CN101066794A - Activated water with low salt content and small water molecule cluster - Google Patents

Activated water with low salt content and small water molecule cluster Download PDF

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CN101066794A
CN101066794A CN 200710100317 CN200710100317A CN101066794A CN 101066794 A CN101066794 A CN 101066794A CN 200710100317 CN200710100317 CN 200710100317 CN 200710100317 A CN200710100317 A CN 200710100317A CN 101066794 A CN101066794 A CN 101066794A
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water
cluster
activated
small
molecule
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CN100482598C (en
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李福志
赵璇
彭若梦
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Tsinghua University
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Tsinghua University
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Abstract

The activated water with low salt content and small water molecule cluster is compounded with pure water with resistivity higher than 0.5 magaohm.cm. It contains Ca2+ in 0.1-0.2 mg/l, Na+ in 0.2-0.3 mg/l, Li+ in 4-6 mcg/l, Sr2+ in 8-9 mcg/l, Zn2+ in 18-20 mcg/l, metasilicic acid in 60-80 mcg/l, Mg2+ in 0.2-0.25 mg/l, Fe2+ in 0.04-0.05 mg/l, K+ in 100-150 mcg/l, total cation of 0.6-1.0 mg/l. It has 17O-NMR peak width at half height in 51-60 Hz stably. The drinking water is safe and healthful.

