CN101120908A - Aerosol type shaving agent composition - Google Patents

Aerosol type shaving agent composition Download PDF

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Publication number
CN101120908A
CN101120908A CN 200710141819 CN200710141819A CN101120908A CN 101120908 A CN101120908 A CN 101120908A CN 200710141819 CN200710141819 CN 200710141819 CN 200710141819 A CN200710141819 A CN 200710141819A CN 101120908 A CN101120908 A CN 101120908A
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shaving
agent composition
acid
aerosol type
ester
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CN101120908B (en
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堀隆
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Kao Corp
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Kao Corp
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Abstract

The present invention provides an aerosol type shaving agent composition which improves slide performance when shaving and prevents soapy handle when cleaning. The composition is composed of (A) 4 to 21 percent of anionic surface active agent by quality, (B) 0.1 to 5 percent of carrageenan by quality and (C) spray agent.

Description

Aerosol type shaving agent composition
Technical field
The present invention relates to the aerosol type shaving agent composition that when shaving with razor, uses except that beard and useless chaeta etc.
Background technology
When shaving with razor, use the agent of shaving except that beard and chaeta.Shave agent mostly with fatty acid soaps as main base, for example, except that general solid or powder soap (shaving soap), have shaving cream, aerosol type shaving foam, post-foaming to coagulate white (non-patent literatures 1) such as (gel-cream).
These agent state uses of shaving with bubble.This is in order to make the sagging difficulty that becomes of liquid on skin, and is in order to prevent that the razor excessive contact is in skin and injured.
Shaving soap mainly business with in use, generate dense and the bubble of persistence arranged.But,, bubble so must add water in use because shaving soap is the solid article of powder etc.In addition, because hygroscopicity is strong under the solid article state, so easy solidified problem is also arranged in preservation.In addition, the persistence and the conformality of bubble are insufficient, must coat enough bubbles in the process of shaving.
On the other hand, aerosol type shaving foam and post-foaming coagulate frost, shaving agent and used by numerous consumers when particularly shaving as the male.
Physical property ground bubbles the aerosol type shaving foam by the gasification of propellant.
In addition, the aerial fog type post-foaming coagulates frost, is to be to shave to mix the high liquid gas of boiling point in the gel host of agent and be filled in the agent of shaving in the container.Gel host is ejected on the skin from container one, and liquid gas just gasification bubbles.
In the agent of shaving in the past that the state with bubble uses, pay attention to the retentivity of alveolar substance amount and bubble, reduce the friction of razor and skin with the activating agent aqueous solution liquid film of supplying with from bubble.Therefore, in case the part of shaving is removed the just rapid variation of sliding when moving owing to do not steep so shave repeatedly.
On the other hand, as the agent of shaving of the main base that does not use foaming characteristic, the gel shaving agent composition (patent documentation 1, patent documentation 2) of non-foaminess is arranged.
This gel shaving agent composition, be directly to be coated on the position of beard and chaeta under the bubble-tight situation and the shaving agent composition that uses, it contains large quantity of moisture, sticks on beard and chaeta and the skin and makes their softnessizationes, can successfully shave except that beard and chaeta thus.
But in order to remain on the skin, the gel shaving agent composition is full-bodied, for the user that the aerosol type shaving foam of getting used to steeping sense of touch and post-foaming coagulate frost, because feel soapy feeling and be clamminess sense and be difficult to accept.
In recent years, owing to the raising of realizing is modified in the attention that is the center with young layer, how the chance of shaving except that beard and chaeta has become.In such trend, require the agent of shaving of a kind of sliding, whose serial foaming that can operate simply, good that can improve the razor when shaving mao.
Non-patent literature 1: Nan Shantang, newly make up conduct and learning, the 2nd edition, p392~p396
Patent documentation 1: the spy opens flat 9-132516 communique
Patent documentation 2: the spy opens flat 10-87454 communique
Summary of the invention
Razor sliding when the object of the present invention is to provide a kind of raising to shave mao, and do not have the aerosol type shaving agent composition of soapy feeling when shaving afterflush.
