CN101143947B - Halogen-free intumescent flame retardant for polypropylene - Google Patents
Halogen-free intumescent flame retardant for polypropylene Download PDFInfo
- Publication number
- CN101143947B CN101143947B CN200610112927A CN200610112927A CN101143947B CN 101143947 B CN101143947 B CN 101143947B CN 200610112927 A CN200610112927 A CN 200610112927A CN 200610112927 A CN200610112927 A CN 200610112927A CN 101143947 B CN101143947 B CN 101143947B
- Authority
- CN
- China
- Prior art keywords
- fire retardant
- halogen
- polypropylene
- retardant
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 95
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 31
- -1 polypropylene Polymers 0.000 title claims abstract description 31
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 29
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 29
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 22
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 22
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 22
- 239000007822 coupling agent Substances 0.000 claims abstract description 17
- 239000000314 lubricant Substances 0.000 claims abstract description 14
- 239000003610 charcoal Substances 0.000 claims description 19
- BEOXJJSYIKCCCH-UHFFFAOYSA-N cyanamide;1,3,5-triazine-2,4,6-triamine Chemical compound NC#N.NC1=NC(N)=NC(N)=N1 BEOXJJSYIKCCCH-UHFFFAOYSA-N 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 8
- 229920002292 Nylon 6 Polymers 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000000779 smoke Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 6
- 229920000098 polyolefin Polymers 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 4
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 abstract description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052794 bromium Inorganic materials 0.000 abstract description 3
- 230000000979 retarding effect Effects 0.000 abstract description 3
- 239000008187 granular material Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 abstract description 2
- 150000007974 melamines Chemical class 0.000 abstract 2
- 239000012467 final product Substances 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 230000032050 esterification Effects 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910018626 Al(OH) Inorganic materials 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229910019440 Mg(OH) Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- OHRVBDRGLIWLPA-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] dihydrogen phosphate Chemical compound OCC(CO)(CO)COP(O)(O)=O OHRVBDRGLIWLPA-UHFFFAOYSA-N 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Images
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of polypropylene uses the halogen-free expansion type fire retardant, relate to a fire retardant for polyolefin, by melamine salt, ammonium polyphosphate, lubricant, coupling agent and char forming promoter complex formulation to get final product, the percentage of each component accounts for the total weight of fire retardant in the fire retardant is, melamine salt 14% -90%, ammonium polyphosphate 9% -85%, lubricant 0.1% -2%, coupling agent 0.1% -2%, char forming promoter 0.1% -5%; when the flame retardant is used for flame retarding polypropylene powder or granules, the lowest addition amount is 21 percent (wt), and the flame retarding grade can reach V-0 grade according to the test of the American UL94 method. Compared with bromine, the flame retardant of the invention is environment-friendly, and the halogen-free flame retardant polypropylene has low smoke density, less smoke generation, low mass loss rate and large residual mass.
Description
Technical field
The present invention relates to a kind of polyolefine fire retardant, particularly a kind of halogen-free expansion fire retardant for polypropylene.
Background technology
Fire retardant material particularly environmentally friendly type halogen-free flame-retardant polymer material and flame-retarded technology are just becoming the focus of whole world research, and the cry of halogen-free flameproof grows to even greater heights, and countries such as European Union put into effect laws and regulations in succession, the use of restriction halogenated flame retardant.Make macromolecular material have flame retardant resistance, do not produce toxic smog during burning, must introduce pollution-free type ignition-proof element in polymer, introducing the most practical and effective means of pollution-free ignition-proof element in the material is to add environmentally friendly type fire retardant.
At present, the fire-retardant means that are used for superpolymer mainly are to add halogenated flame retardant, halogenated flame retardant can be emitted the black smoke of the toxic gas that includes the victimization body in a large number in fire-retardant process, still be that resuming work after the calamity all can be caused very big difficulty to the rescue in the fire.According to fire report statistics, really burn lethal number in the fire and only account for 15%, and 85% people dies from suffocating that toxic smoke causes.In addition, there is data to show, produces highly toxic bromo dibenzo during some hydrobromic ether fire retardant (as decabromodiphynly oxide) burnings and cough up alkane and bromo diphenylene-oxide.For the consideration to human health and environment protection, simultaneously according to some experimental results that now obtained, people hold scrupulous more attitude to bromide fire retardant.Halogen-free flame retardants is used extensive day by day with its low-smoke and avirulent advantage, the trend that replaces halogenated flame retardant is arranged.
