CN101177238A - Hydroboron hydrogen generator using soft package - Google Patents
Hydroboron hydrogen generator using soft package Download PDFInfo
- Publication number
- CN101177238A CN101177238A CNA200710156161XA CN200710156161A CN101177238A CN 101177238 A CN101177238 A CN 101177238A CN A200710156161X A CNA200710156161X A CN A200710156161XA CN 200710156161 A CN200710156161 A CN 200710156161A CN 101177238 A CN101177238 A CN 101177238A
- Authority
- CN
- China
- Prior art keywords
- hydroborate
- soft package
- hydrogen generator
- hydrogen
- nabh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 69
- 239000001257 hydrogen Substances 0.000 title claims abstract description 69
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000007788 liquid Substances 0.000 claims abstract description 44
- 238000003860 storage Methods 0.000 claims abstract description 40
- 239000007787 solid Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000008247 solid mixture Substances 0.000 claims abstract description 10
- 239000012528 membrane Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- -1 polyethylene Polymers 0.000 claims description 11
- 239000012530 fluid Substances 0.000 claims description 10
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical group [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 9
- 239000010409 thin film Substances 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 239000000446 fuel Substances 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 239000003575 carbonaceous material Substances 0.000 claims description 3
- 239000012876 carrier material Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000002808 molecular sieve Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical group 0.000 claims description 3
- 239000012279 sodium borohydride Substances 0.000 abstract description 25
- 229910000033 sodium borohydride Inorganic materials 0.000 abstract description 25
- 238000004806 packaging method and process Methods 0.000 abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 239000000376 reactant Substances 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 150000002431 hydrogen Chemical class 0.000 description 12
- 230000000694 effects Effects 0.000 description 7
- 230000001186 cumulative effect Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000012448 Lithium borohydride Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Fuel Cell (AREA)
Abstract
The invention discloses a borohydride hydrogen generator using soft packaging, comprising a soft packaging bag, a flow regulator, a reactor and a gas-liquid separator, which are connected mutually; wherein, a liquid inlet is arranged on the soft packaging bag; the soft packaging bag comprises a new solution storage cavity and a waste solution storage cavity which are formed with three layers of membranes, borohydride solid compounds; borohydride solid mixture or water solution of borohydride mixture is arranged in the new solution storage cavity of the soft packaging bag, and hydrogen generation catalyst is arranged in the generator. As membrane is adopted to divide the soft packaging bag into two cavities, the invention not only meets the requirement of reaction, but also enables the reactant to share space with the resultants, so as to save the space; thereby the system reaches minimum volume at any time, and the sodium borohydride hydrogen generator is more superior than other hydrogen generation systems in weight, volume and hydrogen storage density.
Description
Technical field
The present invention relates to a kind of hydroborate hydrogen generator that uses soft package.
Background technology
Hydrogen Energy is a kind of secondary energy of cleaning.Foundation is the problem that the renewable energy source system of carrier can solve present energy shortage and these two big serious restriction Economic developments of environmental pollution effectively with hydrogen.In recent years the leap raising of fuel cell on performance also provides wide prospect for the use of Hydrogen Energy.But also do not find a kind of energy economical, efficient at present, store the method for hydrogen safely, thereby hindered the commercialization process of fuel cell to a great extent.
Under this background, hydroborate (M (BH
4) n, M=Li, Na, K, Mg, Al etc.) especially sodium borohydride is because of its hydrogen content up to 10.6wt%, and under the effect of catalyzer, can emit whole hydrogen at normal temperatures and gazed at:
NaBH
4+2H
2O＝NaBO
2+4H
2
In above-mentioned reaction, can generate the weight that the hydrogen amount accounts for reactant and reach 10.8wt%.In addition, the gas resultant of sodium borohydride hydrolysis reaction has only hydrogen, does not contain the impurity that carbon monoxide etc. might be poisoned fuel battery performance.Therefore, sodium borohydride is particularly suitable as the hydrogen source of fuel cell.
Consider the Commercial Prospect of sodium borohydride as the portable hydrogen source of small-sized and micro fuel cell (power is less than 100W), be energy safety, use easily, it is principle that the present invention produces hydrogen with the sodium borohydride catalyzing hydrolyzation reaction, make a kind of safety easy to carry, the hydrogen-storage density height uses simple portable apparatus for forming hydrogen.
Summary of the invention
The purpose of this invention is to provide a kind of hydroborate hydrogen generator that uses soft package.
Use the hydroborate hydrogen generator of soft package to have soft package bag, flow regulator, reactor, the gas-liquid separator that is connected, on the soft package bag, be provided with fluid inlet, the soft package bag is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, the aqueous solution of hydroborate solid chemical compound, hydroborate solid mixture or hydroborate mixture is housed in the soft package bag new soln liquid storage space, hydrogen generation catalyzer is housed in the reactor.
