CN101144039A - Biodegradable fuel performance additives - Google Patents

Biodegradable fuel performance additives Download PDF

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Publication number
CN101144039A
CN101144039A CNA200710005387XA CN200710005387A CN101144039A CN 101144039 A CN101144039 A CN 101144039A CN A200710005387X A CNA200710005387X A CN A200710005387XA CN 200710005387 A CN200710005387 A CN 200710005387A CN 101144039 A CN101144039 A CN 101144039A
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China
Prior art keywords
oil
fuel
engine
carrier oil
plant
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Granted
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CNA200710005387XA
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CN101144039B (en
Inventor
L·J·卡宁哈姆
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Afton Chemical Corp
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Afton Chemical Corp
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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224—Amides; Imides carboxylic acid amides, imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B47/00—Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines
    • F02B47/04—Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines the substances being other than water or steam only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/191—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polyhydroxyalcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/221—Organic compounds containing nitrogen compounds of uncertain formula; reaction products where mixtures of compounds are obtained
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

There is disclosed a biodegradable fuel additive composition derived from at least one animal or plant source, and a fuel composition containing a biodegradable fuel additive composition derived from at least one animal or plant source useful for reducing the formation of engine deposits and for improving fuel economy of a vehicle combusting the fuel composition.

Description

Biodegradable fuel performance additives
Technical field
[0001] the present invention relates to reducing the formation or the existence of oil thrower, valve and other engine deposits, for improving fuel economy and protecting gasoline that engine avoids wearing and tearing and the biodegradable and biodegradable additive of part of diesel oil.The present invention provides especially in one embodiment as the biodegradable and biodegradable carrying object of the part of gasoline and diesel fuel additive or carrier oil and the biodegradable and biodegradable sanitising agent of part.
Background technology
[0002] be known with biology-derivatived fuel such as ethanol and biofuel as the blending ingredients of diesel oil fuel and gasoline.But still need at present to be applicable to the biology-deutero-of gasoline and diesel oil fuel and/or biodegradable or to the biodegradable fuel dope of small part.Especially need to be applicable to the improved carrying object and the sanitising agent of gasoline and diesel oil fuel.
[0003] fuel providers has begun exploitation and has and can help to overcome the existing circumscribed advanced biofuel of biofuel.This work has at present proceeded to supply can be for enlarging the advanced biofuel that energy supply provides better option and quickens to shift to renewable communications and transportation fuel.
[0004] many companies are utilizing fuel technology expert and market secret formula to promote biotechnology and biological manufacturing capacity.By concentrating the knowledge and the expert of this respect, many companies are intended to improve the development and the production of advanced biofuel, thereby promote the growth of biofuel.Existing plan shows, biofuel and biodegradable fuel dope will become integral part in the communications and transportation fuel mixture in future.
[0005] one of Shang Shi firstling is derived from the ethanol of cereal and the biofuel of being made up of plant-derived and zoogenous fatty acid methyl ester.Advanced biofuel is likely the biological butanol as the gasoline biological components.Although the existence of biological components has proved the good starting point of introducing biofuel and biofuel additive and will continue to work in future, could improve market penetration power but still need to solve some problems.Especially determine to have needed improved field to have: with the consistency of existing supply of fuel and marketing system, need not to change vehicle and can be with higher concentration blended ability and fuel economy.
Summary of the invention
[0006] the present invention provides the carrier oil composition that comprises derived from least a plant or zoogenous Biodegradable vehicles oil in one embodiment.
[0007] in another embodiment of the invention, provides to comprise the fuel cleanser compositions that is derived from least a plant or zoogenous biodegradable sanitising agent.
[0008] provide fuel cleaning additive bag in yet another embodiment of the present invention, it comprises derived from least a plant or zoogenous Biodegradable vehicles oil and the sanitising agent that comprises derived from least a plant or zoogenous amine-functionalized hydrocarbonaceous Biodegradable vehicles oil.
[0009] another embodiment of the present invention comprises gasoline or Dresel fuel compositions, and said composition comprises gasoline, sanitising agent and at least a derived from least a plant or zoogenous Biodegradable vehicles oil.
[0010] another embodiment of the present invention comprises gasoline or Dresel fuel compositions, said composition comprise fuel, derived from least a plant or zoogenous biodegradable sanitising agent and, randomly, carrier oil.
[0011] reduce the method that engine deposits form in the engine that also has the class A fuel A that an embodiment is provided at burns gasoline or diesel oil of the present invention, this method is included in the fuel composition that the engine internal combustion comprises following component: most component boiling points are 15 ℃～400 ℃ fuel, are selected from the sanitising agent of succinimide, Mannichs and polyetheramine and at least a derived from least a plant or zoogenous carrier oil.Other embodiment comprises that the boiling point of fuel is 15 ℃～225 ℃ a method, and to also have some embodiments to have boiling point be 150 ℃～400 ℃ fuel.
