CN101030658A - Method for producing lithium-ion battery and lithium-ion battery - Google Patents
Method for producing lithium-ion battery and lithium-ion battery Download PDFInfo
- Publication number
- CN101030658A CN101030658A CNA2006100599761A CN200610059976A CN101030658A CN 101030658 A CN101030658 A CN 101030658A CN A2006100599761 A CNA2006100599761 A CN A2006100599761A CN 200610059976 A CN200610059976 A CN 200610059976A CN 101030658 A CN101030658 A CN 101030658A
- Authority
- CN
- China
- Prior art keywords
- ion battery
- lithium ion
- baking
- manufacture method
- battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims description 25
- 238000000034 method Methods 0.000 claims abstract description 21
- 238000000576 coating method Methods 0.000 claims abstract description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 3
- 239000003570 air Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000010304 firing Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 7
- 229910052744 lithium Inorganic materials 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- -1 EC) Chemical compound 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000011245 gel electrolyte Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- CJYZTOPVWURGAI-UHFFFAOYSA-N lithium;manganese;manganese(3+);oxygen(2-) Chemical compound [Li+].[O-2].[O-2].[O-2].[O-2].[Mn].[Mn+3] CJYZTOPVWURGAI-UHFFFAOYSA-N 0.000 description 1
- VROAXDSNYPAOBJ-UHFFFAOYSA-N lithium;oxido(oxo)nickel Chemical compound [Li+].[O-][Ni]=O VROAXDSNYPAOBJ-UHFFFAOYSA-N 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention is concerned with manufacture method of the lithium ion cell, consists of: matches the material, coatings, makes slice, assembly, infuses liquid, pre-charge, seals the opening, the characteristic is: includes the step that is firing the cell after the pre-charge. The invention can eject the residue gas in the cell after the pre-charge in order to avoid the safety hidden trouble.
Description
[technical field]
The present invention relates to the lithium ion battery field, be specifically related to the manufacture method and the battery of lithium ion battery.
[technical background]
In recent years, the function of computer, communication electronic product and consumption electronic products is more and more stronger, and its overall dimension requirement is more and more littler, quality is more and more lighter, so high power capacity, undersized battery product receive an acclaim.Lithium ion battery particularly, characteristics such as capacity is big, energy density is high, voltage height that it has constantly rise in the occupation rate of market of products such as mobile phone, notebook computer, digital camera.
Lithium ion battery is with lithium and cobalt oxides (LiCoO
2), lithium nickel oxide (LiNiO
2) or lithium manganese oxide (LiMn
2O
4) wait and be positive electrode active materials, be negative active core-shell material with lithium metal, lithium alloy or material with carbon element.Its electrolyte can use liquid state organic electrolyte or solid gel electrolyte, and the latter is called lithium polymer battery (Lithium Polymer Battery) again, and commonly used is liquid electrolyte at present.The liquid electrolyte that lithium ion battery uses is organic non-aqueous solution, as ethylene carbonate (EthyleneCarbonate, EC), diethyl carbonate (Diethyl Carbonate, mixture DEC) is a solvent, with lithium salts (as LiPF
6) be solute, and add a small amount of additive and form.
The lithium ion battery production technology generally comprises following steps: the assembling of both positive and negative polarity batching → both positive and negative polarity coating → both positive and negative polarity film-making → electric core → → fluid injection and preliminary filling → seal.Because battery is in charge and discharge process, the polarity active material of battery can produce in some gases, particularly preliminary filling process with the electrolyte reaction, and the gas of generation is more, as untimely discharge, will bring potential safety hazard to battery.
[summary of the invention]
At the deficiency of above present lithium ion battery production technology, the object of the present invention is to provide a kind of inside battery gas behind the preliminary filling can the discharge, avoid bringing the lithium ion battery manufacture method of potential safety hazard to battery.
Another object of the present invention is to provide a kind of lithium ion battery made from said method.
For achieving the above object, the present invention is by the following technical solutions:
A kind of lithium ion battery manufacture method, step such as it comprises batching, coating, film-making, assembling, fluid injection, preliminary filling, seal is characterized in that: also comprise the step that the battery behind the preliminary filling is toasted.
The further part of this technical scheme is: the battery behind the preliminary filling is positioned in the baking oven toasts, and use the dry gas protection.
Above-mentioned dry gas comprises dry air, nitrogen, inert gas etc., preferred nitrogen.
The temperature of toasting in the said method is 40-80 ℃, preferred 55-65 ℃, and most preferably 60 ℃.
The time of toasting in the said method is 4-8 hour, preferred 5-7 hour, and most preferably 6 hours.
The present invention also provides a kind of lithium ion battery made from said method.
Adopting said method to compare the beneficial effect that is produced with prior art is: by increasing the step of baking, can more completely the gas that remains in inside battery behind the preliminary filling be discharged, thereby avoid because the potential safety hazard that residual gas brings to battery.
[embodiment]
The invention provides a kind of lithium ion battery manufacture method, step such as it comprises batching, coating, film-making, assembling, fluid injection, preliminary filling, seal is characterized in that: also comprise the step that the battery behind the preliminary filling is toasted.By the battery behind the preliminary filling is toasted, can more completely the gas that remains in inside battery behind the preliminary filling be discharged, thereby avoid because the potential safety hazard that residual gas brings to battery.The temperature why the present invention selects to toast is 40-80 ℃, is because if the temperature of baking is when being lower than 40 ℃, and the efficient of baking is not high can not discharge residual gas more completely, and the time of baking is longer, has prolonged the battery manufacturing cycle; When being higher than 80 ℃, return electrolyte volatilization on the one hand with liquid state, bring adverse effect to battery performance, temperature is too high on the other hand, can destroy the battery positive/negative plate barrier film, and barrier film is a macromolecular material, and the contraction situation appears in the too high meeting of temperature.The time why selection is toasted is 4-8 hour, is because the time too short (<4 hours), baking not exclusively can not drain residual gas; Stoving time long (>8 hours) has prolonged production cycle of battery.Be because avoided moisture to enter battery with dry gas protection when battery toasts in baking oven, bring adverse effect to battery, preferred nitrogen be because, the nitrogen price is compared with inert gas and is not too expensive, to compare composition single with air.To further specify realization of the present invention with concrete example below.
Embodiment 1
Make battery according to usual technology, place baking oven to toast on battery behind the preliminary filling, use dry air to protect, temperature of oven is 40 ℃, and the time of baking is 8 hours.Baking such as seals after finishing at subsequent handling.
Embodiment 2
Make battery according to usual technology, place baking oven to toast on battery behind the preliminary filling, use drying nitrogen to protect, temperature of oven is 55 ℃, and the time of baking is 7 hours.Baking such as seals after finishing at subsequent handling.
Embodiment 3
Make battery according to usual technology, place baking oven to toast on battery behind the preliminary filling, use dry helium gas to protect, temperature of oven is 65 ℃, and the time of baking is 5 hours.Baking such as seals after finishing at subsequent handling.
Embodiment 4
Make battery according to usual technology, place baking oven to toast on battery behind the preliminary filling, use dry argon gas to protect, temperature of oven is 55 ℃, and the time of baking is 6 hours.Baking such as seals after finishing at subsequent handling.
Embodiment 5
Make battery according to usual technology, place baking oven to toast on battery behind the preliminary filling, use drying nitrogen to protect, temperature of oven is 60 ℃, and the time of baking is 6 hours.Baking such as seals after finishing at subsequent handling.
Claims (10)
1. lithium ion battery manufacture method, step such as it comprises batching, coating, film-making, assembling, fluid injection, preliminary filling, seal is characterized in that: also comprise the step that the battery behind the preliminary filling is toasted.
2. lithium ion battery manufacture method according to claim 1 is characterized in that: described baking is the battery behind the preliminary filling to be positioned in the baking oven toast, and uses the dry gas protection.
3. lithium ion battery manufacture method according to claim 2 is characterized in that: dry gas comprises dry air, nitrogen, inert gas etc., preferred nitrogen.
4. lithium ion battery manufacture method according to claim 2 is characterized in that: the temperature of described baking is 40-80 ℃.
5. lithium ion battery manufacture method according to claim 2 is characterized in that: the preferred 55-65 of the temperature of described baking ℃, and most preferably 60 ℃.
6. lithium ion battery manufacture method according to claim 2 is characterized in that: the time of baking is 4-8 hour.
7. lithium ion battery manufacture method according to claim 2 is characterized in that: preferred 5-7 of the time of baking hour, and most preferably 6 hours.
8. lithium ion battery manufacture method according to claim 2 is characterized in that: dry gas comprises dry air or nitrogen, and the temperature of baking is 55-65 ℃, and stoving time is 5-7 hour.
9. lithium ion battery manufacture method according to claim 2 is characterized in that: described dry gas is a nitrogen, and stoving time is 6 hours, and baking temperature is 60 ℃.
10. use the lithium ion battery of above-mentioned either party's manufactured.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2006100599761A CN101030658A (en) | 2006-03-04 | 2006-03-04 | Method for producing lithium-ion battery and lithium-ion battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2006100599761A CN101030658A (en) | 2006-03-04 | 2006-03-04 | Method for producing lithium-ion battery and lithium-ion battery |
Publications (1)
Publication Number | Publication Date |
---|---|
CN101030658A true CN101030658A (en) | 2007-09-05 |
Family
ID=38715820
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2006100599761A Pending CN101030658A (en) | 2006-03-04 | 2006-03-04 | Method for producing lithium-ion battery and lithium-ion battery |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101030658A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103344097A (en) * | 2013-06-03 | 2013-10-09 | 奇瑞汽车股份有限公司 | Lithium ion battery cell drying method and lithium ion battery |
WO2018054231A1 (en) * | 2016-09-22 | 2018-03-29 | Grst International Limited | Method of drying electrode assemblies |
CN109119695A (en) * | 2018-08-25 | 2019-01-01 | 浙江谷神能源科技股份有限公司 | A kind of big cylinder lithium-ion electric core baking method |
-
2006
- 2006-03-04 CN CNA2006100599761A patent/CN101030658A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103344097A (en) * | 2013-06-03 | 2013-10-09 | 奇瑞汽车股份有限公司 | Lithium ion battery cell drying method and lithium ion battery |
WO2018054231A1 (en) * | 2016-09-22 | 2018-03-29 | Grst International Limited | Method of drying electrode assemblies |
CN109119695A (en) * | 2018-08-25 | 2019-01-01 | 浙江谷神能源科技股份有限公司 | A kind of big cylinder lithium-ion electric core baking method |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C12 | Rejection of a patent application after its publication | ||
RJ01 | Rejection of invention patent application after publication |
Open date: 20070905 |