CN101037311B - Concrete reinforced abrasion-aided additive and its application - Google Patents
Concrete reinforced abrasion-aided additive and its application Download PDFInfo
- Publication number
- CN101037311B CN101037311B CN200710013699A CN200710013699A CN101037311B CN 101037311 B CN101037311 B CN 101037311B CN 200710013699 A CN200710013699 A CN 200710013699A CN 200710013699 A CN200710013699 A CN 200710013699A CN 101037311 B CN101037311 B CN 101037311B
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- China
- Prior art keywords
- admixture
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- cement
- weight
- concrete reinforced
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses an enhanced grinding admixture of cement and the application. It solves the problem of environmental pollution generated by discarding the industrial waste such as ethyl cyanoacetate and methyl cyanoacetate and the problem of waste of the available components for a secondary use. It has the advantages that the formula is simple, the processing is brief, and it can make thebest of the useful components. The composition is that (wt.%): leftovers of the ethyl cyanoacetate or methyl cyanoacetate is 30-70, glauber's salt is 0-30, alunite is 0-20, lime is 0-10 and filling material is 20-60, weighing and blending uniformly.
Description
Technical field
The present invention relates to a kind of cement grinding aid, relate in particular to a kind of concrete reinforced abrasion-aided additive.
Background technology
Admixture in order to the cement enhancement is of a great variety, and inorganic and organic and inorganic and organic compound admixture are arranged.As the villaumite of some alkalies and alkaline earths, vitriol etc.; Organically as alcamines etc.In recent years, in order to strengthen its action effect, some composite admixtures had appearred again.The raw material of these admixtures mostly is salt industry and salt chemical engineering byproduct, because the source is complicated, kind is many, its difficult quality control often causes the admixture quality instability of being produced.
In ethyl cyanoacetate and methyl cyanoacetate process of producing product,, wherein contain ethanol 8% because its tankage are soluble substances, sulfuric acid 0.4%, nitrogen 0.3%, sodium 83%, cyanogen root GTM 76/1000000ths, the accumulation deposit serious environment pollution is especially to soil and contaminated water source.Mostly past is to carry out landfill, and not only pollution problem is really solved, and the composition that wherein has a utility value is wasted.
Summary of the invention
Purpose of the present invention is exactly to pollute the ring mirror in order to solve the ethyl cyanoacetate and the methyl cyanoacetate industrial waste that abandon at present, the problem that its beneficiating ingredient that can utilize once more is wasted, provide a kind of and have prescription simply, production process is easy, can make full use of the concrete reinforced abrasion-aided additive and the application thereof of the advantages such as useful component of this kind industrial waste.
For achieving the above object, the present invention adopts following technical scheme:
A kind of concrete reinforced abrasion-aided additive, its moiety is counted by weight, contain ethanol 8%, sulfuric acid 0.4%, nitrogen 0.3%, sodium 83%, 30~70 parts of the tankage of cyanogen root GTM 76/1000000ths, 0~30 part in saltcake, 0~20 part of alunite, 0~10 part in lime and flyash or other natural or 20~60 parts in artificial powder shape Mineral feedstock weighting material, their weighings, mix are evenly got final product.
Described weighting material be flyash or other natural or artificial powder shape Mineral feedstock, i.e. rubble powder, crushed slag, granulated blast-furnace slag.
A kind of application of concrete reinforced abrasion-aided additive is when mixing the system concrete, by weight: 60~100 parts of cement, 0~20 part of slag powders, 0~20 part in flyash, 0.6~1 part of admixture said ratio admixture.
A kind of application of concrete reinforced abrasion-aided additive whenever grinds 100 parts by weight of cement, admixture said ratio admixture 0.6~1 weight part.
The present invention is that concrete reinforced abrasion-aided additive and preparation production method thereof are produced in the main raw material preparation with the tankage in ethyl cyanoacetate and the methyl cyanoacetate production.Wherein, admixture mainly comprises tankage 30%~70%, saltcake 0%~30%, alunite 0%~20%, lime 0%~10% and the multiple weighting material such as the flyash etc. 20%~60% of ethyl cyanoacetate and methyl cyanoacetate.With tankage, saltcake, alunite, lime and the weighting material of institute's certainty ratio (as being crushed to for bulk less than 3mm or specific surface area greater than 300m
2/ kg) wait weighing, mix even, promptly obtain admixture of the present invention.
Admixture of the present invention is carried out the cement intensifier experiment, and its data are as follows:
The cyanogen root that is contained among the present invention with prescription in after each composition combined reaction, its content GTM is by original 76/1000000ths, be reduced to 8/1000000ths, simultaneously when grinding cement, because grinding machine surpasses 80 degree, reached 80 degree boiling points of cyanogen root, thereby the cyanogen radical content is further reduced, the finished product will be non-toxic substances.
Admixture of the present invention has mainly been used:
1) be used to mix system cement concrete or mortar:
Mixing 0.6~1 part of this admixture for per hundred parts can reduce by 10~25 parts cement consumption and substitute with mineral admixture;
2) be used for Cement Production:
(1) improve the cement quality grade and do not change the manufacture of cement proportioning, mix 0.6~1 part of this admixture for per hundred parts, the cement 3d that is produced, 28d intensity can increase a grade (former 32.5 grades of proportionings can be produced 42.5 class g cements);
(2) reduce the manufacture of cement cost and mix 0.6~1 part of this admixture for per hundred parts, can increase by 6~15 parts of blended material addition contents, the cement of production is identical with former proportioning or close;
(3) improve per hundred parts of soundness of cement and mix 0.6~1 part of this admixture, can improve and mill soundness qualification rate;
(4) shorten cement setting time and mix 0.6~1 part of this admixture for per hundred parts, cement setting time can shorten 0.5~1.5 hour.Help rapid construction and shorten demould time;
(5) improve cement mill output and mix this admixture for per hundred parts and grind cement for 0.6~1 part, mill output can improve 5%~10%.
The invention has the beneficial effects as follows: adopt admixture of the present invention, can improve cement performance, increase blended material addition content in the cement, reduce the manufacture of cement cost; This admixture has higher economic benefit and environmental benefit with useless (tankage in ethyl cyanoacetate and the methyl cyanoacetate production) sharp useless (flyash, slag, slag etc.); Admixture is turned waste into wealth, and has solved the pollution problem of ethyl cyanoacetate and the methyl cyanoacetate tankage in producing to environment, and has created benefit for factory; Admixture of the present invention utilizes the beneficiating ingredient in the tankage, belongs to inorganic organic compound additive; The main raw material stable components of admixture of the present invention, can guarantee join the quality of admixture.
Embodiment
The invention will be further described below in conjunction with embodiment.
Its moiety of grinding aid of the present invention is counted by weight, 30~70 parts of the tankage of ethyl cyanoacetate or methyl cyanoacetate, 20~60 parts in 0~30 part in saltcake, 0~20 part of alunite, 0~10 part in lime and weighting material wait weighing, mix evenly to get final product their.When wherein containing lime, can mix evenly after, leave standstill one night better effects if.
Embodiment 1:
The admixture proportioning, by weight: 30 parts of tankage, 20 parts of alunites, 5 parts in 15 parts of lime of saltcake, 30 parts in flyash.
Be used to mix the system concrete, 1 part in admixture said ratio admixture pulvis (accounting for the agglutinate quality), former C30 concrete proportioning: 100 parts of cement, existing concrete proportioning: 80 parts of cement, 10 parts of slag powders, 10 parts in flyash, gained concrete strength unanimity.
Embodiment 2:
The admixture proportioning, by weight: 30 parts of tankage, 20 parts of alunites, 20 parts in saltcake, 30 parts in flyash.
Be used to grind cement, former jelling time 4:10, final setting time 5:45,3d, 28d intensity are respectively 18.6Mpa, 41.5Mpa; 1 part of admixture said ratio admixture, jelling time 3:35, final setting time 4:30, soundness of cement is qualified, and 3d, 28d intensity are respectively 22.7Mpa, 46.3Mpa.
Embodiment 3:
The admixture proportioning, by weight: 30 parts of tankage, 20 parts of alunites, 20 parts in saltcake, 30 parts in flyash.
Be used to grind cement, former jelling time 4:25, final setting time 5:30,3d, 28d intensity are respectively 18.6Mpa, 41.5Mpa; 1 part of admixture said ratio admixture, simultaneously with 15 parts of slag powders place of cement grogs, jelling time 4:15, final setting time 5:10, soundness of cement is qualified, and 3d, 28d intensity are respectively 18.2Mpa, 42.3Mpa.
Claims (3)
1. concrete reinforced abrasion-aided additive; it is characterized in that: its moiety is counted by weight; 30~70 parts of the tankage of ethyl cyanoacetate or methyl cyanoacetate; these tankage contain 20~60 parts in ethanol 8%, sulfuric acid 0.4%, nitrogen 0.3%, sodium 83%, cyanogen root GTM 76/1000000ths, 0~30 part in saltcake, 0~20 part of alunite, 0~10 part in lime and powder shape Mineral feedstock weighting material; this material weighting material is rubble powder, crushed slag, granulated blast-furnace slag or flyash, and their weighings, mix are evenly got final product.
2. the application of the described concrete reinforced abrasion-aided additive of claim 1 is characterized in that: when mixing the system concrete, by weight: 60~100 parts of cement, 0~20 part of slag powders, 0~20 part in flyash, 0.6~1 part of admixture said ratio admixture.
3. the described concrete reinforced abrasion-aided additive of claim 1 is used, and it is characterized in that: whenever grind 100 parts by weight of cement, admixture said ratio admixture 0.6~1 weight part.
Priority Applications (1)
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CN200710013699A CN101037311B (en) | 2007-03-21 | 2007-03-21 | Concrete reinforced abrasion-aided additive and its application |
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CN200710013699A CN101037311B (en) | 2007-03-21 | 2007-03-21 | Concrete reinforced abrasion-aided additive and its application |
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CN101037311A CN101037311A (en) | 2007-09-19 |
CN101037311B true CN101037311B (en) | 2010-05-19 |
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CN200710013699A Expired - Fee Related CN101037311B (en) | 2007-03-21 | 2007-03-21 | Concrete reinforced abrasion-aided additive and its application |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103011653B (en) * | 2012-12-13 | 2014-07-09 | 安徽珍珠水泥集团股份有限公司 | Preparation process of polyglycerol cement grinding aid |
CN105541171B (en) * | 2015-12-18 | 2018-10-02 | 卓达新材料科技集团威海股份有限公司 | A kind of additive for foam cement |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1240774A (en) * | 1999-08-06 | 2000-01-12 | 宋延秋 | Grinding-helping and reinforcing additive of cement |
CN1346812A (en) * | 2001-08-14 | 2002-05-01 | 刘长林 | Grinding aid for cement |
CN1896025A (en) * | 2005-07-12 | 2007-01-17 | 山东省华冠建材技术开发有限公司 | Cement grinding aid and its preparation |
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2007
- 2007-03-21 CN CN200710013699A patent/CN101037311B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1240774A (en) * | 1999-08-06 | 2000-01-12 | 宋延秋 | Grinding-helping and reinforcing additive of cement |
CN1346812A (en) * | 2001-08-14 | 2002-05-01 | 刘长林 | Grinding aid for cement |
CN1896025A (en) * | 2005-07-12 | 2007-01-17 | 山东省华冠建材技术开发有限公司 | Cement grinding aid and its preparation |
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