[0012] according to the present invention, the plant-sourced of derivative vector oil can comprise be derived from least a, for example, but be not limited to, be selected from following one group plant-sourced: common vetch (vetch), fescue grass (fescue), trifolium (clover), oat (oats), naked barley (rye), paddy rice (rice), hop (hops), barley (barley), alfalfa (alfalfa), pod beans (legumes), beet (sugar beets), corn grain (corn grain), wheat (wheat), potato (potatoes), Radix Dauci Sativae (carrots), sugarcane (sugarcane), jowar (sorghum), corn stem (corn stalks), soya-bean oil (soy bean oil), Viscotrol C (castor oil), Semen Brassicae campestris (rape seed), simmondsia (jojoba), switchgrass (switchgrass), weeds (field grass), marine alga (seaweed) and their mixture and other biomass sources.Be suitable for zoogenous example and comprise at least a following one group animal source that is selected from: animal tallow, tallow, lard, butter and fish oil and their mixture.
[0013] uses method of the present invention, when the fuel combustion of the gasoline that contains biodegradable or the biodegradable fuel dope carrying object of part and/or biodegradable or the biodegradable sanitising agent of part or diesel oil fuel and so on, reduce and/or prevent direct or indirect engine deposits, fuel injector deposits, air intake valve settling (" IVD ") and combustion chamber deposit (" CCD ").Implementing another benefit of the present invention is, in one embodiment, improves the fuel economy of vehicle.Of the present invention also have a benefit to be, in one embodiment, and because of existing carrying object and/or sanitising agent and lubricity thereof to improve or improving frictional behaviour in the combustion engine.Another benefit of the present invention is, in one embodiment, and because of existing biodegradable carrying object and/or biodegradable sanitising agent to improve in the fuel or improving low temperature viscosity and cause reducing valve gluing.
[0014] other purpose of the present invention and advantage are enumerated part in the following discussion and/or can be realized by implementing the present invention.Objects and advantages of the present invention will be utilized the main idea pointed out especially and combination thereof and be achieved and obtain in claims.
[0015] no matter should be understood that the general introduction of front or detailed description hereinafter all only is to give an example with indicative, rather than of the present invention as what is claimed is restriction.
Embodiment
[0016] in an inventive point of the present invention, provide derived from least a plant or animal source and can use for example to be the further hydrocarbonaceous Biodegradable vehicles oil that characterizes of following performance:
Settling weight %≤5% is (with the test of Penn attitude low-level oxidation *Measure)
Knoack volatility≤50 weight %
Pour point≤0 ℃
Viscosity index 〉=85
Viscosity (100 ℃)≤125 cSt
Sulphur≤50ppm
*The test of Penn attitude low-level oxidation has been described among the Society of Automotive EngineersTechnical Paper 87028.
[0017] the Knoack volatility of carrier oil can be less than in about 50 weight %～greater than about 5 weight % scopes, or less than about 35 weight %～greater than about 20 weight %.In one embodiment, the pour point of carrier oil can be about 0 ℃～-15 ℃ approximately, or in another embodiment, about 0 ℃～-35 ℃ approximately.Carrier oil can be in about 125cSt～about 5cSt scope 100 ℃ viscosity, or in another embodiment, about 75cSt～about 10cSt.The sulphur concentration of carrier oil is unrestricted in this article, but in the embodiment of this paper, is about 5ppm～about 500ppm, or about 10ppm～about 200ppm.Final sulphur concentration in finished product fuel will be determined with the treatment rate of other sulphur source and carrying object.The carrier oil viscosity in this article refers to them under undiluted state, promptly add any other fuel element or mix with it before viscosity.Penn attitude low-level oxidation is tested settling weight in about 0%～5% scope, or in another embodiment, between about 0.5%～2.5%.
[0018] in some embodiment of the present invention, the molecular-weight average of carrier oil in about 500～about 3000 scopes, in another embodiment, for about 750～about 2500, and in another embodiment, be about 1000～about 2000.
[0019] plant-sourced of derivative vector oil can comprise at least a being selected from, for example, but be not limited to following one group plant-sourced: common vetch, fescue grass, trifolium, oat, naked barley, paddy rice, hop, barley, alfalfa, pod beans, beet, corn grain, wheat, potato, Radix Dauci Sativae, sugarcane, palm, palm-kernel, canola, leprosy grass, jowar, corn stem, soya-bean oil, Viscotrol C, Semen Brassicae campestris, simmondsia, switchgrass, weeds, marine alga, other biomass sources and their mixture.Be suitable for zoogenous example and can comprise at least a following one group animal source that is selected from: animal tallow, tallow, lard, butter and fish oil and their mixture.
[0020] according to the present invention plant-derived or zoogenous oil can be used for or as before the carrier oil composition through chemical treatment.For example, can pass through at least a following one group processing that is selected from derived from least a plant or zoogenous oil: the hydrogenation of carbon-to-carbon double bond, partial hydrogenation, esterification and functionalized.Carrying object also can carry out amination with in the several methods known in the art any one, to improve the efficient of bio-derived material.
[0021] from plant or zoogenous starting material may especially the allyl key be easily oxidized because of there being a plurality of pairs of keys.The hydrogenation of two keys or functionalized can making from plant or zoogenous starting material more are applicable to as carrier oil.In addition, the concentration of hydroxyl may should not be used as carrier oil in the starting material of plant or animal derived, and in some cases, can or functionalizedly be modified to more suitable level by hydrogenation.Functionizing method can comprise, for example, and esterification, amination, epoxidation etc.Those of ordinary skill in the art can both select the ideal performance of derivative vector oil and/or sanitising agent and select the modification route to obtain the ideal the finished product.
