CN101029261A - Fuel-oil coking slurry - Google Patents

Fuel-oil coking slurry Download PDF

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Publication number
CN101029261A
CN101029261A CN 200610058278 CN200610058278A CN101029261A CN 101029261 A CN101029261 A CN 101029261A CN 200610058278 CN200610058278 CN 200610058278 CN 200610058278 A CN200610058278 A CN 200610058278A CN 101029261 A CN101029261 A CN 101029261A
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China
Prior art keywords
slurry
coke
fuel
additive
liquid medium
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CN 200610058278
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CN100545247C (en
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朱复东
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JIANGSU DONGJIA ENERGY SCIENCE & TECHNOLOGY Co.,Ltd.
Jiangsu Gongbo Environmental Protection Energy Research Institute Co ltd
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Individual
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Abstract

A fuel-oil coke slurry, its production and use are disclosed. The fuel-oil coke slurry consists of petrol coke 3-7 proportion, liquid medium 3-7 proportion and additive 0.3-1 proportion. The ash content is blow 1%. It's simple and convenient and can be used in various occasions.

Description

A kind of fuel-oil coking slurry
Technical field
The present invention relates to a kind of fuel, relate in particular to a kind of fuel-oil coking slurry, its preparation method and application, belong to chemical field.
Background technology
Existing refinery coke can be used as solid fuel, but can't replace oil (gas) to carry out spray burning.Existing coal water slurry is a kind of fuel slurry that is mixed by coal, water, additive, but in many occasions, such as calcar, high-grade kiln for ceramic tiles etc., can not use coal water slurry acts as a fuel, major cause is that the ash of coal water slurry is too high, also is unpractical below 1% even select for use washed coal under existing coal preparation technology condition ash to be reduced to.So need a kind of new fuel, the ash that is produced after this fuel combustion can be controlled at below 1% always,, be applied to require the occasion of ultra-low ash content in order to replace oil (gas) fuel.
Summary of the invention
The present invention's technical problem at first to be solved is to overcome the deficiencies in the prior art, and a kind of new fuel is provided, and the ash that is produced after this fuel combustion can be controlled at below 1%, can replace oil (gas) fuel, is applied to require the occasion of ultra-low ash content.
The present invention's technical problem at first to be solved realizes by following technological approaches:
A kind of fuel-oil coking slurry, form by the component of following weight part:
Refinery coke 3-7 part, liquid medium 3-7 part, additive 0.3-1 part.
Wherein, described liquid medium is selected from any in water, sanitary wastewater or the trade effluent, or more than one mixtures formed with arbitrary proportion in them.Described water does not have special requirement, tap water, rivers water or spring all can, comprise sanitary wastewater, trade effluent, as long as they in non-combustible impurity below 1 ‰.
Described additive is selected from Vltra tears, hydroxypropylcellulose, methylcellulose gum, stearic acid, oleic acid, alkylbenzene sulfonate, sulfonated alkyl naphathalene, alkyl phenol polyoxyethylene glycol ether vitriol, fatty alcohol polyglycol ether vitriol, ethoxylized fatty alcohol, ethoxylated alkylphenol, oxidation coco dimethyl amine, coco amine, the dimethyl lauryl amine, coco dimethyl amine, N-butter-1,3-diaminopropanes, in cetyltrimethylammonium chloride or the chlorination h-tallow trimethyl ammonium any, or their more than one mixtures of being formed with arbitrary proportion.
Preferably, the weight part of each component is:
Refinery coke 6-7 part, liquid medium 3-4 part, additive 0.5-0.8 part.
Used refinery coke and additive all can be bought from market and obtain among the present invention.
Another technical problem to be solved by this invention provides a kind of method for preparing above-mentioned fuel-oil coking slurry.
Another technical problem to be solved by this invention realizes by following technological approaches:
A kind of method for preparing fuel-oil coking slurry may further comprise the steps:
(1) take by weighing each raw material by following weight part:
Refinery coke 3-7 part, liquid medium 3-7 part, additive 0.3-1 part; Wherein, described liquid medium is selected from any in water, sanitary wastewater or the trade effluent, or more than one mixtures formed with arbitrary proportion in them; Described additive is selected from Vltra tears, hydroxypropylcellulose, methylcellulose gum, stearic acid, oleic acid, alkylbenzene sulfonate, sulfonated alkyl naphathalene, alkyl phenol polyoxyethylene glycol ether vitriol, fatty alcohol polyglycol ether vitriol, ethoxylized fatty alcohol, ethoxylated alkylphenol, oxidation coco dimethyl amine, coco amine, the dimethyl lauryl amine, coco dimethyl amine, N-butter-1,3-diaminopropanes, in cetyltrimethylammonium chloride or the chlorination h-tallow trimethyl ammonium any, or their more than one mixtures of being formed with arbitrary proportion;
(2) refinery coke, liquid medium and the additive with above-mentioned weight part grinds (the coke powder material that is ground in the slurry directly reaches 5-30 μ m) together according to conventional wet method (such as in ball mill), promptly; Or earlier the refinery coke dry grinding to be become particle diameter be the dried coke powder of 5-30 μ m, mixes and stirs into the oil coke slurry with liquid medium and additive again.