Description

A kind of small water molecule cluster activated water of low saline salinity
Technical field
The present invention relates to a kind of tap water, particularly a kind of small water molecule cluster activated water of low saline salinity belongs to technical field of drinking water treatment.
Background technology
In recent years, in physical research, find, between two-layer time of the atom and molecule of the structure of matter and condensed state, exist this important layer of structure of cluster, and develop into a new subject-cluster physics thus.Here said cluster refers to by several and even thousands of metastable aggregates that atom, molecule or ion are formed by physics and Chemical bond power, and its physics and chemical property change with contained atom or molecule number purpose.The space scale of cluster is the scope of nanometer to tens nanometer, describes with inorganic molecule to seem too big, describes with bit solid to seem too little again.Therefore, people regard cluster as the new level of the structure of matter between atom and molecule and macroscopical solid or liquid.
Form by the electronics bonding of cluster decision can change solid, liquid, even the performance of gas and character.When electronics left original position and shared by whole cluster, negative charge can distribute equably, and cluster may present the character of some solid metal, for example electroconductibility.When all electronics all combined with atom tightly, cluster then was similar to the dispersive molecule.Variation on the small cluster size can produce the difference on the huge performance, and the saying that cluster is being represented a kind of special states of matter of material has been consolidated in this discovery.
Water molecules is formed by two hydrogen atoms and a Sauerstoffatom covalent attachment.For the outer shell that makes Sauerstoffatom is saturated, it needs two electronics, so the electronics of each shared in common in it and two hydrogen atoms.These hydrogen atoms and Sauerstoffatom are combined together to form a leg-of-mutton structure, and this shape is to constitute many bases of supporting the solution and the compound of life.
Covalent union key in the water molecules is the polar key, and shared electronics is attracted (most of the time and the coexistence of oxygen nuclear) by oxygen nuclear largely.Therefore, near the nearly oxygen nuclear of water molecules, just form a small negative charge, near nearly proton, then formed a small positive charge.Simultaneously, because hydrogen nuclei has only an electronics outward, the result of its electronic cloud skew Sauerstoffatom makes it become almost bare proton.The Sauerstoffatom that this radius is very little, contain lone electron pair and band portion negative charge in positively charged hydrogen atom and another water molecules again is fully near producing magnetism, and this magnetism is exactly a hydrogen bond.As everyone knows, such hydrogen bonded plays an important role in many biological compounds, and is the basis that protein and nucleic acid keep the macromole shape.
Therefore, outside water exists divided by the unit molecule form, also can form the cluster (water cluster) of the water that links up by hydrogen bond by some water moleculess.This cluster structure of water is all very high reasons of numerical value such as the temperature of the viscosity, surface tension, fusing point and the boiling point that cause it and thermal capacity, what is more important, and the cluster structure of water has significant effects to HUMAN HEALTH.At present, the revolutionary conclusion that scientists is found is exactly, and the shape of molecule is important as the composition of the function of molecule and molecule.
It is found that in the research of the cluster of water the cluster of water is with multiple specific resonant frequency vibration, and help to recover human body cell inside configuration balance by these frequency transduction information.Transduction is meant the process that a kind of energy of form is changed into the energy of another kind of form.We are experiencing this process every day on the sense organ of oneself, eyes change light into electronic signal, and brain is stored in it in brain after experiencing electronic signal.Our ear is low-frequency sound wave transmitter, and gustatory organ then is chemical transmitter.
But after water was subjected to the objectionable impurities pollution, complete molecular structure water will be destroyed, thereby send the bad frequency that impairs one's health.An Austrian physicist and Fu Gelu territory doctor (Dr.Wolfgang Ludwig) point out, really organism damaged, and be not the objectionable impurities body that those naked eyes are seen, but the vibrational frequency that objectionable impurities discharged.He is the bad frequency experiment showed, that those pollutents are produced more, even through multi-filtering or distillation, still can remain in the water, influences our health.This finds that " glassware for drinking water has physical property memory " this theory that is proposed with long-pending doctor Ke Banlehua (Dr.Jacques Beneviste) of French biologist is perfectly in harmony.
Therefore, in the process of water treatment, the objectionable impurities of only removing in the water is not enough, also must adjust the resonant frequency of water, that is the cluster structure of adjustment water (resonant frequency that certain cluster structure is corresponding certain), make it can not constitute a threat to human beings'health.
Thing is not only to terminate in this.1992, the Japanology personnel used magnetic resonance imaging MRI scientific discovery human senility not only to cause dehydration, and remain in in-house water and also structural variation is taking place, and when these change when fairly obvious, it can quicken human senility.Its most significant metamorphosis is that the biological water that is bound by biomacromolecule increases, and is accompanied by the minimizing of " freedom " water cluster equally.The power activity of biological water-such as the cell traffic, the motion of molecule, the conveying of nutrition, the ability of discharging toxin and diffusion all fails with advancing age.
