CN101101955A - Alloy pole for cobalt antimonides-based thermal electrical part and part making method - Google Patents
Alloy pole for cobalt antimonides-based thermal electrical part and part making method Download PDFInfo
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- CN101101955A CN101101955A CNA2007100433898A CN200710043389A CN101101955A CN 101101955 A CN101101955 A CN 101101955A CN A2007100433898 A CNA2007100433898 A CN A2007100433898A CN 200710043389 A CN200710043389 A CN 200710043389A CN 101101955 A CN101101955 A CN 101101955A
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- 238000000034 method Methods 0.000 title claims abstract description 21
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 17
- 239000000956 alloy Substances 0.000 title claims abstract description 17
- 239000010941 cobalt Substances 0.000 title claims description 16
- 229910017052 cobalt Inorganic materials 0.000 title claims description 16
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 16
- 239000000463 material Substances 0.000 claims abstract description 50
- 238000005245 sintering Methods 0.000 claims abstract description 24
- 239000010936 titanium Substances 0.000 claims abstract description 20
- 239000010949 copper Substances 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 15
- 229910001080 W alloy Inorganic materials 0.000 claims abstract description 14
- 230000007704 transition Effects 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910018989 CoSb Inorganic materials 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 238000005422 blasting Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 238000003672 processing method Methods 0.000 claims 1
- SBYXRAKIOMOBFF-UHFFFAOYSA-N copper tungsten Chemical compound [Cu].[W] SBYXRAKIOMOBFF-UHFFFAOYSA-N 0.000 abstract description 10
- 229910018985 CoSb3 Inorganic materials 0.000 abstract description 3
- 230000005616 pyroelectricity Effects 0.000 abstract 5
- NSRGWYQTFLSLOJ-UHFFFAOYSA-N antimony;cobalt(3+) Chemical compound [Co+3].[Sb] NSRGWYQTFLSLOJ-UHFFFAOYSA-N 0.000 abstract 1
- UFIKNOKSPUOOCL-UHFFFAOYSA-N antimony;cobalt Chemical compound [Sb]#[Co] UFIKNOKSPUOOCL-UHFFFAOYSA-N 0.000 description 22
- 239000007772 electrode material Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 8
- 230000008878 coupling Effects 0.000 description 7
- 238000010168 coupling process Methods 0.000 description 7
- 238000005859 coupling reaction Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 5
- 235000012149 noodles Nutrition 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 4
- 208000037656 Respiratory Sounds Diseases 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000036316 preload Effects 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910002665 PbTe Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009661 fatigue test Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- OCGWQDWYSQAFTO-UHFFFAOYSA-N tellanylidenelead Chemical compound [Pb]=[Te] OCGWQDWYSQAFTO-UHFFFAOYSA-N 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910017315 Mo—Cu Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 230000005679 Peltier effect Effects 0.000 description 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Abstract
The invention is concerned with the electrode alloy pyroelectricity device of the cobalt antimonide pyroelectricity device and it's making method. It includes the Cu-W alloy electrode with the W quality percentage 20% to 30%; the rest components are copper and unavoidable impurity; the optimized Cu75W25 electrode hot coefficient of expansion (CTE) and the CoSb3 pyroelectricity are in right hot matching with difference no more than 9.8%. The component making applies the transition layer of the metal Ti, granularity about 20-50mum, and the discharge plasma sintering (SPS) method to achieve the connection of the Cu-W alloy electrode and the pyroelectricity. Because of the high conductivity and the thermal conductivity of the copper tungsten alloy and it is matching with the CoSb3 pyroelectricity material rightly, the invention is with the quite stable surface with no obvious composition plane electrode transition, keeps the making method simple.
Description
Technical field
The present invention relates to a kind of alloy electrode and part making method that is used for cobalt antimonides-based thermal electrical part, relate to the method for attachment of electrode material and the electrode and the thermoelectric material of cobalt antimonides-based thermal electrical part or rather, belong to the preparing technical field of thermoelectric components and parts.