Because expansion type flame retardant amount of being fuming in combustion processes is few, does not produce toxic gas, belongs to environment friendly flame retardant, is considered to realize one of non-halogen fire-retardant approach that gets a good chance of.Expansion type flame retardant can be divided into mixed expanded type fire retardant and single component expansion type flame retardant.Mixed expanded type fire retardant is the fire-retardant agent based on ammonium polyphosphate, it is fire-retardant that the at present existing commercial prod of country such as the U.S., Italy is used for polyolefine, Exolit IFR series as U.S. Hoechst Celanese company, have superior heat-stability and use properties, be applicable to that PP is fire-retardant, when the fire retardant consumption was 25% (wt)～30% (wt), the oxygen index of fire retardant material can reach 30, fire-retardant rank reaches the UL-94V-0 level, and living cigarette amount is with fire retardant material is not equally matched.
The Spinfiam MF-82 series expansion type flame retardant that Italy Monsanto company releases, its characteristics are similar to ExolitIFR series, are applicable to fire-retardant PP and LDPE.The XLDPE toxicity fire-retardant with Spinfiam is little, and living cigarette amount is more much lower than PVC, compares with the XLDPE that adopts magnesium hydroxide flame retardant, and density is low by 30～40%, is the ideal covering material of cable.
The greatest drawback of above-mentioned mixed expanded type fire retardant is problems such as processing difficulties, moisture absorption, large usage quantity, the mechanical property that influences material and price height, causes to use to be restricted.
The R and D of China's flame-retarded technology are started late, still be in early stage of development, no matter from kind quantity, state of the art, or all respects such as application development, the construction of legal rules, still exist sizable gap compared with developed countries, but in recent years, the development of China's flame-retarded technology had obtained relevant department and expert's very big concern, had many R﹠D institutions setting foot in this field.Modified expanded type fire retardant based on ammonium polyphosphate (APP) has become domestic research focus, emphasis concentrates on APP is carried out modification, what have coats APP and encapsulated processing, improve the water absorbability problem, the cyanurotriamide modified APP of the usefulness that has prepares trimeric cyanamide secondary amine salt (MPP), by with carbon source and become the composite flame retarding efficiency that improves such as carbon promotor, carbon forming agent and become the research of carbon promotor also more focuses on improving the quality of expansion charcoal layer.
In the prior art, CN01128575.3 has introduced pentaerythritol phosphate, melamine phosphate, lubricant, coupling agent and has carried out composite formation fire retardant, and when the add-on in polyolefine was 28% (wt), flame retardant rating reached UL94V-0; CN1341669A has introduced the fire retardant that magnesium hydroxide and coupling agent, lubricant carry out composite formation, and the add-on in polypropylene reaches 60%; " research of expansion type flame retardant and expanded flame-retardant polypropylene performance " has been introduced APP, tetramethylolmethane, trimeric cyanamide, red phosphorus and has been joined in the polypropylene according to certain proportioning, and when add-on was 41% (wt), flame retardant rating reached the UL94V-0 level.
Summary of the invention
The objective of the invention is to, a kind of polypropylene fire retardant that is used for is provided, is the halogen-free expansion fire retardant of main ignition-proof element with nitrogen-phosphorus.
A kind of halogen-free expansion fire retardant for polypropylene, by trimeric cyanamide melamine salt, ammonium polyphosphate, lubricant, coupling agent with become that charcoal promotor is composite to be formed, the per-cent of each ingredients constitute fire retardant gross weight is in the fire retardant,
Trimeric cyanamide melamine salt 14%～90%,
Ammonium polyphosphate 9%～85%,
Lubricant 0.1%～2%,
Coupling agent 0.1%～2%,
Become charcoal promotor 0.1%～5%;
Wherein, the structural formula of trimeric cyanamide melamine salt is:
The structural formula of ammonium polyphosphate is:
In the formula: 2000＜n＜10000.
Lubricant is stearic acid, Zinic stearas or calcium stearate.Coupling agent is the silicane material, can be γ-glycidyl ether oxygen propyl trimethoxy silicane or γ-An Bingjisanyiyangjiguiwan or titanate coupling agent.Becoming charcoal promotor is SiO
2, TiO
2Or PA-6.PA-6 is a nylon 6.