[0022] in some embodiment of the present invention, carrier oil can be that part is biodegradable.Though what provide in one embodiment is the carrier oil of totally biodegradable, between the required chemistry of carrier oil or physicals and its biodegradable, can adjust.
[0023] another embodiment of the invention provides fuel cleaning additive bag, and it comprises derived from least a plant or zoogenous Biodegradable vehicles oil and the sanitising agent that comprises derived from least a plant or zoogenous amine-functionalized hydrocarbonaceous Biodegradable vehicles oil.In this embodiment, sanitising agent is combined in or is suspended on or derived from least a plant or animal source deutero-Biodegradable vehicles oil.For each component in the fuel cleaning additive bag, in conjunction with can be the same or different thereon derived from least a plant or zoogenous hydrocarbonaceous Biodegradable vehicles oil.In fuel composition of the present invention and fuel additive composition, can comprise other additive, as long as to having no adverse effect by the performance of implementing the accessible engine oil of the present invention.Therefore in this class A fuel A additive or fuel composition, can use following component: organic peroxy ester, inhibiter, antioxidant, rust-preventive agent, sanitising agent and dispersion agent, lubricant, emulsion splitter, dyestuff, pour point reducer, cold flow improver, inert diluent etc. and manganese source or other containing metal ignition improver.
[0024] in one embodiment, but not as restriction of the present invention, carrier oil component in the fuel cleaning additive bag has following properties: the Knoack volatility is less than or equal to about 50 weight %, pour point is less than or equal to about 0 ℃, viscosity index is more than or equal to 85, and sulphur concentration is less than or equal to about 50ppm and Penn attitude low-level oxidation test settling weight is less than or equal to 5%.Carrier oil can have one or multinomial performance reach shown in level, and be independent of other performance.
[0025] in some embodiment of fuel cleaning additive bag, the plant and animal source of carrier oil can comprise at least a plant and animal source that is selected from the listed source of plant and animal on the same group of preamble.
[0026] in one embodiment, sanitising agent and carrier oil can make up in about 1: 4～about 4: 1 ratio.Particularly advantageous weight ratio scope is about 1: 100～about 100: 1.The ratio of sanitising agent and carrier oil to be being not that benchmark calculates with the clean carrier oil of solvent cut and sanitising agent,
[0027] in some embodiment according to fuel cleaning additive bag of the present invention, hydrocarbonaceous Biodegradable vehicles oil can be derived from least a plant or zoogenous oil.Described oil can pass through at least a following one group chemical treatment that is selected from: the hydrogenation of carbon-to-carbon double bond, partial hydrogenation, esterification and functionalized.Reaction or the degree of handling and handling can be selected to obtain having suitable oil as the ideal performance of carrier oil in the fuel dope bag of the present invention.
[0028] sanitising agent in the fuel cleaning additive bag can comprise derived from least a plant or zoogenous amine-functionalized hydrocarbonaceous Biodegradable vehicles oil.In some embodiment of fuel cleaning additive bag, be used for producing sanitising agent derived from least a plant or zoogenous hydrocarbonaceous Biodegradable vehicles oil can be used as carrier oil derived from least a plant or zoogenous hydrocarbonaceous Biodegradable vehicles oil phase with.
[0029] the method that becomes sanitising agent in the fuel cleaning additive bag derived from the modification of at least a plant or zoogenous hydrocarbonaceous Biodegradable vehicles oil, except amination, can comprise that also the cyano group alkylation reduces then, to obtain the amine-functionalized hydrocarbon compound that contains with desirable sanitising agent performance level.
[0030] no matter various sanitising agents alone or in combination, all are applicable to the present invention, and enforcement of the present invention can expand to all compounds that are applicable to that imperfect precipitation of further minimizing and settling form.
[0031] is the sanitising agent that dissolves in fuel according to the present invention used sanitising agent or dispersion agent, comprises that the long-chain fat hydrocarbon that dissolves in fuel replaces salt, acid amides, imide,  azoles quinoline or ester or their mixture of dicarboxylic acid or its acid anhydrides; Polyetheramine; Have the amine that directly is combined on the chain or the long-chain fat hydrocarbon of polyamine; And by long-chain fat hydrocarbon fortified phenol or cresols and aldehyde (preferred formaldehyde) and monoamine or the formed Mannich condensation product of polyamines condensation.
[0032] in some embodiment, sanitising agent is derived from least a plant or animal source, and it forms amine through after the amination, also can be polyamine.Described amine can comprise at least one amino with at least one active hydrogen atom.Preferably will have and on average contain at least about 10 derived from plant or zoogenous component, preferably at least about 15, more preferably at least about the aliphatic chain of 17 carbon atoms (saturated or the alkene class is unsaturated), so that fuel has for playing needed fuel dissolution degree of sanitising agent effect and stability effectively.
[0033] another embodiment of the invention comprise have Fuel Petroleum, sanitising agent and at least a gasoline composition derived from least a plant or zoogenous biodegradable carrier oil.
[0034] the carrier oil component in the gasoline composition can have following performance: the Knoack volatility is less than or equal to about 50 weight %, pour point is less than or equal to about 0 ℃, viscosity index is more than or equal to about 85, and sulphur concentration is less than or equal to about 50ppm and low-level oxidation settling weight (test of Penn attitude low-level oxidation) is less than or equal to 5%.Carrier oil can have one or multinomial performance reach shown in level, and be independent of other performance.