The bronsted doctor of Martin Ah nurse of Fu Leibao physics university points out that the water cluster of negative charge is common especially in Human Physiology, it is made up of the water molecule cluster of eight or more negative charge.By adjusting the structure (resonant frequency) of water molecule cluster, make it identical with the structure of life water in the human body, so, the water that is produced will be followed the principle that is similar to chemically " similar mixing ", easier being absorbed by the body.Replenish the life water that human body is lost by this approach in aging course, just can play the effect of delaying human body caducity.Simultaneously, can also make cell of organism and organ give full play to the function that absorbs nutrient, accelerate the discharge of refuse in the body, the invasion of the extraneous virus of opposing restores balance health as early as possible, avoids the generation of general diseases.
Water clusters clustering architecture and HUMAN HEALTH have very confidential relation.Many countries and WHO, all reported the long-lived crowd's of world's " Changshou village ", " no cancer village " inhabitation common feature once, find that these areas have all drunk water throughout the year, and the most important is exactly a water molecules number less (as shown in table 1) contained in the cluster structure of water in these good common features that water possessed.
The feature of table 1 world Changshou village drinking-water
Sample Mineral substance (ppm) 17O-NMR peak width at half height (Hz)
Ca Mg K Na Si
1 92.7 13.8 2.78 38.8 11.7 82
2 66.7 14.7 1.43 32.7 11.3 74
3 82.1 18.6 0.95 43.8 13.2 75
4 23.5 13.2 8.44 35.6 26.1 64
5 13.7 2.11 1.82 9.68 23.5 76
6 7.39 1.67 2.14 4.71 24.5 83
As can be seen from Table 1, the difference of various content of mineral substances is very big in the tap water of world's Changshou village, but its 17O-NMR (the oxygen spectrum nucleus magnetic resonance of water) peak width at half height but has a scope roughly, in the scope of 74-83Hz.This shows that the cluster structure of water may have very important influence to HUMAN HEALTH.
In the application of industry such as food, beverage to water, the cluster structure also in action.Find that in the research process of Japanese sake the local flavor of old wine is than not being still drank after a night without the wine that leads to is pure and sweet.Finding all do not having what difference aspect alcoholic strength, pol and other component between the two through chemical analysis, is that water molecules number contained in the water cluster of old wine tails off, and just the physical properties of water is different.Soon, spread out of the saying of the little water of cluster at large in Japan to healthfulness.
Can change the cluster structure of water by physics and chemically treated method.But the adjustment to the microtexture of water at present depends on the physical treatment method more.Electric field, magnetic field, far infrared, ultrasonic wave, pottery etc. are several processing means that are most widely used.
There is the subject matter of following two aspects in the cluster structure that method by physical treatment changes tap water:
1.. the change of cluster structure has ageing
Because change the cluster structure of water by physical method, the cluster structure of the water after the processing is in unsteady state, must take place from the transient process of unstable state to stable state, therefore the change of the cluster structure by the water that physical method caused has ageing.According to research, after handling through physical method, the cluster structure of water is generally at several hrs, even several minutes, just is returned to original state in the kind in several seconds.
2.. the change of cluster structure has uncertainty
Utilizing 17Find in the process of O-NMR research liquid water cluster structure, liquid water is after physical treatment, and water molecule cluster not only can diminish, and also might become big, the change of water molecule cluster size has uncertainty, and the amplitude of this variation can weaken gradually along with the prolongation of time.
Summary of the invention
The objective of the invention is provides a kind of small water molecule cluster activated water of low saline salinity at the existing ageing and probabilistic problem of cluster structure that changes water at present by the physical treatment method.This small water molecule cluster activated water assigns to change the cluster structure of water by regulating chemical group, water molecule cluster is stabilized on the small construction, this structure not in time prolongation and change, when guaranteeing safe for drinking, can promote health comprehensively, effectively enhance immunity power delays senility.
Technical scheme of the present invention is as follows:
A kind of small water molecule cluster activated water of low saline salinity is characterized in that: this activated water is formulated greater than the pure water of 0.5M Ω cm by resistivity, wherein contains:
Ca 2+:0.1~0.2mg/L
Na +:0.2~0.3mg/L
Li +:4~6μg/L
Sr 2+:8~9μg/L
Zn 2+:18~20μg/L
Mg 2+:0.2~0.25mg/L
Fe 2+:40~50μg/L
K +:100~150μg/L
Metasilicic acid: 60~80 μ g/L.
Cationic total content is greater than 0.6mg/L in the described small water molecule cluster activated water, smaller or equal to 1.0mg/L, and activated water 17The O-NMR peak width at half height is between 51~60Hz.
The present invention compared with prior art, have the following advantages and the high-lighting effect: the present invention is by the chemical composition adjusting but not the method for physical treatment changes the cluster structure of water, because the chemical composition of water is stable, therefore water molecule cluster is stabilized on the small construction, this Stability Analysis of Structures exists, not prolongation in time and changing.Test shows, the low saline salinity small water molecule cluster activated water of being prepared 17The O-NMR peak width at half height is in the scope of 51-60Hz (25 ℃).Simultaneously, the result of Bioexperiment shows that this low saline salinity small water molecule cluster activated water can effectively improve the immunity function of human body, and has antineoplastic action.By to the replenishing of life water in the life entity, the small water molecule cluster activated water of long-term drinking low saline salinity can also effectively delay senility.