Background technology
The thermoelectric material functional material that to be a kind of Seebeck of utilization effect and Peltier effect transform heat energy and electric energy mutually; do not need the mechanical movement position when working by the thermoelectric device of thermoelectric material preparation; chemical reaction does not take place yet; it is long to have a life-span; the reliability height; advantages such as environmentally safe, along with increasing the weight of day by day of global environmental pollution and energy crisis, thermoelectric device is subjected to the attention of various countries' research day by day.At present, about the thermoelectric material Element Technology of cryogenic cooling suitable ripe such as bismuth telluride and be widely used in commodity production for example, the thermoelectric material of middle high temperature such as the components and parts of preparations such as PbTe, SiGe also begin to be applied to space field in developed countries such as the U.S. at present.Antimony cobalt-based thermoelectric material because of its special electronic structure be considered to the most promising in warm electricity generation material, the P type that mixes or fill, its thermoelectric figure of merit of antimony cobalt-based thermoelectric material (ZT) of N type have all reached more than 1.0, but its components and parts technology of preparing is still far from perfect, and particularly relates to the difference that electrode is connected owing to thermal coefficient of expansion with the antimony cobalt and has very big difficulty.
Select major requirement to have following characteristic to the electrode of thermoelectric material components and parts: in the serviceability temperature scope, not have serious counterdiffusion mutually or reaction, thereby guarantee that the thermoelectric material self performance is unaffected with corresponding thermoelectric material; Higher conductivity and thermal conductivity are arranged to reduce energy loss; To have certain non-oxidizability in the serviceability temperature scope to guarantee the reliability and the useful life of device; Thereby being the thermal coefficient of expansion and the corresponding thermoelectric material coupling of electrode material, the most important influences thermoelectric transmission performance with thermal stability to prevent to crack.
Low temperature thermoelectric unit spare generally selects for use Al etc. as electrode because the temperature range span is little, has selected for use Al (A1200, A1100, A1050 etc.) as electrode material as BiTe thermoelectric material among the patent documentation JP10012935.But for middle elevated temperature heat electrical component, because the temperature range span is bigger, and the long-term work of thermoelectric device hot junction is under hot conditions, electrode material and thermoelectric material be because the difference of thermal coefficient of expansion (CTE) and very easily cracking at the interface, therefore selects for the electrode of middle elevated temperature heat electrical component and be connected technology higher requirement is arranged.In patent documentation JP11274580, the PbTe thermoelectric material has adopted the Cu electrode, and among the patent documentation JP2000100751, the SiC thermoelectric material is also selected the Cu electrode for use.The research for antimony cobalt-based thermoelectric material device at present is in laboratory stage, and most of cobalt stibium antimonide based thermoelectric device electrodes have also adopted the Cu electrode, as patent documentation JP2004063585, and in fact Cu and CoSb
3CTE difference excessively (be respectively 18 * 10 100 ℃ the time
-6K
-1With 10 * 10
-6K
-1), be easy to cause the cracking of electrode and thermoelectric material.Have only U.S. jet power laboratory (JetPropulsion Laboratory) once when the 20th International Conference onThermoelectrics reports list to the thermoelectric power generation of antimony cobalt-based, to adopt metal Ti abroad as electrode, do not add elaboration for concrete preparation technology, be in the secret stage.Ti is that conductivity is relative with thermal conductivity higher as the shortcoming of electrode, and energy consumption is bigger, and non-oxidizability is poor.A large amount of work has been done by domestic Shanghai Silicate Inst., Chinese Academy of Sciences on the preparation of antimony cobalt-based thermoelectric material and element manufacturing, especially be connected with the reliability of electrode material to have done targetedly and study at selection of electrode materials and antimony cobalt-based thermoelectric material, as in CN1585145 and 200710037778.X (application number), adopt metal M o or Mo-Cu alloy as electrode material, adopt diverse ways to prepare antimony cobalt-based thermoelectric material components and parts, the present invention intends further optimizing on this basis the heat coupling, the more good Cu-W alloy electrode material of hot coupling has been proposed, utilize SPS (plasma discharging) sintering method to prepare antimony cobalt-based thermoelectric material components and parts, realized good being connected of electrode material with antimony cobalt-based thermoelectric material.