[0035] in according to gasoline composition of the present invention, sanitising agent can be at least a following one group material that is selected from: polyamine, polyetheramine, succinimide, succinic diamide, aliphatic polyamines and mannich detergents.
[0036] can comprise also that according to gasoline composition of the present invention fuel is the embodiment of biofuel (as ethanol and/or biological butanol).
[0037] in some embodiment of fuel composition, fuel can comprise that about 50～about 99.999 weight % Fuel Petroleums, about 0.001～about 3.0 weight % sanitising agents and about 0.001～about 3.0 weight % are derived from least a plant or zoogenous carrier oil.
[0038] another embodiment of the invention comprises by comprising that in the engine internal combustion fuel composition of following component reduces the method that forms engine deposits in the engine at combustion fuel: about 15 ℃～about 225 ℃ fuel, sanitising agent and at least a derived from least a plant or zoogenous carrier oil of most boiling points.Used a kind of fuel can be or comprises gasoline in this method.
[0039] another embodiment of the invention comprises by including but not limited to that in the engine internal combustion fuel composition of following component reduces the method that forms engine deposits in the engine at combustion fuel: the fuel of about 150 ℃ of most boiling points～about 400 ℃ and derived from least a plant or the zoogenous biodegradable or biodegradable sanitising agent of part.Used a kind of fuel can be or comprises diesel oil fuel in this method.
[0040] in the method that reduces engine deposits formation according to the present invention, carrier oil can be derived from the listed plant and animal source of preamble.
[0041] the carrier oil component of fuel used composition in the methods of the invention, in one embodiment, can have following performance: the Knoack volatility is less than or equal to about 50 weight %, pour point is less than or equal to about 0 ℃, viscosity index is more than or equal to about 85, and sulphur concentration is less than or equal to about 50ppm and Penn attitude low-level oxidation test settling weight is less than or equal to 5%.Carrier oil can have one or multinomial performance reach shown in level, and be independent of other performance.
[0042] in some embodiment of engine deposits minimizing method, sanitising agent can be at least a following one group material that is selected from: polyamine, polyetheramine, succinimide, succinic diamide, aliphatic poly-amine and mannich detergents.
[0043] in some embodiment of engine deposits minimizing method, basic fuel can be a biofuel, for example, and ethanol and/or biological butanol.In other embodiments, basic fuel can be the mixture of gasoline or gasoline and biofuel.
[0044] in some embodiment of the present invention, used basic fuel can comprise any basic fuel that is applicable to spark ignition internal combustion engine operation when the preparation of fuels composition, as leading or not leading motor gasoline and aviation spirit and contain the hydrocarbon of gasoline boiling spread usually simultaneously and dissolve in the so-called reformed gasoline of fuel oxidation mixture (" oxygenant ") as alcohol, ether and other suitable oxygen-containing organic compound.Preferably having the fuel of carrier oil therein can be the mixture of the hydrocarbon of boiling point in the gasoline boiling spread.Fuel can be made up of straight or branched alkane, cycloalkanes, alkene, aromatic hydrocarbons or their any mixture.Gasoline can be derived from virgin naphtha, polymer gasoline, natural gasoline, catalytically cracked gasoline, alkylide or derived from catalytic reforming raw material and other the refining or chemical feedstocks of boiling point in about 15 ℃～about 225 ℃ of scopes.The octane value of gasoline, vapour pressure and chemical constitution are not crucial, and any conventional gasoline, reformed gasoline or retail gasoline all can be used as and comprises that sulphur concentration is no more than 2000ppm and is low to moderate the basic fuel of the gasoline of 2ppm.
[0045] oxygenant of Shi Yonging can include, but not limited to mixture, methyl tertiary butyl ether, tertiary butyl amyl group methyl ether, Ethyl Tertisry Butyl Ether and the mixed ether of methyl alcohol, ethanol, n-propyl alcohol, Virahol, propyl carbinol, isopropylcarbinol, the trimethyl carbinol, C1～C5 alcohol.Oxygenant, when existing, the amount in basic fuel can be lower than about 30 volume %, and preferably its oxygen level of providing in whole fuel of amount is in about 0.5～about 5 volume % scopes.
[0046] also can use other fuel, comprise 100% ethanol, hydrate alcohol and be called 70%～85% ethanol of E85.
[0047] except that embodiment of the present invention, used basic fuel can comprise that should be used for compression-ignition engine operates when the preparation of fuels composition, as road driving and cross-country run, fixed, navigation and locomotive diesel engine, comprise being applicable to the diesel engine that produces power or other non-vehicle application such as diesel winning equipment.This fuel can comprise straight or branched alkane, cycloalkanes, alkene, aromatic hydrocarbons or their any mixture or be made up of above-mentioned substance.Diesel oil fuel can be derived from straight-run diesel oil, catalytic cracking light cycle oil, kerosene, natural gas liquefaction, coal liquefaction, biomass liquefying and other the refining or chemical feedstocks of boiling point in about 150 ℃～about 400 ℃ of scopes.Also can comprise other biologically-derived mixing raw material in the fuel, as, but be not limited to, fatty acid ester is for example derived from plant and/or zoogenous fatty acid methyl ester.The cetane value of diesel oil fuel and chemical constitution are not crucial, and any flammable liquid of boiling point in about 150 ℃～about 400 ℃ of scopes all can be used as basic fuel.