Description of drawings
Fig. 1 is for water after the physical treatment 17The time dependent curve of O-NMR peak width at half height.Wherein: H 0For water before the physical treatment 17The O-NMR peak width at half height.
Embodiment
The present invention is further described below in conjunction with embodiment.
Embodiment 1: utilize the small water molecule cluster activated water of resistivity greater than the pure water preparation low saline salinity of 0.5M Ω cm, contain Ca in the water of being prepared 2+: 0.154mg/L; Na +: 0.223mg/L; Li +: 5 μ g/L; Sr 2+: 8 μ g/L; Zn 2+: 18 μ g/L; Metasilicic acid: 80 μ g/L; Mg 2+: 0.2mg/L; Fe 2+: 40 μ g/L; K +: 100 μ g/L, cationic total content is 0.828mg/L in the water.
Utilize 17The O-NMR peak width at half height can characterize the average relative size of liquid water cluster structure.For nucleus magnetic resonance because the influence of the relaxation process mainly examined of the life-span of nuclear spin on each energy level, so the relaxation time of nucleus magnetic resonance spectral line width and sample be inversely proportional to.Though there is longitudinal relaxation time (T in the relaxation time 1) and T2 (T 2) branch, but for each nuclear, it only depends on reckling among both in the mean time (life-span) that a certain high level stops.For liquid, T 1〉=T 2Therefore the nucleus magnetic resonance spectral line width of liquid water mainly is subjected to the influence of transverse relaxation process.Because the transverse relaxation process is the exchange of spin states between the contiguous nuclear, and the cluster structure of water is big more, the exchange of spin states is just fast more between oxygen nuclear or proton and the contiguous nuclear, it is just short more that water sample returns to the needed time of equilibrium state, spectral line is just wide more, therefore, utilizes the average relative size that the width of nucleus magnetic resonance spectral line can reflecting liquid water body clustering architecture, spectral line is wide more, and cluster is big more; Spectral line is narrow more, and cluster is more little.
Water is elementary composition by H and two kinds of O, and these two kinds of elements have three kinds of isotropic substances respectively: 1H, 2H (D), 3H (T) and 16O, 17O and 18O.Wherein, 16O and 18The spin quantum number of O is 0, is non magnetic nuclear, can't be used for the measurement of nucleus magnetic resonance.And 3H (T) is a kind of radioactive nuclear that has, and its natural abundance is very low, the signal that obtains when being used for nuclear magnetic resonance spectroscopy very a little less than, therefore also can't be used for the analysis of liquid water cluster structure.When carrying out Nuclear Magnetic Resonance Measurement, usually will with 2The resonance locking magnetic field of H nuclear, so 2H also can't be used for the analysis of liquid water cluster structure.
Different water samples 1The H-NMR spectral line width with 17The O-NMR spectral line width is compared, and the result is less than normal and relative difference is little, is unfavorable for different water samples are compared.Therefore when utilizing nucleus magnetic resonance liquid towards water to study, should select for use 17O nuclear is measured.
Utilize 17The O nucleus magnetic resonance is measured, above-mentioned water sample 17The O-NMR peak width at half height is 51Hz.And general tap water water sample 17The O-NMR peak width at half height is all more than 80Hz, so the average relative size of the water molecule cluster that is comprised in this water sample is less.
Utilize the small water molecule cluster activated water and the pure water nursing mouse of this low saline salinity to compare experiment, found that, after 50 days, drinking the mouse of low saline salinity small water molecule cluster activated water compares with the mouse of purified drinking water, thymus index has improved 12%, the chicken red blood cell phagocytic index has improved 17%, and the NK cytoactive has improved 18%.Because thymus index is one of comprehensive reflection of the non-special variation of immunity system, and the chicken red blood cell phagocytic index to have represented non-specific immunity be mononuclear phagocyte system, therefore, after drinking the small water molecule cluster activated water of low saline salinity, non-specific immunity system of mouse and NK cytoactive strengthen.Because nonspecific immunity system and NK cell participate in antitumor immune function, therefore can think that the small water molecule cluster activated water of low saline salinity has certain antitumor action.
Embodiment 2: utilize the small water molecule cluster activated water of resistivity greater than the pure water preparation low saline salinity of 0.5M Ω cm, contain Ca in the water of being prepared 2+: 0.1mg/L; Na +: 0.3mg/L; Li +: 6 μ g/L; Sr 2+: 9 μ g/L; Zn 2+: 20 μ g/L; Metasilicic acid: 70 μ g/L; Mg 2+: 0.25mg/L; Fe 2+: 50 μ g/L; K +: 150 μ g/L, cationic total content is 0.955mg/L in the water.Utilize 17The O nucleus magnetic resonance is measured, its 17The O-NMR peak width at half height is 57Hz.
Embodiment 3: utilize the small water molecule cluster activated water of resistivity greater than the pure water preparation low saline salinity of 0.5M Ω cm, contain Ca in the water of being prepared 2+: 0.2mg/L; Na +: 0.2mg/L; Li +: 4 μ g/L; Sr 2+: 8 μ g/L; Zn 2+: 19 μ g/L; Metasilicic acid: 60 μ g/L; Mg 2+: 0.2mg/L; Fe 2+: 45 μ g/L; K +: 120 μ g/L, cationic total content is 0.856mg/L in the water.Utilize 17The O nucleus magnetic resonance is measured, its 17The O-NMR peak width at half height is 60Hz.

Claims (1)

1. the small water molecule cluster activated water of a low saline salinity, it is characterized in that: this activated water is formulated greater than the pure water of 0.5M Ω cm by resistivity, wherein contains:
Ca 2+:0.1~0.2mg/L
Na +:0.2~0.3mg/L
Li +:4~6μg/L
Sr 2+:8~9μg/L
Zn 2+:18~20μg/L
Mg 2+:0.2~0.25mg/L
Fe 2+:40~50μg/L
K +:100~150μg/L
Metasilicic acid: 60~80 μ g/L.
Cationic total content is greater than 0.6mg/L in the described small water molecule cluster activated water, smaller or equal to 1.0mg/L, and activated water 17The O-NMR peak width at half height is between 51~60Hz.
CNB2007101003172A 2007-06-08 2007-06-08 Activated water with low salt content and small water molecule cluster Expired - Fee Related CN100482598C (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102452720A (en) * 2010-10-19 2012-05-16 梁春峰 Method for producing activated water by utilizing frequency resonance and implosion and high-frequency energy solution
CN103708576A (en) * 2012-10-08 2014-04-09 苏永安 Method for adjusting water molecule cluster through quantum resonance
CN104966539A (en) * 2015-05-26 2015-10-07 清华大学 Activator for radioactive waste water depth treatment and use of activator
CN105836869A (en) * 2016-05-07 2016-08-10 上海翠利电器科技有限公司 Internal photodisintegration hydrogen-rich mineral activated water
CN105836957A (en) * 2016-05-07 2016-08-10 上海翠利电器科技有限公司 Internal photodisintegration hydrogen-rich mineral activated water generator and application

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102452720A (en) * 2010-10-19 2012-05-16 梁春峰 Method for producing activated water by utilizing frequency resonance and implosion and high-frequency energy solution
CN102452720B (en) * 2010-10-19 2014-12-03 梁海洋 Method for producing activated water by utilizing frequency resonance and implosion and high-frequency energy solution
CN103708576A (en) * 2012-10-08 2014-04-09 苏永安 Method for adjusting water molecule cluster through quantum resonance
CN104966539A (en) * 2015-05-26 2015-10-07 清华大学 Activator for radioactive waste water depth treatment and use of activator
CN105836869A (en) * 2016-05-07 2016-08-10 上海翠利电器科技有限公司 Internal photodisintegration hydrogen-rich mineral activated water
CN105836957A (en) * 2016-05-07 2016-08-10 上海翠利电器科技有限公司 Internal photodisintegration hydrogen-rich mineral activated water generator and application
CN105836869B (en) * 2016-05-07 2019-06-18 上海翠利电器科技有限公司 Interior light fission hydrogen-rich mineral activation water

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