The inventor finds can finish above-mentioned problem by cooperate the high molecular aerosol type shaving agent of specific water soluble in anion surfactant.
That is, the present invention provides a kind of aerosol type shaving agent composition, it is characterized in that, also contains (C) propellant in the aerosol stock solution of (B) carrageenin of (A) anion surfactant that contains 4~21 quality % and 0.1~5 quality %.
Aerosol type shaving agent composition of the present invention is owing to continue good razor sliding, so razor is difficult to block on beard and skin, and the soapy feeling the during flushing after not shaving is so complete operation like a cork.
The specific embodiment
Operable in the present invention (A) anion surfactant is the composition that becomes the foaming characteristic base, can enumerate at least one that is selected from phosphate monoester salt, soap, N-acylated amino salt, alkyl sulfate and polyoxyethylene alkyl ether sulfate salt.These salt can contain separately, and perhaps appropriate combination is more than 2 kinds and contain.
As the mono phosphoric acid ester alkanol ester that constitutes above-mentioned phosphate monoester salt, can enumerate phosphoric acid straight chain alkanol ester, phosphoric acid branched alkane alcohol ester, glucose-1-phosphate, polyoxyethylene alkyl ether phosphate ester, 1-alkyl glycerol-3-phosphate ester, 2-hydroxy alkyl phosphate ester, glucose-1-glycerol-3-phosphate ester, polysaccharide phosphate ester etc.
More specifically, viewpoint from foaming characteristic, preferably phosphoric acid single lauryl alcohol ester, mono phosphoric acid ester Semen Myristicae alcohol ester, mono phosphoric acid ester spermaceti alcohol ester, has carbon number and is the mixing alkanol phosphate ester of 11,13,15 alkyl, has carbon number and is polyoxyethylene alkyl ether phosphoric acid of 12~16 alkyl etc., these can be independent, also can suitably be used in combination.
As the fatty acid that constitutes above-mentioned soap, can enumerate the saturated or unsaturated fatty acid of the straight or branched of carbon number 10~22.In these acid, from the viewpoint of foaming characteristic, preferred lauric acid, myristic acid, Palmic acid, stearic acid, and the fatty acid that contains more these fatty acids from natural oil, these can use separately, also can appropriate combination use.
In addition, constitute the N-acylated amino of above-mentioned N-acylated amino salt, the method that can be obtained by the Schotten-Baumann reaction with aminoacid and fatty acid chlorination thing waits and obtains.Glycine, α-Bing Ansuan, valine, leucine, isoleucine, serine, threonine, lysine, arginine, aspartic acid, glutamic acid, agedoite, glutamine, cysteine, cystine, methionine, phenylalanine, tyrosine, proline, hydroxyproline, tryptophan, histidine, Beta-alanine, episilon amino caproic acid, sarcosine, DL-pyroglutamic acid etc. can be enumerated as amino acid whose example, lauric acid, myristic acid, Palmic acid, stearic acid, oleic acid, coco-nut oil fatty acid etc. can be enumerated as the example of fatty acid.
As the alkylsurfuric acid that constitutes abovementioned alkyl sulfate, can enumerate lauryl sulfate, myristyl sulphuric acid, palmityl sulphuric acid etc.
In addition, as the polyoxyethylene alkyl ether sulphuric acid that constitutes above-mentioned polyoxyethylene alkyl ether sulfate salt, can enumerate polyoxyethylene lauryl ether sulphuric acid, polyoxyethylene myristyl ether sulphuric acid, Polyoxyethylene cetyl ether sulphuric acid etc.
In addition, there is no particular limitation with alkali in above-mentioned anion surfactant, for example, can enumerate the organic base of inorganic salt, alkanolamine and the basic amino acid etc. of alkali hydroxide metal etc.Particularly, can enumerate sodium hydroxide, potassium hydroxide, triethanolamine, 2-amino-2-methyl-1-propanol, L-arginine etc.