[0048] in some embodiment of fuel dope of the present invention and fuel composition, supplementary additive can exist with carrier oil as herein described and sanitising agent.The example of supplementary additive can comprise other carrier oil, dispersion agent/sanitising agent, oxidation inhibitor, metal passivator, dyestuff, marker, inhibiter, biocide, anti static additive, flow improver, emulsion splitter, de-misting agent, antifreeze additive, antiknock dope, anti-valve seat shrinks (anti-valve-seat recession) additive, cold flow improver, pour point reducer, lubricant, friction modified additive, the fuel economy additive, the octane improving agent, the n-Hexadecane improving agent, combustion improving agent and other similar additive and other additive that may be present in the gasoline maybe may be from processing, store or sell the additive that brings in the fuel.
[0049] used additive can be mixed into basic fuel respectively or with various sub-combinations thereof when preparation as the fuel that contains carrier oil and sanitising agent of the present invention.Preferably all components is blended together multifunctional additive for lubricating oils simultaneously, can bring into play the advantage of the property compatible with each other that the combination by component provides like this, also shorten the blend time simultaneously and reduce the possibility of mixing errors.
[0050] use the method for the present composition can comprise the method (" keeping clean ") that the minimizing engine deposits form and reduce the method (" cleaningization ") of engine deposits existence and the method that improves fuel economy.
[0051] the present invention relates to contain act as a fuel derived from the composition of plant and/or the zoogenous biodegradable and biodegradable oil of part and with them in the method for sanitising agent and other additive carrier.So target of the present invention is to add these biodegradable and composition, purposes, the system and method for the biodegradable oil of part to reduce or eliminate fuel injector, valve and combustion chamber deposit.More specifically, the present invention relates to comprise the fuel composition and the purposes of this fuel composition in various internal-combustion engine systems of fuel, carrier oil and sanitising agent.So-called " firing system " in this article refers to oil engine, for example, but be not limited to, the Atkinson cycle engine, Wankel engine, spray is led, wall is led with wall and is led/sprays and lead combination direct injection gasoline (" DIG ") engine, turbo-charging DIG engine, supercharging DIG engine, homogeneous combustion DIG engine, evenly/stratiform DIG engine, dispose the DIG engine that each injection all has the piezoelectric type oil thrower of a plurality of fuel impulses, dispose the DIG engine of EGR, the engine that has poor-NOx collector contains the engine of poor-NOx catalyzer, has the DIG engine of SN-CR NOx control, have the DIG engine that sprays (afterfire) behind the row's diesel oil that is used for NOx control, dispose the flexible fuel operation (as gasoline, ethanol, methyl alcohol, biofuel, synthol, Sweet natural gas, liquefied petroleum gas (LPG) (LPG) and composition thereof) DIG engine.Also comprise the oil engine of tradition and advanced inlet mouth fueling, no matter have or not advanced exhaust aftertreatment system ability, have or not turbo-charging, have or not supercharging, have or not combination supercharging/turbo-charging, have inaction burning and discharging to improve and the onboard capabilities of transmission additive and have or not vario valve regularly.Homogeneous charge compression ignition (HCCI) engine that also comprises the Fuel Petroleum of annotating, the diesel oil hcci engine, two-cycle engine, diesel-fueled engine, gasoline engines, stationary power generation machine, gasoline and diesel oil HCCI, supercharging, turbo charged gasoline and diesel oil direct injection ic engine can change the engine of valve timing, poor burn engine, engine and any other oil engine of energy passivation cylinder.Other example of firing system comprises any above-listed system and the combination of electric motor in motor vehicle driven by mixed power.
[0052], be derived from least a plant or the zoogenous biodegradable or biodegradable carrier oil of part especially unexpectedly or in fact sanitising agent can reduce and the settling that do not form in the increasing combustion engine according to the present invention.
[0053] as used herein, term " biofuel " uses by its original meaning, is well-known to those skilled in the art.Specifically, it is meant and originates from the oil or the fuel of other combustible portion of the living species of platymiscium and animal kingdom once.Their example comprises: tradition harvesting crop, oil-produced vegetable, animal and animal part etc.Here, " biofuel " fuel of also comprising organic substance and so on is as " biological butanol ", ethanol and " bio-ethanol ", other pure and mild alcohol mixture, hydrocarbon and the cut that distills from biofuel.Other example of biofuel is derived from plant or zoogenous fatty acid ester.
[0054] so-called " biodegradable " in this article refers to material by the susceptibility of microbiological degradation, and promptly compound can be by the speed of bacterium and/or the fracture of other factor of natural environment chemistry.
[0055] so-called " part is biodegradable ", in this article refer to accounted for by microbiological degradation or chemistry fracture whole at least about 30% and less than about 90%.
[0056] so-called " carrier oil " in this article refers to by making additives suspended or being dissolved in and helps fuel dope to disperse the into material of fuel in the fuel.So-called " carrier oil " and/or " carrying object ", also referring in this article provides fluidizing performance to fuel, or can " carry " or transport additive in fuel, and/or functional any oil or fluid except that dilution are provided.
[0057] so-called " sanitising agent " in this article refers to and can dissolve those and can form settling and/or do not need the element of compound or the compound of compound in fuel or engine and parts thereof.