Described soft package bag 1 volume is 5-500ml.The material of borohydride fuel soft package bag 1 is a polyethylene, polypropylene, poly-third ethene, polystyrene, polyvinylidene chloride, polymeric amide, polyvinyl alcohol, the composite membrane of these materials or aluminum-plastic composite membrane.The hydroborate solid chemical compound is LiBH
4, NaBH
4Or KBH
4The hydroborate solid mixture is LiBH
4, NaBH
4Or KBH
4Mixture with stablizer.The hydroborate solid mixture aqueous solution is LiBH
4, NaBH
4Or KBH
4The aqueous solution with stablizer.With LiBH
4, NaBH
4Or KBH
4Corresponding stablizer is LiOH, NaOH or KOH, and the weight ratio of hydroborate solid chemical compound and stablizer is 1: 0.1-1.LiBH
4, NaBH
4Or KBH
4With LiBH in the aqueous solution of stablizer
4, NaBH
4Or KBH
4Weight percent concentration be 1-50%, the stablizer weight percent concentration is 1-10%.Hydrogen generation catalyzer is transition metal Fe, Co, Ni, Cu, Pd, Pt, Ru and alloy thereof, or the thunder Buddhist nun type catalyzer of these elements and alloy thereof.Hydrogen generation catalyzer is held in Al by load
2O
3, molecular sieve, various carbon materials are on resin or the foam metal carrier material.
The present invention is producing, and in the processes such as accumulating, the mixture of sodium borohydride or sodium borohydride and stablizer is encapsulated in the soft packaging bag with solid form.The volume of hydrogen production bioreactor minimizes before using like this.And owing in preservation and storage and transport process, do not make solution, eliminated the possibility of sodium borohydride hydrolysis in this process, improved security and high efficiency in the storage process greatly.Because though sodium borohydride solution has certain stability under catalyst-free and the situation that has stablizer such as sodium hydroxide to exist, but still with faint speed and water reaction, so have certain potential safety hazard.In addition, big too with solution form accumulating volume.Sodium borohydride is encapsulated in the soft packaging separately or after sodium borohydride and the few stable agent mixing, and the water wiring solution-forming reinjects before the use.The volume of producer remains at minimum before can using like this, does not also have any inconvenience during use.Compare with rigid container, soft package can make device not account for unnecessary volume all along.
On the other hand, because hydrolysis reaction speed is subjected to the influence of sodium borohydride concentration in the solution, concerning big multi-catalyst, reaction is first order reaction kinetics, i.e. speed of response and the proportional relation of sodium borohydride concentration.For making speed of response reach invariable, be necessary to make that sodium borohydride solution is disposable promptly finishes reaction by reactor, enter waste fluid container then.So just need two containers, take one times space.If use the present invention to cut apart two spaces with film, can reach the requirement of reaction, can make the reactant and the resultant communal space again and seldom account for volume.So just make system at any time can both reach volume and minimize, thereby the sodium borohydride hydrogen generator is all had superiority than other hydrogen generation systems on the weight and volume hydrogen-storage density.
Description of drawings
Accompanying drawing is a soft packaging hydrogen generator structural representation, among the figure: soft package bag 1, new soln liquid storage space 1 (a), lean solution liquid storage space 1 (b), flow regulator 2, reactor 3, gas-liquid separator 4, fluid inlet 5.
Embodiment
As shown in drawings, use the hydroborate hydrogen generator of soft package to have soft package bag 1, flow regulator 2, reactor 3, the gas-liquid separator 4 that is connected, on soft package bag 1, be provided with fluid inlet 5, soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, the aqueous solution of hydroborate solid chemical compound, hydroborate solid mixture or hydroborate mixture is housed in the soft package bag 1 new soln liquid storage space, hydrogen generation catalyzer is housed in the reactor 3.
Described soft package bag 1 volume is 5-500ml.The material of borohydride fuel soft package bag 1 is a polyethylene, polypropylene, poly-third ethene, polystyrene, polyvinylidene chloride, polymeric amide, polyvinyl alcohol, the composite membrane of these materials or aluminum-plastic composite membrane.The hydroborate solid chemical compound is LiBH
4, NaBH
4Or KBH
4The hydroborate solid mixture is LiBH
4, NaBH
4Or KBH
4Mixture with stablizer.The hydroborate solid mixture aqueous solution is LiBH
4, NaBH
4Or KBH
4The aqueous solution with stablizer.With LiBH
4, NaBH
4Or KBH
4Corresponding stablizer is LiOH, NaOH or KOH, and the weight ratio of hydroborate solid chemical compound and stablizer is 1: 0.1-1.LiBH
4, NaBH
4Or KBH
4With LiBH in the aqueous solution of stablizer
4, NaBH
4Or KBH
4Weight percent concentration be 1-50%, the stablizer weight percent concentration is 1-10%.Hydrogen generation catalyzer is transition metal Fe, Co, Ni, Cu, Pd, Pt, Ru and alloy thereof, or the thunder Buddhist nun type catalyzer of these elements and alloy thereof.Hydrogen generation catalyzer is held in Al by load
2O
3, molecular sieve, various carbon materials are on resin or the foam metal carrier material.
