 | 2000-12-28 | Mitsui Engineering & Shipbuilding Co., Ltd. | Method and apparatus for purifying water |
| CN1562798A (en) * | 2004-04-15 | 2005-01-12 | 大连理工大学 | Fe 203/A1 203 catalyzer through high level oxidation to treat organic wastewater, and preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101185898A (en) | 2008-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101185898B (en) | Method for preparing ceramsite catalyst for ozone catalytic oxidation | |
| CN103331170A (en) | Ceramsite catalyst containing metallic oxide particles as well as preparation method and application thereof | |
| CN109607699A (en) | A kind of iron-carbon micro-electrolysis filler and preparation method thereof | |
| CN105080550B (en) | The preparation method of the ozone oxidation catalyst of gas treatment waste water | |
| CN103586026A (en) | Carbon supported catalyst for ozone oxidation, and preparation method and use thereof | |
| CN106807362A (en) | One kind load manganese dioxide activated-carbon catalyst and preparation method and application | |
| CN108993475B (en) | Ternary composite material heterogeneous light Fenton catalyst and preparation and application thereof | |
| CN105618066B (en) | A kind of catalytic wet oxidation catalyst and preparation method thereof | |
| CN101711981B (en) | Palladium catalyst for processing chlorinated organics in water and method for preparing same | |
| CN113856691B (en) | Ozone catalyst and preparation method thereof | |
| Zhang et al. | Photo-assisted bismuth ferrite/manganese dioxide/nickel foam composites activating PMS for degradation of enrofloxacin in water | |
| CN104772137A (en) | Ceramsite catalyst with high manganese dioxide content for ozone catalysis, and preparation method and application thereof | |
| González-González et al. | Nanohybrid catalysts with porous structures for environmental remediation through photocatalytic degradation of emerging pollutants | |
| CN103894236A (en) | Ceramsite carrier applicable to fenton fluidized bed and having catalytic action, preparation method and application of carrier | |
| Asadzadeh et al. | The removal of tetracycline with biogenic CeO2 nanoparticles in combination with US/PMS process from aqueous solutions: kinetics and mechanism | |
| CN102049253B (en) | Preparation method of special catalyst for waste water treatment by ozone oxidation | |
| CN103962149A (en) | Method for preparing multiphase ozonation solid catalyst for water treatment by using rare earth molecular sieve waste residues | |
| CN101658789A (en) | Metal-doped oxyhydroxide catalyst and preparation method and application thereof | |
| Dang et al. | Tannin-functionalized Mn3O4 as support for FeNiB alloy to construct sono-Fenton-like reaction for the degradation of antibiotic pollutants in water | |
| CN105536773B (en) | Substrate catalyst of making pottery and preparation method thereof | |
| CN105381806A (en) | Novel supported manganese sulfate ozone catalyst as well as preparation method and application thereof | |
| CN102008965A (en) | Method for preparing ozone catalytic oxidation catalyst for treating cyanide waste water | |
| Cui et al. | Reverse Osmosis coupling Multi-Catalytic Ozonation (RO-MCO) in treating printing and dyeing wastewater and membrane concentrate: Removal performance and mechanism | |
| Yueyu | The synergistic degradation of pollutants in water by photocatalysis and PMS activation | |
| CN115282979B (en) | Preparation method and application of modified manganese-based heterogeneous ozone catalyst |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100519 |