CN101143999B - Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent and preparation thereof - Google Patents
Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent and preparation thereof Download PDFInfo
- Publication number
- CN101143999B CN101143999B CN200710012706XA CN200710012706A CN101143999B CN 101143999 B CN101143999 B CN 101143999B CN 200710012706X A CN200710012706X A CN 200710012706XA CN 200710012706 A CN200710012706 A CN 200710012706A CN 101143999 B CN101143999 B CN 101143999B
- Authority
- CN
- China
- Prior art keywords
- gram
- weight
- percent
- emulsion
- deionized water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a material static flocking adhesive for automobile internal decoration textile, in particular to an environment-friendly static flocking adhesive for automobile internal decoration textile material and a preparation method, the static flocking adhesive is aqueous dispersion liquid formed by polymerization of the emulsion of the following raw material, the weight percentage of the raw material is that 2.5-4 percent by weight of methacrylic acid poly(750)ethylene glycol methyl ether ester, 2-3 percent by weight of methacrylic acid trimethylammonium ethyl ester chlorinate, 4-6 percent by weight of diacetone acrylamide, 2-4 percent by weight of adipic dihydrazide, 2-8 percent by weight of acrylic acid, 25-35.5 percent by weight of acrylic ester, 2-4 percent by weight of S-400emulsifier, 0.2-0.8 percent by weight of potassium persulfate; deionized water is added to 44-46 percent solid content. The product of the invention has significantly comparison superiority in indexes, such as wear resistance times, electrostatic charge decay time, wrinkle slow elasticity, which can obviously improve the quality of the static flocking products.
Description
Technical field
The present invention relates to automobile inner decoration textile materials electrostatic flocking binding agent, specifically a kind of environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent and preparation thereof, it is a kind of aqueous liquid dispersion of acrylic polymer, is specially adapted to the static flocking of various textile materialss.
Background technology
Static flocking is by the interaction of high tension electrostatic field to fine hair, makes fine hair dependence electrical forces and implants the substrate surface (as base cloth) that scribbles tackiness agent, becomes a kind of special fabric.Because the combination of fine hair and base material all realizes by tackiness agent, so tackiness agent all has a direct impact every technical indicator of implanted article such as water absorbability, electroconductibility, crock fastness, elasticity etc., therefore in building-up process, should be taken into account the composite factor of each side, improve the technical feature of product comprehensively.
With to take textiles different, automobile inner decoration textile materials requires graceful outward appearance, and soft and warm feel will have comfortableness simultaneously: comprise feel, characteristics such as friction resistance, heat conduction heat insulating ability, breathable moisture permeability, smell, anti-pilling.Have functional: comprise characteristics such as wear-resisting, colour fastness, sun-resistant, antibiotic, uvioresistant, antifouling, fire-retardant, easy to clean and dimensional stability.Have ornamental: comprise characteristics such as woven fabric structure, appearance style, spreadability, flower type color and luster.Because it is with high content of technology, the common adhesive product generally is difficult to the requirement that touches the mark, representative products in the market has the DY-821 of the big positive company of R-605 and Shanghai of French Lu Di company, but still is difficult to meet the demands fully on some key indexs such as wear resistance, electrostatic attenuation time, elasticity.
Summary of the invention
In order to overcome the above problems, the object of the present invention is to provide a kind of environment-friendly type textile materials electrostatic flocking binding agent that is applicable to automotive trim.
For achieving the above object, the technical solution used in the present invention is;
A kind of environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent, be the aqueous liquid dispersion that forms after following routine raw emulsion copolymerization, its raw materials in part by weight consists of methacrylic acid poly-(750) glycol methyl ether ester 2.5-4, methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2-3, diacetone-acryloamide(DAA) 4-6, adipic dihydrazide 2-4, vinylformic acid 2-8; Acrylate 25-35.5, S-400 emulsifying agent (formal name used at school: secondary alkyl alcohol polyethylene oxide (40)) 2-4, Potassium Persulphate 0.2-0.8; Adding deionized water to solid content is 44-46%.