Summary of the invention
The object of the invention is to provide a kind of preparation method who is used for the alloy electrode and the thermoelectric element of cobalt antimonides-based thermal electrical part, be that the present invention puies forward the good Cu-W alloy electrode of a kind of and antimony cobalt-based thermoelectric material heat coupling and the technology that is connected of electrode and antimony cobalt-based thermoelectric material, thereby it is good to prepare interface electrical property transition, interface reliability height and the easy cobalt antimonides-based thermal electrical part of technology.
The present invention selects for use copper-tungsten (Cu-W) to do electrode, copper-tungsten made at 1400 ℃ of high temperature hot pressed sinterings in 1-2 hour, the microstructure of copper-tungsten owing to can freely design on the thermal expansion matching, has been avoided single Cu electrode because the excessive micro-crack that causes of thermal coefficient of expansion as shown in Figure 1.Mensuration knows that antimony cobalt thermoelectric material thermal coefficient of expansion is in 10-11 * 10 in 100-600 ℃ of temperature range
-6K
-1In the scope, the Cu-W alloy electrode component that is provided is that the content of tungsten is 20-30%, and surplus is copper and a small amount of unavoidable impurities, and best composition is the quality percentage composition 25% of tungsten, and surplus is copper and impurity, and note is made Cu
75W
25, also i.e. Cu after optimal design of the present invention
75W
25The electrode thermal expansion coefficient in 100-600 ℃ of temperature range basically in 9-11 * 10
-6K
-1In the scope, its CTE difference maximum only has 9.8%, described Cu
75W
25Electrode material and CoSb
3The thermal coefficient of expansion of thermoelectric material more as shown in Figure 2.Owing to obtained very good heat coupling, will reduce greatly like this because electrode in the thermal stress that produces at the interface, will farthest improve the useful life of cobalt stibium antimonide based thermoelectric device with the different of antimony cobalt-based thermoelectric material thermal expansion.
The electrode that the present invention selects for use with the processing step that the CoSb3 thermoelectric material adopts SPS to be connected is: at first Cu-W alloy electrode sheet metal is through blasting treatment, make its surface have certain roughness, sonicated is removed its surperficial impurity then, puts it in the graphite jig.Particle diameter is evenly covered the surface of electrode metal sheet at the Ti powder of 20-50 μ m, spread CoSb more equably on Ti powder surface then
3Powder, carry out discharge plasma sintering in the vacuum, vacuum degree is 1Pa-15Pa, programming rate is controlled at 80-150 ℃/min, sintering temperature is 550-600 ℃, sintering pressure is at 30-60MPa, and temperature retention time utilized the SPS method that antimony cobalt thermoelectric material and Cu-W alloy electrode good binding are in the same place at 10-30 minute.Use as the Ti layer of transition zone as resilient coating, is because Ti and CoSb on the one hand
3Can form alloy-layer, the introducing of Ti transition zone simultaneously also becomes semiconductor and being connected of metal being connected of metal and metal, and the Ti layer about 50-200 μ m can not introduced too big interface resistance and thermal resistance yet on the other hand.Described Cu-W electrode metal sheet thickness is 1-3mm.
This shows, the invention provides a kind of and good alloy electrode and element electrode and the CoSb of antimony cobalt-based thermoelectric material heat coupling
3Interconnection technique technology, its maximum characteristics are to finish connection by discharge plasma sintering is once sintered, the composition surface does not have the transition of sharp interface resistance, combination interface is good, good reliability and technological operation are easy, and, make be improved useful life because the good heat coupling of electrode and thermoelectric material will farthest reduce the generation of thermal stress at the interface.
Description of drawings
Fig. 1 is thermal coefficient of expansion and CoSb
3The Cu that material is complementary
75W
25The microstructure of electrode.
Fig. 2 is CoSb
3With the thermal coefficient of expansion comparison diagram of Cu-W electrode at 100-600 ℃.
