CN101032705A - Massifying method of medical stone ultra fines produced by waterproof pulverization and concentrated solution - Google Patents
Massifying method of medical stone ultra fines produced by waterproof pulverization and concentrated solution Download PDFInfo
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- CN101032705A CN101032705A CN 200710098655 CN200710098655A CN101032705A CN 101032705 A CN101032705 A CN 101032705A CN 200710098655 CN200710098655 CN 200710098655 CN 200710098655 A CN200710098655 A CN 200710098655A CN 101032705 A CN101032705 A CN 101032705A
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- medical stone
- wet grinding
- concentrate
- superfine powder
- filtrate
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- 239000004575 stone Substances 0.000 title claims abstract description 82
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000010298 pulverizing process Methods 0.000 title abstract 3
- 239000000843 powder Substances 0.000 claims abstract description 27
- 239000002366 mineral element Substances 0.000 claims abstract description 13
- 239000000706 filtrate Substances 0.000 claims abstract description 11
- 238000005516 engineering process Methods 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 6
- 239000012141 concentrate Substances 0.000 claims description 32
- 238000001238 wet grinding Methods 0.000 claims description 26
- 238000002360 preparation method Methods 0.000 claims description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- 235000013312 flour Nutrition 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000012856 packing Methods 0.000 abstract description 5
- 239000000047 product Substances 0.000 abstract description 4
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 238000007865 diluting Methods 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 238000000227 grinding Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000007654 immersion Methods 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000009700 powder processing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 feed Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 230000001089 mineralizing effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The present invention belongs to the field of powder preparing technology and health product producing technology, and is especially integrated wet pulverizing process for preparing superfine Chinese medicinal stone powder and concentrated Chinese medicinal stone liquid. The process includes the following steps: wet pulverizing Chinese medicinal stone to prepare slurry, filtering to obtain filtrate and filter residue, diluting the filtrate and packing as concentrated Chinese medicinal stone liquid, and stoving, crushing and packing the filter residue to obtain superfine Chinese medicinal stone powder. The said production process has the features of high concentrated Chinese medicinal stone liquid producing efficiency, high mineral element leaching rate, being suitable for large scale production, etc.
Description
Technical field
The invention belongs to powder technology of preparing and health products preparing technical field.Being particularly related to a kind of processing method of medical stone product, specifically is that a kind of wet grinding prepares medical stone superfine powder and the incorporate method of medical stone concentrate.
Background technology
Medical stone is a kind of subvolcano rock rice stone stone, because of its outward appearance is gained the name like the rice rice dumpling.Inside has the mesh-like structure of pores'growth, and constant, trace and the trace element of energy stripping needed by human body have the ability that poisonous and hazardous heavy metal in the water, organic matter, bacterium, virus and peculiar smell etc. are removed in absorption simultaneously behind the water logging bubble.Since the 1980s, at the property of medical stone, developed a series of health cares, functional product, as be used for water treatment field, do water purification, mineralizing material; Be used for animals and plants and culture, do feed or fertilizer; Do the function fiberfill; Do mineral drug etc.
The medical stone processing method comprises powder processing and particle processing at present, and particle processing is to adopt pulverizer to be crushed to certain particle size, does mineralising then, purifies material for water treatment; Powder processing is that employing ball mill dry method grinding becomes the fine powder about 600 orders, does the raw material of crawl, deodorant for refregerator, water purification mineralising, sandwich pillow eliminating smell agent, toilet eliminating smell agent, feed, fertilizer, mineral drug etc. then.And the preparation method of medical stone concentrate is: adopt dry method grinding medical stone, then fine powder is passed through immersion treatment, the stripping mineral element carries out concentration again.Shortcoming is: the medical stone process is that powder preparation and concentrate preparation are carried out respectively, and mineral element dissolution rate, production efficiency and medical stone utilization rate are low in the medical stone, influence large-scale production.
Summary of the invention
The objective of the invention is the shortcoming that exists in existing medical stone powder and the concentrate process, provide a kind of wet grinding to prepare medical stone superfine powder and medical stone concentrate integral method, have medical stone utilization rate and production efficiency height, the mineral element dissolution rate is big, easy characteristics such as large-scale production.
For achieving the above object, the present invention has taked following technical scheme:
Wet grinding prepares medical stone superfine powder and medical stone concentrate integral method, comprises the steps:
(1) the medical stone wet grinding prepares slurry: with omnipotent flour mill medical stone is roughly ground to 60～80 orders, in the ball mill of packing into, total filling amount is 70～80%, adds entry again, and solid-to-liquid ratio is 1: 1～2: 1, carries out wet grinding, and milling time is 10～30 hours;
(2) filtering the medical stone slurry is filtrate and filter residue;
(3) filtrate is through dilution, and canned is medical stone mineral element concentrate;
(4) filter residue is through drying, break up and pack preparation medical stone superfine powder.
Wherein, the medical stone grinding adopts wet ball grinding, and abrasive media is alumina balls, zirconia ball or agate ball.
Medical stone filters and adopts plate and frame filter press.
Preparation medical stone concentrate: it is about 400-600 that filtrate filtered is diluted to TDS, and canned is medical stone mineral element concentrate;
Preparation medical stone superfine powder: the filter residue after will filtering is dried in drying baker, breaks up packing.
Compared with the prior art, the present invention has following beneficial effect:
1. the medical stone wet grinding prepares medical stone superfine powder and medical stone concentrate integral method, has the high characteristics of production efficiency.
2. when wet ball grinding, collision between medical stone and abrasive media, ball mill barrel, friction make the mineral element stripping under the mechanical force invigoration effect in the medical stone, and the mineral element dissolution rate improves, the kind of mineral element stripping increases, and the nutrient source material in the medical stone concentrate is abundanter.
3. medical stone superfine powder, because a large amount of mineral element strippings are arranged, inner duct is more unimpeded, and its absorption property is stronger, and the raw material of using as fields such as water treatment, deodorizing, feed, breed has more advantage.
The specific embodiment
The invention provides a kind of wet grinding and prepare medical stone superfine powder and medical stone concentrate integral method.
Embodiment 1
Medical stone wet grinding and preparation medical stone concentrate integral method comprise the steps:
(1) the medical stone wet grinding prepares slurry: medical stone through the jaw crusher coarse crushing, is milled to about 60 orders with omnipotent flour mill meal again, carries out wet grinding.Solid-to-liquid ratio is 2: 1, and total filling amount is 80%, and abrasive media is alumina balls, and milling time is 12 hours.
(2) adopting plate and frame filter press is filtrate and filter residue with above-mentioned medical stone slurries filtration;
(3) filtrate filtered is diluted to about TDS 400-600, canned is medical stone mineral element concentrate;
(4) filter cake after will filtering is broken up 120 ℃ of oven dry down, and packing is prepared into the medical stone superfine powder.
Embodiment 2
Same with embodiment 1, just abrasive media is a zirconia ball, and total filling amount is 70%.
Embodiment 3
(1) with the coarse crushing of medical stone process jaw crusher, be milled to about 80 orders with omnipotent flour mill meal, carry out wet grinding, its solid-to-liquid ratio is 1: 1, and total filling amount is 80%, and abrasive media is an agate ball, and milling time is 24 hours; Later on embodiment 1.
Comparative Examples 1
Below prepare medical stone superfine powder and medical stone concentrate integral method and dry method grinding medical stone, immersion and produced the medical stone concentrate in 96 hours and compare, the results are shown in shown in the table 1 of back with embodiment 1,2,3 described medical stone wet grindings.
Table 1 embodiment of the invention and dry method grinding soak the representative concentration of element contrast of medical stone concentrate again
| Embodiment 1 (oxygen aluminium ball wet-milling concentrate) | Embodiment 2 (zirconia ball wet-milling concentrate) | Embodiment 3 (agate ball wet-milling concentrate) | Dry method grinding (96 hours immersion concentrates) | Embodiment soaked concentrate in 2/96 hour | |
| Calcium (mg/L) | 85.824 | 113.51 | 65.334 | 38.176 | 2.973 |
| Potassium (mg/L) | 153.9618 | 184.212 | 95.275 | 1.576 | 116.886 |
| Magnesium (mg/L) | 19.3793 | 27.315 | 16.654 | 10.478 | 2.607 |
| Sodium (mg/L) | 667.221 | 707.616 | 500.290 | 45.884 | 15.422 |
| Strontium (mg/L) | 0.172 | 1.105 | 0.099 | 0.221 | 5.002 |
| Lithium (mg/L) | 0.542 | 0.834 | 0.452 | 0.05 | 16.688 |
| Zinc (mg/L) | 0.196 | 0.222 | 0.109 | 0.031 | 7.174 |
| Iron (mg/L) | 6.744 | 17.275 | 2.334 | 0.038 | 401.990 |
| Manganese (mg/L) | 0.160 | 0.434 | 0.089 | 0.853 | 0.509 |
| Copper (mg/L) | ＜0.006 | ＜0.012 | ＜0.006 | 0.024 | ＜0.500 |
| Plumbous (mg/L) | 0.225 | 0.095 | 0.025 | ＜0.006 |
As shown in Table 1: the medical stone wet grinding prepares the concentrate concentration of medical stone superfine powder and the preparation of medical stone concentrate integral method and produced the medical stone concentrate in 96 hours apparently higher than dry method grinding medical stone, immersion; And having characteristics such as technology is simple, health, production efficiency height, is a kind of new medical stone production technology, is a kind of desirable production medical stone powder and the production method of medical stone concentrate, is worth further research and development.
Above-mentioned filtrate filtered is diluted among the TDS 400-600 total dissolved solid in the TDS ie in solution, solution chats matter-element have multiple, and how many difference of content are very big, and with a kind of concentration qualification, general way is to explain with TDS not too easily.
Claims (4)
1. a wet grinding prepares medical stone superfine powder and medical stone concentrate integral method, it is characterized in that, wet grinding is prepared medical stone ultra-fine powder technology and mineral element extractive technique are molten to be one, comprises the steps:
(1) the medical stone wet grinding prepares slurry: with flour mill medical stone is roughly ground to 60～80 orders, reinstalled in the wet grinding machine, total filling amount is 70～80%, adds entry, and solid-to-liquid ratio is 1: 1～2: 1, carries out wet grinding, and milling time is 10～30 hours;
(2) filtering the medical stone slurry is filtrate and filter residue;
(3) filtrate through the dilution, canned be medical stone mineral element concentrate;
(4) filter residue is through drying, break up and pack preparation medical stone superfine powder.
2. prepare medical stone superfine powder and medical stone concentrate integral method according to the described wet grinding of claim 1, it is characterized in that, the flour mill that is adopted in the described step (1) is ball mill, stirs and grind or vibromill.
3. prepare medical stone superfine powder and medical stone concentrate integral method according to the described wet grinding of claim 1, it is characterized in that, the medium of wet grinding is aluminium oxide, zirconia or agate material in the described step (1).
4. prepare medical stone superfine powder and medical stone concentrate integral method according to the described wet grinding of claim 1, it is characterized in that, described step is diluted to TDS 400-600 with filtrate in (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100986557A CN100506389C (en) | 2007-04-24 | 2007-04-24 | Massifying method of medical stone ultra fines produced by waterproof pulverization and concentrated solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100986557A CN100506389C (en) | 2007-04-24 | 2007-04-24 | Massifying method of medical stone ultra fines produced by waterproof pulverization and concentrated solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101032705A true CN101032705A (en) | 2007-09-12 |
| CN100506389C CN100506389C (en) | 2009-07-01 |
Family
ID=38729561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100986557A Expired - Fee Related CN100506389C (en) | 2007-04-24 | 2007-04-24 | Massifying method of medical stone ultra fines produced by waterproof pulverization and concentrated solution |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100506389C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101999483A (en) * | 2010-10-13 | 2011-04-06 | 张建华 | Medical stone healthcare tea |
| CN104475213A (en) * | 2014-11-10 | 2015-04-01 | 张藜泷 | Method for preparing ultra-fine Hetian jade powder |
| CN107215926A (en) * | 2017-07-19 | 2017-09-29 | 北京建元天地环保科技有限公司 | A kind of alkalescent drinking water manufacture method containing electronics and ionization mineral matter |
-
2007
- 2007-04-24 CN CNB2007100986557A patent/CN100506389C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101999483A (en) * | 2010-10-13 | 2011-04-06 | 张建华 | Medical stone healthcare tea |
| CN104475213A (en) * | 2014-11-10 | 2015-04-01 | 张藜泷 | Method for preparing ultra-fine Hetian jade powder |
| CN107215926A (en) * | 2017-07-19 | 2017-09-29 | 北京建元天地环保科技有限公司 | A kind of alkalescent drinking water manufacture method containing electronics and ionization mineral matter |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100506389C (en) | 2009-07-01 |
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