Synthetic method:
1) secondary alkyl alcohol polyethylene oxide (40) 2-4 gram is dissolved in the 24-27 gram deionized water, add pre-emulsification still, with poly-(750) the glycol methyl ether ester 2.5-4 gram of methacrylic acid, methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2-3 gram, diacetone-acryloamide(DAA) 4-6 gram, vinylformic acid 2-8 gram, acrylate 20-35.5 gram, add successively in the pre-emulsification still, fully stirring and emulsifying forms pre-emulsion;
2) it is stand-by with deionized water 8-2 gram 0.2-0.8 to be restrained Potassium Persulphate dissolving back;
3) in reactor, add 23-26 gram deionized water, reactor is warming up to 80-90 ℃, get the 7-12% for preparing the pre-emulsion gross weight in the step 1) and add reactor, stirs add step 2 after 5-10 minute) the 40-55% initiated polymerization of the middle persulfate aqueous solution gross weight of preparing;
4) after initiated polymerization 20-35 minute, drip pre-emulsion and persulfate aqueous solution under remaining after step 3) is used simultaneously in reactor, control at the uniform velocity dripped time 3-4 hour, and temperature of reaction is controlled at 80-90 ℃;
5) be warming up to 85-95 ℃ after dripping, slaking 30 minutes-2 hours is cooled to 30-45 ℃, adds adipic dihydrazide 2-4 gram, fully dissolving is adjusted to 44-46% with deionized water with emulsion solid content and obtains environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent.
Described acrylate can be butyl acrylate, ethyl propenoate and/or Octyl acrylate.
The present invention has following advantage:
1. improve the wear resistance of static flocking product, prolong its work-ing life;
2. shorten the electrostatic attenuation time of static flocking product, enlarge the Application Areas of product;
3. improve the slow elasticity of wrinkle of static flocking product, improve use properties.
Embodiment
Embodiment 1
S-400 emulsifying agent 3.3 grams are dissolved in the 25 gram deionized waters, add pre-emulsification still, with poly-(750) glycol methyl ether ester 2.8 grams of methacrylic acid; Methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2.3 grams; Diacetone-acryloamide(DAA) 5 grams; Vinylformic acid 7 grams; Butyl acrylate 14 grams; Ethyl propenoate 8.1 grams add in the pre-emulsification still, and fully stirring and emulsifying forms pre-emulsion.With deionized water 6 grams that 0.4 gram Potassium Persulphate dissolving back is stand-by, add 24 gram deionized waters in the reactor, reactor is warming up to 82 ℃, get 10% pre-emulsion adding reactor, stir the persulfate aqueous solution initiated polymerization of adding 45% after 10 minutes, cause after 25 minutes, drip pre-emulsion and persulfate aqueous solution simultaneously, 3.5 hours dropping time, temperature of reaction is controlled at 83 ± 1 ℃, be warming up to 90 ± 1 ℃ after adding, slaking 1 hour is cooled to 40 ℃, add adipic dihydrazide 2.5 grams, fully dissolving is adjusted to 44.5% with deionized water with emulsion solid content, obtains environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent.
Embodiment 2
S-400 emulsifying agent 2.3 grams are dissolved in the 24 gram deionized waters, add pre-emulsification still, with poly-(750) glycol methyl ether ester 2.5 grams of methacrylic acid; Methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2.0 grams; Diacetone-acryloamide(DAA) 4.2 grams; Vinylformic acid 8 grams; Butyl acrylate 14.9 grams; Ethyl propenoate 4 grams; Octyl acrylate 5 grams add in the pre-emulsification still, and fully stirring and emulsifying forms pre-emulsion.With deionized water 6 grams that 0.5 gram Potassium Persulphate dissolving back is stand-by, add 25 gram deionized waters in the reactor, reactor is warming up to 85 ℃, get 10% pre-emulsion adding reactor, stir the persulfate aqueous solution initiated polymerization of adding 45% after 10 minutes, cause after 25 minutes, drip pre-emulsion and persulfate aqueous solution simultaneously, 3.5 hours dropping time, temperature of reaction is controlled at 87 ± 1 ℃, be warming up to 93 ± 1 ℃ after adding, slaking 1 hour is cooled to 40 ℃, add adipic dihydrazide 2.1 grams, fully dissolving is adjusted to 44.5% with deionized water with emulsion solid content, obtains environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent.