The content of (A) anion surfactant in aerosol type shaving agent composition of the present invention, usually, viewpoint from foaming characteristic, whole amounts with respect to shaving agent composition (removing the aerosol stock solution of propellant), be preferably 4~21 quality %, especially, just can obtain sufficient foaming characteristic if 8 quality % are above, if it is the following zest to skin of 21 quality % is also few, thereby preferred.
(B) carrageenin of Shi Yonging is the natural macromolecular material that contains in a large number in red algae in the present invention.
Usually, the carrageenin that obtains by the extraction of red algae, different according to the difference of raw material and extracting method are divided into κ class, ι class, λ class 3 kinds.Any can use, but the λ class is not owing to cause the excessive rising of viscosity and can give the razor sliding and preferred.
(B) carrageenin at shaving agent composition (removing the aerosol stock solution of propellant) if in content very fewly just can not improve the razor sliding, if the sense of being clamminess too much when flushing, just occurs.
Like this, from the effect and the viewpoint of usability, content preferably 0.1~5 quality %, to be more preferably 0.1~2.5 quality %, to be more preferably be 0.2~2.5 quality %.If 0.1 quality % above, just can guarantee the razor sliding, if 5 quality % are following, just can be suppressed at the sense of being clamminess when washing.
Aerosol type shaving agent composition of the present invention cooperates (C) propellant together and is made into goods with the above-mentioned agent of shaving in pressure vessel.
As (C) propellant that uses among the present invention, can use liquefied petroleum gas (LPG), liquefied natural gas (LNG) or the Compressed Gas low to the dissolubility of water.At least one that is selected from nitrogen, oxygen, neon, air and these mist can be enumerated as the object lesson of Compressed Gas, also multiple gases can be and used.Wherein, LPG gives appropriate expulsion pressure thereby preferred.There is no particular limitation for the consumption of this (C) propellant, in the aerosol goods that obtain, is that expulsion pressure becomes for example amount of 0.2~0.8MPa in the time of 35 ℃, is the amount that becomes 1~10 quality % ratio of common aerosol type shaving agent composition.
In aerosol type shaving agent composition of the present invention, can also contain (D) non-ionic surface active agent as required.
By containing (D) non-ionic surface active agent, it is more tiny that the bubble of the agent of shaving will become, the bubble that the sense of touch that can obtain enriching is extremely good.
As such non-ionic surface active agent, can enumerate the polyoxyalkylene alkyl class of polyoxyalkylene sorbitan fatty acid ester class, polyoxyalkylene Sorbitol fatty acid ester, polyoxyalkylene glycerine fatty acid esters, polyoxyalkylene fatty acid ester, polyoxyethylene lauryl ether, polyoxyethylene tridecyl ether etc., polyoxyalkylene alkyl phenyl ethers, polyoxyalkylene hydrogenated castor oils, sucrose-fatty esters, polyglycerol alkyl ether class, polyglyceryl fatty acid ester class, fatty acid alkanol amides, alkyl polyglucoside class etc.Wherein, preferred polyoxyalkylene fatty acid ester, more particularly, preferred monostearate macrogol ester, mono laurate macrogol ester, distearyl acid polyethylene glycol ester.
In addition, (D) content of non-ionic surface active agent, foaming characteristic from the agent stability that shaves, when using, the viewpoint of extremely thin and softish alveolar substance amount, are more preferably 0.5~7 quality %, 1~5 quality % especially preferably at 0.2~10 quality % in the agent of shaving preferably of the present invention (removing the aerosol stock solution of propellant).
Two or more kinds may be used for above-mentioned non-ionic surface active agent, particularly more preferably makes up monostearate macrogol ester, mono laurate macrogol ester.Ratio between two when in addition, making up monostearate macrogol ester, mono laurate macrogol ester preferably 3: 1~1: 3.