The weight percent preferred 25%～60% of trimeric cyanamide melamine salt in the fire retardant, the weight percent of ammonium polyphosphate preferred 20%～70%, the weight percent of lubricant preferred 0.5%～2%, the weight percent of coupling agent is preferred 0.5%～2%, becomes the weight percent preferred 0.5%～4% of charcoal promotor.
Fire retardant adopts following method to be prepared from:
At first trimeric cyanamide melamine salt and ammonium polyphosphate are dried, make water-content＜0.2% (wt), pulverize then, make its particle diameter＜35 μ m.
Secondly, in proportion with trimeric cyanamide melamine salt and ammonium polyphosphate with lubricant, coupling agent, become charcoal promotor to put into to mix 1～10 minute in the high speed mixer, can obtain halogen-free expansion fire retardant for polypropylene.
Expansion type flame retardant mainly plays fire retardation by forming porous foam charcoal layer at condensed phase, and this charcoal layer is the (see figure 1) that forms in following several steps of experience:
(1) at a lower temperature (actual temp depends on the character of acid source and other components) emitted by acid source can esterification polyol and can be used as the mineral acid of dewatering agent;
(2) discharge under the sour temperature a little higher than, esterification takes place, the amine in the system then can be used as catalyst for esterification;
(3) system melts before esterification or in the esterification process;
(4) water vapour that produces of reaction and the non-flammable gases that is produced by source of the gas make molten system expanded foamed.Simultaneously, polyvalent alcohol and ester dehydration carbonization form inorganics and charcoal resistates, and system are further expanded foamed;
When (5) reacting approaching finishing, system gel and curing form porous foam charcoal layer at last.
Set forth as can be seen by above mechanism, for expansion type flame retardant, becoming charcoal is the key of flame retardant effect quality.Fire retardant of the present invention, the trimeric cyanamide melamine salt in its two kinds of components are can the gas collection source, charcoal source and acid source be in the fire retardant of one; And ammonium polyphosphate has improved the one-tenth charcoal speed and the neat coal amout of fire retardant as acid source, and therefore, two kinds of composite uses of fire retardant have reached the independent use flame retardant effect that is beyond one's reach, and have played synergistic effect, have reduced the add-on of fire retardant.Synergistic effect between various auxiliary agents and the fire retardant is also similar therewith.
When fire retardant of the present invention is used for polypropylene flame redardant powder or pellet, addition is minimum when being 21% (wt), by the test of U.S. UL94 method, flame retardant rating can reach the V-0 level, compared to existing technology, the addition of fire retardant significantly reduces (referring to table 2), has reduced cost, and the while is the processing characteristics of impact polypropylene not.System compares with bromine, fire retardant environmental protection of the present invention, and the halogen-free polypropylene flame redardant smoke density is low, the amount of being fuming is few, mass loss rate is little, remaining quality is big.
Description of drawings
Fig. 1: porous charcoal layer formation process synoptic diagram
Embodiment
Embodiment 1～26
Embodiment sees Table 1, at first trimeric cyanamide melamine salt and ammonium polyphosphate is dried, and makes water-content＜0.2% (wt), pulverizes then, makes its particle diameter＜35 μ m.
Secondly, according to the form below 1 form with trimeric cyanamide melamine salt and ammonium polyphosphate with lubricant, coupling agent, become charcoal promotor to put into to mix 1～10 minute in the high speed mixer, can obtain halogen-free expansion fire retardant for polypropylene.
Table 1 polypropylene halogen-free flame retardants proportioning
C in the table
18Be stearic acid; C
18The Zn Zinic stearas; C
18Ca is a calcium stearate; KH-550 is a kind of product of γ-An Bingjisanyiyangjiguiwan; NDZ-101 is the monoalkoxytitanates coupling agent; ZQ-560 is a kind of product of γ-glycidyl ether oxygen propyl trimethoxy silicane; TiO
2Be titanium dioxide; PA-6 is a nylon 6.
Polypropylene granules or powder and the composite halogen-free flame retardants that forms are put in the high speed mixer, the stearic acid or the Zinic stearas (improving the apparent property and the processing characteristics of polymkeric substance) that add the white oil and 0.5% (wt) of 0.2% (wt) simultaneously, thorough mixing 1～10 minute. granulation in twin screw extruder machine then, extrusion is provided with vacuum exhaust, makes moulded product with injection moulding machine then.