Fig. 3 is Cu-W electrode/CoSb in the thermoelectric element
3The sem photograph at interface.
Fig. 4 is Cu-W electrode/CoSb in the thermoelectric element
3The sem photograph of the various elements in interface, Fig. 4 (a) is the ESEM of institute's favored area; Fig. 4 (b) is the vegetarian noodles scanning of the favored area W of institute unit; Fig. 4 (c) is the first vegetarian noodles scanning of selected zone C u; Fig. 4 (d) is the first vegetarian noodles scanning of selected zone C o; Fig. 4 (e) is the first vegetarian noodles scanning of selected region S b; Fig. 4 (f) is the vegetarian noodles scanning of the favored area Ti of institute unit.
Fig. 5 is a phase boundary potential changes in distribution situation, and wherein abscissa is a test position, and unit is mm, and ordinate is voltage V, and unit is mV.
Embodiment
Below by instantiation substantive distinguishing features of the present invention and obvious improvement are described, but the present invention only is confined to embodiment by no means.
The copper tungsten electrode consists of Cu
75W
25Thickness 1mm, at first blasting treatment 2 minutes in sand-blasting machine of surface, sonicated is 10 minutes then, the copper tungsten electrode is put into the graphite jig of Φ 10, spread the titanium valve of granularity uniformly at electrode surface, then press antimony cobalt thermoelectric material, preload pressure 10MPa uniformly in advance at 20 μ m, carry out the SPS sintering then, vacuum degree 1Pa, sintering pressure are 30MPa, and heating rate is 80 ℃/min, sintering temperature is 600 ℃, is incubated 10min then and finishes sintering.
Resulting Cu-W electrode/CoSb
3Block is through scanning electron microscopic observation, the interface is in conjunction with good, do not see the crackle (see figure 3) is arranged, electron probing analysis shows and does not have tangible interfacial diffusion between antimony cobalt-based thermoelectric material and electrode interface that Fig. 4 a shows device interfaces selected sector scanning Electronic Speculum figure and W, Cu respectively to Fig. 4 f, Ti, Co, the face of Sb element distributes, by contrasting as can be seen at CoSb among the figure
3/ Ti interlayer has formed a TiSb alloy-layer that approaches, and this should be to form owing to Sb in the SPS process diffuses into the Ti layer.Adopt four termination electrode methods that the interface zone Potential Distributing is measured, the mild transition of electromotive force on the interface as can be seen, maximum potential difference only is 15 μ V when electric current is 10mA, there is not big electromotive force transition, illustrate from the side that also tangible resistance transition (see figure 5) is not taking place resistance at the interface, 500 hours thermal fatigue test rear interface microstructures and phase boundary potential do not have significant change, have illustrated to utilize SPS to connect the Cu-W electrode and thermoelectric material can stand long thermal fatigue test.
Copper tungsten electrode component is Cu
80W
20Thickness 2mm, with with embodiment 1 in identical method and condition electrode is handled, the copper tungsten electrode is put into the graphite jig of Φ 10, spread the titanium valve of granularity 40 μ m equably at electrode surface, then press antimony cobalt thermoelectric material equably in advance, preload pressure 10MPa carries out SPS sintering, vacuum degree 7Pa then, sintering pressure is 50MPa, heating rate is 120 ℃/min, and sintering temperature is 580 ℃, is incubated 20min then and finishes sintering.
Resulting Cu-W electrode/CoSb
3Block finds no crackle through scanning electron microscopic observation, and electron probing analysis antimony cobalt-based thermoelectric material and electrode interface do not have tangible interfacial diffusion, and tangible electromotive force transition does not take place interfacial potential.
Embodiment 3
Copper tungsten electrode Cu
70W
30Thickness 3mm, with with embodiment 1 in identical method and condition electrode is handled, the copper tungsten electrode is put into the graphite jig of Φ 10, spread the titanium valve of granularity 50 μ m uniformly at electrode surface, then press antimony cobalt thermoelectric material uniformly in advance, preload pressure 10MPa carries out SPS sintering, vacuum degree 15Pa then, sintering pressure is 60MPa, heating rate is 150 ℃/min, and sintering temperature is 550 ℃, is incubated 30min then and finishes sintering.