Embodiment 1
Soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, and cumulative volume is 200ml.Wrapping material are polyethylene film.In the new soln liquid storage space of soft package bag 1 sodium borohydride (NaBH is housed
4) 30g and sodium hydroxide 5g.Inject water 165g from fluid inlet, form sodium borohydride solution in new soln liquid storage space.Open flow regulator 2 and make the solution inflow reactor, 5g Ni/Al is housed in the reactor 3
2O
3Hydrogen generation catalyzer, solution produce 0.5 liter/minute hydrogen under the effect of catalyzer, hydrogen separates at gas-liquid separator 4 places with raffinate, and raffinate flows into the lean solution liquid storage space of soft packaging bag.Common property hydrogen 68 standard cube liters.
Embodiment 2
Soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, and cumulative volume is 100ml.The packing bag skin is an aluminum-plastic composite membrane, and two liquid storage spatial separate layers are polyvinylidene chloride.In the new soln liquid storage space of soft package bag 1 sodium borohydride (NaBH is housed
4) 15g, sodium hydroxide 5g, water 80g.Open flow regulator 2 and make the solution inflow reactor, 2g Co/Al is housed in the reactor 3
2O
3Hydrogen generation catalyzer, solution produce 0.2 liter/minute hydrogen under the effect of catalyzer, hydrogen separates at gas-liquid separator 4 places with raffinate, and raffinate flows into the lean solution liquid storage space of soft packaging bag.Common property hydrogen 33.8 standard cube liters.
Embodiment 3
Soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, and cumulative volume is 500ml.Wrapping material are polyethylene film.In the new soln liquid storage space of soft package bag 1 sodium borohydride (NaBH is housed
4) 75g.Inject water 425g from fluid inlet, form sodium borohydride solution in new soln liquid storage space.Open flow regulator 2 and make the solution inflow reactor, 5g Ni/Al is housed in the reactor 3
2O
3Hydrogen generation catalyzer, solution produce 0.5 liter/minute hydrogen under the effect of catalyzer, hydrogen separates at gas-liquid separator 4 places with raffinate, and raffinate flows into the lean solution liquid storage space of soft packaging bag.Common property hydrogen 168 standard cube liters.
Embodiment 4
Soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, and cumulative volume is 200ml.Wrapping material are polyethylene film.In the new soln liquid storage space of soft package bag 1 sodium borohydride (NaBH is housed
4) 40g and sodium hydroxide 5g.Inject water 155g from fluid inlet, form sodium borohydride solution in new soln liquid storage space.Open flow regulator 2 and make the solution inflow reactor, 2g Pt/Al is housed in the reactor 3
2O
3Hydrogen generation catalyzer, solution produce 1 liter/minute hydrogen under the effect of catalyzer, hydrogen separates at gas-liquid separator 4 places with raffinate, and raffinate flows into the lean solution liquid storage space of soft packaging bag.Common property hydrogen 85 standard cube liters.
Embodiment 5
Soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, and cumulative volume is 100ml.Wrapping material are polyethylene film.In the new soln liquid storage space of soft package bag 1 lithium borohydride (LiBH is housed
4) 10g and lithium hydroxide 5g.Inject water 85g from fluid inlet, form lithium borohydride solution in new soln liquid storage space.Open flow regulator 2 and make the solution inflow reactor, 2g Pt/Al is housed in the reactor 3
2O
3Hydrogen generation catalyzer, solution produce 0.25 liter/minute hydrogen under the effect of catalyzer, hydrogen separates at gas-liquid separator 4 places with raffinate, and raffinate flows into the lean solution liquid storage space of soft packaging bag.Common property hydrogen 40.5 standard cube liters.
Embodiment 6
Soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, and cumulative volume is 100ml.Wrapping material are polyethylene film.In the new soln liquid storage space of soft package bag 1 sodium borohydride (KBH is housed
4) 10g and potassium hydroxide 2g.Inject water 88g from fluid inlet, form sodium borohydride solution in new soln liquid storage space.Open flow regulator 2 and make the solution inflow reactor, 2g Ru/ foam ni-mh generation catalyzer is housed in the reactor 3, solution produces 0.2 liter/minute hydrogen under the effect of catalyzer, hydrogen separates at gas-liquid separator 4 places with raffinate, and raffinate flows into the lean solution liquid storage space of soft packaging bag.Common property hydrogen 15 standard cube liters.