[0058] all publications, paper, patent, patent publications and other reference quoted of this paper draws in this entirely for various purpose references.
[0059] though aforementioned content at the preferred embodiments of the invention, but need point out, for those skilled in the art, other change and modification will be conspicuous, and this class changes and revises and can carry out under prerequisite without departing from the spirit and scope of the present invention.
[0060] the following example provides the more complete understanding of the present invention in order to provide.For illustrating that concrete technology, condition, material that principle of the present invention is listed and the data of being reported all are illustrative, should not regard them as limitation of the scope of the invention.
Embodiment
[0061] can prepare 5 kinds of samples, wherein basic fuel (Colonial Pipeline " P/L " fuel) is tried separately, and 4 kinds of combinations of sanitising agent and carrier oil are as shown in table 1.The measurement of advancing valve deposits formation obtains by ASTM D-6201 test method(s).This test is estimated not with 2.3 liters of array 4 Cylinder engines of Ford, and the valve deposits that advances of leading spark plug engine fuel forms.
[0062] will test to determine benefit of the present invention carrier.The mineral oil vehicle (500N) of prior art, of the present invention 2 kinds derived from least a plant or zoogenous hydrocarbonaceous Biodegradable vehicles oil (CO-001, be soya-bean oil, and CO-002, be simmondsia oil) and 2 kinds of sanitising agent (D-001, i.e. polyisobutenyl succinimide and the D-002 that makes from 950MW polyisobutene, maleic anhydride and tetren, the i.e. Mannich that obtains from the reaction of cresols, 950MW polyisobutene, formaldehyde and polyamine) between compare.The weight ratio of sanitising agent and carrier oil is 1: 1, and basic fuel is Colonial Pipeline " P/L " fuel, and its performance is as described below.
The performance of test fuel (Colonial Pipeline " P/L " fuel)
Test subject Net result ASTM methods of test
Api gravity amount (@60 ) 60.6 D-4052
Distillation, gasoline () D-86
Initial boiling point 84.9
05% volatilization temperature 100.1
10% volatilization temperature 113.3
20% volatilization temperature 133.4
30% volatilization temperature 155.1
40% volatilization temperature 180.5
50% volatilization temperature 207.1
60% volatilization temperature 233.0
70% volatilization temperature 259.9
80% volatilization temperature 293.5
90% volatilization temperature 339.0
95% volatilization temperature 372.5
Final boiling point 437.5
The rate of recovery (volume %) 95.8
Residue (volume %) 1.2
Loss (volume %) 3.0
Type-the FIA of hydrocarbon
Aromatic hydrocarbons (LV%) 26.0 D1319
Alkene (LV%) 12.6
Stable hydrocarbon (LV%) 61.4
The fuel analysis report:
Test subject Net result ASTM methods of test
Inductive phase (min) 960+ D-525
Octane
Research octane 91.5 D-2699
Motor octane 82.6 D-2700
R+M/2 87.0
Table 2:Settling forms to be measured
Testing of engine result's (ASTM D-6201,2.3 liters of engines of Ford)
Basic fuel Sanitising agent Carrier Ratio Average IVD (mg/ valve) Average CCD (mg/ cylinder)
Colonial P/L (A) Do not have 500N(1) Do not have 415.6 1298
Colonial P/L (A) Do not have CO-001(2) Do not have <415 <1298
Colonial P/L (A) Do not have CO-002(2) Do not have <415 <1298
ColonialP/L (A) D-001 CO-001(2) 1/1 <415 <1298
Colonial P/L (A) D-002 CO-001(2) 1/1 <415 <1298
(1) standard mineral oil carrier
(2) biodegradable hydrocarbon oil carriers of the present invention
[0063] as shown in table 2, the Biodegradable vehicles oil of the application of the invention, the total amount such as the expection of advancing valve deposits (IVD) and combustion chamber deposit (CCD) have been reduced.In addition, by using Biodegradable vehicles of the present invention oil simultaneously and derived from the sanitising agent of Biodegradable vehicles oil of the present invention, the total amount such as the expection of advancing valve deposits (IVD) and combustion chamber deposit (CCD) have been reduced.

Claims (55)

1. comprise carrier oil composition derived from least a plant or zoogenous Biodegradable vehicles oil.
2. according to the carrier oil composition of claim 1, wherein the Knoack volatility of carrier oil is less than or equal to about 50 weight %.
3. according to the carrier oil composition of claim 1, wherein the pour point of carrier oil is less than or equal to about 0 ℃.
4. according to the carrier oil composition of claim 1, wherein the viscosity index of carrier oil is more than or equal to about 85.
5. according to the carrier oil composition of claim 1, wherein the sulphur concentration of carrier oil is less than or equal to about 50ppm.
6. according to the carrier oil composition of claim 1, wherein the Penn attitude low-level oxidation settling weight of carrier oil is less than 5%.
7. according to the carrier oil composition of claim 1, wherein plant-sourced comprises at least a following one group plant-sourced that is selected from: common vetch, fescue grass, trifolium, oat, naked barley, paddy rice, hop, barley, alfalfa, pod beans, beet, corn grain, wheat, potato, Radix Dauci Sativae, sugarcane, palm, palm-kernel, canola, leprosy grass, jowar, corn stem, soya-bean oil, Viscotrol C, Semen Brassicae campestris, simmondsia, switchgrass, weeds, marine alga, other biomass sources and their mixture.
