CN101041754A - Aqueous painting material - Google Patents
Aqueous painting material Download PDFInfo
- Publication number
- CN101041754A CN101041754A CN 200710088939 CN200710088939A CN101041754A CN 101041754 A CN101041754 A CN 101041754A CN 200710088939 CN200710088939 CN 200710088939 CN 200710088939 A CN200710088939 A CN 200710088939A CN 101041754 A CN101041754 A CN 101041754A
- Authority
- CN
- China
- Prior art keywords
- water
- weight
- based emulsion
- aqueous
- polymkeric substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 77
- 238000010422 painting Methods 0.000 title claims description 48
- 239000000839 emulsion Substances 0.000 claims abstract description 102
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 95
- 239000000126 substance Substances 0.000 claims description 50
- 230000007704 transition Effects 0.000 claims description 25
- 239000002131 composite material Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 abstract description 17
- 239000011248 coating agent Substances 0.000 abstract description 16
- 238000000576 coating method Methods 0.000 abstract description 16
- 239000000203 mixture Substances 0.000 abstract description 12
- 239000004816 latex Substances 0.000 abstract description 9
- 229920000126 latex Polymers 0.000 abstract description 9
- 239000011521 glass Substances 0.000 abstract description 4
- 238000001035 drying Methods 0.000 description 33
- -1 2-EHA Chemical compound 0.000 description 31
- 239000000049 pigment Substances 0.000 description 19
- 239000011347 resin Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 10
- 239000012528 membrane Substances 0.000 description 10
- 239000004034 viscosity adjusting agent Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000000178 monomer Substances 0.000 description 7
- 239000000975 dye Substances 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- YARNEMCKJLFQHG-UHFFFAOYSA-N prop-1-ene;styrene Chemical compound CC=C.C=CC1=CC=CC=C1 YARNEMCKJLFQHG-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 235000019439 ethyl acetate Nutrition 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- LFWGYTIGZICTTE-BTJKTKAUSA-N (z)-but-2-enedioic acid;styrene Chemical compound C=CC1=CC=CC=C1.OC(=O)\C=C/C(O)=O LFWGYTIGZICTTE-BTJKTKAUSA-N 0.000 description 1
- WGYZMNBUZFHYRX-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-ol Chemical compound COCC(C)OCC(C)O WGYZMNBUZFHYRX-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- LARNQUAWIRVQPK-UHFFFAOYSA-N 2-methyloxiran-2-amine Chemical compound NC1(CO1)C LARNQUAWIRVQPK-UHFFFAOYSA-N 0.000 description 1
- SHUGUNYYEAYLKM-UHFFFAOYSA-N 3-(methoxymethyl)heptane Chemical compound CCCCC(CC)COC SHUGUNYYEAYLKM-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- PMZBHPUNQNKBOA-UHFFFAOYSA-N 5-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=CC(C(O)=O)=CC(C(O)=O)=C1 PMZBHPUNQNKBOA-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920002310 Welan gum Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-PQMKYFCFSA-N alpha-D-mannose Chemical compound OC[C@H]1O[C@H](O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-PQMKYFCFSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- NKKMVIVFRUYPLQ-UHFFFAOYSA-N but-2-enenitrile Chemical compound CC=CC#N NKKMVIVFRUYPLQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- UZBQIPPOMKBLAS-UHFFFAOYSA-N diethylazanide Chemical compound CC[N-]CC UZBQIPPOMKBLAS-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical class S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Abstract
The invention provides an aqueous plotting material, which contains aqueous emulsion ink composition of aqueous latex A of the first polymers with occupancy rate of above 50 weight% at the glass temperature range of -10 degree~10 degree and aqueous latex B of the second polymers at the glass temperature range of 25 degree~60 degree, wherein the content of the aqueous latex A accounts for above 50 weight % of the gross amount of aqueous latex A and aqueous latex B. The aqueous plotting material contains the aqueous emulsion ink composition of the first polymers and the second polymers accounting for above 45 weight % of the gross amount. Especially preferably, the occupancy rate of the first polymers is above 55 weight % in the aqueous latex A, and the occupancy rate of the second polymers is above 45 weight % in the aqueous latex B. Using the said aqueous plotting material, the character and figure described on a great variety of basis material to used as thick coating film with, and the coating film is dried rapidly, the dried coating film is basically without bindability.