Claims (10)
1. hydroborate hydrogen generator that uses soft package, it is characterized in that having the soft package bag 1, flow regulator 2, reactor 3, the gas-liquid separator 4 that are connected, on soft package bag 1, be provided with fluid inlet 5, soft package bag 1 is formed new soln and two liquid storage spaces of lean solution by three-layer thin-film, the aqueous solution of hydroborate solid chemical compound, hydroborate solid mixture or hydroborate mixture is housed in the soft package bag 1 new soln liquid storage space, hydrogen generation catalyzer is housed in the reactor 3.
2. a kind of hydroborate hydrogen generator that uses soft package according to claim 1 is characterized in that described soft package bag 1 volume is 5-500ml.
3. a kind of hydroborate hydrogen generator that uses soft package according to claim 1, it is characterized in that, the material of described borohydride fuel soft package bag 1 is a polyethylene, polypropylene, poly-third ethene, polystyrene, polyvinylidene chloride, polymeric amide, polyvinyl alcohol, the composite membrane of these materials or aluminum-plastic composite membrane.
4. a kind of hydroborate hydrogen generator that uses soft package according to claim 1 is characterized in that described hydroborate solid chemical compound is LiBH
4, NaBH
4Or KBH
4
5. a kind of hydroborate hydrogen generator that uses soft package according to claim 1 is characterized in that described hydroborate solid mixture is LiBH
4, NaBH
4Or KBH
4Mixture with stablizer.
6. a kind of hydroborate hydrogen generator that uses soft package according to claim 1 is characterized in that the described hydroborate solid mixture aqueous solution is LiBH
4, NaBH
4Or KBH
4The aqueous solution with stablizer.
7. a kind of hydroborate hydrogen generator that uses soft package according to claim 5 is characterized in that described and LiBH
4, NaBH
4Or KBH
4Corresponding stablizer is LiOH, NaOH or KOH, and the weight ratio of hydroborate solid chemical compound and stablizer is 1: 0.1-1.
8. a kind of hydroborate hydrogen generator that uses soft package according to claim 6 is characterized in that described LiBH
4, NaBH
4Or KBH
4With LiBH in the aqueous solution of stablizer
4, NaBH
4Or KBH
4Weight percent concentration be 1-50%, the stablizer weight percent concentration is 1-10%.
9. a kind of hydroborate hydrogen generator that uses soft package according to claim 1 is characterized in that described hydrogen generation catalyzer is transition metal Fe, Co, Ni, Cu, Pd, Pt, Ru and alloy thereof, or the thunder Buddhist nun type catalyzer of these elements and alloy thereof.
10. a kind of hydroborate hydrogen generator that uses soft package according to claim 1 is characterized in that described hydrogen generation catalyzer is held in Al by load
2O
3, molecular sieve, various carbon materials are on resin or the foam metal carrier material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200710156161XA CN101177238A (en) | 2007-10-19 | 2007-10-19 | Hydroboron hydrogen generator using soft package |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200710156161XA CN101177238A (en) | 2007-10-19 | 2007-10-19 | Hydroboron hydrogen generator using soft package |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101177238A true CN101177238A (en) | 2008-05-14 |
Family
ID=39403689
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200710156161XA Pending CN101177238A (en) | 2007-10-19 | 2007-10-19 | Hydroboron hydrogen generator using soft package |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101177238A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101633492B (en) * | 2008-07-22 | 2013-02-27 | 汉能科技有限公司 | Solid hydroboron hydrogen production method and device thereof |
| CN108883930A (en) * | 2015-11-06 | 2018-11-23 | H2燃料系统有限公司 | Obtain method and apparatus, the corresponding mixture for generating the mixture of H2 |
| CN109273741A (en) * | 2018-11-01 | 2019-01-25 | 上海重塑能源科技有限公司 | The hydrogen of fuel cell system is separated from water device and its working method |
-
2007
- 2007-10-19 CN CNA200710156161XA patent/CN101177238A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101633492B (en) * | 2008-07-22 | 2013-02-27 | 汉能科技有限公司 | Solid hydroboron hydrogen production method and device thereof |
| CN108883930A (en) * | 2015-11-06 | 2018-11-23 | H2燃料系统有限公司 | Obtain method and apparatus, the corresponding mixture for generating the mixture of H2 |
| CN109273741A (en) * | 2018-11-01 | 2019-01-25 | 上海重塑能源科技有限公司 | The hydrogen of fuel cell system is separated from water device and its working method |
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Open date: 20080514 |