Embodiment 3
S-400 emulsifying agent 3.8 grams are dissolved in the 27 gram deionized waters, add pre-emulsification still, with poly-(750) glycol methyl ether ester 3.7 grams of methacrylic acid; Methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2.9 grams; Diacetone-acryloamide(DAA) 5.7 grams; Vinylformic acid 3.6 grams; Butyl acrylate 11 grams; Ethyl propenoate 5.3 grams, Octyl acrylate 6 grams add in the pre-emulsification still, and fully stirring and emulsifying forms pre-emulsion.With deionized water 5 grams that 0.7 gram Potassium Persulphate dissolving back is stand-by, add 23 gram deionized waters in the reactor, reactor is warming up to 82 ℃, get 8% pre-emulsion adding reactor, stir the persulfate aqueous solution initiated polymerization of adding 52% after 10 minutes, cause after 30 minutes, drip pre-emulsion and persulfate aqueous solution simultaneously, 3 hours 50 minutes dropping time, temperature of reaction is controlled at 85 ± 1 ℃, be warming up to 88 ± 1 ℃ after adding, slaking 45 minutes is cooled to 36 ℃, add adipic dihydrazide 2.8 grams, fully dissolving is adjusted to 44.2% with deionized water with emulsion solid content, obtains environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent.
Embodiment 4
S-400 emulsifying agent 2.2 grams are dissolved in the 26 gram deionized waters, add pre-emulsification still, with poly-(750) glycol methyl ether ester 2.5 grams of methacrylic acid; Methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2 grams; Diacetone-acryloamide(DAA) 4.1 grams; Vinylformic acid 2.2 grams; Butyl acrylate 16.5 grams; Ethyl propenoate 7.5 grams, Octyl acrylate 6.8 grams add in the pre-emulsification still, and fully stirring and emulsifying forms pre-emulsion.With deionized water 5 grams that 0.3 gram Potassium Persulphate dissolving back is stand-by, add 23.3 gram deionized waters in the reactor, reactor is warming up to 82 ℃, get 12% pre-emulsion adding reactor, stir the persulfate aqueous solution initiated polymerization of adding 42% after 10 minutes, cause after 30 minutes, drip pre-emulsion and persulfate aqueous solution simultaneously, 3 hours 15 minutes dropping time, temperature of reaction is controlled at 81 ± 1 ℃, be warming up to 86 ± 1 ℃ after adding, slaking 1.5 hours is cooled to 43 ℃, add adipic dihydrazide 2.1 grams, fully dissolving is adjusted to 45.1% with deionized water with emulsion solid content, obtains environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent.
Using method:
Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent 100g adds amino resin crosslinking agent 5-10g, transfers viscosity to 30000 ± 3000mPa.S with the FS-20A thickening material, and with the scraper coating, spread is 160g/m on the T/C base cloth
2, carry out static flocking.130 ℃ baked 3 minutes after the flocking, removed floating hair, washed and carry out softening to get final product.
Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent effect and detection method:
Testing installation:
The RAPID shaping drying
The F140-II HV generator
Y522 plain grinding instrument
LFY-1B pincher elasticity instrument
LFY-401 fabric induction electrostatic tester
The 302A temperature and humidity regulator
The JA3003 electronic balance
2B01 garden dish sampler
1, above form institute column data all is gained results under T/C base cloth equal conditions.
2, Y522 plain grinding instrument is used in the wear resistance experiment, pressurization 500g, and show-through with the sample part is terminal point, record friction number of times.
3, the electrostatic attenuation time tests with LFY-401 fabric induction electrostatic tester, and multiplying power transfers to 0.5, and numerical value end static resistance more is good more.
4, the pincher elasticity test uses LFY-1B pincher elasticity instrument to test (horizontal method), and sample folds and divides the positive front is folded with reverse side that reverse side is folded (positive is that villous surface is to villous surface to the front).