Resulting Cu-W electrode/CoSb
3Block is not found crackle through scanning electron microscopic observation, and electron probing analysis antimony cobalt-based thermoelectric material and electrode interface do not have tangible interfacial diffusion, and tangible electromotive force transition does not take place interfacial potential.
Claims (8)
1, a kind of alloy electrode that is used for cobalt antimonides-based thermal electrical part is characterized in that described alloy electrode is the Cu-W alloy, and wherein the quality percentage composition of W is 20%-30%, and surplus is copper and a small amount of unavoidable impurities.
2, by the described alloy electrode that is used for cobalt antimonides-based thermal electrical part of right 1 requirement, the quality percentage composition that it is characterized in that W in the described Cu-W alloy electrode is 25%, and surplus is Cu and a small amount of unavoidable impurities.
3, a kind of by claim 1 or the 2 described methods of attachment that are used for the alloy electrode and the thermoelectric material of cobalt antimonides-based thermal electrical part, it is characterized in that connecting processing step and be:
(a) at first the Cu-W alloy electrode is made sheet metal, through blasting treatment, remove surface impurity with ultrasonic processing method, the quality percentage composition of W is 20%-30% in the Cu-W alloy electrode sheet metal, and surplus is Cu and a small amount of unavoidable impurities;
(b) step (a) Cu-W alloy electrode sheet metal is after treatment put into graphite jig, on the electrode metal sheet, evenly cover the Ti powder, spread CoSb more equably on Ti powder surface then as transition zone
3Powder;
(c) carry out discharge plasma sintering in the vacuum, vacuum degree 1Pa-15Pa, sintering temperature 550-600 ℃, sintering pressure is 30-60Mpa, utilizes the plasma discharging method with CoSb
3Thermoelectric material is connected with the Cu-W alloy electrode.
4,, it is characterized in that described Cu-W electrode metal sheet thickness is 1-3mm by the described method of attachment that is used for the alloy electrode and the thermoelectric material of cobalt antimonides-based thermal electrical part of claim 3
5,, it is characterized in that employed Ti powder directly is 20-50 μ m by the described method of attachment that is used for the alloy electrode and the thermoelectric material of cobalt antimonides-based thermal electrical part of claim 3.
6, by the described method of attachment that is used for the alloy electrode and the thermoelectric material of cobalt antimonides-based thermal electrical part of claim 3, the programming rate when it is characterized in that discharge plasma sintering in the step (c) is 80-150 ℃/min.
7,, it is characterized in that the discharge plasma sintering temperature retention time is 10-30 minute in the step (c) by the described method of attachment that is used for the alloy electrode and the thermoelectric material of cobalt antimonides-based thermal electrical part of claim 3.