When fire retardant of the present invention is used for polypropylene flame redardant powder or pellet, minimum 21% (wt) that reach of addition, flame retardant rating all reaches the UL94V-0 level, and the processing characteristics of polypropylene flame redardant is good.Compare with bromine system that the halogen-free polypropylene flame redardant smoke density is low, the amount of being fuming is few, mass loss rate is little, remaining quality is big.Compare with the flame retardant effect of the fire retardant of other kind, the results are shown in following table:
Several polypropylene of table 2 flame retardant effect contrast table of fire retardant
| The fire retardant kind | The auxiliary agent kind | Addition | Flame retardant rating |
| Bromide fire retardant | Sb 2O 3 | 40％ | UL94V-0 |
| Al(OH) 3 | - | 60％ | UL94V-0 |
| Mg(OH) 2 | - | 65％ | UL94V-0 |
| IFR | The self-control composite assistant | 21％ | UL94V-0 |
Annotate: IFR is a complex intumescent flame retardant of the present invention.
Claims (7)
1. halogen-free expansion fire retardant for polypropylene is characterized in that: by trimeric cyanamide melamine salt, ammonium polyphosphate, lubricant, coupling agent with become that charcoal promotor is composite to be formed, the per-cent of each ingredients constitute fire retardant gross weight is in the fire retardant,
Trimeric cyanamide melamine salt 14%～90%,
Ammonium polyphosphate 9%～85%,
Lubricant 0.1%～2%,
Coupling agent 0.1%～2%,
Become charcoal promotor 0.1%～5%;
Wherein, the structural formula of trimeric cyanamide melamine salt is:
The structural formula of ammonium polyphosphate is:
In the formula: 2000＜n＜10000
Lubricant is stearic acid, Zinic stearas or calcium stearate;
Coupling agent is the silicane material;
Becoming charcoal promotor is SiO
2, TiO
2Or PA-6.
2. halogen-free expansion fire retardant for polypropylene according to claim 1 is characterized in that: coupling agent is γ-glycidyl ether oxygen propyl trimethoxy silicane or γ-An Bingjisanyiyangjiguiwan.
3. halogen-free expansion fire retardant for polypropylene according to claim 1 is characterized in that: the weight percent of trimeric cyanamide melamine salt is 25%～60% in the fire retardant.
4. halogen-free expansion fire retardant for polypropylene according to claim 1 is characterized in that: the weight percent of ammonium polyphosphate is 20%～70% in the fire retardant.
5. halogen-free expansion fire retardant for polypropylene according to claim 1 is characterized in that: the weight percent of lubricant is 0.5%～2% in the fire retardant.
6. halogen-free expansion fire retardant for polypropylene according to claim 1 is characterized in that: the weight percent of coupling agent is 0.5%～2% in the fire retardant.
7. halogen-free expansion fire retardant for polypropylene according to claim 1 is characterized in that: becoming the weight percent of charcoal promotor in the fire retardant is 0.5%～4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610112927A CN101143947B (en) | 2006-09-13 | 2006-09-13 | Halogen-free intumescent flame retardant for polypropylene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610112927A CN101143947B (en) | 2006-09-13 | 2006-09-13 | Halogen-free intumescent flame retardant for polypropylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101143947A CN101143947A (en) | 2008-03-19 |
| CN101143947B true CN101143947B (en) | 2010-05-12 |
Family
ID=39206694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610112927A Active CN101143947B (en) | 2006-09-13 | 2006-09-13 | Halogen-free intumescent flame retardant for polypropylene |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101143947B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134351B (en) * | 2011-04-09 | 2012-09-26 | 太原理工大学 | Preparation method of antiflaming polypropylene composite material |
| CN106893140B (en) * | 2017-01-19 | 2019-04-09 | 北京化工大学 | A kind of preparation method of the Novel Intumescent Flame Retardant based on supramolecular materials |
| CN107415355A (en) * | 2017-07-27 | 2017-12-01 | 合肥伊只门窗有限公司 | A kind of fire protection flame retarding composite fire door |