The using method of fuel-oil coking slurry of the present invention and the scope of application:, on Industrial Boiler, station boiler, Industrial Stoves, replace the oil gas use with being pumped to oil coke slurry burner and compressed air or steam atomizing afterfire after oil coke slurry of the present invention stirring, the filtration.
Fuel-oil coking slurry of the present invention is a component with refinery coke, liquid medium and additive.Refinery coke unit's calorific value is than coal height, and ash is again far below coal, thereby can be used in the occasion that requires low ash and replace oil (gas) burning.
Refinery coke is the final product in the petroleum refining process.Refinery coke is divided into common Jiao (retard petroleum coke), three kinds of high-quality Jiao's (needle coke) and extraordinary refinery cokes by working accuracy and burnt quality.The refinery coke of these three kinds of specifications all can be used as the raw material of fuel-oil coking slurry of the present invention.Common Jiao, promptly retard petroleum coke claims green coke, oil coke, refinery coke again.Retard petroleum coke is divided into 7 grades, i.e. 6 salable product such as first grade and 1A, 1B, 2A, 2B, 3A, 3B by quality.Refinery coke is black or dimmed harder solid, have metalluster, be porousness, be to form the charcoal body thing that granular, column or needle-like constitute by small graphite crystallization, main component is a carbon, about carbon containing 90~97%, hydrogeneous 1.5~8%, contain a spot of nitrogen, chlorine, sulphur and other metallic compound and dirt simultaneously.Common Jiao is used to make electrode, insulating material, silicon carbide and metallurgy industry fuel.The burnt main Graphite Electrodes of high-quality as steel-making superpower and ultra high power.Extraordinary Jiao is production reactor nuclear graphite sleeve pipe raw material.Make through the heating pyrolyze refinery by various Residual oils, pitch or heavy oil in the refining of petroleum.
Refinery coke product quality specifications and test method: meet SH0527-92.See Table 1.
The table 1 refinery coke specification of quality and test method
Project Quality index Test method
First grade Salable product
1A 1B 2A 2B 3A 3B
Sulphur content, % is not more than 0.5 0.5 0.8 1.0 1.5 2.0 3.0 GB/T387
Volatile matter, % is not more than 12 12 14 17 18 20 SH/T0026
Ash content, % is not more than 0.3 0.3 0.5 0.8 1.2 SH/T0029
Moisture is not more than 3 SH/T0032
True density, g/cm 3 2.08~2.13 Report - SH/T0033
Powder coke content (piece grain 8mm is following), % is not more than 25 - Appendix A
Silicone content, % is not more than 0.08 - SH/T0058
Content of vanadium, % is not more than 0.015 - SH/T0058
Iron level, % is not more than 0.08 - SH/T0058
So the ash that fuel-oil coking slurry burning of the present invention back is produced can be controlled at below 1%, even the 3B refinery coke is made its ash of oil coke slurry back also below 1%.Can replace oil (gas) fuel applications in the occasion of various requirement ultra-low ash content.Advantages such as in addition, it is simple that the present invention also has technological operation, easy to implement.
Embodiment
Further describe the present invention below in conjunction with embodiment.Should be noted that these embodiment only are used for the purpose of illustration, do not constitute any limitation of the invention.
Embodiment 1
By following weight take by weighing each raw material (unit: kg):
Refinery coke 65, tap water 34.4, Vltra tears 0.6; Above-mentioned raw materials is mixed back wet grinding in ball mill, and the coke powder material that is ground in the slurry directly reaches 5-30 μ m, promptly.
Embodiment 2
By following weight take by weighing each raw material (unit: kg):
Refinery coke 60, seawater 38.2, alkylbenzene sulfonate 0.8; Above-mentioned raw materials is mixed back wet grinding in ball mill, and the coke powder material that is ground in the slurry directly reaches 5-30 μ m, promptly.
Embodiment 3
By following weight take by weighing each raw material (unit: kg):
Refinery coke 65, river 34.7, cetyltrimethylammonium chloride 0.3; Above-mentioned raw materials is mixed back wet grinding in ball mill, and the coke powder material that is ground in the slurry directly reaches 5-30 μ m, promptly.
Embodiment 4
By following weight take by weighing each raw material (unit: kg):
Refinery coke 80, trade effluent 118, alkylbenzene sulfonate 1, alkyl phenol polyoxyethylene glycol ether vitriol 0.4, ethoxylated alkylphenol 0.6 mixes back wet grinding in ball mill with above-mentioned raw materials, and the coke powder material that is ground in the slurry directly reaches 5-30 μ m, promptly.
Embodiment 5
It is dried coke powder below the 20 μ m that 65kg refinery coke dry grinding in ball mill is become particle diameter, adds the sanitary wastewater of 34kg then, adds sulfonated alkyl naphathalene 0.2kg again, stearic acid 0.3kg, and oleic acid 0.5kg mixes and stirs into the oil coke slurry.
Embodiment 6
It is dried coke powder below the 30 μ m that 50kg refinery coke dry grinding in ball mill is become particle diameter, adds the sanitary wastewater of 49kg then, adds coco dimethyl amine 0.2kg again, N-butter-1, and 3-diaminopropanes 0.8kg mixes and stirs into the oil coke slurry.