As the solvent of above-mentioned (A), (B), (D) composition, make water in the shaving agent composition of the present invention and use the polyhydric alcohol of propylene glycol, 1,3 butylene glycol, glycerol, Sorbitol, Polyethylene Glycol etc. as required.Polyhydric alcohol can use separately, or appropriate combination and cooperating.
Shaving agent composition of the present invention adds above-mentioned each composition, stirring, mixing and prepares in based on the solvent of water.
In shaving agent composition of the present invention, can also further cooperate the common anti-inflammatory agent that in cosmetic, is engaged, freshener, spice etc., can enjoy refrigerant sense and fragrance by cooperating these.
In addition, if cooperate antibacterial, stage of agent is shaved in the coating before using razor can peace and quiet skin, can prevent that therefore pathogenic bacteria from invading to skin.
Embodiment
Below, illustrate in greater detail the present invention by embodiment.
Embodiment 1~17 and comparative example 1~5
Made the aerosol type shaving agent stock solution of the prescription of expression in table 1.After in aerosol container, filling this stock solution, be pressed into propellant, obtain trial target.
In addition, (B) carrageenin and (C) the following article of propellant use.In addition, the mass ratio of aerosol stock solution and propellant is 96: 4.
(MRC POLYSACCHARIDE company produces λ-carrageenin, trade name: SOAGEENA LX22K)
LPG (liquid gas company in ocean produces, trade name: deodorizing and refining LPG, 20 ℃ of expulsion pressure 0.44MPa)
(evaluation methodology)
Use the aerosol type shaving agent composition of embodiment 1~17 and comparative example 1~5, allow 10 adult male investigators shave, the assessment item of " sliding of razor ", " not having soapy feeling (cleaning) during flushing ", " sense of touch of bubble " is carried out the sense evaluation according to following evaluation criterion.
This result of expression in table 1.
In addition, actual shaving is after washing one's face, wiping aqueous vapor with towel, under constant temperature and humidity (20 ℃, 65RH%) condition, with hands the shaving agent composition that aerosol sprays is applicable on the beard, uses the safety razor of twolip to carry out.
Evaluation criterion
(1) " sliding of razor "
Grade: state
A: it is 9 when above that the sliding of razor is evaluated as good investigator's number
B: when the sliding of razor is evaluated as good investigator's number and is 7~8
C: when the sliding of razor is evaluated as good investigator's number and is 5~6
D: when the sliding of razor is evaluated as good investigator's number and is 3~4
E: it is below 2 that the sliding of razor is evaluated as good investigator's number
(2) " there is not soapy feeling (cleaning) during flushing "
Grade: state
A: the investigator's number that is evaluated as flushing and the time does not have soapy feeling is 9 when above
B: when the investigator's number that is evaluated as flushing and the time does not have soapy feeling is 7~8
C: when the investigator's number that is evaluated as flushing and the time does not have soapy feeling is 5~6
D: when the investigator's number that is evaluated as flushing and the time does not have soapy feeling is 3~4
E: the investigator's number that is evaluated as flushing and the time does not have soapy feeling is 2 when following
(3) " sense of touch of bubble "
Grade: state
A: being evaluated as good investigator's number for the sense of touch of bubble is 8 when above
B: when being evaluated as good investigator's number and being 6~7 for the sense of touch of bubble
C: when being evaluated as good investigator's number and being 4~5 for the sense of touch of bubble
D: being evaluated as good investigator's number for the sense of touch of bubble is 3 when following
Table 1
Table 1-1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8 Embodiment 0
(A) anion surfactant Phosphate monoester The phosphoric acid single lauryl alcohol ester 5.50 8.00 8.00 8.00
Mono phosphoric acid ester spermaceti alcohol ester 4.50
Fatty acid Lauric acid 0.40 0.40 0.40 1.00 2.40 1.00 1.00
Myristic acid 1.20 1.20 1.20 0.10 0.10 0.10
Palmic acid 0.90 0.90 0.90 3.40 3.40 3.40
Stearic acid 1.10 1.10 1.10 4.00 5.50 4.00 4.00
Polyoxyethylene alkyl ether sulfate salt Sodium laureth sulfate 3.40
N-acylated amino salt The cocoyl Kaglutam 5.30
Alkali Potassium hydroxide 2.31 2.47 2.47 2.47
Triethanolamine 3.20 2.86 1.40 3.20 3.20
Subtotal 12.31 12.07 12.07 12.07 11.70 11.75 9.10 11.70 11.70
(B) carrageenin 0.10 0.20 0.25 2.50 0.25 0.25 2.00 3.50 5.00
Water soluble polymer Hydroxyethyl-cellulose
Hydroxypropyl emthylcellulose
The alginic acid propylene glycol ester
(D) tween Polyoxyethylene hydrogenated Oleum Ricini 0.50 0.50
Monostearate polyoxyethylene sorbitol ester (20E.0) 3.50 3.50
Polyoxyethylene lauryl ether (23E.0) 2.50
The monostearate macrogol ester
The mono laurate macrogol ester
The coco-nut oil fatty acid diethanolamine 4.20
Solvent Glycerol 4.00 4.00 4.00 4.00 6.00 6.00 6.00 6.00 6.00
Propylene glycol 5.00 6.00 5.00 5.00
Sorbitol 0.06 0.12 0.13 1.50 3.50 3.50 3.50 3.50 3.50
Water 78.03 78.61 78.03 74.03 75.08 76.00 75.20 75.31 70.31
Subtotal 87.00 87.73 87.18 85.43 84.58 85.50 84.70 84.81 70.01
Assessment item The sliding of razor B A A A A A A A A
There is not soapy feeling during flushing A A A A A A A B C
The sense of touch of bubble C C C C C C C C C
Table 1-2
Embodiment 10 Embodiment 11 Embodiment 12 Embodiment 13 Embodiment 14 Embodiment 15 Embodiment 16 Embodiment 17
(A) anion surfactant Phosphate monoester The phosphoric acid single lauryl alcohol ester 6.00 6.00 6.00 6.00 6.00
Mono phosphoric acid ester spermaceti alcohol ester
Fatty acid Lauric acid 0.40 0.40 0.40 0.40 0.40 0.15 0.15 0.15
Myristic acid 1.20 1.20 1.20 1.20 1.20 0.45 0.45 0.45
Palmic acid 0.90 0.90 0.90 0.90 0.90 1.58 1.58 1.58
Stearic acid 1.10 1.10 1.10 1.10 1.10 1.93 1.93 1.93
Polyoxyethylene alkyl ether sulfate salt Sodium laureth sulfate 5.01 5.01 5.01
N-acylated amino salt The cocoyl Kaglutam
Alkali Potassium hydroxide 2.47 2.47 2.47 2.47 2.47 0.41 0.41 0.41
Triethanolamine
Subtotal 12.07 12.07 12.07 12.07 12.07 9.52 9.52 9.52
(B) carrageenin 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50
Water soluble polymer Hydroxyethyl-cellulose
Hydroxypropyl emthylcellulose
The alginic acid propylene glycol ester
(D) tween Polyoxyethylene hydrogenated Oleum Ricini
Monostearate polyoxyethylene sorbitol ester (20E.0)
Polyoxyethylene lauryl ether (23E.0)
The monostearate macrogol ester 1.00 0.75 0.50 0.25 1.50 1.00 0.50
The mono laurate macrogol ester 0.25 0.50 0.75 1.00 0.50 1.00 1.50
The coco-nut oil fatty acid diethanolamine
Solvent Glycerol 4.00 4.00 4.00 4.00 4.00 9.00 9.00 9.00
Propylene glycol 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00
Sorbitol 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15
Water 77.28 77.28 77.28 77.28 77.28 73.83 73.83 73.83
Subtotal 86.43 86.43 86.43 86.43 86.43 87.98 87.98 87.98
Assessment item The sliding of razor A A A A A A A A
There is not soapy feeling during flushing A A A A A A A A
The sense of touch of bubble B A A A B A A A
Table 1-3
Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4 Comparative example 5
(A) anion active agent Phosphate monoester The phosphoric acid single lauryl alcohol ester 5.50 5.50 5.50
Mono phosphoric acid ester spermaceti alcohol ester 4.50 4.50 4.50
Fatty acid Lauric acid 1.00 1.00
Myristic acid 0.10 0.10
Palmic acid 3.40 3.40
Stearic acid 4.00 4.00
Polyoxyethylene alkyl ether sulfate salt Sodium laureth sulfate
N-acylated amino salt The cocoyl Kaglutam
Alkali Potassium hydroxide 2.31 2.31 2.31
Triethanolamine 3.20 3.20
Subtotal 12.31 12.31 12.31 11.70 11.70
(B) carrageenin 6.00
Water soluble polymer Hydroxyethyl-cellulose 0.10
Hydroxypropyl emthylcellulose 5.50
The alginic acid propylene glycol ester 6.00
(D) tween Polyoxyethylene hydrogenated Oleum Ricini
Monostearate polyoxyethylene sorbitol ester (20E.0)
Polyoxyethylene lauryl ether (23E.0) 3.50 3.50
The monostearate macrogol ester
The mono laurate macrogol ester
The coco-nut oil fatty acid diethanolamine
Solvent Glycerol 4.00 4.00 4.00 6.00 6.00
Propylene glycol 5.00 5.00 5.00
Sorbitol 0.09 0.09 4.00 4.00
Water 76.69 72.60 73.10 74.71 66.81
Subtotal 87.69 81.69 82.19 64.71 78.61
Assessment item The sliding of razor D A A D A
There is not soapy feeling during flushing A D D A E
The sense of touch of bubble D D D C C
Aerosol type shaving agent composition of the present invention can not make skin injured because having good razor sliding, and soapy feeling when not shaving afterflush, has outstanding usability.
Therefore, exceedingly useful as aerosol type shaving agent composition.

Claims (4)

1. an aerosol type shaving agent composition is characterized in that,
In the aerosol stock solution of (B) carrageenin of (A) anion surfactant that contains 4~21 quality % and 0.1~5 quality %, also contain (C) propellant.
2. aerosol type shaving agent composition as claimed in claim 1 is characterized in that,
(A) anion surfactant is at least one that is selected from phosphate monoester salt, soap, N-acylated amino salt, alkyl sulfate, polyoxyethylene alkyl ether sulfate salt.
3. aerosol type shaving agent composition as claimed in claim 1 or 2 is characterized in that,
Also contain (D) non-ionic surface active agent.
4. aerosol type shaving agent composition as claimed in claim 3 is characterized in that,
(D) non-ionic surface active agent is at least one that is selected from polyethylene glycol monolaurate, polyethylene glycol mono stearate and polyglycol distearate.
CN 200710141819 2006-08-11 2007-08-13 Aerosol type shaving agent composition Expired - Fee Related CN101120908B (en)

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JP2006220225 2006-08-11
JP2006-220226 2006-08-11
JP2006-220225 2006-08-11
JP2006220226 2006-08-11
JP2006220225 2006-08-11
JP2006220226 2006-08-11

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06102619B2 (en) * 1990-03-09 1994-12-14 花王株式会社 Hair setting composition
JP2005206463A (en) * 2004-01-19 2005-08-04 Kao Corp Shaving agent composition
JP2006096754A (en) * 2004-09-03 2006-04-13 Kao Corp Shaving agent
JP4746327B2 (en) * 2005-01-14 2011-08-10 株式会社林原生物化学研究所 Skin cleanser composition

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