8. according to the carrier oil composition of claim 1, wherein animal source comprises at least a following one group animal source that is selected from: animal tallow, tallow, lard, butter and fish oil.
9. according to the carrier oil composition of claim 1, wherein hydrocarbonaceous Biodegradable vehicles oil comprises derived from least a plant or zoogenous oil, and described oil will pass through at least a following one group processing that is selected from: the hydrogenation of carbon-to-carbon double bond, partial hydrogenation, esterification and functionalized.
10. according to the carrier oil composition of claim 1, wherein Biodegradable vehicles oil is that part is biodegradable.
11. comprise the fuel cleaning additive bag of following component:
Derived from least a plant or zoogenous Biodegradable vehicles oil and
The sanitising agent that comprises amine-functionalized Biodegradable vehicles oil, described Biodegradable vehicles oil is derived from least a plant or animal source.
12. according to the fuel cleaning additive bag of claim 11, wherein the Knoack volatility of carrier oil is less than or equal to about 50 weight %.
13. according to the fuel cleaning additive bag of claim 11, wherein the pour point of carrier oil is less than or equal to about 0 ℃.
14. according to the fuel cleaning additive bag of claim 11, wherein the viscosity index of carrier oil is more than or equal to about 85.
15. according to the fuel cleaning additive bag of claim 11, wherein the sulphur concentration of carrier oil is less than or equal to about 50ppm.
16. according to the fuel cleaning additive bag of claim 11, wherein the Penn attitude low-level oxidation settling weight of carrier oil is less than 5%.
17. according to the fuel cleaning additive bag of claim 11, wherein plant-sourced comprise be selected from following one group one of at least: common vetch, fescue grass, trifolium, oat, naked barley, paddy rice, hop, barley, alfalfa, pod beans, beet, corn grain, wheat, potato, Radix Dauci Sativae, sugarcane, palm, palm-kernel, canola, leprosy grass, jowar, corn stem, soya-bean oil, Viscotrol C, Semen Brassicae campestris, simmondsia, switchgrass, weeds, marine alga, other biomass sources and their mixture.
18. according to the fuel cleaning additive bag of claim 11, wherein animal source comprises at least a following one group animal source that is selected from: animal tallow, tallow, lard, butter and fish oil.
19. according to the fuel cleaning additive bag of claim 11, wherein the combination of sanitising agent and carrier oil ratio is about 1: 4～about 4: 1.
20. comprise the fuel cleaning additive bag of following component:
Derived from least a plant or zoogenous Biodegradable vehicles oil and
Non-derived from least a plant or zoogenous sanitising agent.
21. fuel cleaning additive bag according to claim 11, wherein Biodegradable vehicles oil comprises derived from least a plant or zoogenous oil, and described oil will pass through at least a following one group processing that is selected from: the hydrogenation of carbon-to-carbon double bond, partial hydrogenation, esterification and functionalized.
22. comprise the gasoline composition of following component:
Fuel Petroleum,
Sanitising agent and
At least a derived from least a plant or zoogenous hydrocarbonaceous Biodegradable vehicles oil.
23. according to the gasoline composition of claim 22, wherein carrier oil is selected from following one group plant-sourced derived from least a: common vetch, fescue grass, trifolium, oat, naked barley, paddy rice, hop, barley, alfalfa, pod beans, beet, corn grain, wheat, potato, Radix Dauci Sativae, sugarcane, jowar, corn stem, soya-bean oil, Viscotrol C, Semen Brassicae campestris, simmondsia, switchgrass, weeds, marine alga, other biomass sources and their mixture.
24. according to the gasoline composition of claim 22, wherein carrier oil is derived from being selected from following one group animal source: animal tallow, tallow, lard, butter and fish oil.
25. according to the gasoline composition of claim 22, wherein the Knoack volatility of carrier oil is less than or equal to about 50 weight %.
26. according to the gasoline composition of claim 22, wherein the pour point of carrier oil is less than or equal to about 0 ℃.
27. according to the gasoline composition of claim 22, wherein the viscosity index of carrier oil is more than or equal to about 85.
28. according to the gasoline composition of claim 22, wherein the sulphur concentration of carrier oil is less than or equal to about 50ppm.
29. according to the gasoline composition of claim 22, wherein the Penn attitude low-level oxidation settling weight of carrier oil is less than 5%.
30. according to the gasoline composition of claim 22, wherein sanitising agent comprises at least a following one group material that is selected from: polyamine, polyetheramine, succinimide, succinic diamide, aliphatic polyamines and mannich detergents.
31., wherein also comprise biofuel according to the gasoline composition of claim 22.
32. according to the gasoline composition of claim 22, wherein biofuel is at least a material that is selected from ethanol and biological butanol.
33. according to the gasoline composition of claim 22, wherein composition comprises
About 50～about 99.999 weight % Fuel Petroleums, about 0.001～about 3.0 weight % sanitising agents and about 0.001～about 3.0 weight % carrier oils.
34. reduce the method that forms engine deposits in the engine of combustion fuel, described method is included in the fuel composition that the engine internal combustion comprises following component:
Overwhelming majority boiling point is about 15 ℃～about 400 ℃ fuel,
Sanitising agent and
At least a derived from least a plant or zoogenous carrier oil.