Description
Technical field
The present invention relates to aqueous painting material, in detail, the present invention relates to form on various base materials the aqueous painting material that literal and figure are filmed as the solid with thickness, this material comprises the water-based emulsion of the 1st polymkeric substance with low Tg and has the water-based emulsion of the 2nd polymkeric substance of high glass transition temperature.
Background technology
Make polymkeric substance in aqueous medium the dispersive water-based emulsion since be with water as medium, not with an organic solvent, therefore not only help saving resource, and cause the dangerous little of fire, poisoning, topsoil, therefore as record in Japanese kokai publication hei 09-111154 communique, Japanese kokai publication hei 10-176122 communique, the TOHKEMY 2004-339472 communique etc., be widely used as coating and insulating covering agent especially.
For example, in Japanese kokai publication hei 09-111154 communique, put down in writing with second-order transition temperature be the water-based emulsion of the polymkeric substance more than 60 ℃ and second-order transition temperature less than the water-based emulsion of 20 ℃ polymkeric substance mix make, the second-order transition temperature of polymkeric substance in this mixture is 25～55 ℃, improved the fusible water-based covering composition on metal or plastics.
But, contain the composition of this water-based emulsion, as mentioned above since with water as medium, so the rate of drying of filming of its formation is slow.Thereby as a countermeasure of the rate of drying of the composition of accelerating to contain this water-based emulsion, the known method that the amount that reduces the water that composition had is arranged for example improves the method for the polymer concentration of used water-based emulsion.In addition, the binding property of dried coating that contains the composition of water-based emulsion depends on the second-order transition temperature of the polymkeric substance that forms emulsion usually.That is to say, when the second-order transition temperature of above-mentioned polymkeric substance is higher than when using this water-based emulsion to form the atmosphere temperature of filming, this is filmed and be difficult to have binding property after drying, and be lower than when using this water-based emulsion to form the atmosphere temperature of filming when the second-order transition temperature of above-mentioned polymkeric substance, even if this coating also is easy to have binding property after drying.
But as a rule, in commercially available numerous water-based emulsions, second-order transition temperature is higher than normal temperature, and polymer concentration is low.This be because, for the emulsion of for example coating purposes, the water-based emulsion that second-order transition temperature is higher than normal temperature mainly is to use in requiring the external decorative material of hardness of film, in addition, owing to also require water tolerance, therefore when making emulsion, reduce the amount of polymkeric substance at water emulsive emulsifying agent that be used for, this emulsifying agent is the reason that reduces this water-resistance property of coating.And, can not increase can be in water the amount of dispersive polymkeric substance because the ratio of water relatively increases, therefore formed rate of drying of filming is slack-off.
On the other hand, be lower than in the water-based emulsion of normal temperature in second-order transition temperature, also there is polymer concentration high, the soft film coating that this water-based emulsion forms, have binding property, seldom be used in the water-proof purposes of above-mentioned requirements, therefore when making emulsion, can use the necessary emulsifying agent of polymkeric substance emulsification in water in large quantities, therefore can increase can be in water the amount of dispersive polymkeric substance, and the ratio of water relatively reduces in the emulsion, rate of drying is accelerated.
Water-based emulsion can be used as painting material, on various base materials, describe literal and figure and film, but thisly film promptly that drying is the extremely important characteristic that requires as the solid with thickness.Therefore, as mentioned above, in order to accelerate the rate of drying of water-based emulsion, if use the emulsion that second-order transition temperature is low, polymer concentration is high, even if it is promptly dry then to film, also having residually on filming has a fusible problem.Therefore, this filming not only is easy to adsorb dust, is easy to contaminatedly, and paper or film be contacted with when filming, and also has this problem bonding etc. with these paper or film of filming.Therefore, binding property do not arranged, use the water-based emulsion of the high polymkeric substance of second-order transition temperature, but therefore this emulsion has long problem time of drying because the concentration of polymkeric substance is low usually for residual on dried coating.
The present invention finishes in order to solve the problems referred to above that exist in containing the aqueous painting material of water-based emulsion, its purpose is to provide a kind of aqueous painting material, this material can describe literal on various base materials and figure is filmed as the solid with thickness, and, film the exsiccant while promptly this, this is filmed does not almost have binding property.