Claims (5)

1. fuel-oil coking slurry, form by the component of following weight part:
Refinery coke 3-7 part, liquid medium 3-7 part, additive 0.3-1 part; Wherein, described liquid medium is selected from any in water, sanitary wastewater or the trade effluent, or more than one mixtures formed with arbitrary proportion in them; Described additive is selected from Vltra tears, hydroxypropylcellulose, methylcellulose gum, stearic acid, oleic acid, alkylbenzene sulfonate, sulfonated alkyl naphathalene, alkyl phenol polyoxyethylene glycol ether vitriol, fatty alcohol polyglycol ether vitriol, ethoxylized fatty alcohol, ethoxylated alkylphenol, oxidation coco dimethyl amine, coco amine, the dimethyl lauryl amine, coco dimethyl amine, N-butter-1,3-diaminopropanes, in cetyltrimethylammonium chloride or the chlorination h-tallow trimethyl ammonium any, or their more than one mixtures of being formed with arbitrary proportion.
2. according to the fuel-oil coking slurry of claim 1, it is characterized in that the weight part of each component is:
Refinery coke 6-7 part, liquid medium 3-4 part, additive 0.5-0.8 part.
3. method for preparing fuel-oil coking slurry may further comprise the steps:
(1), take by weighing each raw material by following weight part:
Refinery coke 3-7 part, liquid medium 3-7 part, additive 0.3-1 part; Wherein, described liquid medium is selected from any in water, sanitary wastewater or the trade effluent, or more than one mixtures formed with arbitrary proportion in them; Described additive is selected from Vltra tears, hydroxypropylcellulose, methylcellulose gum, stearic acid, oleic acid, alkylbenzene sulfonate, sulfonated alkyl naphathalene, alkyl phenol polyoxyethylene glycol ether vitriol, fatty alcohol polyglycol ether vitriol, ethoxylized fatty alcohol, ethoxylated alkylphenol, oxidation coco dimethyl amine, coco amine, the dimethyl lauryl amine, coco dimethyl amine, N-butter-1,3-diaminopropanes, in cetyltrimethylammonium chloride or the chlorination h-tallow trimethyl ammonium any, or their more than one mixtures of being formed with arbitrary proportion;
(2), the refinery coke with above-mentioned weight part, liquid medium and additive grind together according to conventional wet method, promptly; Or earlier the refinery coke dry grinding to be become particle diameter be the dried coke powder of 5-30 μ m, mixes and stirs into the oil coke slurry with liquid medium and additive again.
4. the application of claim 1 or 2 fuel-oil coking slurry acts as a fuel it.
5. according to the application of claim 4, comprising: be pumped to oil coke slurry burner and compressed air or steam atomizing afterfire after described oil coke slurry is stirred, filters.
CNB200610058278XA 2006-02-28 2006-02-28 A kind of fuel-oil coking slurry Expired - Fee Related CN100545247C (en)

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Application Number Priority Date Filing Date Title
CNB200610058278XA CN100545247C (en) 2006-02-28 2006-02-28 A kind of fuel-oil coking slurry

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CN101029261A true CN101029261A (en) 2007-09-05
CN100545247C CN100545247C (en) 2009-09-30

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104845678A (en) * 2015-05-20 2015-08-19 江苏天诺道路材料科技有限公司 Solid-liquid mixed fuel and preparation method thereof
CN110511796A (en) * 2014-12-23 2019-11-29 罗地亚经营管理公司 Pulp suspension comprising the wood particle being fired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110511796A (en) * 2014-12-23 2019-11-29 罗地亚经营管理公司 Pulp suspension comprising the wood particle being fired
CN104845678A (en) * 2015-05-20 2015-08-19 江苏天诺道路材料科技有限公司 Solid-liquid mixed fuel and preparation method thereof

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