35. according to the method for claim 34, wherein carrier oil is selected from following one group plant-sourced derived from least a: common vetch, fescue grass, trifolium, oat, naked barley, paddy rice, hop, barley, alfalfa, pod beans, beet, corn grain, wheat, potato, Radix Dauci Sativae, sugarcane, palm, palm-kernel, canola, leprosy grass, jowar, corn stem, soya-bean oil, Viscotrol C, Semen Brassicae campestris, simmondsia, switchgrass, weeds, marine alga, other biomass sources and their mixture.
36. according to the method for claim 34, wherein carrier oil is derived from being selected from following one group animal source: animal tallow, tallow, lard, butter and fish oil.
37. according to the method for claim 34, wherein the Knoack volatility of carrier oil is less than or equal to about 50 weight %.
38. according to the method for claim 34, wherein the pour point of carrier oil is less than or equal to about 0 ℃.
39. according to the method for claim 34, wherein the viscosity index of carrier oil is more than or equal to about 85.
40. according to the method for claim 34, wherein the Penn attitude low-level oxidation settling weight of carrier oil is less than 5%.
41. according to the method for claim 34, wherein the sulphur concentration of carrier oil is less than or equal to about 50ppm.
42. according to the method for claim 34, wherein sanitising agent is at least a following one group material that is selected from: polyamine, polyetheramine, succinimide, succinic diamide, aliphatic polyamines and mannich detergents.
43. according to the method for claim 34, wherein fuel comprises biofuel.
44. according to the method for claim 34, wherein biofuel comprises at least a material that is selected from ethanol and biological butanol.
45. according to the method for claim 34, wherein fuel comprises gasoline.
46. improve the method in the engine internal fuel economy of combustion fuel, described method is included in the fuel composition that the engine internal combustion comprises following component:
Overwhelming majority boiling point is about 15 ℃～about 400 ℃ fuel,
Sanitising agent and
At least a derived from least a plant or zoogenous carrier oil.
47. reduce in the gluing method of the engine internal valve of combustion fuel, described method is included in the fuel composition that the engine internal combustion comprises following component:
Overwhelming majority boiling point is about 15 ℃～about 225 ℃ fuel,
Sanitising agent and
At least a derived from least a plant or zoogenous carrier oil.
48. comprise the Dresel fuel compositions of following component:
Diesel oil fuel and
Derived from least a plant or zoogenous carrier oil.
49. the Dresel fuel compositions of claim 48, wherein diesel oil fuel comprises biofuel.
50. the Dresel fuel compositions of claim 48, wherein sanitising agent is biodegradable to small part.
51. the Dresel fuel compositions of claim 48, wherein sanitising agent comprises derived from least a plant or zoogenous amine-functionalized Biodegradable material.
52. the Dresel fuel compositions of claim 48, wherein sanitising agent comprises and is selected from following one group amine-functionalized Biodegradable material: polyamine, polyetheramine, succinimide, succinic diamide, aliphatic polyamines and mannich detergents.
53. reduce the method that forms engine deposits in the engine of combustion fuel, described method is included in the fuel composition that the engine internal combustion comprises following component:
Overwhelming majority boiling points be about 150 ℃～about 400 diesel oil and
Derived from least a plant or zoogenous sanitising agent.
54. the fuel dope bag of claim 11 also comprises at least a following one group material that is selected from: the organic peroxy ester, inhibiter, oxidation inhibitor, rust-preventive agent, sanitising agent and dispersion agent, lubricant, emulsion splitter, dyestuff, pour point reducer, cold flow improver, inert diluent, biocide, anti static additive, flow improver, de-misting agent, antifreeze additive, antiknock dope, anti-valve seat shrink additives, slip additive, friction improves additive, pour point reducer, cold flow improver, the fuel economy additive, the octane improving agent, the n-Hexadecane improving agent, combustion improving agent, manganese source and other containing metal ignition improver.
55. the method for claim 34, wherein engine is selected from following one group: the Atkinson cycle engine, Wankel engine, spray is led, wall is led with wall and is led/sprays and lead combination direct injection gasoline (" DIG ") engine, turbo-charging DIG engine, supercharging DIG engine, homogeneous combustion DIG engine, evenly/stratiform DIG engine, dispose the DIG engine that each injection can both have the piezoelectric type oil thrower of a plurality of fuel impulses, dispose the DIG engine of EGR, engine with poor-NOx collector, the DIG engine that contains poor-NOx catalyzer, DIG engine with SN-CR NOx control, has the DIG engine that sprays (afterfire) behind the row's diesel oil that is used for NOx control, dispose the DIG engine of flexible fuel operation, the oil engine of inlet mouth fueling, no matter have or not advanced exhaust aftertreatment system ability, have or not turbo-charging, have or not supercharging, have or not the supercharging/turbo-charging of combination, the onboard capabilities of inaction burning and discharging improvement transmission additive is arranged and have or not vario valve regularly, filling Fuel Petroleum homogeneous charge compression ignition (HCCI) engine, the diesel oil hcci engine, two-cycle engine, diesel-fueled engine, gasoline engines, the stationary power generation machine, gasoline and diesel oil HCCI, supercharging, turbo charged gasoline and diesel oil direct injection ic engine can change the engine of valve timing, poor burn engine, engine or any other oil engine, any above-listed system and the combination of electric motor in motor vehicle driven by mixed power of energy passivation cylinder.
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