Summary of the invention
The invention provides a kind of aqueous painting material, this material is to contain the water-based emulsion A of the 1st polymkeric substance that second-order transition temperature is-10 ℃～10 ℃ of scopes and the aqueous emulsion ink composite more than second-order transition temperature accounts for water-based emulsion A and water-based emulsion B total amount more than or equal to 25 ℃ of water-based emulsion B less than 60 ℃ the 2nd polymkeric substance, water-based emulsion A the 50 weight % a kind of comprising with the containing ratio more than the 50 weight %, and this aqueous painting material contains and contains the aqueous emulsion ink composite that total amount accounts for the above-mentioned the 1st and the 2nd above polymkeric substance of 45 weight %.
According to the present invention, in this painting material, water-based emulsion A preferably contains the 1st polymkeric substance with the containing ratio more than the 55 weight %, and water-based emulsion B preferably contains the 2nd polymkeric substance with the containing ratio more than the 45 weight %.
And then painting material of the present invention more preferably contains water-based emulsion A and water-based emulsion B with water-based emulsion A/ water-based emulsion B weight ratio 5/5～7/3, further preferably to contain the 1st and the 2nd polymkeric substance more than the total amount 50 weight %.
Embodiment
Aqueous painting material of the present invention is to contain the water-based emulsion A of the 1st polymkeric substance that second-order transition temperature is-10 ℃～10 ℃ of scopes and the aqueous emulsion ink composite more than second-order transition temperature accounts for water-based emulsion A and water-based emulsion B total amount more than or equal to 25 ℃ of water-based emulsion B less than 60 ℃ the 2nd polymkeric substance, water-based emulsion A the 50 weight % a kind of comprising with the containing ratio more than the 50 weight %, and this aqueous painting material contains and contains the aqueous emulsion ink composite that total amount accounts for the above-mentioned the 1st and the 2nd above polymkeric substance of 45 weight %.
Among the present invention, water-based emulsion A plays the effect of giving the high drying property of gained painting material, contains the 1st polymkeric substance that second-order transition temperature is-10 ℃～10 ℃ of scopes with the concentration more than the 50 weight %.The content of the 1st polymkeric substance among the water-based emulsion A has the relatively poor danger of rate of drying of gained painting material during less than 50 weight %.The content of the 1st polymkeric substance among the water-based emulsion A is preferably more than the 55 weight %, most preferably is more than the 60 weight %.
In addition, when the second-order transition temperature of the 1st polymkeric substance among the water-based emulsion A during, there be filming that the gained painting material forms after drying, to still have fusible danger less than-10 ℃.When the second-order transition temperature of the 1st polymkeric substance among the water-based emulsion A during greater than 10 ℃, as mentioned above, because the polymer concentration of emulsion is low usually, the therefore relatively poor danger of the drying property of filming that has the gained painting material to form.
On the other hand, water-based emulsion B be second-order transition temperature more than or equal to 25 ℃ of water-based emulsions less than 60 ℃ the 2nd polymkeric substance, preferably contain the 2nd polymkeric substance with the containing ratio more than the 45 weight %.When the second-order transition temperature of the 2nd polymkeric substance is lower than 25 ℃, there be filming that the gained painting material forms after drying, to still have fusible danger, when second-order transition temperature is more than 60 ℃ the time, the relatively poor danger of the drying property of filming that has the gained painting material to form.According to the present invention, the 2nd polymkeric substance in the preferred especially water-based emulsion has more than or equal to 35 ℃ of second-order transition temperatures less than 60 ℃.
Painting material of the present invention in the drying property excellence, make dried coating not have binding property, total amount with water-based emulsion A and B is that benchmark contains the water-based emulsion A more than the 50 weight %, is that benchmark contains the 1st and the 2nd polymkeric substance that amounts to more than the 45 weight %, more than the preferred 50 weight % with the aqueous emulsion ink composite simultaneously.According to the present invention, in order when filming of gained painting material has high drying property, after making drying, not have binding property, especially preferably making water-based emulsion A/ water-based emulsion B weight ratio is 5/5～7/3, contains the 1st and the 2nd polymkeric substance that 45 weight % are above, preferred 50 weight % are above simultaneously altogether.Among the present invention, the weight ratio of most preferred water-based emulsion A/ water-based emulsion B is 5/5～6/4 scope.
The 1st above-mentioned polymkeric substance and the water-based emulsion of the 2nd polymkeric substance all can obtain by vinyl monomer emulsion (being total to) polymerization that makes intramolecularly more than a kind or 2 kinds have at least one free-radical polymerised group in water.