8, by claim 3 or the 5 described methods of attachment that are used for the alloy electrode and the thermoelectric material of cobalt antimonides-based thermal electrical part, it is characterized in that described alloy electrode sheet metal and CoSb
3Thermoelectric material connects, and the thickness of Ti transition zone is 50-200 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100433898A CN101101955A (en) | 2007-07-03 | 2007-07-03 | Alloy pole for cobalt antimonides-based thermal electrical part and part making method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100433898A CN101101955A (en) | 2007-07-03 | 2007-07-03 | Alloy pole for cobalt antimonides-based thermal electrical part and part making method |
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| Publication Number | Publication Date |
|---|---|
| CN101101955A true CN101101955A (en) | 2008-01-09 |
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ID=39036130
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|---|---|---|---|
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101728477B (en) * | 2009-12-04 | 2011-08-17 | 北京工业大学 | Method for preparing CeyFe4Sb12/Ca3Co4O9(y=0.8-1.2) based block gradient thermoelectric material |
| CN103311423A (en) * | 2012-02-17 | 2013-09-18 | 雅马哈株式会社 | Thermoelectric conversion module and method for manufacturing thermoelectric conversion module |
| CN104347788A (en) * | 2013-08-05 | 2015-02-11 | 中国科学院上海硅酸盐研究所 | Skutterudite-based thermoelectric element equipment and preparation method thereof |
| CN104362249A (en) * | 2014-11-14 | 2015-02-18 | 武汉理工大学 | Layered electrode matched with Mg-Si-Sn-based thermoelectric element and connecting technology thereof |
| CN104934523A (en) * | 2014-03-19 | 2015-09-23 | 中国科学院上海硅酸盐研究所 | Middle-high temperature thermoelectric module |
| EP2927973A1 (en) * | 2012-11-28 | 2015-10-07 | Furukawa Co., Ltd. | Thermoelectric conversion module |
| CN111014929A (en) * | 2019-12-28 | 2020-04-17 | 哈尔滨工业大学 | Rapid diffusion welding connection method for skutterudite thermoelectric material and electrode |
| CN114284422A (en) * | 2022-01-20 | 2022-04-05 | 济南大学 | Is suitable for CoSb3High-entropy electrode based on thermoelectric material and connection method of thermoelectric material and high-entropy electrode |
-
2007
- 2007-07-03 CN CNA2007100433898A patent/CN101101955A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101728477B (en) * | 2009-12-04 | 2011-08-17 | 北京工业大学 | Method for preparing CeyFe4Sb12/Ca3Co4O9(y=0.8-1.2) based block gradient thermoelectric material |
| US9705061B2 (en) | 2012-02-17 | 2017-07-11 | Yamaha Corporation | Thermoelectric conversion module and method for manufacturing thermoelectric conversion module |
| CN103311423A (en) * | 2012-02-17 | 2013-09-18 | 雅马哈株式会社 | Thermoelectric conversion module and method for manufacturing thermoelectric conversion module |
| EP2927973A1 (en) * | 2012-11-28 | 2015-10-07 | Furukawa Co., Ltd. | Thermoelectric conversion module |
| JPWO2014084315A1 (en) * | 2012-11-28 | 2017-01-05 | 古河機械金属株式会社 | Thermoelectric conversion module |
| EP2927973A4 (en) * | 2012-11-28 | 2017-05-03 | Furukawa Co., Ltd. | Thermoelectric conversion module |
| CN104347788A (en) * | 2013-08-05 | 2015-02-11 | 中国科学院上海硅酸盐研究所 | Skutterudite-based thermoelectric element equipment and preparation method thereof |
| CN104347788B (en) * | 2013-08-05 | 2017-02-15 | 中国科学院上海硅酸盐研究所 | Skutterudite-based thermoelectric element equipment and preparation method thereof |
| CN104934523A (en) * | 2014-03-19 | 2015-09-23 | 中国科学院上海硅酸盐研究所 | Middle-high temperature thermoelectric module |
| CN104934523B (en) * | 2014-03-19 | 2017-11-10 | 中国科学院上海硅酸盐研究所 | A kind of high temperature electrothermal module |
| CN104362249A (en) * | 2014-11-14 | 2015-02-18 | 武汉理工大学 | Layered electrode matched with Mg-Si-Sn-based thermoelectric element and connecting technology thereof |
| CN104362249B (en) * | 2014-11-14 | 2017-07-11 | 武汉理工大学 | A kind of layered electrode and its Joining Technology matched with Mg Si Sn base thermoelectric elements |
| CN111014929A (en) * | 2019-12-28 | 2020-04-17 | 哈尔滨工业大学 | Rapid diffusion welding connection method for skutterudite thermoelectric material and electrode |
| CN111014929B (en) * | 2019-12-28 | 2021-04-20 | 哈尔滨工业大学 | Rapid diffusion welding connection method for skutterudite thermoelectric material and electrode |
| CN114284422A (en) * | 2022-01-20 | 2022-04-05 | 济南大学 | Is suitable for CoSb3High-entropy electrode based on thermoelectric material and connection method of thermoelectric material and high-entropy electrode |
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