| CN116478472A (en) * | 2023-03-31 | 2023-07-25 | 天津金发新材料有限公司 | Thin-wall flame-retardant modified PP material with high ignition temperature and preparation and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3936416A (en) * | 1973-07-24 | 1976-02-03 | Phillips Petroleum Company | Nonburning, nondripping, char-forming, polypropylene composition |
| US4480093A (en) * | 1983-05-23 | 1984-10-30 | Borg-Warner Chemicals, Inc. | Amines salts of phosphoric acid |
| US4966931A (en) * | 1988-01-29 | 1990-10-30 | Chisso Corporation | Flame-retardant polypropylene resin composition |
| CN1335332A (en) * | 2001-08-28 | 2002-02-13 | 巴陵石化岳阳石油化工总厂 | Halogen-free intumescent flame retardant composition for polyolefin |
| CN1721423A (en) * | 2004-07-16 | 2006-01-18 | 中国石油天然气集团公司 | Process for synthesis of melamine salt of pentaerythritol bis (dihydrogen phosphate) |
-
2006
- 2006-09-13 CN CN200610112927A patent/CN101143947B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3936416A (en) * | 1973-07-24 | 1976-02-03 | Phillips Petroleum Company | Nonburning, nondripping, char-forming, polypropylene composition |
| US4480093A (en) * | 1983-05-23 | 1984-10-30 | Borg-Warner Chemicals, Inc. | Amines salts of phosphoric acid |
| US4966931A (en) * | 1988-01-29 | 1990-10-30 | Chisso Corporation | Flame-retardant polypropylene resin composition |
| CN1335332A (en) * | 2001-08-28 | 2002-02-13 | 巴陵石化岳阳石油化工总厂 | Halogen-free intumescent flame retardant composition for polyolefin |
| CN1721423A (en) * | 2004-07-16 | 2006-01-18 | 中国石油天然气集团公司 | Process for synthesis of melamine salt of pentaerythritol bis (dihydrogen phosphate) |
Non-Patent Citations (2)
| Title |
|---|
| 李云东.聚磷酸铵阻燃剂的应用.云南化工32 4.2005,32(4),第51-54页. |
| 李云东.聚磷酸铵阻燃剂的应用.云南化工32 4.2005,32(4),第51-54页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101143947A (en) | 2008-03-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102174223B (en) | Flame-retardant foamed polyethylene material and preparation method thereof | |
| CN101372548B (en) | High-impact polystyrene blend and preparation thereof | |
| CN101293983B (en) | Expansion flame-proof polypropelene composition and preparation method thereof | |
| CN102875851B (en) | Environment-friendly flame retardant | |
| CN101508809A (en) | Halogen-free expansion type flame-proof polyolefin composite material | |
| CN102964681B (en) | Halogen-free flame-retardant polypropylene material and preparation method thereof | |
| CN101153116B (en) | Bitumen flame-proof modifier | |
| CN102367306A (en) | High efficiency halogen-free flame retardant polypropylene composite material and its preparation method | |
| CN103172918A (en) | Low-smoke halogen-free flame-retardant cable material and preparation method thereof | |
| CN101735514B (en) | Flame-retardant polypropylene material and preparation method | |
| CN101693835A (en) | Environment-friendly polypropylene composite material with high efficiency flame retardance | |
| CN106832813B (en) | Flame-retardant polyethylene terephthalate resin composition | |
| CN101143944A (en) | Halogen-free intumescent flame retardant for polyethylene | |
| CN101928448A (en) | Nano composite flame-retardant reinforced polyester engineering plastic and preparation method thereof | |
| CN105295101A (en) | Microencapsulated red phosphorus fire retardant and preparation method and application thereof | |
| CN101143947B (en) | Halogen-free intumescent flame retardant for polypropylene | |
| CN103232635A (en) | Synergetic intumescent flame-retardant polypropylene composite material and preparation method thereof | |
| CN101368000A (en) | Sepiolite based flame retarding polymer and method of producing the same | |
| CN101656304B (en) | Casing material of halogen-free expanding type flame-retardant storage battery | |
| CN103333423B (en) | Compound flame-retardant polystyrene composition and preparation method thereof | |
| CN109608691A (en) | A kind of preparation method of serpentine-magnesium hydroxide-boric acid magnesium compound fire retardant | |
| CN101659778A (en) | Expanded halogen-free flame-retardant ABS compound material | |
| CN108912444A (en) | A kind of environment friendly halogen-free fireproof master batch and preparation method thereof | |
| CN107868460A (en) | A kind of halogen-free flame-retardant resin and preparation method thereof | |
| CN102585355B (en) | A kind of dispersing method of halogen-free polypropylene flame redardant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |