CN101064977A - Process for manufacturing organic electroluminescence display apparatus - Google Patents

Process for manufacturing organic electroluminescence display apparatus Download PDF

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Publication number
CN101064977A
CN101064977A CN 200610060517 CN200610060517A CN101064977A CN 101064977 A CN101064977 A CN 101064977A CN 200610060517 CN200610060517 CN 200610060517 CN 200610060517 A CN200610060517 A CN 200610060517A CN 101064977 A CN101064977 A CN 101064977A
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CN
China
Prior art keywords
substrate
organic electroluminescence
hygroscopic agent
electroluminescence display
display apparatus
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CN 200610060517
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Chinese (zh)
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CN100464443C (en
Inventor
黄荣龙
赖建廷
彭家鹏
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Innolux Shenzhen Co Ltd
Innolux Corp
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Innolux Shenzhen Co Ltd
Innolux Display Corp
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Priority to CNB2006100605175A priority Critical patent/CN100464443C/en
Publication of CN101064977A publication Critical patent/CN101064977A/en
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Publication of CN100464443C publication Critical patent/CN100464443C/en
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Abstract

The invention relates to an organic electroluminescence lighting display device preparing method that comprises following steps: providing a first base; the hygroscopic agent is adhibited to the base; using a plasma machine to process the hygroscopic agent on the first base; providing a second base with organic electroluminescence lighting unit and adhibited to the first base and pressurized.

Description

Process for manufacturing organic electroluminescence display apparatus
[technical field]
The present invention relates to a kind of organic electroluminescence display device and method of manufacturing same (Organic LightEmitting Display, OLED) manufacture method.
[background technology]
Along with the develop rapidly of science and technology, people are also more and more higher to the requirement of display unit, make display unit develop to lighter, thinner, more power saving direction, thereby produced organic electroluminescence display device and method of manufacturing same.Because of organic electroluminescence display device and method of manufacturing same is that self-luminous shows, compared to liquid crystal indicator, need not the bigger module backlight of energy consumption, so therefore its lighter, thinner, more power saving has obtained extensive use.
See also Fig. 1, structural representation for a kind of organic electroluminescence display device and method of manufacturing same in the prior art, this organic electroluminescence display device and method of manufacturing same 100 comprises first substrate 110 and second substrate 120 that is oppositely arranged, be arranged on relative two surfaces sealant 130 all around of these two substrates 110,120, paste hygroscopic agent 140 and the organic electroluminescence cell 150 that is arranged in this second substrate 120 in this first substrate 110.These two substrates 110,120 and sealant 130 form a confined space, and this hygroscopic agent 140 and organic electroluminescence cell 150 are arranged in this confined space.This hygroscopic agent 140 and organic electroluminescence cell 150 are separately positioned on relative two surfaces of these two substrates 110,120, and this hygroscopic agent 140 also is oppositely arranged with this organic electroluminescence cell 150.
This hygroscopic agent 140 is generally alkaline earth metal oxide (MO), as calcium oxide (CaO), magnesium oxide (MgO) etc., is arranged in the substrate with powdery or film mode, is used to absorb the water vapour in the confined space, keeps the confined space inner drying, and its reaction equation is:
MO+H 2O→M(OH) 2
Since alkaline earth metal oxide activity a little less than, wettability power is relatively poor, so the alkaline earth metal oxide is gradually by the stronger alkaline earth metal hydride (MH of wettability power 2) replace.
See also Fig. 2, be the manufacturing flow chart of organic electroluminescence display device and method of manufacturing same shown in Figure 1.At first, provide one first substrate 110 and it is carried out ultraviolet light clean.
Then, in nitrogen environment hygroscopic agent 140 is pasted in this first substrate 110, this hygroscopic agent 140 contains alkaline earth metal hydride (MH 2), as calcium hydride (CaH 2), magnesium hydride (MgH 2) etc.
At last, provide second substrate 120 with organic electro luminescent unit 150, in vacuum environment, first substrate 110 and second substrate 120 are fitted and sealing, make organic electroluminescence display device and method of manufacturing same 100.
Yet the hygroscopic agent 140 that this process for manufacturing organic electroluminescence display apparatus adopts contains alkaline earth metal hydride, and this hygroscopic agent 140 be finished product, generally needs through just pasting after packing, transportation and the storage.In addition, this alkaline earth metal hydride activity is higher, and its time in packing, transportation and storage process is longer, and chemical reaction very easily takes place, and makes these hygroscopic agent 140 wettability powers lose, and then makes these organic electroluminescence display device and method of manufacturing same 100 yields descend.
[summary of the invention]
In order to solve the lower problem of organic electroluminescence display device and method of manufacturing same fine ratio of product in the prior art, be necessary the process for manufacturing organic electroluminescence display apparatus that provides a kind of yield preferable.
A kind of process for manufacturing organic electroluminescence display apparatus, it comprises: one first substrate is provided; Hygroscopic agent is pasted in this first substrate; Utilize a plasma machine that this first suprabasil hygroscopic agent is carried out the hydrogen plasma treatment; Provide one to have second substrate of organic electro luminescent unit and fit and sealing with first substrate.
Another kind of process for manufacturing organic electroluminescence display apparatus, it comprises: utilize a plasma machine that hygroscopic agent is carried out the hydrogen plasma treatment; One first substrate is provided; This hygroscopic agent is pasted in this first substrate; Provide one to have second substrate of organic electro luminescent unit and fit and sealing with first substrate.
Another process for manufacturing organic electroluminescence display apparatus, it comprises: utilize a plasma machine that hygroscopic agent is carried out the hydrogen plasma treatment; One second substrate with organic electro luminescent unit is provided, and this hygroscopic agent is pasted around the organic electroluminescence cell of this second substrate; One first substrate is provided, and fits and sealing with this second substrate.
Above-mentioned process for manufacturing organic electroluminescence display apparatus utilizes the hydrogen plasma treatment that the alkaline earth metal oxygenate conversion in the hygroscopic agent is alkaline earth metal hydride, then, first substrate and second substrate are fitted, react to avoid alkaline earth metal hydride.Because alkaline earth metal hydride is fitted immediately after making and is sealed, and the process that need not pack, transport and store, it is less that the chemical reaction probability takes place, and then make that this process for manufacturing organic electroluminescence display apparatus yield is preferable.
[description of drawings]
Fig. 1 is the structural representation of organic electroluminescence display device and method of manufacturing same in a kind of prior art.
Fig. 2 is the manufacturing flow chart of organic electroluminescence display device and method of manufacturing same shown in Figure 1.
Fig. 3 is a kind of structural representation of organic electroluminescence cell.
Fig. 4 is the flow chart of process for manufacturing organic electroluminescence display apparatus first execution mode of the present invention.
Fig. 5 is the flow chart of process for manufacturing organic electroluminescence display apparatus second execution mode of the present invention.
Fig. 6 is the flow chart of process for manufacturing organic electroluminescence display apparatus the 3rd execution mode of the present invention.
[embodiment]
A kind of organic electroluminescence display device and method of manufacturing same as shown in Figure 3, this organic electroluminescence display device and method of manufacturing same 200 comprises two first substrate 210, second substrates 220 that are oppositely arranged, be arranged on these two substrates 210,220 sealant 230 all around, paste hygroscopic agent 240 and the organic electroluminescence cell 250 that is arranged in this second substrate 220 in this first substrate 210.These two substrates 210,220 and sealant 230 are enclosed in this hygroscopic agent 240 and organic electroluminescence cell 250 in the space of its formation.This hygroscopic agent 240 also is oppositely arranged with this organic electroluminescence cell 250.
These two substrates 210,220 are transparent material, as quartz glass or acryl series organic material.This hygroscopic agent 240 pastes in substrate 210 in the non-transparent film mode, is used to absorb the water vapour in the confined space, keeps the confined space inner drying.
See also Fig. 4, be the flow chart of process for manufacturing organic electroluminescence display apparatus first execution mode of the present invention.At first, provide one first substrate 210 and it is carried out ultraviolet light clean.
Then, in nitrogen environment hygroscopic agent 240 is pasted in this first substrate 210, this hygroscopic agent 240 contains alkaline earth metal oxide (MO), as calcium oxide (CaO), magnesium oxide (MgO) etc.
Then, utilize a plasma machine in vacuum environment, this hygroscopic agent 240 to be carried out the hydrogen plasma treatment, make the alkaline earth metal oxide (MO) in this hygroscopic agent 240 partly or entirely be converted into alkaline earth metal hydride (MH 2), reaction equation is:
MO+H *→MH *+O
MH *+H *→MH 2
At last, provide second substrate 220 with organic electro luminescent unit 250, in vacuum environment, first substrate 210 and second substrate 220 are fitted and sealing, make organic electroluminescence display device and method of manufacturing same 200.
Because above-mentioned process for manufacturing organic electroluminescence display apparatus utilizes the hydrogen plasma treatment that the alkaline earth metal oxygenate conversion in the hygroscopic agent 240 is alkaline earth metal hydride, then, immediately first substrate 210 and second substrate 220 are fitted and sealing, also make the sealing of alkaline earth metal hydride, react to avoid alkaline earth metal hydride.Because sealing immediately after alkaline earth metal hydride generates, and the process that does not have alkaline earth metal hydride packing, transportation and store, it is less that the chemical reaction probability takes place, and then make that this process for manufacturing organic electroluminescence display apparatus yield is preferable.
See also Fig. 5, be the flow chart of process for manufacturing organic electroluminescence display apparatus second execution mode of the present invention.At first, utilize a plasma machine in vacuum environment, this hygroscopic agent 240 to be carried out the hydrogen plasma treatment, make the alkaline earth metal oxide (MO) in this hygroscopic agent 240 partly or entirely be converted into alkaline earth metal hydride (MH 2).
Then, provide one first substrate 210 and it is carried out ultraviolet light clean.
Then, in nitrogen environment, hygroscopic agent 240 is pasted in first substrate 210.
At last, provide second substrate 220 with organic electro luminescent unit 250, in vacuum environment, first substrate 210 and second substrate 220 are fitted and sealing, make organic electroluminescence display device and method of manufacturing same 200.
See also Fig. 6, be the flow chart of process for manufacturing organic electroluminescence display apparatus the 3rd execution mode of the present invention.At first, utilize a plasma machine in vacuum environment, hygroscopic agent 240 to be carried out the hydrogen plasma treatment, make the alkaline earth metal oxide (MO) in this hygroscopic agent 240 partly or entirely be converted into alkaline earth metal hydride (MH 2).
Then, provide second substrate 220 with organic electro luminescent unit 250, in vacuum environment, this hygroscopic agent 240 is pasted around the organic electroluminescence cell 250 of this second substrate 220.
Then, provide one first substrate 210 and it is carried out ultraviolet light clean.
At last, first substrate 210 and second substrate 220 are fitted and sealing, make organic electroluminescence display device and method of manufacturing same 200.
Above-mentioned hygroscopic agent 240 can also carry out the hydrogen plasma treatment in the normal pressure hydrogen environment.

Claims (10)

1. process for manufacturing organic electroluminescence display apparatus, it comprises: one first substrate is provided; Hygroscopic agent is pasted in this first substrate; Provide one to have second substrate of organic electro luminescent unit and fit and sealing, it is characterized in that: before this second substrate and first substrate applying, utilize a plasma machine that this first suprabasil hygroscopic agent is carried out the hydrogen plasma treatment with first substrate.
2. process for manufacturing organic electroluminescence display apparatus as claimed in claim 1 is characterized in that: this first substrate is carried out ultraviolet light and is cleaned before pasting hygroscopic agent.
3. process for manufacturing organic electroluminescence display apparatus as claimed in claim 1 is characterized in that: this hygroscopic agent pastes in nitrogen environment in this first substrate.
4. process for manufacturing organic electroluminescence display apparatus as claimed in claim 1 is characterized in that: this hygroscopic agent carries out the hydrogen plasma treatment in vacuum environment.
5. process for manufacturing organic electroluminescence display apparatus as claimed in claim 1 is characterized in that: this hygroscopic agent carries out the hydrogen plasma treatment in the normal pressure hydrogen environment.
6. process for manufacturing organic electroluminescence display apparatus, it comprises: one first substrate is provided; This hygroscopic agent is pasted in this first substrate; Provide one to have second substrate of organic electro luminescent unit and fit and sealing, it is characterized in that: before this hygroscopic agent pastes, utilize a plasma machine that hygroscopic agent is carried out the hydrogen plasma treatment with first substrate.
7. process for manufacturing organic electroluminescence display apparatus as claimed in claim 6 is characterized in that: this first substrate is carried out ultraviolet light and is cleaned before pasting hygroscopic agent.
8. process for manufacturing organic electroluminescence display apparatus as claimed in claim 6 is characterized in that: this hygroscopic agent carries out the hydrogen plasma treatment in vacuum environment.
9. process for manufacturing organic electroluminescence display apparatus as claimed in claim 6 is characterized in that: this hygroscopic agent carries out the hydrogen plasma treatment in the normal pressure hydrogen environment.
10. process for manufacturing organic electroluminescence display apparatus, it comprises: second substrate with organic electro luminescent unit is provided, and this hygroscopic agent is pasted around the organic electroluminescence cell of this second substrate; One first substrate is provided, and fits and sealing, it is characterized in that: before this hygroscopic agent pastes, utilize a plasma machine that hygroscopic agent is carried out the hydrogen plasma treatment with this second substrate.
CNB2006100605175A 2006-04-28 2006-04-28 Process for manufacturing organic electroluminescence display apparatus Expired - Fee Related CN100464443C (en)

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CN100464443C CN100464443C (en) 2009-02-25

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106328825A (en) * 2016-10-31 2017-01-11 武汉华星光电技术有限公司 OLED (organic light emitting diode) display
WO2018107555A1 (en) * 2016-12-15 2018-06-21 武汉华星光电技术有限公司 Method for packaging oled display, and oled display

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000003783A (en) * 1998-06-12 2000-01-07 Tdk Corp Organic electroluminescent display device
JP3411864B2 (en) * 1999-06-11 2003-06-03 ティーディーケイ株式会社 Organic EL display
CN1198483C (en) * 2002-02-27 2005-04-20 光磊科技股份有限公司 Luminous element with hygroscopic film and process for prparing hygroscopic film
US20060001041A1 (en) * 2004-07-01 2006-01-05 Lightronik Technology Inc. Organic light emitting device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106328825A (en) * 2016-10-31 2017-01-11 武汉华星光电技术有限公司 OLED (organic light emitting diode) display
CN106328825B (en) * 2016-10-31 2019-01-15 武汉华星光电技术有限公司 OLED display
WO2018107555A1 (en) * 2016-12-15 2018-06-21 武汉华星光电技术有限公司 Method for packaging oled display, and oled display
US10355245B2 (en) 2016-12-15 2019-07-16 Wuhan China Star Optoelectronics Technology Co., Ltd OLED display with desiccant layer and packaging method for the same
KR20190091550A (en) * 2016-12-15 2019-08-06 우한 차이나 스타 옵토일렉트로닉스 테크놀로지 컴퍼니 리미티드 Packaging method of OLED display and OLED display
KR102253214B1 (en) 2016-12-15 2021-05-17 우한 차이나 스타 옵토일렉트로닉스 테크놀로지 컴퍼니 리미티드 OLED display packaging method and OLED display

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Granted publication date: 20090225

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