As the important example of this vinyl monomer, can enumerate methyl methacrylate, ethyl propenoate, 2-EHA, methacrylic acid etc., can also unite with above-mentioned monomer and use following vinyl monomer that can copolymerization.
Promptly, can enumerate methyl acrylate as vinyl monomer that can copolymerization, Jia Jibingxisuanyizhi, (methyl) n-butyl acrylate, (methyl) sec-butyl acrylate, (methyl) tert-butyl acrylate, (methyl) cyclohexyl acrylate, methacrylic acid 2-ethylhexyl, (methyl) lauryl acrylate, (methyl) stearyl acrylate ester etc. has (methyl) alkyl acrylate of the alkyl of carbonatoms 1～18, vinylbenzene, alpha-methyl styrene, aromatic ethenyl compounds such as p-methylstyrene, (methyl) vinylformic acid 2-hydroxy methacrylate, (methyl) vinylformic acid hydroxyalkyl acrylates such as (methyl) vinylformic acid 2-hydroxy propyl ester, two (methyl) vinylformic acid glycol ester, two (methyl) vinylformic acid diol esters such as two (methyl) vinylformic acid butanediol ester, (methyl) acrylic acid alkyl amino ester such as (methyl) vinylformic acid dimethylamino ethyl ester, (methyl) allyl acrylate, trimethylolpropane tris (methyl) acrylate, (methyl) glycidyl acrylate, vinyl acetate, propionate, (methyl) vinyl cyanide, (methyl) benzyl acrylate, vinylformic acid, 1,2-cyclohexane dicarboxylic acid list hydroxyethyl (methyl) acrylate, 1,2-cyclohexane dicarboxylic acid list hydroxypropyl (methyl) acrylate, single hydroxypropyl (methyl) acrylate of tetrahydrophthalic acid, the 5-methyl isophthalic acid, 2-cyclohexane dicarboxylic acid list hydroxyethyl (methyl) acrylate, phthalic acid list hydroxyethyl (methyl) acrylate, phthalic acid list hydroxypropyl (methyl) acrylate, the vinyl monomer that contains carboxyl of oxalic acid list hydroxyethyl (methyl) acrylate etc. etc.
As everyone knows, utilize the letex polymerization of above-mentioned vinyl monomer to make water-based emulsion.This water-based emulsion can be used as commercially available product and easily obtains.
Painting material of the present invention contains the emulsion of the high polymkeric substance of second-order transition temperature, and common this emulsion is because the minimum film temperature height of making therefore in order to reduce the minimum film temperature of making of gained painting material, preferably contains membrane producing promoter.This membrane producing promoter is high boiling organic solvent, when emulsion drying (making film), helps polymer particle reciprocally molten sticking, can reduce and make the necessary temperature of film.
As membrane producing promoter, usually can enumerate ethylene glycol monobutyl ether, glycol monomethyl 2-ethylhexyl ether, list or Diethylene Glycol monoalky lethers such as Diethylene Glycol single-butyl ether, above-mentioned list or Diethylene Glycol monoalky lether acetic esters such as Diethylene Glycol single-butyl ether acetic ester, propylene glycol list n-butyl ether, dipropylene glycol list n-butyl ether, tripropylene glycol list n-butyl ether, DPGME, tripropylene glycol monomethyl ether etc. are single, two or the tripropylene glycol monoalky lether, dibutyl phthalate, bialkyl ortho phthalates such as dioctyl phthalate (DOP), 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate etc.This membrane producing promoter uses with the scope of 0.5～5 weight % usually with respect to the aqueous emulsion ink composite.
Painting material of the present invention preferably contains alkaline matter in order to make excellent in stability, and its pH is 6.5～10.0 scope.As this alkaline matter, can enumerate ammonia, Trimethylamine, propylamine, diethylamide, tripropylamine, dibutylamine, amylamine, 1-amino-octane, 2-dimethylaminoethanol, 1-amino-2-propyl alcohol, 2-amino-1-propyl alcohol, 3-amino-1-propyl alcohol, 1-dimethylamino-2-propyl alcohol, 3-dimethylamino-1-propyl alcohol, 2-propyl group monoethanolamine, epoxy propylamine, amino-benzene methyl alcohol, morpholine, sodium hydroxide, potassium hydroxide etc.This alkaline matter common scope with 0.1～5 weight % in painting material is used.
In the painting material of the present invention, can also suitably contain additives such as tinting materials such as dyestuff, pigment, pigment dispersing agent, organic solvent, viscosity modifier, defoamer, sanitas, mould inhibitor as required.
Tinting material then is not particularly limited so long as can make the mixture of above-mentioned water-based emulsion catch needed color, can suitably use known in the past pigment or dyestuff.As pigment, can enumerate the pigment dyestuff of azo class pigment, condensation polyazo class pigment, phthalocyanine pigment, quinacridine ketone pigment, anthraquinone class pigment, two piperazine class pigment, indigo class pigment, thioindigo class pigment, perynone (ペ リ ノ Application), perylene class pigment, melamine class pigment etc., mineral dyes such as titanium oxide, ferric oxide, carbon black, metal powder pigments such as aluminium pigment, resin emulsion colouring agent etc.
The resin emulsion colouring agent, as known in the past, be the tinting material that the water dispersion of the polymeric microsphere of letex polymerization median size 0.1～1 μ m that resins such as styrene resin, acrylic resin, acrylonitrile resin, urethane resin obtain more than a kind or 2 kinds is obtained after painted by with basic dyestuff, fluorescence basic dye, white dyes etc.In addition, also being can be used as tinting material by the phosphorus sheet light particle of the sheet glass of metal or metal oxide covering, inorganic particulate, resin film sheet etc. uses.Above-mentioned various tinting material can use separately, also can make up more than 2 kinds and use.
This tinting material common scope with 0.01～20 weight % in painting material contains, and preferably the scope with 0.1～10 weight % contains.The content of tinting material is very few, and then the formed depth of shade of filming of gained painting material is low excessively, and if the too high levels of tinting material, then the viscosity of gained painting material is too high, mobile variation.
Pigment dispersing agent uses in the past generally the water soluble resin that uses as this material or tensio-active agent etc.Water soluble resin can be any one in natural product, semi-synthetic, the synthetics.As synthetics, can enumerate water soluble acrylic resin, water-soluble maleic acid resin, water-soluble phenylethene resin, water-soluble phenylethene-acrylic resin, water-soluble phenylethene-maleic acid resin, polyvinylpyrrolidone, polyvinyl alcohol, water soluble polyurethane resin etc.Tensio-active agent can be any in anionic property, cationic, nonionic, the amphoterics.This pigment dispersing agent as required with the scope use of 0.01～10 weight %, preferably uses with the scope of 0.1～5 weight % in painting material.
Painting material of the present invention can also contain viscosity modifier.Use this viscosity modifier can make the higher painting material of viscosity.As viscosity modifier, except alkali salt, amine salt or the alkanolamine salt etc. of crosslinked acrylic acid polymer, can also use the plain family macromolecule of natural polysaecharides or semi-synthetic fibre.
As natural polysaecharides, can use guar gum with the macromolecular compound structure that constitutes by monoses such as glucose, semi-lactosi, rhamnosyl, seminose, glucuronic acids, Viscogum BE, Welan gum, rhamsan gum, xanthan gum, レ オ ザ Application ガ system (three crystalline substances (strain)) etc.As the plain family macromolecule of semi-synthetic fibre, can use methylcellulose gum, ethyl cellulose, carboxymethyl cellulose etc. with cellulosic hydroxy esterification or etherificate, water-solubleization.
This viscosity modifier uses with the scope of 0.01～10 weight % in painting material as required, preferably uses in the scope with 0.1～5 weight %.
Embodiment
Below enumerate embodiment and comparative example explanation the present invention, but the present invention is not subjected to any qualification of these embodiment.In embodiment and comparative example, " % " expression weight %.In addition, the water-based emulsion that uses in following examples and comparative example, tinting material and viscosity modifier are as described below.
(water-based emulsion A)
Port リ ト ロ Application A65 (styrene-propene acid-acrylate copolymer, the Tg that Asahi Chemical Industry's (strain) produces is that 7 ℃, the minimum film temperature (MFT) of making are 20 ℃, solids component 65 weight %)
Port リ ト ロ Application A55 (styrene-propene acid-acrylate copolymer, the Tg that Asahi Chemical Industry's (strain) produces is that 0 ℃, MFT are 12 ℃, solids component 45.5 weight %)
プ ラ イ マ Le RHA691 (styrene-propene acid-acrylate copolymer that ロ one system ア Application De Ha one ス produces, Tg are 0 ℃, solids component 62.5 weight % for-7 ℃, MFT)
(emulsion B)
プ ラ イ マ Le AC3001 (acrylic acid and acrylic ester copolymers, the Tg that ロ one system ア Application De Ha one ス produces is that 32 ℃, MFT are 27 ℃, solids component 48 weight %)
ダ one ト ジ one Le De K1 (acrylic acid and acrylic ester copolymers, the Tg that ロ one system ア Application De Ha one ス produces is that 53 ℃, MFT are 45 ℃, solids component 50 weight %)
Tinting material
NKW6238 (the blue-fluorescence tinting material that Japanese fluorescence (strain) is produced)
(viscosity modifier)
カ one ボ ボ one Le 940 (cross linked polyacrylate that BF グ Star De リ Star チ produces)
The aqueous emulsion ink composite is by putting into the raw material of table 1 record in the container, utilizes dissolving machine to stir 30 minutes and makes.In embodiment and comparative example, the following evaluation of rerum natura of gained aqueous emulsion ink composite.
(1) drying temperature
Under normal temperature (20 ℃ of temperature, relative humidity 65%, following same), use painting material on plotting paper, to describe straight line to wide 1.5mm, long 200mm, coating thickness 1.0mm, when scraping this straight line with glass stick (10g) in per 5 minutes, time that will be when retouching straight line does not extend or peels off is as time of drying.According to this time of drying, drying property that can following evaluation painting material.Time of drying is during less than 20 minutes, and is very excellent; Time of drying is more than or equal to 20 minutes during less than 30 minutes, excellence; Be more than or equal to 30 minutes during less than 40 minutes time of drying, poor slightly; When surpassing 40 minutes time of drying, non-constant.
(2) binding property
At normal temperatures, use painting material on the 1st plotting paper, to describe straight line to wide 1.5mm, long 30mm, coating thickness 1.0mm, after dry 1 day, described overlapping the 2nd plotting paper on the collinear paper at this, further put sheet glass thereon, be placed on the base station of level, apply the loading of 1kg from above-mentioned sheet glass.After placing for 1 week under this state, observe the situation when the 1st plotting paper peeled off the 2nd plotting paper, the following evaluation.That is,, be evaluated as " well " though on the 1st paper, can easily peel off or the 2nd paper can easily peel off on attached to the 1st paper the time when the 2nd paper is non-cohesive; When the 2nd paper attached to be depicted in the 1st on the paper straight line, the 2nd paper breaks and sticks to securely on the above-mentioned straight line when peeling off the 2nd paper, perhaps break near near the paper the above-mentioned straight line on the 2nd paper and when adhering to securely, be evaluated as " poor ".
Embodiment 1 and 2
With water-based emulsion A and the B shown in the table 1, use tinting material, membrane producing promoter and water, modulate painting material as mentioned above, the binding property of containing ratio, rate of drying and the dry coating of polymkeric substance in the painting material is shown in the table 1.
Comparative example 1～3
With the A of water-based emulsion shown in the table 1 and B or one of them, use tinting material and membrane producing promoter and water, modulate painting material as mentioned above, the binding property of containing ratio, rate of drying and the dry coating of polymkeric substance in these painting materials is shown in the table 1.
Table 1
| Embodiment | Comparative example | ||||
| 1 | 2 | 1 | 2 | 3 | |
| Ink composite composition (% by weight) latex A Port リ ト ロ Application A65 Port リ ト ロ Application A55 emulsion B プ ラ イ マ Le AC3001 ダ one ト シ one Le K1 colouring agent membrane producing promoter water | 45 45 4 1 5 | 45 45 4 1 5 | 90 4 6 | 45 45 4 5 | 90 4 4 |
| Ink composite performance polymer containing ratio (weight %) rate of drying (minute) binding property of filming | 51 20 is good | 52 20 is good | 59 15 is poor | 42 40 is good | 43 30 is poor |
Embodiment 3～5
With water-based emulsion A and the B shown in the table 2, use tinting material, membrane producing promoter, viscosity modifier, ammoniacal liquor and water, modulate painting material as mentioned above, the binding property of containing ratio, rate of drying and the dry coating of polymkeric substance in these painting materials is shown in the table 2.
Comparative example 4～6
With the A of water-based emulsion shown in the table 2 and B or one of them, use tinting material, membrane producing promoter, viscosity modifier, ammoniacal liquor and water, modulate the aqueous emulsion ink composite as mentioned above, the binding property of containing ratio, rate of drying and the dry coating of polymkeric substance in these painting materials is shown in the table 2.
Table 2
| Embodiment | Comparative example | |||||
| 3 | 4 | 5 | 4 | 5 | 6 | |
| Ink composite composition (% by weight) latex A Port リ ト ロ Application A65 Port リ ト ロ Application A55 プ ラ イ マ Le RHA691 emulsion B プ ラ イ マ Le AC3001 ダ one ト シ one Le K1 colouring agent membrane producing promoter viscosity modifier alkaline matter water | 44 44 4 1 0.3 0.1 6.6 | 44 44 4 1 0.3 0.1 6.6 | 46 46 4 1 0.3 0.1 2.6 | 88 4 0.3 0.1 7.6 | 44 44 4 1 0.3 0.1 6.6 | 88 4 2 0.3 0.1 5.6 |
| Ink composite performance polymer containing ratio (weight %) rate of drying (minute) binding property of filming | 50 20 is good | 51 20 is good | 51 20 is good | 57 15 is poor | 41 45 is good | 42 35 is poor |
Industrial applicability
Aqueous painting material of the present invention comprises the water-based emulsion A that contains the 1st polymer with different glass temperature and the water-based emulsion B that contains the 2nd polymer with the regulation ratio as mentioned above, contain altogether simultaneously the above-mentioned the 1st and the 2nd above polymer of 50 % by weight, can be at various base materials, paper for example, cloth and silk, timber, pottery, plastics, describe literal and figure on the metal etc. as having filming of thickness, and, because this films promptly dry, substantially not residual cohesive on dried filming, therefore being toilet tissue or film contacts with filming, and also is difficult to each other bonding.
Claims (3)
1. aqueous painting material, this material is to contain the water-based emulsion A of the 1st polymkeric substance that second-order transition temperature is-10 ℃～10 ℃ of scopes and the aqueous emulsion ink composite more than second-order transition temperature accounts for water-based emulsion A and water-based emulsion B total amount more than or equal to 25 ℃ of water-based emulsion B less than 60 ℃ the 2nd polymkeric substance, water-based emulsion A the 50 weight % a kind of comprising with the containing ratio more than the 50 weight %, and this aqueous painting material contains and contains the aqueous emulsion ink composite that total amount accounts for the described the 1st and the 2nd above polymkeric substance of 45 weight %.
2. the aqueous painting material of claim 1, wherein, water-based emulsion A preferably contains the 1st polymkeric substance with the containing ratio more than the 55 weight %, and water-based emulsion B preferably contains the 2nd polymkeric substance with the containing ratio more than the 45 weight %.
3. the aqueous painting material of claim 1 wherein, contains water-based emulsion A and water-based emulsion B with the ratio of water-based emulsion A/ water-based emulsion B weight ratio 5/5～7/3.
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| JP2006-081838 | 2006-03-24 | ||
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| CN110402275A (en) * | 2017-12-27 | 2019-11-01 | 株式会社Lg化学 | Ultraviolet solidifiable printing ink composition manufactures in display base plate the method for frame pattern and the thus frame pattern that manufactures using it |
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| AU4313489A (en) * | 1988-09-27 | 1990-04-18 | Data Card Corporation | Water-based lamination ink |
| ZA947537B (en) * | 1993-09-29 | 1995-05-26 | Ici Australia Operations | Water-borne soil resistant coatings |
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| CN110402275A (en) * | 2017-12-27 | 2019-11-01 | 株式会社Lg化学 | Ultraviolet solidifiable printing ink composition manufactures in display base plate the method for frame pattern and the thus frame pattern that manufactures using it |
| CN110402275B (en) * | 2017-12-27 | 2022-03-04 | 株式会社Lg化学 | Ultraviolet-curable ink composition, method of manufacturing bezel pattern in display substrate using the same, and bezel pattern manufactured thereby |
| US11560488B2 (en) | 2017-12-27 | 2023-01-24 | Lg Chem, Ltd. | Ultraviolet curable ink composition, method for manufacturing bezel pattern in display substrate by using same, and bezel pattern manufactured thereby |
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