5, outward appearance test after the fabric washing: wash sample by hand, dry naturally and original sample contrast.This law makes tackiness agent and R-605 to wash back cloth facial vision smooth as a result, and fine hair is neat, and washes preceding no significant difference, and DY-821 washes the back fabrics cloth cover wrinkle are arranged, and fine hair is swung to confusion, and the surface forms the uneven color that coloured light differs.
As can be seen, product of the present invention on abrasion resistance at present commercially available import tackiness agent improved closely 10%, improve more than 30% than general homemade tackiness agent; The electrostatic attenuation time, also present commercially available import tackiness agent improved 10%, was enhanced about more than once than general homemade tackiness agent; The slow elasticity of wrinkle also improves significantly.Compare with at present commercially available all kinds of tackiness agents, product of the present invention has tangible comparative advantages aspect above several the key technical indexes, can significantly improve the quality of static flocking product.
Claims (2)
1. environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent, it is characterized in that: this flocking adhesive is the aqueous liquid dispersion that forms behind the following raw materials according emulsion copolymerization, and its raw materials in part by weight consists of methacrylic acid poly-(750) glycol methyl ether ester 2.5-4, methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2-3, diacetone-acryloamide(DAA) 4-6, adipic dihydrazide 2-4, vinylformic acid 2-8; Acrylate 20-35.5, S-400 emulsifying agent 2-4, Potassium Persulphate 0.2-0.8; Adding deionized water to solid content is 44-46%;
The concrete preparation process of described tackiness agent is as follows,
1) secondary alkyl alcohol polyethylene oxide (40) 2-4 gram is dissolved in the 24-27 gram deionized water, add pre-emulsification still, poly-(750) the glycol methyl ether ester 2.5-4 gram of methacrylic acid, methyl chloride vinylformic acid trimethylammonium ammonia ethyl ester 2-3 gram, diacetone-acryloamide(DAA) 4-6 gram, vinylformic acid 2-8 gram, acrylate 20-35.5 gram are added in the pre-emulsification still, fully stirring and emulsifying forms pre-emulsion;
2) it is stand-by with deionized water 8-2 gram 0.2-0.8 to be restrained Potassium Persulphate dissolving back;
3) in reactor, add 23-26 gram deionized water, reactor is warming up to 80-90 ℃, get the 7-12% for preparing the pre-emulsion gross weight in the step 1) and add reactor, stirs add step 2 after 5-10 minute) the 40-55% initiated polymerization of the middle persulfate aqueous solution gross weight of preparing;
4) after initiated polymerization 20-35 minute, drip pre-emulsion and persulfate aqueous solution under remaining after step 3) is used simultaneously in reactor, control at the uniform velocity dripped time 3-4 hour, and temperature of reaction is controlled at 80-90 ℃;
5) be warming up to 85-95 ℃ after dripping, slaking 30 minutes-2 hours is cooled to 30-45 ℃, adds adipic dihydrazide 2-4 gram, fully dissolving is adjusted to 44-46% with deionized water with emulsion solid content and obtains environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent.
2. according to the described tackiness agent of claim 1, it is characterized in that: described acrylate is butyl acrylate, ethyl propenoate and/or Octyl acrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710012706XA CN101143999B (en) | 2007-09-05 | 2007-09-05 | Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710012706XA CN101143999B (en) | 2007-09-05 | 2007-09-05 | Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101143999A CN101143999A (en) | 2008-03-19 |
| CN101143999B true CN101143999B (en) | 2010-04-14 |
Family
ID=39206739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710012706XA Expired - Fee Related CN101143999B (en) | 2007-09-05 | 2007-09-05 | Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101143999B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102527600B (en) * | 2011-11-25 | 2013-10-30 | 上海瀚氏模具成型有限公司 | Plasma flocking method for automobile interior parts |
| CN102527599B (en) * | 2011-11-25 | 2013-10-30 | 上海瀚氏模具成型有限公司 | Electrostatic flocking method for automobile interior parts |
| CN103194157B (en) * | 2013-04-17 | 2015-06-03 | 山东天鼎丰非织造布有限公司 | Acrylate adhesive for waterproof roll tyre base fabrics and preparation method thereof |
| CN105294925B (en) * | 2015-11-24 | 2017-04-19 | 辽宁恒星精细化工有限公司 | Electrostatic flocking adhesive for high fastness carpet and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1280159A (en) * | 1999-07-09 | 2001-01-17 | 盐城冬阳化工有限公司 | Method for low-temperature synthesizing water emulsion type flocking adhesive |
-
2007
- 2007-09-05 CN CN200710012706XA patent/CN101143999B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1280159A (en) * | 1999-07-09 | 2001-01-17 | 盐城冬阳化工有限公司 | Method for low-temperature synthesizing water emulsion type flocking adhesive |
Non-Patent Citations (3)
| Title |
|---|
| 左建军.静电植绒革用粘合剂的研究.塑料科技 1988年第03期.1988,(1988年第03期),6-9页. |
| 左建军.静电植绒革用粘合剂的研究.塑料科技 1988年第03期.1988,(1988年第03期),6-9页. * |
| 汪多仁.丙烯酸酯乳液在纺织助剂中的应用.胶体与聚合物第19卷 第3期.2001,第19卷(第3期),40-41页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101143999A (en) | 2008-03-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102619103B (en) | Pigment printing imitated reactive printing adhesive and preparation method thereof | |
| CN102605648B (en) | Textile water-based pigment printing binding agent and preparation method | |
| CN104831540B (en) | Water-repellent, oil-repellent, sun-proof, anti-bend torsion and cold-resistant matt-leather-membrane aqueous coating adhesive for textiles and preparation method of matt-leather-membrane aqueous coating adhesive | |
| US8507102B1 (en) | Conductive leather materials and methods for making the same | |
| CN109610183B (en) | Aqueous polyurethane coating adhesive for textiles and fabric treatment method | |
| CN103233375B (en) | Stereo printing paste for suede and preparation method thereof | |
| CN101343525B (en) | Watersoluble adhesive agent used in imitation leather electrostatic real leather embedding product and preparation thereof | |
| CN101143999B (en) | Environment-friendly type automobile inner decoration textile materials electrostatic flocking binding agent and preparation thereof | |
| CN101857791A (en) | Aqueous polyurethane static flocking adhesive and preparation method thereof | |
| CN101798759B (en) | Finishing method of flocking fabric | |
| WO2015058419A1 (en) | Environmentally friendly garment leather and preparation method thereof | |
| CN104151504A (en) | Waterborne polyurethane grafted waterborne polyacrylate emulsion and preparation method thereof | |
| CN102220099B (en) | Fur-imitating static flocking binder and preparation method thereof | |
| CN108411651A (en) | A kind of gold stamping slurry and its preparation method and application | |
| CN103468084B (en) | Polyacrylate modified Casein Leather finishing agent and preparation method | |
| CN109680522A (en) | A kind of research of silicone modified coating printing paste used for textiles and preparation method | |
| CN110904687B (en) | Pure cotton satin fabric imitated silk finishing agent and preparation method thereof | |
| CN107476063B (en) | The good water-and acrylate coating adhesive used for textiles and preparation method thereof of soft, cold-resistant, elastic, fastness, resistance to hydrostatic pressure performance | |
| CN109736098A (en) | A kind of aqueous polyurethane textile coating adhesive of high rigidity and preparation method thereof | |
| CN114044861A (en) | Polyurethane modified acrylate pigment printing adhesive for dacron oxford fabric and preparation method thereof | |
| CN102493195B (en) | Matte involucra coating adhesive for textile and preparation method thereof | |
| CN107936899A (en) | A kind of mail frame electrostatic spinning aqueous adhesive and preparation method thereof | |
| CN101942772A (en) | Low-formaldehyde soaping-resistant adhesive for textile pigment printing and preparation method thereof | |
| CN102108110A (en) | Method for preparing acrylate printing adhesive | |
| CN103045135A (en) | Environment-friendly electrostatic flocking binder for automotive trim textile materials and preparation method of environment-friendly electrostatic flocking binder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100414 Termination date: 20200905 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |