CN101113218A - Method for producing composite polyethylene wax super fine - Google Patents
Method for producing composite polyethylene wax super fine Download PDFInfo
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- CN101113218A CN101113218A CNA2007100417359A CN200710041735A CN101113218A CN 101113218 A CN101113218 A CN 101113218A CN A2007100417359 A CNA2007100417359 A CN A2007100417359A CN 200710041735 A CN200710041735 A CN 200710041735A CN 101113218 A CN101113218 A CN 101113218A
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- wax
- polyethylene wax
- super fine
- poly propylene
- stearylamide
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Abstract
The invention relates to a production method of a composite polymethylene wax super fine powder, and is characterized in that: polypropylene wax or stearamide wax type substance additive are added to and mixed with polymethylene wax raw material, the method is that: the polymethylene wax is mixed with the polypropylene wax or the stearamide with a weight rate of 20-95 percent of polymethylene wax and 5-80 percent of polypropylene wax, or 20-95 percent of polymethylene wax and 5-80 percent of the stearamide, then coarse grinding is firstly made to the mixture till grains with a diameter of 1-5mm are obtained, super fine grinding is carried out with a muller, through which the diameter of the grains can be adjusted, the applicable operating condition of the muller is that the feeding speed is 1-50kg/h; the diameter of the produced wax powder is 20micron-8micron upon filtration, finally the composite polymethylene wax super fine powder is obtained. The invention has the advantages of high rigidity, high softening point, good polish, small grain diameter, low cost, large processing amount and simple technique.
Description
Technical field
The present invention relates to a kind of production method of composite polyethylene wax super fine, can be used to produce powder coating, can lacquer, UV curing, metal finishing coating, high gloss solvent reducible coatings, water-borne coatings, cardboard moisture-proof coating, solvent borne base gravure ink, lithographic printing/offset printing, printing ink, cover print-polishing oil.Belong to composite polyethylene wax super fine modification technology field.
Background technology
Micronized polyethylene wax micro mist is to be raw material with the polyethylene wax, through the high-tech product of complicated modern production explained hereafter.It has that hardness is big, softening temperature is high, wear resistance is good, heat-resisting, scratch resistance, resistance to wear, characteristics such as good waterproof performance.Molecular-weight average 2000-8000,105 ℃ of softening temperatures, penetration degree is less than 5 (1/10mm), density 0.95g/cm
3, acid number is less than 0.1mgKOH/g, and median size is less than 8 microns.
In coating, paint and printing ink, add 0.5-1.5% micronized polyethylene wax micro mist and will produce excellent resistance to marring, antiskid trace and level and smooth feel.Can improve the smooth feel of coating, paint and ink pellet surface, strengthen scratch resistant performance, improve the performance of product.
Because micronized polyethylene wax micro mist is a kind of high-tech product, each manufacturer all holds in close confidence both at home and abroad, so the concrete production technique that disclosed documents and materials patent is introduced micro mist wax seldom.All use single pure polyethylene wax to be raw material from disclosed data at home and abroad.
Use pure polyethylene wax to have following shortcoming as raw material production micronized polyethylene wax micro mist: micronized polyethylene wax micro mist product softening temperature depends on the fusing point of material polyethylene wax, can not adjust flexibly.The fusing point of general polyethylene wax need reach more than 110 ℃ if wish the fusing point of micronized polyethylene wax micro mist between 101 ℃-110 ℃, will be restricted.The wear resistance of micronized polyethylene wax micro mist product is subjected to the restriction of material polyethylene wax, can not change.If raw material is softer, then the wear resistance of product micronized polyethylene wax micro mist is also very poor, can't change, and is requiring the high field of wear resistance to meet consumers' demand.The penetration degree of micronized polyethylene wax micro mist can not be adjusted flexibly.The penetration degree of polyethylene wax is the performance index of expression polyethylene wax hardness, if the penetration degree of polyethylene wax is bigger, represents that then its hardness is less, represents that its hardness is bigger if the penetration degree of polyethylene wax is less.The hardness of wishing polyethylene wax at last optical arena is big, to improve the wiping properties of lustering agent, if still the hardness of polyethylene wax is less, then is difficult to satisfy user's requirement.
Zhao of Beijing Institute of Technology grassland, rectify the celebrating pool, ask that upright peace gold and jade continent etc. discloses a kind of emulsion process that is used to prepare spherical polyethylene micropowder wax, publication number is CN1884348A.This method adopts organic solvent heating for dissolving cracking polyethylene wax, adds the aqueous solution of tensio-active agent again, forms emulsion under the violent stirring, and cryoprecipitation goes out spherical polyethylene micropowder wax then.This method is simple, and is easy and simple to handle, and cost is low.Use this method and can make particle diameter uniform spherical polyethylene micropowder wax.This invention has overcome complex process in the prior art, defective that energy consumption is big; can large-scale industrial production; what but this method was used is single pure polyethylene wax; the every performance index of micronized polyethylene wax micro mist of its preparation depend on raw materials used, can not adjust the performance index such as softening temperature, penetration degree of polyethylene wax micro mist according to customer requirements.
JP53018233B discloses a kind of chemical method and mechanical process combination process of polyethylene wax micro mistization, and its main raw material is single pure polyethylene wax, uses halon solvents such as solvent trichloroethane, trieline, zellon during production.Adopt the high speed rotating pulverization process at last.The raw material that this method technology is used is single pure polyethylene wax, so material performance is decided by that product performance product physical and chemical performance index can not effectively adjust.
Summary of the invention
The purpose of this invention is to provide a kind of hardness height, softening temperature height, good luster, particle diameter is little, cost is low, treatment capacity is big, the production method of the simple composite polyethylene wax super fine of technology.
For realizing above purpose, technical scheme of the present invention provides a kind of production method of composite polyethylene wax super fine, it is characterized in that, adds Poly Propylene Wax or the mixing of stearylamide Wax additive in the polyethylene wax raw material, and its method is:
The first step. polyethylene wax is mixed with Poly Propylene Wax or stearylamide,
The weight ratio prescription of polyethylene wax and Poly Propylene Wax or stearylamide is:
Polyethylene wax 20-95%, Poly Propylene Wax 5-80%;
Or polyethylene wax 20-95%, stearylamide 5-80%;
Second step. earlier the mixture coarse reduction being made its particle diameter is the 1-5 millimeter;
The 3rd step. it is carried out superfine grinding through adjustable particle diameter formula pulverizer again, suitable pulverizer operational condition is: blast 0.1-2Mpa, input speed be the 1-50 kilogram/hour; Through screening, the wax powder of production directly is: 20 microns one 8 microns, promptly get composite polyethylene wax super fine.
Its molecular weight ranges of described Poly Propylene Wax is from 500-20000; Described stearylamide is ethylene bis stearamide, erucicamide or amine hydroxybenzene.
The present invention mixes polyethylene wax with Waxes such as Poly Propylene Wax, ethylene bis stearamides, adopt pulverizing, screening technology production Superfines Polymeric Wax Powder again.
Poly Propylene Wax of the present invention is meant the Poly Propylene Wax that cracking process and polymerization obtain.Its softening temperature is greater than 140 ℃.Its molecular weight is from 200-20000, and suitable Poly Propylene Wax molecular weight is at 1000-8000, and optimum molecular weight ranges is 2000-6000.The softening temperature of Poly Propylene Wax is apparently higher than polyethylene wax, premium properties such as have high rigidity, the toughness oilness is good, wet fastness is good and the melt viscosity range of choice is wide, and high-crystallinity makes it to have remarkable brightness and glossiness.Poly Propylene Wax can be used for pigment dispersing agent, plastics additive, hot melt adhesive, easer, paper conversion auxiliary agent, rubber processing aids of paraffin modification agent, Masterbatch etc.
Ethylene bis stearamide of the present invention (N, N-Ethylene bis-Steramide) is a kind of good plastics lubricant, is called for short EBS.Molecular formula is C
38H
76O
2N
2, outward appearance is white fine particle or fine powder, density 0.988/cm
3(25 ℃), fusing point 142-144 ℃, nontoxic, acid-and base-resisting and water medium, water insoluble, be insoluble to most of usual vehicles such as ethanol, acetone under the normal temperature.Can be fused to the chlorinated hydrocarbon and the aromatic hydrocarbon solvent of heat.Have good internal lubrication and external lubrication effect concurrently.Ethylene bis stearamide is a kind of broad-spectrum plastics and rubber inside and outside lubricant agent, is made by stearic acid and aminated compounds reaction usually.EBS has processing and lubrication effect and the antiseized effect of low temperature to fluoropolymer resin, can be used as lubricant releasing agent in plastic working, to improve the quality of plastics, improves the outward appearance of goods; In Rubber processing, EBS can be used as the surface treatment agent of lubricant, antisticking agent, releasing agent, stuffing surface modification agent and the vulcanite of sizing material; In tackiness agent, wax etc., add EBS, have to prevent to lump and the good effect of release property; In paint remover, add EBS, can improve the performance of paint remover; EBS also can be used as the composition of paper coating, the Embedding Material of electrical element.Waxing is adopted in the protection against corrosion of electrical element usually, as add EBS in wax, can improve the character of wax layer; In addition, in coating and paint, add EBS and can improve resistance to salt water, water tolerance and raising Baking Paint smoothness of the surface.
Erucicamide of the present invention is white powder, sheet, granular substance, and molecular formula is C
22H
45CONH
2, nontoxic, water insoluble, be dissolved in many organic solvents such as ethanol, ether, relative density about 0.98,76~86 ℃ of fusing points have special boundary lubrication effect.The external lubrication effect is good, particularly with other lubricant and time spent very significant synergy is arranged.Antiseized, anti-stick, antistatic and dispersed strong, though at high temperature and polyolefine consistency is arranged, along with the reduction consistency of temperature also will descend significantly, so should note in use.Erucicamide has special boundary lubrication effect.The external lubrication effect is good, particularly with other lubricant and time spent very significant synergy is arranged.The slipping agent that can be used as the processing of high temperature such as PP, PE, PVC is made the goods of lubricant with erucicamide, makes just to show good smooth property after 24 hours.In addition, this product does not influence the printing and the binding property of goods, is specially adapted to polypropylene as lubricant this product.
Advantage of the present invention is hardness height, softening temperature height, good luster, particle diameter is little, cost is low, treatment capacity is big, technology is simple.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
Select the JW5520 type polyethylene wax of Shanghai Joule Wax Industry Co.,Ltd's export trade for use, its molecular weight is 2000-4000, and softening temperature is 105 ℃, (25 ℃ of penetration degrees, 100g) 3, carry out modification with Poly Propylene Wax, used Poly Propylene Wax is the Poly Propylene Wax of import Korea S 1152 trades mark, and molecular weight is 4000-6000, softening temperature is 142 ℃, penetration degree (25 ℃, 100g) 0.1, modified condition is: 160 ℃ of modification temperatures, modification time 1 hour.
Its prescription is:
JW5520 polyethylene wax 85%
Korea S's 1152 Poly Propylene Waxes 15%
Earlier the mixture coarse reduction being made its particle diameter is the 1-5 millimeter, through adjustable particle diameter formula pulverizer it is carried out superfine grinding again, suitable pulverizer operational condition is: modified product performance input speed be the 5-10 kilogram/hour, through screening, the wax powder of production directly is:
Maximum particle diameter: 20 microns
The Dv90:15 micron
The Dv50:8 micron
The modified product performance is:
Softening temperature, ℃ 139 ℃
Penetration degree, 25 ℃, 100g 0.3
Embodiment 2
Select the JW5520 type polyethylene wax of Shanghai Joule Wax Industry Co.,Ltd's export trade for use, its molecular weight is 4000-6000, and softening temperature is 105 ℃.Carry out modification with Poly Propylene Wax, used Poly Propylene Wax is the Poly Propylene Wax of import Korea S 1152 trades mark, and molecular weight is 4000-6000, and softening temperature is 142 ℃, and modified condition is 160 ℃ of modification temperatures, modification time 1 hour.
Its prescription is
JW5528 polyethylene wax 80%
Korea S's 1152 Poly Propylene Waxes 20%
Earlier the mixture coarse reduction being made its particle diameter is the 1-5 millimeter, re-use adjustable particle diameter formula pulverizer it is carried out superfine grinding, suitable pulverizer operational condition is: input speed be the 8-20 kilogram/hour, through screening, the composite polyethylene wax grain size of micropowder of production is:
Maximum particle diameter: 12 microns
The Dv90:8.5 micron
The Dv50:3.9 micron
The modified product performance is:
Softening temperature, ℃ 140 ℃
Penetration degree, 25 ℃, 100g 0.1
Embodiment 3
Select the JW5520 type polyethylene wax of Shanghai Joule Wax Industry Co.,Ltd's export trade for use, its molecular weight is 4000-6000, and softening temperature is 105 ℃.Select import N for use, N ethylene bis stearamide, fusing point be 142 ℃, acid number less than 10mgKOH/g, amine value (mgKOH/g) less than 2.5, particle diameter crosses 200 mesh sieve holes.Modified condition is 160 ℃ of modification temperatures, modification time 1 hour.
The composite polyethylene wax prescription is:
JW5528 polyethylene wax 94%
Import N, N ethylene bis stearamide 6%
Earlier the mixture coarse reduction being made its particle diameter is the 1-5 millimeter, re-use adjustable particle diameter formula pulverizer it is carried out superfine grinding, suitable pulverizer operational condition is: the modified product input speed be the 10-25 kilogram/hour, through screening, the composite polyethylene wax grain size of micropowder of production is:
Maximum particle diameter: 10 microns
The Dv90:6.5 micron
The Dv50:3 micron
Composite polyethylene wax micro mist product performance are:
Softening temperature, ℃ 138 ℃
Penetration degree, 25 ℃, 100g 0.1
Claims (3)
1. the production method of a composite polyethylene wax super fine is characterized in that, adds Poly Propylene Wax or the mixing of stearylamide Wax additive in the polyethylene wax raw material, and its method is:
The first step. polyethylene wax is mixed with Poly Propylene Wax or stearylamide,
The weight ratio prescription of polyethylene wax and Poly Propylene Wax or stearylamide is:
Polyethylene wax 20-95%, Poly Propylene Wax 5-80%;
Or polyethylene wax 20-95%, stearylamide 5-80%;
Second step. earlier the mixture coarse reduction being made its particle diameter is the 1-5 millimeter;
The 3rd step. through adjustable particle diameter formula pulverizer it is carried out superfine grinding again, suitable pulverizer operational condition is: input speed be the 1-50 kilogram/hour, through screening, the wax powder of production directly is: 20 microns-8 microns, promptly get composite polyethylene wax super fine.
2. the production method of a kind of composite polyethylene wax super fine according to claim 1 is characterized in that, its molecular weight ranges of described Poly Propylene Wax is from 500-20000.
3. the production method of a kind of composite polyethylene wax super fine according to claim 1 is characterized in that, described stearylamide is amides organic compound such as ethylene bis stearamide, erucicamide or amine hydroxybenzene.
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CN2007100417359A CN101113218B (en) | 2007-06-07 | 2007-06-07 | Method for producing composite polyethylene wax super fine |
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CN2007100417359A CN101113218B (en) | 2007-06-07 | 2007-06-07 | Method for producing composite polyethylene wax super fine |
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CN101113218B CN101113218B (en) | 2010-07-14 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104194462A (en) * | 2014-08-22 | 2014-12-10 | 南京福臻再生资源科技股份有限公司 | Protective coating and preparation method thereof |
CN105772699A (en) * | 2014-12-22 | 2016-07-20 | 上海家声汽车零部件有限公司 | Iron base powder metallurgy material formula and molding and sintering process |
CN108276507A (en) * | 2018-01-31 | 2018-07-13 | 公安县瑞凯高分子材料股份有限公司 | A kind of aqueous sand flour of high molecular weight oxidized polyethylene wax and preparation method thereof |
CN111333874A (en) * | 2020-03-13 | 2020-06-26 | 宁夏颐星新材料科技有限公司 | Production process of polyvinyl alcohol ultrafine powder |
CN113308207A (en) * | 2021-05-31 | 2021-08-27 | 东莞市雄林新材料科技股份有限公司 | Water-splashing-preventing TPU hot melt adhesive film and preparation method thereof |
CN113713943A (en) * | 2021-07-27 | 2021-11-30 | 上海莱布星科技有限公司 | Preparation method of water wax powder |
-
2007
- 2007-06-07 CN CN2007100417359A patent/CN101113218B/en not_active Expired - Fee Related
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104194462A (en) * | 2014-08-22 | 2014-12-10 | 南京福臻再生资源科技股份有限公司 | Protective coating and preparation method thereof |
CN104194462B (en) * | 2014-08-22 | 2016-06-22 | 南京福臻再生资源科技股份有限公司 | protective coating and preparation method thereof |
CN105772699A (en) * | 2014-12-22 | 2016-07-20 | 上海家声汽车零部件有限公司 | Iron base powder metallurgy material formula and molding and sintering process |
CN108276507A (en) * | 2018-01-31 | 2018-07-13 | 公安县瑞凯高分子材料股份有限公司 | A kind of aqueous sand flour of high molecular weight oxidized polyethylene wax and preparation method thereof |
CN108276507B (en) * | 2018-01-31 | 2020-02-14 | 公安县瑞凯高分子材料股份有限公司 | High-molecular-weight oxidized polyethylene wax water-based sand flour and preparation method thereof |
CN111333874A (en) * | 2020-03-13 | 2020-06-26 | 宁夏颐星新材料科技有限公司 | Production process of polyvinyl alcohol ultrafine powder |
CN113308207A (en) * | 2021-05-31 | 2021-08-27 | 东莞市雄林新材料科技股份有限公司 | Water-splashing-preventing TPU hot melt adhesive film and preparation method thereof |
CN113713943A (en) * | 2021-07-27 | 2021-11-30 | 上海莱布星科技有限公司 | Preparation method of water wax powder |
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